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Keywords = northern margin of North China Craton

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26 pages, 30392 KB  
Article
Multisystem (S–Pb–He–Ar–H–O) Isotopic and Fluid Inclusion Constraints on the Genesis of the Chaijiagou Porphyry Mo Deposit, North China Craton
by Wei Xie, Chao Jin, Qingdong Zeng, Lingli Zhou, Rui Dong, Zhao Wang and Kaiyuan Wang
Minerals 2026, 16(1), 71; https://doi.org/10.3390/min16010071 - 12 Jan 2026
Viewed by 237
Abstract
The Chaijiagou Mo deposit (0.11 Mt Mo @ 0.07%) is located along the northern margin of the North China Craton. This study integrates ore geology, S–Pb–He–Ar–H–O isotopes, and fluid inclusion (FI) analyses to constrain the sources of ore-forming fluids and metals, as well [...] Read more.
The Chaijiagou Mo deposit (0.11 Mt Mo @ 0.07%) is located along the northern margin of the North China Craton. This study integrates ore geology, S–Pb–He–Ar–H–O isotopes, and fluid inclusion (FI) analyses to constrain the sources of ore-forming fluids and metals, as well as mineralization mechanisms. Three principal inclusion types were identified: liquid-rich, vapor-rich, and saline FIs. Microthermometry documents a progressive decline in homogenization temperatures and salinities from early to late mineralization stages: Stage 1 (360–450 °C; 5.3–11.3 and 35.4–51.5 wt.% NaCl equation), Stages 2.1–2.2 (320–380 °C and 260–340 °C; 5.4–11.8 and 33.8–44.5 wt.% NaCl equation), and Stage 4 (140–200 °C; 0.4–3.9 wt.% NaCl equation). Noble gas and stable isotope data reveal that the ore-forming fluids were initially dominated by crustally derived magmatic–hydrothermal components with a minor mantle contribution, subsequently experiencing significant meteoric water input. S–Pb isotopic compositions demonstrate a genetic relationship between mineralization and the ore-bearing granite porphyry, indicating a magmatic origin for both sulfur and lead. Fluid–rock interactions and fluid boiling were the dominant controls on molybdenite and chalcopyrite deposition during Stage 2, whereas mixing with meteoric waters triggered galena and sphalerite precipitation in Stage 3. Full article
(This article belongs to the Special Issue Selected Papers from the 7th National Youth Geological Congress)
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35 pages, 14689 KB  
Article
Multivariate Statistical Analysis and S-A Multifractal Modeling of Lithogeochemical Data for Mineral Exploration: A Case Study from the Buerhantu Area, Hadamengou Gold Orefield, Inner Mongolia, China
by Songhao Fan, Da Wang, Biao Yang, Huchao Ma, Rilige Su, Lei Chen, Panyun Su, Xiuhong Hou, Hanqin Lv and Zhiwei Xia
Geosciences 2025, 15(12), 473; https://doi.org/10.3390/geosciences15120473 - 15 Dec 2025
Viewed by 311
Abstract
The Hadamengou gold deposit, located on the northern margin of the North China Craton, represents one of the region‘s most significant gold mineralization clusters. However, exploration in its deeper and peripheral sectors is constrained by ecological protection policies and the structural complexity of [...] Read more.
The Hadamengou gold deposit, located on the northern margin of the North China Craton, represents one of the region‘s most significant gold mineralization clusters. However, exploration in its deeper and peripheral sectors is constrained by ecological protection policies and the structural complexity of the ore-forming systems. Multivariate analysis combined with multi-model integration provides an effective mathematical approach for interpretating geochemical datasets and guiding mineral exploration, yet, its application in the Hadamengou region has not been systematically investigated. To address this research gap, this study developed a pilot framework in the key Buerhantu area, on the periphery of the Hadamengou metallogenic cluster, applying and adapting a multivariate-multimodel methodology for mineral prediction. The goal is to improve exploration targeting, particularly for concealed and deep-seated mineralization, while addressing the methodological challenges of mathematical modeling in complex geological conditions. Using 1:10,000-scale lithogeochemical data, we implemented a three-step workflow. First, isometric log-ratio (ILR) and centered log-ratio (CLR) transformations were compared to optimize data preprocessing, with a reference column (YD) added to overcome ILR constraints. Second, principal component analysis (PCA) identified a metallogenic element association (Sb-As-Sn-Au-Ag-Cu-Pb-Mo-W-Bi) consistent with district-scale mineralization patterns. Third, S-A multifractal modeling of factor scores (F1–F4) effectively separated noise, background, and anomalies, producing refined geochemical maps. Compared with conventional inverse distance weighting (IDW), the S-A model enhanced anomaly delineation and exploration targeting. Five anomalous zones (AP01–AP05) were identified. Drilling at AP01 confirmed the presence of deep gold mineralization, and the remaining anomalies are recommended for surface verification. This study demonstrates the utility of S-A multifractal modeling for geochemical anomaly detection and its effectiveness in defining exploration targets and improving exploration efficiency in underexplored areas of the Hadamengou district. Full article
(This article belongs to the Section Geochemistry)
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29 pages, 14630 KB  
Article
Tectonic Evolution of the Eastern Central Asian Orogenic Belt: Evidence from Magmatic Activity in the Faku Area, Northern Liaoning, China
by Shaoshan Shi, Yi Shi, Xiaofan Zhou, Nan Ju, Yanfei Zhang and Shan Jiang
Minerals 2025, 15(7), 736; https://doi.org/10.3390/min15070736 - 15 Jul 2025
Viewed by 1193
Abstract
The Permian–Triassic magmatic record in the eastern Central Asian Orogenic Belt (CAOB) provides critical insights into the terminal stages of the Paleo-Asian Ocean (PAO) evolution, including collisional and post-collisional processes following its Late Permian closure. The northeastern China region, tectonically situated within the [...] Read more.
