Search Results (13)

Polyols derived from poly(vinyl alcohol) (PVA) have not been reported before. The hydroxyalkylation of PVA with oxiranes leads to powdered or gum-like products that are not miscible with isocyanates and therefore useless as sources of polyurethane foams. Glycidol and ethylene carbonates were used to dissolve and convert PVA into liquid polyol. The physical properties of the PVA-derived polyol, such as the density, viscosity, and surface tension, were determined. The polyol was then used to obtain rigid polyurethane foams (PUFs). Foaming conditions were optimized, and the apparent density, volume water uptake, dimensional stability, heat conductance coefficient, pore size, thermal resistance, compressive strength, and glass transition temperature of the obtained PUFs were determined. The properties of the obtained PUFs were similar to those of classic rigid PUFs, but the thermal resistance of the former is better. Specifically, PVA-derived PUFs are thermally resistant at temperatures of up to 150 °C. Furthermore, they are ecologically safe; in standard soil conditions, 54.6% or 100% biodegradation of the foams in cube and powder form, respectively, was observed, as measured by BOD after 28 days of storage. Full article

In this paper, the geometric effect on flow structure and mixing performance of two miscible fluids (deionized water and glycerol) in a planetary centrifugal mixer (PCM) during the spin-up is numerically evaluated, using the OpenFOAM interMixingFoam solver. Six different aspect ratios, specifically 0.5, 1, 1.25, 1.5, 2, and 2.5, are considered. The flow structure in each geometric configuration is illustrated by the liquid interface and vorticity isosurface represented by the Q criterion, while the mixing performance is evaluated in terms of a mixing index $MI$. As the aspect ratio increases from small to large, $MI$ first increases and then decreases. The peak $MI$ at the end of spin-up reaches 0.196 for the aspect ratio of 1.25, rather than the other five aspect ratios in our study. The mechanism analysis shows that under an aspect ratio of 1.25, the vortex structure is most violently dissipated, the interface collapse degree is the largest, and the low-velocity region volume is the smallest, which enhances the chaotic convection mixing. Full article

This paper focuses on the current application of machine learning (ML) in enhanced oil recovery (EOR) through CO₂ injection, which exhibits promising economic and environmental benefits for climate-change mitigation strategies. Our comprehensive review explores the diverse use cases of ML techniques in CO₂-EOR, including aspects such as minimum miscible pressure (MMP) prediction, well location optimization, oil production and recovery factor prediction, multi-objective optimization, Pressure–Volume–Temperature (PVT) property estimation, Water Alternating Gas (WAG) analysis, and CO₂-foam EOR, from 101 reviewed papers. We catalog relative information, including the input parameters, objectives, data sources, train/test/validate information, results, evaluation, and rating score for each area based on criteria such as data quality, ML-building process, and the analysis of results. We also briefly summarized the benefits and limitations of ML methods in petroleum industry applications. Our detailed and extensive study could serve as an invaluable reference for employing ML techniques in the petroleum industry. Based on the review, we found that ML techniques offer great potential in solving problems in the majority of CO₂-EOR areas involving prediction and regression. With the generation of massive amounts of data in the everyday oil and gas industry, machine learning techniques can provide efficient and reliable preliminary results for the industry. Full article

Expanded polystyrene will account for 5.3% of total global plastic production in 2021 and is widely used for food packaging due to its excellent moisture resistance and thermal insulation. However, some of these packages are often used only once before being discarded, generating large amounts of environmentally harmful plastic waste. A very attractive alternative to the conventional methods used for polymer processing is the use of supercritical carbon dioxide (scCO₂) since it has mass-transfer properties adapted to the foam morphology, generating different path lengths for the diffusion of active compounds within its structure and can dissolve a wide range of organic molecules under supercritical conditions. The objective of this research was to evaluate the effect of operational variables on the process of caffeic acid (CA) impregnation and subsequent foaming of polylactic acid (PLA) as well as two PLA/poly(butylene-co-terephthalate-adipate) (PBAT) blends using scCO₂. The results showed an increase in the degree of crystallinity of the CA-impregnated samples due to the nucleation effect of the active compound. On the other hand, SEM micrographs of both films and foams showed significant differences due to the presence of PBAT and its low miscibility with PLA. Finally, the results obtained in this work contribute to the knowledge of the important parameters to consider for the implementation of the impregnation and foaming process of PLA and PLA/PBAT blends with potential use in food packaging. Full article

CO₂ foam injection has been shown to be effective under reservoir conditions for enhanced oil recovery. However, its application requires a certain stability and surfactant absorbability on rock surface, and it is also associated with borehole corrosion in the presence of water. Adding surfactants to CO₂ can enhance the interaction between CO₂ and crude oil and control the CO₂ mobility, thereby improving the performance of CO₂ flooding. This paper presents a review of the research of CO₂-soluble surfactants and their applications. Molecular dynamics simulation is introduced as a tool for analyzing the behavior of the surfactants in supercritical CO₂ (scCO₂). The applications of CO₂-soluble surfactants, including CO₂ thickening, reducing miscibility pressure, and generating supercritical CO₂ foam, are discussed in detail. Moreover, some opportunities for the research and development of CO₂-soluble surfactants are proposed. Full article

