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Keywords = international water law

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17 pages, 438 KiB  
Article
Analytic Solutions and Conservation Laws of a 2D Generalized Fifth-Order KdV Equation with Power Law Nonlinearity Describing Motions in Shallow Water Under a Gravity Field of Long Waves
by Chaudry Masood Khalique and Boikanyo Pretty Sebogodi
AppliedMath 2025, 5(3), 96; https://doi.org/10.3390/appliedmath5030096 - 31 Jul 2025
Viewed by 110
Abstract
The Korteweg–de Vries (KdV) equation is a nonlinear evolution equation that reflects a wide variety of dispersive wave occurrences with limited amplitude. It has also been used to describe a range of major physical phenomena, such as shallow water waves that interact weakly [...] Read more.
The Korteweg–de Vries (KdV) equation is a nonlinear evolution equation that reflects a wide variety of dispersive wave occurrences with limited amplitude. It has also been used to describe a range of major physical phenomena, such as shallow water waves that interact weakly and nonlinearly, acoustic waves on a crystal lattice, lengthy internal waves in density-graded oceans, and ion acoustic waves in plasma. The KdV equation is one of the most well-known soliton models, and it provides a good platform for further research into other equations. The KdV equation has several forms. The aim of this study is to introduce and investigate a (2+1)-dimensional generalized fifth-order KdV equation with power law nonlinearity (gFKdVp). The research methodology employed is the Lie group analysis. Using the point symmetries of the gFKdVp equation, we transform this equation into several nonlinear ordinary differential equations (ODEs), which we solve by employing different strategies that include Kudryashov’s method, the (G/G) expansion method, and the power series expansion method. To demonstrate the physical behavior of the equation, 3D, density, and 2D graphs of the obtained solutions are presented. Finally, utilizing the multiplier technique and Ibragimov’s method, we derive conserved vectors of the gFKdVp equation. These include the conservation of energy and momentum. Thus, the major conclusion of the study is that analytic solutions and conservation laws of the gFKdVp equation are determined. Full article
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28 pages, 671 KiB  
Article
How Cooperative Are Games in River Sharing Models?
by Marcus Franz Konrad Pisch and David Müller
Water 2025, 17(15), 2252; https://doi.org/10.3390/w17152252 - 28 Jul 2025
Viewed by 242
Abstract
There is a long tradition of studying river sharing problems. A central question frequently examined and addressed is how common benefits or costs can be distributed fairly. In this context, axiomatic approaches of cooperative game theory often use contradictory principles of international water [...] Read more.
There is a long tradition of studying river sharing problems. A central question frequently examined and addressed is how common benefits or costs can be distributed fairly. In this context, axiomatic approaches of cooperative game theory often use contradictory principles of international water law, which are strictly rejected in practice. That leads to the question: Are these methods suitable for a real-world application? First, we conduct a systematic literature review based on the PRISMA approach to categorise the river sharing problems. We identified several articles describing a variety of methods and real-world applications, highlighting interdisciplinary interest. Second, we evaluate the identified axiomatic literature related to TU games with regard to their suitability for real-world applications. We exclude those “standalone” methods that exclusively follow extreme principles and/or do not describe cooperative behaviour. This is essential for a fair distribution. Third, we propose to use the traditional game-theoretical approach of airport games in the context of river protection measures to ensure a better economic interpretation and to enforce future cooperation in the joint implementation of protective measures. Full article
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20 pages, 9463 KiB  
Article
Mechanical Property Analysis and Sulfate Ion Concentration Prediction of Mortar and Concrete Exposed to Dry–Wet Sulfate Erosion Under Continuous Bending Loads
by Yong Wen, Yuhang Li, Enze Hao, Kaiming Pan, Guoqi Han and Yang Chen
Appl. Sci. 2025, 15(13), 7345; https://doi.org/10.3390/app15137345 - 30 Jun 2025
Viewed by 220
Abstract
The objective of this study is to examine the variations in the properties of cementitious materials subjected to bending loads in conjunction with dry and wet cycles of sulfate exposure. This investigation involved applying continuous bending loads at 0%, 20%, and 40% of [...] Read more.
