Search Results (281)

Pumping stations serve as critical hydraulic infrastructure for water conveyance and irrigation. Sediment deposition in forebays can deteriorate intake flow conditions, increase hydraulic losses, reduce pumping efficiency, and consequently impair the long-term operational performance of pumping systems. To accurately predict sediment deposition in complex three-dimensional flow fields, we developed a dynamics-driven boundary-responsive numerical model that integrates sediment particle dynamics with real-time bed evolution. This model adopts the near-bed vertical velocity of sediment particles as the deposition discrimination criterion and dynamically updates bed topography via a mass-conservation-based boundary response strategy. The proposed method was validated against open-channel experimental data. The simulated flow structures, deposition patterns, and temporal variations in deposition thickness agreed well with the measurements, with average deviations below 4%. Compared with conventional static-boundary numerical methods, the proposed model reproduces the coupled evolution of sediment transport, flow redistribution, and bed deformation with higher fidelity. The developed framework provides an effective numerical tool for sediment deposition prediction and offers practical support for hydraulic structure optimization, maintenance scheduling, and energy-efficient operation of pumping stations with sediment-laden flow. Full article

Rapid corrosion and poor coating adhesion continue to limit the use of magnesium alloys as temporary orthopedic implants. The two-stage laser process was developed to separate the high-temperature melting of 45S5 bioactive glass (BG) from the low-melting-point AZ31 substrate. Femtosecond-laser grids with spacings of 100, 200, and 300 μm were first produced on AZ31 to provide anchoring sites. Then, the target 45S5 BG was suspended above the substrate, locally melted with CO₂ laser, and transported onto the textured surface by gas jet. The 200 μm grid texture for Mg substrate with lowest water contact angle could give the highest tape-test adhesion rating (4B). At the selected deposition conditions of 20 W and 20 L·min⁻¹, two coating cycles produced a continuous layer approximately 50.5 μm thick. Relative to bare Mg alloy, this double-layer coating increased polarization resistance from 1.20 × 103 to 1.39 × 10⁵ Ω·cm² and decreased corrosion current density from 8.70 × 10⁻⁴ to 5.33 × 10⁻⁶ A·cm⁻². It also limited alkalization and mass loss during 28 days in simulated body fluid. As such, the double-layer surface coating supported apatite formation and improved MC3T3-E1 proliferation and alkaline phosphatase activity. These findings indicated that suspended-target deposition was able to form adherent, bioactive glass coatings on magnesium while limiting direct thermal damage to the substrate. Full article

The development of potash deposits is generally accompanied by large losses of minerals in the subsurface. The main reason for these losses is the use of a room-and-pillar mining system, where left pillars hold the overlying rock strata and aquifers located above the productive seams. Over time, the bearing elements of the mining system begin to deteriorate, leading to a loss of continuity of the water-protective stratum, the formation of water-conducting fractures, salt dissolution, and consequently, the flooding of the potash mine. The most effective method for solving production problems in the field of increasing mineral recovery and mine safety is the introduction of backfilling technology. The aim of the study is to identify the effect of backfilling on the stress–strain state of the rock mass in the vicinity of stopping and backfilling operations, to develop a technology for potash ore extraction with increased recovery, and also to solve the fundamental issue of the proposed technology, namely, the transport and property considerations of the backfill mixture. Numerical modeling methods and analytical derivations of calculation formulas for backfill mixture transport are used in the work. A comparison of dry, hydraulic, and hardening backfill mixtures is carried out. The study established that hardening backfill ensures a faster transition to the stage of mining the remaining reserves. A technology for pillar extraction with the leaving of technologically necessary narrow pillars is proposed, allowing for the safety of mining operations. Formulas are derived for calculating the required strength of the backfill based on the loading degree of the technological pillar. Transportability criteria are formulated, and a calculation procedure for pipeline transport parameters under gravity and gravity-pneumatic modes is developed. The proposed technology for potash ore extraction with hardening backfill allows for increased mineral recovery while maintaining safe conditions for undermining the water-protective stratum. Full article

