Search Results (71)

Hyperspectral technology has been widely applied to the retrieval of soil properties, such as soil organic matter (SOM) and particle size distribution (PSD). However, most previous studies have focused on hyperspectral data acquired from the nadir direction, and the influence of viewing geometry on hyperspectral-based soil property retrieval remains unclear. In this study, bidirectional reflectance factors (BRFs) were collected at 48 different viewing angles for 154 soil samples with varying SOM contents and PSDs. SOM and PSD were then retrieved using combinations of ten spectral preprocessing methods (raw reflectance, Savitzky–Golay filter (SG), first derivative (D1), second derivative (D2), standard normal variate (SNV), multiplicative scatter correction (MSC), SG + D1, SG + D2, SG + SNV, and SG + MSC), one sensitive wavelength selection method, and three retrieval algorithms (partial least squares regression (PLSR), support vector machine (SVM), and convolutional neural networks (CNNs)). The influence of viewing geometry on the selection of spectral preprocessing methods, retrieval algorithms, sensitive wavelengths, and retrieval accuracy was systematically analyzed. The results showed that soil BRFs are influenced by both soil properties and viewing angles. The viewing geometry had limited effects on the choice of preprocessing method and retrieval algorithm. Among the preprocessing methods, D1, SG + D1, and SG + D2 outperformed the others, while PLSR achieved a higher accuracy than SVM and CNN when retrieving soil properties. The selected sensitive wavelengths for both SOM and PSD varied slightly with viewing angle and were mainly located in the near-infrared region when using BRFs from multiple viewing angles. Compared with single-angle data, multi-angle BRFs significantly improved retrieval performance, with the R² increasing by 11% and 15%, and RMSE decreasing by 16% and 30% for SOM and PSD, respectively. The optimal viewing zenith angle ranged from 10° to 20° for SOM and around 40° for PSD. Additionally, backward viewing directions were more favorable than forward directions, with the optimal viewing azimuth angles being 0° for SOM and 90° for PSD. These findings provide useful insights for improving the accuracy of soil property retrieval using multi-angle hyperspectral observations. Full article

In this study, the effective radius of aerosol particles was experimentally retrieved using a self-developed dual-wavelength atmospheric aerosol lidar. A single-valued lookup table was first established, based on the OPAC database and the Gamma size distribution model, to define the relationship between the extinction coefficient ratio and the effective radius of atmospheric aerosol particles. The extinction coefficients corresponding to the 355 nm and 1064 nm wavelengths were then calculated using the echo signals retrieved horizontally by the lidar, in conjunction with the Mie scattering lidar equation. Subsequently, the lookup table was used to retrieve the real-time effective radius of aerosol particles by inputting the extinction coefficient ratio of the two wavelengths. Finally, the retrieval results were compared with the effective radii measured by an optical particle spectrometer, which had been corrected for relative humidity. An analysis over six months showed a coefficient of determination (R²) greater than 0.83. The results demonstrated that the dual-wavelength lidar exhibits a stable performance, the retrieval method is valid, and the detection results are accurate and reliable. Full article

Nanodroplets have demonstrated potential for the range detection of hadron radiotherapies. Our formulation uses superheated perfluorobutane (C4F10) stabilized by a poly(vinyl-alcohol) shell. High-LET (linear energy transfer) particles vaporize the nanodroplets into echogenic microbubbles. Tailored ultrasound imaging translates the generated echo-contrast into a dose distribution map, enabling beam range retrieval. This work evaluates the response of size-sorted nanodroplets to carbon-ion radiation. We studied how thesize of nanodroplets affects their sensitivity at various beam-doses and energies, as a function of concentration and shell cross-linking. First, we show the physicochemical characterization of size-isolated nanodroplets by differential centrifugation. Then, we report on the irradiations of the nanodroplet samples in tissue-mimicking phantoms. We compared the response of large (≈900 nm) and small (≈400 nm) nanodroplets to different carbon-ions energies and evaluated their dose linearity and concentration detection thresholds by ultrasound imaging. Additionally, we verified the beam range detection accuracy for the nanodroplets samples. All nanodroplets exhibited sensitivity to carbon-ions with high range verification precision. However, smaller nanodroplets required a higher concentration sensitivity threshold. The vaporization yield depends on the carbon-ions energy and dose, which are both related to particle count/spot. These findings confirm the potential of nanodroplets for range detection, with performance depending on nanodroplets’ properties and beam parameters. Full article

