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Keywords = high-pressure processing

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13 pages, 1803 KiB  
Article
Analysis of Weather Conditions and Synoptic Systems During Different Stages of Power Grid Icing in Northeastern Yunnan
by Hongwu Wang, Ruidong Zheng, Gang Luo and Guirong Tan
Atmosphere 2025, 16(7), 884; https://doi.org/10.3390/atmos16070884 - 18 Jul 2025
Abstract
Various data such as power grid sensors and manual observed icing, CMA (China Meteorological Administration) Land Surface Data Assimilation System (CLDAS) products, and the Fifth Generation Atmospheric Reanalysis of the Global Climate from Europe Center of Middle Range Weather Forecast (ERA5) are adopted [...] Read more.
Various data such as power grid sensors and manual observed icing, CMA (China Meteorological Administration) Land Surface Data Assimilation System (CLDAS) products, and the Fifth Generation Atmospheric Reanalysis of the Global Climate from Europe Center of Middle Range Weather Forecast (ERA5) are adopted to diagnose an icing process under a cold surge during 16–23 December 2023 in northeastern Yunnan Province. The results show that: (1) in the early stage of the process, mainly the freezing types, such as GG (temperature > 0 °C, relative humidity ≥ 75%) and DG (temperature < 0 °C, relative humidity ≥ 75%), occur. At the end of the process, an increase in icing type as GD (temperature > 0 °C, relative humidity < 75%) appears. (2) Significant differences exist in the elements during different stages of icing, and the atmospheric thermal, dynamic, and water vapor conditions are conducive to the occurrence of freezing rain during ice accretion. The main impact weather systems of this process include a strong high ridge in the mid to high latitudes of East Asia, transverse troughs in front of the high ridge south to Lake Baikal, low altitude troughs, and ground fronts. The transverse trough in front of the high ridge can cause cold air to accumulate and then move eastward and southward. The southerly flows, surface fronts, and other low-pressure systems can provide powerful thermodynamic and moisture conditions for ice accumulation. Full article
(This article belongs to the Section Meteorology)
26 pages, 11154 KiB  
Article
The Pore Structure and Fractal Characteristics of Upper Paleozoic Coal-Bearing Shale Reservoirs in the Yangquan Block, Qinshui Basin
by Jinqing Zhang, Xianqing Li, Xueqing Zhang, Xiaoyan Zou, Yunfeng Yang and Shujuan Kang
Fractal Fract. 2025, 9(7), 467; https://doi.org/10.3390/fractalfract9070467 - 18 Jul 2025
Abstract
The investigation of the pore structure and fractal characteristics of coal-bearing shale is critical for unraveling reservoir heterogeneity, storage-seepage capacity, and gas occurrence mechanisms. In this study, 12 representative Upper Paleozoic coal-bearing shale samples from the Yangquan Block of the Qinshui Basin were [...] Read more.
The investigation of the pore structure and fractal characteristics of coal-bearing shale is critical for unraveling reservoir heterogeneity, storage-seepage capacity, and gas occurrence mechanisms. In this study, 12 representative Upper Paleozoic coal-bearing shale samples from the Yangquan Block of the Qinshui Basin were systematically analyzed through field emission scanning electron microscopy (FE-SEM), high-pressure mercury intrusion, and gas adsorption experiments to characterize pore structures and calculate multi-scale fractal dimensions (D1D5). Key findings reveal that reservoir pores are predominantly composed of macropores generated by brittle fracturing and interlayer pores within clay minerals, with residual organic pores exhibiting low proportions. Macropores dominate the total pore volume, while mesopores primarily contribute to the specific surface area. Fractal dimension D1 shows a significant positive correlation with clay mineral content, highlighting the role of diagenetic modification in enhancing the complexity of interlayer pores. D2 is strongly correlated with the quartz content, indicating that brittle fracturing serves as a key driver of macropore network complexity. Fractal dimensions D3D5 further unveil the synergistic control of tectonic activity and dissolution on the spatial distribution of pore-fracture systems. Notably, during the overmature stage, the collapse of organic pores suppresses mesopore complexity, whereas inorganic diagenetic processes (e.g., quartz cementation and tectonic fracturing) significantly amplify the heterogeneity of macropores and fractures. These findings provide multi-scale fractal theoretical insights for evaluating coal-bearing shale gas reservoirs and offer actionable recommendations for optimizing the exploration and development of Upper Paleozoic coal-bearing shale gas resources in the Yangquan Block of the Qinshui Basin. Full article
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20 pages, 3162 KiB  
Article
Study on Separation of Desulfurization Wastewater in Ship Exhaust Gas Cleaning System with Rotating Dynamic Filtration
by Shiyong Wang, Juan Wu, Yanlin Wu and Wenbo Dong
Membranes 2025, 15(7), 214; https://doi.org/10.3390/membranes15070214 - 18 Jul 2025
Abstract
Current treatment methods for desulfurization wastewater in the ship exhaust gas cleaning (EGC) system face several problems, including process complexity, unstable performance, large spatial requirements, and high energy consumption. This study investigates rotating dynamic filtration (RDF) as an efficient treatment approach through experimental [...] Read more.
