Search Results (651)

The results of precise measurements of the temperature dependencies of quadratic electro-optic coefficients, namely $g_{1111}-g_{1122}$ and $n_{\mathrm{o}}^3{g}_{1111}-n_{\mathrm{e}}^3{g}_{3311}$, in KH₂PO₄ (KDP) and KD₂PO₄ (DKDP) crystals at a wavelength of 632.8 nm are presented. We consider electro-optic coefficients describing changes in the optical impenetrability tensor resulting from an applied electric field, as well as intrinsic electro-optic coefficients defined in terms of induced polarization. The results show significant differences in the values of the analogous coefficients for the KDP and DKDP crystals and their temperature dependencies. Therefore, the quadratic electro-optic effect in KDP-type crystals cannot be easily described based solely on the contribution of PO₄ tetrahedra, as assumed in current models of the linear effect. Moreover, the values of the intrinsic coefficients in the KDP and DKDP crystals differ even more than the corresponding usual electro-optic coefficients, which contradicts the conventional belief in their lower variability. Full article

Understanding strain behavior near grain boundaries is critical for controlling structural distortions and oxygen vacancy migration in perovskite oxides. However, conventional techniques often lack the spatial resolution needed to analyze phase and domain evolution at the nanoscale. In this paper, polarization-dependent second-harmonic generation (SHG) imaging is employed as a tool to probe local symmetry breaking and complex domain structures in the vicinity of a low-angle grain boundary of SrTiO₃ (STO) bicrystals. We show that the anisotropic strain introduced by a tilted grain boundary produces strong local distortions, leading to the coexistence of tetragonal and rhombohedral domains. By analyzing SHG intensity and variations in the second-order nonlinear optical susceptibility, we map the distribution of strain fields and domain configurations near the boundary. In pristine samples, the grain boundary acts as a localized source of strain accumulation and symmetry breaking, while in samples subjected to intentional electrical stressing, the SHG response becomes broader and more uniform, suggesting strain relaxation. This work highlights SHG imaging as a powerful technique for visualizing grain-boundary-driven structural changes, with broad implications for the design of strain-engineered functional oxide devices. Full article

Conventional all-optical modulators based on surface plasmon polaritons (SPPs) primarily utilize the nonlinear effect of a given material for modulation. Their performance is heavily dependent on the optical properties of the dielectric materials used and requires high pumping power. However, manipulating SPPs by controlling electron concentrations offers a material-independent approach suitable for all-optical modulators. In this paper, we propose a hybrid gold–ITO–silver block structure integrated within a Mach–Zehnder interferometer configuration to address this problem. The gold–ITO interface effectively localizes propagating SPPs. The pump light excites localized surface plasmons (LSPs) in the silver block, generating surface electric fields that modulate the electron concentration in the adjacent ITO layer. The extinction ratio is 50.8 dB when the electron concentration changes by 3.3 × 10²⁰ cm⁻³, indicating that this structure is an all-optical modulator with a high extinction ratio. This approach shows significant promise for reducing pump power and enhancing the performance of all-optical modulators. Full article

Three-dimensional electric field sensors (3D EFSs) can simultaneously measure electric field components in three mutually orthogonal directions and comprehensively capture the spatial distribution and dynamic changes of the electric field. They can be widely used in atmospheric science, smart grids, aerospace, target detection, and other fields. This paper deeply analyzes the latest progress in 3D EFSs, focusing on four major types of sensors: DC field mill, electro-optic effect, capacitive sensing, and microelectromechanical system (MEMS). It elaborates on their working principles, structural design, and decoupling calibration methods. At the same time, the advantages and disadvantages of various types of 3D EFSs and their applications in different fields are analyzed. Finally, the challenges faced by 3D EFS technology and its future development direction are discussed. Full article

