Search Results (22)

Sustainability in the construction sector has become a fundamental objective for mitigating escalating environmental challenges; given that concrete is the most widely used man-made material, extending its service life is therefore critical. Among durability concerns, magnesium sulfate (MgSO₄) attack is particularly deleterious to concrete structures. Therefore, this study investigates the short- and long-term performance of concrete produced with copper slag (CS)—a massive waste generated by copper mining activities worldwide—employed as a supplementary cementitious material (SCM), together with recycled coarse aggregate (RCA), obtained from concrete construction and demolition waste, when exposed to MgSO₄. CS was used as a 15 vol% cement replacement, while RCA was incorporated at 0%, 20%, 50%, and 100 vol%. Compressive strength, bulk density, water absorption, and porosity were measured after water curing (7–388 days) and following immersion in a 5 wt.% MgSO₄ solution for 180 and 360 days. Microstructural characteristics were assessed using scanning electron microscopy (SEM), X-ray diffraction (XRD), thermogravimetric analysis with its differential thermogravimetric derivative (TG-DTG), and Fourier transform infrared spectroscopy (FTIR) techniques. The results indicated that replacing 15% cement with CS reduced 7-day strength by ≤10%, yet parity with the reference mix was reached at 90 days. Strength losses increased monotonically with RCA content. Under MgSO₄ exposure, all mixtures experienced an initial compressive strength gain during the short-term exposures (28–100 days), attributed to the pore-filling effect of expansive sulfate phases. However, at long-term exposure (180–360 days), a clear strength decline was observed, mainly due to internal cracking, brucite formation, and the transformation of C–S–H into non-cementitious M–S–H gel. Based on these findings, the combined use of CS and RCA at low replacement levels shows potential for producing environmentally friendly concrete with mechanical and durability performance comparable to those of concrete made entirely with virgin materials. Full article

Prestressed concrete railroad ties are the global standard for railway infrastructure due to their structural stability, durability, and cost-effective maintenance. However, their long-term performance is often compromised by premature deterioration. This study investigates the degradation of prestressed concrete railways ties from a Brazilian rail line after ten years of natural exposure, emphasizing critical implications for infrastructure maintenance. Two groups of ties, separated by 30 km, were analyzed through physical property assessments, petrography, X-ray diffraction (XRD), and scanning electron microscopy/energy dispersive spectroscopy (SEM/EDS). The results reveal that deterioration was driven by the combined effects of alkali–silica reaction (ASR) and sulfate attack, confirmed by the presence of (N, C)ASH gels, ettringite crystallization, and cryptocrystalline materials within cracks and voids. Prestressing-induced stresses and environmental moisture further accelerated degradation, leading to a 66% reduction in mechanical strength in the T1 group. These findings demonstrate that internal swelling reactions and moisture exposure synergistically accelerate deterioration in prestressed concrete ties, particularly in low-prestress, poorly drained zones. Full article

When iron sulfides are used as aggregate in concrete production, it easily oxidizes to form harmful substances such as sulfates. This results in acid corrosion and internal sulfate attack (ISA), significantly reducing concrete durability. To date, the quantification methods for iron sulfides in aggregates remain inaccurate, often neglecting pyrrhotite (a type of iron sulfide). No standardized methods or threshold values for the sulfide content in aggregates have been established, nor have technical guidelines for the application of sulfide-containing aggregates, limiting their use. This study proposes an on-site quantification procedure for determining the pyrite and pyrrhotite content in tailings using a selective chemical dissolution process. An orthogonal experiment was designed to determine the optimal dissolution conditions by considering four factors: particle size, reaction temperature, acid concentration, and reaction time. The pyrrhotite quantification method showed a relative standard deviation (RSD) of 3.60% (<5%) and a mean relative error of 3.19% (<5%), while the pyrite quantification method showed an RSD of 3.11% (<5%) with a mean relative error of 4.70% (<5%). The results were further optimized under engineering conditions to reduce costs and enable on-site quantification without relying on complex precision instruments. The quantitative results of pyrite in mineral samples were verified by the XRD internal standard method, and the error was less than 0.6%. This approach ensures the effective monitoring and management of sulfide content in concrete aggregates, promoting the practical application of sulfur-bearing aggregates. Full article

