Search Results (27)

This study reports the synthesis and comprehensive spectroscopic characterization of 4-indolylcyanamide (4ICA), a novel indole-derived infrared (IR) probe designed for assessing local microenvironments in biological systems. 4ICA was synthesized via a two-step procedure with an overall yield of 43%, and its structure was confirmed using high-resolution mass spectrometry and ¹HNMR. Fourier Transform Infrared (FTIR) spectroscopy revealed that the cyanamide group stretching vibration of 4ICA exhibits exceptional solvent-dependent frequency shifts, significantly greater than those of conventional cyanoindole probes. A strong linear correlation was observed between the vibrational frequency and the combined Kamlet–Taft parameter, underscoring the dominant role of solvent polarizability and hydrogen bond acceptance in modulating its spectroscopic behavior. Quantum chemical calculations employing density functional theory (DFT) with a conductor-like polarizable continuum model (CPCM) provided further insight into the solvatochromic shifts and suppression of Fermi resonance in high-polarity solvents such as DMSO. Additionally, IR pump–probe measurements revealed short vibrational lifetimes (~1.35 ps in DMSO and ~1.13 ps in ethanol), indicative of efficient energy relaxation. With a transition dipole moment nearly twice that of traditional nitrile-based probes, 4ICA demonstrates enhanced sensitivity and signal intensity, establishing its potential as a powerful tool for site-specific environmental mapping in proteins and complex biological assemblies using nonlinear IR techniques. Full article

High-specific-energy lithium-ion batteries face accelerated degradation and safety risks. To ensure stable and safe operation of such batteries in electric vehicles throughout their service life, this study proposes a quantitative aging mechanism analysis method based on electrode equilibrium potential reconstruction under rest conditions. First, by integrating the single-particle electrochemical model with equilibrium potential reconstruction, a quantitative mapping framework between State of Charge (SOC) and electrode lithiation concentration is established. Subsequently, to address the strong nonlinearity between equilibrium potential and lithiation concentration, the State Transition Algorithm (STA) is introduced to solve the high-dimensional coupled parameter identification problem, enhancing aging parameter estimation accuracy. Finally, the effectiveness of the proposed method was validated using a commercial NCM622/graphite power cell as the research object, and the battery’s aging pathways were analyzed using differential voltage analysis (DVA) and incremental capacity analysis (ICA) methods. Experimental results indicate that the OCV curve fitting achieved a maximum Root Mean Square Error of 0.00932, while quantitatively revealing the degradation patterns of electrode lithiation degrees during aging under both fully charged (SOC = 100%) and fully discharged (SOC = 0%) states. Full article

Rolling element bearings serve as critical transmission components in industrial automation systems, yet their fault signatures are susceptible to interference from strong background noise, complex operating conditions, and nonlinear impact characteristics. Addressing the limitations of conventional methods in adaptive parameter optimization and weak feature enhancement, this paper proposes an innovative diagnostic framework integrating Improved Goose optimized Variational Mode Decomposition (IGOOSE-VMD), RobustICA, and CYCBD. First, to mitigate modal aliasing issues caused by empirical parameter dependency in VMD, we fuse a refraction-guided reverse learning mechanism with a dynamic mutation strategy to develop the IGOOSE. By employing an energy-feature-driven fitness function, this approach achieves synergistic optimization of the mode number and penalty factor. Subsequently, a multi-channel observation model is constructed based on optimal component selection. Noise interference is suppressed through the robust separation capabilities of RobustICA, while CYCBD introduces cyclostationarity-based prior constraints to formulate a blind deconvolution operator with periodic impact enhancement properties. This significantly improves the temporal sparsity of fault-induced impact components. Experimental results demonstrate that, compared to traditional time–frequency analysis techniques (e.g., EMD, EEMD, LMD, ITD) and deconvolution methods (including MCKD, MED, OMEDA), the proposed approach exhibits superior noise immunity and higher fault feature extraction accuracy under high background noise conditions. Full article

