Search Results (3,200)

To address the frequent faults (e.g., bird-related hazards, wind deviation) of transmission lines under extreme environments and the limitations of traditional insulating materials (insufficient dielectric properties, poor interface compatibility, etc.), this study synthesized a disulfide-containing polyurea (DPU) with dynamic covalent bonds and prepared Halloysite nanotubes (HNTs) modified by aminopropyltriethoxysilane (APTES) to form the HNTs/DPU composite. Methods included characterizations like Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), differential scanning calorimetry (DSC), and performance tests such as contact angle measurement, breakdown strength, arc resistance, dielectric constant tests, and a tower gap breakdown test. Results showed that APTES modification enhanced interface compatibility, leading to a uniform and dense microstructure. Compared with commercial polyurea (CPU) and commercial insulating sheath (CIS), HNTs/DPU exhibited superior performance: higher glass transition temperature (Tg) and thermal stability, excellent hydrophobicity, improved breakdown strength and dielectric constant, longer arc resistance time by blocking microcrack propagation, and optimal insulation effect at 4 mm coating thickness in the tower gap test with a significantly higher breakdown voltage. In conclusion, HNTs/DPU provides a new technical solution for transmission line insulation protection under extreme conditions, with comparative data demonstrating advancements over existing materials. Full article

Selective laser sintering (SLS) is an additive manufacturing method that enables the creation of complex-shaped polymer-based structures with great control over the desired properties. In this study, polyamide 12 (PA12)–based powders containing 0.8 wt.% graphene oxide (GO), introduced via a wet-mixing impregnation method, were processed by selective laser sintering (SLS). Implementation of a double laser scanning strategy increased the tensile strength of the composites by 2.5% relative to pristine SLS-processed PA12 and enhanced the thermal conductivity to 0.74 W·m⁻¹·K⁻¹. The results indicate that the laser sintering process is an effective approach to produce low filler content polymer-matrix composites with enhanced thermal properties while preserving mechanical integrity and maintaining electrical insulation behavior. Full article

Bark is a multifunctional organ critical for tree survival, yet its functional plasticity in response to micro-environmental heterogeneity at alpine timberlines remains poorly understood. Here, we investigated the variations in bark physical traits (thickness, density), allometric scaling, and stoichiometric characteristics (C, N, P) of Abies georgei var. smithii (Viguie & Gaussen) W. C. Cheng & L. K. Fu on contrasting sunny and shady slopes in the Sygera Mountains, southeastern Tibetan Plateau. Despite the relative homogeneity of soil physicochemical properties between slope aspects, bark traits exhibited remarkable phenotypic plasticity. Trees on the shady slope possessed significantly thicker bark with higher nitrogen concentrations, adopting a “resource-acquisitive strategy”. Standardized Major Axis (SMA) regression indicated isometric scaling ($b\approx 1.03$) for trees on the shady slope, reflecting a sustained investment in bark thickness to provide thermal insulation against cold stress. Conversely, trees on the sunny slope exhibited negative allometry ($b \approx 0.87$), characterized by denser tissues and elevated C/N ratios. This shift represents a conservative strategy geared toward hydraulic safety and resistance to high radiation and evaporative loss. Crucially, our results show that bark traits are largely decoupled from soil nutrient gradients, being shaped instead by microclimate. The distinct trade-off—prioritizing insulation on shady slopes versus conservation on sunny slopes—underscores the importance of phenotypic plasticity for the persistence of timberline species in a changing climate. Full article

:The growing demand for smart electronic devices in daily life requires sustainable, renewable energy sources that reliably power portable and wearable systems. Triboelectric nanogenerators (TENGs) have emerged as a promising platform for smart textile-based energy harvesting due to their material versatility and mechanical compliance. In this work, electrospun poly (vinylidene fluoride) (PVDF) fiber mats incorporating boron nitride (BN) nanoparticles and reduced graphene oxide (rGO) were investigated to elucidate the roles of insulating and conductive nanofillers in governing the structural and electroactive properties of PVDF-based triboelectric materials. Electrospun PVDF mats containing 5 wt.% BN exhibited enhanced β-phase content (82%), attributed to the nucleating effect of BN and strong interfacial interactions between the nanofiller and the PVDF matrix. In contrast, 7 wt.% rGO demonstrated a high electroactive β-phase fraction (81%), arising from filler-induced dipole alignment and enhanced charge transport within the fibrous network. A comparative analysis of BN and rGO highlights filler-driven mechanisms influencing the electroactive phase formation and triboelectric charge generation in PVDF mats. The corresponding triboelectric power density reached 231 μWcm⁻² for the 7 wt.% rGO/PVDF and 281 μWcm⁻² for the 5 wt.% BN/PVDF-based TENGs, providing valuable insights for the rational design of high-performance, flexible triboelectric materials for wearable energy-harvesting applications. Full article

