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22 pages, 68111 KB  
Article
Mechanistic Interpretation of Fretting Wear in Z10C13 Steel Under Displacement–Load Coupling
by Ruizhi Li, Bozhen Sun, Zhen Meng, Yigang Wang, Jing Ni and Haohan Zhang
Lubricants 2025, 13(9), 421; https://doi.org/10.3390/lubricants13090421 - 19 Sep 2025
Viewed by 234
Abstract
Considering that the ferritic stainless steel Z10C13 support plate material in nuclear power equipment tends to undergo fretting wear during service, this paper systematically investigates the effect of varying normal loads (10–50 N) and displacement amplitudes (15–75 μm) on its fretting response and [...] Read more.
Considering that the ferritic stainless steel Z10C13 support plate material in nuclear power equipment tends to undergo fretting wear during service, this paper systematically investigates the effect of varying normal loads (10–50 N) and displacement amplitudes (15–75 μm) on its fretting response and wear mechanisms. Through ball-on-flat fretting wear experiments, together with macro- and micro-scale observations of wear scars, it is revealed that normal load primarily controls the contact intensity and the extent of adhesion, whereas displacement amplitude mainly affects the slip amplitude and features of fatigue damage. The results show that the fretting system’s dissipated energy increases nonlinearly with both load and amplitude, and their coupled effect significantly exacerbates interfacial damage. The wear scar morphology evolves from a shallow bowl shape to a structure characterized by multiple spalling pits and propagating fatigue cracks. An equivalent hardness-corrected Archard model is proposed based on the experimental data. The model captures the nonlinear dependence of equivalent material hardness on both load and amplitude. As a result, it accurately predicts wear volume (R2=0.9838), demonstrating its physical consistency and modeling reliability. Overall, this study elucidates the multi-scale damage evolution mechanism of Z10C13 under fretting conditions and provides a theoretical foundation and methodological support for wear-resistant design, life prediction, and safety evaluation of nuclear power support structures. Full article
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13 pages, 41617 KB  
Article
Characterization of the Carbides in Carburized CSS-42L Steel and Their Effect on the Fatigue Failure Mechanism
by Ming Liu, Xingyu Lu, Chengshuai Lei, Xinxin Ma and Hongwei Liu
Metals 2025, 15(9), 1013; https://doi.org/10.3390/met15091013 - 11 Sep 2025
Viewed by 302
Abstract
The types of carbides and their effects on the fatigue failure mechanism in carburized CSS-42L steel were systematically studied in the present investigation. The results indicate that the main carbides in carburized CSS-42L steel are Cr-rich M23C6 carbides and Mo-rich [...] Read more.
The types of carbides and their effects on the fatigue failure mechanism in carburized CSS-42L steel were systematically studied in the present investigation. The results indicate that the main carbides in carburized CSS-42L steel are Cr-rich M23C6 carbides and Mo-rich M6C carbides. M23C6 carbides precipitate along grain boundaries and interconnect, forming network carbides. Rolling contact fatigue (RCF) tests reveal that fatigue cracks in CSS-42L steel can initiate both at the contact surface and within the subsurface. During RCF, the spalling of large-sized, networked M23C6 carbides creates micro-spalling pits on the contact surface, inducing local stress concentration that triggers the initiation of surface cracks. The surface cracks initially propagate perpendicularly to the contact surface and then shift to propagate parallelly to the contact surface, ultimately causing large-scale spalling of the surface layer. Subsurface cracks initiate at a position approximately 100 μm below the contact surface, with their propagation direction roughly parallel to the contact surface. Meanwhile, the development of subsurface cracks can connect with surface cracks, leading to the expansion of surface micro-pitting. Network carbides facilitate the propagation of secondary cracks, leading to the formation of grid-distributed crack networks. Full article
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30 pages, 2129 KB  
Article
Theoretical and Simulation Study of CO2 Laser Pulse Coupled with Composite Mechanical Drill Bit for Rock-Breaking Technology
by Lei Tao, Hailu Li, Liangzhu Yan and Zhiyuan Zhou
Processes 2025, 13(8), 2619; https://doi.org/10.3390/pr13082619 - 19 Aug 2025
Viewed by 698
Abstract
Facing challenges of low efficiency and severe wear in deep hard formations with conventional drilling bits, this study investigates the synergistic rock-breaking technology combining a pulsed CO2 laser with mechanical bits. The background highlights the need for novel methods to enhance drilling [...] Read more.
