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Keywords = mafic sills

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19 pages, 11500 KiB  
Article
Continental Rift Driven by Asthenosphere Flow and Lithosphere Weakening by Flood Basalts: South America and Africa Cenozoic Rifting
by Ingo L. Stotz, Berta Vilacís, Jorge N. Hayek and Hans-Peter Bunge
Minerals 2025, 15(6), 644; https://doi.org/10.3390/min15060644 - 13 Jun 2025
Viewed by 494
Abstract
Continental rifting is the process by which land masses separate and create new ocean basins. The emplacement of large igneous provinces (LIPs) is thought to have played a key role in (super) continental rifting; however, this relationship remains controversial due to the lack [...] Read more.
Continental rifting is the process by which land masses separate and create new ocean basins. The emplacement of large igneous provinces (LIPs) is thought to have played a key role in (super) continental rifting; however, this relationship remains controversial due to the lack of a clearly established mechanism linking LIP emplacement to continental fragmentation. Here, we show that plume flow links LIP magmatism to continental rifting quantitatively. Our findings are further supported by the sedimentary record, as well as by the mineralogy and petrology of the rocks. This study analyzes the early Cretaceous separation of West Gondwana into South America and Africa. Prior to rifting, Jurassic hiatuses in the stratigraphic record of continental sediments from both continents indicate plume ascent and the resulting dynamic topography. Cretaceous mafic dyke swarms and sill intrusions are products of major magmatic events that coincided with continental rifting, leading to the formation of large igneous provinces in South America and Africa, including the Central Atlantic Magmatic Province, Equatorial Magmatic Province, Paraná–Etendeka, and Karoo. It has been suggested that dyke intrusions may weaken the lithosphere by reducing its mechanical strength, creating structural weaknesses that localize extensional deformation and facilitate rift initiation. The sedimentary analysis and petrological evidence from flood basalt magmas indicate that plumes may have migrated from the depths toward the surface during the Jurassic and erupted during the Cretaceous. It is thought that the resulting fast plume flow, induced by one or more mantle plumes, generated a dynamic force that, in combination with lithospheric weakening from dyke intrusion, eventually rifted the lithosphere of West Gondwana. Full article
(This article belongs to the Special Issue Large Igneous Provinces: Research Frontiers)
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12 pages, 9358 KiB  
Article
Constraints on the Geometry of Peripheral Faults above Mafic Sills in the Tarim Basin, China: Kinematic and Mechanical Approaches
by Zewei Yao
Appl. Sci. 2024, 14(19), 8621; https://doi.org/10.3390/app14198621 - 24 Sep 2024
Viewed by 930
Abstract
Host rock deformation associated with sill emplacement is used to constrain magma transfer and storage within the upper crust. In contrast to classic models suggesting that the host rock above mafic sills is dominated by elastic bending, recent studies show that bounding faults [...] Read more.
Host rock deformation associated with sill emplacement is used to constrain magma transfer and storage within the upper crust. In contrast to classic models suggesting that the host rock above mafic sills is dominated by elastic bending, recent studies show that bounding faults that limit the uplift area can occur at the peripheries of a mafic sill. However, the accurate dip of this type of fault, named peripheral faults here, is still not well constrained. Their origin is also controversial in some cases. In this study, kinematic modeling and limit analysis are performed to better constrain the structure and mechanical properties of the peripheral faults based on seismic interpretation of a mafic sill from the Tarim Basin, China. The trishear kinematic model successfully reproduces peripheral faulting and associated folding of the host rock by performing a displacement of 58 m on a vertical fault plane with a fault propagation (P) to fault slip (S) ratio of 2.5. The limit analysis also predicts vertical damage at the sill tip by sill inflation. These results suggest that the dip angle of the fault in the case study is 90°, which is more accurate than that from the seismic interpretation with an 88° inward dip. This value may vary in other cases as it depends on the sill geometry (such as diameter and inclination), thickness, depth, and mechanical properties of the host rock. The study supports that peripheral faulting and associated folding can occur at the tips of the mafic sill due to the vertical uplift of the host rock caused by sill inflation. It is also suggested that trishear kinematic modeling and limit analysis are effective methods for studying the geometry of peripheral faults. Full article
(This article belongs to the Special Issue Seafloor Magmatic and Hydrothermal Activity)
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13 pages, 31812 KiB  
Article
Spatial and Temporal Distribution of Igneous Sills in the Central Tarim Basin and Their Geological Implications
by Zewei Yao
Minerals 2024, 14(9), 862; https://doi.org/10.3390/min14090862 - 24 Aug 2024
Cited by 3 | Viewed by 1432
Abstract
Interpretation of the seismic reflection profiles associated with borehole data from the petroleum industry offers a novel way to study sill emplacement in sedimentary basins. This study uses this approach to reveal the intrusive part of the Tarim Large Igneous Province (LIP) within [...] Read more.