The objective of this study is to examine the variations in the properties of cementitious materials subjected to bending loads in conjunction with dry and wet cycles of sulfate exposure. This investigation involved applying continuous bending loads at 0%, 20%, and 40% of the ultimate bending capacity to cementitious material specimens. Furthermore, three sets of mortars and concretes with differing water–cement ratios were formulated and analyzed using X-ray diffraction, scanning electron microscopy, and compressive strength tests. The findings indicated that while the flexural strength, compressive strength, and porosity of the specimens initially increased, they ultimately declined as the cementitious materials degraded over time within the sulfate solution. Additionally, it was observed that an increase in bending load corresponded with a decrease in flexural strength, alongside a rise in the internal sulfate ion concentration. By integrating an enhanced form of Fick’s second law with chemical reaction kinetics, a transport model for sulfate ions in cement-based materials was developed under the coupling effect of bending load and sulfate exposure, utilizing Comsol Multiphysics. The simulation results, which align well with the experimental observations, exhibit an error of approximately 5% at a depth of 5 mm. Full article
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17 pages, 248 KiB  
Article
Incremental Progress in Combating IUU Fishing: A Review of China’s 2020 Administrative Regulations for Distant-Water Fisheries
by Qing Zhao, Xuexin Yi and Ming Jing
Laws 2025, 14(4), 42; https://doi.org/10.3390/laws14040042 - 23 Jun 2025
Viewed by 523
Abstract
Addressing the illegal, unreported, and unregulated (IUU) fishing in the water beyond its jurisdiction poses a significant challenge for China as it aims to establish itself as a responsible participant in global fishing governance. Inadequate regulation and enforcement largely contribute to the increase [...] Read more.
Addressing the illegal, unreported, and unregulated (IUU) fishing in the water beyond its jurisdiction poses a significant challenge for China as it aims to establish itself as a responsible participant in global fishing governance. Inadequate regulation and enforcement largely contribute to the increase in the suspected illegal fishing by Chinese vessels, fishing enterprises, and crew members. In 2020, China revised the RDWF (2020) to address the growing issues of IUU fishing. This study aims to evaluate the effectiveness of the RDWF (2020) in addressing China’s IUU fishing in distant water. This paper concludes that RDWF (2020) represents an incremental advancement in China’s initiatives to eliminate IUU fishing. RDWF (2020) emphasizes the government’s responsibilities in regulating vessel quantities and ensuring accurate reporting. Furthermore, RDWF (2020) adopts measures to fulfill China’s responsibilities under RFMOs. Additionally, RDWF (2020) expands the roster of operators liable for penalties and delineates IUU fishing activities that necessitate sanctions. Ultimately, RDWF (2020) develops an evaluation system to monitor compliance with anti-IUU fishing obligations as stipulated by international treaties and Chinese laws and regulations. However, RDWF (2020) encounters limitations that may impede its effectiveness in addressing IUU fishing, such as the lack of responsibilities assigned to administrative bodies, insufficient penalties for serious IUU fishing activities, and inadequate compliance with international standards for sustainable fishing. This paper provides policymakers specific recommendations for improving the identified areas of RDWF (2020) and offers insights for distant-water fishing nations that are grappling with significant IUU fishing issues to make gradual improvements in combating IUU fishing. Full article
23 pages, 3668 KiB  
Review
A Review of Intelligent Methods for Environmental Risk Identification in Polar Drilling and Well Completion
by Ruitong Wei, Song Deng, Xiaopeng Yan, Mingguo Peng, Ke Ke, Lei Wang, Zhiqiang Hu, Kai Yang, Bingzhao Huo and Linglong Cao
Processes 2025, 13(6), 1873; https://doi.org/10.3390/pr13061873 - 13 Jun 2025
Viewed by 434
Abstract
The Arctic region is rich in oil and gas resources and has great potential for development. It has become a new hot spot for international development. However, the harsh climatic and geological conditions and fragile ecosystems in the Arctic region put forward stringent [...] Read more.
