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Keywords = municipal solid waste

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28 pages, 1806 KiB  
Systematic Review
Systemic Review and Meta-Analysis: The Application of AI-Powered Drone Technology with Computer Vision and Deep Learning Networks in Waste Management
by Tyrone Bright, Sarp Adali and Cristina Trois
Drones 2025, 9(8), 550; https://doi.org/10.3390/drones9080550 - 5 Aug 2025
Viewed by 158
Abstract
As the generation of Municipal Solid Waste (MSW) has exponentially increased, this poses a challenge for waste managers, such as municipalities, to effectively control waste streams. If waste streams are not managed correctly, they negatively contribute to climate change, marine plastic pollution and [...] Read more.
As the generation of Municipal Solid Waste (MSW) has exponentially increased, this poses a challenge for waste managers, such as municipalities, to effectively control waste streams. If waste streams are not managed correctly, they negatively contribute to climate change, marine plastic pollution and human health effects. Therefore, waste streams need to be identified, categorised and valorised to ensure that the most effective waste management strategy is employed. Research suggests that a more efficient process of identifying and categorising waste at the source can achieve this. Therefore, the aim of the paper is to identify the state of research of AI-powered drones in identifying and categorising waste. This paper will conduct a systematic review and meta-analysis on the application of drone technology integrated with image sensing technology and deep learning methods for waste management. Different systems are explored, and a quantitative meta-analysis of their performance metrics (such as the F1 score) is conducted to determine the best integration of technology. Therefore, the research proposes designing and developing a hybrid deep learning model with integrated architecture (YOLO-Transformer model) that can capture Multispectral imagery data from drones for waste stream identification, categorisation and potential valorisation for waste managers in small-scale environments. Full article
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16 pages, 6744 KiB  
Article
Thermochemical Conversion of Digestate Derived from OFMSW Anaerobic Digestion to Produce Methane-Rich Syngas with CO2 Sorption
by Emanuele Fanelli, Cesare Freda, Assunta Romanelli, Vito Valerio, Adolfo Le Pera, Miriam Sellaro, Giacinto Cornacchia and Giacobbe Braccio
Processes 2025, 13(8), 2451; https://doi.org/10.3390/pr13082451 - 2 Aug 2025
Viewed by 262
Abstract
The energetic valorization of digestate obtained from anaerobic digestion (AD) of the organic fraction of municipal solid waste (OFMSW) was investigated via pyrolysis in a bench-scale rotary kiln. The mass rate of dried digestate to the rotary kiln pyrolyzer was fixed at 500 [...] Read more.
The energetic valorization of digestate obtained from anaerobic digestion (AD) of the organic fraction of municipal solid waste (OFMSW) was investigated via pyrolysis in a bench-scale rotary kiln. The mass rate of dried digestate to the rotary kiln pyrolyzer was fixed at 500 gr/h. The effect of the pyrolysis temperature was investigated at 600, 700, and 800 °C. The pyrolysis products, char, oil, and gas, were quantified and chemically analyzed. It was observed that with the increase in the temperature from 600 to 800 °C, the char decreased from 60.3% to 52.2% and the gas increased from 26.5% to 35.3%. With the aim of increasing the methane production and methane concentration in syngas, the effect of CaO addition to the pyrolysis process was investigated at the same temperature, too. The mass ratio CaO/dried digestate was set at 0.2. The addition of CaO sorbent has a clear effect on the yield and composition of pyrolysis products. Under the experimental conditions, CaO was observed to act both as a CO2 sorbent and as a catalyst, promoting cracking and reforming reactions of volatile compounds. In more detail, at the investigated temperatures, a net reduction in CO2 concentration was observed in syngas, accompanied by an increase in CH4 concentration. The gas yield decreased with the CaO addition because of CO2 chemisorption. The oil yield decreased as well, probably because of the cracking and reforming effect of the CaO on the volatiles. A very promising performance of the CaO sorbent was observed at 600 °C; at this temperature, the CO2 concentration decreased from 32.2 to 13.9 mol %, and the methane concentration increased from 16.1 to 29.4 mol %. At the same temperature, the methane production increased from 34 to 63 g/kgdigestate. Full article
(This article belongs to the Section Chemical Processes and Systems)
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20 pages, 1509 KiB  
Article
Using Community-Based Social Marketing to Promote Pro-Environmental Behavior in Municipal Solid Waste Management: Evidence from Norte de Santander, Colombia
by Myriam Carmenza Sierra Puentes, Elkin Manuel Puerto-Rojas, Sharon Naomi Correa-Galindo and Jose Alejandro Aristizábal Cuellar
Environments 2025, 12(8), 262; https://doi.org/10.3390/environments12080262 - 30 Jul 2025
Viewed by 421
Abstract
The sustainable management of Municipal Solid Waste (MSW) relies heavily on community participation in separating it at the source and delivering it to collection systems. These practices are crucial for reducing pollution, protecting ecosystems, and maximizing resource recovery. However, in the Global South [...] Read more.
