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Search Results (445)

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514 KB  
Article
Investigation of the Variants of Independent Elastic Constants of Rigid Polyurethane Foams with Symmetry Elements
by Aivars Lagzdiņš, Ilze Beverte, Vilis Skruls and Jānis Andersons
Polymers 2025, 17(17), 2431; https://doi.org/10.3390/polym17172431 (registering DOI) - 8 Sep 2025
Abstract
Rigid PU foams have wide practical applications, and their mathematical modelling would benefit from deeper knowledge about the variants of independent elastic constants of symmetric PU foams. Therefore, in this study, various symmetry elements of rigid PU foams were analysed in relation to [...] Read more.
Rigid PU foams have wide practical applications, and their mathematical modelling would benefit from deeper knowledge about the variants of independent elastic constants of symmetric PU foams. Therefore, in this study, various symmetry elements of rigid PU foams were analysed in relation to the characteristics of production moulds and technologies. The generalised Hooke’s law was considered together with additional relationships valid for certain types of symmetry. Variants of independent elastic constants were determined for orthotropic, orthotropic with a rotational symmetry, and isotropic PU foams. For transtropic PU foams, nine variants of independent elastic constants were identified and corresponding equations for the components of response strain tensor were derived. Then, in order to investigate the results provided by the 9 variants, 12 elastic constants were determined experimentally in compression and shear for free-rise, rigid, and quasi-transtropic PU foams with average densities of 34 kg/m3, 55 kg/m3, and 75 kg/m3. Based on the analysis of (a) measurement uncertainties and (b) satisfying of the transtropy equations, an assessment was made of the correspondence of the experimentally determined elastic constants to the constants of a perfectly transtropic material. This made it possible to identify variants of independent constants that ensure the best correspondence between the calculated strains and the set of average strains. Full article
13 pages, 1794 KB  
Article
A New Constitutive Relation for Homogeneous Isotropic Materials by FEM Model of the Brazilian Splitting Test
by Salvatore Benfratello, Antonino Cirello and Luigi Palizzolo
Sci 2025, 7(3), 110; https://doi.org/10.3390/sci7030110 - 3 Aug 2025
Viewed by 405
Abstract
The paper studies the behavior of homogeneous isotropic materials by performing appropriate numerical analyses and utilizing suitable FEMs to reproduce the Brazilian splitting test. Starting with a theoretical approach and adopting suitable numerical simulations, a new formula that is able to characterize the [...] Read more.
The paper studies the behavior of homogeneous isotropic materials by performing appropriate numerical analyses and utilizing suitable FEMs to reproduce the Brazilian splitting test. Starting with a theoretical approach and adopting suitable numerical simulations, a new formula that is able to characterize the Young’s modulus is presented. To this end, in addition to the analysis of the specimen’s response in terms of stresses and strains, the real displacement field resulting from the real kinematical constraints on the specimen is determined. Therefore, the Brazilian test is taken as a reference test and the specimen’s behavior is derived by taking advantage of both the theoretical approach and numerical simulations developed in the ANSYS 2021 R1 environment. The latter allows us to define a new mathematical relation representing the missing part of the kinematical field. Furthermore, a new formula which explicitly relates the Young’s modulus of the material to the geometrical characteristics of the specimen, to the acting force, and to a measured selected displacement is proposed. Future developments will include adopting the proposed formulas for the identification of other mechanical parameters of the material, e.g., by adopting a full-field contactless approach to displacement measurement and studying the behavior of specimens with different geometrical characteristics. Full article
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22 pages, 9122 KB  
Article
Computational Mechanics of Polymeric Materials PEEK and PEKK Compared to Ti Implants for Marginal Bone Loss Around Oral Implants
by Mohammad Afazal, Saba Afreen, Vaibhav Anand and Arnab Chanda
Prosthesis 2025, 7(4), 93; https://doi.org/10.3390/prosthesis7040093 - 1 Aug 2025
Viewed by 503
Abstract
Background/Objectives: Dental practitioners widely use dental implants to treat traumatic cases. Titanium implants are currently the most popular choice among dental practitioners and surgeons. The discovery of newer polymeric materials is also influencing the interest of dental professionals in alternative options. A comparative [...] Read more.