Current treatment methods for desulfurization wastewater in the ship exhaust gas cleaning (EGC) system face several problems, including process complexity, unstable performance, large spatial requirements, and high energy consumption. This study investigates rotating dynamic filtration (RDF) as an efficient treatment approach through experimental testing, theoretical analysis, and pilot-scale validation. Flux increases with temperature and pressure but decreases with feed concentration, remaining unaffected by circulation flow. For a small membrane (152 mm), flux consistently increases with rotational speed across all pressures. For a large membrane (374 mm), flux increases with rotational speed at 300 kPa but firstly increases and then decreases at 100 kPa. Filtrate turbidity in all experiments complies with regulatory standards. Due to the unique hydrodynamic characteristics of RDF, back pressure reduces the effective transmembrane pressure, whereas shear force mitigates concentration polarization and cake layer formation. Separation performance is governed by the balance between these two forces. The specific energy consumption of RDF is only 10–30% that of cross-flow filtration (CFF). Under optimized pilot-scale conditions, the wastewater was concentrated 30-fold, with filtrate turbidity consistently below 2 NTU, outperforming CFF. Moreover, continuous operation proves more suitable for marine environments. Full article
(This article belongs to the Section Membrane Applications for Water Treatment)
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26 pages, 10072 KiB  
Article
Mechanisms of Adhesion Increase in Wet Sanded Wheel–Rail Contacts—A DEM-Based Analysis
by Bettina Suhr, William A. Skipper, Roger Lewis and Klaus Six
Lubricants 2025, 13(7), 314; https://doi.org/10.3390/lubricants13070314 - 18 Jul 2025
Abstract
In railways, problems in braking and traction can be caused by so-called low-adhesion conditions. Adhesion is increased by sanding, where sand grains are blasted towards the wheel–rail contact. Despite the successful use of sanding in practice and extensive experimental studies, the physical mechanisms [...] Read more.
In railways, problems in braking and traction can be caused by so-called low-adhesion conditions. Adhesion is increased by sanding, where sand grains are blasted towards the wheel–rail contact. Despite the successful use of sanding in practice and extensive experimental studies, the physical mechanisms of adhesion increase are poorly understood. This study combines experimental work with a DEM model to aim at a deeper understanding of adhesion increase during sanding. The experimentally observed processes during sanding involve repeated grain breakage, varying sand fragment spread, formation of clusters of crushed sand powders, plastic deformation of the steel surfaces due to the high load applied and shearing of the compressed sand fragments. The developed DEM model includes all these processes. Two types of rail sand are analysed, which differ in adhesion increase in High-Pressure Torsion tests under wet contact conditions. This study shows that higher adhesion is achieved when a larger proportion of the normal load is transferred through sand–steel contacts. This is strongly influenced by the coefficient of friction between sand and steel. Adhesion is higher for larger sand grains, higher sand fragment spread, and higher steel hardness, resulting in less indentation, all leading to larger areas covered by sand. Full article
26 pages, 5344 KiB  
Article
Sliding Mode Repetitive Control Based on the Unknown Dynamics Estimator of a Two-Stage Supply Pressure Hydraulic Hexapod Robot
by Ziqi Liu, Bo Jin, Junkui Dong, Qingyun Yao, Yinglian Jin, Tao Liu and Binrui Wang
Biomimetics 2025, 10(7), 472; https://doi.org/10.3390/biomimetics10070472 - 18 Jul 2025
Abstract
Hydraulic actuated legged robots display bright prospects and significant research value in areas such as unmanned area surveying, disaster rescue, military fields, and other scenarios owing to their excellent bionic characteristics, particularly their heavy payload capabilities and high power density. To realize the [...] Read more.