Aerosol microphysical properties, including aerosol particle size distribution, complex refractive index and concentration properties, are key parameters evaluating the impact of aerosols on climate, meteorology, and human health. High Spectral Resolution Lidar (HSRL) is an efficient tool for probing the vertical optical properties of aerosol particles, including the aerosol backscatter coefficient (β) and extinction coefficient (α), at multiple wavelengths. To swiftly process vast data volumes, address the ill-posedness of retrieval problems, and suit simpler lidar systems, this study proposes an algorithm (modified algorithm) for retrieving microphysical property profiles from the HSRL optical data targeting fine-mode aerosols, building upon a previous algorithm (basic algorithm). The modified algorithm is based on a look-up table (LUT) approach, combined with the k-nearest neighbor (k-NN) and random forest (RF) algorithms, and it optimizes the decision tree generation strategy, incorporating a self-posed scheme. In numerical simulation tests for different lidar configurations, the modified algorithm reduced retrieval errors by 41%, 30%, and 32% compared to the basic algorithm for 3β + 2α, 3β + 1α, and 2β + 1α, respectively, with a remarkable improvement of stability. In two observation scenes of a field campaign, the median relative errors of the effective radius for 3β + 2α were 6% and −3%, and the median absolute errors of single-scattering albedo were 0.012 and 0.005. This method represents a further step toward the use of the LUT approach, with the potential to provide effective and efficient aerosol microphysical retrieval for simpler lidar systems, which could advance our understanding of aerosols’ climatic, meteorological, and health impacts. Full article

The recovery and re-calibration of a dataset of vertical aerosol extinction profiles of the 1963/64 stratospheric aerosol layer measured by a searchlight at 32° N in New Mexico, US, is reported. The recovered dataset consists of 105 aerosol extinction profiles at 550 nm that cover the period from December 1963 to December 1964. It is a unique record of the portion of the aerosol cloud from the March 1963 Agung volcanic eruption that was transported into the Northern Hemisphere subtropics. The data-recovery methodology involved re-digitizing the 105 original aerosol extinction profiles from individual Figures within a research report, followed by the re-calibration. It involves inverting the original equation used to compute the aerosol extinction profile to retrieve the corresponding normalized detector response profile. The re-calibration of the original aerosol extinction profiles used Rayleigh extinction profiles calculated from local soundings. Rayleigh and aerosol slant transmission corrections are applied using the MODTRAN code in transmission mode. Also, a best-estimate aerosol phase function was calculated from observations and applied to the entire column. The tropospheric aerosol phase function from an AERONET station in the vicinity of the searchlight location was applied between 2.76 to 11.7 km. The stratospheric phase function, applied for a 12.2 to 35.2 km altitude range, is calculated from particle-size distributions measured by a high-altitude aircraft in the vicinity of the searchlight in early 1964. The original error estimate was updated considering unaccounted errors. Both the re-calibrated aerosol extinction profiles and the re-calibrated stratospheric aerosol optical depth magnitudes showed higher magnitudes than the original aerosol extinction profiles and the original stratospheric aerosol optical depth, respectively. However, the magnitudes of the re-calibrated variables show a reasonable agreement with other contemporary observations. The re-calibrated stratospheric aerosol optical depth demonstrated its consistency with the tropics-to-pole decreasing trend, associated with the major volcanic eruption stratospheric aerosol pattern when compared to the time-coincident stratospheric aerosol optical depth lidar observations at Lexington at 42° N. Full article

An Nd:YAG-based Raman lidar provides a mature technology to derive profiles of the optical properties of aerosols over a wide altitude range. However, the derivation of micro-physical parameters is an ill-posed problem. Hence, increasing the information content of lidar data is desirable. Recently, ceilometers and wind lidar systems, both operating in the near-infrared region, have been successfully employed in aerosol research. In this study, we demonstrate that the inclusion of additional backscatter coefficients from these two latter instruments clearly improves the inversion of micro-physical parameters such as volume distribution function, effective radius, or single-scattering albedo. We focus on the Arctic aerosol and start with the typical volume distribution functions of Arctic haze and boreal biomass burning. We forward calculate the optical coefficients that the lidar systems should have seen and include or exclude the backscatter coefficients of the ceilometer (910 nm) and wind lidar data (1500 nm) to analyze the value of these wavelengths in their ability to reproduce the volume distribution function, which may be mono- or bimodal. We found that not only the coarse mode but also the properties of the accumulation mode improved when the additional wavelengths were considered. Generally, the 1500 nm wavelength has greater value in correctly reproducing the aerosol properties. Full article

