Search Results (21)

Emergency diesel is prone to degradation during long-term storage, and experimental evaluations are costly and slow. Three-dimensional computational fluid dynamics (CFD) simulations were employed to model the diesel conditioning process. A physical model based on the actual dimensions of the storage tank was constructed. The volume of fraction (VOF) model tracked the gas–liquid interface, and the species transport model handled mixture transport. A UDF then recorded inlet and outlet flow rates and velocities in each cycle. The study focused on the effects of different baffle structures and numbers on conditioning efficiency. Results showed that increasing the baffle flow area significantly delays the mixing time but reduces the cycle time. Openings at the bottom of baffles effectively mitigate the accumulation of high-concentration conditioning oil caused by density differences. Increasing the number of baffles decreases the effective volume of the tank and amplifies density differences across the baffles, which shortens the mixing time. However, excessive baffle numbers diminish these benefits. These findings provide essential theoretical guidance for optimizing baffle design in practical diesel tanks, facilitating rapid achievement of emergency diesel quality standards while reducing costs and improving efficiency. Full article

With changing demands in regulation, understanding methane emissions from offshore oil and gas production infrastructure has become increasingly important. Reported emissions from facilities in the Gulf of Mexico range from zero to thousands of tons of methane per hour, but these is currently no clear understanding of how this range compares to expected emissions from normally operating facilities. To generate realistic emission estimates, we create two bottom-up models that simulate emissions from facilities operating in the Gulf of Mexico. We estimate type 1 prototypical facilities (typically unmanned, older, lower-producing platforms in shallow water with little processing equipment, compressors, or storage tanks) to emit an average of 13 kg CH₄ h⁻¹, which corresponds to a loss of 2.7% of the average facility production. Type 2 prototypical facilities (continuously manned, higher production and operate in deeper water with processing equipment, oil storage tanks, compressors and power generation) emit an average of 88 kg CH₄ h⁻¹, which corresponds to a loss of 2.5% of production. The average measured emission from type 1 facilities was 18 kg CH₄ h⁻¹ with a median production loss estimated at 8%. The average measured emission from type 2 facilities was 36 kg CH₄ h⁻¹ with a median production loss estimated at 2.4%. Using emission factors that consider the long-tail emission distribution partly reconciles the difference between modelled and measured emission estimates, but we suggest the current the fugitive emission estimate may be an underestimate and more data on the number and size of fugitive emissions could explain differences between the modelled and measured emission estimate. We suggest the bottom-up approach described here that uses production data coupled with facility equipment could be used to identify facilities that have abnormally large measured emissions, caused by methodological failure or larger than expected fugitive emissions, which should be targeted for further evaluation resulting in remeasurement or identification of source type so that a more accurate estimates can be made on the absolute emission. Full article

Volatile corrosion inhibitors (VCIs) are increasingly used in closed systems affected by atmospheric corrosion. In order to achieve a satisfactory level of protection, an inhibitor must be present in a sufficient concentration that should be determined experimentally. Electrochemical measurements are indispensable in corrosion studies examining the protection efficiency of corrosion inhibitors. Volatile corrosion inhibitors are often examined by electrochemical measurements conducted in a bulk of electrolyte, although they protect metal surfaces from atmospheric corrosion where a thin film of electrolyte is present. The aim of this work is to study the protection of carbon steel by two VCIs on different types of electrodes that allow electrochemical tests in a thin electrolyte film and to compare the obtained results with those obtained in a larger volume in a classical electrochemical cell. For this purpose, disc and comb-like electrodes are used. The investigations are carried out in two corrosion media simulating either a marine or urban polluted atmosphere. Studies are performed on low-carbon S235JR steel, which is typically used for crude oil tank bottoms that often suffer from atmospheric corrosion and are increasingly protected by VCIs. Two benzoate-based VCIs recommended for such application are selected for this study. Full article

