Sign in to use this feature.

Years

Between: -

Subjects

remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline

Journals

Article Types

Countries / Regions

Search Results (60)

Search Parameters:
Keywords = nuclear fuel damage

Order results
Result details
Results per page
Select all
Export citation of selected articles as:
14 pages, 1262 KiB  
Article
Method of Quality Control of Nuclear Reactor Element Tightness to Improve Environmental Safety
by Eduard Khomiak, Roman Trishch, Joanicjusz Nazarko, Miloslav Novotný and Vladislavas Petraškevičius
Energies 2025, 18(9), 2172; https://doi.org/10.3390/en18092172 - 24 Apr 2025
Viewed by 443
Abstract
Low carbon dioxide (CO2) emissions make nuclear energy crucial in decarbonizing the economy. In this context, nuclear safety, and especially the operation of nuclear power plants, remains a critical issue. This article presents a new fractal cluster method of control that [...] Read more.
Low carbon dioxide (CO2) emissions make nuclear energy crucial in decarbonizing the economy. In this context, nuclear safety, and especially the operation of nuclear power plants, remains a critical issue. This article presents a new fractal cluster method of control that improves the quality of assessing fuel element cladding integrity, which is critical for nuclear and environmental safety. The proposed non-destructive testing method allows for detecting defects on the inner and outer cladding surfaces without removing the elements from the nuclear reactor, which ensures prompt response and prevention of radiation leakage. Studies have shown that the fractal dimension of the cladding surface, which varies from 2.1 to 2.5, indicates significant heterogeneity caused by mechanical damage or corrosion, which can affect its integrity. The density analysis of defect clusters allows quantifying their concentration per unit area, which is an important indicator for assessing the risks associated with the operation of nuclear facilities. The data obtained are used to assess the impact of defects on the vessel’s integrity and, in turn, on nuclear safety. The monitoring results are transmitted in real time to the operator’s automated workstation, allowing for timely decision making to prevent radioactive releases and improve environmental safety. The proposed method is a promising tool for ensuring reliable quality control of the fuel element cladding condition and improving nuclear and environmental safety. While the study is based on VVER-1000 reactor data, the flexibility of the proposed methodology suggests its potential applicability to other reactor types, opening avenues for broader implementation in diverse nuclear systems. Full article
(This article belongs to the Section B4: Nuclear Energy)
Show Figures

Figure 1

29 pages, 17900 KiB  
Article
Multi-Criteria Analysis of Steel–Concrete–Steel Slab Performance: Dynamic Response Assessment Under Post-Fire Explosion
by Shijie Zhang, Zhenfu Chen, Yizhi Liu, Qiuwang Tao, Dan Wu and Pinyu Zou
Buildings 2025, 15(8), 1340; https://doi.org/10.3390/buildings15081340 - 17 Apr 2025
Viewed by 466
Abstract
Steel–concrete–steel (SCS) composite slabs are widely used in critical infrastructures such as nuclear power plants, where systematic performance evaluation through multiple criteria is crucial due to their safety functions. During their use, fires may occur due to fuel or gas leaks, leading to [...] Read more.
Steel–concrete–steel (SCS) composite slabs are widely used in critical infrastructures such as nuclear power plants, where systematic performance evaluation through multiple criteria is crucial due to their safety functions. During their use, fires may occur due to fuel or gas leaks, leading to explosions. This article uses ABAQUS 2020 finite element software and combines the different advantages of the implicit heat transfer algorithm and explosion display algorithm to establish a numerical simulation method for dynamic analysis of SCS slab under explosion after fire. Based on different fire conditions and the propagation laws of explosion shock waves, some key dynamic indicators and failure modes of the slab were studied. The results reveal progressive damage mechanisms with increasing fire duration, characterized by expanding damage areas, significant stress fluctuations, and increasing displacement rates. Additionally, the fire surface shows greater vulnerability than the back fire surface. The results provide multiple evaluation criteria for assessing structural performance, including temperature distribution, stress evolution, and damage patterns, which can support engineering decision-making in structural safety management. Full article
Show Figures