Interpretation of the seismic reflection profiles associated with borehole data from the petroleum industry offers a novel way to study sill emplacement in sedimentary basins. This study uses this approach to reveal the intrusive part of the Tarim Large Igneous Province (LIP) within the basin, which has not been systematically reported. A large number of igneous intrusions (sills) are identified in the sedimentary layers of the Central Tarim Basin. The burial depth of the sills is 6–8 km, and they are mainly located within the upper Ordovician strata. According to their seismic facies and drilling data, it is inferred that they are dolerite sills. Based on the uplift of the overlying strata above the intrusions, it is concluded that the sills were mainly formed during the depositional period of the middle Permian Kupukuziman Formation and Kaipailezike Formation (early stage), with a few formed during the depositional period of the upper Permian strata (late stage). It is likely that these two stages of sill intrusion correspond to the main basaltic eruptions within the basin and the mafic dike emplacement in the Bachu area of the Tarim LIP, respectively. The study suggests that that the dolerite sills reported in this study are also an important component of the Permian Tarim LIP. Full article
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19 pages, 5698 KiB  
Article
Mesoproterozoic (ca. 1.3 Ga) A-Type Granites on the Northern Margin of the North China Craton: Response to Break-Up of the Columbia Supercontinent
by Bo Liu, Shengkai Jin, Guanghao Tian, Liyang Li, Yueqiang Qin, Zhiyuan Xie, Ming Ma and Jiale Yin
Minerals 2024, 14(6), 622; https://doi.org/10.3390/min14060622 - 18 Jun 2024
Viewed by 1668
Abstract
Mesoproterozoic (ca. 1.3 Ga) magmatism in the North China Craton (NCC) was dominated by mafic intrusions (dolerite sills) with lesser amounts of granitic magmatism, but our lack of knowledge of this magmatism hinders our understanding of the evolution of the NCC during this [...] Read more.
Mesoproterozoic (ca. 1.3 Ga) magmatism in the North China Craton (NCC) was dominated by mafic intrusions (dolerite sills) with lesser amounts of granitic magmatism, but our lack of knowledge of this magmatism hinders our understanding of the evolution of the NCC during this period. This study investigated porphyritic granites from the Huade–Kangbao area on the northern margin of the NCC. Zircon dating indicates the porphyritic granites were intruded during the Mesoproterozoic between 1285.4 ± 2.6 and 1278.6 ± 6.1 Ma. The granites have high silica contents (SiO2 = 63.10–73.73 wt.%), exhibit alkali enrichment (total alkalis = 7.71–8.79 wt.%), are peraluminous, and can be classified as weakly peraluminous A2-type granites. The granites have negative Eu anomalies (δEu = 0.14–0.44), enrichments in large-ion lithophile elements (LILEs; e.g., K, Rb, Th, and U), and depletions in high-field-strength elements (HFSEs; e.g., Nb, Ta, and Ti). εHf(t) values range from –6.43 to +2.41, with tDM2 ages of 1905–2462 Ma, suggesting the magmas were derived by partial melting of ancient crustal material. The geochronological and geochemical data, and regional geological features, indicate the Mesoproterozoic porphyritic granites from the northern margin of the NCC formed in an intraplate tectonic setting during continental extension and rifting, which represents the response of the NCC to the break-up of the Columbia supercontinent. Full article
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19 pages, 5970 KiB  
Article
Origin of Redbeds in the Neoproterozoic Socheong Formation and Their Relation to the Dashigou Large Igneous Province
by Hawon Yun, Seung Hwan Lee and Inah Seo
Minerals 2024, 14(1), 59; https://doi.org/10.3390/min14010059 - 2 Jan 2024
Viewed by 1790
Abstract
During the latest Mesoproterozoic–Early Neoproterozoic era, extensional regimes generated a number of sedimentary basins in various regions in the Sino-Korean Craton. Mantle-plume emplacements are widely recognized in the sedimentary strata as mafic dikes and sills of the Dashigou Large Igneous Province (LIP). The [...] Read more.