Facing challenges of low efficiency and severe wear in deep hard formations with conventional drilling bits, this study investigates the synergistic rock-breaking technology combining a pulsed CO2 laser with mechanical bits. The background highlights the need for novel methods to enhance drilling speed in high-strength, abrasive strata where traditional bits struggle. The theoretical analysis explores the thermo-mechanical coupling mechanism, where pulsed laser irradiation rapidly heats the rock surface, inducing thermal stress cracks, micro-spallation, and strength reduction through mechanisms like mineral thermal expansion mismatch and pore fluid vaporization. This pre-damage layer facilitates subsequent mechanical fragmentation. The research employs finite element numerical simulations (using COMSOL Multiphysics with an HJC constitutive model and damage evolution criteria) to model the coupled laser–mechanical–rock interaction, capturing temperature fields, stress distribution, crack propagation, and assessing efficiency. The results demonstrate that laser pre-conditioning significantly achieves 90–120% higher penetration rates compared to mechanical-only drilling. The dominant spallation mechanism proves energy-efficient. Conclusions affirm the feasibility and significant potential of CO2 laser-assisted drilling for deep formations, contingent on optimized laser parameters, composite bit design (incorporating laser transmission, multi-head layout, and environmental protection), and addressing challenges, like high in-situ stress and drilling fluid interference through techniques like gas drilling. Future work should focus on high-power laser downhole transmission, adaptive control, and rigorous field validation. Full article
(This article belongs to the Section Automation Control Systems)
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12 pages, 3332 KB  
Article
Numerical Study on Impact Damage and Damage Evolution of Cemented Backfill
by Qiang Li, Jinshan Sun, Xianqi Xie, Qian Dong, Jianguo Wang, Hongyu Zhang and Tao Wen
Crystals 2025, 15(6), 514; https://doi.org/10.3390/cryst15060514 - 28 May 2025
Cited by 2 | Viewed by 430
Abstract
To quantitatively describe the damage degree and failure process of the cemented backfill (CB) under dynamic loading, this paper performed numerical split Hopkinson pressure bar (SHPB) impact experiments on CB samples using the ANSYS/LS-DYNA. The damage pattern and failure process of CB samples [...] Read more.
To quantitatively describe the damage degree and failure process of the cemented backfill (CB) under dynamic loading, this paper performed numerical split Hopkinson pressure bar (SHPB) impact experiments on CB samples using the ANSYS/LS-DYNA. The damage pattern and failure process of CB samples with four mix ratios (cement-to-sand (c/s) ratios of 1:4, 1:6, 1:8, and 1:10) at different impact velocities (v) (1.5, 1.7, 1.8, and 2.0 m/s) were numerically investigated using the micro-crack density method to define the damage variable (d). The results revealed that the use of a waveform shaper in the numerical simulation yielded a more ideal rectangular wave to ensue uniform stress distribution across the sample’s plane without stress concentration. Numerical simulations effectively depicted the dynamic failure process of the CB, with the overall failure trend exhibiting edge spalling followed by the propagation and interconnection of internal cracks. When the v increased from 1.7 m/s to 1.8 m/s, the d increased by more than 10%. As the v increased from 1.5 m/s to 2.0 m/s, the d for c/s ratios of 1:4, 1:6, 1:8, and 1:10 ranged from 0.238 to 0.336, 0.274 to 0.413, 0.391 to 0.547, and 0.473 to 0.617, respectively. A significant “leap” phenomenon in damage was observed when the c/s ratio changed from 1:6 to 1:8. Full article
(This article belongs to the Section Inorganic Crystalline Materials)
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10 pages, 8534 KB  
Article
Analysis of the Effect of Grease Containing Magnesium Hydroxysilicate in Wind Power Bearing Field Tests
by Peng Wang, Changxing Yang, Bowen Shi and Huizhe Zhang
Processes 2025, 13(5), 1385; https://doi.org/10.3390/pr13051385 - 1 May 2025
Viewed by 489
Abstract
Ultra-high-power wind turbine generator bearings are susceptible to micro-spalling and electrical erosion in long-cycle operation, which seriously affects the operating efficiency and service life of the unit. For this reason, this paper adopts a kind of composite grease containing nano-hydroxy magnesium silicate powder [...] Read more.
