Search Results (226)

Petroleum oily sludge (OLS), a hazardous by-product of the petroleum industry, and high-alkali lignite (HAL), an underutilized low-rank coal, pose significant challenges to sustainable waste management and resource efficiency. This study systematically investigated the combustion behavior, reaction pathways, and gaseous-pollutant-release mechanisms across varying blend ratios, utilizing integrated thermogravimetric-mass spectrometry analysis (TG-MS), interaction analysis, and kinetic modeling. The key findings reveal that co-combustion significantly enhances the combustion performance compared to individual fuels. This is evidenced by reduced ignition and burnout temperatures, as well as an improved comprehensive combustion index. Notably, an interaction analysis revealed coexisting synergistic and antagonistic effects, with the synergistic effect peaking at a blending ratio of 50% OLS due to the complementary properties of the fuels. The activation energy was found to be at its minimum value of 32.5 kJ/mol at this ratio, indicating lower reaction barriers. Regarding gas emissions, co-combustion at a 50% OLS blending ratio reduces incomplete combustion products while increasing CO₂, indicating a more complete reaction. Crucially, sulfur-containing pollutants (SO₂, H₂S) are suppressed, whereas nitrogen-containing emissions (NH₃, NO₂) increase but remain controllable. This study provides novel insights into the synergistic mechanisms between OLS and HAL during co-combustion, offering foundational insights for the optimization of OLS-HAL combustion systems toward efficient energy recovery and sustainable industrial waste management. Full article

Researchers increasingly agree that livestock farming is the leading cause of air pollution with ammonia (NH₃) gas. The existing research suggests that 30–80% of nitrogen is lost from slurry and liquid manure in the gaseous form of ammonia. Most studies have focused on environmental factors influencing ammonia volatilization and manure composition but not on controlling the moisture level on the surface of the excreta. Applying the principles of convective mass exchange, this study was undertaken to compare different types of organic covers that mitigate NH₃ emissions and offer recommendations on how to properly apply organic covers on the surface of manure. Data was obtained from research in laboratory conditions comparing well-known coatings (chopped straw) with less commonly used organic materials (peat) or waste generated in other industries (sawdust, hemp chaff). This research demonstrated that applying bio-coatings can reduce ammonia (NH₃) emissions at coating thicknesses of ≥5 cm for sawdust, ≥3 cm for peat, ≥10 cm for hemp chaff, and 8–12 cm for straw. These reductions are linked to the ability of the coatings to lower manure surface moisture evaporation, a key driver of ammonia volatilization, highlighting the role of surface moisture control in emission mitigation. Full article

This study evaluates the agronomic and environmental performance of pelletized compost derived from olive mill waste as a sustainable alternative to mineral fertilizers for cultivating wheat (Triticum turgidum L.) under conventional tillage methods. A field experiment was conducted in semi-arid Spain, employing three fertilization strategies: inorganic (MAP + Urea), sewage sludge (SS), and organic compost pellets (OCP), each providing 150 kg N ha⁻¹. The parameters analyzed included wheat yield, grain quality, soil properties, and greenhouse gas (GHG) emissions. Inorganic fertilization yielded the highest productivity and nutrient uptake. However, the OCP treatment reduced grain yield by only 15%, while improving soil microbial activity and enzymatic responses. The SS and OCP treatments showed increased CO₂ and N₂O emissions compared to the control and inorganic plots. However, the OCP treatment also acted as a CH₄ sink. Nutrient use efficiency was greatest under mineral fertilization, though the OCP treatment outperformed the SS treatment. These results highlight the potential of OCP as a circular bio-based fertilizer that can enhance soil function and partially replace mineral inputs. Optimizing application timing is critical to aligning nutrient release with crop demand. Further long-term trials are necessary to evaluate their impact on the soil and improve environmental outcomes. Full article