Hydraulic actuated legged robots display bright prospects and significant research value in areas such as unmanned area surveying, disaster rescue, military fields, and other scenarios owing to their excellent bionic characteristics, particularly their heavy payload capabilities and high power density. To realize the all-terrain adaptation locomotion of the hydraulic hexapod robot (HHR) with a heavy payload, one alternative control framework is position–posture control based on joint position control. As the foundation for the steady locomotion of HHRs, it is imperative to realize high-precision joint position control to improve the robustness under external disturbances during the walking process and to complete the attitude control task. To address the above issues, this paper proposes a sliding mode repetitive control based on the unknown dynamics estimator (SMRC + UDE) for the knee and hip joints of the HHR with a two-stage supply pressure hydraulic system (TSS). The effectiveness of the SMRC + UDE method is verified using a simulation environment and the ZJUHEX01 prototype experimental platform, and it is compared with the results for PID and adaptive robust sliding mode control (ARSMC). The results show that SMRC + UDE may be more suitable for our HHR, considering both the control performance and efficiency factors. Full article
(This article belongs to the Section Locomotion and Bioinspired Robotics)
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17 pages, 2840 KiB  
Article
A Digital Twin System for the Sitting-to-Standing Motion of the Knee Joint
by Tian Liu, Liangzheng Sun, Chaoyue Sun, Zhijie Chen, Jian Li and Peng Su
Electronics 2025, 14(14), 2867; https://doi.org/10.3390/electronics14142867 - 18 Jul 2025
Abstract
(1) Background: A severe decline in knee joint function significantly affects the mobility of the elderly, making it a key concern in the field of geriatric health. To alleviate the pressure on the knee joints of the elderly during daily movements such as [...] Read more.
(1) Background: A severe decline in knee joint function significantly affects the mobility of the elderly, making it a key concern in the field of geriatric health. To alleviate the pressure on the knee joints of the elderly during daily movements such as sitting and standing, effective biomechanical solutions are required. (2) Methods: In this study, a biomechanical framework was established based on mechanical analysis to derive the transfer relationship between the ground reaction force and the knee joint moment. Experiments were designed to collect knee joint data on the elderly during the sit-to-stand process. Meanwhile, magnetic resonance imaging (MRI) images were processed through a medical imaging control system to construct a detailed digital 3D knee joint model. A finite element analysis was used to verify the model to ensure the accuracy of its structure and mechanical properties. An improved radial basis function was used to fit the pressure during the entire sit-to-stand conversion process to reduce the computational workload, with an error of less than 5%. In addition, a small-target human key point recognition network was developed to analyze the image sequences captured by the camera. The knee joint angle and the knee joint pressure distribution during the sit-to-stand conversion process were mapped to a three-dimensional interactive platform to form a digital twin system. (3) Results: The system can effectively capture the biomechanical behavior of the knee joint during movement and shows high accuracy in joint angle tracking and structure simulation. (4) Conclusions: This study provides an accurate and comprehensive method for analyzing the biomechanical characteristics of the knee joint during the movement of the elderly, laying a solid foundation for clinical rehabilitation research and the design of assistive devices in the field of rehabilitation medicine. Full article
(This article belongs to the Section Artificial Intelligence)
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21 pages, 9917 KiB  
Article
Rock Exposure-Driven Ecological Evolution: Multidimensional Spatiotemporal Analysis and Driving Path Quantification in Karst Strategic Areas of Southwest China
by Yue Gong, Shuang Song and Xuanhe Zhang
Land 2025, 14(7), 1487; https://doi.org/10.3390/land14071487 - 18 Jul 2025
Abstract
Southwest China, with typical karst, is one of the 36 biodiversity hotspots in the world, facing extreme ecological fragility due to thin soils, limited water retention, and high bedrock exposure. This fragility intensifies under climate change and human pressures, threatening regional sustainable development. [...] Read more.
