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16 pages, 2371 KiB  
Article
Exploring Patterns of Ethnic Diversification and Residential Intermixing in the Neighborhoods of Riga, Latvia
by Sindija Balode and Māris Bērziņš
Urban Sci. 2025, 9(7), 274; https://doi.org/10.3390/urbansci9070274 - 16 Jul 2025
Viewed by 268
Abstract
Residential segregation remains a persistent challenge in European urban environments and is an increasing focal point in urban policy debates. This study investigates the changing geographies of ethnic diversity and residential segregation in Riga, the capital city of Latvia. The research addresses the [...] Read more.
Residential segregation remains a persistent challenge in European urban environments and is an increasing focal point in urban policy debates. This study investigates the changing geographies of ethnic diversity and residential segregation in Riga, the capital city of Latvia. The research addresses the complex dynamics of ethnic residential patterns within the distinctive context of post-socialist urban transformation, examining how historical legacies of ethnic diversity interact with contemporary migration flows to reshape neighborhood ethnic composition. Using geo-referenced data from 2000, 2011, and 2021 census rounds, we examined changes in the spatial distribution of five major ethnic groups. Our analysis employs the Dissimilarity Index to measure ethnic residential segregation and the Location Quotient to identify the residential concentration of ethnic groups across the city. The findings reveal that Riga’s ethnic landscape is undergoing a gradual yet impactful transformation. The spatial distribution of ethnic groups is shifting, with the increasing segregation of certain groups, particularly traditional ethnic minorities, coupled with a growing concentration of Europeans and non-Europeans in the inner city. The findings reveal distinctive patterns of ethnic diversification and demographic change, wherein long-term trends intersect with contemporary migration dynamics to produce unique trajectories of ethnic residential segregation, which differ from those observed in Western European contexts. However, the specific dynamics in Riga, particularly the persistence of traditional ethnic minority communities and the emergence of new ethnic groups, highlight the unique context of post-socialist urban landscapes. Full article
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14 pages, 1124 KiB  
Article
Evolution of the Genetic Diversity and Spatial Distribution of Self-Establishing Black Locust (Robinia Pseudoacacia L.) Stands
by Sinilga Černulienė, Rita Verbylaitė and Vidas Stakėnas
Appl. Biosci. 2025, 4(3), 33; https://doi.org/10.3390/applbiosci4030033 - 7 Jul 2025
Viewed by 272
Abstract
Robinia pseudoacacia is one of the most widely introduced—but also controversial—tree species in Europe. On the one hand, it is valued for its productivity, timber quality, and melliferous blossom. On the other hand, it is highly invasive and causes habitat change and homogenization. [...] Read more.
Robinia pseudoacacia is one of the most widely introduced—but also controversial—tree species in Europe. On the one hand, it is valued for its productivity, timber quality, and melliferous blossom. On the other hand, it is highly invasive and causes habitat change and homogenization. The aim of the study reported on here was to assess the genetic diversity of selected R. pseudoacacia stands in Lithuania in districts with the highest black locust stands frequency and to evaluate its spatial distribution in self-establishing stands. To achieve this aim, we employed four nuclear SSR loci (Rops 02, Rops 05, Rops 06, and Rops 08) and investigated the genetic diversity of five R. pseudoacacia plots. The study results reveal that R. pseudoacacia in Lithuania is genetically diverse (the average allele number per plot was 3.66, and the average Ho was 0.83). R. pseudoacacia in the plots forms tight clonal groups that hardly intermix with each other; it also spreads by seeds (66 single-copy genotypes were found in total in all 5 investigated plots). R. pseudoacacia stands in Lithuania originate from different seed sources and from different introduction events, as revealed by the allelic pattern, genetic diversity, and genetic differentiation among the research plots. Full article
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19 pages, 4809 KiB  
Article
Methodology for Wildland–Urban Interface Mapping in Anning City Using High-Resolution Remote Sensing
by Feng Jiang, Xinyu Hu, Xianlin Qin, Shuisheng Huang and Fangxin Meng
Land 2025, 14(6), 1141; https://doi.org/10.3390/land14061141 - 23 May 2025
Viewed by 430
Abstract
The wildland–urban interface (WUI) has been a global phenomenon, yet parameter threshold determination remains a persistent challenge in this field. In China, a significant research gap exists in the development of WUI mapping methodology. This study proposes a novel mapping approach that delineates [...] Read more.
