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17 pages, 2531 KiB  
Article
Evaluation of the Alkali–Silica Reaction Potential of Korean Aggregates: Experimental Insights and Mitigation Strategies for Concrete Durability
by Chul Seoung Baek and Byoung Woon You
Materials 2025, 18(14), 3373; https://doi.org/10.3390/ma18143373 - 18 Jul 2025
Viewed by 363
Abstract
The alkali–silica reaction (ASR) is an important mechanism of concrete deterioration, whereby reactive silica in aggregate interacts with cement alkalis to form expanding gel, which compromises the structural integrity of the concrete. Although the Republic of Korea has historically been classified as a [...] Read more.
The alkali–silica reaction (ASR) is an important mechanism of concrete deterioration, whereby reactive silica in aggregate interacts with cement alkalis to form expanding gel, which compromises the structural integrity of the concrete. Although the Republic of Korea has historically been classified as a low-risk region for ASR due to its geological stability, documented examples of concrete damage since the late 1990s have necessitated a rigorous reassessment of local aggregates. This study evaluated the ASR potential of 84 aggregate samples sourced from diverse Korean geological regions using standardized protocols, including ASTM C 1260 for mortar bar expansion and ASTM C 289 for chemical reactivity, supplemented by soundness, acid drainage, and weathering index analyses. The results indicate expansion within the range of 0.1–0.2%, classified as potentially deleterious, for some rock types. In addition to ASR reactivity, isolated high anomalies (e.g., high soundness, acid producing, and weathering) suggest the existence of other durability risks. Consequently, while Korean aggregates predominantly have a low ASR reactivity, the adoption of various validated ASR tests as a routine test and the integration of supplementary cementitious materials are recommended to ensure long-term concrete durability, highlighting the need for sustained monitoring and further investigation into mitigation strategies. Full article
(This article belongs to the Section Construction and Building Materials)
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21 pages, 4330 KiB  
Article
The Influence of Boundary Conditions on the Seismic Resistance of Retrofitted Ancient Masonry Towers
by Hrvoje Smoljanović, Ivan Balić, Nikolina Živaljić, Boris Trogrlić and Ante Munjiza
Buildings 2025, 15(14), 2495; https://doi.org/10.3390/buildings15142495 - 16 Jul 2025
Viewed by 232
Abstract
Historic masonry towers represent a significant part of the cultural heritage, which is often subject to retrofitting for preservation purposes. Due to the poor quality of the mortar, if present at all, the connection of existing towers to the foundation is generally such [...] Read more.
Historic masonry towers represent a significant part of the cultural heritage, which is often subject to retrofitting for preservation purposes. Due to the poor quality of the mortar, if present at all, the connection of existing towers to the foundation is generally such that it cannot ensure their monolithic behaviour under seismic action. When choosing a retrofitting technique, engineers often find themselves in a dilemma, whether to strengthen the connection between the tower and the foundation in order to enable the transfer of bending moments from the tower to the foundation due to seismic action, or to leave the towers freely rested on the foundation in order to enable the rocking motion mechanism. The aim of this paper was to investigate how the connection between the tower and the foundation affects the seismic resistance of masonry towers. For this purpose, a series of numerical analyses were performed on 2D numerical models that were created based on the geometry of five towers from the Italian region. In these numerical analyses, each of the towers is subjected to an incremental dynamic analysis in time for the case that it is freely supported on the base and for the case that it is freely rested base. The numerical analyses showed that: (i) unretrofitted towers have relatively low seismic resistance and rocking mechanisms cannot be realised to a significant extent; (ii) retrofitted masonry towers resting freely on the base have a significantly higher seismic resistance compared to the same towers connected to the base due to the rocking motion mechanism. The conclusions drawn on the basis of the conducted studies can serve engineers when choosing a technique for strengthening masonry towers. Full article
(This article belongs to the Special Issue Challenges in Structural Repairs and Renovations)
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27 pages, 21889 KiB  
Article
Modulus of Elasticity and Mechanical Properties Assessment of Historical Masonry Elements After Elevated Temperature: Experimental Study and Numerical Analysis
by Ahmet Fazıl Kara, Ferit Cakir and Metehan Calis
Buildings 2025, 15(13), 2324; https://doi.org/10.3390/buildings15132324 - 2 Jul 2025
Viewed by 433
Abstract
Historical masonry structures deteriorate over time, requiring restoration and strengthening. Hydraulic lime-based mortars (HLMs), due to their compatibility with historical materials, are commonly used for this purpose. This study examines the fire resistance of masonry walls constructed with HLMs. Masonry prisms with clay [...] Read more.