Ultra-high-power wind turbine generator bearings are susceptible to micro-spalling and electrical erosion in long-cycle operation, which seriously affects the operating efficiency and service life of the unit. For this reason, this paper adopts a kind of composite grease containing nano-hydroxy magnesium silicate powder and, through the wind turbine assembly machine test and raceway surface analysis, systematically investigates its impact on bearing temperature rise, bearing vibration, and wind turbine power under actual working conditions to meet the lubrication requirements of wind turbine generator bearings. The results of the study showed that the composite grease significantly reduced the operating temperature of the wind turbine bearings under full operating conditions. It is worth noting that the reduction in generator bearing temperature varied among the three turbines due to uncertain environmental factors. In addition, the grease effectively increased the output power of the turbine under medium wind speed loading conditions, further verifying its potential value and practical effect in the application of wind turbines. Full article
(This article belongs to the Section Energy Systems)
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20 pages, 15551 KB  
Article
Effect of Microstructure and Compressive Residual Stress on the Fatigue Performance of AISI 4140 Steel with QPQ Salt-Bath Nitro-Carburizing
by Hao Chen, Tai-Cheng Chen, Hsiao-Hung Hsu and Leu-Wen Tsay
Materials 2025, 18(9), 1995; https://doi.org/10.3390/ma18091995 - 28 Apr 2025
Cited by 1 | Viewed by 1099
Abstract
Quench–polish–quench (QPQ) nitro-carburizing of AISI 4140 steel in a salt bath was performed in this study. Nitro-carburizing in a salt bath enhanced the formation of Fe-nitride on the outer surface layer. Moreover, the oxidizing treatment formed a thin oxide layer decorated on the [...] Read more.
Quench–polish–quench (QPQ) nitro-carburizing of AISI 4140 steel in a salt bath was performed in this study. Nitro-carburizing in a salt bath enhanced the formation of Fe-nitride on the outer surface layer. Moreover, the oxidizing treatment formed a thin oxide layer decorated on the outermost part of the QPQ-treated sample. The dense compound layer formed after nitro-carburizing in a salt bath consisted of refined granular Fe3N and transformed to Fe2N after post-oxidation treatment. Micro-shot peening (MSP) was adopted before QPQ treatment to increase the treated steel’s fatigue performance. The results indicated that MSP slightly increased the thickness of the compound layer and harden depth, but it had little effect on improving the fatigue strength/life of the QPQ-treated sample (SP-QPQ) compared to the non-peened one (NP-QPQ). A deep compressive residual stress (CRS) field (about 200 μm) and a hard nitrided layer showed a noticeable improvement in the fatigue performance of the QPQ-treated ones relative to the 4140 substrates tempered at 570 °C. The ease of slipping or deforming on the substrate surface was responsible for its poor resistance to fatigue failure. The cracking and spalling of the brittle surface layer were the causes for the fatigue crack initiation and growth of all of the QPQ-treated samples fatigue-loaded at/above 875 MPa. It was noticed that fatigue crack initiation at the subsurface inclusions was more likely to occur in the SP-QPQ sample fatigue-loading at 850 MPa or slightly above the fatigue limit. Full article
(This article belongs to the Special Issue Microstructure Engineering of Metals and Alloys, 3rd Edition)
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28 pages, 12079 KB  
Article
Ultrasound Reconstruction Tomography Using Neural Networks Trained with Simulated Data: A Case of Theoretical Gradient Damage in Concrete
by Carles Gallardo-Llopis, Jorge Gosálbez, Sergio Morell-Monzó, Santiago Vázquez, Alba Font and Jordi Payá
Appl. Sci. 2025, 15(8), 4273; https://doi.org/10.3390/app15084273 - 12 Apr 2025
Viewed by 705
Abstract
Gradient damage processes in cementitious materials are generally produced by chemical and/or physical processes that travel from outside to inside. Depending on the type of damage, it can cause different effects such as decreased porosity, cracking, or steel corrosion in the case of [...] Read more.
