Search Results (132)

Three-dimensional computational fluid dynamics (CFD) simulation was performed using the eddy-dissipation concept coupled with detailed hydrogen oxidation kinetics and a reduced two-step methane mechanism for a newly proposed W-shaped radiant tube burner (RTB). The effects of the hydrogen volume fraction (0–100%) and excess air ratio (0%, 10%, 20%) on the flame morphology, temperature distribution, and NO_X emissions are systematically analyzed. The results deliver three main points. First, a flame-shape transformation was identified in which the near-injector flame changes from a triangular attached mode to a splitting mode as the mixture reactivity increases with the transition occurring at a characteristic laminar flame speed window of about 0.33 to 0.36 m/s. Second, NO_X shows non-monotonic behavior with dilution, and 10% excess air can produce higher NO_X than 0% or 20% because OH radical enhancement locally promotes thermal NO pathways despite partial cooling. Third, a multi-parameter coupling strategy was established showing that hydrogen enrichment raises the maximum gas temperature by roughly 100 to 200 K from 0% to 100% H₂, while higher excess air improves axial temperature uniformity and can suppress NO_X if over-dilution is avoided. These findings provide a quantitative operating map for balancing stability, uniform heating, and NO_X–CO trade-offs in hydrogen-enriched industrial RTBs. Full article

Methoxy radicals (CH₃O•), formed as intermediates during methane oxidation, may play an underexplored but locally significant role in the atmospheric oxidation of dimethyl sulfide (DMS), a key sulfur-containing compound emitted primarily by marine phytoplankton. This study presents a comprehensive computational investigation of the reaction mechanisms and kinetics of DMS oxidation initiated by CH₃O•, using density functional theory B3LYP-D3(BJ)/6-311++G(3df,3pd), CCSD(T)/6-311++G(3df,3pd), and UCBS-QB3 methods. Our calculations show that DMS reacts with CH₃O• via hydrogen atom abstraction to form the methyl-thiomethylene radical (CH₃SCH₂•), with a rate constant of 3.05 × 10⁻¹⁶ cm³/molecule/s and a Gibbs free energy barrier of 14.2 kcal/mol, which is higher than the corresponding barrier for reaction with hydroxyl radicals (9.1 kcal/mol). Although less favorable kinetically, the presence of CH₃O• in localized, methane-rich environments may still allow it to contribute meaningfully to DMS oxidation under specific atmospheric conditions. While the short atmospheric lifetime of CH₃O• limits its global impact on large-scale atmospheric sulfur cycling, in marine layers where methane and DMS emissions overlap, CH₃O• may play a meaningful role in forming sulfur dioxide and downstream sulfate aerosols. These secondary organic aerosols lead to cloud condensation nuclei (CCN) formation, subsequent changes in cloud properties, and can thereby influence local radiative forcing. The study’s findings underscore the importance of incorporating CH₃O• driven oxidation pathways into atmospheric models to enhance our understanding of regional sulfur cycling and its impacts on local air quality, cloud properties and radiative forcing. These findings provide mechanistic insights that improve data interpretation for atmospheric models and extend predictions of localized variations in sulfur oxidation, aerosol formation, and radiative forcing in methane-rich environments. Full article

This research investigates a methane-fueled open gas system, enhanced by Prof. Szewalski’s idea of venting exhaust gases at various turbine stages. It assesses the impact of hydrogen co-combustion, which can range from 0% to 100%, on system parameters. The novel approach increased the gas turbine’s electrical efficiency to 41.25%. Two additional heat exchangers raised the inlet fluid temperature, affecting the exhaust gases entering the turbine. The highest exhaust gas temperature reached was 1491.08 °C. A higher hydrogen ratio significantly lowered CO₂ emissions. The study’s originality lies in its innovative technology combination, allowing flexible combustion adjustments to meet energy demands and fuel availability. The gas turbine model provides a detailed analysis of cooling air at each expander stage, enhancing understanding of efficiency factors. Integration with Power-to-Fuel technology facilitates the creation of energy systems that efficiently store and use renewable energy. This contributes to sustainable energy technology development, crucial for achieving climate goals and reducing emissions. Full article