The Arctic region is rich in oil and gas resources and has great potential for development. It has become a new hot spot for international development. However, the harsh climatic and geological conditions and fragile ecosystems in the Arctic region put forward stringent technical requirements for oil and gas development. Polar permafrost has an impact on the growth of plant roots and the absorption of water. When drilling activities are carried out, the permafrost layer may be broken, resulting in the erosion of polar soil and disorder of the water balance, thus affecting local vegetation and ecosystems. Moreover, the legal system of polar environmental protection is lacking, and it is necessary to form a perfect risk assessment method to improve the relevant laws and regulations. Therefore, it is very important to study the environmental risk identification technology for polar drilling. For polar drilling, it is necessary to establish a risk source classification and identification method for environmental pollution events. However, at present, it mainly faces the following challenges: poor polar environment, lack of monitoring data, and lack of a legal system for polar environmental protection. By systematically discussing risk identification technology, the application and applicable models of different types of risk evaluation methods are categorized and summarized, the advantages and disadvantages of different types of risk evaluation methods and their application effects are analyzed based on the unique environment of the polar regions, and then the development direction of the future environmental risk identification technology for polar drilling is proposed. In order to accelerate the development of polar drilling environmental risk identification technology, research should be focused on the following three aspects: ① Promoting the multi-dimensional integration of polar drilling environmental pollution index data, to make up for the short board of less relevant data in the polar region. ② Combining the machine modeling algorithm with risk evaluation of polar drilling environmental pollution to improve the scientificity and accuracy of the evaluation results. ③ Establishing a scientific and accurate polar drilling environmental pollution risk identification system to reduce pollution risk. Full article
(This article belongs to the Section Energy Systems)
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18 pages, 15631 KiB  
Article
Resolving the Faint Young Sun Paradox and Climate Extremes: A Unified Thermodynamic Closure Theory
by Hsien-Wang Ou
Climate 2025, 13(6), 116; https://doi.org/10.3390/cli13060116 - 2 Jun 2025
Viewed by 543
Abstract
Clouds play a central role in regulating incoming solar radiation and outgoing terrestrial emission; hence, they must be internally constrained to prognose Earth’s temperature. At the same time, planetary fluids are inherently turbulent, so the climate state would tend toward maximum entropy production—a [...] Read more.
Clouds play a central role in regulating incoming solar radiation and outgoing terrestrial emission; hence, they must be internally constrained to prognose Earth’s temperature. At the same time, planetary fluids are inherently turbulent, so the climate state would tend toward maximum entropy production—a generalized second law of thermodynamics. Incorporating these requirements, I have previously formulated an aquaplanet model to demonstrate that intrinsic water properties may strongly lower the climate sensitivity to solar irradiance, thereby resolving the faint young Sun paradox (FYSP). In this paper, I extend the model to include other external forcings and show that sensitivity to the reduced outgoing longwave radiation by the elevated pCO2 can be several times greater, but the global temperature remains capped at ~40 °C by the exponential increase in saturated vapor pressure. I further show that planetary albedo augmented by a tropical supercontinent may cool the climate sufficiently to cause tropical glaciation. And since the glacial edge is marked by above-freezing temperature, it abuts an open, co-zonal ocean, thereby obviating the “Snowball Earth” hypothesis. Our theory thus provides a unified framework for interpreting Earth’s diverse climates, including the FYSP, the warm extremes of the Cambrian and Cretaceous, and the tropical glaciations of the Precambrian. Full article
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17 pages, 2618 KiB  
Article
Coordination Analysis and Driving Factors of “Water-Land-Energy-Carbon” Coupling in Nine Provinces of the Yellow River Basin
by Daiwei Zhang, Ming Jing, Buhui Chang, Weiwei Chen, Ziming Li, Shuai Zhang and Ting Li
Water 2025, 17(8), 1138; https://doi.org/10.3390/w17081138 - 10 Apr 2025
Cited by 1 | Viewed by 411
Abstract
As an important ecological barrier and economic belt in China, the sustainable development of the Yellow River Basin (YRB) is of great significance to national ecological security and regional economic balance. Based on the coupled and coordinated development analysis of the water–soil–energy–carbon (W-L-E-C) [...] Read more.