Steep rock slopes are widely distributed in the karst mountainous regions of southwestern China, where structurally controlled rockfalls frequently threaten transportation infrastructure and human safety. Accurate identification of unstable rock blocks (URs) and quantitative assessment of their post-failure hazards remain major challenges because of complex discontinuity networks and fragmentation during rockfall motion. Taking the Zuojiaying steep rock slope in Guizhou Province as a representative case, this study integrates high-resolution UAV photogrammetry, automatic discontinuity identification, unstable rock block detection, and three-dimensional rockfall simulation to investigate the formation mechanisms and hazard characteristics of discontinuity-controlled rockfalls. A high-resolution three-dimensional terrain model was reconstructed from UAV imagery, and six dominant discontinuity sets were automatically identified using the I-MinPts-constrained DBSCAN algorithm. Combined with the Rock Occurrence Kinematic Analysis (ROKA) algorithm and Block Theory, 54 unstable rock blocks were identified, with wedge failure and toppling failure representing the dominant instability modes. The results indicate that discontinuity combinations govern both rock mass segmentation and unstable rock block geometry. Specifically, discontinuity sets J1, J3, and J5 mainly control wedge-shaped blocks, and J2 and J4 dominate columnar toppling blocks, whereas J6 further promotes the formation of isolated unstable rock blocks. Three-dimensional RockGIS simulations considering fragmentation reproduced the complete rockfall process from detachment to final deposition. The maximum travel distance, kinetic energy, and bounce height reached 395 m, 748.5 kJ, and 40.1 m, respectively. Fragmentation increased the number of rock blocks from 54 to 1013, substantially enlarging the potential impact area. A raster-based Rockfall Hazard Index (RHI) further revealed that the middle–lower slope and slope toe constitute the principal high-hazard zones, and under extreme scenarios, high-energy fragments may reach the G246 National Highway and adjacent infrastructure. This study revealed the formation mechanisms and hazard characteristics of unstable rock blocks controlled by discontinuity combinations in the study area, providing a case reference for rockfall hazard identification and mitigation on similar high-steep rock slopes in karst mountainous regions. Full article

Ferdinandea Island, part of a shallow-water submarine volcanic field, emerged in the Sicily Channel between Italy and Tunisia in July 1831 and was eroded below sea level within months; its submerged remnant forms the shallowest water depth region of Graham Bank. Here, we review nearly two centuries of historical accounts, geological interpretations and geomorphological data analysis and reassess them against high-resolution multibeam bathymetry, sub-bottom profiles (CHIRP) and published multichannel seismic data. The field comprises six volcanic edifices (V1–V6), 100–170 m high, located along structural trends characteristic of the Sicily Channel Rift. V3, the shallowest edifice, is the remnant of Ferdinandea Island formed during the 1831 Surtseyan eruption. Its flat summit, wave-reworked terrace and steep flanks record rapid post-eruptive modification. Historical observations and hydrographic surveys document the destruction of the emergent island and a further ~6 m lowering of its shallowest point between 1883 and 2012–2015; the separate contributions of wave erosion, subsidence and gravitational adjustment cannot be resolved from the available data. The same regional structural framework appears to have governed the distribution of the other volcanic centres, pockmarks, erosional escarpments and mass-transport deposits of the study area. Seventeen pockmarks, up to ~540 m wide and 22 m deep, occur as isolated, clustered and locally aligned depressions; they are associated with subsurface concave-upward reflectors and local water-column acoustic anomalies, consistent with focused fluid escape. Failures of volcanic and sedimentary slopes are widespread, with the largest debris-avalanche deposit covering ~2.2 km². Taken together, these observations indicate that tectonics, volcanism, fluid migration, wave- and bottom-current reworking, and gravitational instability have operated over different timescales to shape Graham Bank. Ferdinandea thus offers a rare historical and geological reference for investigating the rapid construction, degradation and long-term evolution of shallow-water volcanic edifices and highlights the still-open questions regarding the evolution and fate of ephemeral volcanic islands. Full article