Over 292 million tons of municipal solid waste (MSW) are generated annually in the United States, with more than half disposed of in landfills. Municipal solid waste landfills (MSWLFs) are stationary sources of air pollution and potential health risks for nearby communities. The Agency for Toxic Substances and Disease Registry (ATSDR) has completed over 300 public health assessments (PHAs) and related investigations at MSWLFs and open dumps since the 1980s. This paper reviews the ATSDR’s evaluations of air pathway concerns at 125 MSWLF sites assessed between 1988 and early 2025, with many being evaluated during the 1990s. Most sites were located in the Midwest and Northeast, and only 25% remained active. The ATSDR found no air-related public health hazard at 86% of sites. At sites where hazards were identified, common issues included elevated outdoor or indoor toxicants (e.g., hydrogen sulfide, benzene, trichloroethylene, and mercury) and unsafe methane accumulations. Contributing factors included older site designs, inadequate gas-collection, subsurface fires, and distance from nearby residences. Corrective actions effectively reduced exposures at the affected sites. Results suggest that well-located and maintained landfills minimize public health hazards, while aging or poorly managed sites pose risks. Continued monitoring and research are warranted as waste management shifts toward reducing, reusing, recycling, composting, and energy-recovery technologies to improve efficiency, advance technologies, and address systemic public health challenges. Full article

This study aims to qualitatively and quantitatively assess the ability of the flow solver “reactingFoam” of the open-source OpenFOAM software v.2506 for a control-volume-based computational fluid dynamics (CFD) solver in treating the reacting flow problem of a popular benchmarking bluff-body-stabilized turbulent diffusion (non-premixed) flame, that is, the HM1 flame. The HM1 flame has a fuel stream composed of 50% hydrogen (H₂) and 50% methane (CH₄) by mole. Thus, the acronym “HM1” stands for “hydrogen–methane, with level 1 of jet speed”. This fuel stream is surrounded by a coflow of oxidizing air jet. This flame was studied experimentally at the University of Sydney. A measurement dataset of flow and chemical fields was compiled and made available freely for validating relevant computational models. We simulate the HM1 flame using the reactingFoam solver and report here various comparisons between the simulation results and the experimental results to aid in judging the feasibility of this open-source CFD solver. The computational modeling was conducted using the specialized wedge geometry, suitable for axisymmetric problems. The turbulence–chemistry interaction (TCI) was based on the Chalmers’ partially stirred reactor (CPaSR) model. The two-equation k-epsilon framework is used in modeling the small eddy scales. The four-step Jones-Lindstedt (JL) reaction mechanism is used to describe the chemical kinetics. Two meshes (coarse and fine) were attempted, and a converged (mesh-independent) solution was nearly attained. Overall, we notice good agreement with the experimental data in terms of resolved profiles of the axial velocity, mass fractions, and temperature. For either mesh resolution, the overall deviation between the computational results and the experimental results is approximately 8% (mean absolute deviation) and 10% (root mean square deviation). These are favorably low. The current study, and the presented details about the reactingFoam solver and its implementation, can be viewed as a good case study in CFD modeling of reacting flows. In addition, the information we provide about the measurement dataset, the emphasized recirculation zone, the entrainment phenomena, and the irregularity in the radial velocity can help other researchers who may use the same HM1 data. Full article

The growing demand for air connectivity, coupled with the forecasted increase in passengers by 2040, implies an exigency in the aviation sector to adopt sustainable approaches for net zero emission by 2050. Sustainable Aviation Fuel (SAF) is currently the most promising short-term solution; however, ensuring its overall sustainability depends on reducing the life cycle carbon footprints. A key challenge prevails in hydrogen usage as a reactant for the approved ASTM routes of SAF. The processing, conversion and refinement of feed entailing hydrodeoxygenation (HDO), decarboxylation, hydrogenation, isomerisation and hydrocracking requires substantial hydrogen input. This hydrogen is sourced either in situ or ex situ, with the supply chain encompassing renewables or non-renewables origins. Addressing this hydrogen usage and recognising the emission implications thereof has therefore become a novel research priority. Aside from the preferred adoption of renewable water electrolysis to generate hydrogen, other promising pathways encompass hydrothermal gasification, biomass gasification (with or without carbon capture) and biomethane with steam methane reforming (with or without carbon capture) owing to the lower greenhouse emissions, the convincing status of the technology readiness level and the lower acidification potential. Equally imperative are measures for reducing hydrogen demand in SAF pathways. Strategies involve identifying the appropriate catalyst (monometallic and bimetallic sulphide catalyst), increasing the catalyst life in the deoxygenation process, deploying low-cost iso-propanol (hydrogen donor), developing the aerobic fermentation of sugar to 1,4 dimethyl cyclooctane with the intermediate formation of isoprene and advancing aqueous phase reforming or single-stage hydro processing. Other supportive alternatives include implementing the catalytic and co-pyrolysis of waste oil with solid feedstocks and selecting highly saturated feedstock. Thus, future progress demands coordinated innovation and research endeavours to bolster the seamless integration of the cutting-edge hydrogen production processes with the SAF infrastructure. Rigorous techno-economic and life cycle assessments, alongside technological breakthroughs and biomass characterisation, are indispensable for ensuring scalability and sustainability. Full article

