Search Results (56)

The current work is established with the object of modifying the source of Fenton system and substituting iron source as a catalyst with magnetite/potato peels composite material (POT400-M) to be an innovative solar photocatalyst. The structural and morphological characteristics of the material are assessed through X-ray diffraction (XRD) and scanning electron microscopy (SEM). The technique is applied to treat oil spills that pollute seawater. The effectiveness of the operating parameters is studied, and numerical optimization is applied to optimize the most influential parameters on the system, including POT400-M catalyst (47 mg/L) and hydrogen peroxide reagent (372 mg/L) at pH 5.0, to maximize oil removal, reaching 93%. Also, the aqueous solution and wastewater temperature on the oxidation reaction is evaluated and the reaction exhibited an exothermic nature. Kinetic modeling is evaluated, and the reaction is found to follow the second-order kinetic model. Thermodynamic examination of the data exhibits negative enthalpy (ΔH′) values, confirming that the reaction is exothermic, and the system is verified to be able to perform at the minimal activation energy barrier (−51.34 kJ/mol). Full article

The Bohai Sea is the only semi-enclosed inland sea in China. With active marine economic activities, it faces a persistently high risk of oil spill accidents. This study assesses the occurrence risk and pollution risk of oil spills by considering factors such as sea state, the location of oil platform, and shipping route density in the Bohai Sea. The results show that the central part of the Bohai Sea, the southern Liaodong Peninsula, and the Bohai Strait area have a relatively high occurrence risk of oil spills due to busy maritime traffic and harsh sea conditions. In contrast, some areas in the northern, western, and southern parts of the Bohai Sea have a relatively low occurrence risk of oil spills because of weak maritime activity intensity and relatively calm sea state. In terms of the oil pollution risk, its distribution in the Bohai Sea shows significant seasonal characteristics, which are mainly comprehensively affected by multiple dynamic factors such as circulation, monsoon, and seawater exchange. Based on the oil pollution risk distribution, seasonally targeted strategies are proposed, which can provide a scientific basis for oil spill prevention and emergency management in the Bohai Sea, and help relevant departments formulate targeted prevention and control strategies. Full article

This study assesses the spatial distribution and contamination levels of some heavy metals (HMs), i.e., cadmium (Cd), chromium (Cr), copper (Cu), nickel (Ni), and lead (Pb), in seawater and surface sediments along the Romanian Black Sea coast (RBSC). Sampling was conducted at 40 stations across 12 transects during May–June 2021, and the measured levels of HM concentrations were compared with Environmental Quality Standards (EQS), i.e., maximum allowable concentration (MAC) values, for seawater and effects range-low (ERL) thresholds for sediments. HM concentrations were measured using high-resolution continuum source atomic absorption spectrometry (HR-CS AAS). In seawater, the levels of Cd, Cu, and Pb concentrations exceeded the MAC values at three stations located in areas influenced by the Danube River or anthropogenic activities. In sediments, exceedances of ERL thresholds were found for Ni at 11 stations, for Cu at three stations, and for Pb at one station. HM contamination of sediment samples collected from these stations can be caused by both natural and anthropogenic sources, e.g., the Danube River, rock/soil weathering and erosion, agricultural runoff, port and construction activities, maritime and road transport, coastal tourism, petrochemical industry, wastewater discharges, offshore oil and gas extraction. Principal Component Analysis (PCA) provided valuable information about the relationships between relevant variables, including water depth and HM concentrations in seawater and sediments, and potential sources of contamination. The results highlight the influence of fluvial inputs and localized human activities on HM contamination. While the overall chemical status of Romanian Black Sea waters and sediments remains favorable, targeted management strategies are needed to address localized pollution hotspots and mitigate potential ecological risks. These findings provide valuable insights for environmental monitoring and sustainable coastal management. Full article