Southwest China, with typical karst, is one of the 36 biodiversity hotspots in the world, facing extreme ecological fragility due to thin soils, limited water retention, and high bedrock exposure. This fragility intensifies under climate change and human pressures, threatening regional sustainable development. Ecological strategic areas (ESAs) are critical safeguards for ecosystem resilience, yet their spatiotemporal dynamics and driving mechanisms remain poorly quantified. To address this gap, this study constructed a multidimensional ecological health assessment framework (pattern integrity–process efficiency–function diversity). By integrating Sen’s slope, a correlated Mann–Kendall (CMK) test, the Hurst index, and fuzzy C-means clustering, we systematically evaluated ecological health trends and identified ESA differentiation patterns for 2000–2024. Orthogonal partial least squares structural equation modeling (OPLS-SEM) quantified driving factor intensities and pathways. The results revealed that ecological health improved overall but exhibited significant spatial disparity: persistently high in southern Guangdong and most of Yunnan, and persistently low in the Sichuan Basin and eastern Hubei, with 41.47% of counties showing declining/slightly declining trends. ESAs were concentrated in the southwest/southeast, whereas high-EHI ESAs increased while low-EHI ESAs declined. Additionally, the natural environmental and human interference impacts decreased, while unique geographic factors (notably the rock exposure rate, with persistently significant negative effects) increased. This long-term, multidimensional assessment provides a scientific foundation for targeted conservation and sustainable development strategies in fragile karst ecosystems. Full article
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18 pages, 1642 KiB  
Article
Changes in the Physicochemical Properties of Reduced Salt Pangasius (Pangasianodon hypophthalmus) Gels Induced by High Pressure and Setting Treatment
by Binh Q. Truong, Binh T. T. Vo, Roman Buckow and Van Chuyen Hoang
Sci 2025, 7(3), 99; https://doi.org/10.3390/sci7030099 - 17 Jul 2025
Abstract
Pangasius (Pangasianodon hypophthalmus) minced muscle with 1 and 2% salt was treated with different high-pressure processing and thermal methods, including conventional heat-induced gels (HIGs), high-pressure processing (HPP) prior to cooking (PC), HPP prior to setting (PS), and setting prior to HPP [...] Read more.
Pangasius (Pangasianodon hypophthalmus) minced muscle with 1 and 2% salt was treated with different high-pressure processing and thermal methods, including conventional heat-induced gels (HIGs), high-pressure processing (HPP) prior to cooking (PC), HPP prior to setting (PS), and setting prior to HPP (SP), to evaluate for their effects on the selected physicochemical properties. The results showed that the PC treatment produced gels with a significantly higher gel strength (496.72–501.26 N·mm), hardness (9.62–10.14 N), and water-holding capacity (87.79–89.74%) compared to the HIG treatment, which showed a gel strength of 391.24 N·mm, a hardness of 7.36 N, and a water-holding capacity of 77.98%. PC gels also exhibited the typical microstructure of pressure-induced gels, with a denser and homogeneous microstructure compared to the rough and loosely connected structure of HIGs. In contrast, SP treatment exhibited the poorest gel quality in all parameters, with gel strength ranging from 319.79 to 338.34 N·mm, hardness from 5.87 to 6.31 N, and WHC from 71.91 to 73.72%. Meanwhile, the PS treatment showed a comparable gel quality to HIGs. SDS-PAGE analysis revealed protein degradation and aggregation in HPP-treated samples, with a decrease in the intensity