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Search Results (3,110)

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Keywords = physical activity environment

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28 pages, 3545 KiB  
Article
Including Citizens’ Perspective in Advancing Urban Green Infrastructure: A Design-Toolkit for Private Open Spaces
by Maria Stella Lux
Sustainability 2025, 17(15), 6781; https://doi.org/10.3390/su17156781 (registering DOI) - 25 Jul 2025
Abstract
In response to the growing pressure from urban expansion and the risks associated with climate change, adapting cities and reintroducing nature into the urban environment are becoming increasingly urgent. The implementation of Urban Green Infrastructure plays a key role in adaptation strategies, thanks [...] Read more.
In response to the growing pressure from urban expansion and the risks associated with climate change, adapting cities and reintroducing nature into the urban environment are becoming increasingly urgent. The implementation of Urban Green Infrastructure plays a key role in adaptation strategies, thanks to its ability to offer a wide range of ecosystem services. However, the adaptation process must necessarily be trans-scalar and include collective participation to ensure a real improvement in both physical and social urban resilience. For this reason, citizen participation in planning processes is essential, but even more important is the recognition of their active role and the scope for private citizens’ involvement. The transformation of private spaces according to UGI principles and with a view to the common interest, however, is still a theme that is scarcely included in urban resilience plans. This study presents the results of a survey conducted in the case study of Milan through questionnaires and focus groups to record preferences, concerns, and priorities in the sustainable transformation of private open spaces. The outcome of the study is the definition of a toolkit for the design of private open spaces, integrating Nature-Based Solutions and adhering to UGI principles. Full article
(This article belongs to the Section Sustainable Urban and Rural Development)
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17 pages, 560 KiB  
Article
Redefining Body-Self Relationships Through Outdoor Physical Activity: Experiences of Women Navigating Illness, Injury, and Disability
by Joelle Breault-Hood, Tonia Gray, Jacqueline Ullman and Son Truong
Behav. Sci. 2025, 15(8), 1006; https://doi.org/10.3390/bs15081006 - 24 Jul 2025
Abstract
Physical challenges such as illness, injury, and disability significantly alter women’s relationships with their bodies, disrupting established notions of functionality and self-worth. This study re-examines the Holistic Model of Positive Body Image and Outdoor Physical Activity through secondary analysis focusing on women with [...] Read more.
Physical challenges such as illness, injury, and disability significantly alter women’s relationships with their bodies, disrupting established notions of functionality and self-worth. This study re-examines the Holistic Model of Positive Body Image and Outdoor Physical Activity through secondary analysis focusing on women with illness, injury, and disability. From the original sample of N = 553 female participants, open-ended survey responses were identified from n = 84 participants (15.2%) who self-disclosed as having illness, injury, or disability to examine how outdoor settings facilitate positive body image. Through reflexive thematic analysis, the study revealed three key mechanisms: (1) personalized redefinition of functionality transcending standardized metrics, (2) therapeutic engagement with natural environments fostering embodied acceptance, and (3) cyclical reinforcement between physical capability and psychological wellbeing. The findings confirm the model’s utility while indicating necessary adaptations to address the fluctuating nature of body functionality. The adapted model emphasizes how outdoor recreational activities create contexts for reimagining body-self relationships across the spectrum of physical experiences—from temporary recovery to ongoing adaptation of persistent conditions—with implications for rehabilitation professionals, outdoor educators, and healthcare providers. Full article
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12 pages, 262 KiB  
Article
Sex Differences in Bench Press Strength and Power: A Velocity-Based Analysis Adjusted for Body Composition
by Olga López-Torres, Raúl Nieto-Acevedo, Amelia Guadalupe-Grau and Valentín Emilio Fernández Elías
J. Funct. Morphol. Kinesiol. 2025, 10(3), 284; https://doi.org/10.3390/jfmk10030284 - 24 Jul 2025
Abstract
Background: Resistance training (RT) promotes muscle hypertrophy and strength gains in both men and women. However, sex differences in neuromuscular performance, muscle fiber composition, and the hormonal environment influence strength and power adaptations. While men generally exhibit greater absolute and relative strength, it [...] Read more.