A major breakthrough in environmentally friendly building materials is the development of sustainable unfired clay bricks including alumina waste produced during liquid nitrogen generation. Though used extensively, conventional fired clay bricks require energy-intensive manufacturing techniques that produce significant amounts of CO₂ and aggravate environmental damage. By removing the need for high-temperature firing and allowing for the valorization of industrial byproducts including alumina waste and lateritic soil, unfired clay bricks offer a reasonable low-carbon alternative. High silica and alumina contents define the alumina waste, which shows pozzolanic reactivity, thus improving the physicomechanical performance of the bricks. With alumina waste substituting 0–8.57% of the cement content, seven different formulations showed improvements in compressive strength, reduced water absorption, and optimal thermal conductivity. Especially, the mechanical performance was much enhanced with alumina waste inclusion up to 30%, without sacrificing thermal insulation capacity or moisture resistance. Further supporting the environmental and financial sustainability of the suggested brick compositions is the economic viability of using industrial waste and regionally derived soils. A comparative analysis of the conventional fired bricks shows that the unfired substitutes have a much lower environmental impact and show better mechanical properties, including greater compressive strength and modulus of rupture. These results support the more general goals of circular economy systems and low-carbon urban development by highlighting the feasibility of including alumina waste and lateritic soil into sustainable building materials. Using such waste-derived inputs in building fits world initiatives to lower resource consumption, lower greenhouse gas emissions, and build strong infrastructure systems. Full article

Conventional ammonia production uses fossil-based hydrogen, resulting in high greenhouse gas emissions. Given the growing demand for sustainable solutions, it is essential to replace fossil hydrogen with renewable alternatives. This study assessed the technical, economic, and environmental viability of renewable ammonia production in Minas Gerais. To this end, an optimization model based on mixed integer linear programming (MILP) was developed and implemented in LINGO 20^® software. The model incorporated investment costs; raw materials; transportation; emissions; and indicators such as NPV, payback, and minimum sale price. Hydrogen production routes integrated into the Haber–Bosch process were analyzed: biomass gasification (GS_WGS), anaerobic digestion of vinasse (Vinasse_BD_SMR), ethanol reforming (Ethanol_ESR), and electrolysis (PEM_electrolysis). Vinasse_BD_SMR showed the lowest costs and the greatest economic viability, with a payback of just 2 years, due to the use of vinasse waste as a raw material. In contrast, the electrolysis-based route had the longest payback time (8 years), mainly due to the high cost of the electrolyzers. The substitution of conventional hydrogen made it possible to avoid 580,000 t CO₂ eq/year for a plant capacity of 200,000 t NH₃/year, which represents 13% of the Brazilian emissions from the nitrogenated fertilizer sector. It can be concluded that the viability of renewable ammonia depends on the choice of hydrogen source and logistical optimization and is essential for reducing emissions at large scale. Full article

The purpose of this study was to evaluate the energy and environmental potential of waste biomass in the form of hazelnut shells from selected Turkish varieties of Corylus avellana L. Eight commercial varieties (Çakıldak, Foşa, İnce Kara, Kalın Kara, Palaz, Tombul, Yassı Badem and Yuvarlak Badem) grown in different regions of the Black Sea coast of Turkey were analyzed. The scope of this study included whole nut and shell weight determination, technical and elemental analysis, higher heating value (HHV) and lower net heating value (LHV), as well as emission factors (CO, CO₂, NO_x, SO₂, dust) and flue gas composition based on stoichiometric calculations. The results showed a significant effect of varietal characteristics on all analyzed parameters. The share of shell in the total weight of the nut ranged from 43.5% (Tombul) to 55.3% (İnce Kara). HHV values ranged from 18.37 to 19.20 MJ·kg⁻¹, and LHV from 17.05 to 17.90 MJ·kg⁻¹. The İnce Kara and Yassı Badem varieties showed the most favorable energy properties. Elemental analysis confirmed a low nitrogen and sulfur content, which translated into low NO_x and SO₂ emissions. NO_x emissions were lowest for the Tombul variety (1.43 kg·Mg⁻¹), and SO₂ emissions were close to zero in each variety. The results confirm that Turkish hazelnut shells are a valuable energy resource and can be used as solid fuel or supplementary biomass. In particular, the İnce Kara variety was identified as the most promising due to its high shell weight, very good fuel properties, and high yield potential. This study underscores the importance of selecting the right variety to optimize agricultural waste utilization strategies within a circular economy. Full article