of myosin heavy chains and actin bands. Fourier-transform infrared spectroscopy (FTIR) analysis showed minor shifts in protein secondary structures, with the PC treatment showing a significant increase in α-helices (28.09 ± 0.51%) and a decrease in random coil content (6.69 ± 0.92%) compared to α-helices (23.61 ± 0.83) and random coil structures (9.47 ± 1.48) in HIGs (p < 0.05). Only the PC treatment resulted in a significant reduction in total plate count (TPC) (1.51–1.58 log CFU/g) compared to 2.33 ± 0.33 log CFU/g in the HIG treatment. These findings suggest that HPP should be applied prior to thermal treatments (cooking or setting) to achieve an improved gel quality in reduced-salt pangasius products. Full article
(This article belongs to the Section Biology Research and Life Sciences)
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12 pages, 1804 KiB  
Article
Evaluation Method of Gas Production in Shale Gas Reservoirs in Jiaoshiban Block, Fuling Gas Field
by Haitao Rao, Wenrui Shi and Shuoliang Wang
Energies 2025, 18(14), 3817; https://doi.org/10.3390/en18143817 - 17 Jul 2025
Abstract
The gas-production potential of shale gas is a comprehensive evaluation metric that assesses the reservoir quality, gas-content properties, and gas-production capacity. Currently, the evaluation of gas-production potential is generally conducted through qualitative comparisons of relevant parameters, which can lead to multiple solutions and [...] Read more.
The gas-production potential of shale gas is a comprehensive evaluation metric that assesses the reservoir quality, gas-content properties, and gas-production capacity. Currently, the evaluation of gas-production potential is generally conducted through qualitative comparisons of relevant parameters, which can lead to multiple solutions and make it difficult to establish a comprehensive evaluation index. This paper introduces a gas-production potential evaluation method based on the Analytic Hierarchy Process (AHP). It uses judgment matrices to analyze key parameters such as gas content, brittleness index, total organic carbon content, the length of high-quality gas-layer horizontal sections, porosity, gas saturation, formation pressure, and formation density. By integrating fuzzy mathematics, a mathematical model for gas-production potential is established, and corresponding gas-production levels are defined. The model categorizes gas-production potential into four levels: when the gas-production index exceeds 0.65, it is classified as a super-high-production well; when the gas-production index is between 0.45 and 0.65, it is classified as a high-production well; when the gas-production index is between 0.35 and 0.45, it is classified as a medium-production well; and when the gas-production index is below 0.35, it is classified as a low-production well. Field applications have shown that this model can accurately predict the gas-production potential of shale gas wells, showing a strong correlation with the unobstructed flow rate of gas wells, and demonstrating broad applicability. Full article
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21 pages, 3490 KiB  
Article
Energy-Efficient CO2 Conversion for Carbon Utilization Using a Gliding Arc/Glow Discharge with Magnetic Field Acceleration—Optimization and Characterization
by Svetlana Lazarova, Snejana Iordanova, Stanimir Kolev, Veselin Vasilev and Tsvetelina Paunska
Energies 2025, 18(14), 3816; https://doi.org/10.3390/en18143816 - 17 Jul 2025
Abstract
The dry conversion of CO2 into CO and O2 provides an attractive path for CO2 utilization which allows for the use of the CO produced for the synthesis of valuable hydrocarbons. In the following work, the CO2 conversion is [...] Read more.