As an important ecological barrier and economic belt in China, the sustainable development of the Yellow River Basin (YRB) is of great significance to national ecological security and regional economic balance. Based on the coupled and coordinated development analysis of the water–soil–energy–carbon (W-L-E-C) system in the provinces of the Yellow River Basin from 2002 to 2022, this study systematically analyzed the interaction relationship among the various factors through WLECNI index assessment, factor identification, and driving factor exploration. Thus, it fully reveals the spatiotemporal evolution law of regional coordinated development and its internal driving mechanism. It is found that the coordinated development of the W-L-E-C system in different provinces of the Yellow River Basin presents significant spatiotemporal differentiation, and its evolution process is influenced by multiple factors. It is found that the coordination of the YRB presents a significant spatial difference, and Inner Mongolia and Shaanxi, as high coordination areas, have achieved significant improvement in coordination, through ecological restoration and clean energy replacement, arable land intensification, and industrial water-saving technology, respectively. Shandong, Henan, and Shanxi in the middle coordination zone have made some achievements in industrial greening and water-saving technology promotion, but they are still restricted by industrial carbon emissions and land resource pressure. The Ningxia and Gansu regions with low coordination are slow to improve their coordination due to water resource overload and inefficient energy utilization. Barrier factor analysis shows that the water resources utilization rate (W4), impervious area (L4), energy consumption per unit GDP (E1), and carbon emissions from energy consumption (C3) are the core factors restricting coordination. Among them, the water quality compliance rate (W5) of Shanxi and Henan is very low, and the impervious area (L4) of Shandong is a prominent problem. The interaction analysis of the driving factors showed that there were significant interactions between water resource use and ecological protection (W-E), land resource and energy use (L-E), and carbon emissions and ecosystem (C-E). Inner Mongolia, Shaanxi, and Shandong achieved coordinated improvement through “scenic energy + ecological restoration”, cultivated land protection, and industrial greening. Shanxi, Henan, and Ningxia are constrained by the “W-L-E-C” complex obstacles. In the future, the Yellow River Basin should implement the following zoning control strategy: for the areas with high coordination, it should focus on consolidating the synergistic advantages of ecological protection and energy development; water-saving technology and energy consumption reduction measures should be promoted in the middle coordination area. In the low coordination area, efforts should be made to solve the problem of resource overload, and the current situation of low resource utilization efficiency should be improved by improving the utilization rate of recycled water and applying photovoltaic sand control technology. This differentiated governance plan will effectively enhance the level of coordinated development across the basin. The research results provide a decision-making framework of “zoning regulation, system optimization and dynamic monitoring” for the sustainable development of the YRB, and provide a scientific basis for achieving high-quality development of the basin. Full article
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13 pages, 1519 KiB  
Review
Reviewing Water Wars and Water Weaponisation Literatures: Is There an Unnoticed Link?
by Paula Duarte Lopes and Margarida Gama
Water 2025, 17(6), 897; https://doi.org/10.3390/w17060897 - 20 Mar 2025
Viewed by 1379
Abstract
The prediction made by former Vice President of the World Bank, Ismail Serageldin, that the wars of the 21st century will be about water, remains on the international political agenda. Yet, there is enough evidence corroborating that water wars have not occurred in [...] Read more.
The prediction made by former Vice President of the World Bank, Ismail Serageldin, that the wars of the 21st century will be about water, remains on the international political agenda. Yet, there is enough evidence corroborating that water wars have not occurred in the past and that there are sufficient mechanisms in place to prevent them in the future. Simultaneously, domestic water violent conflicts have been taking place, usually as immediate reactions to localised disputes. More importantly, water weaponisation has been gaining visibility during violent conflicts, violating international humanitarian law without any consequences so far. This paper reviews the water wars and water weaponisation literatures, arguing that there is an under-researched link between these two literatures and practices. This review suggests that the water weaponisation discourse and practice may facilitate the context for the water wars prophecy to become true. Full article
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22 pages, 4482 KiB  
Article
Evolution of Pore Structure and Mechanical Characteristics of Red Sandstone Under Drying–Wetting Cycles
by Hongwei Deng, Shiyu Zhou, Songtao Yu, Yao Liu and Jingbo Xu
Minerals 2025, 15(2), 158; https://doi.org/10.3390/min15020158 - 7 Feb 2025
Cited by 1 | Viewed by 845
Abstract
Red sandstone is widely distributed in southern China. Due to the significant difference in mechanical properties before and after hydration and its poor water stability, red sandstone often triggers landslide accidents. In this paper, red sandstone from an open pit slope in Jiangxi [...] Read more.