Nano- and microplastics (NMPs) are now widely detected across agroecosystems and can act as physiological stressors in plants. Exposure occurs through contaminated soil, irrigation water, or airborne deposition, bringing particles into direct contact with roots and above-ground tissues. Reported entry routes include apoplastic transport, cracks formed at lateral root emergence, leaf stomata, and endocytosis once particles have crossed the cell wall. Once internalized, particles may translocate through the xylem and, in some cases, the phloem, accumulating in roots, stems, and leaves depending on particle size, surface charge, and plant structural characteristics. NMPs have been associated with oxidative stress, disrupted photosynthesis, and altered metabolic pathways. Detecting NMPs within heterogeneous, hydrated plant tissues remains challenging, as particles often show low contrast against biological structures and can be mistaken for cellular components. This review examines how microscopy techniques reveal NMPs size, surface attachment, tissue distribution, and cellular-level interactions, while noting that these approaches primarily provide morphological or localization information rather than confirming polymer identity. Complementary spectroscopic and mass-based analytical methods are discussed for their role in chemical confirmation and quantification. This review supports informed selection among imaging, spectroscopic, and quantitative techniques for studying plant–plastic interactions, while highlighting current analytical challenges facing the field. Full article

Despite its geodynamic significance, the northern Tyrrhenian Back-Arc Basin, characterized by a complex tectono-magmatic evolution, remains poorly investigated. We present the first geophysical characterization of the Flavia Seamount, a previously uninvestigated edifice in the northern Tyrrhenian Sea, integrating new multibeam, seismic, and magnetic data. The new high-resolution bathymetric data reveal a flat, nearly circular summit and strongly asymmetric flanks. Reduced-to-the-pole magnetic anomalies exhibit a north–south polarity pattern, with positive values in the northern sector and negative values in the southern sector. Seismic data, integrated with Sparker profiles collected in 1985, reveal a flat-topped acoustic basement overlain by a ~100 m thick stratified sequence and affected by inactive east-dipping extensional faults, indicating tectonic control on the evolution of the seamount. Widespread landslide scarps and associated mass-transport deposits document recurrent gravitational instability along the flanks and within surrounding basins. Pockmark morphometry suggests distinct formation processes, with summit pockmarks controlled by fluid seepage and gravitational processes, and basin pockmarks mainly related to fluid escape from mass-transport deposits. Magnetic forward modelling constrained by seismic data provides new insights into the distribution of magnetic susceptibility bodies and the crustal architecture beneath the seamount. Results suggest that the present-day morphology of the Flavia Seamount reflects the combined effects of tectonic, sedimentary, and gravitational processes. Full article

Lead and zinc mineralization have been documented in low-temperature Mississippi Valley type (MVT), Volcanogenic Massive Sulfide (VMS), and high-temperature porphyry and skarn ore deposits. These deposits are characterized by the precipitation of galena (PbS) and sphalerite (ZnS) from a saline hydrothermal fluid. The direct relationship between metal concentration and the total chloride of the fluid has been documented previously; however, the role of acidity has not been studied extensively. Experiments were conducted in René 41 cold-seal pressure vessels at temperatures of 200, 300, and 500 °C and a pressure of 100 MPa to provide better constraints on the formation of galena and sphalerite in hydrothermal systems spanning a range of fluid acidities (pH). The concentrations of Pb and Zn in the synthetic hydrothermal fluids were determined at galena and sphalerite saturation as a function of HCl and at a total chloride of 15 wt.% NaCl_eq.. Zn concentrations ranged from 1.7 (±0.3) × 10² µg/g at 200 °C and an HCl concentration of 2.28 × 10³ µg/g to 2.55 (±0.5) × 10³ µg/g at 500 °C and an HCl concentration of 3.40 × 10⁴ µg/g. Pb concentrations were 1.8 (±0.4) µg/g at 200 °C and a HCl of 2.28 × 10³ µg/g and increased to 7.93 (±1.5) × 10³ µg/g at 500 °C and a HCl concentration of 3.40 × 10⁴ µg/g. Zn/Pb mass ratios in the fluids at sphalerite and galena saturation decreased with increasing temperature. The experimental data demonstrate that the concentration of Pb and Zn in the fluid increase with both temperature and HCl concentration and, consequently, decrease with increasing pH. These results demonstrate that acidic fluids can transport substantially greater concentrations of Pb and Zn than neutral or basic fluids. Experimentally determined slopes of Pb and Zn concentrations as a function of HCl in the fluid provide empirical measurements of the apparent dependence of metal solubility on HCl at a constant total salinity. These results are consistent with Pb and Zn being transported predominantly as chloride-complexes under acidic, although the experiments do not directly determine aqueous metal speciation. Consequently, the experimentally determined HCl dependencies should be interpreted as empirical measures of apparent metal solubility rather than direct measurements of speciation or ligand coordination. The observed dependence of dissolved metal concentrations on HCl likely reflects the combined effects of chloride complexation, increasing HCl association with increasing temperature, non-ideal solution behavior, and changes in the distribution of dissolved chloride- and possibly sulfur-based complexes. Therefore, the neutralization of an acidic Pb- and Zn-bearing, chloride-rich hydrothermal fluid could produce substantial galena and sphalerite mineralization if sufficient reduced sulfur is available. In hydrothermal fluids depleted in reduced sulfur, H₂S must be supplied through sulfate reduction or by mixing with an H₂S-rich fluid to promote galena and sphalerite precipitation. Full article