Figure 1

18 pages, 8602 KiB  
Article
A Preliminary Exploratory Study of the Flow and Heat Transfer Characteristics of Fuel Elements in Low-Enriched Uranium Cores
by Mingxue Shao, Songjiang Feng, Kangkang Guo, Yiheng Tong and Wei Lin
Aerospace 2025, 12(4), 290; https://doi.org/10.3390/aerospace12040290 - 30 Mar 2025
Viewed by 338
Abstract
Nuclear thermal propulsion, which uses a reactor core as the energy source of a nuclear thermal rocket, is expected to become an effective means of deep space exploration in the future. The reactor core can be damaged by a large temperature gradient. Thus, [...] Read more.
Nuclear thermal propulsion, which uses a reactor core as the energy source of a nuclear thermal rocket, is expected to become an effective means of deep space exploration in the future. The reactor core can be damaged by a large temperature gradient. Thus, investigating the structural distribution of its internal components and understanding its flow and heat transfer characteristics is highly important. In this study, a 19-hole hollow hexagonal prism fuel element is selected for simulation. A new type of fuel element is proposed by changing the diameter of the channels in the work material, and the heat transfer characteristics are compared and analyzed. Compared with a conventional fuel element under uniform inlet conditions, when the inlet conditions and the diameter of the channel in the work material are changed, the peak temperature inside the fuel element decreases, but the overall temperature distribution is more uniform. Along the flow direction, the temperature distribution boundary is located at y = 300–500 mm. From the inlet to this position, the temperature distribution on the axial cross-section is uniform. From this position to the outlet, the temperature difference along the radial cross-section is significantly reduced, and the temperature fluctuation at the periphery of the fuel element is significantly improved. The research results can provide a reference for the design of fuel elements. Full article
(This article belongs to the Section Astronautics & Space Science)
Show Figures

Figure 1

12 pages, 1640 KiB  
Article
Probabilistic Approach for Best Estimate of Fuel Rod Fracture During Loss-of-Coolant Accident
by Hiroki Tanaka, Takafumi Narukawa and Takashi Takata
J. Nucl. Eng. 2025, 6(1), 6; https://doi.org/10.3390/jne6010006 - 28 Feb 2025
Viewed by 684
Abstract
Nuclear power plant risk assessments rely on conservative deterministic criteria for core-damage determination despite significant advancements in plant response and system analyses. This study proposes a probabilistic approach to determine fuel rod fracture during loss-of-coolant accidents (LOCAs) in light-water reactors, addressing the need [...] Read more.
Nuclear power plant risk assessments rely on conservative deterministic criteria for core-damage determination despite significant advancements in plant response and system analyses. This study proposes a probabilistic approach to determine fuel rod fracture during loss-of-coolant accidents (LOCAs) in light-water reactors, addressing the need for more rational and realistic assessments. The methodology integrates a fuel rod fracture probability estimation model with best-estimate-plus-uncertainty analysis of plant response, utilizing the stress–strength model and Monte Carlo simulations. Both stress and strength distributions are estimated through Bayesian statistical modeling, with numerical integration techniques implemented to enhance accuracy for low-frequency events. The application of this approach to a virtual dataset demonstrated that while conventional deterministic methods indicated definitive rod fracture, our probabilistic analysis revealed a more realistic fracture probability of 15.1%. This significant finding highlights the potential reduction in assessment conservatism. The proposed methodology enables a transition from conservative binary evaluations to more realistic probabilistic assessments of core damage, providing more accurate risk insights for decision-making. Full article
(This article belongs to the Special Issue Probabilistic Safety Assessment and Management of Nuclear Facilities)
Show Figures