Background: Resistance training (RT) promotes muscle hypertrophy and strength gains in both men and women. However, sex differences in neuromuscular performance, muscle fiber composition, and the hormonal environment influence strength and power adaptations. While men generally exhibit greater absolute and relative strength, it remains unclear to what extent these differences persist across various load intensities. A better understanding of sex-specific strength and power profiles may help optimize training strategies. The aim of this study was to compare strength and power performance during the bench press exercise in physically active males and females, relative to body mass and fat-free mass (FFM). Methods: Twenty-nine physically active individuals (16 men: 21.3 ± 4.1 years, 13 women: 22.6 ± 4.9 years) performed a one-repetition maximum (1RM) test and an incremental velocity-based assessment at 45%, 55%, 65%, 75%, and 85% of the 1RM using a Smith machine. The barbell velocity was measured via a linear transducer, with the mean propulsive velocity (MPV) recorded for each load. Power-related variables (e.g., peak force [F0], maximal velocity [V0], and maximal power [Pmax]) were analyzed. To account for differences in body composition, data were adjusted for body mass and FFM. Results: Men exhibited significantly greater strength and power than women across most loads when adjusted for both body mass and fat-free mass (FFM) (p < 0.05). These differences were particularly pronounced when normalized to FFM (45–75%1RM; p = 0.001–0.031), with large effect sizes observed (ηp2 = 0.185–0.383). Notably, sex differences in mean propulsive velocity (MPV) disappeared at 85%1RM (p = 0.208; ηp2 = 0.06), suggesting that maximal neuromuscular recruitment may minimize sex-related disparities at higher intensities. Furthermore, men demonstrated significantly higher values in six of the seven power-related variables, with no significant differences in the %1RM required to achieve an optimal power output. Conclusions: These findings confirm that men exhibit greater strength and power than women, even after adjusting for body composition. However, at high relative loads (≥85%1RM), sex differences in movement velocity appear to diminish, likely due to similar recruitment patterns of high-threshold motor units. These results highlight the importance of sex-specific resistance training programs, particularly in relation to load prescription and the application of velocity-based training methods. Full article
14 pages, 623 KiB  
Article
Forest- and Nature-Based Recreation for Older Adults: Preferences, Well-Being, and the Need for Inclusive Planning
by Yaara Spiegel, Noga Collins-Kreiner and Eran Ketter
Forests 2025, 16(8), 1213; https://doi.org/10.3390/f16081213 - 23 Jul 2025
Viewed by 46
Abstract
This study provides user-centered insights into how inclusive forest design can support the physical, emotional, and social well-being of older adults. It operationalizes universal design principles in natural settings and confirms their relevance through empirical evidence. With the acceleration of global population aging, [...] Read more.