Red sandstone is widely distributed in southern China. Due to the significant difference in mechanical properties before and after hydration and its poor water stability, red sandstone often triggers landslide accidents. In this paper, red sandstone from an open pit slope in Jiangxi Province was taken as the research object. Two variables, namely the initial saturation degree (25%, 50%, 75%, and 100%) and the number of wetting–drying cycles (0, 10, 20, 30, and 40), were set. With the help of nuclear magnetic resonance, the Brazilian disc test, and fractal theory, the relationships among its meso-structure, macroscopic fracture mechanics characteristics, and deterioration mechanism were analyzed. The research results are as follows: (1) Wetting–drying cycles have a significant impact on the pore structure and fracture mechanics characteristics of red sandstone. Moreover, the higher the initial saturation degree, the more obvious the deterioration effect of the wetting–drying cycles on the rock mass. (2) After further subdividing the pores according to their size for research, it was found that sandstone is mainly composed of mesopores, and the deterioration laws of different types of pores after the wetting–drying cycles are different. The porosities of total pores and macropores increase, while the proportions of mesopores and micropores decrease. The fractal dimensions of macropores and total pores of each group of rock samples are all within the range of 2–3, and the fractal dimension value increases with the increase in the number of wetting–drying cycles, showing significant and regular fractal characteristics. Micropores and some mesopores do not possess fractal characteristics. The fractal dimension of rock samples basically satisfies the rule that the larger the pore diameter, the larger the fractal dimension and the more complex the pore structure. (3) Both the type I and type II fracture toughness of rock samples decrease with the increase in the number of cycles, and the decrease is the most significant when the initial saturation degree is 100%. After 40 cycles, the decreases in type I and type II fracture toughness reach 23.578% and 30.642%, respectively. The fracture toughness is closely related to the pore structure. The porosity and fractal dimension of rock samples and their internal macropores are linearly negatively correlated with the type II fracture toughness. The development of the macropore structure is the key factor affecting its fracture mechanics performance. (4) After the wetting–drying cycles, the internal pores of red sandstone continue to develop. The number of pores increases, the pore diameter enlarges, and the proportion of macropores rises, resulting in internal damage to the rock mass. When bearing loads, the expansion and connection of internal cracks intensify, ultimately leading to the failure of the rock mass. The research results can provide important reference for the stability analysis of sandstone slope engineering. Full article
(This article belongs to the Special Issue Advances in Mine Backfilling Technology and Materials)
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21 pages, 6247 KiB  
Article
Analysis of the Existing Air Emissions Detection Methods for Stationary Pollution Sources Monitoring
by Alexandr Neftissov, Andrii Biloshchytskyi, Ilyas Kazambayev, Lalita Kirichenko, Ultuar Zhalmagambetova and Svitlana Biloshchytska
Appl. Sci. 2024, 14(23), 10934; https://doi.org/10.3390/app142310934 - 25 Nov 2024
Viewed by 1264
Abstract
The application of coal technologies for energy generation leads to high pollutant emissions. Thus, governmental and international organizations have created new programs and laws for monitoring emissions. Recently, the government of Kazakhstan has introduced regulations for the measurement of emissions produced by factories [...] Read more.
