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Search Results (2,138)

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Keywords = high-energy laser

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36 pages, 8958 KiB  
Article
Dynamic Resource Target Assignment Problem for Laser Systems’ Defense Against Malicious UAV Swarms Based on MADDPG-IA
by Wei Liu, Lin Zhang, Wenfeng Wang, Haobai Fang, Jingyi Zhang and Bo Zhang
Aerospace 2025, 12(8), 729; https://doi.org/10.3390/aerospace12080729 (registering DOI) - 17 Aug 2025
Abstract
The widespread adoption of Unmanned Aerial Vehicles (UAVs) in civilian domains, such as airport security and critical infrastructure protection, has introduced significant safety risks that necessitate effective countermeasures. High-Energy Laser Systems (HELSs) offer a promising defensive solution; however, when confronting large-scale malicious UAV [...] Read more.
The widespread adoption of Unmanned Aerial Vehicles (UAVs) in civilian domains, such as airport security and critical infrastructure protection, has introduced significant safety risks that necessitate effective countermeasures. High-Energy Laser Systems (HELSs) offer a promising defensive solution; however, when confronting large-scale malicious UAV swarms, the Dynamic Resource Target Assignment (DRTA) problem becomes critical. To address the challenges of complex combinatorial optimization problems, a method combining precise physical models with multi-agent reinforcement learning (MARL) is proposed. Firstly, an environment-dependent HELS damage model was developed. This model integrates atmospheric transmission effects and thermal effects to precisely quantify the required irradiation time to achieve the desired damage effect on a target. This forms the foundation of the HELS–UAV–DRTA model, which employs a two-stage dynamic assignment structure designed to maximize the target priority and defense benefit. An innovative MADDPG-IA (I: intrinsic reward, and A: attention mechanism) algorithm is proposed to meet the MARL challenges in the HELS–UAV–DRTA problem: an attention mechanism compresses variable-length target states into fixed-size encodings, while a Random Network Distillation (RND)-based intrinsic reward module delivers dense rewards that alleviate the extreme reward sparsity. Large-scale scenario simulations (100 independent runs per scenario) involving 50 UAVs and 5 HELS across diverse environments demonstrate the method’s superiority, achieving mean damage rates of 99.65% ± 0.32% vs. 72.64% ± 3.21% (rural), 79.37% ± 2.15% vs. 51.29% ± 4.87% (desert), and 91.25% ± 1.78% vs. 67.38% ± 3.95% (coastal). The method autonomously evolved effective strategies such as delaying decision-making to await the optimal timing and cross-region coordination. The ablation and comparison experiments further confirm MADDPG-IA’s superior convergence, stability, and exploration capabilities. This work bridges the gap between complex mathematical and physical mechanisms and real-time collaborative decision optimization. It provides an innovative theoretical and methodological basis for public-security applications. Full article
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28 pages, 4811 KiB  
Article
Millisecond Laser Oblique Hole Processing of Alumina Ceramics
by Yuyang Chen, Xianshi Jia, Zhou Li, Chuan Guo, Ranfei Guo, Kai Li, Cong Wang, Wenda Cui, Changqing Song, Kai Han and Ji’an Duan
Nanomaterials 2025, 15(16), 1261; https://doi.org/10.3390/nano15161261 - 15 Aug 2025
Abstract
Alumina ceramic substrates are ideal materials for next-generation microelectronic systems and devices, widely used in aerospace, 5G communications, and LED lighting. High-quality hole processing is essential for system interconnection and device packaging. Millisecond lasers have emerged as a promising choice for hole processing [...] Read more.
Alumina ceramic substrates are ideal materials for next-generation microelectronic systems and devices, widely used in aerospace, 5G communications, and LED lighting. High-quality hole processing is essential for system interconnection and device packaging. Millisecond lasers have emerged as a promising choice for hole processing in alumina ceramic due to their high processing efficiency. However, existing research has rarely explored the mechanisms and processing techniques of millisecond laser oblique hole formation. This study systematically investigates the dynamic evolution of oblique hole processing in alumina ceramic through theoretical simulations, online detection, and process experiments. Through the simulation model, we have established the relationship between material temperature and hole depth. By analyzing the ablation phenomena on the upper and lower surfaces of the ceramic during the transient interaction process between the millisecond laser and the ceramic, the material removal mechanism in this process is elucidated. Additionally, this study examines the millisecond laser oblique hole processing technology by analyzing the influence of various laser parameters on hole formation. It reveals that appropriately increasing the single-pulse energy of millisecond lasers can optimize the material removal rate and hole taper. Ultimately, the formation mechanism of millisecond laser oblique hole processing in alumina ceramics is comprehensively summarized. The results provide theoretical and methodological guidance for high-speed laser drilling of alumina ceramic substrates. Full article
23 pages, 7663 KiB  
Review
Advances in 3D Printing: Microfabrication Techniques and Forming Applications
by Di Pan, Fanghui Jia, Muyuan Zhou, Hao Liu, Jingru Yan, Lisong Zhu, Ming Yang and Zhengyi Jiang
Micromachines 2025, 16(8), 940; https://doi.org/10.3390/mi16080940 - 15 Aug 2025
Abstract
Stainless steel is essential in high-performance industries due to its strength, corrosion resistance, and biocompatibility. However, conventional manufacturing methods limit material efficiency, design complexity, and customization. Additive manufacturing (AM) has emerged as a powerful alternative, enabling the production of stainless-steel components with complex [...] Read more.