Gradient damage processes in cementitious materials are generally produced by chemical and/or physical processes that travel from outside to inside. Depending on the type of damage, it can cause different effects such as decreased porosity, cracking, or steel corrosion in the case of carbonation, or increased porosity, micro-cracks, expansion, and spalling (also present in thermal damage) in the case of external attack by sulphates or acid attack. Therefore, estimating the boundaries of this damage is an essential task for concrete quality assessment. The first objective of this work was to use neural networks (NNs) for ultrasound tomographic reconstruction of concrete samples in order to estimate the advance front in gradient damage. Unlike the usual X-ray tomography, ultrasound tomography is affected by diffraction, among other factors. NNs can learn to compensate for these effects; however, they require a large amount of training data to achieve accurate results. In the case of cement-based materials, obtaining and measuring a real training database could be complicated, expensive, and time-consuming. For this purpose, a training process using simulated measurements was carried out. The second objective of this work was to demonstrate the feasibility of training neural networks through simulations, which reduces costs. Finally, the trained neural network for tomographic reconstruction was evaluated using real cylindrical concrete specimens. Each specimen consisted of an outer cylinder, representing externally exposed cement, and an inner cylinder, simulating the unaffected core. The Structural Similarity Index (SSIM) was used as a metric to assess the reconstruction accuracy, achieving values of 0.95 for simulated signals and up to 0.82 for real signals. Full article
(This article belongs to the Special Issue Application of Ultrasonic Non-destructive Testing)
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30 pages, 4441 KB  
Review
A Review on the Effect of Synthetic Fibres, Including Macro Fibres, on the Thermal Behaviour of Fibre-Reinforced Concrete
by Peyman Mehrabi, Ulrike Dackermann, Rafat Siddique and Maria Rashidi
Buildings 2024, 14(12), 4006; https://doi.org/10.3390/buildings14124006 - 17 Dec 2024
Cited by 2 | Viewed by 2189
Abstract
The mechanical properties of concrete degrade rapidly when exposed to elevated temperatures. Adding fibres to concrete can enhance its thermal stability and residual mechanical characteristics under high-temperature conditions. Various types of fibres, including steel, synthetic and natural fibres, are available for this purpose. [...] Read more.
The mechanical properties of concrete degrade rapidly when exposed to elevated temperatures. Adding fibres to concrete can enhance its thermal stability and residual mechanical characteristics under high-temperature conditions. Various types of fibres, including steel, synthetic and natural fibres, are available for this purpose. This paper provides a comprehensive review of the impact of synthetic fibres on the performance of fibre-reinforced concrete at high temperatures. It evaluates conventional synthetic fibres, including polypropylene (PP), polyethylene (PE), and polyvinyl alcohol (PVA) fibres, as well as newly emerging macro fibres that improve concrete’s fire resistance properties. The novelty of this review lies in its focus on macro fibres as a promising alternative to conventional synthetic fibres. The findings reveal that PE fibres significantly influence the residual mechanical properties of fibre-reinforced concrete at high temperatures. Although PVA fibres may reduce compressive strength at elevated temperatures, they help reduce micro-cracking and increase flexibility and flexural strength. Finally, this review demonstrates that while conventional synthetic fibres are effective in limiting fire-induced damage, macro fibres offer enhanced benefits, including improved toughness, energy absorption, durability, corrosion resistance, and post-cracking capacity. This study provides valuable insights for developing fibre-reinforced concrete with superior high-temperature performance. Steel fibres offer superior strength but are prone to corrosion and spalling, while PP fibres effectively reduce explosive spalling but provide limited strength improvement. PE fibres enhance flexural performance, and PVA fibres improve tensile strength and shrinkage control, although their performance decreases at high temperatures. Macro fibres stand out for their post-cracking capacity and toughness, offering a lightweight alternative with better overall durability. Full article
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16 pages, 7297 KB  
Article
Enhanced Water Resistance of TiO2–GO–SMS-Modified Soil Composite for Use as a Repair Material in Earthen Sites
by Wei Li, Wenbo Bao, Zhiqiang Huang, Yike Li, Yuxuan Guo and Ming Wang
Materials 2024, 17(18), 4610; https://doi.org/10.3390/ma17184610 - 20 Sep 2024
Viewed by 1162
Abstract
Most earthen sites are located in open environments eroded by wind and rain, resulting in spalling and cracking caused by shrinkage due to constant water absorption and loss. Together, these issues seriously affect the stability of such sites. Gypsum–lime-modified soil offers relatively strong [...] Read more.