Salt lakes and the surrounding saline soils distributed across northwestern China and Inner Mongolia impose severe physicochemical corrosion on cement-based concrete. Understanding the corrosion products and mechanisms are crucial scientific and technological factors in ensuring the durability and service life of concrete structures in these regions. In this study, various analytical techniques—including X-ray diffraction, thermogravimetric–differential thermal analysis, X-ray fluorescence, and scanning electron microscopy coupled with energy-dispersive spectroscopy—were employed to systematically analyze the corrosion products of ordinary Portland cement (OPC) and high-performance concrete (HPC) specimens after eight years of field exposure in the Qarhan Salt Lake area of Qinghai. The study provided an in-depth understanding of the physicochemical corrosion mechanisms involved. The results showed that, after eight years of exposure, the corrosion products comprised both physical corrosion products (primarily sodium chloride crystals), and chemical corrosion products (associated with chloride, sulfate, and magnesium salt attacks). A strong correlation could be observed between the chemical corrosion products and the strength grade of the concrete. In C25 OPC, the detected corrosion products included gypsum, monosulfate-type calcium sulfoaluminate (AFm), Friedel’s salt, chloro-ettringite, brucite, magnesium oxychloride hydrate 318, calcium carbonate, potassium chloride, and sodium chloride. In C60 HPC, the identified corrosion products included Kuzel’s salt, Friedel’s salt, chloro-ettringite, brucite, calcium carbonate, potassium chloride, and sodium chloride. Among them, sulfate-induced corrosion led to the formation of gypsum and AFm, whereas chloride-induced corrosion resulted in chloro-ettringite and Friedel’s salt. Magnesium salt corrosion contributed to the formation of brucite and magnesium oxychloride hydrate 318, with Kuzel’s salt emerging as a co-corrosion product of chloride and sulfate attacks. Furthermore, a conversion phenomenon was evident between the sulfate and chloride corrosion products, which was closely linked to the internal chloride ion concentration in the concrete. As the chloride ion concentration increased, the transformation sequence of sulfate corrosion products occurred in the following order: AFm → Kuzel’s salt → Friedel’s salt → chloro-ettringite. There was a gradual increase in chloride ion content within these corrosion products. This investigation into concrete durability in salt-lake ecosystems offers technological guidance for infrastructure development and material specification in hyper-saline environments. Full article

For concrete structures in marine or groundwater environments, sulfate attack is a major factor contributing to the degradation of concrete performance. This paper analyzes the existing literature on the chemical reactions and physical crystallization effects of sulfate attack on cement-based materials, summarizing the degradation mechanisms of corroded concrete. Experiments have been conducted to study the performance evolution of concrete under sulfate attack, considering both external environmental factors and internal factors of the cement-based materials. External environmental factors, such as the temperature, humidity, concentration, and type of sulfate solutions, wet-dry cycles, freeze-thaw cycles, chloride coupling effects, and stray currents significantly impact sulfate attack on concrete. Internal factors, including internal sources of corrosion, the chemical composition of the cement, water-cement ratio, and the content of C-S-H gel and Ca(OH)₂, influence the density and sulfate resistance of the cement-based materials. Additionally, five typical methods for enhancing the sulfate resistance of concrete are summarized. Finally, the paper identifies current challenges in the study of corroded concrete and proposes directions for future research. Full article