The sustainable management of Municipal Solid Waste (MSW) relies heavily on community participation in separating it at the source and delivering it to collection systems. These practices are crucial for reducing pollution, protecting ecosystems, and maximizing resource recovery. However, in the Global South context, with conditions of socioeconomic vulnerability, community participation in the sustainable management of MSW remains limited, highlighting the need to generate context-specific interventions. MSW includes items such as household appliances, batteries, and electronic devices, which require specialized handling due to their size, hazardous components, or material complexity. This study implemented a Community-Based Social Marketing approach during the research and design phases of an intervention focused on promoting source separation and management of hard-to-manage MSW in five municipalities within the administrative region of Norte de Santander (Colombia), which borders Venezuela. Using a mixed-methods approach, we collected data from 1775 individuals (63.83% women; M age = 33.48 years; SD = 17.25), employing social mapping, focus groups, semi-structured interviews, participant observation, and a survey questionnaire. The results show that the source separation and delivery of hard-to-manage MSW to collection systems are limited by a set of psychosocial, structural, and institutional barriers that interact with each other, affecting communities’ willingness and capacity for action. Furthermore, a prediction model of willingness to engage in separation and delivery behaviors showed a good fit (R2 = 0.83). The strongest predictors were awareness of the negative consequences of non-participation and perceived environmental benefits, with subjective norms contributing to a lesser extent. Based on these results, we designed a context-specific intervention focused on reducing these barriers and promoting community engagement in the sustainable management of hard-to-manage MSW. Full article
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22 pages, 642 KiB  
Article
Policy Tools, Policy Perception, and Compliance with Urban Waste Sorting Policies: Evidence from 34 Cities in China
by Yingqian Lin, Shuaikun Lu, Guanmao Yin and Baolong Yuan
Sustainability 2025, 17(15), 6787; https://doi.org/10.3390/su17156787 - 25 Jul 2025
Viewed by 370
Abstract
Promoting municipal solid waste (MSW) sorting is critical to advancing sustainable and low-carbon urban development. While existing research often focuses separately on external policy tools or internal behavioral drivers, limited attention has been given to their joint effects within an integrated framework. This [...] Read more.
Promoting municipal solid waste (MSW) sorting is critical to advancing sustainable and low-carbon urban development. While existing research often focuses separately on external policy tools or internal behavioral drivers, limited attention has been given to their joint effects within an integrated framework. This study addresses this gap by analyzing micro-survey data from 1983 residents across 34 prefecture-level and above cities in China, using a bivariate probit model to examine how policy tools and policy perception—both independently and interactively—shape residents’ active and passive compliance with MSW sorting policies. The findings reveal five key insights. First, the adoption and spatial distribution of policy tools are uneven: environment-type tools dominate, supply-type tools are moderately deployed, and demand-type tools are underutilized. Second, both policy tools and policy perception significantly promote compliance behaviors, with policy cognition exerting the strongest effect. Third, differential effects are observed—policy cognition primarily drives active compliance, whereas policy acceptance more strongly predicts passive compliance. Fourth, synergistic effects emerge when supply-type tools are combined with environment-type or demand-type tools. Finally, policy perception not only directly enhances compliance but also moderates the effectiveness of policy tools, with notable heterogeneity among residents with higher cognitive or emotional alignment. These findings contribute to a deeper understanding of compliance mechanisms and offer practical implications for designing perception-sensitive and regionally adaptive MSW governance strategies. Full article
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14 pages, 728 KiB  
Article
Groundwater Quality Analysis: Assessing the Impact of a Closed Landfill—A Case Study on Physico-Chemical and Microplastic Contaminants
by Grzegorz Przydatek, Józef Ciuła, Narcis Barsan, Diana Mirila and Emilian Mosnegutu
Appl. Sci. 2025, 15(15), 8223; https://doi.org/10.3390/app15158223 - 24 Jul 2025
Viewed by 313
Abstract
In the context of increasing concern over long-term environmental impacts of closed landfill sites, this study investigates the composition of groundwater and leachate at a municipal waste landfill in southwestern Poland, two decades after its closure. The research, conducted in 2023, aimed to [...] Read more.