Background/Objectives: Dental practitioners widely use dental implants to treat traumatic cases. Titanium implants are currently the most popular choice among dental practitioners and surgeons. The discovery of newer polymeric materials is also influencing the interest of dental professionals in alternative options. A comparative study between existing titanium implants and newer polymeric materials can enhance professionals’ ability to select the most suitable implant for a patient’s treatment. This study aimed to investigate material property advantages of high-performance thermoplastic biopolymers such as PEEK and PEKK, as compared to the time-tested titanium implants, and to find the most suitable and economically fit implant material. Methods: Three distinct implant material properties were assigned—PEEK, PEKK, and commercially pure titanium (CP Ti-55)—to dental implants measuring 5.5 mm by 9 mm, along with two distinct titanium (TI6AL4V) abutments. Twelve three-dimensional (3D) models of bone blocks, representing the mandibular right molar area with Osseo-integrated implants were created. The implant, abutment, and screw were assumed to be linear; elastic, isotropic, and orthotropic properties were attributed to the cancellous and cortical bone. Twelve model sets underwent a three-dimensional finite element analysis to evaluate von Mises stress and total deformation under 250 N vertical and oblique (30 degree) loads on the top surface of each abutment. Results: The study revealed that the time-tested titanium implant outperforms PEEK and PEKK in terms of marginal bone preservation, while PEEK outperforms PEKK. Conclusions: This study will assist dental practitioners in selecting implants from a variety of available materials and will aid researchers in their future research. Full article
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16 pages, 2159 KB  
Article
A New Depth-Averaged Eulerian SPH Model for Passive Pollutant Transport in Open Channel Flows
by Kao-Hua Chang, Kai-Hsin Shih and Yung-Chieh Wang
Water 2025, 17(15), 2205; https://doi.org/10.3390/w17152205 - 24 Jul 2025
Cited by 1 | Viewed by 389
Abstract
Various nature-based solutions (NbS)—such as constructed wetlands, drainage ditches, and vegetated buffer strips—have recently demonstrated strong potential for mitigating pollutant transport in open channels and river systems. Numerical modeling is a widely adopted and effective approach for assessing the performance of these interventions. [...] Read more.
Various nature-based solutions (NbS)—such as constructed wetlands, drainage ditches, and vegetated buffer strips—have recently demonstrated strong potential for mitigating pollutant transport in open channels and river systems. Numerical modeling is a widely adopted and effective approach for assessing the performance of these interventions. This study presents the first development of a two-dimensional (2D) meshless advection–diffusion model based on an Eulerian smoothed particle hydrodynamics (SPH) framework, specifically designed to simulate passive pollutant transport in open channel flows. The proposed model marks a pioneering application of the ESPH technique to environmental pollutant transport problems. It couples the 2D depth-averaged shallow water equations with an advection–diffusion equation to represent both fluid motion and pollutant concentration dynamics. A uniform particle arrangement ensures that each fluid particle interacts symmetrically with eight neighboring particles for flux computation. To represent the pollutant transport process, the dispersion coefficient is defined as the sum of molecular and turbulent diffusion components. The turbulent diffusion coefficient is calculated using a prescribed turbulent Schmidt number and the eddy viscosity obtained from a Smagorinsky-type mixing-length turbulence model. Three analytical case studies, including one-dimensional transcritical open channel flow, 2D isotropic and anisotropic diffusion in still water, and advection–diffusion in a 2D uniform flow, are employed to verify the model’s accuracy and convergence. The model demonstrates first-order convergence, with relative root mean square errors (RRMSEs) of approximately 0.2% for water depth and velocity, and 0.1–0.5% for concentration. Additionally, the model is applied to a laboratory experiment involving 2D pollutant dispersion in a 90° junction channel. The simulated results show good agreement with measured velocity and concentration distributions. These findings indicate that the developed model is a reliable and effective tool for evaluating the performance of NbS in mitigating pollutant transport in open channels and river systems. Full article
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17 pages, 2928 KB  
Article
Comparison Between Broadband and Personal Exposimeter Measurements for EMF Exposure Map Development Using Evolutionary Programming
by Alberto Nájera, Rocío Sánchez-Montero, Jesús González-Rubio, Jorge Guillén-Pina, Ricardo Chocano-del-Cerro and Pablo-Luis López-Espí
Appl. Sci. 2025, 15(13), 7471; https://doi.org/10.3390/app15137471 - 3 Jul 2025
Viewed by 434
Abstract
In this study, we provide a comparison of radiofrequency electromagnetic field exposure level maps as determined using two approaches: a broadband meter (NARDA EMR-300) equipped with an isotropic probe in the range of 100 kHz to 3 GHz, and a Personal Exposimeter (Satimo [...] Read more.