In salt lake areas, the cast-in-situ concrete structure has been corroded by the combination of sulfate and chloride for a long time. The incorporation of basalt fiber materials into concrete helps to improve the durability of concrete. In this paper, experiments were conducted to study the corrosion deterioration mechanisms of basalt fiber-reinforced cast-in-situ concrete under sulfate, chloride, and combined attack. The appearance, size, mass, flexural, and compressive strength of specimens were investigated during the immersion period to determine the changes in the physical and mechanical properties of specimens. Moreover, the microstructure and mineral changes of specimens during the immersion period were observed by Scanning Electron Microscope (SEM), Energy Dispersive Spectrometer (EDS), X-ray diffraction (XRD), and Thermogravimetric (TG)/ Derivative Thermogravimetric (DTG) analyses. Results show that premixed chloride has a significant detrimental influence on the strength development of cast-in-situ concrete, with concrete powder spalling occurring on the surface of the specimen. Severe corrosion degradation of specimens occurs under the external sulfate and internal chloride combined attack, resulting in lower flexural and compressive strength. The compressive strength and flexural strength of the corroded specimens decreased by 15.4% and 24.8%, respectively, compared with the control group at 28 days. Moreover, premixed basalt fiber has a beneficial influence on cast-in-situ concrete. When the basalt fiber content is 0.5%, the flexural strength of the specimen is increased by 16.2%. The filling and bridging effect of basalt fiber alleviates the negative effects caused by corrosion. In addition, increasing fiber content is beneficial for enhancing its effectiveness when the fiber content is less than 0.5%. This paper provides a valuable reference for the application of basalt fiber-reinforced cast-in-situ concrete under the condition of sulfate–chloride compound corrosion. Full article

This study aims to investigate the influence of exposure conditions on the behavior of mortar subjected to an external sulfate attack (ESA). Three different exposure conditions (full immersion, semi-immersion, and drying/wetting cycles) were tested on mortar prisms made with Portland cement and two w/c ratios (0.45 and 0.6). To monitor degradation, it was necessary to evaluate variations in length (expansion), mass changes, compressive and tensile strengths, changes in the total porosity measured using water accessible porosity tests, and changes in the macroscopic behavior of the samples. Mercury intrusion porosimetry (MIP) was used to determine the size distribution of the pores. It was demonstrated that mixing mortar with the lower w/c ratio of 0.45 results in improved performance against an ESA. This study also demonstrates that the type of exposure to an ESA has no significant effect on the kinetics of sulfate penetration during the exposure period. However, the sample’s surface becomes more cracked when subjected to repeated drying and wetting cycles. For all the considered exposure conditions, expansion occurred in three stages. In stage 1, the reaction product (ettringite) precipitated in large voids, without causing significant expansion (the expansion remained low and stable). During the second stage, the reaction products generated growing internal stress. The final stage of expansion resulted in microcracks, strength losses, and the formation of macropores, which ultimately lead to material failure. The MIP results indicate that major changes in the porosity and pore volume distribution occur at the surface layer in regard to the gel and capillary pore ranges. Full article

Lithium mica slag is a byproduct acquired via the sulfate method of lithium extraction, and it contains a certain quantity of soluble sulfates. The improper storage of lithium mica slag not only takes up a large amount of land resources, but also poses a threat in terms of environmental pollution. Therefore, this study aimed to investigate the mechanism by which SO₄²⁻ dissolves in lithium mica slag, along with the impacts of internal sulfate attacks on mortar specimens with 10%, 20%, and 30% lithium mica slag contents. Testing was carried out in terms of the expansion, mass change, flexural and compressive strengths, porosity, composition, and contents of the products. It was determined that a significant quantity of SO₄²⁻ was generated in mortar specimens with lithium mica slag. The mortar specimens mixed with lithium mica slag produced more ettringite (AFt: 3CaO·Al₂O₃·3CaSO₄·32H₂O), which is the product of internal sulfate attacks. This demonstrates that there was an internal sulfate reaction in the mortar specimens mixed with lithium mica slag. The internal sulfate reaction in mortar samples with lithium mica slag was finished in the later stages. It is noteworthy that the reaction did not lead to any cracking or damage; instead, it later allowed for a retention of strength that was equivalent to the strength of mortar specimens without lithium mica slag. In addition, the partial replacement of cement with lithium mica slag not only reduced the environmental pollution caused by soluble sulfates in lithium mica slag, but also reduced the use of cement and, thus, lowered costs. Full article