The dry conversion of CO2 into CO and O2 provides an attractive path for CO2 utilization which allows for the use of the CO produced for the synthesis of valuable hydrocarbons. In the following work, the CO2 conversion is driven by an arc discharge at atmospheric pressure, producing hot plasma. This study presents a series of experiments aiming to optimize the process. The results obtained include the energy efficiency and the conversion rate of the process, as well as the electrical parameters of the discharge (current and voltage signals). In addition, optical emission spectroscopy diagnostics based on an analysis of C2’s Swan bands are used to determine the gas temperature in the discharge. The data is analyzed according to several aspects—an analysis of the arc’s motion based on the electrical signals; an analysis of the effect of the gas flow and the discharge current on the discharge performance for CO2 conversion; and an analysis of the vibrational and rotational temperatures of the arc channel. The results show significant improvements over previous studies. Relatively high gas conversion and energy efficiency are achieved due to the arc acceleration caused by the Lorentz force. The rotational (gas) temperatures are in the order of 5500–6000 K. Full article
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19 pages, 923 KiB  
Article
Optimizing Bioactive Compound Recovery from Chestnut Shells Using Pressurized Liquid Extraction and the Box–Behnken Design
by Magdalini Pazara, Georgia Provelengiadi, Martha Mantiniotou, Vassilis Athanasiadis, Iordanis Samanidis, Ioannis Makrygiannis, Ilias F. Tzavellas, Ioannis C. Martakos, Nikolaos S. Thomaidis and Stavros I. Lalas
Processes 2025, 13(7), 2283; https://doi.org/10.3390/pr13072283 - 17 Jul 2025
Abstract
Chestnut (Castanea sativa Mill.) is an edible nut recognized for its nutritional attributes, particularly its elevated levels of carbohydrates (starch) and proteins. Chestnuts are popular for their health-promoting properties and hold significant environmental and economic importance in Europe. During this study, after [...] Read more.
Chestnut (Castanea sativa Mill.) is an edible nut recognized for its nutritional attributes, particularly its elevated levels of carbohydrates (starch) and proteins. Chestnuts are popular for their health-promoting properties and hold significant environmental and economic importance in Europe. During this study, after the characterization of the fruit, attention was directed toward the valorization of chestnut shells, a predominant by-product of industrial chestnut processing that is typically discarded. Valuable bioactive compounds were extracted from the shells using Pressurized Liquid Extraction (PLE), a green, efficient, scalable method. Response surface methodology (RSM) was utilized to determine optimal extraction conditions, identified as 40% v/v ethanol as the solvent at a temperature of 160 °C for 25 min under a constant pressure of 1700 psi. High total polyphenol content (113.68 ± 7.84 mg GAE/g dry weight) and notable antioxidant activity—determined by FRAP (1320.28 ± 34.33 μmol AAE/g dw) and DPPH (708.65 ± 24.8 μmol AAE/g dw) assays—were recorded in the optimized extracts. Ultrahigh-performance liquid chromatography coupled with a hybrid trap ion mobility-quadrupole time-of-flight mass spectrometer (UHPLC-TIMS-QTOF-MS) was applied to further characterize the compound profile, enabling the identification of phenolic and antioxidant compounds. These findings highlight the possibility of using chestnut shell residues as a long-term resource to make valuable products for the food, medicine, cosmetics, and animal feed industries. This study contributes to the advancement of waste valorization strategies and circular bioeconomy approaches. Full article
(This article belongs to the Special Issue Research of Bioactive Synthetic and Natural Products Chemistry)
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32 pages, 5641 KiB  
Review
Review of the Research on Underwater Explosion Ice-Breaking Technology
by Xiao Huang, Zi-Xian Zhong, Xiao Luo and Yuan-Dong Wang
J. Mar. Sci. Eng. 2025, 13(7), 1359; https://doi.org/10.3390/jmse13071359 - 17 Jul 2025
Abstract
Underwater explosion ice-breaking technology is critical for Arctic development and ice disaster prevention due to its high efficiency, yet it faces challenges in understanding the coupled dynamics of shock waves, pulsating bubbles, and heterogeneous ice fracture. This review synthesizes theoretical models, experimental studies, [...] Read more.