Figure 1

13 pages, 3103 KiB  
Article
The Effect of Activated Carbon Support on Ru/AC Catalysts Used for the Catalytic Decomposition of Hydroxylamine Nitrate and Hydrazine Nitrate
by Zhi Cao, Deyan Yu, Tiansheng He, Tianchi Li, Chen Zuo, Baole Li, Hongbin Lv, Taihong Yan and Weifang Zheng
Processes 2025, 13(3), 641; https://doi.org/10.3390/pr13030641 - 24 Feb 2025
Viewed by 829
Abstract
Hydroxylamine nitrate (HAN) and hydrazine nitrate (HN) are commonly found in radioactive waste solutions in nuclear fuel reprocessing, and their efficient removal is essential for waste treatment processes. In this study, six activated carbon carriers were selected to prepare Ru/AC catalysts for the [...] Read more.
Hydroxylamine nitrate (HAN) and hydrazine nitrate (HN) are commonly found in radioactive waste solutions in nuclear fuel reprocessing, and their efficient removal is essential for waste treatment processes. In this study, six activated carbon carriers were selected to prepare Ru/AC catalysts for the simultaneous catalytic decomposition of HAN and HN, with the aim of exploring the effect of carrier properties on catalytic performance. The catalyst’s activity was evaluated in a batch reaction unit, and its structural properties were characterized using N2 physical adsorption, XRD, SEM, and TEM techniques. The results revealed that the catalyst’s activity was primarily determined by the carrier’s particle size and specific surface area. Additionally, corrosion-induced damage to the pore structure and Ru loss were identified as the main factors responsible for catalyst deactivation. This study highlights the importance of optimizing carrier structure to enhance the activity and stability of Ru/AC catalysts. Full article
(This article belongs to the Section Catalysis Enhanced Processes)
Show Figures

Figure 1

36 pages, 12554 KiB  
Review
A Review of Maritime Nuclear Reactor Systems
by Keith E. Holbert
J. Nucl. Eng. 2025, 6(1), 5; https://doi.org/10.3390/jne6010005 - 5 Feb 2025
Cited by 2 | Viewed by 5118
Abstract
Marine reactors have been applied to floating nuclear power plants, naval vessels such as submarines, and civilian ships such as icebreakers. Nuclear-powered shipping is gaining increased interest because of decarbonization goals motivated by climate change. Enhanced reactor safety can potentially reduce regulatory and [...] Read more.
Marine reactors have been applied to floating nuclear power plants, naval vessels such as submarines, and civilian ships such as icebreakers. Nuclear-powered shipping is gaining increased interest because of decarbonization goals motivated by climate change. Enhanced reactor safety can potentially reduce regulatory and liability challenges to the adoption of nuclear propulsion systems for merchant ships. This gives strong impetus for reviewing past use of nuclear reactor systems in marine environments, especially from the perspective of any accident scenarios, lest planners be caught unaware of historical incidents. To that end, a loss of coolant accident (LOCA) in a Lenin icebreaker reactor in 1965 and disposal at sea of some of its damaged fuel and reactor vessel as well as the entire tri-reactor compartment is recounted. Full article
Show Figures

Figure 1

13 pages, 6245 KiB  
Article
A Study of the Creep-Fatigue Damage Mechanism of a P92 Welded Joint Using Nanoindentation Characterization
by Zhangmin Jin, Zhihui Cai, Xuecheng Gu, Zhiqiang Wang, Yiwen Han, Ting Yu, Yuxuan Song, Zengliang Gao and Zhongrui Zheng
Metals 2025, 15(1), 53; https://doi.org/10.3390/met15010053 - 9 Jan 2025
Cited by 1 | Viewed by 1042
Abstract
In fossil fuel and nuclear power plants, welded joints continuously experience creep-fatigue loading, which can result in premature cracking during the in-service term. To study the creep-fatigue interactive (CFI) behavior, the CFI test of P92 steel was performed with different strain rates at [...] Read more.
In fossil fuel and nuclear power plants, welded joints continuously experience creep-fatigue loading, which can result in premature cracking during the in-service term. To study the creep-fatigue interactive (CFI) behavior, the CFI test of P92 steel was performed with different strain rates at 823 K. Results indicate that the short cycle life is measured with the increasing strain rate. Relying on the scanning electron microscope, the fracture mechanism of P92 steel gradually changes from fatigue-dominating to creep-fatigue interactive damage with the increasing strain rate. The hardness (H), elastic modulus (E) and creep deformation were then measured by nanoindentation, and the strain rate sensitivity (m) was estimated. The relation between the degenerated mechanical properties and microstructural evaluations, i.e., enhanced grain size and nucleation of creep voids, was established, and the damage mechanism was discussed. Full article
Show Figures