During the latest Mesoproterozoic–Early Neoproterozoic era, extensional regimes generated a number of sedimentary basins in various regions in the Sino-Korean Craton. Mantle-plume emplacements are widely recognized in the sedimentary strata as mafic dikes and sills of the Dashigou Large Igneous Province (LIP). The occurrence of Fe-rich redbeds is first reported in the Neoproterozoic Socheong Formation of the Sangwon Supergroup in the Pyeongnam Basin. Their geochemical and mineralogical characteristics indicate basin-wide Fe enrichment due to hydrothermal fluid input. The episodic yet repetitive hydrothermal injection into the basin generated short-lived anoxia, recorded as greenish-gray coloration in the ferruginous beds. This hydrothermal fluid was likely sourced from the mafic igneous activities involved in the Dashigou LIP. The redbeds can be utilized as key beds for intra- or inter-basinal stratigraphic correlation and to study the negative carbon isotope excursions that occurred in the genetically related basins in the region (e.g., the Sangwon, Xu-Huai, and Dalian basins). Full article
(This article belongs to the Special Issue Large Igneous Provinces: Research Frontiers)
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19 pages, 18955 KiB  
Article
Re-Os Systematics in the Layered Rocks and Cu-Ni-PGE Sulfide Ores from the Dovyren Intrusive Complex in Southern Siberia, Russia: Implications for the Original Mantle Source and the Effects of Two-Stage Crustal Contamination
by Alexey A. Ariskin, Svetlana G. Tessalina, Yuri A. Kostitsyn, Ivan V. Pshenitsyn, Sergei N. Sobolev, Georgy S. Nikolaev and Evgeny V. Kislov
Minerals 2023, 13(11), 1356; https://doi.org/10.3390/min13111356 - 24 Oct 2023
Cited by 1 | Viewed by 1616
Abstract
The Dovyren Intrusive Complex (Northern Baikal region, 728 ± 3 Ma) includes the dunite–troctolite–gabbronorite Yoko–Dovyren massif (YDM) associated with a sequence of underlying mafic-to-ultramafic sills, locally demonstrating interbedding relations with the most primitive rocks of the pluton. These sills and apophyses contain sulfide [...] Read more.