Macroscopic structures consisting of two or more materials are called composites. The decreasing reserves of the world’s oil reserve and the environmental pollution of existing energy and production resources made the use of recycling methods inevitable. There are mechanical, thermal, and chemical recycling methods for the recycling of thermosets among composite materials. The recycling of thermoset composite materials economically saves resources and energy in the production of reinforcement and matrix materials. Due to the superior properties such as hardness, strength, lightness, corrosion resistance, design width, and the flexibility of epoxy/vinylester/polyester fibre formation composite materials combined with thermoset resin at the macro level, environmentally friendly sustainable development is happening with the increasing use of composite materials in many fields such as the maritime sector, space technology, wind energy, the manufacturing of medical devices, robot technology, the chemical industry, electrical electronic technology, the construction and building sector, the automotive sector, the defence industry, the aviation sector, the food and agriculture sector, and sports equipment manufacturing. Bonded joint studies in composite materials have generally been investigated at the level of a single composite material and single joint. The uncertainty of the long-term effects of different composite materials and environmental factors in single-lap bonded joints is an important obstacle in applications. The aim of this study is to investigate the effects of single-lap bonded GFRP (glass fibre-reinforced polymer) and CFRP (carbon fibre-reinforced polymer) specimens on the material at the end of seawater exposure. In this study, 0/90 orientation twill weave seven-ply GFRP and eight-ply CFRP composite materials were used in dry conditions (without seawater soaking) and the hand lay-up method. Seawater was taken from the Aegean Sea, İzmir province (Selçuk/Pamucak), in September at 23.5 °C. This seawater was kept in different containers in seawater for 1 month (30 days), 2 months (60 days), and 3 months (90 days) separately for GFRP and CFRP composite samples. They were cut according to ASTM D5868-01 for single-lap joint connections. Moisture retention percentages and axial impact tests were performed. Three-point bending tests were then performed according to ASTM D790. Damage to the material was examined with a ZEISS GEMINESEM 560 scanning electron microscope (SEM). The SEM was used to observe the interface properties and microstructure of the fracture surfaces of the composite samples by scanning images with a focused electron beam. Damage analysis imaging was performed on CFRP and GFRP specimens after sputtering with a gold compound. Moisture retention rates (%), axial impact tests, and three-point bending test specimens were kept in seawater with a seawater salinity of 3.3–3.7% and a seawater temperature of 23.5 °C for 1, 2, and 3 months. Moisture retention rates (%) are 0.66%, 3.43%, and 4.16% for GFRP single-lap bonded joints in a dry environment and joints kept for 1, 2, and 3 months, respectively. In CFRP single-lap bonded joints, it is 0.57%, 0.86%, and 0.87%, respectively. As a result of axial impact tests, under a 30 J impact energy level, the fracture toughness of GFRP single-lap bonded joints kept in a dry environment and seawater for 1, 2, and 3 months are 4.6%, 9.1%, 14.7%, and 11.23%, respectively. At the 30 J impact energy level, the fracture toughness values of CFRP single-lap bonded joints in a dry environment and in seawater for 1, 2, and 3 months were 4.2%, 5.3%, 6.4%, and 6.1%, respectively. As a result of three-point bending tests, GFRP single-lap joints showed a 5.94%, 8.90%, and 12.98% decrease in Young’s modulus compared to dry joints kept in seawater for 1, 2, and 3 months, respectively. CFRP single-lap joints showed that Young’s modulus decreased by 1.28%, 3.39%, and 3.74% compared to dry joints kept in seawater for 1, 2, and 3 months, respectively. Comparing the GFRP and CFRP specimens formed by a single-lap bonded connection, the moisture retention percentages of GFRP specimens and the amount of energy absorbed in axial impact tests increased with the soaking time in seawater, while Young’s modulus was less in three-point bending tests, indicating that CFRP specimens have better mechanical properties. Full article

At present, energy demands are mainly covered by the use of fossil fuels. The process of fossil fuel production increases pollution from oil extraction, transport to processing centers, treatment to obtain lighter fractions, and delivery and use by the final consumers. Such polluting circumstances are aggravated in the case of accidents involving fossil fuels. They are also linked to speculative markets. As a result, the trend is towards the decarbonization of lifestyles in advanced societies. The present paper addresses the problem of the optimal sizing of a hybrid renewable energy system for scheduling green hydrogen production. A local system fully powered by renewable energies is designed to obtain hydrogen from seawater. In order to monetize excess energy, the grid connection of the system is considered under realistic energy market constraints, designing an hourly purchasing strategy. This crucial problem, which has not been taken into account in the literature, is solved by the specific dispatch strategy designed. Several optimization methods have been used to solve this problem; however, the scatter search method has not previously been employed. In this paper, the problem is faced with a novel implementation of this method. The implementation is competitive in terms of performance when compared to, on the one hand, the genetic algorithm and differential evolution methods, which are well-known state-of-the-art evolutionary algorithms, and, on the other hand, the optimal foraging algorithm (OFA), a more recent algorithm. Furthermore, scatter search outperformed all other methods in terms of computational cost. This is promising for real-world applications that require quick responses. Full article