Figure 1

14 pages, 21527 KiB  
Article
Detailed Analysis of the Debris-Fretting Damage Areas on Coated Fuel Cladding
by Ondřej Pašta, Marcin Kopeć, Ladislav Cvrček, Jakub Krejčí, Patricie Halodová and Kristína Sihelská
Materials 2025, 18(1), 143; https://doi.org/10.3390/ma18010143 - 2 Jan 2025
Viewed by 877
Abstract
Fuel failure caused by fretting damage to cladding remains a relevant issue despite decades of research and development aimed at enhancing the physical parameters of fuel. This paper presents the results of experiments conducted at the Research Centre Řež on Zr-1%Nb alloy tube [...] Read more.
Fuel failure caused by fretting damage to cladding remains a relevant issue despite decades of research and development aimed at enhancing the physical parameters of fuel. This paper presents the results of experiments conducted at the Research Centre Řež on Zr-1%Nb alloy tube specimens covered with protective coatings made of chromium (Cr) and nitrogen (N) compounds. The experiments involved debris-fretting tests under dry conditions at room temperature as well as microscopic measurements of groove depths. A detailed analysis was performed using the Scanning Electron Microscopy, Energy-Dispersive X-Ray Spectroscopy, Electron Backscatter Diffraction, and Focused Ion Beam techniques. The objectives of the tests were (1) to compare the debris-fretting resistance between the reference Zr-1%Nb specimens and those of the same alloy coated with various compositions, and (2) to demonstrate the positive effects of coating applications on the endurance of fuel cladding. The conducted analysis revealed a significant advantage in using cladding with a thin, wear-resistant layer compared to standard cladding material, with the CrN-coated specimens exhibiting 36 times better fretting resistance. Full article
(This article belongs to the Special Issue Key Materials in Nuclear Reactors)
Show Figures

Graphical abstract

19 pages, 4719 KiB  
Article
Anomaly Detection and Analysis in Nuclear Power Plants
by Abhishek Chaudhary, Junseo Han, Seongah Kim, Aram Kim and Sunoh Choi
Electronics 2024, 13(22), 4428; https://doi.org/10.3390/electronics13224428 - 12 Nov 2024
Cited by 4 | Viewed by 2753
Abstract
Industries are increasingly adopting digital systems to improve control and accessibility by providing real-time monitoring and early alerts for potential issues. While digital transformation fuels exponential growth, it exposes these industries to cyberattacks. For critical sectors such as nuclear power plants, a cyberattack [...] Read more.
Industries are increasingly adopting digital systems to improve control and accessibility by providing real-time monitoring and early alerts for potential issues. While digital transformation fuels exponential growth, it exposes these industries to cyberattacks. For critical sectors such as nuclear power plants, a cyberattack not only risks damaging the facility but also endangers human lives. In today’s digital world, enormous amounts of data are generated, and the analysis of these data can help ensure effectiveness, including security. In this study, we analyzed the data using a deep learning model for early detection of abnormal behavior. We first examined the Asherah Nuclear Power Plant simulator by initiating three different cyberattacks, each targeting a different system, thereby collecting and analyzing data from the simulator. Second, a Bi-LSTM model was used to detect anomalies in the simulator, which detected it before the plant’s protection system was activated in response to a threat. Finally, we applied explainable AI (XAI) to acquire insight into how distinctive features contribute to the detection of anomalies. XAI provides valuable explanations of model behavior by revealing how specific features influence anomaly detection during attacks. This research proposes an effective anomaly detection technique and interpretability to better understand counter-cyber threats in critical industries, such as nuclear plants. Full article
Show Figures

