Search Results (152)

Dye-sensitized solar cells (DSSCs) are promising alternatives for power generation due to their environmental friendliness, cost effectiveness, and strong performance under diffused light. Conversely, their low spectral response in the ultraviolet (UV) region significantly obliterates their overall performance. The so-called luminescent down-shifting (LDS) presents a practical solution by converting high-energy UV photons into visible light that can be efficiently absorbed by sensitizer dyes. Herein, a conventional solid-state technique was applied for the synthesis of an LDS, europium (II)-doped barium orthosilicate (BaSiO₃:Eu²⁺) material. The material exhibited strong UV absorption, with prominent peaks near 400 nm and within the 200–300 nm range, despite a weaker response in the visible region. The estimated optical bandgap was 3.47 eV, making it well-suited for UV absorbers. Analysis of the energy transfer mechanism from the LDS material to the N719 dye sensitizer depicted a strong spectral overlap of $2\times {10}^{10}{\mathrm{M}}^{-1}{\mathrm{c}\mathrm{m}}^{-1}{\mathrm{n}\mathrm{m}}^4$, suggesting efficient energy transfer from the donor to the acceptor. The estimated Förster distance was approximately $6.83\mathrm{n}\mathrm{m}$, which matches the absorption profile of the dye-sensitizer. Our findings demonstrate the potential of BaSiO₃:Eu²⁺ as an effective LDS material for enhancing UV light absorption and improving DSSC performance through increased spectral utilization and reduced UV-induced degradation. Full article

Majority of commercial L-asparaginase (L-ASNase) activity assays are based on coupled enzymatic reaction, which converts aspartate into pyruvate, subsequently reacting with the probe to form a stable chromophore, which can be detected spectrophotometrically. However, in complex biological samples this method can be inaccurate due to poor optical transparency or presence of compounds interfering with the coupled enzyme reaction–for this kind of cases alternative methods have been suggested. Here we suggest a strategy to rationally pick a method of choice in a variety of situations, taking into consideration the upsides and downsides of each method. A high-throughput fluorometric assay employing the substrate Asp-AMC was rigorously validated for L-ASPNase activity screening. Aassay performance is evaluated in complex biological matrices, including bovine serum, whole and diluted human blood, and finally the mouse blood and liver homogenates samples obtained from pharmacokinetic studies. This comprehensive validation process ensures the reliability and applicability of the assay for assessing L-asparaginase activity in diverse and physiologically relevant environments. Potential interfering factors and matrix effects were addressed, and assay conditions were optimized for each matrix. The optimized assay was employed to screen various L-asparaginase types (intracellular L-ASNases type I RrA, periplasmic L-ASNases type II EcA and EwA) and ASPNase formulations (conjugates with polyamines or polyelectrolyte complexes), comparing their kinetic parameters and stability. Fourier-transform infrared (FTIR) spectroscopy was further employed to investigate the fine features of molecular mechanisms of L-asparaginase catalysis. FTIR spectra of Asn during hydrolysis were analyzed in buffer solutions and in complex biological matrices, such as blood sample or liver homogenates which is crucial in the context of pharmacokinetic research. This combined fluorometric and FTIR approach provides a powerful platform for optimizing L-ASNase formulations and therapeutic strategies for ALL. Based on the results obtained we have developed a strategy to choose an approach for L-Asparaginase activity assessment for a variety of difficult situations when dealing with complex biological samples. Full article

The currently used electrical energy devices for portable applications are in limited life and need of frequent recharging, it is a big bottleneck for wireless and transportation systems. The scientific community is motivated to find innovative and efficient devices to convert environmental energy into useful forms. Nanogenerator can mitigate this issue by harvesting ambient energy of different forms into useful electrical energy. Particularly flexible nanogenerators can efficiently convert ambient mechanical energy into electrical energy which can be fruitfully used for self-powered sensors and electronic appliances. Zinc oxide is an interesting photosensitive and piezoelectric material that is expected to play a vital role in the synergetic harvesting of environmental thermal, sound, mechanical, and solar energies. As ZnO can be synthesized using easy methods and materials at low cost, the conversion efficiencies of solar and other energy forms can increase considerably. ZnO is a versatile material with interesting semiconducting, optical, and piezoelectric properties; it can be used advantageously to harvest more than one type of ambient energy. The coupled semiconducting and piezoelectric properties of ZnO are attractive for fabricating nanogenerators capable of harvesting both ambient optical and mechanical energies simultaneously. These nanolevel conversion devices are much required to power remote and implantable devices without the need for additional power sources. The present review briefly discusses the principles and mechanisms of different energy harvesting abilities of ZnO nanorods and their composites by consolidating available literature. In addition, the developments taking place in nanogenerators of different kinds—such as photovoltaic, piezoelectric, pyroelectric, and triboelectrics for self-powered technology—and their progress in hybrid energy harvesting application is reviewed. Full article