In the context of increasing concern over long-term environmental impacts of closed landfill sites, this study investigates the composition of groundwater and leachate at a municipal waste landfill in southwestern Poland, two decades after its closure. The research, conducted in 2023, aimed to assess groundwater quality using 11 physico-chemical and 13 microplastic indicators. Groundwater and leachate samples were collected seasonally to assess of groundwater quality around landfill, including presence of heavy metals (Cd, Cr6+, Cu, Pb), PAHs and TOC, and microplastics. The results revealed persistent environmental degradation, with elevated concentrations of total organic carbon (24.8 mg/L) and cadmium (0.0211 mg/L), particularly in the second half of the year. Additionally, PET microplastics were detected in correlation with increased precipitation and leachate generation. These findings indicate that pollutants continue to migrate from the waste deposit into the surrounding groundwater, with seasonal patterns amplifying their presence. The study confirms that even decades after closure, municipal landfills can remain significant sources of both chemical and microplastic contamination, underlining the need for long-term monitoring and remediation strategies to protect groundwater resources. Full article
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49 pages, 4131 KiB  
Review
Municipal Solid Waste Gasification: Technologies, Process Parameters, and Sustainable Valorization of By-Products in a Circular Economy
by Nicoleta Ungureanu, Nicolae-Valentin Vlăduț, Sorin-Ștefan Biriș, Mariana Ionescu and Neluș-Evelin Gheorghiță
Sustainability 2025, 17(15), 6704; https://doi.org/10.3390/su17156704 - 23 Jul 2025
Viewed by 417
Abstract
Gasification of municipal solid waste and other biogenic residues (e.g., biomass and biowaste) is increasingly recognized as a promising thermochemical pathway for converting non-recyclable fractions into valuable energy carriers, with applications in electricity generation, district heating, hydrogen production, and synthetic fuels. This paper [...] Read more.
Gasification of municipal solid waste and other biogenic residues (e.g., biomass and biowaste) is increasingly recognized as a promising thermochemical pathway for converting non-recyclable fractions into valuable energy carriers, with applications in electricity generation, district heating, hydrogen production, and synthetic fuels. This paper provides a comprehensive analysis of major gasification technologies, including fixed bed, fluidized bed, entrained flow, plasma, supercritical water, microwave-assisted, high-temperature steam, and rotary kiln systems. Key aspects such as feedstock compatibility, operating parameters, technology readiness level, and integration within circular economy frameworks are critically evaluated. A comparative assessment of incineration and pyrolysis highlights the environmental and energetic advantages of gasification. The valorization pathways for main product (syngas) and by-products (syngas, ash, tar, and biochar) are also explored, emphasizing their reuse in environmental, agricultural, and industrial applications. Despite progress, large-scale adoption in Europe is constrained by economic, legislative, and technical barriers. Future research should prioritize scaling emerging systems, optimizing by-product recovery, and improving integration with carbon capture and circular energy infrastructures. Supported by recent European policy frameworks, gasification is positioned to play a key role in sustainable waste-to-energy strategies, biomass valorization, and the transition to a low-emission economy. Full article
(This article belongs to the Special Issue Sustainable Waste Process Engineering and Biomass Valorization)
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15 pages, 677 KiB  
Article
Zero-Shot Learning for Sustainable Municipal Waste Classification
by Dishant Mewada, Eoin Martino Grua, Ciaran Eising, Patrick Denny, Pepijn Van de Ven and Anthony Scanlan
Recycling 2025, 10(4), 144; https://doi.org/10.3390/recycling10040144 - 21 Jul 2025
Viewed by 310
Abstract
Automated waste classification is an essential step toward efficient recycling and waste management. Traditional deep learning models, such as convolutional neural networks, rely on extensive labeled datasets to achieve high accuracy. However, the annotation process is labor-intensive and time-consuming, limiting the scalability of [...] Read more.