Historical masonry structures deteriorate over time, requiring restoration and strengthening. Hydraulic lime-based mortars (HLMs), due to their compatibility with historical materials, are commonly used for this purpose. This study examines the fire resistance of masonry walls constructed with HLMs. Masonry prisms with clay bricks were prepared using HLMs in accordance with material testing standards. Specimens were subjected to high temperatures ranging from 200 °C to 800 °C, followed by flexural–compression tests for mortar and compression tests for masonry prisms. A total of 20 masonry prism specimens, 15 brick specimens, and 15 mortar specimens were tested, including reference specimens at room temperature. Experimental results indicate that masonry prisms, clay bricks, and HLMs progressively lose their mechanical properties as temperature increases. The elastic modulus of masonry prisms was evaluated according to relevant standards, and Finite Element Analysis (FEA) was conducted to validate temperature-dependent material properties. The stress–strain response of M15 HLM masonry prisms was determined, addressing the absence of such data in EN 1996-1-2. Additionally, compression test results were compared with digital image correlation (DIC) analyses to enhance measurement accuracy. This study provides critical insights into the thermal performance of masonry walls with HLMs, contributing to the development of fire-resistant restoration materials. Full article
(This article belongs to the Section Building Structures)
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21 pages, 5396 KiB  
Article
A Numerical Strategy to Assess the Stability of Curved Masonry Structures Using a Simple Nonlinear Truss Model
by Natalia Pingaro, Martina Buzzetti and Alessandro Gandolfi
Buildings 2025, 15(13), 2226; https://doi.org/10.3390/buildings15132226 - 25 Jun 2025
Viewed by 433
Abstract
A straightforward and versatile numerical approach is proposed for the nonlinear analysis of single and double-curvature masonry structures. The method is designed to broaden accessibility to both experienced and less specialized users. Masonry units are discretized with elastic quadrilateral elements, while mortar joints [...] Read more.
A straightforward and versatile numerical approach is proposed for the nonlinear analysis of single and double-curvature masonry structures. The method is designed to broaden accessibility to both experienced and less specialized users. Masonry units are discretized with elastic quadrilateral elements, while mortar joints are modeled with a combination of elastic orthotropic plate elements or shear panels and elastic perfectly brittle trusses (cutoff bars). This method employs the simplest inelastic finite element available in any commercial software to lump nonlinearities exclusively within the mortar joints. It effectively captures the failure of curved structures under Mode 1 deformation, reproducing the typical collapse mechanism of unreinforced arches and vaults via flexural plastic hinges. The proposed method is benchmarked through three case studies drawn from the literature, each supported by experimental data and numerical results of varying complexity. A comprehensive evaluation of the global force–displacement curves, along with the analysis of the thrust line and the evolution of nonlinearities within the model, demonstrates the effectiveness, reliability, and simplicity of the approach proposed. By bridging the gap between advanced simulation and practical application, the approach provides a robust tool suitable for a wide range of users. This study contributes to a deeper understanding of the behavior of unreinforced curved masonry structures and lays a base for future advancements in the analysis and conservation of historical heritage. Full article
(This article belongs to the Collection Innovation in Structural Analysis and Dynamics for Constructions)
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21 pages, 3488 KiB  
Article
Sample Origin Effect on Chemical Reactivity of Tajogaite Volcanic Ashes for Ancient Mortar Repair
by Imren Basar, David Torrens-Martín, Lucía Fernández-Carrasco, Cristhian Caiza, Joan Martínez-Bofill and Marcel Hürlimann
Sustain. Chem. 2025, 6(3), 18; https://doi.org/10.3390/suschem6030018 - 24 Jun 2025
Viewed by 567
Abstract
Volcanic ashes (VA) ejected by the Tajogaite Volcano were studied to determine their potential as pozzolanic materials for construction applications. A representative number of VA samples (15 in total) were collected from different geolocations and altitudes during and immediately after the volcanic eruption, [...] Read more.