Satellite communication systems, as a core component of global information infrastructure, have undergone unprecedented development. However, the open nature of satellite channels renders them vulnerable to electromagnetic interference, making anti-jamming techniques a persistent research focus in this domain. Satellite transponders contain various power-sensitive components that exhibit nonlinear characteristics under interference conditions, yet conventional anti-jamming approaches typically neglect the nonlinear distortion in transponders when suppressing interference. To address this challenge, this paper proposes a kernel-method-optimized FastICA algorithm (Kernel-FastICA) that establishes a post-nonlinear mixing model to precisely characterize signal transmission and reception processes. The algorithm transforms nonlinear separation tasks into high-dimensional, linear independent-component-analysis problems through kernel learning methodology. Furthermore, we introduce a regularized pre-whitening strategy to mitigate potential ill-conditioned issues arising from dimensional expansion, thereby enhancing numerical stability and separation performance. The simulation results demonstrate that the proposed algorithm exhibits superior robustness against interference and enhanced generalization capabilities in nonlinear jamming environments compared with existing solutions. Full article

Drought is a complex and interconnected natural phenomenon, involving multiple drought types that mutually influence each other. To capture this complexity, various composite drought indices have been developed using diverse methodologies. Traditionally, Principal Component Analysis (PCA) has served as the primary method for extracting index weights, predominantly capturing linear relationships among variables. This study proposes an innovative approach by employing Independent Component Analysis (ICA) to develop an ICA-based Composite Drought Index (ICDI), capable of addressing both linear and nonlinear interdependencies. Three drought indices—representing meteorological, hydrological, and agricultural droughts—were integrated. Specifically, the Standardized Precipitation Index (SPI) was adopted as the meteorological drought indicator, whereas the Standardized Reservoir Supply Index (SRSI) was utilized to represent both hydrological (SRSI(H)) and agricultural (SRSI(A)) droughts. The ICDI was derived by extracting optimal weights for each drought index through ICA, leveraging the optimization of non-Gaussianity. Furthermore, constraints (referred to as ICDI-C) were introduced to ensure all index weights were positive and normalized to unity. These constraints prevented negative weight assignments, thereby enhancing the physical interpretability and ensuring that no single drought index disproportionately dominated the composite. To rigorously assess the performance of ICDI, a PCA-based Composite Drought Index (PCDI) was developed for comparative analysis. The evaluation was carried out through three distinct performance metrics: difference, model, and alarm performance. The difference performance, calculated by subtracting composite index values from individual drought indices, indicated that PCDI and ICDI-C outperformed ICDI, exhibiting comparable overall performance. Notably, ICDI-C demonstrated a superior preservation of SRSI(H) values, yielding difference values closest to zero. Model performance metrics (Root Mean Square Error (RMSE), Mean Absolute Error (MAE), and correlation) highlighted ICDI’s comparatively inferior performance, characterized by lower correlations and higher RMSE and MAE. Conversely, PCDI and ICDI-C exhibited similar performance across these metrics, though ICDI-C showed notably higher correlation with SRSI(H). Alarm performance evaluation (False Alarm Ratio (FAR), Probability of Detection (POD), and Accuracy (ACC)) further confirmed ICDI’s weakest reliability, with notably high FAR (up to 0.82), low POD (down to 0.13), and low ACC (down to 0.46). PCDI and ICDI-C demonstrated similar results, although PCDI slightly outperformed ICDI-C as meteorological and agricultural drought indicators, whereas ICDI-C excelled notably in hydrological drought detection (SRSI(H)). The results underscore that ICDI-C is particularly adept at capturing hydrological drought characteristics, rendering it especially valuable for water resource management—a critical consideration given the significance of hydrological indices such as SRSI(H) in reservoir management contexts. However, ICDI and ICDI-C exhibited limitations in accurately capturing meteorological (SPI(6)) and agricultural droughts (SRSI(A)) relative to PCDI. Thus, while the ICA-based composite drought index presents a promising alternative, further refinement and testing are recommended to broaden its applicability across diverse drought conditions and management contexts. Full article