Automated waste classification is an essential step toward efficient recycling and waste management. Traditional deep learning models, such as convolutional neural networks, rely on extensive labeled datasets to achieve high accuracy. However, the annotation process is labor-intensive and time-consuming, limiting the scalability of these approaches in real-world applications. Zero-shot learning is a machine learning paradigm that enables a model to recognize and classify objects it has never seen during training by leveraging semantic relationships and external knowledge sources. In this study, we investigate the potential of zero-shot learning for waste classification using two vision-language models: OWL-ViT and OpenCLIP. These models can classify waste without direct exposure to labeled examples by leveraging textual prompts. We apply this approach to the TrashNet dataset, which consists of images of municipal solid waste organized into six distinct categories: cardboard, glass, metal, paper, plastic, and trash. Our experimental results yield an average classification accuracy of 76.30% with Open Clip ViT-L/14-336 model, demonstrating the feasibility of zero-shot learning for waste classification while highlighting challenges in prompt sensitivity and class imbalance. Despite lower accuracy than CNN- and ViT-based classification models, zero-shot learning offers scalability and adaptability by enabling the classification of novel waste categories without retraining. This study underscores the potential of zero-shot learning in automated recycling systems, paving the way for more efficient, scalable, and annotation-free waste classification methodologies. Full article
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13 pages, 3049 KiB  
Article
Preparation of Foamed Ceramic from Cr Slag and MSWI Fly Ash and Its Cr Leaching Inhibition
by Hesong Li, Cheng Liu, Yikun Tang and Shilin Zhao
Materials 2025, 18(14), 3372; https://doi.org/10.3390/ma18143372 - 18 Jul 2025
Viewed by 241
Abstract
The sustainable utilization of solid waste is crucial for environmental protection. This work investigates the fabrication of foamed ceramics from Cr slag and municipal solid waste incineration (MSWI) fly ash, focusing on the effects of three inhibitors—NH2SO3H, ZnO·TiO2 [...] Read more.
The sustainable utilization of solid waste is crucial for environmental protection. This work investigates the fabrication of foamed ceramics from Cr slag and municipal solid waste incineration (MSWI) fly ash, focusing on the effects of three inhibitors—NH2SO3H, ZnO·TiO2, and (NH4)2HPO4—on material properties and Cr leaching behavior. Experimental analysis, chemical thermodynamic calculations, and material characterization were all employed. Results show that the prepared foamed ceramics meet the JG/T 511-2017 standard for building materials, exhibiting excellent physical properties but significant Cr leaching. Among the inhibitors, (NH4)2HPO4 with a molar ratio of n(P)/n(Cr) = 1 shows the best performance, achieving a bulk density of 205 kg/m3, compressive strength of 0.850 MPa, Cr leaching concentration of 188 μg/L, and a 70.0% of Cr leaching inhibition rate. The improvement is attributed to the AlPO4 formation that enhancing the strength, and Ca2P2O7 that stabilizing Cr during sintering. This work provides a feasible method for the safe resource utilization of Cr-containing waste. Full article
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13 pages, 4134 KiB  
Article
Use of Biodried Organic Waste as a Soil Amendment: Positive Effects on Germination and Growth of Lettuce (Lactuca sativa L., var. Buttercrunch) as a Model Crop
by Rosa María Contreras-Cisneros, Fabián Robles-Martínez, Marina Olivia Franco-Hernández and Ana Belem Piña-Guzmán
Processes 2025, 13(7), 2285; https://doi.org/10.3390/pr13072285 - 17 Jul 2025
Viewed by 309
Abstract
Biodrying and composting are aerobic processes to treat and stabilize organic solid waste, but biodrying involves a shorter process time and does not require the addition of water. The resulting biodried material (BM) is mainly used as an energy source in cement production [...] Read more.