This study provides user-centered insights into how inclusive forest design can support the physical, emotional, and social well-being of older adults. It operationalizes universal design principles in natural settings and confirms their relevance through empirical evidence. With the acceleration of global population aging, adapting forest recreation environments to meet the specific needs of older adults is increasingly urgent. This study investigates how infrastructure influences both participation and emotional well-being among older visitors to forest recreation areas. Data were collected from 446 participants aged 65 and older, using a structured survey distributed through in-person contact and digital snowball sampling. Participants reported their infrastructure preferences and their emotional responses related to forest visits. The findings show that older adults highly value site cleanliness, shaded seating, accessible restrooms, and clear signage. Expectations varied significantly according to health status, age group, and visitation frequency. Emotional well-being was positively associated with both comfort and visit frequency. These results demonstrate how inclusive infrastructure plays a vital role in supporting older adults’ access to and enjoyment of forest environments. The study affirms that universally designed forests not only reduce barriers but also promote psychological health and active aging, contributing to developing more equitable and sustainable nature-based recreation areas. Full article
(This article belongs to the Special Issue The Sustainable Use of Forests in Tourism and Recreation)
18 pages, 2652 KiB  
Article
The Use of a Composite of Modified Construction Aggregate and Activated Carbon for the Treatment of Groundwater Contaminated with Heavy Metals and Chlorides
by Katarzyna Pawluk, Marzena Lendo-Siwicka, Grzegorz Wrzesiński, Sylwia Szymanek and Osazuwa Young Osawaru
Materials 2025, 18(15), 3437; https://doi.org/10.3390/ma18153437 - 22 Jul 2025
Viewed by 102
Abstract
The treatment of contaminants from road infrastructure poses significant challenges due to their variable composition and the high concentrations of chloride ions, heavy metals, and oil-derived substances. Traditional methods for protecting groundwater environments are often insufficient. A promising alternative is permeable reactive barrier [...] Read more.
The treatment of contaminants from road infrastructure poses significant challenges due to their variable composition and the high concentrations of chloride ions, heavy metals, and oil-derived substances. Traditional methods for protecting groundwater environments are often insufficient. A promising alternative is permeable reactive barrier (PRB) technology, which utilizes recycled materials and construction waste as reactive components within the treatment zone of the ground. This paper delves into the potential of employing a composite (MIX) consisting of modified construction aggregate (as recycled material) and activated carbon (example of reactive material) to address environmental contamination from a mixture of heavy metals and chloride. The research involved chemical modifications of the road aggregate, activated carbon, and their composite, followed by laboratory tests in glass reactors and non-flow batch tests to evaluate the kinetics and chemical equilibrium of the reactions. The adsorption process was stable and conformed to the pseudo-second-order kinetics and Langmuir, Toth, and Redlich–Peterson isotherm models. Studies using MIX from a heavy metal model solution showed that monolayer adsorption was a key mechanism for removing heavy metals, with strong fits to the Langmuir (R2 > 0.80) and Freundlich models, and optimal efficiencies for Cd and Ni (R2 > 0.90). The best fit, at Cd, Cu, Ni = 0.96, however, was with the Redlich–Peterson isotherm, indicating a mix of physical and chemical adsorption on heterogeneous surfaces. The Toth model was significant for all analytes, fitting Cl and Cd well and Pb and Zn moderately. The modifications made to the composite significantly enhanced its effectiveness in removing the contaminant mixture. The test results demonstrated an average reduction of chloride by 85%, along with substantial removals of heavy metals: lead (Pb) by 90%, cadmium (Cd) by 86%, nickel (Ni) by 85%, copper (Cu) by 81%, and zinc (Zn) by 79%. Further research should focus on the removal of other contaminants and the optimization of magnesium oxide (MgO) dosage. Full article
(This article belongs to the Special Issue Recovered or Recycled Materials for Composites and Other Materials)
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18 pages, 3744 KiB  
Article
Effect of Plant Growth Regulators on the Physiological Response and Yield of Cucumis melo var. inodorus Under Different Salinity Levels in a Controlled Environment
by Dayane Mércia Ribeiro Silva, Francisca Zildélia da Silva, Isabelly Cristina da Silva Marques, Eduardo Santana Aires, Francisco Gilvan Borges Ferreira Freitas Júnior, Fernanda Nery Vargens, Vinicius Alexandre Ávila dos Santos, João Domingos Rodrigues and Elizabeth Orika Ono
Horticulturae 2025, 11(7), 861; https://doi.org/10.3390/horticulturae11070861 - 21 Jul 2025
Viewed by 121
Abstract
The objective of this study was to evaluate the physiological, biochemical, and productive effects of the foliar application of bioregulators, based on auxin, cytokinin, and gibberellic acid, on yellow melon, cultivar DALI®, plants subjected to different salinity levels in a protected [...] Read more.