Anaerobic digestion of manures, crop residues, food waste, and sludge frequently yields biogas with elevated hydrogen sulfide concentrations, which accelerate corrosion and reduce biogas quality. Microaeration, defined as the controlled addition of oxygen at 1 to 5% of the biogas production rate, has been investigated as a low-cost desulfurization strategy. This review synthesizes studies from 2015 to 2025 spanning laboratory, pilot, and full-scale anaerobic digester systems. Continuous sludge digesters supplied with ambient air at 0.28–14 m³ h⁻¹ routinely achieved 90 to 99% H₂S removal, while a full-scale dairy manure system reported a 68% reduction at 20 m³ air d⁻¹. Pure oxygen dosing at 0.2–0.25 m³ O₂ (standard conditions) per m³ reactor volume resulted in greater than 99% removal. Reported methane yield improvements ranged from 5 to 20%, depending on substrate characteristics, operating temperature, and aeration control. Excessive oxygen, however, reduced methane yields in some cases by inhibiting methanogens or diverting carbon to CO₂. Documented benefits of microaeration include accelerated hydrolysis of lignocellulosic substrates, mitigation of sulfide inhibition, and stimulation of sulfur-oxidizing bacteria that convert sulfide to elemental sulfur or sulfate. Optimal redox conditions were generally maintained between −300 and −150 mV, though monitoring was limited by low-resolution oxygen sensors. Recent extensions of the Anaerobic Digestion Model No. 1 (ADM1), a mathematical framework developed by the International Water Association, incorporate oxygen transfer and sulfur pathways, enhancing its ability to predict gas quality and process stability under microaeration. Economic analyses estimate microaeration costs at 0.0015–0.0045 USD m⁻³ biogas, substantially lower than chemical scrubbing. Future research should focus on refining oxygen transfer models, quantifying microbial shifts under long-term operation, assessing effects on digestate quality and nitrogen emissions, and developing adaptive control strategies that enable reliable application across diverse substrates and reactor configurations. Full article

This study investigates the combustion behavior of H₂–CH₄ mixtures with oxygen-enriched air, achieved through injecting ozone (O₃) into the air intake of the burner fan. The motivation for this approach lies in the high reactivity of hydrogen compared to methane, with the aim of promoting a more favorable oxidizing environment for overall combustion. The research combines theoretical analysis with experimental validation using a diffusion-type burner operating at a fuel flow rate of 1.2 Nm³/h. For this flow rate, the ozone injection led to an equivalent O₂ concentration of approximately 21.7%. At this enrichment level, flame temperature was calculated to increase by 70–90 °C. The burner was specifically designed for the diffusion combustion of H₂–CH₄ mixtures and features three fuel injection nozzles, each surrounded by five air inlets. Experiments employed premixed H₂-CH₄ gas cylinders (Linde) with hydrogen concentrations of 20% and 30%, respectively. The results confirmed slight combustion intensification due to elevated oxygen concentration, with no issues related to flame stability or pulsations observed. Core flame temperature and flue gas emissions, including CO₂, were measured. The results support the further development of this combustion technology by increasing the allowable oxygen concentration limit. Full article