Biodrying and composting are aerobic processes to treat and stabilize organic solid waste, but biodrying involves a shorter process time and does not require the addition of water. The resulting biodried material (BM) is mainly used as an energy source in cement production or in municipal solid waste incineration with energy recovery, but when obtained from agricultural or agroindustrial organic waste, it could also be used as a soil amendment, such as compost (CO). In this study, the phytotoxicity of BM compared to CO, both made from organic wastes (orange peel, mulch and grass), was evaluated on seed germination and growth (for 90 days) of lettuce (Lactuca sativa L.) seedlings on treatments prepared from mixtures of BM and soil, soil (100%) and a mixture of CO and soil. The germination index (GI%) was higher for BM extracts (200 g/L) than for CO extracts (68% vs. 53%, respectively). According to their dry weight, lettuce grew more on the CO mixture (16.5 g) than on the BM (5.4–7.4 g), but both materials far exceeded the soil values (0.15 g). The absence of phytotoxicity suggests that BM acts as a soil amendment, improving soil structure and providing nutrients to the soil. Therefore, biodrying is a quick and low-cost bioprocess to obtain a soil improver. Full article
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19 pages, 1165 KiB  
Article
Expansion of Mechanical Biological Residual Treatment Plant with Fermentation Stage for Press Water from Organic Fractions Involving a Screw Press
by Rzgar Bewani, Abdallah Nassour, Thomas Böning, Jan Sprafke and Michael Nelles
Recycling 2025, 10(4), 141; https://doi.org/10.3390/recycling10040141 - 16 Jul 2025
Viewed by 285
Abstract
A three-year optimization study was conducted at a mechanical biological treatment plant with the aim of enhancing organic fractions recovery from mechanically separated fine fractions (MSFF) of residual waste using a screw press. The study aimed to optimize key operating parameters for the [...] Read more.
A three-year optimization study was conducted at a mechanical biological treatment plant with the aim of enhancing organic fractions recovery from mechanically separated fine fractions (MSFF) of residual waste using a screw press. The study aimed to optimize key operating parameters for the employed screw press, such as pressure, liquid-to-MSFF, feeding quantity per hour, and press basket mesh size, to enhance volatile solids and biogas recovery in the generated press water for anaerobic digestion. Experiments were performed at the full-scale facility to evaluate the efficiency of screw press extraction with other pretreatment methods, like press extrusion, wet pulping, and hydrothermal treatment. The results indicated that hydrolysis of the organic fractions in MSFF was the most important factor for improving organic extraction from the MSFF to press water for fermentation. Optimal hydrolysis efficiency was achieved with a digestate and process water-to-MSFF of approximately 1000 L/ton, with a feeding rate between 8.8 and 14 tons per hour. Increasing pressure from 2.5 to 4.0 bar had minimal impact on press water properties or biogas production, regardless of the press basket size. The highest volatile solids (29%) and biogas (50%) recovery occurred at 4.0 bar pressure with a 1000 L/ton liquid-to-MSFF. Further improvements could be achieved with longer mixing times before pressing. These findings demonstrate the technical feasibility of the pressing system for preparing an appropriate substrate for the fermentation process, underscoring the potential for optimizing the system. However, further research is required to assess the cost–benefit balance. Full article
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16 pages, 3177 KiB  
Article
Cadmium as the Critical Limiting Factor in the Co-Disposal of Municipal Solid Waste Incineration Fly Ash in Cement Kilns: Implications for Three-Stage Water Washing Efficiency and Safe Dosage Control
by Zhonggen Li, Qingfeng Wang, Li Tang, Liangliang Yang and Guangyi Sun
Toxics 2025, 13(7), 593; https://doi.org/10.3390/toxics13070593 - 15 Jul 2025
Viewed by 373
Abstract
The co-disposal of municipal solid waste incineration fly ash (MSWI-FA) in cement kilns is an effective method for managing incineration by-products in China. However, the presence of heavy metals in MSWI-FA raises environmental concerns. This study analyzed the Cu, Zn, Cd, Pb, Cr, [...] Read more.