Maritime transport has adapted to recent political and economic shifts by addressing stringent pollution reduction requirements, redrawing transport routes for safety, reducing onboard technical incidents, managing data security risks and transitioning to autonomous vessels. This paper presents a novel approach to predictive maintenance in the maritime industry, leveraging Artificial Intelligence (AI) and Machine Learning (ML) techniques to enhance fault detection and maintenance planning for naval systems. Traditional maintenance strategies, such as corrective and preventive maintenance, are increasingly ineffective in meeting the high safety and efficiency standards required by maritime operations. The proposed model integrates AI-driven methods to process operational data from shipboard systems, enabling more accurate fault diagnosis and early identification of system failures. By analyzing historical operational data, ML algorithms identify patterns and estimate the functional states, helping prevent unplanned failures and costly downtime. This approach is critical in environments where technical failures are a leading cause of incidents, as demonstrated by the high rate of machinery-related accidents in maritime operations. Our study highlights the growing importance of AI and ML in predictive maintenance and offers a practical tool for improving operational safety and efficiency in the naval industry. The paper discusses the development of a fault detection approach, evaluates its performance on real shipboard data-through tests on a seawater cooling system from an oil tanker and concludes with insights into the broader implications of AI-driven maintenance in the maritime sector. Full article

With the advancement of deep-sea exploration, the demand for underwater manipulators capable of long-duration heavy-duty operations has intensified. Water-hydraulic systems exhibit less viscosity variation with increasing depth than oil-based systems, offering better adaptability to deep-sea conditions. Using seawater as the driving medium inherently eliminates issues such as oil contamination by water, frequent maintenance limiting underwater operation time, and environmental pollution caused by oil leaks. This paper introduces a deep-sea manipulator directly driven by seawater from the deep-sea environment. To address the challenges of weak lubrication and high corrosion associated with water hydraulics, a reciprocating plunger seal was adopted, and a water-hydraulic actuator was developed. The installation positions of actuator hinges and maximum output force requirements were optimized using particle swarm optimization (PSO), effectively reducing the manipulator’s self-weight. Through kinematic and inverse kinematic analyses and joint performance tests, a six-degree-of-freedom water-hydraulic manipulator was designed with a maximum reach of 2.5 m, a lifting capacity of 5000 N, and end-effector positioning accuracy within 18 mm. Full article

Qatar and other Gulf States have a diverse range of marine vegetation that is adapted to the stressful environmental conditions of seawater. The industrial wastewater produced by oil and gas activities adds further detrimental conditions for marine aquatic photosynthetic organisms on the Qatari coastlines. Thus, these organisms experience severe stress from both seawater and industrial wastewater. This review discusses the biodiversity in seawater around Qatar, as well as remediation methods and metabolic pathways to reduce the negative impacts of heavy metals and petroleum hydrocarbons produced during these activities. The role of microorganisms that are adjacent to or associated with these aquatic marine organisms is discussed. Exudates that are released by plant roots enhance the role of microorganisms to degrade organic pollutants and immobilize heavy metals. Seaweeds may have other roles such as biosorption and nutrient uptake of extra essential elements to avoid or reduce eutrophication in marine environments. Special attention is paid to mangrove forests and their roles in remediating shores polluted by industrial wastewater. Seagrasses (Halodule uninervis, Halophila ovalis, and Thalassia hemprichii) can be used as promising candidates for phytoremediation or bioindicators for pollution status. Some genera among seaweeds that have proven efficient in accumulating the most common heavy metals found in gas activities and biodegradation of petroleum hydrocarbons are discussed. Full article