Fluvial superfloods are geomorphologically significant episodes due to their enormous energy and extremely low recurrence in the geological record. Their rarity is particularly notable in areas far from the major continental glacial masses. Hydraulic constrictions in the Lower Ebro River gorges caused the accumulation of fluvial deposits, as floodwaters from the Ebro River were forced upstream into the tributary valleys of the Móra Basin. The most illustrative example is the Comte Creek, where two depositional units of different ages show upstream flood accumulations (extending up to ~4 km) with very high-energy sedimentary structures, followed by downstream reworking during backflow. Two-dimensional hydraulic simulations indicate that peak discharges reaching 385,000 m³·s⁻¹, with water depths of approximately 28 m in the confluence area, would have been required to transport sediments to the observed outcrop positions. Luminescence dating of the slackwater deposits indicates that the formative processes occurred during the latest Middle Pleistocene or the Last Interglacial (Eemian). Full article

A frequent and sudden two-phase (solid–liquid) geological hazard in mountainous areas, the evolution of debris flows involves the coupling of multiple physical fields, making monitoring and early warning particularly challenging. To accurately reveal the dynamic patterns of debris flow evolution and improve early-warning accuracy, this study focused on the Ni Chang Valley area in Shimian County, Ya’an City, Sichuan Province. Based on the COMSOL Multiphysics coupling simulation platform, a multiphysics bidirectionally strongly coupled numerical model was proposed and constructed, integrating the SPH (smoothed particle hydrodynamics) meshless particle method, FLO-2D shallow-water dynamics, and the MassFlow full-process simulation approach. Using COMSOL as a unified framework, this model employs MassFlow’s deep-integration, continuous medium method to simulate rainfall triggering and material source activation, FLO-2D’s shallow-water equations to describe macroscopic flow-deposition processes, and SPH’s mesh-free particle method to accurately capture large deformations and free-surface flow. The model fully reproduces the entire dynamic chain of debris flow processes, from rainfall triggering and soil mobilization to fluid transport and channel deposition. The reliability and accuracy of the model were verified by comparing it with field measurements from the 20 September 2022 historical debris flow event at Ni Chang Valley. Quantitative analysis indicates that when the viscosity coefficient increases from 0.1 Pa·s to 100 Pa·s, the flow velocity decreases by approximately 47% and the flow depth increases by approximately 62%. When the yield stress increases from 1 Pa to 100 Pa, the deposition area shrinks from 269,900 m² to approximately 109,000 m², a reduction of about 60%. Combining the results of the dynamic analysis, daily maximum temperature, daily precipitation, moisture content, mud-water level, and ground surface displacement were selected as core monitoring indicators. The analytic hierarchy process (AHP) was used to determine the weights of each indicator, and a data- and physics-driven weighted summation model for debris flow monitoring and early warning was constructed to achieve a five-level debris flow monitoring and early-warning system. Historical disaster cases demonstrate that this early-warning model can provide advance predictions of debris flow disasters up to 2 h and 40 min in advance. The warning lead time is sufficient, the grading logic is clear, and the model is capable of accurately capturing precursor information on disasters. Full article