In this study, we provide a comparison of radiofrequency electromagnetic field exposure level maps as determined using two approaches: a broadband meter (NARDA EMR-300) equipped with an isotropic probe in the range of 100 kHz to 3 GHz, and a Personal Exposimeter (Satimo EME Spy 140) in the range of 88 MHz to 5.8 GHz. The aim of this research was to determine the necessary adjustments to the measurements made with personal exposimeters to obtain RF-EMF exposure maps equivalent to those made with broadband meters. We evaluated different possibilities to obtain the best equivalence of measurements between both devices. For this purpose, the datasets obtained in both cases were analyzed, as well as the possible correction factors. First, the possibility of establishing a single or double correction factor depending on the existence (or lack thereof) of a line of sight with respect to the base stations was analyzed by minimizing the average value of the error between the values of the broadband meter and the corrected values of the personal exposure meter. Due to the differences observed in the exposure maps, a second procedure was carried out, in which a genetic algorithm was used to determine the ratio between the measurements from both methods (the broadband meter and personal exposure meter), depending on the existence (or lack thereof) of a line of sight, and we compared the exposure maps generated using kriging interpolation. Full article
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10 pages, 1554 KB  
Article
Investigating the Secondary Thermal Neutron Intensity of Neutron Capture-Enhanced Proton Therapy
by Takahiro Shimo, Shintaro Shiba, Hiroyuki Watanabe, Masashi Yamanaka, Kazuki Matsumoto, Akihiro Yamano, Hisato Nagano and Kohichi Tokuuye
Appl. Sci. 2025, 15(12), 6833; https://doi.org/10.3390/app15126833 - 17 Jun 2025
Viewed by 426
Abstract
This study aimed to investigate the distribution of thermal neutron fluence generated during proton-beam therapy (PBT) scanning, focusing on neutrons produced within the body using Monte Carlo simulations (MCSs). MCSs used the Particle and Heavy Ion Treatment Code System to define a 35 [...] Read more.