The application of coal technologies for energy generation leads to high pollutant emissions. Thus, governmental and international organizations have created new programs and laws for monitoring emissions. Recently, the government of Kazakhstan has introduced regulations for the measurement of emissions produced by factories and power plants. However, the requirements and Corecommendations for the monitoring methods have not been defined. Therefore, this article addresses the problem and focuses on determining the measurement errors made by optical SGK510 and electrochemical POLAR devices used for coal power plants. The hypothesis is based on the fact that there are currently no systems for monitoring probe drying, and its implementation is expensive. The main methods are analyzed, namely their operation, taking into account the presence of water particles in samples, and the possibility of using adjustment coefficients is considered. The main pollutants chosen for analysis are CO, NO, NO2, NOx, SO2, and O2. Using the Broich–Pagan test, homoscedasticity was determined, and the Fisher test showed the possibility of using tuning coefficients. The data for the optical method were compared to measurements taken using Inspector 500. The error for SO2 determination was 7.19% for NO, 44.0985% for NO2, 733.26% for NOx, 7.39% for O2, 2.75% for CO, 60.81%. The comparison between SGK510 and POLAR demonstrated the following errors: for CO—1.5%, for NOx—82.4405%, for SO2—41.17%, for O2—11.61%. According to the Fisher criteria analysis of the optical method, only SO2 and CO values measured by SGK510 in comparison to Inspector 500 had close similarity, while others demonstrated high deviations. The significance tests were carried out by Fisher’s, t-test, and ANOVA methods. For the electrochemical measurement, only CO values had close similarity. In the future, methods will be proposed to improve the accuracy of the system while reducing maintenance costs, as well as cleaning sampling systems. The multicomponent analysis application for accuracy improvement with the exhaust gas humidity, temperature, and flow consideration was recommended as a possible solution. Full article
(This article belongs to the Section Ecology Science and Engineering)
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19 pages, 15114 KiB  
Article
Study on the Vibration-Damping Mechanism of a New Phononic Crystal Suspension Equipped on Underwater Gliders
by Qindong Sun, Yuhan Yang, Pan Wu, Ming Yang, Tongshuai Sun, Wendong Niu and Shaoqiong Yang
J. Mar. Sci. Eng. 2024, 12(11), 2088; https://doi.org/10.3390/jmse12112088 - 19 Nov 2024
Cited by 1 | Viewed by 1096
Abstract
The vibration caused by the movement of internal actuating components within an acoustic underwater glider can interfere with onboard sensors. However, as a new vibration-damping material, phononic crystals can effectively reduce this impact. Using simulation and an underwater test, this work studied the [...] Read more.
The vibration caused by the movement of internal actuating components within an acoustic underwater glider can interfere with onboard sensors. However, as a new vibration-damping material, phononic crystals can effectively reduce this impact. Using simulation and an underwater test, this work studied the vibration-damping mechanism of the phononic crystal suspension (PCS) designed by Tianjin University, China. The bandgaps and the modes of PCS were calculated first, which offered basic data for the following simulation. Then, the relationship between the modes and attenuation zones (AZs) were broadly considered to reveal the variation law of the AZs with the change in modes, both in the air and under water. Finally, an underwater test was carried out to verify the good vibration-damping effect of the PCS. The results show that the cutoff frequency of the AZs could be predicted by finding the relevant modes. The PCS showed a good vibration-damping effect from 170 Hz to 5000 Hz in the underwater test, with a maximum decrease of 6 dB at 2000 Hz. Finally, the damping of the PCS could suppress the overlap of modes that resulted from Bragg scattering. This work will also provide theoretical guidance for further study on the optimization of phononic crystal mechanisms for vibration damping. Full article
(This article belongs to the Special Issue Marine Autonomous Vehicles: Design, Test and Operation)
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12 pages, 1069 KiB  
Article
A Novel High Performance Liquid Chromatography Method for Camphor Determination and Application in Cosmetics and Pharmaceuticals: Development and Validation
by Martin Lalić, Ana Soldić, Zdenka Lalić and Miranda Sertić
Molecules 2024, 29(18), 4290; https://doi.org/10.3390/molecules29184290 - 10 Sep 2024
Cited by 2 | Viewed by 1723
Abstract
A novel high-performance liquid chromatography (HPLC) method with 4-N,N-dimethylaminobenzaldehyde as an internal standard was developed for the determination of Camphor with the main goal of facilitating the analysis of different cosmetic and pharmaceutical products that contain Camphor in analytical [...] Read more.