The Permian–Triassic magmatic record in the eastern Central Asian Orogenic Belt (CAOB) provides critical insights into the terminal stages of the Paleo-Asian Ocean (PAO) evolution, including collisional and post-collisional processes following its Late Permian closure. The northeastern China region, tectonically situated within the eastern segment of the CAOB, is traditionally known as the Xingmeng Orogenic Belt (XOR). This study integrates zircon U-Pb geochronology, whole-rock geochemistry, and zircon Hf isotopic analyses of intermediate-acid volcanic rocks and intrusive rocks from the former “Tongjiatun Formation” in the Faku area of northern Liaoning. The main objective is to explore the petrogenesis of these igneous rocks and their implications for the regional tectonic setting. Zircon U-Pb ages of these rocks range from 260.5 to 230.1 Ma, indicating Permian–Triassic magmatism. Specifically, the Gongzhuling rhyolite (260.5 ± 2.2 Ma) and Gongzhuling dacite (260.3 ± 2.4 Ma) formed during the Middle-Late Permian (270–256 Ma); the Wangjiadian dacite (243 ± 3.0 Ma) and Wafangxi rhyolite (243.9 ± 3.0 Ma) were formed in the late Permian-early Middle Triassic (256–242 Ma); the Haoguantun rhyolite (240.9 ± 2.2 Ma) and Sheshangou pluton (230.1 ± 1.7 Ma) were formed during the Late Middle-Late Triassic (241–215 Ma). Geochemical studies, integrated with the geochronological results, reveal distinct tectonic settings during successive stages: (1) Middle-Late Permian (270–256 Ma): Magmatism included peraluminous A-type rhyolite with in calc-alkaline series (e.g., Gongzhuling) formed in an extensional environment linked to a mantle plume, alongside metaluminous, calc-alkaline I-type dacite (e.g., Gongzhuling) associated with the subduction of the PAO plate. (2) Late Permian-Early Middle Triassic (256–242 Ma): Calc-alkaline I-type magmatism dominated, represented by dacite (e.g., Wangjiadian) and rhyolite (e.g., Wafangxi), indicative of a collisional uplift environment. (3) Late Middle-Late Triassic (241–215 Ma): Magmatism transitioned to high-K calc-alkaline with A-type rocks affinities, including rhyolite (e.g., Haoguantun) and plutons (e.g., Sheshangou), formed in a post-collisional extensional environment. This study suggests that the closure of the PAO along the northern margin of the North China Craton (NCC) occurred before the Late Triassic. Late Triassic magmatic rocks in this region record a post-orogenic extensional setting, reflecting tectonic processes following NCC-XOR collision rather than PAO subduction. Combined with previously reported age data, the tectonic evolution of the eastern segment of the CAOB during the Permian-Triassic can be divided into four stages: active continental margin (293–274 Ma), plate disintegration (270–256 Ma), final collision and closure (256–241 Ma), and post-orogenic extension (241–215 Ma). Full article
(This article belongs to the Special Issue Selected Papers from the 7th National Youth Geological Congress)
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25 pages, 9142 KB  
Article
Petrogenesis and Tectonic Significance of Middle Jurassic Mafic–Ultramafic Cumulate Rocks in Weiyuanpu, Northern Liaoning, China: Insights from Zircon Geochronology and Isotope Geochemistry
by Yifan Zhang, Xu Ma, Jiafu Chen, Yuqi Liu, Yi Zhang and Yongwei Ma
Minerals 2025, 15(6), 651; https://doi.org/10.3390/min15060651 - 17 Jun 2025
Viewed by 930
Abstract
The tectonic evolution of the Paleo-Pacific Ocean and the destruction mechanism of the North China Craton (NCC) are still controversial. In this study, we conducted zircon U-Pb dating, whole-rock geochemistry, and Sr-Nd-Hf isotope analyses on the Weiyuanpu mafic–ultramafic intrusions in the eastern segment [...] Read more.