Most earthen sites are located in open environments eroded by wind and rain, resulting in spalling and cracking caused by shrinkage due to constant water absorption and loss. Together, these issues seriously affect the stability of such sites. Gypsum–lime-modified soil offers relatively strong mechanical properties but poor water resistance. If such soil becomes damp or immersed in water, its strength is significantly reduced, making it unviable for use as a material in the preparation of earthen sites. In this study, we achieved the composite addition of a certain amount of sodium methyl silicate (SMS), titanium dioxide (TiO2), and graphene oxide (GO) into gypsum–lime-modified soil and analyzed the microstructural evolution of the composite-modified soil using characterization methods such as XRD, SEM, and EDS. A comparative study was conducted on changes in the mechanical properties of the composite-modified soil and original soil before and after immersion using water erosion, unconfined compression (UCS), and unconsolidated undrained (UU) triaxial compression tests. These analyses revealed the micro-mechanisms for improving the waterproof performance of the composite-modified soil. The results showed that the addition of SMS, TiO2, and GO did not change the crystal structure or composition of the original soil. In addition, TiO2 and GO were evenly distributed between the modified soil particles, playing a positive role in filling and stabilizing the structure of the modified soil. After being immersed in water for one hour, the original soil experienced structural instability leading to collapse. While the water absorption rate of the composite-modified soil was only 0.84%, its unconfined compressive strength was 4.88 MPa (the strength retention rate before and after immersion was as high as 93.1%), and the shear strength was 614 kPa (the strength retention rate before and after immersion was as high as 96.7%). Full article
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15 pages, 11707 KB  
Article
Experimental Study and Mechanism Analysis of the Influence of Micro-Dimple Geometry on the Adhesion Strength of Textured Coatings
by Hao Fu, Xiao Yang, Mei Mei, Jie Yang, Yanhu Zhang, Jinghu Ji and Yonghong Fu
Coatings 2024, 14(8), 973; https://doi.org/10.3390/coatings14080973 - 2 Aug 2024
Cited by 5 | Viewed by 1738
Abstract
Textured coating technology is an effective method to improve the friction and wear performance of mold surfaces. The adhesion strength at the interface between the texture and the coating is crucial for its long-term serviceability. This paper studies the adhesion strength of micro-dimple’s [...] Read more.