The objective of this study was to evaluate the physiological, biochemical, and productive effects of the foliar application of bioregulators, based on auxin, cytokinin, and gibberellic acid, on yellow melon, cultivar DALI®, plants subjected to different salinity levels in a protected environment to simulate Brazil’s semi-arid conditions. The experiment was conducted using a completely randomized block design, in a 4 × 3 factorial scheme, with four salinity levels (0, 2, 4, and 6 dS m−1) and three doses of the bioregulator, Stimulate® (0%, 100%, and 150% of the recommended dose), with six weekly applications. The physiological variables (chlorophyll a fluorescence and gas exchange) and biochemical parameters (antioxidant enzyme activity and lipid peroxidation) were evaluated at 28 and 42 days after transplanting, and the agronomic traits (fresh fruit mass, physical attributes, and post-harvest quality) were evaluated at the end of the experiment. The results indicated that salinity impaired the physiological and productive performance of the plants, especially at higher levels (4 and 6 dS m−1), causing oxidative stress, reduced photosynthesis, and decreased yield. However, the application of the bioregulator at the 100% dose mitigated the effects of salt stress under moderate salinity (2 dS m−1), promoting higher CO2 assimilation rates of up to 31.5%, better water-use efficiency, and reduced lipid peroxidation. In addition, the fruits showed a greater mass of up to 66%, thicker pulp, and higher soluble solids (> 10 °Brix) content, making them suitable for sale in the market. The 150% dose did not provide additional benefits and, in some cases, resulted in inhibitory effects. It is concluded that the application of Stimulate® at the recommended dose is effective in mitigating the effects of moderate salinity, up to ~3 dS m−1, in yellow melon crops; however, its effectiveness is limited under high salinity conditions, requiring the use of complementary strategies. Full article
(This article belongs to the Section Protected Culture)
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16 pages, 251 KiB  
Article
Active Breaks to Promote Sustainable Cognitive Development in Primary School Children
by Gaetano Raiola, Tiziana D’Isanto, Sara Aliberti, Giampiero Merati and Francesca D’Elia
Sustainability 2025, 17(14), 6616; https://doi.org/10.3390/su17146616 - 19 Jul 2025
Viewed by 254
Abstract
Promoting sustainable lifestyles through early interventions in schools is increasingly recognized as a critical component of public health and educational policy. Sustainable development, as outlined by the United Nations Sustainable Development Goals (SDGs), particularly Goal 3 (Good Health and Well-being) and Goal 4 [...] Read more.
Promoting sustainable lifestyles through early interventions in schools is increasingly recognized as a critical component of public health and educational policy. Sustainable development, as outlined by the United Nations Sustainable Development Goals (SDGs), particularly Goal 3 (Good Health and Well-being) and Goal 4 (Quality Education), calls for integrating health-promoting behaviors into all aspects of life, including school settings. Active breaks (ABs) could represent a promising strategy to counteract these effects. This study assessed the impact of ABs on the attention of fifth-grade children, aiming to promote both immediate cognitive benefits and long-term health. A total of 32 primary children (age, 9.34 ± 0.77 years old), divided into an experimental group (AB sessions) and a control group, participated in this study. Attention and concentration were measured using the D2-R Test, while processing speed and distraction-related behaviors were tracked. Additionally, questionnaires assessed children’s and teachers’ perceptions. After five weeks, the experimental group demonstrated significant improvements in attention (p < 0.05), especially after high intensity ABs at 12:00. This study suggested the effectiveness of ABs as a tool for improving children’s attention and behavior in primary schools. The findings suggest that integrating physical activity breaks not only enhances cognitive function but also contributes to sustainable educational practices by fostering better learning environments and supporting children’s health and well-being. Full article
17 pages, 601 KiB  
Article
“It’s Like a Nice Atmosphere”—Understanding Physics Students’ Experiences of a Flipped Classroom Through the Lens of Transactional Distance Theory
by Anna K. Wood
Educ. Sci. 2025, 15(7), 921; https://doi.org/10.3390/educsci15070921 - 18 Jul 2025
Viewed by 417
Abstract
In this paper, physics students’ experiences of a flipped, active learning physics class are explored through the lens of transactional distance theory (TDT). Transactional distance (TD) is the psychological and communicative distance that may arise between students and their teacher in learning environments [...] Read more.