To address severe ammonia gas and dust pollution coupled with resource waste in exhaust gases from urea prilling towers, a production process for gasified biochar-based slow-release fertilizer is proposed to achieve resource recovery of exhaust pollutants. Through phosphoric acid impregnation modification applied to gasified biochar, its ammonia gas adsorption capacity was significantly enhanced, with saturated adsorption capacity increasing from 0.61 mg/g (unmodified) to 32 mg/g. Coupled with the tower-top bag filter, the modified biochar combines with ammonia gas and urea dust in exhaust gases, subsequently forming biochar-based slow-release fertilizer through dehydration and granulation processes. Material balance analysis demonstrates that a single 400,000-ton/year urea prilling tower achieves a daily fertilizer production capacity of 55 tons, with 18% active ingredient content. The nitrogen content can be upgraded to national standards through urea supplementation. Economic analysis demonstrates a total capital investment of USD1.2 million, with an annual net profit of USD0.88 million and a static payback period of 1.36 years. This process not only achieves ammonia gas emission reduction but also converts waste biochar into high-value fertilizer. It displays dual advantages of environmental benefits and economic feasibility and provides an innovative solution for resource utilization of the exhaust gases from the urea prilling process. Full article

Tomato waste (TW) was employed as a sustainable source for the synthesis of fluorescent carbon dots (CDs) via a microwave-assisted hydrothermal carbonization (Mw-HTC) method, aiming at its valorization. Several amines were used as nitrogen additives to enhance the fluorescence quantum yield (QY) of CDs, and a set of reaction conditions, including additive/TW mass ratio (0.04–0.32), dwell time (15–60 min), and temperature (200–230 °C) of the HTC process, were scrutinized. The structural analysis of the tomato waste carbon dots (TWCDs) was undertaken by FTIR and ¹H NMR techniques, revealing their most relevant features. In solid state, transmission electron microscopy (TEM) analysis showed the presence of nearly spherical nanoparticles with an average lateral size of 8.1 nm. Likewise, the topographical assessment by atomic force microscopy (AFM) also indicated particles’ heights between 3 and 10 nm. Their photophysical properties, revealed by UV–Vis, steady-state, and time-resolved fluorescence spectroscopies, are fully discussed. Higher photoluminescent quantum yields (up to 0.08) were attained when the biomass residues were mixed with organic aliphatic amines during the Mw-HTC process. Emission tunability is a characteristic feature of these CDs, which display an intensity average fluorescence lifetime of 8 ns. The new TWCDs demonstrated good antioxidant properties by the ABTS radical cation method (75% inhibition at TWCDs’ concentration of 5 mg/mL), which proved to be related to the dwell time used in the CDs synthesis. Moreover, the synthesized TWCDs suppressed the growth of Escherichia coli and Staphylococcus aureus at concentrations higher than 2000 μg/mL, encouraging future antibacterial applications. Full article

The cement industry faces increasing energy costs and environmental pressures, driving the adoption of alternative fuels derived from waste materials. In Togo, approximately 350,000 t of end-of-life tires (ELT) are generated annually, creating significant environmental and health hazards through uncontrolled disposal and burning practices. This study investigated the technical feasibility and economic viability of incorporating waste tires as an alternative fuel in cement manufacturing. Tire-derived fuel (TDF) performance was evaluated by comparing pre-processed industrial tires with unprocessed ones, focusing on clinker production loss, elemental composition, heating values, and bulk density. The results demonstrate that TDF exhibits superior performance characteristics, with the highest heating values, and meets all the required specifications for cement production. In contrast, whole tire incineration fails to satisfy the recommended criteria, necessitating blending with conventional fuels to maintain clinker quality and combustion efficiency. The investigation revealed no significant adverse effects on production processes or clinker quality while achieving substantial reductions in nitrogen and sulfur oxide emissions. The experimental results were compared with the theoretical burnout times to optimize the shredding operations and injection methods. However, several challenges remain unaddressed, including the absence of streamlined handling processes, limited understanding of long-term ecological and health impacts, and insufficient techno-economic assessments. Future research should prioritize identifying critical aging points, investigating self-rejuvenating behaviors, and quantifying long-term environmental implications. These findings provide a foundation for developing computational models to optimize the mixing ratios of alternative and fossil fuels in cement manufacturing, offering significant environmental, economic, and societal benefits for the cement industry. Full article