Textured coating technology is an effective method to improve the friction and wear performance of mold surfaces. The adhesion strength at the interface between the texture and the coating is crucial for its long-term serviceability. This paper studies the adhesion strength of micro-dimple’s topography textured coatings, aiming to reveal the influence mechanism of micro-dimples on the adhesion strength of textured coating interfaces. Different diameters or texture area ratios of micro-dimples were prepared on the sample surface using a picosecond laser, followed by PVD coating deposition. Scratching tests and indentation tests were then conducted on the textured coating surface. The adhesion strength and crack propagation behavior of the coating on the surface of different samples were studied under dynamic and static contact conditions. The results showed that under dynamic contact conditions, the critical load for coating failure of most textured samples was higher than that of non-textured samples. As the depth and diameter of the micro-dimple’s topography increased, the critical load first increased and then decreased, with the maximum critical load being 14.9% higher than that of the non-textured samples. Under static contact conditions, almost no coating spalling was observed around the indentation on the surface of the micro-dimple’s topography textured coating, while the spalling areas of non-textured samples were mainly at the edges and surrounding areas of the indentation. In contrast, the spalling regions of the textured samples were primarily concentrated at the edges of the texture. It can be seen that the dimpled texture hinders crack propagation and reduces the interlocking network of cracks, thereby reducing coating spalling. The research results provide important theoretical guidance for the design and optimization of textured coatings on mold surfaces. Full article
(This article belongs to the Special Issue Smart Coatings)
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19 pages, 27754 KB  
Article
Experimental Investigation on the Influence of Water on Rockburst in Rock-like Material with Voids and Multiple Fractures
by Guokun Liu, Xiaohua Li, Zhili Peng and Wei Chen
Materials 2024, 17(12), 2818; https://doi.org/10.3390/ma17122818 - 10 Jun 2024
Cited by 2 | Viewed by 1347
Abstract
To investigate the influence of water content on the rockburst phenomena in tunnels with horizontal joints, experiments were conducted on simulated rock specimens exhibiting five distinct levels of water absorption. Real-time monitoring of the entire blasting process was facilitated through a high-speed camera [...] Read more.
To investigate the influence of water content on the rockburst phenomena in tunnels with horizontal joints, experiments were conducted on simulated rock specimens exhibiting five distinct levels of water absorption. Real-time monitoring of the entire blasting process was facilitated through a high-speed camera system, while the microscopic structure of the rockburst debris was analyzed using scanning electron microscopy (SEM) and a particle size analyzer. The experimental findings revealed that under varying degrees of water absorption, the specimens experienced three stages: debris ejection; rockburst; and debris spalling. As water content increased gradually, the intensity of rockburst in the specimens was mitigated. This was substantiated by a decline in peak stress intensity, a decrease in elastic modulus, delayed manifestation of pre-peak stress drop, enhanced amplitude, diminished elastic potential energy, and augmented dissipation energy, resulting in an expanded angle of rockburst debris ejection. With increasing water content, the bond strength between micro-particles was attenuated, resulting in the disintegration of the bonding material. Deformation failure was defined by the expansion of minuscule pores, gradual propagation of micro-cracks, augmentation of fluffy fine particles, exacerbation of structural surface damage akin to a honeycomb structure, diminishment of particle diameter, and a notable increase in quantity. Furthermore, the augmentation of secondary cracks and shear cracks, coupled with the enlargement of spalling areas, signified the escalation of deformation failure. Simultaneously, the total mass of rockburst debris gradually diminished, accompanied by a corresponding decrease in the proportion of micro and fine particles within the debris. Full article
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17 pages, 14199 KB  
Article
The Risk of Alkali–Carbonate Reaction and the Freeze–Thaw Resistance of Waste Dolomite Slag-Based Concrete
by Yulin Chen, Xuefei Xiong, Ding Wang, Xianliang Zhou, Changwu Liu and Zhipeng Xu
Buildings 2024, 14(6), 1664; https://doi.org/10.3390/buildings14061664 - 4 Jun 2024
Cited by 2 | Viewed by 1751
Abstract
The alkali–carbonate reaction (ACR) is a type of alkali–aggregate reaction (AAR) that may lead to serious damage in concrete construction. There is sufficient research on the effect of the ACR on dolomite limestone; however, research on the effect of the ACR on pure [...] Read more.