Volcanic ashes (VA) ejected by the Tajogaite Volcano were studied to determine their potential as pozzolanic materials for construction applications. A representative number of VA samples (15 in total) were collected from different geolocations and altitudes during and immediately after the volcanic eruption, in order to assess their reactivity as a function of position and environmental exposure. Various analytical techniques—XRD, FTIR, and SEM/EDX—were used to determine the initial microstructural composition of the VA samples. Additionally, saturated lime testing and the Frattini test were performed to evaluate their pozzolanic reactivity for use in historical mortars. The microstructural analyses revealed that the dominant mineral phases are aluminosilicates. The reactivity tests confirmed a good pozzolanic response, with the formation of C-A-S-H gels identified as the main hydration products at the studied curing times. Full article
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19 pages, 2201 KiB  
Article
Acoustic Emission for Structural Monitoring of Historical Masonry: An In-Field Application
by Luciana Di Gennaro, Giovanni Loreto, Giorgio Frunzio, Gianvittorio Rizzano and Claudio Guarnaccia
Appl. Sci. 2025, 15(13), 7111; https://doi.org/10.3390/app15137111 - 24 Jun 2025
Viewed by 293
Abstract
Acoustic Emission is a non-invasive technique with potential applications in Structural Health Monitoring (SHM), particularly for assessing historic masonry structures. However, its use in this field is complex due to the heterogeneous nature of masonry, where variations in density, mortar joints, and internal [...] Read more.
Acoustic Emission is a non-invasive technique with potential applications in Structural Health Monitoring (SHM), particularly for assessing historic masonry structures. However, its use in this field is complex due to the heterogeneous nature of masonry, where variations in density, mortar joints, and internal discontinuities influence signal propagation, leading to attenuation and distortion that complicate damage detection and localization. Nonetheless, AE can offer qualitative insights into damage initiation and progression, serving as a complementary approach to traditional monitoring methods. This study explores the feasibility of AE through an in-field test conducted on the historic Santa Maria delle Grazie complex, assessing its ability to capture qualitative indicators of structural behaviour. By integrating AE results with data from conventional monitoring instruments, a comprehensive interpretation of the load test outcomes was developed despite the challenges posed by the irregularities of ancient masonry. The findings contribute to the ongoing evaluation of AE as a diagnostic tool and highlight its potential role in heritage conservation strategies. Full article
(This article belongs to the Section Acoustics and Vibrations)
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34 pages, 8454 KiB  
Article
Architectural Heritage Conservation and Green Restoration with Hydroxyapatite Sustainable Eco-Materials
by Alina Moșiu, Rodica-Mariana Ion, Iasmina Onescu, Meda Laura Moșiu, Ovidiu-Constantin Bunget, Lorena Iancu, Ramona Marina Grigorescu and Nelu Ion
Sustainability 2025, 17(13), 5788; https://doi.org/10.3390/su17135788 - 24 Jun 2025
Cited by 1 | Viewed by 619
Abstract
Sustainable architectural heritage conservation focuses on preserving historical buildings while promoting environmental sustainability. It involves using eco-friendly materials and methods to ensure that the cultural value of these structures is maintained while minimizing their ecological impact. In this paper, the use of the [...] Read more.