Ecosystem functioning depends on complex interactions between microorganisms, hosts, and the environment. Changes in environmental conditions (e.g., ocean acidification) in combination with anthropogenic pollution have been shown to affect the composition and function of free-living microbial communities, but little is known about the effects these stressors on host-associated communities. This study aims to characterize the response of host-associated bacterial communities of the bottom-dwelling polychaete Hediste diversicolor and the epibenthic gastropod Peringia ulvae to oil contamination and reduced seawater pH. The independent and interactive effects of both stressors were simulated under controlled conditions. The response of host-associated bacterial communities was assessed using the high-throughput sequencing of the 16S rRNA gene and several biochemical markers related to host metabolic pathways, e.g., neurotransmission, anaerobic metabolism, biotransformation, oxidative stress, and energy consumption. In H. diversicolor, reduced seawater pH was associated with a high relative abundance of Cyanobacteria, while in P. ulvae oil contamination was associated with a reduction in the relative abundance of Chitinophagales. In P. ulvae, enrichment with oil hydrocarbon-degrading bacteria suggests a possible role of these organisms in the dispersion of oil hydrocarbon degraders. Furthermore, oil supplementation shifted some specific biochemical markers of gastropods related to oxidative stress and energy consumption, which suggests host stress. In general, the bacterial communities and biochemical markers of the gastropod were more affected by stressors than those of the polychaete. Overall, this study contributes to a better understanding of the response of host-associated bacterial communities of benthic macrofauna to anthropogenic contamination and environmental change. Full article

The search for practical solutions to alleviate the destructive impact of petroleum hydrocarbons in marine environments is contributing to the implementation of prospecting strategies for indigenous microorganisms with biodegradative and bioremediation potential. The levels of petroleum contamination entering the marine environment each year have been estimated at around 1.3 million tonnes, a figure that is expected to increase by 1.9% annually over the next decade. The recent interest in decarbonizing our energy system and accelerating the clean energy transition has created a demand for greener technologies and strategies to find innovative, sustainable, and cost-effective treatments for the marine environment. Diatoms (Bacillariophyta) are one of the most diverse and successful taxa in coastal–marine environments and are a relatively untapped pool of biodiversity for biotechnological applications. Recent reports have revealed the significant presence of diatoms associated with oil spills and petroleum hydrocarbon degradation. Most diatoms can secrete substantial amounts of exopolysaccharides (EPSs) into their environment, which can act as biosurfactants that, in addition to oxygen and other enzymes produced by diatoms, create suitable conditions to enhance hydrocarbon solubility and degradation into less toxic compounds in seawater. Recent reports on the biodegradation of aliphatic and aromatic hydrocarbons by diatoms are indicative of the potential of these taxa to achieve success in the bioremediation of hydrocarbons in marine environments. This review highlights the main attributes and roles that diatoms could play in integrated strategies for biodegradation and bioremediation of petroleum hydrocarbon pollutants and as such represent a green, eco-friendly, and sustainable contribution to mitigate damage to biodiversity and value chains of marine ecosystems. Full article

Pollution caused by marine oil spills can lead to persistent ecological disasters and severe social and economic damages. Numerical simulations are useful and essential tools for accurate decision making during emergencies and planning response actions. In this study, we applied the Princeton Ocean Model (POM) to determine current data, including seawater velocity, salinity, and temperature, and we obtained the fate and trajectory of spilled oil using OpenOil. Several probable oil slicks around Taiwan were simulated over time (12 months) and space (four spill locations in the marine area of each coastal city or county) using the model. The percentage risk under the effect of an oil spill is estimated. The risk zone of the coastal waters of Taiwan was identified based on the frequency of simulated oil slicks hitting the coast and sensitive resources. This information not only helps authorities guide the preparation of effective plans to minimise the impacts of oil spill incidents but could also be used to improve regulations related to shipping and vessel navigation in regional seas. Full article

In recent years, the ecosystem has been seriously affected by sewage discharge and oil spill accidents. A series of issues (such as the continuous pollution of the ecological environment and the imminent exhaustion of freshwater resources) are becoming more and more unmanageable, resulting in a crisis of water quality and quantity. Therefore, studies on industrial wastewater purification and solar-driven seawater desalination based on wood composites have been widely considered as an important development direction. This paper comprehensively analyzes and summarizes the applications of wood composites in the fields of solar-driven seawater desalination and polluted water purification. In particular, the present situation of industrial wastewater containing heavy metal ions, microorganisms, aromatic dyes and oil stains and related problems of solar-driven seawater desalination are comprehensively analyzed and summarized. Generally, functional nanomaterials are loaded into the wood cell wall, from which lignin and hemicellulose are selectively removed. Alternatively, functional groups are modified on the basis of the molecular structure of the wood microchannels. Due to its three-dimensional (3D) pore structure and low thermal conductivity, wood is an ideal substrate material for industrial wastewater purification and solar-driven seawater desalination. Based on the study of objective conditions such as the preparation process, modification method and selection of photothermal conversion materials, the performances of the wood composites in filtration, adsorption and seawater desalination are analyzed in detail. In addition, this work points out the problems and possible solutions in applying wood composites to industrial wastewater purification and solar-driven seawater desalination. Full article