Optoelectronic devices, which combine optics and electronics, are vital for converting light energy into electrical energy. Various solar cell technologies, such as dye-sensitized solar cells (DSSCs), silicon solar cells, and perovskite solar cells, among others, belong to this category. DSSCs have gained significant attention due to their affordability, flexibility, and ability to function under low light conditions. The current research incorporates machine learning (ML) models to predict the performance of a modified Eu³⁺-doped Y₂WO₆/TiO₂ photo-electrode DSSC. Experimental data were collected from the “Dryad Repository Database” to feed into the models, and a detailed data visualization analysis was performed to study the trends in the datasets. The support vector regression (SVR) and Random Forest regression (RFR) models were applied to predict the short-circuit current density (J_sc) and maximum power (P_max) output of the device. Both models achieved reasonably accurate predictions, and the RFR model attained a better prediction response, with the percentage difference between the experimental data and model prediction being 0.73% and 1.01% for the J_sc and P_max respectively, while the SVR attained a percentage difference of 1.22% and 3.54% for the J_sc and P_max respectively. Full article

We demonstrate the use of Laser Power Converters (LPCs) driven by fiber laser light while immersed in transformer oil for heat management purposes. Reliability tests performed via extended continuous operation using 6–7 W of input power from 808 nm and 976 nm light propagating through oil show no degradation of components nor transmission losses from the oil for up to 1000 h. The operation of a bare die designed for use with 1040–1080 nm light and in direct contact with oil is also shown to be feasible. We discuss how the use of transformer oil can be beneficial to transfer excess heat away from LPCs in special applications. Full article

High-efficiency multijunction laser power converters are demonstrated for the first time at high power for optical inputs around 1070 nm. The InP-based photovoltaic power-converting III–V heterostructures are designed with eight lattice-matched InGaAsP subcells (PT8-1070 nm). Conversion efficiencies of 55% were obtained at 18 W of output power. Endurance testing was performed for over 1000 h of continuous operation with an average output power of 13.2 W at an input wavelength of 1064 nm. An average steady-state efficiency of 54.4% at an ambient temperature of ~20 °C was obtained for that duration. The results demonstrate that 1 cm² optical power converter devices can produce electrical outputs of 20 W at maximum power voltages around V_mpp ~6 V, thus retaining an optimal load near R_mpp at ~2 ohms. Efficiencies between 57.9% and 59.0% were also obtained for smaller 0.029 cm² chips for input intensities between 35 and 69 W/cm². This is an important development for power beaming applications: the unprecedented combination of power and conversion efficiency capabilities is expected to enable deployments for key wavelengths between 1040 and 1080 nm. Full article

Achieving a stable color output across wide temperature ranges in automotive LED applications is challenging, especially when using cost-sensitive chips with limited computational resources. This study proposes an improved temperature model that integrates Fourier heat conduction and thermal resistance concepts to more accurately capture self-heating and power dissipation effects. To accommodate the constraints of low-cost automotive-grade microcontrollers (MCUs), the associated optical algorithm is converted from floating-point to a 16.16 fixed-point format, reducing both memory usage and computational overhead. Experimental results conducted from −40 °C to 120 °C show that the improved model predicts LED temperatures within 5 °C of measured values, reducing errors by up to 30% compared to conventional PN-junction-based methods. Furthermore, by comparing the chromaticity points generated under the new and traditional models—and implementing an additional three-duty-cycle offset at 1% brightness—the improved approach reduces chromaticity drift by approximately 0.0052 in the CIE 1931 xy color space. These findings confirm the superior stability and accuracy of the new model for both thermal management and chromaticity compensation, offering a cost-effective solution for automotive LED systems requiring precise color control under constrained MCU resources. Full article

The Cryo-PoF project is an R&D project funded by the Italian Insitute for Nuclear Research (INFN) in Milano-Bicocca (Italy). The technology at the basis of the project is Power over Fiber (PoF). By sending laser light through an optical fiber, this technology delivers electrical power to a photovoltaic power converter, in order to power sensors or electrical devices. Among the several advantages this solution can provide, we can underline the spark-free operation when electric fields are present, the removal of noise induced by power lines, the absence of interference with electromagnetic fields, and robustness in hostile environments. R&D for the application of PoF in cryogenic environments started at Fermilab in 2020; for the DUNE Vertical Drift detector, it was needed to operate the Photon Detector System on a high-voltage cathode surface. Cryo-PoF, starting from this project, developed a single-laser input line system to power, at cryogenic temperatures, both an electronic amplifier and Photon Detection devices, tuning their bias by means of the input laser power, without adding ancillary fibers. The results obtained in Milano-Bicocca will be discussed, presenting the tests performed using power photosensors at liquid nitrogen temperature. Full article