The present study investigates Vietnam’s economic structural transformation from 2007 to 2023, identifying key sectors contributing to output growth and poverty reduction. The study is situated within the broader context of industrialization and sustainable development in emerging economies. It employs structural decomposition analysis using Vietnam’s national input–output tables for the years 2007, 2011, 2015, 2019, and 2023. The analysis decomposes changes in total output into technical effects and final demand effects, allowing for an evaluation of the relative contributions of sectoral productivity and demand side factors. The findings of the study indicate that the manufacturing and services sectors have been the primary drivers of economic growth, with the electrical and optical equipment, food, beverages and tobacco, and basic metals sectors demonstrating particularly strong performance. The factor of final demand, which is derived from consumption, investment, and exports, has played a dominant role in driving output. Notably, export-led manufacturing has experienced significant benefits due to Vietnam’s engagement in free trade agreements. It is noteworthy that the agriculture sector demonstrated a period of recovery between 2019 and 2023, driven by an increase in final demand. This study underscores the pivotal function of sectoral adaptability, trade openness, and strategic policy in maintaining inclusive economic development. It is evident that the phenomenon under scrutiny is not only indicative of vulnerabilities and opportunities but also shaped by global shocks, for example, the coronavirus pandemic. Full article

A series of water-soluble molecules based on 8-isopropyl-2-methyl-5-nitroquinoline and 1,10-phenanthroline core were designed by introducing a π-conjugated bridge, vinyl unit –CH=CH–. We present the selective conversion of methyl groups located on the C2 and C9 positions in the constitution of selected quinoline or 1,10-phenanthroline derivatives, respectively, into vinyl (or styryl) products by applying Perkin condensation. The two groups of ligands differ in the presence of one or two arms. The structure of the molecule ((1E,1′E)-(1,10-phenanthroline-2,9-diyl)bis(ethene-2,1-diyl))bis(benzene-4,1,3-triyl) tetraacetate was determined by single-crystal X-ray diffraction measurements. The X-ray, NMR, and DFT computational studies indicate the influence of rotation (rotamers) on the physical properties of studied styryl molecules. The results show that the styryl molecules with the vinyl unit –CH=CH– exhibit significant static and dynamic hyperpolarizabilities. Quantum chemical calculations using density functional theory and B3LYP/6-311++G(d,p) with Grimme’s dispersion correction approach predict the existence and relative stability of different spatial cis(Z)- and trans(E)-conformers of styryl derivatives of quinoline and 1,10-phenanthroline, which exhibit different electronic distribution and conjugation within the molecular skeleton, dipole moments, and steric interactions, leading to variations in their photophysical behavior and various applications. Our studies indicate that the rotation and isomerization of aryl groups can significantly influence the electronic and optical properties of π-conjugated systems, such as vinyl units (–CH=CH–). The rotation of aryl groups around the single bond that connects them to the vinyl unit can lead to changes in the effective π-conjugation between the aryl group and the rest of the π-conjugated system. The rotation and isomerization of aryl groups in π-conjugated systems significantly impact their electronic and optical properties. These changes can modify the efficiency of π-conjugation, affecting charge transfer processes, absorption properties, light emission, and electrical conductivity. In designing optoelectronic materials, such as organic dyes, organic semiconductors, or electrochromic materials, controlling the rotation and isomerization of aryl groups can be crucial for optimizing their functionality. Full article

The development of artificial intelligence has resulted in significant challenges to conventional von Neumann architectures, including the separation of storage and computation, and power consumption bottlenecks. The new generation of brain-like devices is accelerating its evolution in the direction of high-density integration and integrated sensing, storage, and computing. The structural and information transmission similarity between memristors and biological synapses signifies their unique potential in sensing and memory. Therefore, memristors have become potential candidates for neural devices. In this paper, we have designed an optoelectronic memristor based on a ZnO/Cu₂O structure to achieve synaptic behavior through the modulation of electrical signals, demonstrating the recognition of a dataset by a neural network. Furthermore, the optical synaptic functions, such as short-term/long-term potentiation and learn-forget-relearn behavior, and advanced synaptic behavior of optoelectronic modulation, are successfully simulated. The mechanism of light-induced conductance enhancement is explained by the barrier change at the interface. This work explores a new pathway for constructing next-generation optoelectronic synaptic devices, which lays the foundation for future brain-like visual chips and intelligent perceptual devices. Full article

Tunable photonic devices are increasingly pivotal in modern optical systems, enabling the dynamic control over light propagation, modulation, and filtering. This review systematically explores two prominent classes of materials, thermo-optic and electro-optic, for their roles in such tunable devices. Thermo-optic materials utilize refractive index changes induced by temperature variations, offering simple implementation and broad material compatibility, although often at the cost of slower response times. In contrast, electro-optic materials, particularly those exhibiting the Pockels and Kerr effects, enable rapid and precise refractive index modulation under electric fields, making them suitable for high-speed applications. The paper discusses the underlying physical mechanisms, material properties, and typical figures of merit for each category, alongside recent advancements in organic, polymeric, and inorganic systems. Furthermore, integrated photonic platforms and emerging hybrid material systems are highlighted for their potential to enhance performance and scalability. By evaluating the tradeoffs in speed, power consumption, and integration complexity, this review identifies key trends and future directions for deploying thermo-optic and electro-optic materials in the next generation tunable photonic devices. Full article