A novel high-performance liquid chromatography (HPLC) method with 4-N,N-dimethylaminobenzaldehyde as an internal standard was developed for the determination of Camphor with the main goal of facilitating the analysis of different cosmetic and pharmaceutical products that contain Camphor in analytical laboratories. The method can be applied to cosmetic and pharmaceutical samples such as gels, ointments, and creams containing Camphor. Chromatographic separation was carried out on the Symmetry® C18, 5 μm column (Waters), 250 × 4.6 equipped with guard column E, InertSustain C18, 5 µm, while using the flow of 1.4 mL/min, with a column temperature of 25 °C. The mobile phase consisted of 600 mL of acetonitrile, 400 mL of purified water, and 6 mL of glacial acetic acid. The method was evaluated in accordance with ICH Q2 (R2) guidelines for validation parameters: selectivity, linearity (range 0.10–3.00 mg/mL), the limit of detection (LOD = 0.028 mg/mL), the limit of quantification (LOQ = 0.085 mg/mL), accuracy (confidence intervals < 0.05%), repeatability (peak area ratio = 0.39–1.97), and intermediate precision (peak area ratio = 0.40–1.98). The method is applicable for detecting and quantifying Camphor in a variety of cosmetic and pharmaceutical products from different parts of the world, thus covering the concentrations required by different law legislations. Full article
(This article belongs to the Section Analytical Chemistry)
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20 pages, 11516 KiB  
Article
Numerical Study of Internal Flow Field in a Disc Stack Centrifuge Based on Mixture-PBM Model
by Hefeng Dong, Ran Wan, Changan Huang, Shoulie Liu, Shamiao Luo, Liangbin Chen, Shaobin Li and Xizhen Song
Appl. Sci. 2024, 14(17), 8070; https://doi.org/10.3390/app14178070 - 9 Sep 2024
Viewed by 2240
Abstract
Disc stack centrifuge belongs to one kind of sedimentation centrifuge, widely used in the environmental protection, pharmacy, and chemical industries, etc. The flow process inside the disc stack centrifuge seriously affects the separation efficiency. However, the flow process inside the disc stack centrifuge [...] Read more.
Disc stack centrifuge belongs to one kind of sedimentation centrifuge, widely used in the environmental protection, pharmacy, and chemical industries, etc. The flow process inside the disc stack centrifuge seriously affects the separation efficiency. However, the flow process inside the disc stack centrifuge and its influence on the separation efficiency have not yet been detailed. We plan to study the flow process of oil and water phases inside the disc stack centrifuge and to explore the process of fragmentation and accumulation of water droplets. In this study, the Mixture-PBM (Population Balance Model) model is used to numerically simulate the two-phase flow of oil and water in the disc stack centrifuge and compare it with the tests. The research found that with the increase in rotational speed, the separation efficiency rises in both the test and numerical simulation results, and the difference between the test and simulation results is below 1%. The effect of ribs on the flow is considered, and the results show that the hysteresis of the liquid flow in the disc stack centrifuge is significantly reduced after considering the ribs, and the numerical simulation results can reach 98% of the theoretical results. Fluid entering the separation channel from the neutral pore creates a vortex, and as the dimensionless number λ increases, the degree of deviation of the fluid’s trajectory from the generatrix increases. The circumferential and radial velocities in the separation channel appear large in the center and small near the wall. The water content in the rising channel gradually decreases, and 90% of the water finishes settling in the distributor. The processing volume of the separation channel in each layer shows a small bottom layer, a large top layer, and a uniform law in the middle. The coalescence of water droplets occurs mainly in the separation channel, as found by analyzing the laws of the internal flow of the disc stack centrifuge, which provides the basis for improving the structure of the disc stack centrifuge, increasing the separation efficiency and reducing the floor space. Full article
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30 pages, 9516 KiB  
Article
Numerical Simulation Study on Hydraulic Characteristics and Wear of Eccentric Semi-Ball Valve under Sediment Laden Water Flow
by Yixiong Cheng, Yuan Tang, Jianhua Wu, Hua Jin and Lixia Shen
Sustainability 2024, 16(17), 7266; https://doi.org/10.3390/su16177266 - 23 Aug 2024
Cited by 2 | Viewed by 1400
Abstract
To investigate the variation laws of various hydraulic parameters and internal fluid flow patterns of eccentric semi-ball valves under different boundary conditions, the DPM model was used to numerically simulate the eccentric semi-ball valve based on Fluent 2021 R1 software. The flow velocity, [...] Read more.