Quantifying air emissions from livestock pastures remains challenging due to spatial variability and temporal fluctuations in emissions due to weather conditions. In this study we used a small unmanned aerial vehicle (sUAV) equipped with real-time sensors and an air sample collection system to directly measure carbon dioxide (CO₂), methane (CH₄), ammonia (NH₃), nitrous oxide (N₂O), nitrogen dioxide (NO₂), hydrogen sulfide (H₂S), total volatile organic compound (VOC), and particulate matter (PM₁, PM_2.5, PM₁₀) emissions across two dairy pastures, two beef pastures, and one sheep pasture in Wisconsin. Emission rates were calculated using the Lagrangian mass balance model and validated against ground-level dynamic flux chamber (DFC) measurements. UAV-based CO₂ concentrations showed a strong correlation with DFC measurements (R² = 0.86, RMSE = 21.5 ppm, MBE = +9.7 ppm). Dairy 1 yielded the highest emissions for most compounds, with average emission rates of 0.50 ± 0.28 g m⁻² day⁻¹ head⁻¹ for CO₂, 8.48 ± 2.75 mg m⁻² day⁻¹ head⁻¹ for CH₄, and 0.20 ± 0.60 mg m⁻² day⁻¹ head⁻¹ for NH₃. The sheep pasture, on the other hand, had the lowest CH₄ and NH₃ emission rates, averaging 0.35 ± 0.22 mg m⁻² day⁻¹ head⁻¹ and 0.02 ± 0.05 mg m⁻² day⁻¹ head⁻¹, respectively. Rainfall events (≥ 5 mm within five days of sampling) significantly elevated N₂O emissions (0.56 ± 0.40 vs. 0.13 ± 0.17 mg m⁻² day⁻¹ head⁻¹). Particulate matter emissions were significantly affected by forage density. PM_2.5 emission rates reached 1.25 × 10⁻⁴ g m⁻² day⁻¹ head⁻¹ under low vegetative cover. It was concluded that emissions were affected by both animal species and the environmental conditions. The findings of this study provide a foundation for further development of emission inventories for pasture-based livestock production systems. Full article

Blue hydrogen is a promising low-carbon alternative to conventional fossil fuels. This technology has been garnering increasing attention with many technological advances in recent years, with a particular focus on the deployed materials and process configurations aimed at minimising the cost and CO₂ emissions intensity of the process as well as maximising efficiency. However, less attention is given to the practical aspects of large-scale deployment, with the cooling requirements often being overlooked, especially across multiple locations. In particular, the literature tends to focus on CO₂ emissions intensity of blue hydrogen production processes, with other environmental impacts such as water and electrical consumption mostly considered an afterthought. Notably, there is a gap to understand the impact of cooling methods on such environmental metrics, especially with technologies at a lower technology readiness level. Herein, two cooling methods (namely, air-cooling versus water-cooling) have been assessed and cross-compared in terms of their energy impact alongside techno-economics, considering deployment across two specific locations (United Kingdom and Saudi Arabia). A sorption-enhanced steam-methane reforming (SE-SMR) coupled with chemical-looping combustion (CLC) was used as the base process. Deployment of this process in the UK yielded a levelised cost of hydrogen (LCOH) of GBP 2.94/kg H₂ with no significant difference between the prices when using air-cooling and water-cooling, despite the air-cooling approach having a higher electricity consumption. In Saudi Arabia, this process achieved a LCOH of GBP 0.70 and GBP 0.72 /kg H₂ when using air- and water-cooling, respectively, highlighting that in particularly arid regions, air-cooling is a viable approach despite its increased electrical consumption. Furthermore, based on the economic and process performance of the SE-SMR-CLC process, the policy mechanisms and financial incentives that can be implemented have been discussed to further highlight what is required from key stakeholders to ensure effective deployment of blue hydrogen production. Full article