In this paper, physics students’ experiences of a flipped, active learning physics class are explored through the lens of transactional distance theory (TDT). Transactional distance (TD) is the psychological and communicative distance that may arise between students and their teacher in learning environments such as large classes. TD has been shown to have a negative impact on students’ satisfaction, engagement, and learning outcomes, yet there is lack of research on how pedagogical approaches, such as the flipped classroom and active learning, may ameliorate the impacts of TD. In this paper, I use a qualitative methodology to gain an in-depth understanding of the ways in which a flipped class can impact the experience of transactional distance for first year physics students. Eleven students took part in semi-structured interviews about their experience of the class, from which three themes were developed: (a) creating connections; (b) stimulating engagement; and (c) supporting responsiveness. These themes are interpreted through the lens of TDT to understand the ways in which the flipped class and active learning pedagogics reduced students’ experience of TD. This gives new insights into students’ experiences of small group discussions, pre-class quizzes, and in-class ‘clicker’ questions. The implications for the pedagogical design of flipped classes will be discussed. Full article
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13 pages, 2968 KiB  
Article
Neurophysiological Effects of Virtual Reality Multitask Training in Cardiac Surgery Patients: A Study with Standardized Low-Resolution Electromagnetic Tomography (sLORETA)
by Irina Tarasova, Olga Trubnikova, Darya Kupriyanova, Irina Kukhareva and Anastasia Sosnina
Biomedicines 2025, 13(7), 1755; https://doi.org/10.3390/biomedicines13071755 - 18 Jul 2025
Viewed by 234
Abstract
Background: Digital technologies offer innovative opportunities for recovering and maintaining intellectual and mental health. The use of a multitask approach that combines motor component with various cognitive tasks in a virtual environment can optimize cognitive and physical functions and improve the quality of [...] Read more.
Background: Digital technologies offer innovative opportunities for recovering and maintaining intellectual and mental health. The use of a multitask approach that combines motor component with various cognitive tasks in a virtual environment can optimize cognitive and physical functions and improve the quality of life of cardiac surgery patients. This study aimed to localize current sources of theta and alpha power in patients who have undergone virtual multitask training (VMT) and a control group in the early postoperative period of coronary artery bypass grafting (CABG). Methods: A total of 100 male CABG patients (mean age, 62.7 ± 7.62 years) were allocated to the VMT group (n = 50) or to the control group (n = 50). EEG was recorded in the eyes-closed resting state at baseline (2–3 days before CABG) and after VMT course or approximately 11–12 days after CABG (the control group). Power EEG analysis was conducted and frequency-domain standardized low-resolution tomography (sLORETA) was used to assess the effect of VMT on brain activity. Results: After VMT, patients demonstrated a significantly higher density of alpha-rhythm (7–9 Hz) current sources (t > −4.18; p < 0.026) in Brodmann area 30, parahippocampal, and limbic system structures compared to preoperative data. In contrast, the control group had a marked elevation in the density of theta-rhythm (3–5 Hz) current sources (t > −3.98; p < 0.017) in parieto-occipital areas in comparison to preoperative values. Conclusions: Virtual reality-based multitask training stimulated brain regions associated with spatial orientation and memory encoding. The findings of this study highlight the importance of neural mechanisms underlying the effectiveness of multitask interventions and will be useful for designing and conducting future studies involving VR multitask training. Full article
(This article belongs to the Section Neurobiology and Clinical Neuroscience)
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13 pages, 839 KiB  
Perspective
Inclusion in Motion: Promoting Equitable Physical Activity and Health in Childhood and Adolescence
by Vidar Sandsaunet Ulset, Luca Oppici, Karin Hamre, James Robert Rudd, Annett Victoria Stornæs, Heidi Marian Haraldsen and Reidar Säfvenbom
Children 2025, 12(7), 942; https://doi.org/10.3390/children12070942 - 17 Jul 2025
Viewed by 201
Abstract
Inclusion in play, physical education, outdoor life, organized sports, and other movement-based activities can promote resilience and support physical, emotional, and social well-being. These arenas are particularly important for reducing health disparities and preventing social marginalization across the lifespan. Yet, children and adolescents [...] Read more.