This study aimed to investigate the distribution of thermal neutron fluence generated during proton-beam therapy (PBT) scanning, focusing on neutrons produced within the body using Monte Carlo simulations (MCSs). MCSs used the Particle and Heavy Ion Treatment Code System to define a 35 × 35 × 35 cm3 water phantom, and proton-beam energies ranging from 70.2 to 228.7 MeV were investigated. The MCS results were compared with neutron fluence measurements obtained from gold activation analysis, showing good agreement with a difference of 3.54%. The internal thermal neutron distribution generated by PBT was isotropic around the proton-beam axis, with the Bragg peak depth varying between 3.45 and 31.9 cm, while the thermal neutron peak depth ranged from 5.41 to 15.9 cm. Thermal neutron generation depended on proton-beam energy, irradiated particle count, and depth. Particularly, the peak of the thermal neutron fluence did not occur within the treatment target volume but in a location outside the target, closer to the source. This discrepancy between the Bragg peak and the thermal neutron fluence peak is a key finding of this study. These data are crucial for optimizing beam angles to maximize dose enhancement within the target during clinical applications of neutron capture-enhanced particle therapy. Full article
(This article belongs to the Section Applied Physics General)
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14 pages, 4888 KB  
Article
Poloxamer-Driven Drug Delivery System for Anti-Inflammatory Drugs Using Small-Angle Neutron Scattering Approach
by Rodrigo Rhinow, Margareth K. K. D. Franco, Mont Kumpugdee Vollrath, Guinther Kellermann and Fabiano Yokaichiya
Gels 2025, 11(6), 410; https://doi.org/10.3390/gels11060410 - 30 May 2025
Viewed by 8620
Abstract
Poloxamer-based drug delivery systems are widely used in the pharmaceutical sector. The structural characterization of these systems is crucial for the development of new drug delivery systems and for the optimization of their properties. In this study, we utilized small-angle neutron scattering (SANS) [...] Read more.
Poloxamer-based drug delivery systems are widely used in the pharmaceutical sector. The structural characterization of these systems is crucial for the development of new drug delivery systems and for the optimization of their properties. In this study, we utilized small-angle neutron scattering (SANS) to investigate the structures of poloxamer-based drug delivery systems. The samples were measured using the SANS technique on the VSANS-V16 instrument at Helmholtz-Zentrum Berlin (HZB), Germany. The samples contained 20% poloxamer (P407) and 0.2% of a drug (ibuprofen, ketoprofen, diclofenac) in deuterated water (D2O) for SANS. The samples varied in terms of temperature analysis (25 °C, common storage temperature; 37 °C, human body temperature; 40 °C, fever temperature). The data analysis involved modeling the data using a Python-based routine. The model used consisted of an isotropic solution of polydisperse spherical micelles. The intensity as a function of the scattering vector was modeled as the product of the form factor and the interparticle structure factor, with the latter described within the local monodisperse approximation regime. Additionally, a scattering contribution was observed, which was associated with the presence of crystalline superstructures formed by micelles that organized into a cubic structure. The data analysis provided important information about the system, such as the average radius, the size distribution, and the thickness of the layer surrounding the micellar core. The results will contribute to the development and optimization of new drug delivery systems that are more effective and safer for medical applications. Full article
(This article belongs to the Special Issue Functional Gels Applied in Drug Delivery)
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12 pages, 1606 KB  
Article
Measurement Grid Optimization for OTA Testing of 5G Smart Watches
by Xudong An, Fei Liu, Meijun Qu and Siyang Sun
Sensors 2025, 25(10), 3185; https://doi.org/10.3390/s25103185 - 19 May 2025
Viewed by 471
Abstract
Over-the-air (OTA) testing is crucial for optimizing wireless performance of 5G smart watches and improving their user experience. However, the current required test time is so long that it is almost impossible to complete the entire OTA testing without recharging and repositioning, which [...] Read more.