As photovoltaic (PV) installations expand globally, effective recycling of end-of-life crystalline silicon solar cells has become increasingly important, including the recovery of valuable metals such as silver (Ag) and aluminium (Al). Traditional nitric acid-based chemical leaching methods, although effective, present environmental challenges due to the generation of hazardous nitrogen oxide (NO_x) emissions. To address these concerns, this study investigated alternative hydrometallurgical leaching strategies. Two selective treatments (NaOH for Al, and NH₃ + H₂O₂ for Ag) and one simultaneous treatment (HNO₃ + H₂O₂) were evaluated for metal recovery efficiency. All methods demonstrated high recovery efficiencies, achieving at least 99% for both metals within 60 min. The investigated methods effectively suppressed NO_x emissions without compromising leaching efficiency. These findings confirm that hydrometallurgical leaching techniques incorporating hydrogen peroxide can achieve efficient and environmentally safer recovery of silver and aluminium from solar cells, providing valuable insights into the development of more sustainable recycling practices for photovoltaic waste management. Full article

CO₂, a major industrial (waste)water treatment process byproduct, significantly contributes to climate change, desertification and overall water depletion. Therefore, there is a significant interest in decreasing CO₂ amounts, generated by various technological processes, through a wide range of methods from geological sequestration to biological sequestration. The CO₂ (waste)water treatment byproduct sequestration into agricultural CO₂-enhanced irrigation water offers several benefits by enhancing crop yield and repurposing emissions. This sustainable approach supports climate neutrality via biological sequestration, promotes circular economy principles, and strengthens the link between agriculture and climate change. In this study, the effect of CO₂-enriched water irrigation was analyzed in a complex network of plants germination, soil bacterial populations’ dynamics and soil composition. Results showed that germination rates of plants irrigated with CO₂-enriched water were species specific. Sage plants increased their germination and growth when irrigated with CO₂-enriched water compared with plants irrigated with plain water. Moreover, CO₂ addition favored the development of soil anaerobic bacteria in detriment of aerobic bacteria and subsequently changing organic and nitrogenous compounds soil composition compared to plain water irrigation. For the first time, the germination process influenced by CO₂ was correlated with on overall possible CO₂ effects on bacterial population growth dynamics and soil quality metabolites availability. Full article

The proximity of ecologically valuable areas to industrial zones indicates a strong need for monitoring their condition. Soil assessment involves both molecular techniques for studying microbial biodiversity, such as PCR, sequencing, and metagenomics, as well as parameters of biochemical and enzymatic activity of soil microorganisms. The authors studied the activity of microorganisms responsible for the nitrogen cycle to compare the condition of soils under different uses (wastelands and arable fields) located in the ecologically valuable areas of the Polesie National Park (PNP, protected area) and its surroundings. Additionally, they assessed the suitability of gangue for reclamation and its effectiveness depending on treatment duration (2 and 10 years). In most of the activities analyzed, their levels were lower in the park. A higher intensity of ammonification and nitrification was observed in the soil sampled from the field in the park; however, a reduced N₂O emission was also recorded after incubation in the lab of soil samples collected in the autumn, which may indicate that nitrogen loss from the soil does not occur in this particular habitat, which requires further, long-term and cyclical field trials. These observations confirm the potential protective role of the park in relation to soils and atmosphere in the context of the nitrogen cycle. The activities under study in the reclaimed soils were in both cases lower than in soils from the fields. The current results prove that this method of reclamation is not entirely effective; however, long-term reclamation yielded better results. The present study provided valuable information on the effectiveness of the protective role of the PNP in relation to soils and air. Additionally, these results may be helpful in making decisions regarding the use of waste, such as gangue, for reclamation. Full article