The tectonic evolution of the Paleo-Pacific Ocean and the destruction mechanism of the North China Craton (NCC) are still controversial. In this study, we conducted zircon U-Pb dating, whole-rock geochemistry, and Sr-Nd-Hf isotope analyses on the Weiyuanpu mafic–ultramafic intrusions in the eastern segment of the northern margin of the NCC to discuss their petrogenesis and tectonic implications. The Weiyuanpu mafic–ultramafic intrusions consist of troctolite, hornblendite, hornblende gabbro, gabbro, and minor diorite, anorthosite, characterized by cumulate structure. The main crystallization sequence of minerals is olivine → pyroxene → magnetite → hornblende. The zircon U-Pb ages of hornblendite, hornblende grabbro, and diorite are ~170Ma. Geochemical characteristics exhibit low-K tholeiitic to calc-alkaline series, enriched in light rare-earth elements (LREE) and significant large-ion lithophile elements (LILE), and depleted in high-field-strength elements (HFSE). Sr-Nd isotopic compositions are ISr = 0.7043–0.7055, εNd(t) = −0.7 to +0.9, and zircon εHf (t) values range from +3.4 to +8.7. These results suggest that the source region was a phlogopite-bearing garnet lherzolite mantle metasomatized by subduction fluids. The study reveals that the northeastern margin of the NCC was in a back-arc extensional setting due to the subduction of the Paleo-Pacific Ocean during the Middle Jurassic, which caused lithosphere thinning and mantle melting in this region. Full article
(This article belongs to the Special Issue Selected Papers from the 7th National Youth Geological Congress)
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22 pages, 12129 KB  
Article
Metallogenic Age and Tectonic Setting of the Haigou Gold Deposit in Southeast Jilin Province, NE China: Constraints from Magmatic Chronology and Geochemistry
by Zhongjie Yang, Yuandong Zhao, Cangjiang Zhang, Chuantao Ren, Qun Yang and Long Zhang
Minerals 2025, 15(6), 582; https://doi.org/10.3390/min15060582 - 29 May 2025
Viewed by 920
Abstract
Haigou deposit, located in Dunhua City, southeast Jilin Province, NE China, is a large-scale gold deposit. The gold ore body is categorized into two types: quartz-vein type and altered rock type, with the quartz-vein type being predominant. The vein gold ore body primarily [...] Read more.
Haigou deposit, located in Dunhua City, southeast Jilin Province, NE China, is a large-scale gold deposit. The gold ore body is categorized into two types: quartz-vein type and altered rock type, with the quartz-vein type being predominant. The vein gold ore body primarily occurs within the monzonite granite and monzonite rock mass in the Haigou area and is controlled by fault structures trending northeast, northwest, and near north-south. In order to constrain the age and tectonic setting of quartz vein-type gold mineralization, we conducted a detailed underground investigation and collected samples of monzonite granite and pyroxene diorite porphyrite veins related to quartz-vein-type gold mineralization for LA-ICP-MS zircon U-Pb dating and whole-rock main trace element data testing to confirm that monzonite granite is closely related to gold mineralization. Pyroxene diorite porphyry and gold mineralization were found in parallel veins. The zircon U-Pb weighted mean ages of monzonite and pyroxene diorite porphyrite veins are 317.1 ± 3.5 Ma and 308.8 ± 3.0 Ma, respectively, indicating that gold mineralization in monzonite, pyroxene diorite porphyrite veins, and quartz veins occurred in the Late Carboniferous. The monzonite granite and pyroxene diorite porphyrite veins associated with quartz vein-type gold mineralization have high SiO2, high K, and high Al2O3 and are all metaluminous high-potassium calc-alkaline rock series. Both of them are relatively enriched in light rare earth elements (LREE) and macroionic lithophile elements (LILE: Rb, Ba, K, etc.), but deficient in heavy rare earth elements (HREE) and high field strength elements (HFSE: Nb, Ta, P, Ti, etc.), the monzonitic granite Eu is a weak positive anomaly (δEu = 1.15–1.46), the pyroxene diorite porphyre dyke Eu is a weak positive anomaly (δEu = 1.09–1.13), and the Nb and Ta are negative anomalies. The Th/Nb values are 0.28–0.73 and 1.48–2.05, and La/Nb are 2.61–4.74 and 4.59–5.43, respectively, suggesting that diagenetic mineralization is the product of subduction in an active continental margin environment. In recent years, scholarly research on Sr, Nd, and Pb isotopes in Haigou rock masses has indicated that the magmatic source region in the Haigou mining areas is complex. It is neither a singular crustal source nor a mantle source but rather a mixed crust-mantle source, primarily resulting from the partial melting of lower crustal materials, with additional contributions from mantle-derived materials. In summary, the metallogenic characteristics, chronology data, geochemical characteristics, and regional tectonic interpretation indicate that at least one phase of magmatic-hydrothermal gold mineralization was established in the Late Carboniferous as a result of the subduction of the Paleo-Asian ocean plate at the northern margin of the North China Craton. Full article
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31 pages, 54013 KB  
Article
Ore-Forming Fluid Evolution and Ore Genesis of the Cuyu Gold Deposit in Central Jilin Province, NE China: Constraints from Geology, Fluid Inclusions, and H–O–S–Pb Isotope Studies
by Haozhe Li, Qun Yang, Leigang Zhang, Yunsheng Ren, Mingtao Li, Chan Li, Bin Wang, Sitong Chen and Xiaolei Peng
Minerals 2025, 15(5), 535; https://doi.org/10.3390/min15050535 - 17 May 2025
Cited by 1 | Viewed by 1460
Abstract
The Cuyu gold deposit in central Jilin Province in Northeast China is located in the eastern segment of the northern margin of the North China Craton (NCC), as well as the eastern segment of the Xing’an–Mongolian Orogenic Belt (XMOB). Gold ore-bodies are controlled [...] Read more.