The wildland–urban interface (WUI) has been a global phenomenon, yet parameter threshold determination remains a persistent challenge in this field. In China, a significant research gap exists in the development of WUI mapping methodology. This study proposes a novel mapping approach that delineates the WUI by integrating both vegetation and building environment perspectives. GaoFen 1 Panchromatic Multi-spectral Sensor (GF1-PMS) imagery was leveraged as the data source. Building location was extracted using object-oriented and hierarchical classification techniques, and the pixel dichotomy method was employed to estimate fractional vegetation coverage (FVC). Building location and FVC were used as input for the WUI mapping. In this methodology, the threshold of FVC was determined by incorporating the remote sensing characteristics of the WUI types, whereas the buffer range of vegetation was refined through sensitivity analysis. The proposed method demonstrated high applicability in Anning City, achieving an overall accuracy of 88.56%. The total WUI area amounted to 49,578.05 ha, accounting for 38.08% of Anning City’s entire area. Spatially, the intermix WUI was predominantly distributed in the Taiping sub-district of Anning City, while the interface WUI was mainly concentrated in the Bajie sub-district of Anning City. MODIS fire spots from 2003 to 2022 were primarily clustered in the Qinglong sub-district, Wenquan sub-district, and Caopu sub-district of Anning City. Our findings indicated a spatial overlap between the WUI and fire-prone areas in Anning City. This study presents an effective methodology for threshold determination and WUI mapping, making up for the scarcity of mapping methodologies in China. Moreover, our approach offers valuable insights for a wise decision in fire risk. Full article
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26 pages, 28790 KiB  
Article
An Ecoregional Conservation Assessment for the Northern Rockies Ecoregion and Proposed Climate Refugium in the Yaak River Watershed, USA
by Dominick A. DellaSala, Kaia Africanis, Bryant C. Baker, Matthew Rogers and Diana Six
Forests 2025, 16(5), 822; https://doi.org/10.3390/f16050822 - 15 May 2025
Viewed by 579
Abstract
The incorporation of climate refugia concepts in large-scale protection efforts (e.g., 30% protected by 2030, 50% by 2050) is needed to forestall the global extinction crisis. The 8.19 M ha Northern Rockies Ecoregion (NRE) of western Montana, northeastern Washington, and northern Idaho, USA, [...] Read more.
The incorporation of climate refugia concepts in large-scale protection efforts (e.g., 30% protected by 2030, 50% by 2050) is needed to forestall the global extinction crisis. The 8.19 M ha Northern Rockies Ecoregion (NRE) of western Montana, northeastern Washington, and northern Idaho, USA, includes the 159,822 Yaak River Watershed (YRW) in northwest Montana, a proposed climate refugium that may buffer extreme climate change effects. Climate projections show temperature increases along with reduced summer precipitation, lowered spring snowpack, and increased wildfire susceptibility across the NRE but to a lesser extent in the YRE under an intermediate emissions scenario. Overall protection levels were quite low in the NRE (2.2% in GAP 1 or 2) and even lower in the YRW (1% of national forests; the USDA Forest Service manages most of the area). Approximately 32% of forests are mature but only 2.4% and 0.25% are protected (GAP 1 or 2) within the NRE and YRW, respectively. Habitat protection levels for eight focal forest species selected to reflect conservation priorities were generally low, with only wolverine (Gulo gulo) meeting conservation targets if roadless areas were better protected. Most (~75%) Forest Service fuel reduction treatments were >1 km from structures despite congressional funds aimed at the wildland–urban interface/intermix. Increased roadless area protections would close the lower bound (30%) target for most ecosystem types and focal species but still fall short of upper targets. We recommend coupling conservation targets with strategic investments in fuel reductions aimed at the innermost buffer around structures, while reducing logging and roadbuilding in priority areas and refugia. Full article
(This article belongs to the Section Forest Biodiversity)
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9 pages, 1796 KiB  
Communication
Hydrogen Stable Isotopes Indicate Reverse Migration of Fall Armyworm in North America
by Eduardo S. Calixto and Silvana V. Paula-Moraes
Insects 2025, 16(5), 471; https://doi.org/10.3390/insects16050471 - 29 Apr 2025
Cited by 1 | Viewed by 575
Abstract
Fall armyworm (FAW), Spodoptera frugiperda (J. E. Smith, 1797) (Lepidoptera: Noctuidae), is a major pest in the U.S. and has spread globally, causing severe agricultural losses in different countries. Due to its high mobility and potential for long-distance dispersal, understanding FAW migration is [...] Read more.