Inclusion in play, physical education, outdoor life, organized sports, and other movement-based activities can promote resilience and support physical, emotional, and social well-being. These arenas are particularly important for reducing health disparities and preventing social marginalization across the lifespan. Yet, children and adolescents from vulnerable or disadvantaged backgrounds encounter persistent barriers to participation, rooted in broader inequalities related to their socioeconomic position, disability, gender, ethnicity, and access to supportive environments. This perspective outlines how inclusive movement contexts, when informed by developmental systems theory and resilience frameworks, can interrupt trajectories of marginalization and promote long-term equity in health, education, and work inclusion. We emphasize the need for interdisciplinary approaches, combining longitudinal and qualitative methods, to uncover how vulnerability and participation interact dynamically over time. By integrating insights from developmental science, education, public health, and spatial ecology, we identify strategic pathways for research and action. Addressing these challenges requires coordinated efforts across sectors and stakeholders to co-create inclusive, context-sensitive interventions. Full article
(This article belongs to the Special Issue Promoting Healthy Lifestyles in Children and Adolescents)
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13 pages, 819 KiB  
Article
Evaluating the Effectiveness of Biodiverse Green Schoolyards on Child BMI z-Score and Physical Metrics: A Pilot Quasi-Experimental Study
by Bo H. W. van Engelen, Lore Verheyen, Bjorn Winkens, Michelle Plusquin and Onno C. P. van Schayck
Children 2025, 12(7), 944; https://doi.org/10.3390/children12070944 - 17 Jul 2025
Viewed by 210
Abstract
Background: Childhood obesity is a significant public health issue linked to poor diet, low physical activity, and limited access to supportive environments. Green schoolyards may promote physical activity and improve health outcomes. This study evaluated the impact of the Green Healthy Primary School [...] Read more.
Background: Childhood obesity is a significant public health issue linked to poor diet, low physical activity, and limited access to supportive environments. Green schoolyards may promote physical activity and improve health outcomes. This study evaluated the impact of the Green Healthy Primary School of the Future (GHPSF) intervention—greening schoolyards—on children’s BMI z-scores, waist circumference, and hip circumference over 18 months, and compared these effects to those observed in the earlier Healthy Primary School of the Future (HPSF) initiative. Methods: This longitudinal quasi-experimental study included two intervention and two control schools in Limburg, a province both in the Netherlands and Belgium. Children aged 8–12 years (n = 159) were assessed at baseline, 12 months, and 18 months for anthropometric outcomes. Linear mixed models were used to estimate intervention effects over time, adjusting for sex, age, country, and socioeconomic background. Standardized effect sizes (ESs) were calculated. Results: The intervention group showed a greater reduction in BMI z-scores at 12 months (ES = −0.15, p = 0.084), though this was not statistically significant. Waist circumference increased in both groups, but less so in the intervention group, at 12 months (ES = −0.23, p = 0.057) and 18 months (ES = −0.13, p = 0.235). Hip circumference and waist–hip ratio changes were minimal and non-significant. GHPSF effect sizes were comparable to or greater than those from the HPSF initiative. Conclusions: Though not statistically significant, trends suggest that greening schoolyards may support favorable changes in anthropometric outcomes. Further research with larger samples and longer follow-up is recommended. Full article
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12 pages, 206 KiB  
Article
Nutritional Challenges of Active Sports Tourists: A Qualitative Study from the Runners’ Perspective
by Mateusz Rozmiarek
Nutrients 2025, 17(14), 2339; https://doi.org/10.3390/nu17142339 - 17 Jul 2025
Viewed by 270
Abstract
Background/Objectives: Sports tourism, particularly international running events such as half marathons and marathons, has rapidly grown due to rising health consciousness and active lifestyles. Runners competing abroad face unique nutritional challenges that extend beyond physiological needs, including adaptation to local food cultures and [...] Read more.