An innovative mobile lidar device, developed to monitor volcanic plumes during explosive eruptions at Mt. Etna (Italy) and to analyse the optical properties of volcanic particles, was upgraded in October 2023 with the aim of improving volcanic plume retrievals. The new configuration of the lidar allows it to obtain new data on both the optical and the microphysical properties of the atmospheric aerosol. In fact, after the upgrade, the lidar is able to measure three backscattering coefficients, two extinction coefficients and two depolarisation ratios in a configuration defined as “state-of-the-art lidar”, where properties such as particle size distribution and the refractive index can be derived. During the lidar implementation, we were able to test the system’s performance through specific calibration measurements. A comparison in an aerosol-free region (7.2–12 km) between lidar signals at 1064 nm, 532 nm and 355 nm and the corresponding pure molecular profiles showed a relative difference of <1% between them for all the wavelengths, highlighting the good dynamic of the signals. The overlap correction allowed us to reduce the underestimation of the backscattering coefficient from 50% to 10% below 450 m and 750 m at both 355 and 532 nm, respectively. The correct alignment between the laser beam and the receiver optical chain was tested using the signal received from the different quadrants of the telescope, and the relative differences between the four directions were comparable to zero, within the margin of error. Finally, the first measurement results are shown and compared with results obtained by other instruments, with the aim of proving the ability of the upgraded system to more precisely characterise aerosol optical and microphysical properties. Full article

Microplastics (MP) encompass not only plastic products but also paint particles. Marine microdebris, including MP, was retrieved from five sampling stations spanning Nagasaki-Goto island and was classified into six types, primarily consisting of MP (A), Si-based (B), and Cu-based (C) paint particles. Type-A particles, i.e., MP, were exceedingly small, with 74% of them having a long diameter of 25 µm or less. The vertical distribution of type C, containing cuprous oxide, exhibited no depth dependence, with its dominant size being less than 7 μm. It was considered that the presence of type C was associated with a natural phenomenon of MP loss. To clarify this, polypropylene (PP) samples containing cuprous oxide were prepared, and their accelerated degradation behavior was studied using a novel enhanced degradation method employing a sulfate ion radical as an initiator. Infrared spectroscopy revealed the formation of a copper soap compound in seawater. Scanning electron microscopy/energy-dispersive X-ray spectroscopy analysis indicated that the chemical reactions between Cl⁻ and cuprous oxide produced Cu⁺ ions. The acceleration of degradation induced by the copper soap formed was studied through the changes in the number of PP chain scissions, revealing that the presence of type-C accelerated MP degradation. Full article

In the summer of 2017, huge wildfires in the British Columbia region (Canada) led to the injection of a remarkably high concentration of biomass burning aerosol in the atmosphere. These aerosol masses reached the city of Naples, Italy, at the end of August 2017, where they were characterized by means of a multiwavelength lidar and a sun–sky–lunar photometer. Here we report on the optical and microphysical properties of this aerosol in an intriguing condition, occurring on 4 September 2017, which is characterized by an interesting multi-layered vertical distribution of the aerosol. The Lidar profiles highlighted the presence of four aerosol layers, with two located in the lower troposphere and the other two at stratospheric altitudes. A rather thorough characterization of the biomass burning aerosol was carried out. The aerosol depolarization ratio showed an increasing dependence on the altitude with averaged values of 2–4% for the tropospheric layers, which are indicative of almost spherical smoke particles, and larger values in the stratospheric layers, suggestive of aspheric particles. Lidar-derived size distributions were retrieved for the first three aerosol layers, highlighting a higher particle concentration in the fine-mode fraction for the layers observed at higher altitudes. A dominance of fine particles in the atmosphere (fine-mode fraction > 0.8) with low absorption properties (absorption AOD < 0.0025 and SSA > 0.97) was also observed over the whole atmospheric column by sun photometer data. The space-resolved results provided by the lidar data are consistent with the columnar features retrieved by the AERONET sun photometer, thus evidencing the reliability and capability of lidar characterization of atmospheric aerosol in a very interesting condition of multiple aerosol layers originating from Canadian fires overpassing the observation station. Full article