The Cuyu gold deposit in central Jilin Province in Northeast China is located in the eastern segment of the northern margin of the North China Craton (NCC), as well as the eastern segment of the Xing’an–Mongolian Orogenic Belt (XMOB). Gold ore-bodies are controlled by NW-trending faults and mainly occur in late Hercynian granodiorite. The mineralization process in the Cuyu deposit can be divided into three stages: quartz + coarse grained arsenopyrite + pyrite (stage I), quartz + sericite + pyrite + arsenopyrite + electrum + chalcopyrite + sphalerite (stage II), and quartz + calcite ± pyrite (stage III). Stage II is the most important for gold mineralization. We conducted analyses including petrography, microthermometry, laser Raman spectroscopy of fluid inclusions, and H–O–S–Pb isotopic analysis to elucidate the mineralization processes in the Cuyu deposit. Five types of primary fluid inclusions (FIs) are present in the hydrothermal quartz and calcite grains of the ore: liquid-rich two-phase aqueous fluid inclusions (L-type), vapor-rich two-phase aqueous fluid inclusions (V-type), CO2-bearing two- or three-phase inclusions (C1-type), CO2-rich two- or three-phase inclusions (C2-type), and pure CO2 mono-phase inclusions (C3-type). From stages I to III, the fluid inclusion assemblages changed from L-, C2-, and C3-types to L-, V-, C1-, C2-, and C3-types and, finally, to L-types only. The corresponding homogenization temperatures for stages I to III were 242–326 °C, 202–298 °C, and 106–188 °C, and the salinities were 4.69–9.73, 1.63–7.30, and 1.39–3.53 wt.% NaCl equiv., respectively. The ore-forming fluid system evolved from a NaCl-H2O-CO2 ± CH4 ± H2S fluid system in stage I and II with immiscible characteristics to a homogeneous NaC-H2O fluid system in stage III. Microthermometric data for stages I to III show a decreasing trend in homogenization temperatures and salinities. The mineral assemblages, fluid inclusions, and H–O–S–Pb isotopes indicate that the initial ore-forming fluids of stage I were exsolved from diorite porphyrite and characterized by a high temperature and low salinity. The addition of meteoric water in large quantities led to decreases in temperature and pressure, resulting in a NaCl-H2O-CO2 ± CH4 ± H2S fluid system with significant immiscibility in stage II, facilitating the deposition of gold and associated polymetallic sulfides. The Cuyu gold deposit has a similar ore genesis to those of gold deposits in the Jiapigou–Haigou gold belt (JHGB) of southeastern Jilin Province indicating potential for gold prospecting in the northwest-trending seam of the JHGB. Full article
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26 pages, 20145 KB  
Article
In Situ Compositional and Sulfur Isotopic Analysis of Sphalerite from the Erdaodianzi Gold Deposit in Southern Jilin Province, Northeast China
by Qingqing Shang, Fengdi Ren, Qun Yang and Bin Wang
Minerals 2025, 15(1), 57; https://doi.org/10.3390/min15010057 - 7 Jan 2025
Cited by 4 | Viewed by 1524
Abstract
The newly discovered Erdaodianzi gold deposit in southern Jilin Province, Northeast China, is located in the eastern segment of the northern margin of the North China Craton (NCC). It is a large-scale gold deposit with reserves of 38.4 tons of gold. Gold mineralization [...] Read more.
The newly discovered Erdaodianzi gold deposit in southern Jilin Province, Northeast China, is located in the eastern segment of the northern margin of the North China Craton (NCC). It is a large-scale gold deposit with reserves of 38.4 tons of gold. Gold mineralization in the ore district primarily occurs in gold-bearing quartz–sulfide veins. The gold ore occurs mainly as vein, veinlet, crumby, and disseminated structures. The hydrothermal process can be divided into three stages: stage I, characterized by quartz, arsenopyrite, and pyrite; stage II, featuring quartz, arsenopyrite, pyrite, pyrrhotite, chalcopyrite, sphalerite, and native gold; and stage III, consisting of quartz, pyrite, sphalerite, galena, electrum (a naturally occurring Au–Ag alloy), and calcite. Electrum and native gold primarily occur within the fissures of the polymetallic sulfides. To determine the enrichment mechanism of the Au element and the genetic types of ore deposits in the Erdaodianzi deposit, sourcing in situ trace element data, element mapping and sulfur isotope analysis were carried out on sphalerites from different stages using LA-ICP-MS. Minor invisible gold, in the form of Au–Ag alloy inclusions, is present within sphalerites, as revealed by time-resolved depth profiles. The LA-ICP-MS trace element data and mapping results indicate that trivalent or quadrivalent cations, such as Sb3+ and Te4+, exhibit a strong correlation with Au. This correlation can be explained by a coupled substitution mechanism, where these cations (Sb3+ and Te4+) replace zinc ions within the mineral structure, resulting in a strong association with Au. Similarly, the element Pb exhibits a close relationship with Au, which can be attributed to the incorporation of tetravalent cations like Te4+ into the mineral structure. The positive correlation between Hg and Au can be attributed to the formation of vacancies and defects within sphalerite, caused by the aforementioned coupled substitution mechanism. A slight positive relationship between Au and other divalent cations, including Fe2+, Mn2+, and Cd2+, may result from these cations simply replacing Zn within the sphalerite lattice. The crystallization temperatures of the sphalerite, calculated via the Fe/Zn ratio, range from 238 °C to 320 °C. The δ34S values are divided into two intervals: one ranging from −1.99 to −1.12‰ and the other varying from 10.96 to 11.48‰. The sulfur isotopic analysis revealed that the ore-forming materials originated from magmatic rock, with some incorporation of metamorphic rock. Comparative studies of the Erdaodianzi gold deposit and other gold deposits in the Jiapigou–Haigou gold belt have confirmed that they are all mesothermal magmatic–hydrothermal lode gold deposits formed at the subduction of the Paleo-Pacific Plate beneath the Eurasian Plate during the Middle Jurassic. The Jiapigou–Haigou gold belt extends northwest to the Huadian area of Jilin province. This suggests potential for research on gold mineralization in the northwest of the belt and indicates a new direction for further gold prospecting in the region. Full article
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21 pages, 6293 KB  
Article
The Formation Age and Magma Source of the Xiaonanshan–Tunaobao Cu-Ni-PGE Deposit in the Northern Margin of the North China Craton
by Guanlin Bai, Jiangang Jiao, Xiaotong Zheng, Yunfei Ma and Chao Gao
Minerals 2024, 14(7), 733; https://doi.org/10.3390/min14070733 - 22 Jul 2024
Cited by 1 | Viewed by 1551
Abstract
The Xiaonanshan–Tunaobao Cu-Ni-PGE deposit is located in the northern margin of the North China Craton (N-NCC) in central Inner Mongolia. However, the age, magma source, petrogenesis, and sulfide mineralization mechanism of the ore-related Xiaonanshan-Tunaobao pluton remain unclear. Zircon U-Pb dating indicates the Tunaobao [...] Read more.