Figure 1

15 pages, 3327 KiB  
Article
A High–Throughput Molecular Dynamics Study for the Modeling of Cryogenic Solid Formation
by Simone Giusepponi, Francesco Buonocore, Massimo Celino, Andrea Iaboni, Antonio Frattolillo and Silvio Migliori
Crystals 2024, 14(8), 741; https://doi.org/10.3390/cryst14080741 - 20 Aug 2024
Viewed by 1107
Abstract
To predict the favorable thermodynamical conditions and characterize cryogenic pellet formations for applications in nuclear fusion reactors, a high–throughput molecular dynamics study based on a unified framework to simulate the growth process of cryogenic solids (molecular deuterium, neon, argon) under gas pressure have [...] Read more.
To predict the favorable thermodynamical conditions and characterize cryogenic pellet formations for applications in nuclear fusion reactors, a high–throughput molecular dynamics study based on a unified framework to simulate the growth process of cryogenic solids (molecular deuterium, neon, argon) under gas pressure have been designed. These elements are used in fusion nuclear plants as fuel materials and to reduce the damage risks for the plasma-facing components in case of a plasma disruption. The unified framework is based on the use of workflows that permit management in HPC facilities, the submission of a massive number of molecular dynamics simulations, and handle huge amounts of data. This simplifies a variety of operations for the user, allowing for significant time savings and efficient organization of the generated data. This approach permits the use of large-scale parallel simulations on supercomputers to reproduce the solid–gas equilibrium curves of cryogenic solids like molecular deuterium, neon, and argon, and to analyze and characterize the reconstructed solid phase in terms of the separation between initial and reconstructed solid slabs, the smoothness of the free surfaces and type of the crystal structure. These properties represent good indicators for the quality of the final materials and provide effective indications regarding the optimal thermodynamical conditions of the growing process. Full article
(This article belongs to the Section Materials for Energy Applications)
Show Figures

Figure 1

12 pages, 7566 KiB  
Article
An Integrated Solution to FIB-Induced Hydride Artifacts in Pure Zirconium
by Yi Qiao, Zongwei Xu, Shilei Li, Fu Wang and Yubo Huang
Micromachines 2024, 15(8), 999; https://doi.org/10.3390/mi15080999 - 1 Aug 2024
Viewed by 1567
Abstract
The preparation method of transmission electron microscopy (TEM) samples for pure zirconium was successfully executed using a focused ion beam (FIB) system. These samples unveiled artifact hydrides induced during the FIB sample preparation process, which resulted from stress damage, ion implantation, and ion [...] Read more.
The preparation method of transmission electron microscopy (TEM) samples for pure zirconium was successfully executed using a focused ion beam (FIB) system. These samples unveiled artifact hydrides induced during the FIB sample preparation process, which resulted from stress damage, ion implantation, and ion irradiation. An innovative solution was proposed to effectively reduce the effect of artifact hydrides for FIB-prepared samples of hydrogen-sensitive materials, such as zirconium alloys. This development lays the groundwork for further research on the micro/nanostructures of zirconium alloys after ion irradiation, thereby facilitating the study of corrosion mechanisms and the prediction of service life for nuclear fuel cladding materials. Furthermore, the solution proposed in this study is also applicable to TEM sample preparation using FIB for other hydrogen-sensitive materials such as titanium, magnesium, and palladium. Full article
Show Figures