Studies on two-dimensional materials (such as topological insulators or transition metal dichalcogenides) have shown that they exhibit unique properties, including high charge carrier mobility and tunable bandgaps, making them attractive for next-generation electronics. Some of these materials (e.g., HfSe${}_2$) also offer thickness-dependent bandgap engineering. However, the standard device fabrication techniques often introduce processing contamination, which reduces device efficiency. In this paper, we present a modified mechanical exfoliation technique, the Reversed Structuring Procedure, which enables the fabrication of hybrid systems based on 2D microflakes with improved interface cleanness and contact quality. Hall effect measurements on Bi${}_2$Se${}_3$ and HfSe${}_2$ devices confirm enhanced electrical performance, including the decrease in the measured total resistance. We also introduce a novel Star-Shaped Electrode Structure, which allows for accurate Hall measurements and the exploration of geometric magnetoresistance effects within the same device. This dual-purpose geometry enhances the flexibility and demonstrates broader functionality of the proposed fabrication method. The presented results validate the Reversed Structuring Procedure method as a robust and versatile approach for laboratory test-platforms for electronic applications of new types of layered materials whose fabrication technology is not yet compatible with CMOS. Full article

The increasing amount of multilayer packaging waste poses significant environmental challenges and calls for sustainable valorization solutions. This study aimed to investigate the acoustic properties of composite materials produced by hot-pressing multilayer waste without the addition of binders or other substances. The waste was carefully cleaned and shredded into square or strip-like geometries, and the composite material plates were compressed at different temperatures (120 °C, 125 °C, 130 °C, 135 °C, and 140 °C) under a constant pressure of 5 MPa. The sound absorption coefficients were evaluated for representative samples, with results analyzed as a function of constituent geometry and processing temperature. Experimental results indicate that the pressing temperature critically affects the internal structure of the material, while waste shape exhibits a frequency-dependent influence on the absorption coefficient. The resulting composite materials display low porosity, which limits internal sound absorption and promotes sound wave reflection, indicating that these materials are more suitable for sound insulation rather than acoustic absorption. These results highlight the potential of multilayer packaging waste-based composites as a sustainable solution for noise control applications and highlight the importance of processing parameters in tailoring their acoustic performance. Full article

Mycelium-based composites (MBCs)—biomaterials made from fungal-inoculated substrates—are promising candidates to replace conventional rigid thermal insulation panels. However, many MBCs are made from hemp, a plant material that is quite difficult to source in many countries for regulation reasons, and mobilizes agricultural fields at the expense of food and feed crops. Meanwhile, many of our natural and urban ecosystems are subject to invasion by plants that are just burnt or even left in place, while they may be very good substrate for MBCs. This study investigated the comparative physical and thermal properties of MBCs derived from two distinct lignocellulosic feedstocks: hemp shives (a traditional material) and biomass from the highly invasive species Reynoutria japonica. Polyisocyanurate (PIR) was included as a synthetic benchmark. The MBCs produced from R. japonica demonstrated as low a thermal conductivity as the hemp MBCs in our internally developed method, but also as the PIR standard. However, they exhibited suboptimal physical characteristics: higher bulk density (166 vs. 128 kg/m³ for hemp) and significantly higher water absorption (7.5% vs. 3.5% volume uptake after 2 min). This suggest that they are a less viable alternative to hemp-based MBCs for heat insulation applications. Full article