Fall armyworm (FAW), Spodoptera frugiperda (J. E. Smith, 1797) (Lepidoptera: Noctuidae), is a major pest in the U.S. and has spread globally, causing severe agricultural losses in different countries. Due to its high mobility and potential for long-distance dispersal, understanding FAW migration is a key tool for forecasting outbreaks and implementing timely management measures. Recent studies using stable hydrogen isotopes indicated reverse (southward) migration of Helicoverpa zea Boddie (Lepidoptera: Noctuidae). Here, we tested the reverse migration hypothesis for FAW in North America. Estimation of the hydrogen isotopic ratio on 324 samples collected in Florida, an intermixing zone at the edge of the continental U.S., indicated evidence of reverse migration in samples of FAW moths. They showed a high probability of origin from the U.S. Corn Belt, with a greater probability of origin in Nebraska, South Dakota, Minnesota, Kansas and Wisconsin. This southward movement provides new insights into the risk of spreading pesticide resistance alleles in this species to southern regions and contributes to the improvement of integrated pest management and insect resistance management programs. Full article
(This article belongs to the Special Issue Corn Insect Pests: From Biology to Control Technology)
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18 pages, 7287 KiB  
Article
Probing the Critical Element Chemistry of Coal-Combustion Fly Ash: Examination of Zircon and Associated Minerals from a Beneficiated Kentucky Fly Ash
by Debora Berti, John G. Groppo, Prakash Joshi, Dorin V. Preda, David P. Gamliel, Todd Beers, Michael Schrock, Shelley D. Hopps, Tonya D. Morgan, Bernd Zechmann and James C. Hower
Minerals 2025, 15(5), 461; https://doi.org/10.3390/min15050461 - 29 Apr 2025
Viewed by 476
Abstract
Along with the principal rare earth (REE) minerals such as monazite, xenotime, and bastnasite, Y-and REE-bearing zircon and associated minerals survive the combustion process and are found in coal-combustion fly ash. Beneficiated fly ash from a power plant burning an eastern-Kentucky-sourced coal blend [...] Read more.
Along with the principal rare earth (REE) minerals such as monazite, xenotime, and bastnasite, Y-and REE-bearing zircon and associated minerals survive the combustion process and are found in coal-combustion fly ash. Beneficiated fly ash from a power plant burning an eastern-Kentucky-sourced coal blend was found to have zircon (ZrSiO4), baddeleyite (ZrO2), fergusonite (YNbO4), yttriaite (Y2O3), and xenotime (YPO4). Previous studies of the same fly had also identified monazite with a broad REE suite. Scanning electron microscopy–electron dispersive spectroscopy (EDS) and transmission electron microscopy (TEM)–EDS as well as other TEM-based techniques revealed a variety of zircon associations, including heavy-REE suites with Y, Nb, and Hf. Hafnium is a common accessory element in zircons and the Y and Nb may be present as fergusonite (YNbO4) intermixed with zircon. Full article
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21 pages, 6597 KiB  
Article
Effects of Fiber Arrangement on Flow Characteristics Along a Four-Fiber Element of Fiber Extractors
by Oluwaseyi O. Ayeni, Holly A. Stretz and Ahmad Vasel-Be-Hagh
Micromachines 2025, 16(4), 425; https://doi.org/10.3390/mi16040425 - 1 Apr 2025
Viewed by 463
Abstract
Fiber extractors, as process-intensified equipment, facilitate many applications, such as the purification of oils. The development of high-fidelity computational models is crucial to optimize the design. However, simulating microscale flows around tens of thousands of microfiber arrays is computationally unfeasible. Thus, it is [...] Read more.