This study developed a finite element model to address the issue of non-uniform settlement in large crude oil storage tanks. The model consisted of four key components: the tank foundation, bottom plate, wall plate, and large fillet welds. The Ramberg-Osgood model was used to describe the material’s nonlinearity. Key factors such as the radius-to-thickness ratio, height-to-diameter ratio, harmonic number, and amplitude were evaluated for their impact on the radial deformation of the tank’s top wall. Two numerical models were developed—one accounting for the coupling effect between the foundation and the tank bottom, and the other without it. The differences in radial deformation between these models were analyzed, revealing that deformation was minimally influenced by the radius-to-thickness ratio, but increased with higher height-to-diameter ratios and harmonic amplitudes. At low liquid levels, radial deformation increased with harmonic number, but at high levels, it decreased once the harmonic number exceeded four due to the decoupling of the tank bottom from the foundation. The model considering foundation coupling exhibited less radial deformation compared to the one neglecting it, particularly as the harmonic number and amplitude increased. An improved evaluation method identified a critical range of harmonic amplitudes for a 100,000 m³ tank, within which the coupling effect can be reasonably neglected, allowing deformation to be calculated using the simpler model. Full article

Ship grounding onto multiple rocks is one of the scenarios where a ship may suffer severe hull damage, thus leading to some serious consequences, such as casualties, oil spill pollution, and property damage. Ship bottom raking is the most common and severe damage type in grounding caused by sharp rocks moving against the bottom plate. This paper investigates the dynamic responses of ship grounding onto multiple sharp rocks, which has rarely been studied in the literature. Nine ship grounding in-tank model tests were conducted to provide experimental data for ship grounding onto a single rock or multiple rocks. A simplified scaled ship model with replaceable bottom plating was designed and used in the model test. Some artificial cone rock models with a 1 mm tip radius and a 15° semi-apex angle were assumed. The damage modes of the bottom plating and motions during ship grounding onto multiple rocks were obtained and recorded in the model tests, as well as the longitudinal grounding resistances. The effects of the initial relative height of each rock and the size of rock distribution on the structural damage mode and dynamic response of a ship model in multi-rock ship grounding were investigated. In addition, the results obtained from single-rock and multi-rock ship grounding model tests are compared. Full article

This paper presents an acoustic emission (AE) detection method for refined oil storage tanks which is aimed towards specialized places such as oil storage tanks with high explosion-proof requirements, such as cave oil tanks and buried oil tanks. The method utilizes an explosion-proof acoustic emission instrument to detect the floor of a refined oil storage tank. By calculating the time difference between the defective acoustic signal and the speed of acoustic wave transmission, a mathematical model is constructed to analyze the detected signals. An independent channel AE detection system is designed, which can store the collected data in a piece of independent explosion-proof equipment, and can analyze and process the data in a safe area after the detection, solving the problems of a short signal acquisition distance and the weak safety protection applied to traditional AE instruments. A location analysis of the AE sources is conducted on the bottom plate of the tank, evaluating its corrosion condition accurately. The consistency between the evaluation and subsequent open-tank tests confirms that using AE technology effectively captures corrosion signals from oil storage tanks’ bottoms. The feasibility of carrying out online inspection under the condition of oil storage in vertical steel oil tanks was verified through a comparison with open inspections, which provided a guide for determining the inspection target and opening order of large-scale oil tanks. Full article

In order to study the mechanical properties of inverted cone bottom oil storage tanks under earthquakes when the foundation is uneven, finite element modeling calculation for a 20,000 m³ storage tank is carried out based on ANSYS Workbench. Wind load, hydraulic pressure load, and seismic load are all equalized as distributed loads with varying spatial positions. Considering various combinations of different heterogeneous foundations and seismic loads, and by adjusting the preset foundation bed coefficient, the final foundation bed coefficient and the maximum foundation settlement value when the equivalent stress of the tank floor reaches yield strength under different conditions are calculated. The results show that under the condition of heterogeneous foundation stiffness considering seismic action, when the coefficient of local foundation bed is higher than that of natural silty clay, the requirement for safe use of the inverted cone bottom storage tank can be met. Among the seven simulated heterogeneous foundation forms, the form with high foundation stiffness on the windward side has a great influence on the safety of storage tanks. Full article