Sustainable architectural heritage conservation focuses on preserving historical buildings while promoting environmental sustainability. It involves using eco-friendly materials and methods to ensure that the cultural value of these structures is maintained while minimizing their ecological impact. In this paper, the use of the hydroxyapatite (HAp) in various combinations on masonry samples is presented, with the aim of identifying the ideal solution to be applied to an entire historical building in Banloc monument. The new solution has various advantages: compatibility with historical lime mortars (chemical and physical), increased durability under aggressive environmental conditions, non-invasive and reversible, aligning with conservation ethics, bioinspired material that avoids harmful synthetic additives, preservation of esthetics—minimal visual change to treated surfaces, and nanostructural (determined via SEM and AFM) reinforcement to improve cohesion without altering the porosity. An innovative approach involving hydroxiapatite addition to commercial mortars is developed and presented within this paper. Physico-chemical, mechanical studies, and architectural and economic trends will be addressed in this paper. Some specific tests (reduced water absorption, increased adhesion, high mechanical strength, unchanged chromatic aspect, high contact angle, not dangerous freeze–thaw test, reduced carbonation test), will be presented to evidence the capability of hydroxyapatite to be incorporated into green renovation efforts, strengthen the consolidation layer, and focus on its potential uses as an eco-material in building construction and renovation. The methodology employed in evaluating the comparative performance of hydroxyapatite (HAp)-modified mortar versus standard Baumit MPI25 mortar includes a standard error (SE) analysis computed column-wise across performance indicators. To further substantiate the claim of “optimal performance” at 20% HAp addition, independent samples t-tests were performed. The results of the independent samples t-tests were applied to three performance and cost indicators: Application Cost, Annualized Cost, and Efficiency-Cost-Performance (ECP) Index. This validates the claim that HAp-modified mortar offers superior overall performance when considering efficiency, cost, and durability combined. Full article
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16 pages, 2704 KiB  
Article
Shear Capacity of Masonry Walls Externally Strengthened via Reinforced Khorasan Jacketing
by Cagri Mollamahmutoglu, Mehdi Ozturk and Mehmet Ozan Yilmaz
Buildings 2025, 15(13), 2177; https://doi.org/10.3390/buildings15132177 - 22 Jun 2025
Viewed by 361
Abstract
This study investigates the in-plane shear behavior of solid brick masonry walls, both unreinforced and retrofitted using Reinforced Khorasan Jacketing (RHJ), a traditional pozzolanic mortar technique rooted in Iranian and Ottoman architecture. Six one-block-thick English bond masonry walls were tested in three configurations: [...] Read more.
This study investigates the in-plane shear behavior of solid brick masonry walls, both unreinforced and retrofitted using Reinforced Khorasan Jacketing (RHJ), a traditional pozzolanic mortar technique rooted in Iranian and Ottoman architecture. Six one-block-thick English bond masonry walls were tested in three configurations: unreinforced with Horasan plaster (Group I), reinforced with steel mesh aligned to wall edges (Group II), and reinforced with mesh aligned diagonally (Group III). All the walls were plastered with 3.5 cm of Horasan mortar and tested after 18 months using diagonal compression, with load-displacement data recorded. A detailed 3D micro-modeling approach was employed in finite element simulations, with bricks and mortar modeled separately. The Horasan mortar was represented using an elastoplastic Mohr-Coulomb model with a custom softening law (parabolic-to-exponential), calibrated via inverse parameter fitting using the Nelder-Mead algorithm. The numerical predictions closely matched the experimental data. Reinforcement improved the shear strength significantly: Group II showed a 1.8 times increase, and Group III up to 2.7 times. Ductility, measured as post-peak deformation capacity, increased by factors of two (parallel) and three (diagonal). These enhancements transformed the brittle failure mode into a more ductile, energy-absorbing behavior. RHJ is shown to be a compatible, effective retrofit solution for historic masonry structures. Full article
(This article belongs to the Section Building Structures)
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17 pages, 6282 KiB  
Article
Preliminary Analysis of the Impact of Finishing Layers on the Hygroscopic Performance of Vernacular Earthen Plasters from Santiago, Chile
by Patrícia Marchante, Amanda Rivera Vidal, Simone Murgia, Antonia Navarro Ezquerra, Maddalena Achenza and Paulina Faria
Buildings 2025, 15(11), 1930; https://doi.org/10.3390/buildings15111930 - 3 Jun 2025
Viewed by 635
Abstract
Buildings of historic neighborhoods of Santiago de Chile are protected by a coating system composed of different layers of earth-based mortars, as part of a building culture that has been neglected and forgotten since the introduction of industrialized materials but still exists in [...] Read more.