To investigate the variation laws of various hydraulic parameters and internal fluid flow patterns of eccentric semi-ball valves under different boundary conditions, the DPM model was used to numerically simulate the eccentric semi-ball valve based on Fluent 2021 R1 software. The flow velocity, pressure distribution, and erosion wear rate on the valve wall were simulated under different combinations of opening, inlet flow velocity, and sediment concentration conditions, and hydraulic parameters such as drag coefficient, flow coefficient, and cavitation coefficient were calculated. The results show that as the opening of the eccentric semi-ball valve increases, the valve drag coefficient decreases, the flow coefficient increases, the cavitation coefficient increases, and the degree of cavitation decreases. The flow velocity in the high-velocity zone at both ends of the valve plate decreases, and the gradient of water flow velocity passing through the valve decreases. The area of the low-velocity zone at the rear of the valve plate decreases, and the vortex phenomenon gradually weakens; as the sediment content in the water increases, the valve drag coefficient increases, the flow coefficient decreases, and the cavitation coefficient first increases and then decreases. The maximum flow velocity of the pipeline decreases faster and faster, causing an increase in pressure gradient in the flow area and drastic changes. This results in higher pressure on the pipe wall near the valve plate, especially a significant increase in negative pressure; As the inlet flow rate increases, the valve drag coefficient decreases, the flow coefficient increases, and the cavitation coefficient gradually decreases. The flow velocity of the water passing through the valve increases, and the low-pressure area downstream of the valve plate increases. The pressure gradient at both ends of the valve port increases significantly from small to large, and the positive pressure upstream of the valve plate gradually increases. The force of the water flow on the valve plate is large, causing friction between the valve stem and the valve body, which is not conducive to long-term operation. With the increase in inlet flow rate, the maximum wear amount and wear range of the valve plate have significantly increased, and erosion wear is mainly distributed in point blocks at the edge of the valve plate. This study can provide certain references and solutions for the key technology research of eccentric semi-ball valves and assess the performance indicators of the operation being maintained. Full article
(This article belongs to the Section Sustainable Water Management)
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12 pages, 7134 KiB  
Article
Methodology for the Identification of Moisture Content in Tailings Dam Walls Based on Electrical Resistivity Tomography Technique
by Leopoldo Córdova, Aaron Moya, Diana Comte and Igor Bravo
Minerals 2024, 14(8), 760; https://doi.org/10.3390/min14080760 - 27 Jul 2024
Viewed by 1412
Abstract
The design of tailings dams has improved significantly in recent decades due to experience and advances in applied research. However, there are still several environmental and geomechanical uncertainties associated with the response of these structures. Failures on the wall of tailings dams are [...] Read more.
The design of tailings dams has improved significantly in recent decades due to experience and advances in applied research. However, there are still several environmental and geomechanical uncertainties associated with the response of these structures. Failures on the wall of tailings dams are well documented, where the most common causes are related to the action of water overtopping, slope instability, seepage, and foundation failure. Measuring the humidity or the saturation level at tailings dam walls has become a must do in the recent years. Resistivity monitoring using electrical resistivity tomography (ERT) techniques has proven to be one of the tools that provide good subsurface characterization for internal erosion detection and seepage assessment to evaluate potential environmental risks and the physical stability of tailings dams. Also, the integrated techniques of geotechnical, geophysical, and geochemical data have been used to correlate, coordinate, and improve the characterization. In this research, a procedure to guide us to a new methodology of acquiring and monitoring humidity content is presented, in which 2D electrical resistivity tomography (ERT) profiles are linked to the degree of soil saturation, using moisture sensors installed in a nearby well. The ERT profiles provide a 2D resistivity profile, and the moisture sensors can measure resistivity and volumetric water content (VWC) at a given installation depth. This second measure (VWC), with a defined total porosity, can be combined with Archie’s empirical law to obtain the degree of saturation, allowing the possibility to create remote monitoring suitable for mining operations without excessive laboratory testing. Full article
(This article belongs to the Section Mineral Processing and Extractive Metallurgy)
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