Accurate prediction of the on-orbit positions of Low Earth Orbit (LEO) satellites is essential for mission success, operational efficiency, and safety. Nevertheless, the non-stationary nature of orbital data and sensor noise presents significant challenges for accurate prediction. To address these challenges, we propose a novel forecasting model, EMD-ICA-DLinear, which combines trend-residual representation with EMD-ICA in an innovative manner. By integrating the TSR (Trend, Seasonality, and Residual) framework with the EMD-ICA dual perspective, this approach provides a comprehensive understanding of time series data and outperforms traditional models in capturing subtle nonlinear relationships. When predicting the orbital position of the Fengyun-3C satellite, the model uses MSE and MAE as evaluation metrics. Experimental results indicate that the proposed EMD-ICA-DLinear hybrid model achieves MSE and MAE values of 0.1101 and 0.1567, respectively, when predicting the orbital position of the Fengyun-3C satellite 6 h in advance, representing reductions of 37.87% and 19.85% compared to the best baseline model, TimesNet. This advancement enhances satellite orbit prediction accuracy, supports operational stability, and enables timely adjustments, thereby improving mission efficiency and safety. Full article

Protecting AC microgrids (MGs) is a challenging task due to their dual operating modes—grid-connected and islanded—which cause sudden variations in fault currents. Traditional protection methods may no longer ensure network security. This paper presents a novel approach to protection coordination in AC MGs using non-standard features of directional over-current relays (DOCRs). Three key optimization variables are considered: Time Multiplier Setting (TMS), the plug setting multiplier’s (PSM) maximum limit, and the standard characteristic curve (SCC). The proposed model is formulated as a mixed-integer nonlinear programming problem and solved using four metaheuristic techniques: the genetic algorithm (GA), Imperialist Competitive Algorithm (ICA), Harmonic Search (HS), and Firefly Algorithm (FA). Tests on a benchmark IEC MG with distributed generation and various operating modes demonstrate that this approach reduces coordination times compared to existing methods. This paper’s main contributions are threefold: (1) introducing a methodology for assessing the optimal performance of different standard curves in MG protection; (2) utilizing non-standard characteristics for optimal coordination of DOCRs; and (3) enabling the selection of curves from both North American and European standards. This approach improves trip time performance across multiple operating modes and topologies, enhancing the reliability and efficiency of MG protection systems. Full article

Wildfires increasingly threaten ecosystems and infrastructure, making accurate burn severity mapping (BSM) essential for effective disaster response and environmental management. Machine learning (ML) models utilizing satellite-derived vegetation indices are crucial for assessing wildfire damage; however, incorporating many indices can lead to multicollinearity, reducing classification accuracy. While principal component analysis (PCA) is commonly used to address this issue, its effectiveness relative to other feature extraction (FE) methods in BSM remains underexplored. This study aims to enhance ML classifier accuracy in BSM by evaluating various FE techniques that mitigate multicollinearity among vegetation indices. Using composite burn index (CBI) data from the 2014 Carlton Complex fire in the United States as a case study, we extracted 118 vegetation indices from seven Landsat-8 spectral bands. We applied and compared 13 different FE techniques—including linear and nonlinear methods such as PCA, t-distributed stochastic neighbor embedding (t-SNE), linear discriminant analysis (LDA), Isomap, uniform manifold approximation and projection (UMAP), factor analysis (FA), independent component analysis (ICA), multidimensional scaling (MDS), truncated singular value decomposition (TSVD), non-negative matrix factorization (NMF), locally linear embedding (LLE), spectral embedding (SE), and neighborhood components analysis (NCA). The performance of these techniques was benchmarked against six ML classifiers to determine their effectiveness in improving BSM accuracy. Our results show that alternative FE techniques can outperform PCA, improving classification accuracy and computational efficiency. Techniques like LDA and NCA effectively capture nonlinear relationships critical for accurate BSM. The study contributes to the existing literature by providing a comprehensive comparison of FE methods, highlighting the potential benefits of underutilized techniques in BSM. Full article