An important aspect of lithium-ion batteries related to lifetime and aging is the change in state within the cells, which results from the expansion of the electrode materials and causes internal stress during operation. In this work, fiber optical sensors by means of Bragg gratings are utilized to determine the internal strain in the anode material. The collected data were employed to approximate aging-related changes in anode strain using a combination of established methods, such as the differential voltage and incremental capacity analysis. Moreover, additional methodologies are proposed and explored, substituting electrical data with optical strain measurements to quantify degradation effects linked to changes in strain. During the cycling of the cell, changes in the strain behavior have been observed and can be partially attributed to changes in the cell’s electrochemical composition. The methods suggested have proven effective in providing additional insights into the current state of the cells and tracking changes over time due to detected degradation effects. Full article

The Al-Sb co-doped SnO₂ composite thin films were prepared by the sol–gel spin-coating method. The structure, morphology, optical and electrical properties of the samples were investigated using XRD, XPS, SEM, UV-Vis spectroscopy, and Hall effect tester, respectively. It was found that when the aluminum doping amount was 15 at%, the resistivity of the sample was the lowest, and the overall optoelectronic performance was the best. Moreover, the Al-SnO₂ composite thin film transformed from an n-type semiconductor to a p-type semiconductor. When Al and Sb were co-doped, the carrier concentration increased significantly from 4.234 × 10¹⁹ to 6.455 × 10²⁰. Finally, the conduction type of the Al-Sb-SnO₂ composite thin film changed from p-type to n-type. In terms of optical performance, the transmittance of the Al-Sb co-doped SnO₂ composite thin films in the visible light region was significantly improved, reaching up to 80% on average, which is favorable for applications in transparent optoelectronic devices. Additionally, the absorption edge of the thin films exhibited a blue-shift after co-doping, indicating an increase in the bandgap energy, which can be exploited to tune the light-absorption properties of the thin films for specific photonic applications. Full article

The rise in temperature worldwide, especially in hot regions with extreme weather conditions, has made climate change one of the critical issues that degrades the solar photovoltaic (PV) system performance. In this paper, a new design of solar cells based on plasmonic thin-film Silver (Ag) technology is introduced. The new design is characterized by enhancing thermal effects, optical power absorption, and output power significantly, thus compensating for the deterioration in the solar cells efficiency when the ambient temperature rises to high levels. The temperature distribution on a PV solar module is determined using a three-dimensional computational fluid dynamics (CFD) model that includes the front glass, crystalline cells, and back sheet. Experimental and analytical results are presented to validate the CFD model. The parameters of temperature distribution, absorbed optical power, and output electrical power are considered to evaluate the device performance during daylight hours in summer. The effects of solar radiation falling on the solar cell, actual temperature of the environment, and wind speed are investigated. The results show that the proposed cells’ temperature is reduced by 1.2 °C thanks to the plasmonic Ag thin-film technology, which leads to enhance 0.48% real value as compared to that in the regular solar cells. Consequently, the absorbed optical power and output electrical power of the new solar cells are improved by 2.344 W and 0.38 W, respectively. Full article

The increasing demand for optical technologies with dynamic spectral control has driven interest in chromogenic materials, particularly for applications in tunable infrared metasurfaces. Phase-change materials such as vanadium dioxide and germanium–antimony–tellurium, for instance, have been widely used in the infrared regime. However, their reliance on thermal and electrical tuning introduces challenges such as high power consumption, limited emissivity tuning, and slow modulation speeds. Photochromic materials may offer an alternative approach to dynamic infrared metasurfaces, potentially overcoming these limitations through rapid, light-induced changes in their optical properties. This manuscript explores the potential of thiazolothiazole-embedded polymers, known for their reversible photochromic transitions and strong infrared absorption changes, for use in tunable infrared metasurfaces. The material exhibits low absorption and a strong photochromic contrast in the spectral range from 1500 ${\mathrm{cm}}^{-1}$ to 1700 ${\mathrm{cm}}^{-1}$, making it suitable for dynamic infrared light control. This manuscript reports on infrared imaging experiments demonstrating the photochromic contrast in thiazolothiazole-embedded polymer, and thereby provides compelling evidence for its potential applications in dynamic infrared metasurfaces. Full article