The Xiaonanshan–Tunaobao Cu-Ni-PGE deposit is located in the northern margin of the North China Craton (N-NCC) in central Inner Mongolia. However, the age, magma source, petrogenesis, and sulfide mineralization mechanism of the ore-related Xiaonanshan-Tunaobao pluton remain unclear. Zircon U-Pb dating indicates the Tunaobao pluton formed at 275.9 ± 2.8 Ma (Early Permian), similar to the Xiaonanshan pluton (272.7 ± 2.9 Ma). The ore-related gabbro is enriched in LREE and LILE (e.g., Rb) and depleted in HREE and HFSE (e.g., Nb and Ti). It likely originated from enriched mantle metasomatized by subduction fluids, supported by enriched Hf-Nd isotopes (–34.34 to –6.16 for zircon εHf(t) and –7.24 to –5.92 for whole-rock εNd(t) values) and high Ba/La but low Rb/Y ratios. The δ34S values of the Xiaonanshan sulfides range from 4.5‰ to 11.4‰, indicating a mantle origin with contribution from surrounding rocks. Combining previous recognition with this study, we propose that the Xiaonanshan–Tunaobao pluton formed in a post-collision extensional setting. Full article
(This article belongs to the Special Issue Mineral Resources in North China Craton)
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27 pages, 12287 KB  
Article
Molybdenum Mineralization in Eastern Hebei, China: Evidence from Geochronology and Isotopic Composition
by Jinlong Sun, Yang Cheng, Xinxing Liu, Guang’an Meng and Xintong Dong
Minerals 2024, 14(7), 662; https://doi.org/10.3390/min14070662 - 27 Jun 2024
Viewed by 1833
Abstract
The northern margin of the North China Craton is one of the most important porphyry-skarn molybdenum ore belts in the world. The eastern Hebei Province, which contains a high number of molybdenum and gold (molybdenum) resources, is an important portion of the northern [...] Read more.
The northern margin of the North China Craton is one of the most important porphyry-skarn molybdenum ore belts in the world. The eastern Hebei Province, which contains a high number of molybdenum and gold (molybdenum) resources, is an important portion of the northern margin of the North China Craton. Xichanggou and Huashi, located in eastern Hebei, are quartz-molybdenum vein deposits that are intimately associated with intrusions that are deeply concealed in the mining area. This work presents two zircon U-Pb dates and ten molybdenite Re-Os ages from samples of the aforementioned two deposits in order to determine the timing of the intrusion and mineralization. The zircon U-Pb ages of the quartz monzonite porphyry from Xichanggou are determined to be 163.3 ± 0.3 Ma and 162.8 ± 0.4 Ma. The molybdenite Re-Os dating yielded ages of 160.3 ± 4.6 Ma for Xichanggou and 171.4 ± 19 Ma for Huashi, respectively. The isotopic composition of oxygen and hydrogen of the ore-forming fluid from Huashi, as indicated by the δDV-SMOW values (−80.0‰ to −67.6‰) and δ18OH2O values (−1.86‰ to 2.33‰), suggests that the fluid is primarily composed of water derived from magma, with some contribution from atmospheric precipitation. The sulfur isotope values (δ34S) of sulfides from Xichanggou range from 6.5‰ to 7.1‰, while the δ34S values from Huashi range from 3.3‰ to 4.9‰. The lead isotope ratios (206Pb/204Pb and 207Pb/204Pb) of sulfides from Xichanggou and Huashi average at 17.414, 15.428, and 17.591, 15.379, respectively. The Re-Os isotopic compositions of ore sulfides mostly fall within the range of 318 ppm to 50,114 ppm. These isotopic compositions indicate that the materials responsible for the formation of the ores in Xichanggou and Huashi primarily originate from the melting of lower crust materials that have been contaminated by the mantle. Based on the regional data, the molybdenum deposits in eastern Hebei were formed in multiple periods, specifically approximately 170 Ma and 160 Ma in Huahsi and Xichanggou, respectively. The subduction of the Paleo-Pacific plate during the middle–late Jurassic period led to the partial remelting of lower crust material, resulting in the acquisition of a significant quantity of metal elements (Mo), which were subsequently deposited. Full article
(This article belongs to the Section Mineral Deposits)
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27 pages, 5945 KB  
Article
Middle Silurian–Middle Devonian Magmatic Rocks in the Eastern Segment of the Northern Margin of the North China Craton: Implications for Regional Tectonics
by Bin Li, Jingsheng Chen, Fan Yang, Miao Liu, Yanqing Zang and Chao Zhang
Minerals 2024, 14(7), 641; https://doi.org/10.3390/min14070641 - 23 Jun 2024
Cited by 3 | Viewed by 1882
Abstract
This paper presents a detailed study including LA-ICP-MS zircon U-Pb dating, geochemical, zircon Hf isotope, and whole rock Sr-Nd isotope analysis of magmatic rocks from the Yitong County, Jilin Province, NE China. These data are used to better constrain the Middle Silurian–Middle Devonian [...] Read more.