High Velocity Oxy-Fuel (HVOF) thermal spraying enables the deposition of dense coatings with low porosity, high hardness, and good fracture resistance. Tungsten carbide–cobalt (WC-Co) coatings are widely used in industrial and aerospace applications due to their excellent wear resistance; however, improving crack resistance and coating–substrate adhesion remains a key challenge. In this study, WC-Co+Ni composite coatings were deposited on ductile cast iron, with emphasis on the role of Ni addition in controlling microstructure development under HVOF conditions. Microstructural characterization was performed using optical, scanning, and transmission electron microscopy (OM, SEM, TEM), while phase composition and chemical analysis were determined by X-ray diffraction (XRD) and energy-dispersive spectroscopy (EDS). The coatings exhibited a dense, low-porosity microstructure composed of fine WC and W₂C carbides embedded in a Co–Ni binder, with locally nanocrystalline regions. XRD analysis confirmed WC and W₂C as the dominant phases, with weak reflections corresponding to the η-phase (Co₆W₆C), indicating local decarburization. The addition of Ni increases the fraction of the transient liquid phase during particle flight, enhancing carbide dissolution and mass transport in the binder, which accelerates decarburization kinetics and promotes η-phase formation. Simultaneously, Ni modifies the binder into a more ductile Co–Ni matrix, reducing the detrimental effect of brittle η-phase on coating integrity. Mechanical and tribological testing (instrumented indentation and scratch testing) demonstrated improved crack resistance, wear resistance, and adhesion. The results show that Ni addition enables process-driven microstructural tailoring of HVOF-sprayed WC-Co coatings, leading to enhanced performance despite the presence of η-phase. Full article

The nucleation and growth mechanisms of copper electrodeposition from Cu(I)-containing-reline, a deep eutectic solvent, were investigated through a combination of electrochemical techniques and surface characterization. Cyclic voltammetry revealed the characteristic nucleation loop associated with an overpotential-driven electrocrystallization process, from which the equilibrium potential of the Cu(I)/Cu(0) redox couple was determined to be −0.35 V vs. a Ag quasi-reference electrode. Experimental potentiostatic current density transients were analyzed using nucleation models capable of accounting for both adsorption and three-dimensional (3D) diffusion-controlled growth, thereby allowing deconvolution of the individual contributions to the overall current response. The kinetic parameters, including the nucleation frequency and the number density of active sites, exhibited an exponential dependence on the applied overpotential, thus indicating enhanced nucleation kinetics at greater driving forces, while determining a Cu(I) diffusion coefficient of (3.39 + 0.09) × 10⁻⁷ cm² s⁻¹. Thermodynamic analysis showed that the Gibbs free energy of the formation of the critical nucleus decreases with increasing overpotential and follows the expected dependence on the inverse square of the overpotential, in agreement with classical nucleation theory. The estimated critical nucleus size was found to be smaller than one atom, suggesting that nucleation occurs at highly active surface sites. Furthermore, an exchange current density of (3 ± 1) μA cm⁻² was estimated for the Cu(I) electrochemical reduction. Scanning electron microscopy revealed a high density of copper nanoparticles (~20 nm) distributed across the electrode surface, along with larger aggregates (~100 nm) formed by coalescence and growth, consistent with a progressive nucleation mechanism. X-ray photoelectron spectroscopy confirmed that the deposits consist exclusively of metallic copper, with no evidence of oxidized species. These results demonstrate that copper electrodeposition in reline is governed by a complex interplay between the thermodynamic driving force, the interfacial kinetics, and mass transport, comprehensively providing fundamental insight into the electrocrystallization processes in deep eutectic solvents. Full article

The sustainability, crop production, and food safety of agriculture are increasingly challenged by microplastic pollution, as agricultural soils are the largest reservoirs and may serve as points of contact for plastic particles in the food chain. This review provides a comprehensive overview of plant materials, fate and uptake pathways, detection techniques, and the possible risks of microplastics in agriculture. Agroecosystems are also a source of microplastics, such as plastic mulch films, sewage sludge, compost and manure additives, wastewater irrigation, polymer-coated fertilizers, greenhouse materials, atmospheric deposition, and decomposition of discarded agricultural plastics. Their distribution and mobility in soil are controlled by polymer composition, particle size, morphology, density, surface ageing, soil texture, organic matter content, tillage practices, runoff, leaching, and soil biota. Recent data show that microplastics, especially smaller microplastics and nanoplastics, can attach to root surfaces, penetrate plants via cracks in roots, areas of lateral root development, and apoplastic pathways, and eventually move to tissues aboveground. Plant tissue detection is often accomplished by digestion of the sample, density separation, visual and fluorescence microscopy, Fourier-transform infrared spectroscopy, Raman spectroscopy, pyrolysis–gas chromatography mass spectrometry, and electron microscopy, but standardization of these methods remains a significant challenge. Microplastics can disrupt seed germination, root structure, nutrient absorption, photosynthesis, oxidative homeostasis, biomass buildup, yield development, and quality. Further, their capacity to transport additives, plasticizers, heavy metals, and persistent organic pollutants raises concerns about the transfer of contaminants to edible plant parts and their potential transfer to human diets. Further studies are needed focusing on field-realistic exposure conditions, long-term crop–soil interactions, nanoplastics behaviour, standardised analysis procedures, uptake and translocation pathways, edible crop risk assessments, and sustainable mitigation approaches to reduce microplastics in agroecosystems. Full article

