Search Results (6)

The growing need for effective air pollution control technologies has prompted significant interest in innovative flue gas treatment methods. This study investigates the plasma–chemical mechanisms and pollutant abatement performance of a pilot-scale microwave-assisted plasma reactor operating at 915 MHz and up to 75 kW for simultaneous removal of sulfur dioxide (SO₂), nitrogen oxides (NO_x), and carbon dioxide (CO₂) from combustion flue gas. Plasma treatment induced radical-driven oxidation of nitric oxide (NO), substantially enhancing the aqueous solubility of nitrogen oxides and thereby improving ammonia scrubbing efficiency. However, excessive plasma power resulted in thermal NO_x formation, governed by local gas temperature, highlighting the critical need for optimized specific energy input. A logarithmic correlation between plasma power and NO_x concentration was derived, enabling estimation of power thresholds necessary to suppress thermal NO formation. Complete or near-complete SO₂ removal and high CO₂ capture efficiency (50–100%) were achieved, demonstrating the synergistic coupling of plasma activation with alkaline scrubbing. These findings demonstrate the viability of microwave-assisted plasma technology as a flexible and efficient solution for integrated flue gas pollutant control with potential for industrial-scale deployment in coal-fired power plants and other combustion facilities. Full article

This study explored methods used to improve the ignition efficiency of a microwave radiation igniter; experimental analyses were conducted to characterize the device’s performance in a model combustion chamber. High-speed imaging combined with an image intensifier tracked flame kernel formation and propagation dynamics under varying airflow rates, residual gas coefficients, and microwave pulse parameters. The results demonstrate that increased airflow rates reduced the relative decline in ignition delay time under microwave application, with the flame area growth curve exhibiting a steeper slope compared to non-microwave conditions. Elevated residual gas coefficients enhanced the microwave-induced reduction in ignition delay time, though this effect weakened significantly in fuel-rich environments. Additionally, higher microwave pulse frequencies and peak power levels both contributed to shorter ignition delay times; the delay decreased linearly with the rising pulse frequency and followed a power-dependent reduction trend. These findings systematically quantify the synergistic effects of flow dynamics, residual gases, and microwave parameters on ignition performance. Full article

Hydrothermal treatment (HTT) offers the potential to upgrade low-value biomass such as digestate (DG) or forest residue (FR) by producing solids and liquids for material use or energetic utilization. In this study, microwave-assisted HTT experiments with DG and FR as feedstocks were executed at different temperatures (130, 150, 170 °C) and with different holding times (30, 60, 90 min) to determine the influences on product properties (ash and elemental concentrations, calorific values and chemical compounds). In general, DG and FR reacted differently to HTT. For the DG solids, for instance, the ash concentration was reduced to 8.68%_DM at 130 °C (initially 27.67%_DM), and the higher heating value increased from 16.55 MJ/kg_DM to 20.82 MJ/kg_DM at 170 °C, while the FR solids were affected only marginally. Elements with importance for emissions in combustion were leached out in both HTT solids. The DG and FR liquids contained different chemical compounds, and the temperature or holding time affected their formation. Depending on the designated application of HTT, less severe conditions can deliver better results. It was demonstrated that different low-temperature HTT conditions already induce strong changes in the product qualities of DG and FR. Optimized interactions between process parameters (temperature, holding time and feedstock) might lead to better cost–benefit effects in HTT. Full article

Microwave-assisted solid sampling analysis coupled to flame furnace atomic absorption spectrometry (MW-SS-FF-AAS) was used for Cd and Pb determination in food-contact polymer samples, with the aim of minimizing reagents and laboratory waste. Operational parameters, such as the FF tube design, the oxygen flow rate, the flame stoichiometry, the sample mass, among others, were evaluated and optimized. Calibration was performed using only reference solutions, and the limits of quantification were 1.7 and 4.6 μg g⁻¹ for Cd and Pb, respectively. Accuracy was assessed by the analysis of certified reference materials (CRMs), and by comparison with the results obtained by inductively coupled plasma mass spectrometry after microwave-assisted wet digestion. The MW-SS-FF-AAS results for the CRMs showed no statistical difference with the certified values, and good agreement was observed with the results of the digestion method. The MW-SS-FF-AAS method was considered suitable for Cd and Pb determination in food-contact polymers. The concentrations of Cd and Pb in the analyzed samples varied from <1.7 to 628 μg g⁻¹, and from <4.6 to 614 μg g⁻¹, respectively. As sample digestion is not necessary, the use of concentrated acids can be avoided by using the proposed MW-SS-FF-AAS method, greatly reducing waste generation. Full article

Microwave-assisted spark ignition (MAI) is a promising way to enhance the ignition performance of engines under lean conditions. To understand the effect of microwave-induced flow during MAI, the development and morphology of spark-ignited methane-air flame kernel under various microwave pulse parameters are experimentally studied. Experiments are conducted in a constant volume combustion chamber, and flame development is recorded through a high-speed shadowgraph method. Flame area and deformation index are adopted to evaluate the flame characteristic. Results show that increasing the microwave pulse energy from 0 to 150 mJ exhibits a threshold process for expanding the flame kernel area under 0.2 MPa ambient pressure. When the pulse energy is below the threshold of 90 mJ, the microwave enhancing efficiency is much lower than that beyond the threshold. Increasing microwave pulse repetition frequency (PRF) changes the flow on flame surface and raises the absorption efficiency for microwave energy, and thus helps to improve the MAI performance under higher pressures. Hence, 1 kHz pulses cause more obvious flame deformation than those with higher PRF pulses under 0.2 MPa, while this tendency is reversed as the ambient pressure increases to 0.6 MPa. Besides, microwave pulses of different repetition frequencies lead to different flame kernel morphology, implying the various regimes behind the interaction between a microwave and spark kernel. Full article

Three series of binary metal oxide catalysts containing Ni, Cu, or Co oxides were prepared, fully characterized and tested in CO oxidation. The catalysts, with a constant transition metal loading of 10 wt%, were prepared from metal nitrates and urea mixtures by a microwave-assisted solution combustion method. The RV/OV ratio, corresponding to the stoichiometry of the reactants, calculated from their elemental oxidizing and reducing valences, was varied. In order to modify the redox character of the synthesis medium from the quantity of urea; an excess of urea was used for attaining reducing conditions, while a deficit of urea shifted the medium to oxidizing conditions. Three RV/OV ratios (0.9, 1.0, and 1.1) were selected to elaborate the different binary metal oxide catalysts, nine oxide catalysts were synthesized. Then, the influence of the stoichiometry (RV/OV ratio) on the bulk and surface properties of the binary metal oxide catalysts was investigated. Similarly, the influence of the RV/OV ratio on the CO oxidation activity was discussed and the optimal value of RV/OV ratio was identified. The results show that the increasing of the RV/OV ratio from 0.9 to 1.1, particularly in Ni- and Co-containing catalysts, induces stronger metal-aluminum interactions, in the form of aluminates phases, and that are correlated to the dramatic reduction of the CO oxidation activity. The best physicochemical properties and highest catalytic activities were achieved with the catalysts prepared in redox systems stoichiometrically balanced (RV/OV = 1). The Cu-containing catalysts presented the best catalytic activities in CO oxidation. Full article