The integration of communication and sensing (ICAS) in optical networks is an inevitable trend in building intelligent, multi-scenario, application-converged communication systems. However, due to the impact of nonlinear effects, co-fiber transmission of sensing signals and communication signals can cause interference to the communication signals, leading to an increased bit error rate (BER). This paper proposes a noncoherent solution based on the alternate polarization chirped return-to-zero frequency shift keying (Apol-CRZ-FSK) modulation format to realize a 4 × 100 Gbps dense wavelength division multiplexing (DWDM) optical network. Simulation results show that compared to traditional modulation formats, such as chirped return-to-zero frequency shift keying (CRZ-FSK) and differential quadrature phase shift keying (DQPSK), this solution demonstrates superior resistance to nonlinear effects, enabling longer transmission distances and better transmission performance. Moreover, to meet the transmission requirements and signal sensing and recognition needs in future optical networks, this study employs the Inception-ResNet-v2 convolutional neural network model to identify three modulation formats. Compared with six deep learning methods including AlexNet, ResNet50, GoogleNet, SqueezeNet, Inception-v4, and Xception, it achieves the highest performance. This research provides a low-cost, low-complexity, and high-performance solution for signal transmission and signal recognition in high-speed optical networks designed for integrated communication and sensing. Full article

Advanced statistics can enable the detailed characterization of ground deformation time series, which is a fundamental step for thoroughly understanding the phenomena of land subsidence and their main drivers. This study presents a novel methodological approach based on pre-existing open-access statistical tools to exploit satellite differential interferometric synthetic aperture radar (DInSAR) data to investigate land subsidence processes, using European Ground Motion Service (EGMS) Sentinel-1 DInSAR 2018−2022 datasets. The workflow involves the implementation of Persistent Scatterers (PS) time series classification through the PS-Time tool, deformation signal decomposition via independent component analysis (ICA), and drivers’ investigation through spatio-temporal correlation with geospatial and monitoring data. Subsidence time series at the three demonstration sites of Bologna, Ravenna and Carpi (Po Plain, Italy) were classified into linear and nonlinear (quadratic, discontinuous, uncorrelated) categories, and the mixed deformation signal of each PS was decomposed into independent components, allowing the identification of new spatial clusters with linear, accelerating/decelerating, and seasonal trends. The relationship between the different independent components and DInSAR-derived displacement velocity, acceleration, and seasonality was also analyzed via regression analysis. Correlation with geological and groundwater monitoring data supported the investigation of the relationship between the observed deformation and subsidence drivers, such as aquifer resource exploitation, local geological setting, and gas extraction/reinjection. Full article

The aim of electrical load dispatch (ELD) is to achieve the optimal planning of different power plants to supply the required power at the minimum operation cost. Using the combined heat and power (CHP) units in modern power systems, increases energy efficiency and, produce less environmental pollution than conventional units, by producing electricity and heat, simultaneously. Consequently, the ELD problem in the presence of CHP units becomes a very non-linear and non-convex complex problem called the combined heat and power economic dispatch (CHPED), which supplies both electric and thermal loads at the minimum operational cost. In this work, at first, a brief review of optimization algorithms, in different categories of classical, or conventional, stochastic search-based, and hybrid optimization techniques for solving the CHPED problem is presented. Then the CHPED problem in large-scale power systems is investigated by applying the imperialist competitive Harris hawks optimization (ICHHO), as the combination of imperialist competitive algorithm (ICA), and Harris hawks optimizer (HHO), for the first time, to overcome the shortcomings of using the ICA and HHO in the exploitation, and exploration phases, respectively, to solve this complex optimization problem. The effectiveness of the combined algorithm on four standard case studies, including 24 units as a medium-scale, 48, 84, units as the large-scale, and 96-unit as a very large-scale heat and power system, is detailed. The obtained results are compared to those of different algorithms to demonstrate the performance of the ICHHO algorithm in terms of better solution quality and lower fuel cost. The simulation studies verify that the proposed algorithm decreases the minimum operation costs by at least 0.1870%, 0.342%, 0.05224%, and 0.07875% compared to the best results in the literature. Full article