The longitudinal girder (LG) between fuel oil tanks (FOT) and water ballast tanks in the double bottoms of ships represent critical structural parts whose watertight nature could be harmed by corrosion, thus, causing the pollution of water ballast tanks and adjacent areas. The new common structural rules (CSR) define the minimum thickness values of structural elements and corrosion margins. The assessment of the deviations from the prescribed values during ship operation could optimize the prescribed criteria. Assuming that corrosive processes begin after four years of operation, the paper analyzes a linear model that describes the percentage of plate wear as a function of the built-in thickness of LG of FOT. The research included 20 ships and provided the database for 1918 corrosion depth values. The gauging records included the average values of the original thickness of steel plates grouped in three intervals (11–13 mm, 13–15 mm, 15–18 mm). Based on the difference between the built-in and subsequently measured values, the paper analyzes the percentage of thickness reduction due to corrosion, concerning the original plate thickness. The findings of the research should facilitate the optimization of corrosion margins and prevent potential structural collapse and pollution. Full article

Nowadays, the floating production storage and offload system (FPSO) is one of the most common platform types for offshore oil production. The traditional arrangement of the stiffened panels creates obstacles for automated cleaning and inspections by remote devices. This paper summarizes the results of an initial study for the design and construction of FPSO hulls with SPS in order to overcome this problem. The main goal is to have the walls and bottom of the cargo tanks free of stiffeners. This research is conducted by first designing the hull with a conventional structural arrangement using steel according to the ABS rules as a benchmark. Following that, the equivalent hull structure with sandwich plates is designed in accordance with the guidelines for SPS construction from DNV rules. Finally, this paper provides the results of a finite element analysis to compare the stresses and ultimate strengths of both types of structures. Briefly, the main results are that the SPS design provides a reduction of 2.8% of the total weight and a better overall structural performance by an increase of 26% for the ultimate strength of the hull. Full article

Asphaltene is a component of crude oil that has remained relatively unexplored for organic electronic applications. In this study, we report on its extraction technique from crude oil tank bottom sludge (COTBS) and its thin-film characteristics when 1-ethyl-3-methylimidazolium chloride ([EMIM]Cl) ionic liquid (IL) was introduced as dopants. The extraction technique yielded asphaltene with more than 80% carbon content. The IL resulted in asphaltene thin films with a typical root-mean-square surface roughness of 4 nm, suitable for organic electronic applications. The thin films each showed an optical band gap of 3.8 eV and a sheet resistance as low as 10⁵ Ω/□. When the film was used as a conductive layer in organic field-effect transistors (OFET), it exhibited hole and electron conduction with hole (µ_h) and electron (µ_e) mobilities in the order of 10⁻⁸ and 10⁻⁶ cm²/Vs, respectively. These characteristics are just preliminary in nature. With the right IL, asphaltene thin films may become a good alternative for a transport layer in organic electronic applications. Full article

Mexico approved amendments to its constitution in December 2013 that initiated transformational changes to its energy sector. This study developed a 2016 bottom-up emissions inventory for volatile organic compounds (VOCs), nitrogen oxides (NO_x), sulfur dioxide (SO₂), carbon monoxide (CO), and fine particulate matter (PM_2.5) from upstream and midstream sector sources, including onshore and offshore well sites, gas flaring, natural gas processing facilities, and natural gas compressor stations, throughout Mexican basins. Crude oil storage tanks at onshore oil well sites and venting and fugitive sources at offshore oil production sites were the primary sources of VOC emissions. Key contributions to NO_x, CO, and PM_2.5 emissions were from internal combustion engines at offshore oil well sites and midstream operations. SO₂ emissions were associated with onshore and offshore gas flaring and boilers and process heaters at natural gas processing facilities. Application of the inventory with the Comprehensive Air Quality Model with Extensions (CAMx) indicated that oil and gas production operations could contribute to ozone and PM_2.5 concentrations in Mexican and U.S. states under favorable transport patterns. This study provides a foundation for assessing the implications of Mexico’s future energy policies on emissions and domestic and cross-border air quality and public health. Full article