This paper presents a detailed study including LA-ICP-MS zircon U-Pb dating, geochemical, zircon Hf isotope, and whole rock Sr-Nd isotope analysis of magmatic rocks from the Yitong County, Jilin Province, NE China. These data are used to better constrain the Middle Silurian–Middle Devonian tectonic evolution in the eastern segment of the northern margin of the North China Craton (NCC). Zircon U-Pb dating results show that the Ximangzhang tonalite formed in the Late Silurian (425 ± 6 Ma); the basalt, andesite, and metamorphic olivine-bearing basalt in the Fangniugou volcanic rocks formed in the Middle Silurian (428 ± 6.6 Ma) and Middle Devonian (388.4 ± 3.9 Ma, and 384.1 ± 4.9 Ma). The Late Silurian tonalites are characterized by high SiO2 and Na2O and low K2O, MgO, FeOT, and TiO2, with an A/CNK ratio of 0.91–1.00, characteristic of calc-alkaline I-type granite. They are enriched in Rb, Ba, Th, U, and K, and depleted in Nb, Sr, P, and Ti, with positive εNd(t) (+0.35) and εHf(t) (+0.44 to +6.31) values, suggesting that they mainly originated from the partial melting of Meso–Neoproterozoic accretionary lower crustal material (basalt). The Middle Silurian basalts are characterized by low SiO2, P2O5, TiO2, and Na2O and high Al2O3, FeOT, and K2O, enriched in Rb, Ba, Th, U, and K and depleted in Nb, Ta, Sr, P, and Ti, indicative of shoshonitic basalt. The Late Silurian tonalites have positive εNd(t) (+4.91 to +6.18) values and primarily originated from depleted mantle magmas metasomatized by subduction fluids, supplemented by a small amount of subducted sediments and crustal materials. The Middle Devonian volcanic rocks exhibit low SiO2, TiO2, and Na2O and high K2O, and MgO, enriched in Rb, K, and LREEs and depleted in Nb, Ta, Sr, and HREEs, characteristic of shoshonitic volcanic rocks. Their εNd(t) (+2.11 to +3.77) and εHf(t) (+5.90 to +11.73) values are positive. These characteristics indicate that the Middle Devonian volcanic rocks primarily originated from depleted mantle magmas metasomatized by subduction fluids, with the addition of crustal materials or subducted sediments during their formation. Based on regional geological data, it is believed that the study area underwent the following evolutionary stages during the Silurian–Devonian period: (1) active continental margin stage of southward subduction of the Paleo–Asian Ocean (PAO) (443–419 Ma); (2) arc-continent collision stage (419–405 Ma); (3) post-collision extension stage (404–375 Ma); (4) active continental margin stage, with the PAO plate subducting southward once again (375–360 Ma). Full article
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19 pages, 5698 KB  
Article
Mesoproterozoic (ca. 1.3 Ga) A-Type Granites on the Northern Margin of the North China Craton: Response to Break-Up of the Columbia Supercontinent
by Bo Liu, Shengkai Jin, Guanghao Tian, Liyang Li, Yueqiang Qin, Zhiyuan Xie, Ming Ma and Jiale Yin
Minerals 2024, 14(6), 622; https://doi.org/10.3390/min14060622 - 18 Jun 2024
Viewed by 2571
Abstract
Mesoproterozoic (ca. 1.3 Ga) magmatism in the North China Craton (NCC) was dominated by mafic intrusions (dolerite sills) with lesser amounts of granitic magmatism, but our lack of knowledge of this magmatism hinders our understanding of the evolution of the NCC during this [...] Read more.
Mesoproterozoic (ca. 1.3 Ga) magmatism in the North China Craton (NCC) was dominated by mafic intrusions (dolerite sills) with lesser amounts of granitic magmatism, but our lack of knowledge of this magmatism hinders our understanding of the evolution of the NCC during this period. This study investigated porphyritic granites from the Huade–Kangbao area on the northern margin of the NCC. Zircon dating indicates the porphyritic granites were intruded during the Mesoproterozoic between 1285.4 ± 2.6 and 1278.6 ± 6.1 Ma. The granites have high silica contents (SiO2 = 63.10–73.73 wt.%), exhibit alkali enrichment (total alkalis = 7.71–8.79 wt.%), are peraluminous, and can be classified as weakly peraluminous A2-type granites. The granites have negative Eu anomalies (δEu = 0.14–0.44), enrichments in large-ion lithophile elements (LILEs; e.g., K, Rb, Th, and U), and depletions in high-field-strength elements (HFSEs; e.g., Nb, Ta, and Ti). εHf(t) values range from –6.43 to +2.41, with tDM2 ages of 1905–2462 Ma, suggesting the magmas were derived by partial melting of ancient crustal material. The geochronological and geochemical data, and regional geological features, indicate the Mesoproterozoic porphyritic granites from the northern margin of the NCC formed in an intraplate tectonic setting during continental extension and rifting, which represents the response of the NCC to the break-up of the Columbia supercontinent. Full article
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16 pages, 3380 KB  
Article
Mineralogical and Geochemical Evidence for the Origin of the DL Uranium Deposit in the Songliao Basin, Northeast China
by Jialin Liu, Mingkuan Qin, Shaohua Huang, Zhangyue Liu and Liangliang Zhang
Minerals 2024, 14(2), 149; https://doi.org/10.3390/min14020149 - 30 Jan 2024
Cited by 1 | Viewed by 1974
Abstract
The DL deposit is a typical tabular-shaped U deposit hosted in sandstones of the Upper Cretaceous Yaojia Formation in the southwestern Songliao Basin, northeast China. Owing to its recent discovery, the origin of the deposit remains unclear. In this study, mineralogical and geochemical [...] Read more.