Unmanned aerial vehicles, also termed as unarmed aerial vehicles, are used for various purposes in and around the environment, such as delivering things, spying on opponents, identification of aerial images, extinguishing fire, spraying the agricultural fields, etc. As there are multi-functions in a single UAV model, it can be used for various purposes as per the user’s requirement. The UAVs are used for faster communication of identified information, entry through the critical atmospheres, and causing no harm to humans before entering a collapsed path. In relation to the above discussion, a UAV system is designed to classify and transmit information about the atmospheric conditions of the environment to a central controller. The UAV is equipped with advanced sensors that are capable of detecting air pollutants such as carbon monoxide (CO), carbon dioxide (CO₂), methane (CH₄), ammonia (NH₃), hydrogen sulfide (H₂S), etc. These sensors present in the UAV model monitor the quality of air, time-to-time, as the UAV navigates through different areas and transmits real-time data regarding the air quality to a central unit; this data includes detailed information on the concentrations of different pollutants. The central unit analyzes the data that are captured by the sensor and checks whether the quality of air meets the atmospheric standards. If the sensed levels of pollutants exceed the thresholds, then the system present in the UAV triggers a warning alert; this alert is communicated to local authorities and the public to take necessary precautions. The developed UAV is furnished with cameras which are used to capture real-time images of the environment and it is processed using the YOLO V3 algorithm. Here, the YOLO V3 algorithm is defined to identify the context and source of pollution, such as identifying industrial activities, traffic congestion, or natural sources like wildfires. Full article

In order to ensure the safety of methane/hydrogen, regular SiO₂ powder was modified. Fe(C₅H₅)₂/SiO₂ composite dry powder (CDP) was selected as the explosion-suppression material. Explosion-suppression experiments and numerical simulations were adopted to investigate the inhibition effect of 0% (${\mathit{X}}_{{\mathrm{H}}_2}$ = 0%) and 20% (${\mathit{X}}_{{\mathrm{H}}_2}$ = 20%) hydrogen doping ratios. The flame structure, flame propagation speed, and maximum explosion pressure are depicted to compare the inhibition effect of different mass fractions (X_Fe(C5H5)2 = 0–6%). The results showed that CDP significantly reduced the flame propagation velocity and maximum explosion pressure of ${\mathit{X}}_{{\mathrm{H}}_2}$ = 0%. The best effect was observed when 6% Fe(C₅H₅)₂ was added, with the velocity reduced to 9.241 m/s. The maximum explosion pressure was reduced to 0.518 MPa, and the effect was relatively weak for ${\mathit{X}}_{{\mathrm{H}}_2}$ = 20%, with the maximum pressure reduced to 0.525 MPa. In addition, the key radical production and temperature sensitivity showed that Fe(C₅H₅)₂ altered the molar fractions of the major species and increased the consumption of •H, •O, and •OH. As the mass fraction of Fe(C₅H₅)₂ increased, the steady-state concentrations of •H, •O, and •OH in the system showed a significant decreasing trend. This phenomenon originated from the two-step synergistic mechanism of Fe(C₅H₅)₂ inhibiting radical generation and accelerating radical consumption. This study provides insight into the process of Fe(C₅H₅)₂/SiO₂ composite dry powder inhibition and renders theoretical guidance for the explosion protection of methane/hydrogen. Full article

In recent years, frequent open biomass burning (OBB) activities such as agricultural residue burning and forest fires have led to severe air pollution and carbon emissions across South and Southeast Asia (SSEA). We selected this area as our study area and divided it into two sub-regions based on climate characteristics and geographical location: the South Asian Subcontinent (SEAS), which includes India, Laos, Thailand, Cambodia, etc., and Equatorial Asia (EQAS), which includes Indonesia, Malaysia, etc. However, existing methods—primarily emission inventories relying on burned area, fuel load, and emission factors—often lack accuracy and temporal resolution for capturing fire dynamics. Therefore, in this study, we employed high-resolution fire point data from China’s Feng Yun-4A (FY-4A) geostationary satellite and the Fire Radiative Power (FRP) method to construct a daily OBB emission inventory at a 5 km resolution in this region for 2020–2022. The results show that the average annual emissions of carbon (C), carbon dioxide (CO₂), carbon monoxide (CO), methane (CH₄), non-methane organic gases (NMOGs), hydrogen (H₂), nitrogen oxide (NO_X), sulfur dioxide (SO₂), fine particulate matter (PM_2.5), total particulate matter (TPM), total particulate carbon (TPC), organic carbon (OC), black carbon (BC), ammonia (NH₃), nitric oxide (NO), nitrogen dioxide (NO₂), non-methane hydrocarbons (NMHCs), and particulate matter ≤ 10 μm (PM₁₀) are 178.39, 598.10, 33.11, 1.44, 4.77, 0.81, 1.02, 0.28, 3.47, 5.58, 2.29, 2.34, 0.24, 0.58, 0.43, 0.99, 1.87, and 3.84 Tg/a, respectively. Taking C emission as an example, 90% of SSEA’s emissions come from SEAS, especially concentrated in Laos and western Thailand. Due to the La Niña climate anomaly in 2021, emissions surged, while EQAS showed continuous annual growth at 16.7%. Forest and woodland fires were the dominant sources, accounting for over 85% of total emissions. Compared with datasets such as the Global Fire Emissions Database (GFED) and the Global Fire Assimilation System (GFAS), FY-4A showed stronger sensitivity and regional adaptability, especially in SEAS. This work provides a robust dataset for carbon source identification, air quality modeling, and regional pollution control strategies. Full article