The co-disposal of municipal solid waste incineration fly ash (MSWI-FA) in cement kilns is an effective method for managing incineration by-products in China. However, the presence of heavy metals in MSWI-FA raises environmental concerns. This study analyzed the Cu, Zn, Cd, Pb, Cr, and Ni concentrations in MSWI-FA from 11 representative facilities across China and assessed the efficacy of a three-stage water washing process for Cl and heavy metal removal. The results revealed significant regional variations in heavy metal content that were strongly correlated with surface soil levels, with Zn, Pb, and Cu exhibiting the highest concentrations. Elemental correlations, such as Cu-Pb and Zn-Cd synergies and Cd-Ni antagonism, suggest common waste sources and temperature-dependent volatilization during incineration. The washing process (solid–liquid ratio = 1:10) achieved 97.1 ± 2.0% Cl removal, reducing residual Cl to 0.45 ± 0.32%, but demonstrated limited heavy metal elimination (10.28–19.38% efficiency), resulting in elevated concentrations (32.5–60.8% increase) due to 43.4 ± 9.2% mass loss. Notably, the washing effluents exceeded municipal wastewater discharge limits by up to 52-fold for Pb and 38-fold for Cd, underscoring the need for advanced effluent treatment. To mitigate environmental risks, the addition of washed MSWI-FA in cement kilns should be restricted to ≤0.5%, with Cd content prioritized in pre-disposal assessments. This study provides actionable insights for optimizing MSWI-FA co-processing while ensuring compliance with ecological safety standards. Full article
(This article belongs to the Special Issue Distribution and Behavior of Trace Metals in the Environment)
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29 pages, 27846 KiB  
Review
Recycling and Mineral Evolution of Multi-Industrial Solid Waste in Green and Low-Carbon Cement: A Review
by Zishu Yue and Wei Zhang
Minerals 2025, 15(7), 740; https://doi.org/10.3390/min15070740 - 15 Jul 2025
Viewed by 275
Abstract
The accelerated industrialization in China has precipitated a dramatic surge in solid waste generation, causing severe land resource depletion and posing substantial environmental contamination risks. Simultaneously, the cement industry has become characterized by the intensive consumption of natural resources and high carbon emissions. [...] Read more.
The accelerated industrialization in China has precipitated a dramatic surge in solid waste generation, causing severe land resource depletion and posing substantial environmental contamination risks. Simultaneously, the cement industry has become characterized by the intensive consumption of natural resources and high carbon emissions. This review aims to investigate the current technological advances in utilizing industrial solid waste for cement production, with a focus on promoting resource recycling, phase transformations during hydration, and environmental management. The feasibility of incorporating coal-based solid waste, metallurgical slags, tailings, industrial byproduct gypsum, and municipal solid waste incineration into active mixed material for cement is discussed. This waste is utilized by replacing conventional raw materials or serving as active mixed material due to their content of oxygenated salt minerals and oxide minerals. The results indicate that the formation of hydration products can be increased, the mechanical strength of cement can be improved, and a notable reduction in CO2 emissions can be achieved through the appropriate selection and proportioning of mineral components in industrial solid waste. Further research is recommended to explore the synergistic effects of multi-waste combinations and to develop economically efficient pretreatment methods, with an emphasis on balancing the strength, durability, and environmental performance of cement. This study provides practical insights into the environmentally friendly and efficient recycling of industrial solid waste and supports the realization of carbon peak and carbon neutrality goals. Full article
(This article belongs to the Section Mineral Processing and Extractive Metallurgy)
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17 pages, 1651 KiB  
Article
Compositional Analysis of Municipal Solid Waste from Tshwane Metropolitan Landfill Sites in South Africa for Potential Sustainable Management Strategies
by Khanyisile Lepota, Kasturie Premlall and Major Mabuza
Waste 2025, 3(3), 22; https://doi.org/10.3390/waste3030022 - 15 Jul 2025
Viewed by 376
Abstract
The modern world has brought extensive socioeconomic and ecological changes. Urbanization in developing nations has significantly increased municipal solid waste, necessitating in-depth understanding of waste composition particularly in developing nations for sustainable management practices. This study aimed to classify and characterize waste while [...] Read more.
The modern world has brought extensive socioeconomic and ecological changes. Urbanization in developing nations has significantly increased municipal solid waste, necessitating in-depth understanding of waste composition particularly in developing nations for sustainable management practices. This study aimed to classify and characterize waste while evaluating potential waste management methods. Mixed methods were used to examine landfilled waste from Soshanguve and Hatherley sites in Tshwane Metropolitan, South Africa, using techniques such as Fourier transform infrared spectroscopy, X-ray fluorescence, proximate, and ultimate analysis. Seasonal variations in waste components were analysed over two seasons. The study identified that both sites are predominantly composed of organic waste, accounting for over 42 wt.%, with moisture content of ~50 wt.%, and minimal recyclables (<5 wt.%). Seasonal variations in MSW were significant for glass (<4% increase), organic waste (<5% increase), while plastic decreased by ~7% during spring. The biodegradable waste showed high carbon (>50%) and oxygen (>40%) levels, low ash content (<18%), and calorific values of 15–19 MJ/kg. Biodegradables mainly contained oxides of calcium, silicon, iron (III), and potassium with chemical composition indicating functional groups that emphasize composting and energy recovery benefits. The research provides insights into sustainable waste management, revealing waste composition at Tshwane landfills, aiding informed decision-making for resource usage and environmental conservation. Full article
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22 pages, 1279 KiB  
Review
State of the Art of Biomethane Production in the Mediterranean Region
by Antonio Comparetti, Salvatore Ciulla, Carlo Greco, Francesco Santoro and Santo Orlando
Agronomy 2025, 15(7), 1702; https://doi.org/10.3390/agronomy15071702 - 15 Jul 2025
Viewed by 394
Abstract
The Mediterranean region is increasingly confronted with intersecting environmental, agricultural, and socio-economic challenges, including biowaste accumulation, soil degradation, and high dependency on imported fossil fuels. Biomethane, a renewable substitute for natural gas, offers a strategic solution that aligns with the region’s need for [...] Read more.