The alkali–carbonate reaction (ACR) is a type of alkali–aggregate reaction (AAR) that may lead to serious damage in concrete construction. There is sufficient research on the effect of the ACR on dolomite limestone; however, research on the effect of the ACR on pure dolomite is absent, and there are a large number of dolomite resources that cannot be effectively utilized in civil engineering. This study aims to investigate whether the ACR occurs in pure dolomite spoil and to determine the freeze–thaw resistance of pure waste dolomite slag-based concrete (PWDSC). In this study, X-ray diffraction (XRD) and the lithofacies method (LM) confirmed that the tested samples were pure dolomite. The rock cylinder method (RCM) and rapid preliminary screening testing for carbonate aggregates (AAR-5) were employed to determine the alkali activity of pure dolomite: the RCM indicated a variation of −0.09% in length during the 84-day test period, the AAR-5 exhibited a length expansion rate of 0.03% within 28 days, and the expansion rates were less than 0.1%. These findings suggest that pure waste dolomite slag (PWDS) does not possess alkali activity. The freeze–thaw cycle test showed no significant spalling on the concrete surface, the inside of the cement produced few micro-cracks according to scanning electron microscopy (SEM), and the uniaxial compressive strength (UCS) test showed a decrease of approximately 20% after 200 freeze–thaw cycles. The results verified that ACR does not occur in PWDS and that it can withstand freeze–thaw damage, to a certain extent, when used as concrete coarse aggregate. Full article
(This article belongs to the Section Building Materials, and Repair & Renovation)
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19 pages, 4295 KB  
Article
Geopolymerization of Recycled Glass Waste: A Sustainable Solution for a Lightweight and Fire-Resistant Material
by Marios Valanides, Konstantinos Aivaliotis, Konstantina Oikonomopoulou, Alexandros Fikardos, Pericles Savva, Konstantinos Sakkas and Demetris Nicolaides
Recycling 2024, 9(1), 16; https://doi.org/10.3390/recycling9010016 - 7 Feb 2024
Cited by 9 | Viewed by 4531
Abstract
Glass is considered a sustainable material with achievable recovery rates within the EU. However, there are limited data available for construction glass waste management. Furthermore, glass is a heavy material, and considering the geographical limitations of Cyprus, the transportation trading cost within the [...] Read more.
Glass is considered a sustainable material with achievable recovery rates within the EU. However, there are limited data available for construction glass waste management. Furthermore, glass is a heavy material, and considering the geographical limitations of Cyprus, the transportation trading cost within the EU is extremely high. Therefore, another method for utilizing this by-product should be developed. The aim of this research is to investigate the production of a low-cost, lightweight and fireproof material able to retain its structural integrity, using the geopolymerization method with the incorporation of randomly collected construction glass waste. The glass waste was initially processed in a Los Angeles abrasion machine and then through a Micro-Deval apparatus in order to be converted to a fine powder. Mechanical (compressive and flexural strength), physical (setting time and water absorption) and thermal properties (thermal conductivity) were investigated. The fire-resistant materials presented densities averaging 450 kg/m3 with a range of compressive strengths of 0.5 to 3 MPa. Additionally, a techno-economic analysis was conducted to evaluate the viability of the adopted material. Based on the results, the final geopolymer product has the potential to be utilized as a fire resistance material, preventing yielding or spalling. Full article
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14 pages, 11603 KB  
Article
The Shock-Induced Deformation and Spallation Failure of Bicrystal Copper with a Nanoscale Helium Bubble via Molecular Dynamics Simulations
by Qi Zhu, Jianli Shao and Pei Wang
Nanomaterials 2023, 13(16), 2308; https://doi.org/10.3390/nano13162308 - 11 Aug 2023
Cited by 5 | Viewed by 1730
Abstract
Both the nanoscale helium (He) bubble and grain boundaries (GBs) play important roles in the dynamic mechanical behavior of irradiated nanocrystalline materials. Using molecular dynamics simulations, we study the shock-induced deformation and spallation failure of bicrystal copper with a nanoscale He bubble. Two [...] Read more.