In salt lake areas, cast-in situ concrete structures are subjected to long-term corrosion by sulfate and magnesium ions. The properties of concrete can be improved by adding materials like basalt fiber (BF). To investigate the degradation process and mechanism of cast-in situ concrete with premixed BF under the dual corrosion of sulfate and magnesium salts, concrete with a content of BF ranging from 0 to 0.5% was prepared. Specimens were subjected to different internal and external corrosion conditions and immersed for 180 days. Dimension, mass, and appearance changes at different immersion times were recorded. The compressive and flexural strength of the specimens were tested and continually observed throughout the immersion time. Mineral and microstructural changes at different immersion times were determined by the XRD, TG, and SEM analysis methods. Results indicated that external sulfate–internal magnesium combined attack had a significant negative effect on the early strength. The compressive and flexural strength of the corroded specimens decreased by 17.2% and 14.1%, respectively, compared to the control group at 28 days. The premixed magnesium ions caused the decomposition of the C-S-H gel, resulting in severe spalling and lower mechanical properties after immersing for a long time. As the BF can inhibit crack development, the properties of the concrete premixed with BF were improved. Specimens exhibited superior performance at a BF content of 0.5%, resulting in a 16.2% increase in flexural strength. This paper serves as a valuable reference for the application of basalt fiber-reinforced concrete under the challenging conditions of sulfate–magnesium combined attack. Full article

This study presents an in-depth investigation into optimizing the mix design of ultra-high-performance concrete (UHPC) for enhanced sulfate erosion resistance, utilizing the modified Andreasen and Andersen (MAA) method. By testing the mechanical properties and slump flow of UHPC, it was determined that the optimal W/B = 0.2, and the best volume content of steel fibers is 2%. Through long-term tests lasting 360 days on three groups of UHPC specimens under different curing conditions, their mass loss, compressive strength corrosion resistance coefficient, surface appearance, and erosion layer thickness were tested. The results indicate that under sulfate attack, the mass and compressive strength corrosion resistance coefficients of UHPC specimens showed a trend of first increasing and then decreasing, due to the formation and expansion of ettringite and gypsum. The thickness of the erosion layer increases over time. By 360 days, the internal damage caused by sulfate attack is about twice as severe as it was after 60 days. However, the addition of steel fibers was found to effectively mitigate these effects, reducing mass loss and preserving the structural integrity of UHPC. Full article

The expansion induced by sulfate attack on cement-treated aggregates (SACA) is a well-known problem that can be solved. It causes obvious heaves in road bases and railway subgrades. In this paper, the effects of the sodium sulfate content, cement content, degree of compaction, sulfate types, attack types, aluminum ion supply, concentration of curing sulfate solution, and temperature on the expansion behavior induced by SACA were investigated over 60 days in the laboratory. Based on the Sobol sensitivity analysis method, the influence of the sensitivity of each factor on the expansion was quantitatively analyzed, and the dominant factor of expansion was proposed. Results show that sulfate content is the domain factor of expansion that is induced by SACA, and it presents a logarithmic function relationship with strain. The 0.5% sodium sulfate content is the minimum sulfate content which causes the expansion that is induced by SACA. When the sulfate content is less than 1%, the expansion induced by SACA is minor. When the sulfate content is between 1% and 3%, the expansion behavior is expressed in four stages as follows: rapid strain increase, followed by a short stagnation period, then a significant strain increase and, finally, constant strain. When the sulfate content is greater than 5%, there are two stages comprising the expansion behavior as follows: the rapid strain increases and constant strain occurs. Greater sulfate content, greater degree of compaction, and lower temperature have positive effects on the expansion induced by SACA. The cement content does not have a consistent effect on expansion behavior. Compared with a sodium sulfate attack, both the reaction rate and expansion of cement-treated aggregates that are attacked by gypsum are smaller, and the attack period is also longer. When the sulfate content is greater than 1%, the addition of kaolin promotes the progression of the expansion induced by SACA. A small amount of water is sufficient for the demand for the sulfate attack. When the sulfate content is at a certain level, the expansion induced by SACA that is under external attack is much smaller than the expansion that is under internal attack. This study is expected to serve as a reference for future research on the mechanics of SACA, and it attempts to provide theoretical support for amending expansions that are induced by SACA. Full article