The DL deposit is a typical tabular-shaped U deposit hosted in sandstones of the Upper Cretaceous Yaojia Formation in the southwestern Songliao Basin, northeast China. Owing to its recent discovery, the origin of the deposit remains unclear. In this study, mineralogical and geochemical data were used to constrain the genesis of the DL deposit. Two sources of U were recognized: (1) pre-ore U enrichment in the Yaojia Formation during diagenesis; and (2) the provenance of the Yaojia Formation, which comprises late Permian–Early Cretaceous granitic rocks from the southern Great Xing’an Range and northern margin of the North China Craton, rather than the oils and diabase dikes in the study area. Mineralogical and geochemical characteristics indicate that organic matter (OM) in the Yaojia Formation was derived mainly from plant debris and hydrocarbons. In situ S isotope data for pyrite from the ore-bearing sandstones show that most of the pyrite has similar δ34S values (−43.8‰ to −20.6‰) to those of pyrite associated with bacterial sulfate reduction (BSR). The pyrite is often typically replaced and/or overgrown by pitchblende, which has a high P2O5 content (0.07–1.64 wt.%), indicative of a genetic relationship between BSR and U mineralization. The geological, mineralogical, and geochemical features suggest that the U mineralization in the DL deposit was mainly associated with BSR. Full article
(This article belongs to the Section Mineral Deposits)
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25 pages, 28317 KB  
Article
Provenance of the Upper Carboniferous Yanghugou Formation in the Western Margin of the Ordos Basin, China: Constraints on Paleogeography and Basin Development
by Tao Zhang, Rong Chen, Feng Wang, Jianling Hu, Min Zhang, Qian Li, Jingyi Wu and Lei Liu
Minerals 2024, 14(1), 78; https://doi.org/10.3390/min14010078 - 10 Jan 2024
Cited by 3 | Viewed by 2397
Abstract
The Carboniferous Yanghugou Formation in the western margin of the Ordos Basin exhibits significant potential for oil and gas exploration. However, due to the influence of complex tectonic activities, there are substantial variations in stratigraphic thickness and depositional environments across the formation. The [...] Read more.
The Carboniferous Yanghugou Formation in the western margin of the Ordos Basin exhibits significant potential for oil and gas exploration. However, due to the influence of complex tectonic activities, there are substantial variations in stratigraphic thickness and depositional environments across the formation. The lack of a systematic source–sink comparative study has resulted in an unclear understanding of sediment sources and paleogeographic patterns, impacting the exploration for hydrocarbon accumulations. We conducted a comprehensive study of the source–sink system characteristics and paleogeography in the research area through field outcrop observations and drilling core sampling. By utilizing detrital zircon U–Pb geochronology and geochemistry, paleocurrent directions, lithofacies types, and sedimentary features, we delve into the understanding of the source–sink systems. Four major source–sink regions in the research area were identified: the Alxa, Yinshan, Alxa–Yinshan mixed and Qilian source–sink regions. The Alxa source–sink region formed a transitional delta-barrier-island sedimentary system. The northern part of the Yinshan source–sink region developed a transitional tidal-controlled delta-tidal-flat sedimentary system, while the southern deep-water area developed a shallow marine to semi-deep marine shelf sedimentary systems. The sediments of Alxa–Yinshan mixed source–sink region were deposited in a transitional tidal-controlled delta-tidal-flat barrier-island system. The Qilian source–sink region is characterized by small tidal-controlled delta-barrier-island system. From the analysis of the source–sink systems, it is inferred that the Alxa Block and the North China Craton had already merged before deposition of the late Carboniferous Yanghugou Formation. The delta sand bodies in the Alxa–Yinshan mixed source–sink region have the highest compositional and structural maturity, the best reservoir performance, and the great exploration potential. Full article
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27 pages, 15311 KB  
Article
Permian Granitic Plutons from the Northern Margin of the North China Craton: Implications for the Tectonic Evolution of the Central Asian Orogenic Belt
by Jingsheng Chen, Dexin Tian, Bin Li, Yi Shi, Zhonghui Gao, Yi Tian, Weiwei Li, Chao Zhang and Yan Wang
Minerals 2023, 13(12), 1554; https://doi.org/10.3390/min13121554 - 17 Dec 2023
Cited by 2 | Viewed by 2466
Abstract
As the world’s largest accretionary orogen, the Central Asian Orogenic Belt (CAOB) underwent continuous juvenile crustal growth in the Phanerozoic. The northern margin of the North China Craton (NCC) and its adjacent area form the eastern segment of the CAOB, which is a [...] Read more.