Figure 1

20 pages, 3956 KiB  
Article
A Crystal Plasticity-Based Simulation to Predict Fracture Initiation Toughness of Reactor-Grade Aluminium: Experimental Verification and Study of Effect of Crystal Orientation
by Mahendra Kumar Samal, Trishant Sahu and Ather Syed
Appl. Mech. 2024, 5(3), 513-532; https://doi.org/10.3390/applmech5030029 - 17 Jul 2024
Viewed by 1862
Abstract
Aluminium alloys are used for the fabrication of the fuel clad of research-grade nuclear reactors as well as for several types of core components of high-flux research reactors. In order to carry out design and safety analysis of these components, their mechanical and [...] Read more.
Aluminium alloys are used for the fabrication of the fuel clad of research-grade nuclear reactors as well as for several types of core components of high-flux research reactors. In order to carry out design and safety analysis of these components, their mechanical and fracture properties are required by the designer. In this work, experiments have been conducted on tensile specimens machined from an aluminium alloy block to evaluate the material stress-strain curve. Experiments have also been conducted on disc-shaped compact tension specimens in order to determine the fracture toughness of aluminium alloy. Numerical simulations of both tensile and fracture specimens have been carried out using the crystal plasticity model. Initially, the slip system level parameters of the crystal plasticity material model have been calibrated using experimental stress-strain data for single as well as polycrystalline aluminium. For the prediction of crack initiation toughness, Rice and Tracey’s damage model has been used. The critical damage parameter has been evaluated for a fractured specimen with a crack length-to-width (a/W) ratio of 0.6. The attainment of the critical damage parameter in the analysis corresponds to the instance of experimentally observed ductile crack initiation in the specimen. Later, this model was applied to other fracture specimens with different a/W ratios with values ranging from 0.39 to 0.59. It was observed that the critical damage parameter corresponding to crack initiation in the material has a very small variation, even if the specimens have different crack lengths. It is well-known in the literature that Rice and Tracey’s critical damage parameter is a material constant. Hence, we have applied the same model to predict crack initiation for single crystal fracture specimens with two different orientations of the crack plane. It was observed that the <111> orientation is more susceptible to crack initiation and propagation compared with the <100> orientation, as the damage parameter is high in the ligament of the specimen ahead of the crack tip for the same level of applied loading. As the [111] crack plane is more closely packed compared with the [100] plane, the distance between atomic planes is greater for the former, and hence, it is more susceptible to ductile damage. The results of the experiments and the material damage parameter are helpful for the integrity analysis of the fuel clad of research reactors as well as components of high-flux research reactors. Full article
(This article belongs to the Collection Fracture, Fatigue, and Wear)
Show Figures

Figure 1

28 pages, 11309 KiB  
Review
Preparation, Deformation Behavior and Irradiation Damage of Refractory Metal Single Crystals for Nuclear Applications: A Review
by Benqi Jiao, Weizhong Han, Wen Zhang, Zhongwu Hu and Jianfeng Li
Materials 2024, 17(14), 3417; https://doi.org/10.3390/ma17143417 - 10 Jul 2024
Cited by 3 | Viewed by 1474
Abstract
Refractory metal single crystals have been applied in key high-temperature structural components of advanced nuclear reactor power systems, due to their excellent high-temperature properties and outstanding compatibility with nuclear fuels. Although electron beam floating zone melting and plasma arc melting techniques can prepare [...] Read more.
Refractory metal single crystals have been applied in key high-temperature structural components of advanced nuclear reactor power systems, due to their excellent high-temperature properties and outstanding compatibility with nuclear fuels. Although electron beam floating zone melting and plasma arc melting techniques can prepare large-size oriented refractory metals and their alloy single crystals, both have difficulty producing perfect defect-free single crystals because of the high-temperature gradient. The mechanical properties of refractory metal single crystals under different loads all exhibit strong temperature and crystal orientation dependence. Slip and twinning are the two basic deformation mechanisms of refractory metal single crystals, in which low temperatures or high strain rates are more likely to induce twinning. Recrystallization is always induced by the combined action of deformation and annealing, exhibiting a strong crystal orientation dependence. The irradiation hardening and neutron embrittlement appear after exposure to irradiation damage and degrade the material properties, attributed to vacancies, dislocation loops, precipitates, and other irradiation defects, hindering dislocation motion. This paper reviews the research progress of refractory metal single crystals from three aspects, preparation technology, deformation behavior, and irradiation damage, and highlights key directions for future research. Finally, future research directions are prospected to provide a reference for the design and development of refractory metal single crystals for nuclear applications. Full article
(This article belongs to the Special Issue Key Materials in Nuclear Reactors)
Show Figures