Hydrogen and some of its derivatives (such as e-methanol, e-methane, and e-ammonia) are promising energy carriers that have the potential to replace conventional fuels, thereby eliminating their harmful environmental impacts. An innovative use of hydrogen as a zero-emission fuel is forming weakly ionized plasma by seeding the combustion products of hydrogen with a small amount of an alkali metal vapor (cesium or potassium). This formed plasma can be used as a working fluid in supersonic open-cycle magnetohydrodynamic (OCMHD) power generators. In these OCMHD generators, direct-current (DC) electricity is generated straightforwardly without rotary turbogenerators. In the current study, we quantitatively and qualitatively explore the levels of electric conductivity and the resultant volumetric electric output power density in a typical OCMHD supersonic channel, where thermal equilibrium plasma is accelerated at a Mach number of two (Mach 2) while being subject to a strong applied magnetic field (applied magnetic-field flux density) of five teslas (5 T), and a temperature of 2300 K (2026.85 °C). We varied the total pressure of the pre-ionization seeded gas mixture between 1/16 atm and 16 atm. We also varied the seed level between 0.0625% and 16% (pre-ionization mole fraction). We also varied the seed type between cesium and potassium. We also varied the oxidizer type between air (oxygen–nitrogen mixture, 21–79% by mole) and pure oxygen. Our results suggest that the ideal power density can reach exceptional levels beyond 1000 MW/m³ (or 1 kW/cm³) provided that the total absolute pressure can be reduced to about 0.1 atm only and cesium is used for seeding rather than potassium. Under atmospheric air–hydrogen combustion (1 atm total absolute pressure) and 1% mole fraction of seed alkali metal vapor, the theoretical volumetric power density is 410.828 MW/m³ in the case of cesium and 104.486 MW/m³ in the case of potassium. The power density can be enhanced using any of the following techniques: (1) reducing the total pressure, (2) using cesium instead of potassium for seeding, and (3) using air instead of oxygen as an oxidizer (if the temperature is unchanged). A seed level between 1% and 4% (pre-ionization mole fraction) is recommended. Much lower or much higher seed levels may harm the OCMHD performance. The seed level that maximizes the electric power is not necessarily the same seed level that maximizes the electric conductivity, and this is due to additional thermochemical changes caused by the additive seed. For example, in the case of potassium seeding and air combustion, the electric conductivity is maximized with about 6% seed mole fraction, while the output power is maximized at a lower potassium level of about 5%. We also present a comprehensive set of computed thermochemical properties of the seeded combustion gases, such as the molecular weight and the speed of sound. Full article

A thermodynamic analysis of a compact hydrogen generation system for mobile fuel cell applications is presented. The system consists of a miniature autothermal steam reformer (ATR) and a water–gas shift (WGS) reactor, designed to produce hydrogen from hydrocarbon fuels for a 1 kW proton exchange membrane (PEM) fuel cell. Methane is used as the model fuel, and the study focuses on optimizing feed compositions and operational conditions to maximize hydrogen yield and purity. Feed compositions and operational conditions are optimized. In total, 0.7 Nm³ h⁻¹ H₂ is generated from 0.25 Nm³ h⁻¹ CH₄ with properly adjusted steam and air feeding. Issues with product purity and start-up procedures have been identified and discussed, along with feasible solutions. The system is suitable for remote and mobile applications. Full article