The Dovyren Intrusive Complex (Northern Baikal region, 728 ± 3 Ma) includes the dunite–troctolite–gabbronorite Yoko–Dovyren massif (YDM) associated with a sequence of underlying mafic-to-ultramafic sills, locally demonstrating interbedding relations with the most primitive rocks of the pluton. These sills and apophyses contain sulfide mineralization ranging from globular to net-textured and massive ores. Major types of the YDM cumulates and sulfide mineralization were examined for their PGE contents and Re-Os isotopic systematics. The ten analyzed samples included chilled and basal rocks, poorly mineralized troctolite, PGE-rich anorthosite, as well as three samples from a thick ore-bearing apophysis DV10 connected with the YDM. These samples yielded a Re-Os isochron with an age of 759 ± 36 Ma and an initial 187Os/188Os of 0.1309 ± 0.0026 (MSWD = 110), which is in consistent with the previously reported U–Pb zircon age. It is shown that being recalculated to γOs(t) at t = 728 Ma, these isotopic compositions demonstrate three clusters regarding the relationship between γOs(t) and 187Re/188Os: (i) the chilled gabbronorite (YDM) and subcontact olivine gabbronorite (DV10) yielded the most radiogenic values of γOs(t) 10.5 and 10.0 among basal ultramafics, (ii) plagiodunite, troctolite, and sulfide ores showed lower radiogenic compositions, with γOs(t) ranging from 7.3 to 8.7, (iii) olivine gabbronorite, plagioperidotite, and one sample of PGE-rich anorthosite yield very primitive γOs(t) in the range 4.5 to 5.6 (on average 5.2 ± 0.6). The lowest values of γOs(t) for the least fractionated rocks of the YDM suggest a primitive mantle source, formed from a partly contaminated Neoarchean protolith, which is considered to be anomalous in Upper Riphean due to very low εNd(t) of −16 for the most primitive Dovyren magma (Fo88-parent). The highest values of γOs(t) and relative enrichment in the 34S isotope in the chilled gabbronorite (YDM) and subcontact olivine gabbronorite (DV10) evidence that their primitive to evolved magmatic precursors could be affected by a metamorphic fluid enriched in radiogenic 187Os, originating in the exocontact halo due to the thermal decomposition of pyrite from the dehydrated country rocks. This is consistent with the second-stage contamination of the Dovyren magma by the hosting crustal rocks (probably of 10 wt% shists), generating more evolved Fo86-parent magma with higher εNd(t) of −14. Full article
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28 pages, 24421 KiB  
Article
Paleoproterozoic East Pana Layered Intrusion (Kola Peninsula, Russia): Geological Structure, Petrography, Geochemistry and Cu-Ni-PGE Mineralization
by Pavel Pripachkin, Tatiana Rundkvist and Nikolay Groshev
Minerals 2023, 13(5), 681; https://doi.org/10.3390/min13050681 - 16 May 2023
Cited by 2 | Viewed by 1914
Abstract
The East Pana intrusion is a part of the Paleoproterozoic Fedorova–Pana complex (FPC), which belongs to the group of Fennoscandian layered mafic–ultramafic massifs. This article discusses the magmatic stratification of the East Pana intrusion, as well as Cu-Ni and platinum-group elements (PGE) mineralization [...] Read more.
The East Pana intrusion is a part of the Paleoproterozoic Fedorova–Pana complex (FPC), which belongs to the group of Fennoscandian layered mafic–ultramafic massifs. This article discusses the magmatic stratification of the East Pana intrusion, as well as Cu-Ni and platinum-group elements (PGE) mineralization (PGE zones A, B and C) in its various parts with a total length of more than 20 km, including the East Chuarvy PGE deposit. Based on the whole-rock data on the distribution of major, trace, and ore-forming elements, it is assumed that PGE zone A belongs to the main ore–magmatic system of the FPC, while PGE zones B and C belong to the minor ore–magmatic systems. At the same time, additional magmatic injection played an important role in the formation of economic Cu-Ni-PGE mineralization (PGE zone B), characterized by high PGE concentrations and moderate palladium enrichment. On the normalized distribution spectra of trace elements, the crystallization products of this injection (Gabbronorite Zone 2) have a positive Zr-Hf anomaly, which distinguishes it from host rocks with an anomaly of the opposite sign (Gabbronorite Zone 1, Gabbro Zone). It is assumed that this portion of magma was intruded as a sill of crystal mush, the fractionation of which at depth led to its enrichment with residual liquid. Full article
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26 pages, 12441 KiB  
Article
First Evidence of the Post-Variscan Magmatic Pulse on the Western Edge of East European Craton: U-Pb Geochronology and Geochemistry of the Dolerite in the Lublin Podlasie Basin, Eastern Poland
by Ewa Krzemińska, Leszek Krzemiński, Paweł Poprawa, Jolanta Pacześna and Krzysztof Nejbert
Minerals 2021, 11(12), 1361; https://doi.org/10.3390/min11121361 - 2 Dec 2021
Cited by 3 | Viewed by 3454
Abstract
The U–Pb measurements of youngest, coherent group of zircons from the Mielnik IG1 dolerite at the Teisseyre-Tornquist margin (TTZ) of East European Craton (EEC) in Poland yielded age of 300 ± 4 Ma. Zircon dated an evolved portion of magma at the late [...] Read more.