Over-the-air (OTA) testing is crucial for optimizing wireless performance of 5G smart watches and improving their user experience. However, the current required test time is so long that it is almost impossible to complete the entire OTA testing without recharging and repositioning, which is unacceptable for the industry. Therefore, test-time reduction is significant. The objective of this work is to optimize measurement grids for OTA testing of 5G smart watches, which balance accuracy with efficiency. In this research, passive patterns from a typical 5G commercial smart watch are measured at different bands as reference patterns, which represent general radiation properties of 5G commercial smart watches. The effect of various coarse grids on OTA testing precision is characterized quantitatively by analyzing their accuracy in reconstructing reference patterns. The related measurement uncertainty (MU) terms are then evaluated and determined quantitatively based on statistical analysis. According to the derived MU limits for grid configurations, reducing grid points from currently required 62 (30/30) to 26 (45/45), and from 266 (15/15) to 62 (30/30) could save roughly 60% and 75% of the test time, respectively, with an uncertainty increase of 0.1 dB for both Total Isotropic Sensitivity (TIS) and Total Radiated Power (TRP) testing, which is considered acceptable. Furthermore, the feasibility of the proposed MU analysis and recommended grids have been experimentally verified. Full article
(This article belongs to the Special Issue Challenges and Future Trends in Antenna Technology)
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20 pages, 48436 KB  
Article
Characterising Through-Thickness Shear Anisotropy Using the Double-Bridge Shear Test and Finite Element Model Updating
by Bojan Starman, Bin Chen, Andraž Maček, Yi Zhang, Miroslav Halilovič and Sam Coppieters
Materials 2025, 18(10), 2220; https://doi.org/10.3390/ma18102220 - 11 May 2025
Viewed by 476
Abstract
The accuracy of numerical predictions in sheet metal processes involving multiaxial stress–strain states (e.g., blanking, riveting, and incremental forming) heavily depends on the characterisation of plastic anisotropy under multiaxial loading conditions. A fully calibrated 3D plastic anisotropy model is essential for this purpose. [...] Read more.
The accuracy of numerical predictions in sheet metal processes involving multiaxial stress–strain states (e.g., blanking, riveting, and incremental forming) heavily depends on the characterisation of plastic anisotropy under multiaxial loading conditions. A fully calibrated 3D plastic anisotropy model is essential for this purpose. While in-plane material behaviour can be conventionally characterised through uniaxial and equi-biaxial tensile tests, calibrating out-of-plane material behaviour remains a significant challenge. This behaviour, governed by out-of-plane shear stress and associated material parameters, is typically described by out-of-plane shear yielding. These parameters are notoriously difficult to determine, leading researchers to frequently assume isotropic behaviour or identical shear parameters for in-plane and out-of-plane responses. Although advanced calibrations may utilise crystal plasticity modelling, there remains a critical need for macro-mechanical characterisation methods. This paper presents an out-of-plane shear testing and material characterisation procedure based on full-field strain measurements using digital image correlation (DIC). Strains within the shear zone are measured via DIC and employed in the Finite Element Model Updating (FEMU) to identify out-of-plane shear parameters of a 2.42 mm thick, cold-rolled AW5754-H22 aluminium alloy sheet, using the Yld2004-18p yield criterion. Given that the characteristic strain response at this scale may be influenced by local crystal structure behaviour on the surface, this paper evaluates the feasibility of such measurements. Finally, to test the validity of the full-field-based approach, the FEMU-identified parameters are compared against results obtained through a classical optimisation procedure based on force-elongation measurements from the shear zone. Full article
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24 pages, 9196 KB  
Article
Assessment of Anisotropy in Cold In-Place Recycled Materials Using Shear Wave Velocity and Computed Tomography Analysis
by Quentin Lecuru, Yannic Ethier, Alan Carter and Mourad Karray
Infrastructures 2025, 10(5), 115; https://doi.org/10.3390/infrastructures10050115 - 8 May 2025
Viewed by 566
Abstract
Pavement materials like hot mix asphalt (HMA) and cold recycled mixes (CRMs) are typically considered isotropic. This study evaluates the anisotropy of a cold in-place recycled (CIR) material using the shear wave velocity (Vs) parameter. The piezoelectric ring actuator technique (P-RAT) [...] Read more.