Buildings of historic neighborhoods of Santiago de Chile are protected by a coating system composed of different layers of earth-based mortars, as part of a building culture that has been neglected and forgotten since the introduction of industrialized materials but still exists in many buildings. This study presents preliminary results from ongoing research that explores the hygroscopic capacity of this vernacular coating system and the impact of incorporating recent finishing layers into traditional construction practices. The investigation focuses on identifying materials and techniques typical of traditional Chilean coatings, highlighting their role in enhancing the durability of historic buildings, improving user comfort, and promoting environmental sustainability. It contributes to the conservation of historic buildings and their reuse, as well as to the health of its inhabitants, due to its contribution to hygrometric regulation. This article focuses on this last purpose, through the identification and characterization of the coating system and its finishing layer materials, and a comparative sorption/desorption test of four case studies with these vernacular coatings. This study began with the sample extraction in situ, followed by its observation and cataloguing. Stratigraphic and stereo microscope analysis of the finishing layers were carried out to identify them. The characterization of the finishing materials was performed using FTIR-ATR and SEM-EDX tests. The sorption/desorption test was performed with a set of original complete samples of the four case studies. Subsequently, another set was prepared with the removal of the finishing layers in order to compare their influence on the hygroscopicity of the coating systems. The results elucidate the variety of materials employed on the finishing layer of these coatings, which are often superimposed, revealing renovations and reparations over time. The influence of these finishing materials on sorption properties of the coating system (the scratch and base coats) is exposed by comparing the samples with and without them. Full article
(This article belongs to the Special Issue Materials and Technologies for Regenerative Built Environments)
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20 pages, 4225 KiB  
Article
Enhancing Lime-Based Mortars with Multiwalled Carbon Nanotubes—Composites for Historic Building Restoration: Mechanical, Thermal, and Hygric Performance Analysis
by Adam Pivák, Martina Záleská, Milena Pavlíková and Zbyšek Pavlík
J. Compos. Sci. 2025, 9(6), 266; https://doi.org/10.3390/jcs9060266 - 27 May 2025
Cited by 1 | Viewed by 813
Abstract
The use of binders in construction dates back to antiquity, with lime-based materials historically playing a significant role. However, the 20th century brought the widespread replacement of lime with Portland cement (PC), for its superior mechanical strength, durability, and faster setting time. Despite [...] Read more.
The use of binders in construction dates back to antiquity, with lime-based materials historically playing a significant role. However, the 20th century brought the widespread replacement of lime with Portland cement (PC), for its superior mechanical strength, durability, and faster setting time. Despite these advantages, the restoration of historic masonry structures has revealed the incompatibility of PC with traditional materials, leading to damage due to increased brittleness, stiffness, and reduced permeability. Consequently, lime mortars remain the preferred choice for heritage conservation. To enhance their durability while maintaining compatibility with historic materials, the incorporation of carbon-based nanoparticles has gained attention. This study investigated the impact of the carbon nanotubes (CNTs) additive on two types of lime-based mortars, calcium lime (CL) and hydraulic lime (HL), evaluating structural and mechanical properties, heat transport characteristics, and hygric properties after modification by CNTs with dosages of 0.1%, 0.3%, and 0.5% binder weight. Incorporation of CNTs into CL mortar resulted in an increase in mechanical strength and slight reduction in heat transport and water absorption due to changes in porosity. The addition of CNTs into HL mortars reduced porosity, pore size distribution, and other depending characteristics. The utilisation of CNTs as an additive in the investigated lime-based composites has been identified as a potentially effective approach for the reinforcement and functionalisation of these composite materials, as they exhibited enhanced mechanical resistance while preserving their other engineering properties, making them well suited for use as compatible mortars in building heritage repairs. Full article
(This article belongs to the Special Issue Sustainable Composite Construction Materials, Volume II)
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16 pages, 8970 KiB  
Article
Analysis of the Thermal Properties of Soft Silica Limestone Walls of Traditional Buildings in Central Poland
by Aleksandra Gorączko, Paula Szczepaniak and Marcin Gorączko
Materials 2025, 18(10), 2399; https://doi.org/10.3390/ma18102399 - 21 May 2025
Viewed by 514
Abstract
The challenge of thermally upgrading traditional stone masonry buildings is addressed through the analysis of a representative example typical of regional rural architecture in central Poland, constructed using soft silica limestone and clay mortar. These buildings, which form an important part of the [...] Read more.