The Mediterranean region is increasingly confronted with intersecting environmental, agricultural, and socio-economic challenges, including biowaste accumulation, soil degradation, and high dependency on imported fossil fuels. Biomethane, a renewable substitute for natural gas, offers a strategic solution that aligns with the region’s need for sustainable energy transition and circular resource management. This review examines the current state of biomethane production in the Mediterranean area, with a focus on anaerobic digestion (AD) technologies, feedstock availability, policy drivers, and integration into the circular bioeconomy (CBE) framework. Emphasis is placed on the valorisation of regionally abundant feedstocks such as olive pomace, citrus peel, grape marc, cactus pear (Opuntia ficus-indica) residues, livestock manure, and the Organic Fraction of Municipal Solid Waste (OFMSW). The multifunctionality of AD—producing renewable energy and nutrient-rich digestate—is highlighted for its dual role in reducing greenhouse gas (GHG) emissions and restoring soil health, especially in areas threatened by desertification such as Sicily (Italy), Spain, Malta, and Greece. The review also explores emerging innovations in biogas upgrading, nutrient recovery, and digital monitoring, along with the role of Renewable Energy Directive III (RED III) and national biomethane strategies in scaling up deployment. Case studies and decentralised implementation models underscore the socio-technical feasibility of biomethane systems across rural and insular territories. Despite significant potential, barriers such as feedstock variability, infrastructural gaps, and policy fragmentation remain. The paper concludes with a roadmap for research and policy to advance biomethane as a pillar of Mediterranean climate resilience, energy autonomy and sustainable agriculture within a circular bioeconomy paradigm. Full article
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12 pages, 5245 KiB  
Article
Evaluation of Fly Ash Composition from Municipal Solid Waste Incinerators: The Role of the Incinerator Type and Flue Gas Deacidification Process
by Xuetong Qu, Yanan Wang, Feifei Chen, Chuqiao Li, Yunfei He, Jibo Dou, Shuai Zhang, Jiafeng Ding, Hangjun Zhang and Yuchi Zhong
Toxics 2025, 13(7), 588; https://doi.org/10.3390/toxics13070588 - 14 Jul 2025
Viewed by 321
Abstract
The resource utilization potential and environmental impact of fly ash from municipal solid waste incinerators (MSWIs) have attracted wide attention. In this study, four MSWIs in Hangzhou, Zhejiang Province were selected to systematically evaluate the effects of different incinerator types and flue gas [...] Read more.
The resource utilization potential and environmental impact of fly ash from municipal solid waste incinerators (MSWIs) have attracted wide attention. In this study, four MSWIs in Hangzhou, Zhejiang Province were selected to systematically evaluate the effects of different incinerator types and flue gas deacidification processes on fly ash’s oxide and heavy metal components and their temporal changes as well as conduct risk assessment. The results showed that the contents of MgO, Al2O3, SiO2, and Fe2O3 in the grate furnace fly ash were significantly lower than those in the fluidized bed fly ash, but the compressive strength of its fly ash was high. Chemicals added during the flue gas deacidification process such as CaO and NaHCO3 significantly affected the contents of CaO and Na2O. In addition, heavy metals such as Cu, Mn, Cr, and Ni were mainly distributed in the fluidized bed fly ash, while heavy metals such as Pb and Cd were mainly collected in the grate furnace fly ash. The concentrations of various components in the fly ash fluctuated but were not significant under different time dimensions. Risk assessment indicated that heavy metals such as Cd, Pb, and Sb posed a high risk. This study is expected to provide theoretical support for the safe management and resource utilization of fly ash. Full article
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