Pavement materials like hot mix asphalt (HMA) and cold recycled mixes (CRMs) are typically considered isotropic. This study evaluates the anisotropy of a cold in-place recycled (CIR) material using the shear wave velocity (Vs) parameter. The piezoelectric ring actuator technique (P-RAT) is utilized to assess the Vs parameter in three directions in CIR slabs. Similarly, the ultrasonic pulse velocity (UPV) technique is employed to measure P-wave velocities. Both methods evaluate mechanical properties in multiple directions. Complex modulus tests are conducted to link velocities results to |E*| modulus. Finally, computed tomography (CT) scans are performed on the specimens in order to evaluate anisotropy resulting from aggregate alignment. The Vs obtained using P-RAT and the Vp from UPV indicate anisotropy, as the wave velocities differ across the three directions. Differences range from 0.6 to 11.6% in Vs, influenced by measurement location. UPV results are analysed in relation to the |E*| modulus master curves, demonstrating that the first peak arrival time for the P-wave corresponds with the master curve. CT scan analysis reveals that the aggregates tend to be more aligned in the direction of the compacting wheel’s displacement, which also highlights anisotropy. Full article
(This article belongs to the Special Issue Sustainable and Digital Transformation of Road Infrastructures)
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18 pages, 3725 KB  
Article
Statistical Structural Damage Detection of Functionally Graded Euler–Bernoulli Beams Based on Element Modal Strain Energy Sensitivity
by Delei Yang, Chunyan Kang, Sihan Cheng, Zhongming Hu and Adesola Ademiloye
Buildings 2025, 15(9), 1521; https://doi.org/10.3390/buildings15091521 - 1 May 2025
Viewed by 415
Abstract
In practical engineering, uncertainties inevitably exist in the models and measurement data used for structures. Therefore, a statistical strategy related to damage detection methods become crucial. In this paper, a probabilistic statistical damage detection method for FG Euler–Bernoulli beam structures is proposed, extending [...] Read more.
In practical engineering, uncertainties inevitably exist in the models and measurement data used for structures. Therefore, a statistical strategy related to damage detection methods become crucial. In this paper, a probabilistic statistical damage detection method for FG Euler–Bernoulli beam structures is proposed, extending the approach originally developed for isotropic materials. Our approach determines the probability of damage occurrence for each element, which aids in evaluating whether beam structures have been damaged. This evaluation is based on integrating the sensitivity of modal strain energy for each element with the perturbation method. To demonstrate the effectiveness and accuracy of the proposed method, several numerical examples are investigated. These examples include a simply supported FG Euler–Bernoulli beam subjected to both single and multiple element damages. The influence of gradient index, damage severity, boundary condition, and noise level on the accuracy of detection are also considered. The studies demonstrate that the probability of damage for each element remains relatively stable despite variations in the gradient indices. For the damaged elements, these probabilities approach 1, indicating that the proposed method effectively identifies damage in FG beams even when the gradient index varies. Additionally, as the level of damage increases, the accuracy of damage detection tends to improve. However, varying boundary conditions can substantially affect the outcomes of damage identification, potentially leading to inconsistencies in results. Furthermore, our proposed method demonstrates excellent resistance against noise levels of up to 5%. We also found that different boundary conditions have a great impact on the damage detection. Full article
(This article belongs to the Special Issue Recent Developments in Structural Health Monitoring)
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22 pages, 2421 KB  
Article
Effect of Blank-Holder Force in Springback of a Gas Cooktop Component Made from Non-Stable Austenitic 1.4301 Steel
by Cesar Aguado, Miguel Iglesias, Ana de-Juan and Pablo Garcia
Appl. Sci. 2025, 15(9), 4934; https://doi.org/10.3390/app15094934 - 29 Apr 2025
Cited by 1 | Viewed by 407
Abstract
The main dimensional errors in stamped parts are caused by the springback phenomenon. Those errors usually lead to assembly difficulties and/or the malfunction of those parts. The objective of this contribution is to give a comprehensive and detailed view of the sheet metal-forming [...] Read more.