Fiber extractors, as process-intensified equipment, facilitate many applications, such as the purification of oils. The development of high-fidelity computational models is crucial to optimize the design. However, simulating microscale flows around tens of thousands of microfiber arrays is computationally unfeasible. Thus, it is necessary to identify smaller elements, consisting of only a few fibers, that can represent flow within massively arrayed fiber extractors. This study employed computational fluid dynamics to investigate different configurations of four-fiber elements to achieve this aim. Following previous modeling featuring flow around only one fiber, the goal was to understand how variations in inter-fiber distances affect the phase structures of a corn oil/water mixture, the steady-state interfacial surface area per unit of fluid volume, and the pressure drop along the flow direction. The study explored various total and relative flow rates and contact angles. The research characterized the flow as semi-restricted annular, noting the influence of neighboring fibers on phase complexity. The inter-fiber distance played a crucial role in generating high interfacial areas and reducing pressure. The chaotic nature of the slug interfaces facilitated intermixing between flows along different fibers. Interestingly, the specific interfacial area reached an optimum when the inter-fiber distance was between 10 and 50 μm. Full article
(This article belongs to the Special Issue Application of Microfluidic Technology in Bioengineering)
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19 pages, 2306 KiB  
Article
Cognitive Priming During Warmup Enhances Sport and Exercise Performance: A Goldilocks Effect
by Jesús Díaz-García, Ana Rubio-Morales, David Manzano-Rodríguez, Tomás García-Calvo and Christopher Ring
Brain Sci. 2025, 15(3), 235; https://doi.org/10.3390/brainsci15030235 - 23 Feb 2025
Cited by 3 | Viewed by 2153
Abstract
Background: Mental fatigue can impair sport, exercise and cognitive performance. Warmup activities can improve performance when the individual is rested. However, their effectiveness when the individual is fatigued has yet to be established. The research objectives were to evaluate the effects of physical [...] Read more.
Background: Mental fatigue can impair sport, exercise and cognitive performance. Warmup activities can improve performance when the individual is rested. However, their effectiveness when the individual is fatigued has yet to be established. The research objectives were to evaluate the effects of physical and combined physical plus cognitive warmup activities on subsequent sport, exercise, and cognitive performance when rested and fatigued by sleep restriction in athletes (Study 1) and older adults (Study 2). Methods: In Study 1, 31 padel players completed a padel performance test and Stroop task after physical and combined warmups when rested and fatigued by sleep deprivation. In Study 2, 32 older adults completed sit–stand, arm curl, walking, Stroop, and psychomotor vigilance tests after no warmup, physical warmup, and combined warmup when rested and fatigued by sleep deprivation. In both studies, combined warmups intermixed short-, medium-, or long-duration cognitive tasks between physical warmup activities. Mental fatigue was measured using visual analog scale ratings. Results: In both studies, sleep deprivation increased mental fatigue and impaired performance. In Study 1, relative to a physical warmup, padel and Stroop performance were improved by combined warmups (with short-to-medium cognitive tasks) when rested and fatigued. In Study 2, relative to no warmup, sit–stand, arm curl, walking, Stroop, and reaction time performance were improved by physical and combined warmups (with short-to-medium cognitive tasks) when rested and fatigued. Conclusions: The negative effects of sleep deprivation on sport, exercise, and cognitive performance were best mitigated by combined warmups with short-to-medium cognitive tasks. Combined warmups are effective countermeasures against the deleterious effects of mental fatigue on performance. Full article
(This article belongs to the Section Cognitive, Social and Affective Neuroscience)
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10 pages, 8113 KiB  
Article
Adjustment of Magnetic Characteristics for [Co/Pt] Multilayer Thin Films
by Mikhail V. Dorokhin, Anton V. Zdoroveyshchev, Polina B. Demina, Yurii M. Kuznetsov, Daniil A. Zdoroveyshchev, Alexey V. Kudrin, Marina P. Temiryazeva, Alexei G. Temiryazev, Irina L. Kalentyeva, Mikhail V. Ved’, Ruslan N. Kryukov, Sergey Yu. Zubkov and Dmitry A. Tatarskiy
Coatings 2025, 15(2), 186; https://doi.org/10.3390/coatings15020186 - 6 Feb 2025
Viewed by 699
Abstract
In the present paper, we discuss the results of the study of magnetic properties and micromagnetic structure of the multilayer [Co(4 × t) Å/Pt(5 × t) Å]10 thin films with varied bilayer thickness (t). The structures were fabricated [...] Read more.