The challenge of thermally upgrading traditional stone masonry buildings is addressed through the analysis of a representative example typical of regional rural architecture in central Poland, constructed using soft silica limestone and clay mortar. These buildings, which form an important part of the local cultural heritage, are increasingly becoming the subject of interdisciplinary research and conservation initiatives. This study presents a detailed characterization of the materials and architectural features specific to this building typology. Thermal transmittance calculations were performed and analyzed, with the use of THERM 7.6.1.0 software enabling precise modeling of the wall’s heterogeneous structure. The physical and thermal properties of natural materials—particularly soft silica limestone and clay—were taken into account. The analysis included evaluation of the heat transfer coefficient, temperature distribution, and heat flux density for a reference wall model, as well as for variants with both internal and external insulation layers. The study explores thermal comfort and energy performance within the broader context of preserving and reusing historic rural buildings. Furthermore, the findings are discussed in relation to current European energy efficiency regulations and heritage protection frameworks. The scientific value of this work lies in its context-specific, material-sensitive methodology and in providing practical insight into balancing energy retrofitting with architectural conservation. Full article
(This article belongs to the Special Issue Testing of Materials and Elements in Civil Engineering (4th Edition))
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15 pages, 5803 KiB  
Article
Use of Recycled Aggregates in Lime Mortars for Conservation of Historical Buildings
by Menard Kilumile, Marilda Barra, Fatma Mohamed and Diego Aponte
Constr. Mater. 2025, 5(2), 28; https://doi.org/10.3390/constrmater5020028 - 24 Apr 2025
Viewed by 1004
Abstract
The use of recycled burnt clay brick sand (RBS) and recycled concrete sand (RCS) in historical lime-based repair mortars can reduce the environmental impact caused by construction and demolition waste disposal. This study examined the use of fine recycled concrete and recycled brick [...] Read more.
The use of recycled burnt clay brick sand (RBS) and recycled concrete sand (RCS) in historical lime-based repair mortars can reduce the environmental impact caused by construction and demolition waste disposal. This study examined the use of fine recycled concrete and recycled brick aggregates for the production of historical repair mortars using hydraulic lime binder and the influence of the resulting mortars on the performance of historical buildings in reduced scale walls (stacks). Natural-river-sand mortar (NSM) was used as control. Results showed that the recycled-burnt-brick-sand mortar (RBSM) performed better in terms of strength compared to the recycled-concrete sand (RCSM) and the NSM mortars. At the age of 7 and 28 days, the flexural strength of the RBSM and the RCSM was 131% and 44%, respectively, and 300% and 68% above that of the control mortar. The 45-day flexural strength of the NSM and RCSM was similar whilst the RBSM mortar’s strength was 177% higher. The compressive strength followed similar trend. On the other hand, the strength and modulus of elasticity of the stacks were found to be largely influenced by the strength of the brick units. Full article
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29 pages, 29974 KiB  
Article
Restoration Study of a Masonry Monumental Building in Thrapsano, Greece
by Barbara Charalambidi, Maria E. Stavroulaki and Georgios E. Stavroulakis
Buildings 2025, 15(8), 1266; https://doi.org/10.3390/buildings15081266 - 12 Apr 2025
Viewed by 498
Abstract
This study investigates structural integrity and proposes retrofitting solutions for the historical two-storey school building in Thrapsano, Crete, severely impacted by the September 2021 earthquake. An extensive methodology was adopted, incorporating field surveys, material characterization, finite element modeling, and experimental analysis. The assessment [...] Read more.
This study investigates structural integrity and proposes retrofitting solutions for the historical two-storey school building in Thrapsano, Crete, severely impacted by the September 2021 earthquake. An extensive methodology was adopted, incorporating field surveys, material characterization, finite element modeling, and experimental analysis. The assessment is focused on identifying structural damage, such as cracking and delamination in masonry walls, and evaluating the dynamic and static performance of the load-bearing system under seismic loads. Key interventions include grouting for masonry reinforcement, replacement of mortar with compatible materials, stitching of cracks, and the addition of reinforced concrete and metallic tie elements to enhance diaphragm action. Advanced numerical simulations, validated through experimental data, were employed to model the pre- and post-retrofit behavior of the structure. The proposed retrofitting measures align with Eurocodes 6 and 8, and the Greek code for masonry structures (KADET), aiming to restore the structural stability and improve seismic resilience while respecting the building’s historical significance. The results from the finite element analysis confirm the effectiveness of the interventions in reducing tensile stresses and improving load redistribution, ensuring compliance with modern safety standards. This case study offers a framework for the seismic retrofitting of heritage structures in a similar context. Full article
(This article belongs to the Special Issue Challenges in Seismic Analysis and Assessment of Buildings)
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30 pages, 7718 KiB  
Review
Research Progress of the Preparation of Cellulose Ethers and Their Applications: A Short Review
by Meng He, Yanmei Lin, Yujia Huang, Yunhui Fang and Xiaopeng Xiong
Molecules 2025, 30(7), 1610; https://doi.org/10.3390/molecules30071610 - 4 Apr 2025
Cited by 3 | Viewed by 1579
Abstract
Cellulose ethers (CEs), synthesized through the etherification of cellulose, have emerged as indispensable “green additives” in our modern industries, earning the moniker of industrial “monosodium glutamate” due to their unparalleled multifunctionality. Unlike traditional petroleum-based modifiers, CEs offer a unique combination of renewability, low [...] Read more.