The main dimensional errors in stamped parts are caused by the springback phenomenon. Those errors usually lead to assembly difficulties and/or the malfunction of those parts. The objective of this contribution is to give a comprehensive and detailed view of the sheet metal-forming process of an actual industrial part, with the focus on the setup adjustment of the blank-holder force (BHF), using the springback as the determining factor of the manufacturing quality. The complete cycle of the simulation will be detailed from the experimental determination of the model parameters to the correlation with experimental results of the simulated values. Many studies use simple geometries with limited practical application, failing to provide a quantitative understanding of actual springback in industrial processes. This work aims to offer a realistic reference for springback in a real production part, combining numerical prediction during design using a well-established model and experimental measurements in the factory. The simulation, carried out using LS-DYNA, determines the influence of the BHF in the springback observed in the manufacturing process of a gas cooktop part made from non-stable austenitic 1.4301 steel. The material has been modeled using Barlat’s Yld2000, experimentally determining the strain rate-dependent hardening, yield locus and isotropic–kinematic hardening. To validate the model, an experimental campaign has been developed, testing the part with values of BHF within the range of 50 t to 200 t. The results show that the numerical model is able to represent the influence of the BHF on the springback, demonstrating the relation between them. Full article
(This article belongs to the Section Mechanical Engineering)
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12 pages, 4037 KB  
Article
Tuning Magneto-Birefringence of Two-Dimensional Vermiculite Dispersions Through Magnetic Ion Exchange
by An Wu, Tengxuan Cao, Hangkuan Ji, Wenjun Kuang, Jiarong Liu, Zichen Song, Jiandong Yao and Yi-Chao Zou
Inorganics 2025, 13(5), 139; https://doi.org/10.3390/inorganics13050139 - 29 Apr 2025
Viewed by 557
Abstract
Liquid crystals based on dispersions of two-dimensional (2D) materials have recently been developed for light modulation, exhibiting superior performances compared to conventional organic liquid crystals in a variety of prototypical applications, including coloration, solar-blind communications and blue-light fluoresce. Among the diverse family of [...] Read more.
Liquid crystals based on dispersions of two-dimensional (2D) materials have recently been developed for light modulation, exhibiting superior performances compared to conventional organic liquid crystals in a variety of prototypical applications, including coloration, solar-blind communications and blue-light fluoresce. Among the diverse family of 2D liquid crystals, vermiculite-based liquid crystals stand out with advantages in low cost, ease of mass production and environmental sustainability, owing to the high natural abundance of the material. Here, we demonstrated magnetic-field tunable optics with 2D vermiculite dispersions prepared through a facile ‘exchange and redispersion’ method. By exploiting the intrinsic ion-exchange capability of clay minerals, we observed a significantly enhanced magneto-birefringence of the vermiculite dispersion upon replacing the native cations with magnetic ions, manifesting in a doubled Cotton–Mouton coefficient, representing the highest value among previous reports. Magnetization measurements reveal that there is a remarkable magnetic anisotropy in Fe ion-exchanged vermiculite samples in contrast to the isotropic magnetism of pristine vermiculite, which accounts for the observed enhancement of magneto-birefringence. Our findings demonstrate that ion exchange can serve as a simple and effective strategy to modulate the physical and chemical properties of 2D materials’ dispersions, thereby opening avenues for broader and more diverse applications. Full article
(This article belongs to the Special Issue Physicochemical Characterization of 2D Materials)
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10 pages, 2833 KB  
Communication
Crust and Upper Mantle Structure of Mars Determined from Surface Wave Analysis
by Víctor Corchete
Appl. Sci. 2025, 15(9), 4732; https://doi.org/10.3390/app15094732 - 24 Apr 2025
Viewed by 586
Abstract
The crust and upper mantle structure of Mars is determined in the depth range of 0 to 100 km, by means of dispersion analysis and its inversion, which is performed for the surface waves present in the traces of the seismic event: S1094b. [...] Read more.