The electrochemical performance of hydrogen compressors (EHCs) depends critically on the hierarchical microstructure of their catalyst layers (CLs), where platinum, carbon, and ionomer phases govern coupled charge and mass transport across nanometric (Nano) and mesoporous (Meso) scales, the latter characterized by agglomerate and pore phases. This work presents an experimental–computational framework to establish quantitative microstructure–transport–performance relationships in EHC CLs. CLs were fabricated by electrospray deposition on Nafion^® 117 membranes and characterized by scanning electron microscopy, from which 33 representative Meso MCs were extracted and used to assemble an EHC cell for experimental polarization curves. Statistically equivalent Nano MCs resolved phase connectivity within the agglomerate phase and determined the effective catalyst area from neighboring phase configurations. Effective transport coefficients for electronic conductivity, protonic conductivity, and H₂ diffusivity were computed via the finite volume method and multiscale-coupled into an analytical polarization model. Electronic and protonic conductivities are controlled by conductive-phase connectivity at the Nano scale, while H₂ diffusivity is governed by the pore fraction and spatial distribution at the Meso scale, with variations exceeding three orders of magnitude. Multiscale transport coupling factors obtained via inverse calibration reduced model–experiment discrepancies to 0.05 V, validating the framework for EHC electrode design. Full article

Hydrogen-rich shaft furnaces operated with coke oven gas (COG) represent an important low-carbon ironmaking route. Conventional porous-medium CFD models, however, do not explicitly resolve geometry-dependent burden descent or downward advection of solid sensible heat in variable-cross-section moving beds. To address this gap, a user-defined-scalar (UDS)-based pseudo-fluid moving-bed dual-temperature CFD framework is developed in this study. The framework couples geometry-dependent pseudo-solid kinematics, UDS-based transport of pseudo-solid species and sensible enthalpy, and a 12-step reduction-reforming-carbon reaction network on a fixed Eulerian mesh. It is applied to a 0.5 Mt·a⁻¹ industrial reactor through one reference case and three parametric groups covering solid descent velocity, cooling-side back pressure, and CH₄ content. Mesh-independence and mass-conservation checks indicate that the medium mesh is adequate for the intended trend-level assessment; the fine-to-medium deviations are 0.54% for DRI metallization, 0.23% for DRI outlet temperature, and 0.20% for top-gas temperature, with a net global mass residual of 1.53 × 10⁻⁶ kg·s⁻¹; the baseline DRI metallization (96.3%), carbon content (1.1%), and combined H₂ + CO utilization (29.45%) all fall within the reported ranges of the HBIS demonstration line and Energiron-ZR projects. As the descent velocity increases from 2.88 to 6.72 × 10⁻⁴ m·s⁻¹, DRI metallization drops from 98.0% to 79.4% and the outlet temperature rises from 313.3 to 719.4 K. Increasing the cooling-gas outlet back pressure from 60 to 100 kPa reduces the cooling-outlet excess flow from 1.49 to 0.11 kg·s⁻¹, indicating a dynamic gas-seal control between the two gas circuits, whereas raising the inlet CH₄ fraction from 10 to 23 vol% lowers the apparent CH₄ conversion from 29.5% to 18.5% and broadens the carbon-deposition zone. The framework offers a continuum basis for proof-of-concept and trend-level analysis of variable-cross-section hydrogen-rich moving-bed shaft furnaces. Full article