Cellulose ethers (CEs), synthesized through the etherification of cellulose, have emerged as indispensable “green additives” in our modern industries, earning the moniker of industrial “monosodium glutamate” due to their unparalleled multifunctionality. Unlike traditional petroleum-based modifiers, CEs offer a unique combination of renewability, low toxicity, and tunable properties (e.g., water retention, thickening, and stimuli-responsiveness), making them pivotal for advancing sustainable construction practices. This review presents an overview of the preparation methods of various CEs and the applications of CEs especially in concrete and mortars as well as corresponding mechanisms. We systematically analyze the preparation methodologies (homogeneous vs. heterogeneous processes) and highlight the effect of molecular determinants (degree of substitution, molecular weight, functional groups) on the performances of CEs. CEs can enhance the workability and other properties of concrete and mortars primarily by acting as water-retaining and thickening agents to mitigate rapid water loss, improve hydration efficiency and cohesion. The effects of CEs on the delay of hydration and microstructure of concrete and mortars are also analyzed and highlighted. Beyond construction, we reviewed the current and emerging CE applications in biomedicine, tissue-engineering, petroleum industry and food engineering, highlighting their cross-disciplinary potential. This review provides some insights into the structure–property–application relationships of CEs and their brief historical developments, offering guidance for optimizing their utilizations especially in sustainable construction practices. Full article
(This article belongs to the Special Issue Bio-Based Polymers for Sustainable Future)
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15 pages, 3478 KiB  
Article
Discrimination of Thermoluminescent Signals from Natural Quartz and Carbonate Crystals Mixture
by Rosaria Galvagno, Giuseppe Stella, Riccardo Reitano and Anna Maria Gueli
Crystals 2025, 15(4), 306; https://doi.org/10.3390/cryst15040306 - 26 Mar 2025
Viewed by 521
Abstract
Luminescence techniques, especially thermoluminescence (TL) and optically stimulated luminescence (OSL), are essential for dating materials in Cultural Heritage. TL is effective for dating bricks by determining their last heating event, but brick reuse can introduce inaccuracies. OSL enhances accuracy by dating the last [...] Read more.
Luminescence techniques, especially thermoluminescence (TL) and optically stimulated luminescence (OSL), are essential for dating materials in Cultural Heritage. TL is effective for dating bricks by determining their last heating event, but brick reuse can introduce inaccuracies. OSL enhances accuracy by dating the last light exposure of quartz grains in mortars, a material that is coeval with the construction of the building. However, partial bleaching of quartz grains can lead to overestimated ages. A promising solution involves dating the carbonate fraction of mortars, as calcium carbonate experiences bleaching during mortar preparation. This study investigates the feasibility of isolating signals from quartz and calcite in a composite material. Initially, TL signals for quartz and calcite were characterized separately. A laboratory mixture, comprising 75% quartz and 25% calcite, was irradiated to simulate partial bleaching. TL curve deconvolution revealed distinct peaks: quartz displayed four peaks, while calcite had three, notably lacking a low-temperature peak. The mixed sample exhibited peaks at 527 K, 573 K, 618 K, and 690 K, with the first peak being exclusively quartz, the second primarily quartz with minor calcite, and the third showing contributions from both. Dose-response curves indicated that the quartz peaks aligned with the expected 41.40 Gy dose, and the calcite signal matched 10.40 Gy. This confirms the feasibility of separating TL signals from quartz and calcite in mixed samples, offering a potential method for accurately dating the carbonate fraction in mortars and addressing partial bleaching issues. Future work will focus on optimizing detection parameters and applying this method to historically significant mortars to assess its effectiveness. Full article
(This article belongs to the Collection Topic Collection: Mineralogical Crystallography)
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