The crust and upper mantle structure of Mars is determined in the depth range of 0 to 100 km, by means of dispersion analysis and its inversion, which is performed for the surface waves present in the traces of the seismic event: S1094b. From these traces, Love and Rayleigh waves are measured in the period range of 4 to 40 s. This dispersion was calculated with a combination of digital filtering techniques, and later was inverted to obtain both models: isotropic (from 0 to 100 km depth) and anisotropic (from 0 to 15 km depth), which were calculated considering the hypothesis of the surface wave propagation in slightly anisotropic media. The seismic anisotropy determined from 0 to 5 km depth (7% of S-velocity variation and ξ ~ 1.1) could be associated with the presence of sediments or lava-flow layering, and wide damage zones surrounding the long-term fault networks. For greater depths, the observed anisotropy (17% of S-velocity variation and ξ ~ 1.4) could be due to the possible presence of volcanic materials and/or the layering of lava flows. Another cause for this anisotropy could be the presence of layered intrusions due to a single or multiple impacts, which could cause internal layering within the crust. Finally, the Moho depth is determined at 50 km as a gradual transition from crust to mantle S-velocities, through an intermediate value (3.90 km/s) determined from 50 to 60 km-depth. Full article
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26 pages, 8150 KB  
Article
Coefficients of Thermal Expansion in Aligned Carbon Staple Fiber-Reinforced Polymers: Experimental Characterization with Numerical Investigation
by Julian Kupski, Lucian Zweifel, Miriam Preinfalck, Stephan Baz, Mohammad Hajikazemi and Christian Brauner
Polymers 2025, 17(8), 1088; https://doi.org/10.3390/polym17081088 - 17 Apr 2025
Viewed by 819
Abstract
Carbon staple fiber composites are materials reinforced with discrete-length carbon fibers processed using traditional textile technologies, offering moderate mechanical properties and flexibility in manufacturing. These composites can be produced from recycled carbon staple fibers, aligned into yarn and tape-like structures, providing a more [...] Read more.
Carbon staple fiber composites are materials reinforced with discrete-length carbon fibers processed using traditional textile technologies, offering moderate mechanical properties and flexibility in manufacturing. These composites can be produced from recycled carbon staple fibers, aligned into yarn and tape-like structures, providing a more sustainable alternative while balancing performance, cost-effectiveness, and environmental impact. Aligning staple fibers into tape-like structures enables similar applications to those of continuous-fiber-based products, while allowing control over fiber orientation distribution, fiber volume fraction, and length distribution, which are all critical factors influencing both mechanical and thermo-mechanical properties. This study focuses on the experimental characterization and numerical investigation of Coefficients of Thermal Expansion (CTEs) in aligned carbon staple fiber composites. The effects of fiber orientation and volume fraction on coefficients of thermal expansion under different fiber alignment parameters are analyzed, revealing distinct thermal expansion behavior compared to typical aligned unidirectional continuous carbon fiber composite laminates. Unlike continuous unidirectional laminates, which typically exhibit transversely isotropic behavior without tensile–shear coupling, staple fiber composites demonstrate different in-plane axial, transverse, and out-of-plane CTE characteristics. To explain these deviations, a modeling approach is introduced, incorporating detailed experimental information on fiber distributions and microstructural features rather than averaged fiber orientation values. This involves a multi-scale analysis based on a laminate analogy through which all composite thermo-elastic properties can be predicted, accounting for variations in fiber orientations, volume fractions, and tape thicknesses. It is shown that while the local variation of fiber volume fraction has a small effect on the homogenized value of the coefficients of thermal expansion, fiber misalignment, tape thickness, and asymmetry in fiber orientation distribution will significantly affect the measurements of CTEs. For the case of carbon staple fiber composites, the asymmetry in fiber orientation distribution significantly influences the measurements of axial CTE. Fiber orientation asymmetry causes tensile–shear coupling under mechanical and thermal loading, leading to an unbalanced laminate with in-plane shear–tensile deformation. This coupling disrupts uniform displacement, complicating strain measurements and the determination of composite properties. Full article
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