In order to investigate the equivalent complex refractive index of atmospheric aerosols near the Earth’s surface, we conducted measurements in the Hefei region from March to April 2022. These measurements utilized a micro-pulse lidar, an Aethalometer, and a Portable Optical Particle Profiler. These measurements encompassed aerosol particle size distribution as well as standard meteorological parameters including temperature, humidity, atmospheric pressure, and wind speed. Subsequently, this dataset was employed to develop an optimization algorithm for retrieving the equivalent complex refractive indices of near-surface aerosols. The methodology relies on lookup tables containing data for extinction efficiency and absorption efficiency factors. It operates on the premise of aerosol property stability within a defined time frame, utilizing measured extinction and absorption coefficients as simultaneous constraints during this period to inversely derive both the real and imaginary parts of the aerosol complex refractive index. Results from the simulation analysis reveal that the newly optimized retrieval algorithm, which relies on lookup tables, exhibits reduced sensitivity to instrument errors when compared to single-point constraint algorithms. This enhancement results in a more efficient and dependable approach for retrieving the aerosol complex refractive index. Empirical inversion and simulation studies were carried out to determine the aerosol equivalent complex refractive index in the Hefei region, utilizing measured data. This inversion process yielded an average complex refractive index of 1.48-i0.017 for aerosols in the Hefei region throughout the experimental period. Correlation analysis unveiled a positive association between the real part of the aerosol complex refractive index and the single-scattering albedo (SSA), whereas the imaginary part displayed a linear negative correlation with the SSA. The mathematical relationship between the real part and the SSA is $y=0.19x+0.62$, and the corresponding relationship between the imaginary part and the SSA is $y=-5.3x+0.99$. This research offers a novel method for the retrieval of the aerosol equivalent complex refractive index. Full article

The advantages of performing aerosol retrieval with multi-angle, multi-spectral photopolarimetric measurements over intensity-only measurements come from this technique’s sensitivity to aerosols’ microphysical properties, such as their particle size, shape, and complex refraction index. In this study, an extended LUT (Look Up Table) algorithm inherited from a previous work based on the assumption of surface reflectance spectral shape invariance is proposed and applied to PARASOL (Polarization and Anisotropy of Reflectances for Atmospheric Science coupled with Observations from a Lidar) measurements to retrieve aerosols’ optical properties including aerosol optical depth (AOD) and aerosol fine-mode fraction (FMF). Case studies conducted over East China for different aerosol scenes are investigated. A comparison between the retrieved AOD regional distribution and the corresponding MODIS (Moderate-resolution Imaging Spectroradiometer) C6 AOD products shows similar spatial distributions in the Jing-Jin-Ji (Beijing–Tianjin–Hebei, China’s mega city cluster) region. The PARASOL AOD retrievals were compared against the AOD measurements of seven AERONET (Aerosol Robotic Network) stations in China to evaluate the performance of the retrieval algorithm. In the fine-particle-dominated regions, lower RMSEs were found at Beijing and Hefei urban stations (0.16 and 0.18, respectively) compared to those at other fine-particle-dominated AERONET stations, which can be attributed to the assumption of surface reflectance spectral shape invariance that has significant advantages in separating the contribution of surface and aerosol scattering in urban areas. For the FMF validation, an RMSE of 0.23, a correlation of 0.57, and a bias of −0.01 were found. These results show that the algorithm performs reasonably in distinguishing the contribution of fine and coarse particles. Full article

We present microphysical properties of pollution layers observed with NASA Langley Research Center’s airborne high-spectral-Resolution lidar (HSRL-2). The data obtained by HSRL-2 consist of vertical profiles of three backscatter coefficients (β) taken at 355, 532 and 1064 nm and two extinction coefficients (α) measured at 355 and 532 nm. In our study we (1) inverted the 3β + 2α data into particle size distributions with a regularization algorithm, and subsequently computed (2) number concentration and (3) single-scattering albedo for four measurement profiles. We carried out a first comparison to the same particle characteristics measured with airborne in-situ instruments. The in-situ instruments were flown aboard the P-3B aircraft, which followed the flight track of the aircraft ER-2 that carried HSRL-2. We found good agreement of the co-located (space and time) data products, with a degree of reliability reaching 90%. A more detailed study on a larger dataset needs to be carried out in future work to (a) obtain important correction factors, (b) study the influence of different light-scattering models on the inversion results, and (c) identify sources of retrieval and measurement uncertainties. Full article

In this study, we try to characterize local aerosols over the city of Ioannina for the first time using continuous AERONET CIMEL Sun–Sky spectral photometer measurements. The instrument, which belongs to the Laboratory of Atmospheric Physics of the Aristotle University of Thessaloniki, was installed in 2022 at the University of Ioannina and operated for a 5-month period from 23 February to 30 June 2022. Based on its measurements and retrievals, we investigate aerosol optical properties on a monthly, daily and hourly mean basis and reveal relationships between Aerosol Optical Depth (AOD) and local particulate matter (PM). It is found that the 5-month mean AOD is 0.17, from which 0.08 is ascribed to fine-mode and 0.09 to coarse-mode aerosols, while the corresponding mean Angstrom Exponent is 0.95. The total PM, PM₁₀ and PM_2.5 concentrations for the same period are equal to 32.51, 22.39 and 11.40 μg/m³, respectively. The correlation coefficient between PM₁₀ and AOD_500nm is equal to 0.79, and the one between the PM_2.5/PM₁₀ ratio and the Fine-Mode Fraction of AOD is equal to 0.76. Events of episodic fine and coarse aerosol conditions, which took place during the study period, are also analyzed using AERONET Volume Size Distribution (VSD) inversion products, along with back trajectories obtained with the NOAA’s HYSPLIT model, to assure the origin of the particles. Full article