The U–Pb measurements of youngest, coherent group of zircons from the Mielnik IG1 dolerite at the Teisseyre-Tornquist margin (TTZ) of East European Craton (EEC) in Poland yielded age of 300 ± 4 Ma. Zircon dated an evolved portion of magma at the late stage crystallization. It is shown that this isolated dyke from the northern margin of the Lublin Podlasie basin (Podlasie Depression) and regional dyke swarms of close ages from the Swedish Scania, Bornholm and Rügen islands, Oslo rift, Norway, and the Great Whine Sill in northeastern England, were coeval. They have been controlled by the same prominent tectonic event. The Mielnik IG1 dolerite is mafic rock with Mg-number between 52 and 50 composed of the clinopyroxene, olivine-pseudomorph, plagioclase, titanite, magnetite mineral assemblage, indicating relatively evolved melt. This hypabyssal rock has been affected by postmagmatic alteration. The subalkaline basalt composition, enrichment in incompatible trace elements, progressive crustal contamination, including abundance of zircon xenocrysts determines individual characteristics of the Mielnik IG1 dolerite. The revised age of dolerite, emplaced in vicinity of TTZ provides more evidences documenting the reach of the Permo-Carboniferous extension and rifting accompanied by magmatic pulses, that were widespread across Europe including the margin of the EEC incorporated that time into the broad foreland of the Variscan orogen. Full article
(This article belongs to the Special Issue East European Craton—From Crustal Growth to Sedimentary Cover)
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23 pages, 13068 KiB  
Article
Late Ordovician Mafic Magmatic Event, Southeast Siberia: Tectonic Implications, LIP Interpretation, and Potential Link with a Mass Extinction
by Andrey K. Khudoley, Andrei V. Prokopiev, Kevin R. Chamberlain, Aleksandr D. Savelev, Richard E. Ernst, Sergey V. Malyshev, Artem N. Moskalenko and Olga Yu. Lebedeva
Minerals 2020, 10(12), 1108; https://doi.org/10.3390/min10121108 - 10 Dec 2020
Cited by 11 | Viewed by 3233
Abstract
A geochronological, isotopic, and geochemical study of the Suordakh event of mafic magmatic intrusions on the southeast Siberian margin was undertaken. U-Pb baddeleyite dating of a mafic sill intruding lower Cambrian rocks, yielded a 458 ± 13 Ma emplacement age. The chemical composition [...] Read more.