Background/Objectives: Sports tourism, particularly international running events such as half marathons and marathons, has rapidly grown due to rising health consciousness and active lifestyles. Runners competing abroad face unique nutritional challenges that extend beyond physiological needs, including adaptation to local food cultures and psychosocial factors. This study aims to explore the nutritional difficulties encountered by international runners during competitions abroad, using participants of the Poznan Half Marathon 2025 as a case example. Methods: A qualitative research design was employed, involving semi-structured in-depth interviews with 12 international runners from the United Kingdom, Germany, and Ukraine. Participants had at least two years of experience competing internationally. Results: Four primary categories of nutritional challenges emerged: (1) quality and availability of food, (2) adaptation to local eating habits and physiological impacts, (3) hydration and access to appropriate fluids, and (4) logistical factors and the interactions between psychological stress, physical well-being, and nutritional choices. These factors influenced runners’ preparation, race-day performance, and recovery, highlighting the complexity of managing nutrition in unfamiliar environments. Conclusions: Nutritional challenges for international runners are multidimensional, requiring flexible and culturally sensitive nutritional strategies. Although these findings offer useful insights, they are based on a small, specific sample and should be generalized with caution. Further research is necessary to explore the broader applicability of the findings and their relevance to diverse athletic populations and contexts. Full article
18 pages, 1944 KiB  
Article
Experimental Study on the Adsorption Performance of Metal–Organic Framework MIL-101 (Cr) for Indoor Toluene
by Zirong Zhao, Jinzhe Nie, Honghao Huang, Fuqun He, Kaiqiao Wang and Pu Yang
Buildings 2025, 15(14), 2506; https://doi.org/10.3390/buildings15142506 - 17 Jul 2025
Viewed by 365
Abstract
In this study, MIL-101 (Cr) was synthesized and characterized in terms of its physical properties. The adsorption breakthrough curves for toluene were measured and compared to those of conventional adsorbents (i.e., silica gel and activated carbon) at typical indoor concentrations of toluene. The [...] Read more.
In this study, MIL-101 (Cr) was synthesized and characterized in terms of its physical properties. The adsorption breakthrough curves for toluene were measured and compared to those of conventional adsorbents (i.e., silica gel and activated carbon) at typical indoor concentrations of toluene. The results show that MIL-101 (Cr) exhibits a 5–8 times higher adsorption capacity for toluene compared to silica gel at low concentrations. The adsorption isotherm of MIL-101 (Cr) for toluene conforms to the Langmuir model. Increasing temperature reduces the adsorption breakthrough time and saturation time, but it leads to a significant decrease in the adsorption capacity. During the breakthrough experiment, flow rate had little effect on adsorption capacity, but higher flow rates notably decreased the breakthrough and saturation times. The negative values of ΔG, ΔH, and ΔS indicate that the adsorption of toluene on MIL-101 (Cr) is a spontaneous and exothermic process. Compared to traditional adsorbents, MIL-101 (Cr) exhibits desirable performance in toluene adsorption in indoor environments. It shows significant potential for indoor air purification applications. Full article
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25 pages, 6069 KiB  
Article
NaCl as a Simple Yet Unique Activator of Kaolin: Surface Engineering for Enhanced Heavy Metal Adsorption
by Amos K. Avornyo, Vasileios E. Katzourakis, Shadi W. Hasan, Fawzi Banat and Constantinos V. Chrysikopoulos
Water 2025, 17(14), 2120; https://doi.org/10.3390/w17142120 - 16 Jul 2025
Viewed by 313
Abstract
This study investigates the effects of NaCl activation on the structural and chemical properties of kaolin for the adsorption of Zn2+ from solution. Kaolin was treated with NaCl solution at varying concentrations (0.5, 1.0, 2.0, and 4.0 M), and ultrasonication was used [...] Read more.