Ceramsite foam concrete (CFC), recognized for its lightweight, thermal insulation, and eco-friendly properties, is a promising material for composite structures. The interfacial shear bond behavior between CFC and normal concrete (NC) critically governs the structural integrity of CFC-NC systems. This study investigates the interfacial shear bond strength through direct double shear tests on twelve cubic specimens with controlled interface roughness and casting intervals. Quantitative analysis reveals that increased roughness enhances shear strength by up to 28.6~59.5%, while prolonged casting intervals reduce strength by 22.3~34.6%. Notably, excessive roughness shifts failure modes from interfacial debonding to material failure within CFC, where shear bond strength becomes governed by CFC’s compressive strength. A rigid–plastic model is developed to characterize the shear bond behavior of CFC-NC interface and demonstrates 96% accuracy in predicting experimental results. The findings provide useful insights for improving CFC-NC composite design in engineering applications. Full article

Air-penetrating and noise-canceling constructions are required for numerous noise control issues. High ventilation performance conflicts with effective sound insulation, and vice versa. For this reason, ventilated noise barriers are currently being intensively researched and developed. One of the most popular solutions is the louvered-type barrier, whose acoustic efficiency depends on its geometric parameters as well as the acoustic properties of the louvers. One of the main challenges is optimizing the acoustic impedance of louver surfaces in order to achieve maximum reflection, absorption, or minimum transmission of sound waves. This paper proposes an analytical solution to the diffraction problem of a plane sound wave incident on a periodic array of similar thin screens with arbitrary impedance surfaces. An infinite system of linear equations is derived, and its numerical solution allows us to find the reflection and transmission coefficients. It has been shown that screens with reactive impedance are necessary to achieve maximum sound reflection. On the other hand, dissipative screens are required for minimal sound transmission. Additionally, the absorption properties of the array have been studied. It has been found that there is an optimal impedance value that provides the maximum absorption coefficient. Full article

Polyethylene waxes (PEWs) are considered promising mid-temperature phase change materials (PCMs). However, their low thermal conductivity limits both applicability and efficiency. One of the more interesting inorganic additives for PCMs is boron nitride (BN), which exhibits high thermal conductivity while remaining electrically insulating, excellent chemical and thermal stability, and good oxidation resistance. In this study, PEW was modified with hexagonal boron nitride (h-BN) in the range of 0.025 to 0.5 wt.%. Differential scanning calorimetry (DSC) results revealed that the addition of h-BN significantly alters the phase-transition behavior of polyethylene wax, broadens the melting and solidification temperature ranges, and reduces supercooling from 11 °C to 9 °C. Thermogravimetric analysis (TGA) showed that the incorporation of h-BN improves the thermal stability of the material. The temperature corresponding to 5% mass loss increased by about 50 °C after incorporation of more than 0.025% h-BN. The temperature of maximum mass-loss rate (T_DTGmax) was shifted about 8 °C toward higher temperatures. FTIR results indicate that h-BN does not change the chemical structure of polyethylene waxes, but does affect their morphology and physical properties by increasing the thermal conductivity from 0.30 to 0.40 mW/K. These effects enable the design of composites with tunable properties for energy-storage applications. Full article

Hemp is a high-yield crop traditionally cultivated for fiber used in products such as paper, textiles, ropes, and animal bedding, and more recently for sustainable applications in biofuels, insulation, and bioplastics. Beyond fiber, hemp is rich in phytochemicals. More than 500 compounds including cannabinoids, terpenes, phenolics, phytosterols, and tocopherols are accumulated in leaves, flowers, and seeds, which are typically considered waste products in the fiber industry. These compounds exhibit antioxidant, anti-inflammatory, neuroprotective, and antimicrobial properties, which have stimulated research into their pharmaceutical potential. However, hemp phytochemicals also find applications in other industrial sectors, including agrochemistry as natural insecticides, cosmetics for skin and hair care, and food and dietary supplements due to their associated health benefits. In light of this, the present review aims to give an overview of the available literature on the most common applications of hemp tissues, hemp extract, and purified hemp phytochemicals in agrochemical, cosmetic, and food sectors. This will be helpful to critically assess the current state of knowledge in this field and contribute to the ongoing debate over the natural and sustainable applications of hemp by-products. Full article