Polyethersulfone (PESU), as both a pristine polymer and a component of a blend, can be used to obtain highly porous foams through batch foaming. However, batch foaming is limited to a small scale and is a slow process. In our study, we used foam extrusion due to its capacity for large-scale continuous production and deployed carbon dioxide (CO₂) and water as physical foaming agents. PESU is a high-temperature thermoplastic polymer that requires processing temperatures of at least 320 °C. To lower the processing temperature and obtain foams with higher porosity, we produced PESU/poly(ethylene glycol) (PEG) blends using material penetration. In this way, without the use of organic solvents or a compounding extruder, a partially miscible PESU/PEG blend was prepared. The thermal and rheological properties of homopolymers and blends were characterized and the CO₂ sorption performance of selected blends was evaluated. By using these blends, we were able to significantly reduce the processing temperature required for the extrusion foaming process by approximately 100 °C without changing the duration of processing. This is a significant advancement that makes this process more energy-efficient and sustainable. Additionally, the effects of blend composition, nozzle temperature and foaming agent type were investigated, and we found that higher concentrations of PEG, lower nozzle temperatures, and a combination of CO₂ and water as the foaming agent delivered high porosity. The optimum blend process settings provided foams with a porosity of approximately 51% and an average foam cell diameter of 5 µm, which is the lowest yet reported for extruded polymer foams according to the literature. Full article

In this work, poly (vinylidene fluoride) (PVDF) hierarchically porous membranes (HPMs) with isolated large pores and continuous narrow nano-pores have been fabricated from its blend with poly (methyl methacrylate) (PMMA) based on the combination of crystallization template with chemical or supercritical CO₂ foaming. On the one hand, the decomposition of azodicarbonamide (ADC, chemical foaming agent) or the release of CO₂ can produce isolated large pores. On the other hand, PMMA is expelled during the isothermal crystallization of PVDF in their miscible blend, yielding narrow nano-pores upon etching with a selective solvent. In the case of supercritical CO₂, the attained PVDF HPMs fail to improve separation performance because of the compact wall of isolated-large-pore and consequent poor connectivity of hierarchical pores. In the case of ADC, the optimal HPM exhibits much higher flux (up to 20 times) without any loss of selectivity compared with the reference only with nano-pores. The enhanced permeability can be attributed to the shorter diffusion length and lower diffusion barrier from isolated large pores, while the comparable selectivity is determined by narrow nano-pores in THE matrix. Full article

The displacement of one fluid by another is an important process, not only in industrial and environmental fields, such as chromatography, enhanced oil recovery, and CO₂ sequestration, but also material processing, such as Lost Foam Casting. Even during hydrodynamically stable fluid displacement where a more viscous fluid displaces a less viscous fluid in porous media or in Hele-Shaw cells, the growing interface fluctuates slightly. This fluctuation is attributed to thermodynamic conditions, which can be categorized as the following systems: fully miscible, partially miscible, and immiscible. The dynamics of these three systems differ significantly. Here, we analyze interfacial fluctuations under the three systems using Family–Vicsek scaling and calculate the scaling indexes. We discovered that the roughness exponent, $\alpha$, and growth exponent, $\beta$, of the partially miscible case are larger than those of the immiscible and fully miscible cases due to the effects of the Korteweg convection as induced during phase separation. Moreover, it is confirmed that fluctuations in all systems with steady values of $\alpha$ and $\beta$ are represented as a single curve, which implies that accurate predictions for the growing interface with fluctuations in Hele-Shaw flows can be accomplished at any scale and time, regardless of the miscibility conditions. Full article

Biopolymer foams manufactured using CO₂ enables a novel intersection for economic, environmental, and ecological impact but limited CO₂ solubility remains a challenge. PHBV has low solubility in CO₂ while PCL has high CO₂ solubility. In this paper, PCL is used to blend into PBHV. Both unfoamed and foamed blends are examined. Foaming the binary blends at two depressurization stages with subcritical CO₂ as the blowing agent, produced open-cell and closed-cell foams with varying cellular architecture at different PHBV concentrations. Differential Scanning Calorimetry results showed that PHBV had some solubility in PCL and foams developed a PCL rich, PHBV rich and mixed phase. Scanning Electron Microscopy and pcynometry established cell size and density which reflected benefits of PCL presence. Acoustic performance showed limited benefits from foaming but mechanical performance of foams showed a significant impact from PHBV presence in PCL. Thermal performance reflected that foams were affected by the blend thermal conductivity, but the impact was significantly higher in the foams than in the unfoamed blends. The results provide a pathway to multifunctional performance in foams of high performance biopolymers such as PBHV through harnessing the CO₂ miscibility of PCL. Full article