In the present paper, we discuss the results of the study of magnetic properties and micromagnetic structure of the multilayer [Co(4 × t) Å/Pt(5 × t) Å]10 thin films with varied bilayer thickness (t). The structures were fabricated by alternating electron beam evaporation of Co and Pt targets. The measurements of the element distribution profile, magnetic field dependence of magnetization, and magnetic force microscopy pictures have shown that varying the t coefficient allows for manipulating the degree Co and Pt layers intermixing, which, in turn, changes the magnetic properties of the films over a wide range. In particular, in structures representing a CoxPt1-x solid solution with a variable composition, magnetic skyrmions were revealed upon magnetization of the films. Varying the Co vs. Pt composition heterogeneity makes it possible to control the skyrmion density. The results are believed to be promising for the fabrication of skyrmion-based memory elements. Full article
(This article belongs to the Section Thin Films)
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20 pages, 2314 KiB  
Article
Perpetuation of Avian Influenza from Molt to Fall Migration in Wild Swan Geese (Anser cygnoides): An Agent-Based Modeling Approach
by John Y. Takekawa, Chang-Yong Choi, Diann J. Prosser, Jeffery D. Sullivan, Nyambayar Batbayar and Xiangming Xiao
Viruses 2025, 17(2), 196; https://doi.org/10.3390/v17020196 - 30 Jan 2025
Viewed by 1761
Abstract
Wild waterfowl are considered to be the reservoir of avian influenza, but their distinct annual life cycle stages and their contribution to disease dynamics are not well understood. Studies of the highly pathogenic avian influenza (HPAI) virus have primarily focused on wintering grounds, [...] Read more.
Wild waterfowl are considered to be the reservoir of avian influenza, but their distinct annual life cycle stages and their contribution to disease dynamics are not well understood. Studies of the highly pathogenic avian influenza (HPAI) virus have primarily focused on wintering grounds, where human and poultry densities are high year-round, compared with breeding grounds, where migratory waterfowl are more isolated. Few if any studies of avian influenza have focused on the molting stage where wild waterfowl congregate in a few selected wetlands and undergo the simultaneous molt of wing and tail feathers during a vulnerable flightless period. The molting stage may be one of the most important periods for the perpetuation of the disease in waterfowl, since during this stage, immunologically naïve young birds and adults freely intermix prior to the fall migration. Our study incorporated empirical data from virological field samplings and markings of Swan Geese (Anser cygnoides) on their breeding grounds in Mongolia in an integrated agent-based model (ABM) that included susceptible–exposed–infectious–recovered (SEIR) states. Our ABM results provided unique insights and indicated that individual movements between different molting wetlands and the transmission rate were the key predictors of HPAI perpetuation. While wetland extent was not a significant predictor of HPAI perpetuation, it had a large effect on the number of infections and associated death toll. Our results indicate that conserving undisturbed habitats for wild waterfowl during the molting stage of the breeding season could reduce the risk of HPAI transmission. Full article
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25 pages, 3742 KiB  
Article
A Revised Taxonomy of the Bassia scoparia Complex (Camphorosmoideae, Amaranthaceae s.l.) with an Updated Distribution of B. indica in the Mediterranean Region
by Alexander P. Sukhorukov, Zhibin Wen, Anastasiya A. Krinitsina, Alina V. Fedorova, Filip Verloove, Maria Kushunina, Jean-François Léger, Mathieu Chambouleyron, Abbès Tanji and Alexander N. Sennikov
Plants 2025, 14(3), 398; https://doi.org/10.3390/plants14030398 - 28 Jan 2025
Cited by 1 | Viewed by 1560
Abstract
Bassia scoparia is a widespread weedy species in the temperate regions of the world and is valued as a medicinal and ornamental plant. To date, the taxonomic concept of B. scoparia remains insufficiently studied due to a limited number of samples used in [...] Read more.