Underwater explosion ice-breaking technology is critical for Arctic development and ice disaster prevention due to its high efficiency, yet it faces challenges in understanding the coupled dynamics of shock waves, pulsating bubbles, and heterogeneous ice fracture. This review synthesizes theoretical models, experimental studies, and numerical simulations investigating damage mechanisms. Key findings establish that shock waves initiate brittle fracture via stress superposition while bubble pulsation drives crack propagation through pressure oscillation; optimal ice fragmentation depends critically on charge weight, standoff distance, and ice thickness. However, significant limitations persist in modeling sea ice heterogeneity, experimental replication of polar conditions, and computational efficiency. Future advancements require multiscale fluid–structure interaction models integrating brine migration effects, enhanced experimental diagnostics for transient processes, and optimized numerical algorithms to enable reliable predictions for engineering applications. Full article
(This article belongs to the Section Ocean Engineering)
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27 pages, 7109 KiB  
Article
The Long-Term Surface Deformation Monitoring and Prediction of Hutubi Gas Storage Reservoir in Xinjiang Based on InSAR and the GWO-VMD-GRU Model
by Wang Huang, Wei Liao, Jie Li, Xuejun Qiao, Sulitan Yusan, Abudutayier Yasen, Xinlu Li and Shijie Zhang
Remote Sens. 2025, 17(14), 2480; https://doi.org/10.3390/rs17142480 - 17 Jul 2025
Abstract
Natural gas storage is an effective solution to address the energy supply–demand imbalance, and underground gas storage (UGS) is a primary method for storing natural gas. The overarching goal of this study is to monitor and analyze surface deformation at the Hutubi underground [...] Read more.
Natural gas storage is an effective solution to address the energy supply–demand imbalance, and underground gas storage (UGS) is a primary method for storing natural gas. The overarching goal of this study is to monitor and analyze surface deformation at the Hutubi underground gas storage facility in Xinjiang, China, which is the largest gas storage facility in the country. This research aims to ensure the stable and efficient operation of the facility through long-term monitoring, using remote sensing data and advanced modeling techniques. The study employs the SBAS-InSAR method, leveraging Synthetic Aperture Radar (SAR) data from the TerraSAR and Sentinel-1 sensors to observe displacement time series from 2013 to 2024. The data is processed through wavelet transformation for denoising, followed by the application of a Gray Wolf Optimization (GWO) algorithm combined with Variational Mode Decomposition (VMD) to decompose both surface deformation and gas pressure data. The key focus is the development of a high-precision predictive model using a Gated Recurrent Unit (GRU) network, referred to as GWO-VMD-GRU, to accurately predict surface deformation. The results show periodic surface uplift and subsidence at the facility, with a notable net uplift. During the period from August 2013 to March 2015, the maximum uplift rate was 6 mm/year, while from January 2015 to December 2024, it increased to 12 mm/year. The surface deformation correlates with gas injection and extraction periods, indicating periodic variations. The accuracy of the InSAR-derived displacement data is validated through high-precision GNSS data. The GWO-VMD-GRU model demonstrates strong predictive performance with a coefficient of determination (R2) greater than 0.98 for the gas well test points. This study provides a valuable reference for the future safe operation and management of underground gas storage facilities, demonstrating significant contributions to both scientific understanding and practical applications in underground gas storage management. Full article
(This article belongs to the Special Issue Advances in Remote Sensing for Land Subsidence Monitoring)
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17 pages, 7633 KiB  
Article
Mechanical Behavior Characteristics of Sandstone and Constitutive Models of Energy Damage Under Different Strain Rates
by Wuyan Xu and Cun Zhang
Appl. Sci. 2025, 15(14), 7954; https://doi.org/10.3390/app15147954 - 17 Jul 2025
Abstract
To explore the influence of mine roof on the damage and failure of sandstone surrounding rock under different pressure rates, mechanical experiments with different strain rates were carried out on sandstone rock samples. The strength, deformation, failure, energy and damage characteristics of rock [...] Read more.