Among the wastes produced in a refinery are solids containing water, in particular: (i) bottom sludge accumulated in storage tanks and (ii) sludge agglomerated during the processing of crude oil. Potentially useful industrial secondary resources, co-processed with clays lead to the manufacturing of novel ceramic building products. Among the expected advantages, resulting to industrial symbiosis, is the inclusion of ashes and residual metals from the wastes within the ceramic structure, leading to the inertization of inorganic ingredients, through the thermal processing of clay to building ceramic products. Full article

The oil tank can form a considerable amount of sludge deposition after continuous accumulation, which cause a seriously negative impact on both the storage capacity and the safe operation of the oil tank. Therefore, it is important to anticipate the rate of sludge deposition in advance so that proper measures can be planned to remove this heavy layer on the bottom. This paper proposes a method using a relatively simple formula for predicting the sludge deposits. The sedimentation mechanism of wax and asphaltene is introduced and summarized from both the micro and macro aspects, the factors causing the interaction between particles and the influence on coalescence were analyzed. We applied our prediction methods to calculate the sludge deposition of four oil tanks in Mo-he Station and compared our results with the data measured by experiments. The results show that our method had a good general accuracy to experimental data and can be used directly for on-site engineers to anticipate real sludge height before measuring the oil level inside the tank. Full article

The latent heat thermal energy storage units are very popular because of their high energy density and almost close to constant temperature during the charging/discharging. In the present study has been proposed new shell-and-coil geometry with a shifted coil position to enhance the performance of phase change thermal magazine. The experimental investigations have been performed both for the melting and solidification process of coconut oil for constant wall temperature conditions. The experiments have been carried out for cylindrical as well as coil shape geometry of the TES unit. In the case of annular TES, the copper tube with outer diameter d = 10 mm and total length equal to 165 mm were used (4). In the case of shell-and-coil TES the coil has been also made of a copper tube but with an outer diameter d = 6 mm. The total length of the tube was 460 mm. However, the length of the tube element that has been used in the process of bending the coil had a total length equal to 360 mm. The rest of the tube was straight. The coil pitch was 15 mm and the outer coil diameter was 26 mm. The experiments have been conducted for the coil position at the top and the bottom of the tank. The results showed the influence of heat transfer geometry for phase change efficiency. The article presents the thermal characteristic of melting and solidification phenomena as well as their visual analysis. A significant impact of heat transfer geometry at the shape of the melting and solidification profile. The optimal performance has been achieved for shell-and-coil TES with a coil arranged at the top of the tank. Full article

The generation of sewage sludge presents a problem for several manufacturing companies as it results from industrial processes or effluent treatment systems. The treatment of this type of waste requires high economic investment, for this reason, it is necessary to find alternatives to recover the valuable materials of the sludges. In this study, metal catalysts were synthesized using waste sludge from the steel, mining, and hydrocarbon industries. The waste sludge was subjected to thermal treatments for the removal of organic content and the reduction of metals with hydrogen current to activate their catalytic properties. The sludge and synthesized catalysts were analyzed to determine their physical, chemical, thermoenergetic, and catalytic properties. Catalytic activity was evaluated using CO chemisorption and by thermal–catalytic decomposition of crude oil. The best conditions for synthesizing the catalysts were a calcination temperature between 300 and 500 °C and a reduction temperature between 300 and 900 °C. The catalysts presented a specific surface between 2.33 and 16.78 m²/g. The catalytic material had a heat capacity between 0.7 and 1.2 kJ/kg∙K. The synthesized materials presented catalytic activity comparable to that of commercial catalysts. With this recovery technique, the industrial waste can be valorized, obtaining catalyst derived from the sludges and promoting the circular economy of manufacturing companies. Full article