As the world’s largest accretionary orogen, the Central Asian Orogenic Belt (CAOB) underwent continuous juvenile crustal growth in the Phanerozoic. The northern margin of the North China Craton (NCC) and its adjacent area form the eastern segment of the CAOB, which is a key area for learning about the geological evolution of the Paleo-Asian Ocean (PAO). In the Permian, the west of the northern margin of the NCC was a post-collision extensional environment, while the east was in a subduction stage. As a connecting area, the Permian evolution of the PAO in the middle of the northern margin of the NCC has not been systematically studied. In order to fill the gap and understand the continuous temporal and spatial evolutionary process of the PAO, this paper focuses on the Permian granitic rocks in the Chifeng area. Zircon U-Pb dating and the geochemical analysis of whole-rock major and trace elements were conducted to build a granite chronological framework, and to discuss the genesis and tectonic background of the granitic rocks, along with tectono-magmatic evolutionary history in the Chifeng area. The respective LA-ICP-MS zircon U-Pb dating results from eight samples are 269 ± 1, 268 ± 3, 260 ± 4, 260 ± 1, 260 ± 1, 255 ± 2, 254 ± 2 and 256 ± 1 Ma, respectively. These results, combined with previous data, revealed that the Permian granitic rocks had undergone three events of magmatism: (1) monzogranitic-syenitic phase (294–284 Ma; Cisuralian); (2) monzogranitic phase (269–260 Ma; Guadalupian) and (3) late monzogranitic-syenitic phase (256–254 Ma; Lopingian). From the Early Permian (294–284 Ma) to the Middle Permian (269–260 Ma), granites with fine-medium-grained locally porphyritic texture and massive structure showed a high-potassium calc-alkaline series formed in a compressional setting, indicating a continuous collision between the Xing’an-Mongolian Orogenic Belt (XMOB) and the NCC. During the Late Permian-Early Triassic (256–248 Ma), granites with massive structure and medium-grained texture in the Chifeng area were magmatism dominated by A- and I-type granites of high-potassium calc-alkaline series, combined with the coeval basic rocks, which constituted a typical “bimodal” rock assemblage. This suggests that the Chifeng area was located in an extensional setting where the subducting slab broke off during the collision between the XMOB and NCC. These granitic plutons from the Permian are believed to have been generated by the subduction-collision of the Paleo-Asian oceanic crust beneath the NCC, according to emplacement time and occurrence location. Our findings provide strong evidence for Permian continuous temporal and spatial tectonic evolution and the characterization of the eventual closure of the PAO in Chifeng area at the northern margin of the NCC. Full article
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26 pages, 12140 KB  
Article
Age and Petrogenesis of the Dongjin Rare Metal Mineralized Intrusion in the Northern Margin of the North China Craton
by Chenyu Liu, Gongzheng Chen, Jinfang Wang, Yi Cheng, Kangshuo Li, Zeqian Lu and Yutong Song
Minerals 2023, 13(12), 1477; https://doi.org/10.3390/min13121477 - 24 Nov 2023
Cited by 3 | Viewed by 2329
Abstract
Highly fractionated granites are widespread in the middle part of the northern margin of the North China Craton (MNNCC), and several are accompanied by rare metal mineralization. The Dongjin rare metal mineralized intrusion, which is representative of this region, is composed of fine-grained [...] Read more.
Highly fractionated granites are widespread in the middle part of the northern margin of the North China Craton (MNNCC), and several are accompanied by rare metal mineralization. The Dongjin rare metal mineralized intrusion, which is representative of this region, is composed of fine-grained alkali-feldspar granite (FAG) and kali-feldspar granite (KG). The FAG and KG evolve continuously, exemplifying the relationship between magmatic evolution and rare metal mineralization. In this contribution, we present integrated columbite U-Pb geochronology, mineralogy, and whole-rock geochemistry analyses of the Dongjin intrusion to determine the timing of the mineralization, petrogenesis, and geodynamic setting, from which the following results are obtained: (1) LA-ICP-MS U-Pb dating for columbite of the FAG and KG yielded the lower intercept ages between 248.9 ± 1.9 Ma and 250.1 ± 1.1 Ma on the Tera–Wasserburg concordia diagram; (2) Geochemically, the Dongjin intrusion is characterized by an enrichment in Si, Al, Rb, Th, U, Nb, and Zr and a strong depletion in Ba, Sr, P, and Ti, with extremely negative Eu anomalies, high LREE and HREE values, and a noticeable tetrad effect of rare earth elements; as a result, it belongs to high-K calc-alkaline rocks; (3) The Dongjin intrusion belongs to a highly differentiated I-type or A-type granite; (4) The fractional crystallization of plagioclase, K-feldspar, and biotite occurred during magmatic evolution; (5) The Dongjin intrusion was formed in a post-collisional extensional environment. In conclusion, the FAG and KG have a homologous evolution, and the FAG has a higher degree of fractional crystallization. The enrichment and mineralization of Nb-Ta are related to the highly fractionated crystallization of granitic magma and fluid–melt interactions in the final stages of magmatic evolution, and there is a rare metal mineralization related to highly fractionated granite in the MNNCC in the Early Triassic, which deserves full attention in future research and prospecting. Full article
(This article belongs to the Special Issue Critical Metals on Land and in the Ocean)
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