An efficient processing approach is essential for increasing identification accuracy since the electroencephalogram (EEG) signals produced by the Brain–Computer Interface (BCI) apparatus are nonlinear, nonstationary, and time-varying. The interpretation of scalp EEG recordings can be hampered by nonbrain contributions to electroencephalographic (EEG) signals, referred to as artifacts. Common disturbances in the capture of EEG signals include electrooculogram (EOG), electrocardiogram (ECG), electromyogram (EMG) and other artifacts, which have a significant impact on the extraction of meaningful information. This study suggests integrating the Singular Spectrum Analysis (SSA) and Independent Component Analysis (ICA) methods to preprocess the EEG data. The key objective of our research was to employ Higher-Order Linear-Moment-based SSA (HOL–SSA) to decompose EEG signals into multivariate components, followed by extracting source signals using Online Recursive ICA (ORICA). This approach effectively improves artifact rejection. Experimental results using the motor imagery High-Gamma Dataset validate our method’s ability to identify and remove artifacts such as EOG, ECG, and EMG from EEG data, while preserving essential brain activity. Full article

Ensuring operational reliability in machinery requires accurate fault detection. While time-domain vibration pulsation signals are intuitive for pattern recognition and feature extraction, downsampling can reduce analytical complexity, but may result in low-precision data, affecting fault detection performance. To address this, we propose time–frequency feature fusion, combining information from both the time and frequency domains for fault detection. Our approach transforms vibrational pulse data into instantaneous revolutions per minute (RPM) and employs statistical analysis for the time-domain features. For the frequency-domain features, we use the combined method of empirical mode decomposition and independent component analysis (EMD-ICA), along with the Wigner bispectrum method to capture the nonlinear characteristics and phase conjugation. Using a deep neural network (DNN), we classify the anomaly states, demonstrating the effectiveness and versatility of our approach in detecting anomalies and improving diagnostic precision. Compared to using time or frequency features alone, our time–frequency feature fusion model achieves higher accuracy, with 100% accuracy at lower downsampling rates and 96.3% accuracy at a downsampling rate of 100×. Full article

This study introduces a new method for identifying COVID-19 infections using blood test data as part of an anomaly detection problem by combining the kernel principal component analysis (KPCA) and one-class support vector machine (OCSVM). This approach aims to differentiate healthy individuals from those infected with COVID-19 using blood test samples. The KPCA model is used to identify nonlinear patterns in the data, and the OCSVM is used to detect abnormal features. This approach is semi-supervised as it uses unlabeled data during training and only requires data from healthy cases. The method’s performance was tested using two sets of blood test samples from hospitals in Brazil and Italy. Compared to other semi-supervised models, such as KPCA-based isolation forest (iForest), local outlier factor (LOF), elliptical envelope (EE) schemes, independent component analysis (ICA), and PCA-based OCSVM, the proposed KPCA-OSVM approach achieved enhanced discrimination performance for detecting potential COVID-19 infections. For the two COVID-19 blood test datasets that were considered, the proposed approach attained an AUC (area under the receiver operating characteristic curve) of 0.99, indicating a high accuracy level in distinguishing between positive and negative samples based on the test results. The study suggests that this approach is a promising solution for detecting COVID-19 infections without labeled data. Full article

A novel physiologically based algorithm (PBA) for the computation of fractional flow reserve (FFR) in coronary artery trees (CATs) using computational fluid dynamics (CFD) is proposed and developed. The PBA was based on an extension of Murray’s law and additional inlet conditions prescribed iteratively and was implemented in OpenFOAM v1912 for testing and validation. 3D models of CATs were created using CT scans and computational meshes, and the results were compared to invasive coronary angiographic (ICA) data to validate the accuracy and effectiveness of the PBA. The discrepancy between the calculated and experimental FFR was within 2.33–5.26% in the steady-state and transient simulations, respectively, when convergence was reached. The PBA was a reliable and physiologically sound technique compared to a current lumped parameter model (LPM), which is based on empirical scaling correlations and requires nonlinear iterative computing for convergence. The accuracy of the PBA method was further confirmed using an FDA nozzle, which demonstrated good alignment with the CFD-validated values. Full article