To explore the influence of mine roof on the damage and failure of sandstone surrounding rock under different pressure rates, mechanical experiments with different strain rates were carried out on sandstone rock samples. The strength, deformation, failure, energy and damage characteristics of rock samples with different strain rates were also discussed. The research results show that with the increases in the strain rate, peak stress, and elastic modulus show a monotonically increasing trend, while the peak strain decreases in the reverse direction. At a low strain rate, the proportion of the mass fraction of complete rock blocks in the rock sample is relatively high, and the shape integrity is good, while rock samples with a high strain rate retain more small-sized fragmented rock blocks. This indicates that under high-rate loading, the bifurcation phenomenon of secondary cracks is obvious. The rock samples undergo a failure form dominated by small-sized fragments, with severe damage to the rock samples and significant fractal characteristics of the fragments. At the initial stage of loading, the primary fractures close, and the rock samples mainly dissipate energy in the forms of frictional slip and mineral fragmentation. In the middle stage of loading, the residual fractures are compacted, and the dissipative strain energy keeps increasing continuously. In the later stage of loading, secondary cracks accelerate their expansion, and elastic strain energy is released sharply, eventually leading to brittle failure of the rock sample. Under a low strain rate, secondary cracks slowly expand along the clay–quartz interface and cause intergranular failure of the rock sample. However, a high strain rate inhibits the stress relaxation of the clay, forces the energy to transfer to the quartz crystal, promotes the penetration of secondary cracks through the quartz crystal, and triggers transgranular failure. A constitutive model based on energy damage was further constructed, which can accurately characterize the nonlinear hardening characteristics and strength-deformation laws of rock samples with different strain rates. The evolution process of its energy damage can be divided into the unchanged stage, the slow growth stage, and the accelerated growth stage. The characteristics of this stage reveal the sudden change mechanism from the dissipation of elastic strain energy of rock samples to the unstable propagation of secondary cracks, clarify the cumulative influence of strain rate on damage, and provide a theoretical basis for the dynamic assessment of surrounding rock damage and disaster early warning when the mine roof comes under pressure. Full article
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13 pages, 6157 KiB  
Article
Mechanistic Study of Oil Adsorption Behavior and CO2 Displacement Mechanism Under Different pH Conditions
by Xinwang Song, Yang Guo, Yanchang Chen and Shiling Yuan
Molecules 2025, 30(14), 2999; https://doi.org/10.3390/molecules30142999 - 17 Jul 2025
Abstract
Enhanced oil recovery (EOR) via CO2 flooding is a promising strategy for improving hydrocarbon recovery and carbon sequestration, yet the influence of pH on solid–liquid interfacial interactions in quartz-dominated reservoirs remains poorly understood. This study employs molecular dynamics (MD) simulations to investigate [...] Read more.
Enhanced oil recovery (EOR) via CO2 flooding is a promising strategy for improving hydrocarbon recovery and carbon sequestration, yet the influence of pH on solid–liquid interfacial interactions in quartz-dominated reservoirs remains poorly understood. This study employs molecular dynamics (MD) simulations to investigate the pH-dependent adsorption behavior of crude oil components on quartz surfaces and its impact on CO2 displacement mechanisms. Three quartz surface models with varying ionization degrees (0%, 9%, 18%, corresponding to pH 2–4, 5–7, and 7–9) were constructed to simulate different pH environments. The MD results reveal that aromatic hydrocarbons exhibit significantly stronger adsorption on quartz surfaces at high pH, with their maximum adsorption peak increasing from 398 kg/m3 (pH 2–4) to 778 kg/m3 (pH 7–9), while their alkane adsorption peaks decrease from 764 kg/m3 to 460 kg/m3. This pH-dependent behavior is attributed to enhanced cation–π interactions that are facilitated by Na+ ion aggregation on negatively charged quartz surfaces at high pH, which form stable tetrahedral configurations with aromatic molecules and surface oxygen ions. During CO2 displacement, an adsorption–stripping–displacement mechanism was observed: CO2 first forms an adsorption layer on the quartz surface, then penetrates the oil phase to induce the detachment of crude oil components, which are subsequently displaced by pressure. Although high pH enhances the Na+-mediated weakening of oil-surface interactions, which leads to a 37% higher diffusion coefficient (8.5 × 10−5 cm2/s vs. 6.2 × 10−5 cm2/s at low pH), the tighter packing of aromatic molecules at high pH slows down the displacement rate. This study provides molecular-level insights into pH-regulated adsorption and CO2 displacement processes, highlighting the critical role of the surface charge and cation–π interactions in optimizing CO2-EOR strategies for quartz-rich reservoirs. Full article
(This article belongs to the Special Issue Advances in Molecular Modeling in Chemistry, 2nd Edition)
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