A geochronological, isotopic, and geochemical study of the Suordakh event of mafic magmatic intrusions on the southeast Siberian margin was undertaken. U-Pb baddeleyite dating of a mafic sill intruding lower Cambrian rocks, yielded a 458 ± 13 Ma emplacement age. The chemical composition and stratigraphic setting of this dated sill differed from that previously attributed to the Suordakh event, implying that additional intrusions, previously mapped as Devonian, potentially belonged to the Suordakh event. No correlation between L.O.I. and concentration of highly mobile major and trace elements was documented, showing small or no influence of hydrothermal alteration on the chemical composition of the intrusions. A new tectonic reconstruction located an island arc and active margin relatively close to the study area. However, all samples had chemical compositions close to that of OIB and did not display Ta-Nb and Ti-negative anomalies, nor other features typical for subduction-related magmatism. The major and trace element distribution was most characteristic of within-plate basalts with the mantle source composition being transitional from spinel to garnet lherzolite. Combining four U-Pb baddeleyite dates of mafic sills and dykes from southeast Siberia, the age of the Suordakh event was estimated at 454 ± 10 Ma. The area of the Suordakh event was at least 35,000–40,000 km2 (an estimate including sills previously interpreted as Devonian), and could be increased with additional dating in Southeastern Siberia. Similar ages for within-plate intrusions were reported from South Korea, West Mongolia, South Argentina, North Iran and Northwest Canada, and these ca. 450 Ma ages were collectively close in timing with the latest Ordovician (Hirnantian) mass extinction. More high-precision dating is necessary to fully test a link between the Suordakh event (and the other age-correlative events) and the end-Ordovician mass extinction. Full article
(This article belongs to the Section Mineral Deposits)
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19 pages, 5388 KiB  
Article
Extensive Sills in the Continental Basement from Deep Seismic Reflection Profiling
by Larry D. Brown and Doyeon Kim
Geosciences 2020, 10(11), 449; https://doi.org/10.3390/geosciences10110449 - 10 Nov 2020
Cited by 12 | Viewed by 4009
Abstract
Crustal seismic reflection profiling has revealed the presence of extensive, coherent reflections with anomalously high amplitudes in the crystalline crust at a number of locations around the world. In areas of active tectonic activity, these seismic “bright spots” have often been interpreted as [...] Read more.
Crustal seismic reflection profiling has revealed the presence of extensive, coherent reflections with anomalously high amplitudes in the crystalline crust at a number of locations around the world. In areas of active tectonic activity, these seismic “bright spots” have often been interpreted as fluid magma at depth. The focus in this report is high-amplitude reflections that have been identified or inferred to mark interfaces between solid mafic intrusions and felsic to intermediate country rock. These “frozen sills” most commonly appear as thin, subhorizontal sheets at middle to upper crustal depths, several of which can be traced for tens to hundreds of kilometers. Their frequency among seismic profiles suggest that they may be more common than widely realized. These intrusions constrain crustal rheology at the time of their emplacement, represent a significant mode of transfer of mantle material and heat into the crust, and some may constitute fingerprints of distant mantle plumes. These sills may have played important roles in overlying basin evolution and ore deposition. Full article
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20 pages, 8106 KiB  
Article
Meso-Neoproterozoic Mafic Sills along the South-Eastern Margin of the Siberian Craton, SE Yakutia: Petrogenesis, Tectonic and Geochemical Features
by Aleksandr D. Savelev, Sergey V. Malyshev, Valery M. Savatenkov, Daniil D. Ignatov and Anastasia D. Kuzkina
Minerals 2020, 10(9), 805; https://doi.org/10.3390/min10090805 - 12 Sep 2020
Cited by 7 | Viewed by 3391
Abstract
We report major and trace element concentrations, along with Nd isotope compositions, for Late Mesoproterozoic to Early Neoproterozoic dolerite sills from the Sette-Daban ridge (southern Verkhoyansk, south-east Siberia). Based on their major element composition, all rocks correspond to low-Ti (<3 wt% TiO2 [...] Read more.