Both the nanoscale helium (He) bubble and grain boundaries (GBs) play important roles in the dynamic mechanical behavior of irradiated nanocrystalline materials. Using molecular dynamics simulations, we study the shock-induced deformation and spallation failure of bicrystal copper with a nanoscale He bubble. Two extreme loading directions (perpendicular or parallel to the GB plane) and various impact velocities (0.5–2.5 km/s) are considered. Our results reveal that the He bubble shows hindrance to the propagation of shock waves at lower impact velocities but will accelerate shock wave propagation at higher impact velocities due to the local compression wave generated by the collapse of the He bubble. The parallel loading direction is found to have a greater effect on He bubble deformation during shock compression. The He bubble will slightly reduce the spall strength of the material at lower impact velocities but has a limited effect on the spallation process, which is dominated by the evolution of the GB. At lower impact velocities, the mechanism of spall damage is dominated by the cleavage fracture along the GB plane for the perpendicular loading condition but dominated by the He bubble expansion and void growth for the parallel loading condition. At higher impact velocities, micro-spallation occurs for both loading conditions, and the effects of GBs and He bubbles can be ignored. Full article
(This article belongs to the Special Issue Nanomechanics, Plasticity and Fracture)
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19 pages, 64672 KB  
Article
Investigations of Abrasive Wear Behaviour of Hybrid High-Boron Multi-Component Alloys: Effect of Boron and Carbon Contents by the Factorial Design Method
by Yuliia Chabak, Ivan Petryshynets, Vasily Efremenko, Michail Golinskyi, Kazumichi Shimizu, Vadym Zurnadzhy, Ivan Sili, Hossam Halfa, Bohdan Efremenko and Viktor Puchy
Materials 2023, 16(6), 2530; https://doi.org/10.3390/ma16062530 - 22 Mar 2023
Cited by 5 | Viewed by 2090
Abstract
This paper is devoted to the evaluation of the “three-body-abrasion” wear behaviour of (wt.%) 5W–5Mo–5V–10Cr-2.5Ti-Fe (balance) multi-component (C + B)-added alloys in the as-cast condition. The carbon (0.3 wt.%, 0.7 wt.%, 1.1 wt.%) and boron (1.5 wt.%, 2.5 wt.%, 3.5 wt.%) contents were [...] Read more.
This paper is devoted to the evaluation of the “three-body-abrasion” wear behaviour of (wt.%) 5W–5Mo–5V–10Cr-2.5Ti-Fe (balance) multi-component (C + B)-added alloys in the as-cast condition. The carbon (0.3 wt.%, 0.7 wt.%, 1.1 wt.%) and boron (1.5 wt.%, 2.5 wt.%, 3.5 wt.%) contents were selected using a full factorial (32) design method. The alloys had a near-eutectic (at 1.5 wt.% B) or hyper-eutectic (at 2.5–3.5 wt.% B) structure. The structural micro-constituents were (in different combinations): (a) (W, Mo, and V)-rich borocarbide M2(B,C)5 as the coarse primary prismatoids or as the fibres of a “Chinese-script” eutectic, (b) Ti-rich carboboride M(C,B) with a dispersed equiaxed shape, (c) Cr-rich carboboride M7(C,B)3 as the plates of a “rosette”-like eutectic, and (d) Fe-rich boroncementite (M3(C,B)) as the plates of “coarse-net” and ledeburite eutectics. The metallic matrix was ferrite (at 0.3–1.1 wt.% C and 1.5 wt.% B) and “ferrite + pearlite” or martensite (at 0.7–1.1 wt.% C and 2.5–3.5 wt.% B). The bulk hardness varied from 29 HRC (0.3 wt.% C–1.5 wt.% B) to 53.5 HRC (1.1 wt.% C–3.5 wt.% B). The wear test results were mathematically processed and the regression equation of the wear rate as a function of the carbon and boron contents was derived and analysed. At any carbon content, the lowest wear rate was attributed to the alloy with 1.5 wt.% B. Adding 2.5 wt.% B led to an increase in the wear rate because of the appearance of coarse primary borocarbides (M2(B,C)5), which were prone to chipping and spalling-off under abrasion. At a higher boron content (3.5 wt.%), the wear rate decreased due to the increase in the volume fraction of the eutectic carboborides. The optimal chemical composition was found to be 1.1 wt.% C–1.5 wt.% B with a near-eutectic structure with about 35 vol.% of hard inclusions (M2(B,C)5, M(C,B), M3(C,B), and M7(C,B)3) in total. The effect of carbon and boron on the abrasive behaviour of the multi-component cast alloys with respect to the alloys’ structure is discussed, and the mechanism of wear for these alloys is proposed. Full article
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