Accurately identifying the fault type of an optical current transformer (optical CT) and evaluating the fault severity can provide strong support for the operation and maintenance of a direct current (DC) power system. In response to the problems that current research overlooks, the spatiotemporal features when making fault identification, which restrain the improvement of identification accuracy, and consider fault identification as an assessment of fault severity, which is unable to provide effective information for actual operation and maintenance work, this paper proposes an optical CT fault severity assessment model based on scene generation and spatiotemporal feature fusion. Firstly, a CNN-Transformer model is constructed to mine the fault characteristics in spatial and temporal dimensions by feature fusion, achieving accurate identification of fault types. Secondly, an improved synthetic minority oversampling method is adopted to generate virtual operating scenes, and the operating range under different operating states of the optical CT is statistically obtained. Finally, based on Shapley Additive Explanations (SHAP), the importance of the feature of optical CT is evaluated under different fault types. Reliant on the importance of features and operating range under different running states, the severity of the fault is assessed by quantifying the difference between the fault state and the normal state of the optical CT under the identified fault type. This study validated the effectiveness of the proposed method using actual operational data from an optical CT at a converter station in Hebei Province in China. Full article

A platform for converting near-infrared (NIR) laser power modulation into the self-mixing (SM) signal of a quantum cascade laser (QCL) operating at terahertz (THz) frequencies is introduced. This approach is based on laser feedback interferometry (LFI) with a THz QCL using a metal-coated silicon nitride trampoline membrane resonator as both the external QCL laser cavity and the mechanical coupling element of the two-laser hybrid system. We show that the membrane response can be controlled with high precision and stability both in its dynamic (i.e., piezo-electrically actuated) and static state via photothermally induced NIR laser excitation. The responsivity to nanometric external cavity variations and robustness to optical feedback of the QCL LFI apparatus allows a highly sensitive and reliable transfer of the NIR power modulation into the QCL SM voltage, with a bandwidth limited by the thermal response time of the membrane resonator. Interestingly, a dual information conversion is possible thanks to the accurate thermal tuning of the membrane resonance frequency shift and displacement. Overall, the proposed apparatus can be exploited for the precise opto-mechanical control of QCL operation with advanced applications in LFI imaging and spectroscopy and in coherent optical communication. Full article

This paper proposes a novel reconfigurable intelligent surface (RIS)-assisted downlink hybrid free-space optics (FSO)/radio frequency (RF) space–air–ground integrated network (SAGIN) architecture, where the high altitude platform (HAP) converts the optical signal sent by the satellite into an electrical signal through optoelectronic conversion. The drone equipped with RIS dynamically adjusts the signal path to serve ground users, thereby addressing communication challenges caused by RF link blockages from clouds or buildings. To improve the security performance of SAGIN, this paper maximizes the sum secrecy rate (SSR) by optimizing the power allocation, RIS phase shift, and drone trajectory. Then, an alternating iterative framework is proposed for a joint solution using the simulated annealing algorithm, semi-definite programming, and the designed deep deterministic policy gradient (DDPG) algorithm. The simulation results show that the proposed scheme can significantly enhance security performance. Specifically, compared with the NOMA and SDMA schemes, the SSR of the proposed scheme is increased by 39.7% and 286.7%, respectively. Full article

Photonic millimeter-wave communication systems are promising for high-capacity, high-speed wireless networks, and their production is driven by the growing demand from data-intensive applications. However, challenges such as inter-symbol interferences (ISIs), inter-band interferences (IBIs), symbol timing offsets (STOs), and nonlinearity impairments exist, especially in non-orthogonal multiband configurations. This paper proposes and demonstrates the neural network-based waveform-to-symbol converter (NNWSC) for a coordinated multi-input and single-output (MISO) photonic millimeter-wave system with multiband multiplexing. The NNWSC replaces conventional matched filtering, down-sampling, and equalization, simplifying the receiver and enhancing interference resilience. Additionally, it reduces computational complexity, improving operational feasibility. As a proof of concept, experiments are conducted in a 16QAM non-orthogonal multiband carrierless amplitude and phase (NM-CAP) modulation system with coordinated MISO configurations in a scenario where two base stations have 5 km and 10 km fiber links, respectively. Data were collected across various roll-off factors, sub-band spacings, and received optical power (ROP) levels. Based on the proposed method, a coordinated MISO photonic millimeter-wave (mmWave) communication system at 91.9 GHz is demonstrated at a transmission speed of 30 Gbps. The results show that the NNWSC-based receiver achieves significant bit error rate (BER) reductions compared to conventional receivers across all configurations. The tolerances to the STO of NNWSC are also studied. These findings highlight NNWSC integration as a promising solution for high-frequency, interference-prone environments, with potential improvements for low-SNR and dynamic STO scenarios. Full article