We report major and trace element concentrations, along with Nd isotope compositions, for Late Mesoproterozoic to Early Neoproterozoic dolerite sills from the Sette-Daban ridge (southern Verkhoyansk, south-east Siberia). Based on their major element composition, all rocks correspond to low-Ti (<3 wt% TiO2) moderately alkaline basalts. The intrusions can be subdivided into two groups based on their trace element compositions. One group includes sills mainly distributed in the southern part of the study area (Yudoma group), with mid-ocean ridge basalt (MORB) trace element patterns enriched in aqueous fluid mobile incompatible (FMI) elements (Sr, Pb, Ba, U). The second group includes sills mostly distributed in the northern part of the study area, enriched in immobile incompatible (II) elements (Th, Nb, light rare earth elements (LREE)) and to a lesser extent, in aqueous fluid mobile elements. The Nd isotope signatures of the dolerites characterize a depleted mantle source, with a small enrichment from recycled continental crust. The geochemical characteristics of these igneous rocks are analogous to low-Ti basalts of large intraplate provinces (e.g., the Karoo and Siberian Traps). We propose that they formed by rifting-induced melting of the heterogeneous metasomatized shallow spinel-bearing mantle zone. We suggest that two different melting sources were involved in the generation of the two geochemically distinct sill groups, including the addition of two different subduction components. The southern sills were formed by melting of depleted lithospheric mantle enriched with FMI elements, corresponding to subduction-induced metasomatic alteration by fluids at shallow depths. The northern dolerites were formed by melting of depleted lithospheric mantle enriched with II elements, associated with the melting of subducted sediments at deeper depths. Full article
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16 pages, 4080 KiB  
Article
The Gersdorffite-Bismuthinite-Native Gold Association and the Skarn-Porphyry Mineralization in the Kamariza Mining District, Lavrion, Greece
by Panagiotis Voudouris, Constantinos Mavrogonatos, Branko Rieck, Uwe Kolitsch, Paul G. Spry, Christophe Scheffer, Alexandre Tarantola, Olivier Vanderhaeghe, Emmanouil Galanos, Vasilios Melfos, Stefanos Zaimis, Konstantinos Soukis and Adonis Photiades
Minerals 2018, 8(11), 531; https://doi.org/10.3390/min8110531 - 16 Nov 2018
Cited by 13 | Viewed by 6641
Abstract
Vein-type Pb-Ni-Bi-Au-Ag mineralization at the Clemence deposit in the Kamariza and “km3” in the Lavrion area, was synchronous with the intrusion of a Miocene granodiorite body and related felsic and mafic dikes and sills within marbles and schists in the footwall of (and [...] Read more.
Vein-type Pb-Ni-Bi-Au-Ag mineralization at the Clemence deposit in the Kamariza and “km3” in the Lavrion area, was synchronous with the intrusion of a Miocene granodiorite body and related felsic and mafic dikes and sills within marbles and schists in the footwall of (and within) the Western Cycladic detachment system. In the Serpieri deposit (Kamariza area), a porphyry-style pyrrhotite-arsenopyrite mineralized microgranitic dike is genetically related to a garnet-wollastonite bearing skarn characterized by a similar base metal and Ni (up to 219 ppm) enrichment. The Ni–Bi–Au association in the Clemence deposit consists of initial deposition of pyrite and arsenopyrite followed by an intergrowth of native gold-bismuthinite and oscillatory zoned gersdorffite. The zoning is related to variable As, Ni, and Fe contents, indicating fluctuations of arsenic and sulfur fugacity in the hydrothermal fluid. A late evolution towards higher sulfur fugacity in the mineralization is evident by the deposition of chalcopyrite, tennantite, enargite, and galena rimming gersdorffite. At the “km3” locality, Ni sulfides and sulfarsenides, vaesite, millerite, ullmannite, and polydymite, are enclosed in gersdorffite and/or galena. The gersdorffite is homogenous and contains less Fe (up to 2 wt.%) than that from the Clemence deposit (up to 9 wt.%). Bulk ore analyses of the Clemence ore reveal Au and Ag grades both exceeding 100 g/t, Pb and Zn > 1 wt.%, Ni up to 9700 ppm, Co up to 118 ppm, Sn > 100 ppm, and Bi > 2000 ppm. The “km3” mineralization is enriched in Mo (up to 36 ppm), Ni (>1 wt.%), and Co (up to 1290 ppm). Our data further support a magmatic contribution to the ore-forming fluids, although remobilization and leaching of metals from previous mineralization and/or host rocks, through the late involvement of non-magmatic fluid in the ore system, cannot be excluded. Full article
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