This study investigates the effects of NaCl activation on the structural and chemical properties of kaolin for the adsorption of Zn2+ from solution. Kaolin was treated with NaCl solution at varying concentrations (0.5, 1.0, 2.0, and 4.0 M), and ultrasonication was used as a means of agitation. Scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), and dynamic light scattering (DLS) were employed to characterize the physical and chemical effects of the NaCl activation and its subsequent influence on the kaolin’s heavy metal removal efficiency. The kaolin activated with 0.5 M NaCl solution yielded the optimal performance with a 13% increase in Zn2+ removal compared to the unmodified clay. The adsorption data best matched the pseudo-second-order kinetic model and the Langmuir isotherm. This indicates a monolayer adsorption on a homogeneous surface, with chemisorption as the dominant adsorption mechanism. Thermodynamic analysis also revealed that the adsorption process was endothermic and spontaneous. Furthermore, NaCl activation slightly enhanced the microstructural properties of the kaolin and moderated the surface charge, creating a more favorable electrostatic environment for improved heavy metal ion adsorption. The findings further highlight the potential of NaCl activation to introduce exchangeable Na+ onto the kaolin surface in a pH-neutral environment and promise a clean, mechanistically clear, and practical route for ion exchange with heavy metals such as Zn2+. Full article
(This article belongs to the Section Wastewater Treatment and Reuse)
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25 pages, 6057 KiB  
Article
Physical Implementation and Experimental Validation of the Compensation Mechanism for a Ramp-Based AUV Recovery System
by Zhaoji Qi, Lingshuai Meng, Haitao Gu, Ziyang Guo, Jinyan Wu and Chenghui Li
J. Mar. Sci. Eng. 2025, 13(7), 1349; https://doi.org/10.3390/jmse13071349 - 16 Jul 2025
Viewed by 203
Abstract
In complex marine environments, ramp-based recovery systems for autonomous underwater vehicles (AUVs) often encounter engineering challenges such as reduced docking accuracy and success rate due to disturbances in the capture window attitude. In this study, a desktop-scale physical experimental platform for recovery compensation [...] Read more.
In complex marine environments, ramp-based recovery systems for autonomous underwater vehicles (AUVs) often encounter engineering challenges such as reduced docking accuracy and success rate due to disturbances in the capture window attitude. In this study, a desktop-scale physical experimental platform for recovery compensation was designed and constructed. The system integrates attitude feedback provided by an attitude sensor and dual-motor actuation to achieve active roll and pitch compensation of the capture window. Based on the structural and geometric characteristics of the platform, a dual-channel closed-loop control strategy was proposed utilizing midpoint tracking of the capture window, accompanied by multi-level software limit protection and automatic centering mechanisms. The control algorithm was implemented using a discrete-time PID structure, with gain parameters optimized through experimental tuning under repeatable disturbance conditions. A first-order system approximation was adopted to model the actuator dynamics. Experiments were conducted under various disturbance scenarios and multiple control parameter configurations to evaluate the attitude tracking performance, dynamic response, and repeatability of the system. The results show that, compared to the uncompensated case, the proposed compensation mechanism reduces the MSE by up to 76.4% and the MaxAE by 73.5%, significantly improving the tracking accuracy and dynamic stability of the recovery window. The study also discusses the platform’s limitations and future optimization directions, providing theoretical and engineering references for practical AUV recovery operations. Full article
(This article belongs to the Section Coastal Engineering)
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