Figure 1

12 pages, 5316 KiB  
Article
Study on the Deactivation Mechanism of Ru/C Catalysts
by Zhi Cao, Tianchi Li, Baole Li, Xiwen Chen, Chen Zuo and Weifang Zheng
Processes 2024, 12(6), 1138; https://doi.org/10.3390/pr12061138 - 31 May 2024
Cited by 2 | Viewed by 1078
Abstract
Employing catalytic decomposition to break down reducing agents in intermediate-level radioactive waste during nuclear fuel reprocessing offers significant advantages. This study focuses on investigating the deactivation behavior of 5% Ru/C catalysts by two different synthesis processes used for reducing agent destruction. Deactivation experiments [...] Read more.
Employing catalytic decomposition to break down reducing agents in intermediate-level radioactive waste during nuclear fuel reprocessing offers significant advantages. This study focuses on investigating the deactivation behavior of 5% Ru/C catalysts by two different synthesis processes used for reducing agent destruction. Deactivation experiments were conducted by subjecting the 5% Ru/C catalysts to 100 and 150 reaction cycles. Changes in the concentration of free radicals on the carbon-based carrier were measured to analyze the loading position and loss of Ru ions. Additionally, sorption–desorption curves and pore size distributions of the four catalysts were obtained. Analysis results reveal that Ru ions on the catalyst adsorb onto active free radical sites on the carbon-based carrier. Under ultrasonic conditions, some Ru ions partially desorb from the free radical sites on the carbon-based carrier, and desorbed Ru ions may adsorb onto weak free radical sites, while undesorbed Ru ions may adsorb onto strong free radical sites. After hundreds of hours of reaction, SM1 and SM2 exhibited approximately a 30% decrease in specific surface area and pore volume compared to SM0. However, the catalyst activity remained unchanged, and the catalyst pore size remained essentially unchanged, which primarily means that the micropores on the catalyst’s surface have undergone corrosion and damage. Full article
(This article belongs to the Section Catalysis Enhanced Processes)
Show Figures

Figure 1

17 pages, 2122 KiB  
Article
Study of the Influence of Doping Efficiency of CeO2 Ceramics with a Stabilizing Additive Y2O3 on Changes in the Strength and Thermophysical Parameters of Ceramics under High-Temperature Irradiation with Heavy Ions
by Artem L. Kozlovskiy, Sholpan G. Giniyatova, Dmitriy I. Shlimas, Daryn B. Borgekov, Ruslan M. Rspayev and Maxim V. Zdorovets
Crystals 2024, 14(4), 320; https://doi.org/10.3390/cryst14040320 - 29 Mar 2024
Cited by 2 | Viewed by 1185
Abstract
The article outlines findings from a comparative analysis of the effectiveness of doping CeO2 ceramics with a stabilizing additive Y2O3 on alterations in the strength and thermophysical parameters of ceramics under high-temperature irradiation with heavy ions comparable in energy [...] Read more.
The article outlines findings from a comparative analysis of the effectiveness of doping CeO2 ceramics with a stabilizing additive Y2O3 on alterations in the strength and thermophysical parameters of ceramics under high-temperature irradiation with heavy ions comparable in energy to fission fragments of nuclear fuel, which allows, during high-temperature irradiation, to simulate radiation damage that is as similar as possible to the fission processes of nuclear fuel. During the studies, it was found that the addition of a stabilizing additive Y2O3 to the composition of CeO2 ceramics in the case of high-temperature irradiation causes an increase in stability to swelling and softening because of a decrease in the thermal expansion of the crystal lattice by 3–8 times in comparison with unstabilized CeO2 ceramics. It has been determined that the addition of a stabilizing additive Y2O3 leads not only to a rise in the resistance of the crystal structure to deformation distortions and swelling, but also to a decrease in the effect of thermal expansion of the crystal structure, which has an adverse effect on the structural ordering of CeO2 ceramics exposed to irradiation at high temperatures. Full article
(This article belongs to the Section Polycrystalline Ceramics)
Show Figures

Figure 1

Back to TopTop