The continued expansion of cities in economic, population and geographical terms leads to significant environmental and infrastructural pressures, including the need for efficient municipal solid waste (MSW) management. This research focuses on the characterization of MSW generated in the city of Skopje and the investigation of its thermo-physical properties and energy utilization potential. The analyses cover physical and chemical properties, including density, moisture content, volatile matter, ash, and higher heating value, using adequate testing methods. The results indicate that MSW has a relatively high gross calorific value, surpassing typical MSW ranges comparable to those of solid fossil fuels. With approximately 79.42% volatile matter and a low ash content of 7.76%, the considered MSW demonstrates excellent combustibility. Chemical analysis reveals high carbon (53.12%) and hydrogen (7.69%) levels, supporting high energy value, while low nitrogen (0.84%) and sulfur (0.26%) levels ensure minimal NO_x and SO_x emissions. These characteristics position MSW as a suitable feedstock for energy production in incineration facilities. However, the heterogeneous composition of MSW presents challenges to process stability, necessitating prior waste preparation. The research concludes that harnessing waste energy potential could contribute to sustainability, reduce reliance on fossil fuels, and improve the environmental conditions in large urban areas. Full article

Motor vehicles emit a large amount of air pollutants. Inspection and Maintenance (I/M) systems serve as a pivotal strategy for mitigating emissions from operational diesel trucks. However, the prevalent issue of blind repairs persists due to insufficient diagnostic capabilities at maintenance stations (M stations). To address this challenge, a multi-source information fusion methodology is proposed, integrating load deceleration testing from inspection stations (I stations), on-board diagnostics (OBD) data, and manual measurements at M stations. Critical diagnostic parameters—including nitrogen oxides (NOx) and particulate matter (PM) emissions, the ratio of measured wheel-side power to rated power, intake volume, common rail pressure, and exhaust back pressure—are systematically selected through statistical analysis and expert evaluations. An adaptive membership function is developed to resolve ambiguities in emission thresholds, enabling the construction of a robust fault diagnosis framework. Validation using 800 National V diesel truck maintenance records from a provincial automotive electronic health platform (2022 data) demonstrates a diagnostic accuracy of 92.8% for 153 emission-exceeding vehicles, surpassing traditional machine learning approaches by over 20%. By minimizing unnecessary repairs and optimizing maintenance efficiency, this approach significantly reduces resource waste and the lifecycle environmental footprints of diesel fleets. The proposed fuzzy-logic-based model effectively detects latent faults during routine maintenance, directly contributing to sustainable transportation through reductions in NOx and PM emissions—critical for improving air quality and advancing global climate objectives. This establishes a scalable technical framework for the effective implementation of I/M systems in alignment with sustainable urban mobility policies. Full article

This study explores the economic benefits and challenges associated with biodegradable waste composting, highlighting its role in promoting sustainability through a circular economy framework. We reviewed the relevant literature and found 160 articles for this study, including the keywords “Biodegradable waste”, “Compost production”, and “Economic Potential”. Considering quality studies, we employed the PRISMA technique to conduct a comprehensive data synthesis and evaluate 89 articles for the final review. Our findings highlight that composting offers significant advantages, including waste reduction, cost savings in waste management, carbon credit, a source of nitrogen, job creation, and reduced reliance on synthetic fertilizers. Further, it supports environmental sustainability by improving soil health, mitigating greenhouse gas emissions, and reducing landfill use. However, challenges such as high upfront costs, quality control, and market competition with chemical fertilizers remain barriers to widespread adoption. The study extends the literature by emphasizing that the integration of composting into a circular economy can foster innovation, enhance local economies, and contribute to climate change mitigation. Furthermore, it offers a promising pathway for advancing sustainability. Future research should focus on improving composting technologies, optimizing their applications, and developing stronger policy frameworks to ensure the successful implementation of biodegradable waste composting practices. Full article