In complex electromagnetic environments, such as substations, converter stations in power systems, and the compartments of aircraft, trains, and automobiles, electromagnetic immunity testing is crucial. It requires that the electric field sensor has features such as a large dynamic measurement range (amplitude from hundreds of V/m to tens of kV/m), a fast response speed (response time in the order of nanoseconds or sub-nanoseconds), a wide test bandwidth (DC to 1 GHz even above), miniaturization, and robustness to strong electromagnetic interference. This paper introduces a multi-channel, ultra-wideband transient electric field measurement system. The system’s analog bandwidth covers the spectrum from DC and a power frequency of 50 Hz to partial discharge signals, from DC to 1.65 GHz, with a storage depth of 2 GB (expandable). It overcomes issues related to the instability, insufficient bandwidth, and lack of accuracy of optical fibers in analog signal transmission by using front-end digital sampling based on field-programmable gate array (FPGA) technology and transmitting digital signals via optical fibers. This approach is effectively applicable to measurements in strong electromagnetic environments. Additionally, the system can simultaneously access four channels of signals, with synchronization timing reaching 300 picoseconds, can be connected to voltage and current sensors simultaneously, and the front-end sensor can be flexibly replaced. The performance of the system is verified by means of a disconnect switch operation and steady state test in an HVDC converter station. It is effectively applicable in scenarios such as the online monitoring of transient electromagnetic environments in high-voltage power equipment, fault diagnosis, and the precise localization of radiation sources such as partial discharge or intentional electromagnetic interference (IEMI). Full article

β-Ga₂O₃ holds significant promise for use in ultraviolet (UV) detectors and high-power devices due to its ultra-wide bandgap. However, the cost-effective preparation of large-area thin films remains challenging. In this study, β-Ga₂O₃ thin films are prepared using an inorganic solution reaction spin-coating method followed by post-annealing. The structures, surface morphologies, and optical properties of the films are then characterized using X-ray diffraction, scanning electron microscopy, and ultraviolet–visible spectrophotometry. A low-cost Ga metal was used to produce NH₄Ga(SO₄)₂, which was then converted into a precursor solution and spin-coated onto sapphire and quartz substrates. Ten cycles of spin coating produced smoother films, although higher annealing temperatures induced more cracks. The films on the (0001) sapphire subjected to spin-coating and preheating processes that were repeated for ten cycles, followed by annealing at 800 °C, had a preferred orientation in the [–201] direction. All the films showed high transmittances of 85% in ultraviolet–visible light with wavelengths above 400 nm. The films on the (0001) sapphire substrate that were annealed at 800 °C and 1000 °C exhibited bandgaps of 4.8 and 4.98 eV, respectively. The sapphire substrates demonstrated a superior compatibility for high-quality Ga₂O₃ film fabrication compared to quartz. This method offers a cost-effective and efficient approach for producing high-quality β-Ga₂O₃ films on high-temperature-resistant substrates with promising potential for optoelectronic applications. Full article

Multi-band optical communication presents a promising avenue for the significant enhancement of fiber-optic transmission capacity without incurring additional costs related to new cable deployment via the utilization of the bandwidth beyond the established C&L bands. However, a big challenge in its field implementation lies in the high cost and suboptimal performance of optical amplifiers, stemming from the underdeveloped state of rare-earth-doped fiber-optic amplifier technologies for these bands. Fiber-optic parametric amplifiers provide an alternative for wideband optical amplification, yet their low power efficiency limits their practical use in the field. In this paper, we study a hybrid optical amplifier that combines the excellent power efficiency of rare-earth-doped amplifiers with broadband wavelength conversion capability of parametric amplifiers. It uses wavelength converters to shift signals between the S- and L-bands, amplifying them with an L-band erbium-doped fiber amplifier, and converting them back to the S-band. We experimentally demonstrate such a hybrid S-band amplifier, characterize its performance with 16-QAM input signals, and evaluate its power efficiency and four-wave-mixing-induced crosstalk. This hybrid approach paves the way for scalable expansion of optical communication bands without waiting for advancements in rare-earth-doped amplifier technology. Full article