We study retrieval methods in regard to their potential to accurately retrieve particle microphysical parameters (PMP) from 3β + 2α HSRL/Raman lidar measurements. PMPs estimated with these methods are number, surface-area and volume concentrations, the effective radius, and complex refractive index of the investigated particle size distribution (PSD). The 3β + 2α optical data are particle backscatter coefficients at 355, 532 and 1064 nm and extinction coefficients at 355 and 532 nm. We present results that are fundamental for our understanding of how uncertainties of the optical data convert into uncertainties of PMPs. PMPs can only be retrieved with preset accuracy if the input optical data are accurate to at least eight significant digits, i.e., 10⁻⁶%. Such measurement accuracy cannot be achieved by currently existing lidar measurement techniques and the fact that atmospheric conditions are not static during lidar observations. Our analysis of the results derived with the novel approach shows that (a) the uncertainty of the retrieved surface-area concentration increases proportionally to the measurement uncertainty of the extinction coefficient at 355 nm, (b) the uncertainty of the effective radius is inversely proportional to the measurement uncertainty of the extinction-related Ångström exponent, (c) the uncertainty of volume concentration is close to the one of the effective radius, and (d) the uncertainty of number concentration is proportional to the inverse of the square value of the uncertainty of the effective radius. The complex refractive index (CRI) cannot be estimated without introducing extra constraints, even if measurement uncertainties of the optical data are as low as 1−3%. We tested constraints and their impact on the solution space, and in how far these constraints could allow us to restrict the retrieval uncertainties. For example, we used information about relative humidity that can be measured with Raman lidar. Relative humidity is an important piece of information that allows for more accurate aerosol typing and thus plays a vital role in any kind of aerosol characterization. The measurement example we used in this study shows that such a constraint can reduce the retrieval uncertainty of single scattering albedo (SSA) to as low as ±0.01–±0.025 (at 532 nm), on the condition that the uncertainty of the input optical data stays below 15%. The results will be used for uncertainty analysis of data products provided by future versions of the Tikhonov Advanced Regularization Algorithm (TiARA). This algorithm has evolved into a standard tool for the derivation of microphysical particle properties from multiwavelength High-Spectral-Resolution Lidar (HSRL)/Raman lidar operated in Europe, East Asia, and the US. Full article

The present work aimed to assess the ambient levels of air pollution with particulate matter for both mass concentrations and number of particles for various fractions in Ploiesti city during the lockdown period determined by the COVID-19 pandemic (March–June 2020). The PM10 continuously monitored data was retrieved from four air quality automatic stations that are connected to the Romanian National Network for Monitoring Air Quality and located in the city. Because no other information was available for other more dangerous fractions, we used monitoring campaigns employing the Lighthouse 3016 IAQ particle counter near the locations of monitoring stations assessing size-segregated mass fraction concentrations (PM0.5, PM1, PM2.5, PM5, PM10, and TPM) and particle number concentration (differential Δ) range between 0.3 and 10 microns during the specified timeline between 8.00 and 11.00 a.m., which were considered the morning rush hours interval. Interpolation maps estimating the spatial distribution of the mass concentrations of various PM fractions and particle number concentration were drawn using the IDW algorithm in ArcGIS 10.8.2. Regarding the particle count of 0.5 microns during the lockdown, the smallest number was recorded when the restriction of citizens’ movement was declared (24 March 2020), which was 5.8-times lower (17,301.3 particles/cm³) compared to a common day outside the lockdown period (100,047.3 particles/cm³). Similar results were observed for other particle sizes. Regarding the spatial distribution of the mass concentrations, the smaller fractions were higher in the middle of the city and west (PM0.5, PM1, and PM2.5) while the PM10 was more concentrated in the west. These are strongly related to traffic patterns. The analysis is useful to establish the impact of PM and the assessment of urban exposure and better air quality planning. Long-term exposure to PM in conjunction with other dangerous air pollutants in urban aerosols of Ploiesti can lead to potential adverse effects on the population, especially for residents located in the most impacted areas. Full article