On maritime vessels, external factors such as explosions, collisions, and grounding can cause the emulsification of lubricating oil by seawater pollution, which can affect the lubrication of a ship’s thrust bearing. To explore the influence of the mixed emulsification of lubricating oil and seawater on the lubrication performance of thrust bearings, this study conducted an emulsification experiment, from which the viscosity equation of the oil–water mixture was obtained. A thermal hydrodynamic model (THD) of bearings considering oil–water mixed emulsification was established, and the Finite Difference Method (FDM) was used for analysis. The results show that according to the characteristics of the manifold, the mixture is divided into water-in-oil (W/O) and oil-in-water (O/W). In the W/O flow with higher viscosity, the film thickness becomes higher, but the power loss increases. In the O/W manifold with low viscosity, the thin film easily causes mixed friction. In the demulsification stage of the mixed liquid, the thickness loss of the film is huge, and the collision between the thrust-bearing pad and the inference plate may cause the pad to be ablated. The influence of specific heat capacity on temperature is greater than the temperature rise caused by viscosity. Full article

The present research is related to the study of p-cresol oxidation reaction in aqueous phase. Firstly, the conventional advanced oxidation process (AOP) in a lab-scale batch reactor was used, seeking to identify the most impacting process variables and then to propose an optimization approach for ensuring the complete p-cresol degradation and the highest total organic carbon (TOC) conversion. In the AOP with the use of hydrogen peroxide as the oxidizing agent, the oxidation reaction was optimized with the aid of a factorial design, and a maximum TOC conversion of 63% was obtained. The Lumped Kinetic Model (LKM) was used to describe the profile of residual TOC concentration due to chemical species, which were categorized into two groups (refractory and non-refractory compounds). The model was able to satisfactorily describe the profile of the residual fractions of these two classes of organic compounds and allowed estimating the related kinetic constants (k) at two different temperatures, namely (a) 3.19 × 10⁻¹ and 2.82 × 10⁻³ min⁻¹ for non-refractory and refractory compounds at 80 °C and (b) 4.73 × 10⁻¹ and 5.09 × 10⁻³ min⁻¹ for the same compound classes at 90 °C, while the activation energy (E_a) of the process was 42.02 and 62.09 kJ mol⁻¹, respectively. The kinetic modeling of organic pollutants oxidation in liquid effluents would allow to perform in situ seawater treatment on vertical reactors installed in offshore platforms and to properly release treated water into the oceans. In this way, ocean contamination caused by the exploration on offshore platforms of oil and natural gas, the main energy sources and vectors in the current world, may be remarkably reduced, thus favoring a more eco-friendly energy production. Full article

Progressive climate changes and the increase in the occurrence of extreme weather phenomena indicate the need to take action to mitigate the negative effects of climate change. One of the main factors affecting climate change is the state of waters that transport heat. Oil pollution present in the water contributes to the absorption of radiation and physico-chemical changes in the sea, which has an impact on the marine ecosystem. This indicates the need to develop methods for effective oil spill detection. This study aimed to improve the methods of early detection of threats related to oil spills in the marine environment, especially when the source of oil may be invisible in the depths of the sea. Therefore, the method based on the fluorometric index is proposed, and its effectiveness for oil detection in seawater is studied. The study has answered the question of how biological activity during a whole year influences the effectiveness of oil detection by the proposed fluorometric index method. Therefore, for the calculation of the fluorometric index, the changes in the seawater fluorescence spectrum in the ultraviolet range were determined, which occurred under the influence of diffusion of some oil components in the sea. The principle of detection of oil contaminants based on the excitation-emission fluorescence spectrum is described. For the measurements, natural seawater samples used in the laboratory were exposed to a mixture of crude oil and oils commonly found in navigation. The effectiveness of oil substance detection using the fluorometric index in the biologically productive and unproductive seasons was analyzed for seawater in the vicinity of Gdynia and Gdansk ports in Poland in northern Europe. The results of excitation-emission spectra and fluorometric index indicate that the changes in the biological activity during the year do not affect the detectability of oil present in seawater for the considered oil-to-water ratio. Summarize the sensitivity analysis of the method indicates the possibility of detection of oil contamination regardless of the season. The obtained results pave the way for the construction of an underwater device to detect oil in the vicinity of such a detector. Full article