Bassia scoparia is a widespread weedy species in the temperate regions of the world and is valued as a medicinal and ornamental plant. To date, the taxonomic concept of B. scoparia remains insufficiently studied due to a limited number of samples used in the previous phylogenetic analyses. To solve the taxonomy of the B. scoparia complex, we constructed a new phylogeny based on the nuclear ribosomal internal transcribed spacer (ITS), plastid intergenic spacer atpB-rbcL, and plastid region rpL16 intron sequences for numerous samples with diverse morphology. Our analysis revealed a close proximity and intermixed positions of the samples of the B. scoparia group with various morphology. Because of this polyphyly, we prefer to broadly delimit the species. An updated nomenclature of B. scoparia is provided including four new synonyms: Bassia angustifolia, B. littorea, Kochia albovillosa, and K. scoparia subsp. hirsutissima. In its new circumscription, B. scoparia encompasses populations with glabrous or variously hairy leaves and perianths. The original material of Kochia sieversiana, previously considered a species with hairy leaves and inflorescences, has the same diagnostic characters as in B. scoparia s.str. The correct name for more hairy-leaved plants is B. scoparia var. subvillosa. Plants with hairy perianths known as Kochia albovillosa and K. scoparia subsp. hirsutissima have a restricted distribution in Central Asia and South Siberia and have never been recorded as alien in other regions; they can be classified as a separate variety, B. scoparia var. hirsutissima. The ornamental variant of oblong or pyramidal shape may be called B. scoparia var. trichophila. Bassia scoparia is often confused with a similarly looking relative, B. indica, especially in North Africa, a region where secondary ranges of both species overlap. Phylogenetically, these species are sister groups; they share some morphological characters but have different primary distribution ranges. We traced a recent expansion of B. indica in the Mediterranean with the first record reported from the European continent (Spain) and uncovered various introduction pathways of the species in this region. Full article
(This article belongs to the Special Issue Taxonomy and Nomenclature of Euro + Mediterranean Vascular Plants)
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17 pages, 1931 KiB  
Article
Lithium Tracer Diffusion in LixCoO2 and LixNi1/3Mn1/3Co1/3O2 (x = 1, 0.9, 0.65)-Sintered Bulk Cathode Materials for Lithium-Ion Batteries
by Erwin Hüger, Daniel Uxa and Harald Schmidt
Batteries 2025, 11(2), 40; https://doi.org/10.3390/batteries11020040 - 21 Jan 2025
Viewed by 1216
Abstract
The knowledge of Li diffusivities in electrode materials of Li-ion batteries (LIBs) is essential for a fundamental understanding of charging/discharging times, maximum capacities, stress formation and possible side reactions. The literature indicates that Li diffusion in the cathode material Li(Ni,Mn,Co)O2 strongly increases [...] Read more.