Nonlinear dynamical states generated by self-delayed feedback based on fiber structures have broad applications. However, fiber-based optoelectronic feedback or pure optical feedback systems exhibit long delays, and the coupling mechanisms between these two loops differ significantly from those in short-delay systems. A systematic investigation of feedback coupling mechanisms under long-delay conditions is of great significance for optimizing such systems. In this paper, the nonlinear dynamic state generated by directly modulated distributed feedback semiconductor laser (DM-DFBL) self-delayed feedback with an optoelectronic oscillation loop is studied. Both numerical and experimental results show that the DM-DFBL’s dynamical states vary with changes in optical and electrical feedback intensities. In the self-delayed feedback, the DM-DFBL exhibits an evolutionary path from a chaos (CO) state to a period-one (P1) state and finally becomes a steady state with the decrease of optical feedback intensity. In the optoelectronic oscillation loop, the DM-DFBL generates a microwave frequency comb (MFC), a full-frequency oscillation, and a P1 state. Additionally, the dynamic state of the DM-DFBL can be disturbed, and the stability of the P1 state and the QP state can be enhanced when the optoelectronic oscillation loop is introduced. These conclusions contribute to the precise control of dynamic evolution. Full article

Vanadium dioxide (VO₂) is a well-known phase-change material that exhibits a thermally driven insulator-to-metal transition (IMT) near 68 °C, leading to significant changes in its electrical and optical properties. This transition is governed by structural modifications in the VO₂ crystal lattice, enabling dynamic control over absorption, reflection, and transmission. Despite its promising tunability, VO₂-based optical absorbers face challenges such as a narrow IMT temperature window, intrinsic optical losses, and fabrication complexities associated with multilayer designs. In this work, we propose and numerically investigate a single-layer VO₂-based optical absorber for the visible spectrum using full-wave electromagnetic simulations. The proposed absorber achieves nearly 95% absorption at 25 °C (insulating phase), which drops below 5% at 80 °C (metallic phase), demonstrating exceptional optical tunability. This behavior is attributed to VO₂’s high refractive index in the insulating state, which enhances resonant light trapping. Unlike conventional multilayer absorbers, our single-layer VO₂ design eliminates structural complexity, simplifying fabrication and reducing material costs. These findings highlight the potential of VO₂-based crystalline materials for tunable and energy-efficient optical absorption, making them suitable for adaptive optics, smart windows, and optical switching applications. The numerical results presented in this study contribute to the ongoing development of crystal-based phase-transition materials for next-generation reconfigurable photonic and optoelectronic devices. Full article

Long-wave infrared (LWIR) broadband absorption is of great significance in science and technology. The electromagnetic field energy is absorbed by the metamaterials material, leading to the enhanced light absorption, from which the Metal–Dielectric–Metal (MDM) structure is designed. FDTD simulation calculation indicate that the bandwidth within which the absorber absorption ratio greater than 90% is 11.04 μm, and the average absorption rate (9.10~20.14 μm) is 93.6%, which can be accounted for by the impedance matching theory. Upon the matching of the impedance of the metamaterial absorber with the impedance of the incident light, the light reflection is reduced to a minimum, and increase the absorption ratio. Meanwhile, the good incidence angle unsensitivity due to the metasurface structural symmetry and the characteristics of the electromagnetic field distribution at different incidence angles. Due to the form regularity of the nanoring–nanowire metasurface structure, the light acts similar in different polarization directions, and the surface plasmon resonance plays a key role. Using FDTD electromagnetic field analysis to visualize the electric field and magnetic field strength distribution within the absorber, the electromagnetic field at the interface in the nanoring–nanowire metasurface structure, promote the surface plasmon resonance and interaction with damaged materials, and improve the light absorption efficiency. Moreover, the different microstructures and the electrical and optical properties of different top materials affect the light absorption. Meanwhile, adjusting the absorption layer thickness and periodic geometry parameters will also change the absorption spectrum. The absorber has high practical value in thermal electronic devices, infrared imaging, and thermal detection. Full article