Plant-based materials exhibit different moisture absorption properties than synthetic materials. In the case of synthetic fibrous insulation, the effect of moisture on thermal conductivity can be relatively easily determined based on the mass fraction of moisture in the material’s skeleton. In the case of cellulosic materials with an open capillary structure, determining this effect requires laboratory testing. The authors conducted laboratory tests of the thermal conductivity coefficient of dry and wet plant-based insulation, such as flax and hemp shives. The effect of material densification at various moisture levels was also considered. The article also presents a numerical analysis of the thermal state and moisture content of thermal insulation used in walls operating under moderate climatic conditions. For damp shives, thermal conductivity increases noticeably with increasing densification, while for dry shives, thermal conductivity decreases until a certain level of densification is achieved. The obtained results were compared with values calculated using a linear model of the relationship between thermal conductivity and moisture content in the material. At higher moisture values, around 14–15 wt.%, thermal conductivity results are significantly lower than those obtained from the linear model (12.5–16.3% in the case of flax shives and 8.4–11.3% in the case of hemp shives) This is a favorable characteristic of shives compared to the performance of, for example, mineral wool in elevated humidity conditions. The authors believe that their results will be not only scientific but also practical, facilitating the assessment of heat loss in buildings. Full article

Hybrid systems consisting of metal–fullerene composites exhibit intriguing properties but often suffer from thermal instability. With proper control, such instability can be harnessed to enable the formation of sophisticated nanostructures with nanometric precision. These self-organization phenomena are not limited to thermal stimulation alone but can also be triggered by other external stimuli. In this work, we investigate the morphological evolution of thin films composed of evaporated C₆₀ and sputtered nickel mixtures, focusing on how external stimuli influence both their structural and electrical properties. Thin films were prepared under controlled deposition conditions, and their surface morphology was analyzed using advanced characterization techniques. Progressive changes in film morphology were observed as a function of composition and external treatment, highlighting the interplay between metallic and molecular components. In particular, it was observed that, due to the annealing treatment, the sample undergoes strong phase separation, with the formation of structures tens of microns in diameter and an increase in electrical resistance, exhibiting insulating behavior. These findings provide insights into the mechanisms governing hybrid thin film formation and suggest potential applications in electronic, optoelectronic, and energy-related devices. Full article

Urban leaf litter represents an underutilized biomass resource with potential applications in sustainable building materials. This study investigates the suitability of dried, comminuted leaves collected from municipal green areas as a loose-fill thermal insulation material. The material was characterized in terms of thermal conductivity, settlement behavior, fire reaction, resistance to mold growth, water vapor diffusion, hygroscopic sorption, and short-term water absorption. Tests were conducted following relevant DIN and ISO standards, with both untreated and flame-retardant-treated samples examined. Results indicate that the thermal conductivity of leaf-based insulation (λ = 0.041–0.046 W/m·K) is comparable to other bio-based loose-fill materials such as cellulose and wood fiber. Optimal performance was achieved for particles sized 2–16 mm, showing settlement below 1%. All variants, including untreated material, fulfilled the fire resistance requirements of class E, while selected treatments further improved fire resistance. The material exhibited moderate vapor permeability (μ ≈ 4–5), low water absorption, and moisture buffering behavior similar to that of other bio-based insulation materials. Resistance to mold growth was satisfactory under standardized conditions. Overall, the results demonstrate that leaf litter can serve as an effective and environmentally favorable loose-fill insulation material, offering an innovative recycling pathway for urban green waste. Full article

A firewood stove’s combustion chamber can withstand temperatures of 1500 °C. To prevent the deterioration of a firewood stove due to excessive heat, it is necessary to use thermal insulation materials that stop heat transfer to the walls. These materials must be economical and durable. This work examines the materials used in the construction of combustion chambers of firewood stoves in southern Mexico and Central America. This field study collects information and samples of materials used in the manufacture of firewood stoves. Heat transfer experiments are conducted, and the thermal properties of each material are analyzed. As a result, methodology and information is provided for the manufacture of future plancha-type firewood stoves used in the study area, such as pine wood (pinus chiapensis) which is mainly used as casing for firewood stoves in coniferous forest areas; in addition, the use of wood ash as thermal insulation material is proposed since it does not present direct costs and has a thermal conductivity between 0.10 and 0.20 W/m°C and a melting point greater than 1500 °C. The next layer proposed is hollow brick, a high-temperature-resistant material that can be used as support due to its mechanical strength and low thermal conductivity of 0.6 W/m°C. Finally, the use of calcium hydroxide as a coating material is proposed, applied in the form of a paste or paint to detail the imperfections of the combustion chamber construction as it resists temperatures above 1000 °C. Full article