The knowledge of Li diffusivities in electrode materials of Li-ion batteries (LIBs) is essential for a fundamental understanding of charging/discharging times, maximum capacities, stress formation and possible side reactions. The literature indicates that Li diffusion in the cathode material Li(Ni,Mn,Co)O2 strongly increases during electrochemical delithiation. Such an increased Li diffusivity will be advantageous for performance if it is present already in the initial state after synthesis. In order to understand the influence of a varying initial Li content on Li diffusion, we performed Li tracer diffusion experiments on LixCoO2 (LCO) and LixNi1/3Mn1/3Co1/3O2 (NMC, x = 1, 0.9, 0.65) cathode materials. The measurements were performed on polycrystalline sintered bulk materials, free of additives and binders, in order to study the intrinsic properties. The variation of Li content was achieved using reactive solid-state synthesis using pressed Li2CO3, NiO, Co3O4 and/or MnO2 powders and high temperature sintering at 800 °C. XRD analyses showed that the resultant bulk samples exhibit the layered LCO or NMC phases with a low amount of cation intermixing. Moreover, the presence of additional NiO and Co3O4 phases was detected in NMC with a pronounced nominal Li deficiency of x = 0.65. As a tracer source, a 6Li tracer layer with the same chemical composition was deposited using ion beam sputtering. Secondary ion mass spectrometry in depth profile mode was used for isotopic analysis. The diffusivities followed the Arrhenius law with an activation enthalpy of about 0.8 eV and were nearly identical within error for all samples investigated in the temperature range up to 500 °C. For a diffusion mechanism based on structural Li vacancies, the results indicated that varying the Li content does not result in a change in the vacancy concentration. Consequently, the design and use of a cathode initially made of a Li-deficient material will not improve the kinetics of battery performance. The possible reasons for this unexpected result are discussed. Full article
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8 pages, 2097 KiB  
Communication
Preparation of High Entropy Alloys Without Pre-Alloying, Using Laser Melt Deposition (LMD) Technique
by Ferenc Hareancz, Gergely Juhász, Márk Windisch, Anita Heczel and Ádám Vida
Coatings 2025, 15(2), 116; https://doi.org/10.3390/coatings15020116 - 21 Jan 2025
Cited by 1 | Viewed by 1048
Abstract
This study explores the fabrication of an equimolar CoCrFeNi high-entropy alloy (HEA) using laser metal deposition (LMD) technique on a 316 L austenitic stainless steel substrate, without pre-alloying. Elemental metal powders were mixed in a planetary ball mill and directly deposited to investigate [...] Read more.
This study explores the fabrication of an equimolar CoCrFeNi high-entropy alloy (HEA) using laser metal deposition (LMD) technique on a 316 L austenitic stainless steel substrate, without pre-alloying. Elemental metal powders were mixed in a planetary ball mill and directly deposited to investigate the effect of layer number on alloy composition and substrate intermixing. Experimental results revealed significant dilution in the first four layers, with substrate intermixing affecting composition. The coarse-grained crystal structure observed in the initial layers persisted in subsequent layers, and hardness measurements indicated the cumulative thermal effects of sequential deposition. From an industrial perspective, this approach offers a cost-effective and flexible manufacturing strategy, eliminating the need for pre-alloying. Moreover, gradient compositional layers can be achieved, enabling tailored material properties. This work demonstrates the feasibility of producing multi-layer HEAs directly from elemental powders while addressing the challenges of compositional stability. Full article
(This article belongs to the Special Issue Research and Application of High Entropy Alloys)
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25 pages, 7000 KiB  
Article
Small- to Large-Scale Electron Beam Powder Bed Fusion of Functionally Graded Steels
by Carlos Botero, William Sjöström, Emilio Jimenez-Pique, Andrey Koptyug and Lars-Erik Rännar
J. Manuf. Mater. Process. 2025, 9(1), 7; https://doi.org/10.3390/jmmp9010007 - 29 Dec 2024
Viewed by 1312
Abstract
The ability to control process parameters over time and build space in electron beam powder bed fusion (PBF-EB) opens up unprecedented opportunities to tailor the process and use materials of a different nature in the same build. The present investigation explored the various [...] Read more.