Cold-bonded Fly Ash Aggregate (CFAA), as an alternative to natural coarse aggregates, can prepare more lightweight, economical, and sustainable concrete. However, CFAA concrete has insufficient durability, which hinders its application in a salt-corrosion environment. Nanosilica (NS) has an advantage of high activity and is generally used as an efficient mineral admixture in engineering. This study aims to improve the strength and durability of CFAA concrete by incorporating NS. To this end, compression tests, splitting tensile tests, and microscopic analyses were performed to investigate the mechanical properties of the concrete containing different NS dosages. Subsequently, the dry–wet and freeze–thaw durability tests were conducted to evaluate the salt-corrosion resistance and the frost resistance in the water, Na₂SO₄ solution, and Na₂CO₃ solution. The results show the compressive and splitting tensile strength peak at 2 wt% NS dosage. In this instance, the concrete has an optimum microstructure and exhibits desirable salt-corrosion resistance in the late stage of dry–wet cycles. During freeze–thaw cycles, NS could improve the frost resistance of the concrete but scarcely diminished internal damage under sulfate attack. The study explores the long-term performance of NS-modified CFAA concrete, providing a simple and effective method to mitigate the concrete deterioration in a harsh environment. Full article

Sulfate attack is one of the main factors affecting the durability of concrete structures. In recent years, multi-walled carbon nanotubes (MWCNTs) have attracted the attention of scholars for their excellent mechanical properties and durability performance. In this paper, the influence of sulfate attack and dry–wet cycles on the performance of multi-walled carbon nanotube–lithium slag concrete (MWCNT-LSC) with varied MWCNT content (0 wt.%, 0.05 wt.%, 0.10 wt.%, and 0.15 wt.%) and varied water–cement ratios (0.35, 0.40, and 0.45) were investigated. In addition, scanning electron microscopy (SEM) and X-ray computed tomography (CT) tests were conducted to analyze the microstructure and pore structure of the concrete. The results showed that concrete incorporated with MWCNTs could effectively mitigate sulfate attack. The resistance to sulfate attack of concrete was negatively related to the water–cement ratio when the dry–wet cycle was fixed. The MWCNT-LSC showed the best compressive strength at the water–cement ratio of 0.35 and 0.10 wt.% MWCNTs. The SEM test results showed that the MWCNTs filled the pores and cracks within the specimen and formed bridges between the cracks, enhancing the resistance to sulfate attack. The CT test results also showed that the addition of MWCNTs could reduce the porosity of concrete, refine the pore size and inhibit the generation and development of cracks, thus optimizing the internal structure of concrete and improving its resistance to sulfate attack. Full article

In order to study the mechanical properties of rubber concrete (RC) with different rubber particle sizes after dry–wet cycles in a sulfate environment, apparent morphology analysis, mass loss analysis, relative dynamic elastic modulus analysis, compressive strength loss analysis, internal microscopic characteristics and deterioration degree analysis of ordinary concrete (NC) and rubber concrete after dry–wet cycles were compared and analyzed. The results show that with the increase in the number of dry–wet cycles, the surface caves of rubber concrete increase, the internal microcracks develop and penetrate, and the macroscopic strength increases first and then decreases significantly. The high elasticity of rubber effectively improves the expansion force caused by sulfate attack and the dry–wet cycle. The deterioration degree of RC in each dry–wet cycle stage is obviously better than that of NC. When the rubber particle size is 0.85 mm, the performance of the sample is the best. After 120 days of dry–wet cycle, the compressive strength is reduced by 37.4%, and the compressive strength of concrete with a rubber particle size of 0.85 mm is reduced by 11.2%. After cyclic loading, the deterioration degree of concrete is 5.1% lower than that of ordinary concrete. Full article

Concrete is a building material that is most widely used because of its excellent mechanical performance and durability. Compressive strength is an essential property of concrete, which changes with time under various factors. In this paper, the time variation law of the compressive strength of concrete was reviewed from three aspects: single, multiple and material internal factors. The mathematical models of compressive strength relative to time under single factors such as carbonization, freeze–thaw cycle, temperature effect and sulfate attack were summarized. Based on the statistical analysis of laboratory experimental data and field test data, the time variation laws of concrete under the coupling action of two or more factors were analyzed. The results show that the strength loss of concrete under the coupling effect of multiple factors is more serious than under the effect of a single factor. In addition, the time variation models of compressive strength in existing buildings were discussed, and it was observed that there are obvious differences between these models. After analysis, it is known that the different data sources and normalization methods are the primary causes of differences. Finally, the influences of concrete internal factors on compressive strength were outlined. The main conclusions of the time variation law of compressive strength were summarized, and further research directions were also proposed. Full article