Unlocking oil from tight reservoirs remains a challenging task, as the existence of fractures and oil-wet rock surfaces tends to make the recovery uneconomic. Injecting a gas in the form of a foam is considered a feasible technique in such reservoirs for providing conformance control and reducing gas-oil interfacial tension (IFT) that allows the injected fluids to enter the rock matrix. This paper presents a modeling strategy that aims to understand the behavior of near-miscible foam injection and to find the optimal strategy to oil recovery depending on the reservoir pressure and gas availability. Corefloods with foam injection following gas injection into a fractured rock were simulated and history matched using a compositional commercial simulator. The simulation results agreed with the experimental data with respect to both oil recovery and pressure gradient during both injection schedules. Additional simulations were carried out by increasing the foam strength and changing the injected gas composition. It was found that increasing foam strength or the proportion of ethane could boost oil production rate significantly. When injected gas gets miscible or near miscible, the foam model would face serious challenges, as gas and oil phases could not be distinguished by the simulator, while they have essentially different effects on the presence and strength of foam in terms of modeling. We provide in-depth thoughts and discussions on potential ways to improve current foam models to account for miscible and near-miscible conditions. Full article

Polylactide foaming materials with promising biocompatibility balance the lightweight and mechanical properties well, and thus they can be desirable candidates for biological scaffolds used in tissue engineering. However, the cells are likely to coalesce and collapse during the foaming process of polylactide (PLA) due to its intrinsic low melt strength. This work introduces a unique PLA stereocomplexation into the microcellular foaming of poly (l-lactide)/poly (butylene succinate) (PLLA/PBS) based on supercritical carbon dioxide. The rheological properties of PLA/PBS with 5 wt% or 10 wt% poly (d-lactide) (PDLA) present enhanced melt strength owing to the formation of PLA stereocomplex crystals (sc-PLA), which act as physical pseudo-cross-link points in the molten blends by virtue of the strong intermolecular interaction between PLLA and the added PDLA. Notably, the introduction of either PBS or PDLA into the PLLA matrix could enhance its crystallization, while introducing both in the blend triggers a decreasing trend in the PLA crystallinity, which it is believed occurs due to the constrained molecular chain mobility by formed sc-PLA. Nevertheless, the enhanced melt strength and decreased crystallinity of PLA/PBS/PDLA blends are favorable for the microcellular foaming behavior, which enhanced the cell stability and provided amorphous regions for gas adsorption and homogeneous nucleation of PLLA cells, respectively. Furthermore, although the microstructure of PLA/PBS presents immiscible sea-island morphology, the miscibility was improved while the PBS domains were also refined by the introduction of PDLA. Overall, with the addition of PDLA into PLA/10PBS blends, the microcellular average cell size decreased from 3.21 to 0.66 μm with highest cell density of 2.23 × 10¹⁰ cells cm⁻³ achieved, confirming a stable growth of cells was achieved and more cell nucleation sites were initiated on the heterogeneous interface. Full article

Nanoparticles have gained attention for increasing the stability of surfactant-based foams during CO₂ foam-enhanced oil recovery (EOR) and CO₂ storage. However, the behavior and displacement mechanisms of hybrid nanoparticle–surfactant foam formulations at reservoir conditions are not well understood. This work presents a pore- to core-scale characterization of hybrid nanoparticle–surfactant foaming solutions for CO₂ EOR and the associated CO₂ storage. The primary objective was to identify the dominant foam generation mechanisms and determine the role of nanoparticles for stabilizing CO₂ foam and reducing CO₂ mobility. In addition, we shed light on the influence of oil on foam generation and stability. We present pore- and core-scale experimental results, in the absence and presence of oil, comparing the hybrid foaming solution to foam stabilized by only surfactants or nanoparticles. Snap-off was identified as the primary foam generation mechanism in high-pressure micromodels with secondary foam generation by leave behind. During continuous CO₂ injection, gas channels developed through the foam and the texture coarsened. In the absence of oil, including nanoparticles in the surfactant-laden foaming solutions did not result in a more stable foam or clearly affect the apparent viscosity of the foam. Foaming solutions containing only nanoparticles generated little to no foam, highlighting the dominance of surfactant as the main foam generator. In addition, foam generation and strength were not sensitive to nanoparticle concentration when used together with the selected surfactant. In experiments with oil at miscible conditions, foam was readily generated using all the tested foaming solutions. Core-scale foam-apparent viscosities with oil were nearly three times as high as experiments without oil present due to the development of stable oil/water emulsions and their combined effect with foam for reducing CO₂ mobility Full article

The incorporation of new equations to extend the applicability of open-source computational fluid dynamics (CFD) software according to the user’s needs must be complemented with code verification and validation with a representative case. This paper presents the development and validation of an OpenFOAM^®-based solver suitable for simulating multiphase fluid flow considering three fluid phases with different densities and temperatures, i.e., two miscible liquids and air. A benchmark “dam-break” experiment was performed to validate the solver. Ten thermistors measured temperature variations in different locations of the experimental model and the temperature time series were compared against those of numerical probes in analogous locations. The accuracy of the temperature field assessment considered three different turbulence models: (a) zero-equation, (b) k-omega (Reynolds averaged simulation; RAS), and (c) large eddy simulation (LES). The simulations exhibit a maximum time-average relative and absolute errors of 9.3% and 3.1 K, respectively; thus, the validation tests proved to achieve an adequate performance of the numerical model. The solver developed can be applied in the modeling of thermal discharges into water bodies. Full article