The ability to control process parameters over time and build space in electron beam powder bed fusion (PBF-EB) opens up unprecedented opportunities to tailor the process and use materials of a different nature in the same build. The present investigation explored the various methods used to adapt the PBF-EB process for the production of functionally graded materials (FGMs). In this way, two pre-alloyed powders—a stainless steel (SS) powder and a highly alloyed cold work tool steel (TS) powder—were combined during processing in an S20 Arcam machine. Feasibility experiments were first carried out in a downscaled build setup, in which a single powder container was installed on top of the rake system. In the container, one powder was placed on top of the other (SS/TS) so that the gradient materials were produced as the powders were spread and intermixed during the build. The process was later scaled up to an industrial machine setup, where a similar approach was implemented using two configurations of powder disposal: SS/SS + TS/TS and TS/TS + SS/SS. Each configuration had an intermediate layer of powder blend. The FGMs obtained were characterized in terms of their microstructure and local and macromechanical properties. For the microstructural analysis, optical microscopy, scanning electron microscopy (SEM), and energy-dispersive X-ray spectroscopy (EDX) were performed on the polished cross-sections. This provided evidence of gradual microstructural and compositional transitions in the samples, with a shift from SS to TS and vice versa. Nanoindentation experiments confirmed that there was a consequent gradient in the hardness, stiffness, and wear ratio from the softer and ductile SS to the harder and stiff TS. Scratch experiments revealed gradual evolution in the sliding wear behavior of the printed materials. A “progressive spring” and a “hardness-tailored punching tool” were fabricated as demonstrators. The results obtained demonstrate the great potential to gradually tailor the composition, microstructure, mechanical properties, and wear resistance by combining different powders, and they suggest that any PBF-EB system can be repurposed to build gradient materials without hardware modification. Potential applications include the tooling industry, where hard and wear-resistant materials are needed for the surfaces of tools, with tougher and more ductile materials used in the cores of tools. Full article
(This article belongs to the Special Issue High-Performance Metal Additive Manufacturing, 2nd Edition)
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27 pages, 3487 KiB  
Article
What Factors Affect Binocular Summation?
by Marzouk Yassin, Maria Lev and Uri Polat
Brain Sci. 2024, 14(12), 1205; https://doi.org/10.3390/brainsci14121205 - 28 Nov 2024
Viewed by 968
Abstract
Binocular vision may serve as a good model for research on awareness. Binocular summation (BS) can be defined as the superiority of binocular over monocular visual performance. Early studies of BS found an improvement of a factor of about 1.4 (empirically), leading to [...] Read more.
Binocular vision may serve as a good model for research on awareness. Binocular summation (BS) can be defined as the superiority of binocular over monocular visual performance. Early studies of BS found an improvement of a factor of about 1.4 (empirically), leading to models suggesting a quadratic summation of the two monocular inputs (√2). Neural interaction modulates a target’s visibility within the same eye or between eyes (facilitation or suppression). Recent results indicated that at a closely flanked stimulus, BS is characterized by instability; it relies on the specific order in which the stimulus condition is displayed. Otherwise, BS is stable. These results were revealed in experiments where the tested eye was open, whereas the other eye was occluded (mono-optic glasses, blocked presentation); thus, the participants were aware of the tested eye. Therefore, in this study, we repeated the same experiments but utilized stereoscopic glasses (intermixed at random presentation) to control the monocular and binocular vision, thus potentially eliminating awareness of the tested condition. The stimuli consisted of a central vertically oriented Gabor target and high-contrast Gabor flankers positioned in two configurations (orthogonal or collinear) with target–flanker separations of either two or three wavelengths (λ), presented at four different presentation times (40, 80, 120, and 200 ms). The results indicate that when utilizing stereoscopic glasses and mixing the testing conditions, the BS is normal, raising the possibility that awareness may be involved. Full article
(This article belongs to the Special Issue From Visual Perception to Consciousness)
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