Stainless steel is essential in high-performance industries due to its strength, corrosion resistance, and biocompatibility. However, conventional manufacturing methods limit material efficiency, design complexity, and customization. Additive manufacturing (AM) has emerged as a powerful alternative, enabling the production of stainless-steel components with complex geometries, tailored microstructures, and integrated functionalities. Key AM methodologies, including laser powder bed fusion (L-PBF), binder jetting, and directed energy deposition (DED), are evaluated for their effectiveness in producing stainless-steel components with optimal performance characteristics. This review highlights innovations in stainless-steel AM, focusing on microfabrication, multi-material approaches, and post-processing strategies such as heat treatment, hot isostatic pressing (HIP), and surface finishing. It also examines the impact of process parameters on microstructure, mechanical anisotropy, and defects. Emerging trends include AM-specific alloy design, functionally graded structures, and AI-based control. Applications span biomedical implants, micro-tooling, energy systems, and automotive parts, with emphasis on microfabrication for biomedical micromachines and precision microforming. Full article
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16 pages, 4050 KiB  
Article
Evaluation Method for Flame-Retardant Property of Sheet Molding Compound Materials Based on Laser-Induced Breakdown Spectroscopy
by Qishuai Liang, Zhongchen Xia, Jiang Ye, Chuan Zhou, Yufeng Wu, Jie Li, Xuhui Cui, Honglin Jian and Xilin Wang
Energies 2025, 18(16), 4353; https://doi.org/10.3390/en18164353 - 15 Aug 2025
Viewed by 55
Abstract
The electric energy metering box serves as a crucial node in power grid operations, offering essential protection for key components in the distribution network, such as smart meters, data acquisition terminals, and circuit breakers, thereby ensuring their safe and reliable operation. However, the [...] Read more.
The electric energy metering box serves as a crucial node in power grid operations, offering essential protection for key components in the distribution network, such as smart meters, data acquisition terminals, and circuit breakers, thereby ensuring their safe and reliable operation. However, the non-metallic housings of these boxes are susceptible to aging under environmental stress, which can result in diminished flame-retardant properties and an increased risk of fire. Currently, there is a lack of rapid and accurate methods for assessing the fire resistance of non-metallic metering box enclosures. In this study, laser-induced breakdown spectroscopy (LIBS), which enables fast, multi-element, and non-contact analysis, was utilized to develop an effective assessment approach. Thermal aging experiments were conducted to systematically investigate the degradation patterns and mechanisms underlying the reduced flame-retardant performance of sheet molding compound (SMC), a representative non-metallic material used in metering box enclosures. The results showed that the intensity ratio of aluminum ionic spectral lines is highly correlated with the flame-retardant grade, serving as an effective performance indicator. On this basis, a one-dimensional convolutional neural network (1D-CNN) model was developed utilizing LIBS data, which achieved over 92% prediction accuracy for different flame-retardant grades on the test set and demonstrated high recognition accuracy for previously unseen samples. This method offers significant potential for rapid, on-site evaluation of flame-retardant grades of non-metallic electric energy metering boxes, thereby supporting the safe and reliable operation of power systems. Full article
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20 pages, 10593 KiB  
Article
Optimising WC-25Co Feedstock and Parameters for Laser-Directed Energy Deposition
by Helder Nunes, José Nhanga, Luís Regueiras, Ana Reis, Manuel F. Vieira, Bruno Guimarães, Daniel Figueiredo, Cristina Fernandes and Omid Emadinia
J. Manuf. Mater. Process. 2025, 9(8), 279; https://doi.org/10.3390/jmmp9080279 - 14 Aug 2025
Viewed by 97
Abstract
Laser-Directed Energy Deposition (L-DED) is an additive manufacturing technique used for producing and repairing components, mainly for coating applications, depositing metal matrix composites such as cemented carbides, composed of hard metal carbides and a metallic binder. In this sense, this study evaluated the [...] Read more.
Laser-Directed Energy Deposition (L-DED) is an additive manufacturing technique used for producing and repairing components, mainly for coating applications, depositing metal matrix composites such as cemented carbides, composed of hard metal carbides and a metallic binder. In this sense, this study evaluated the preparation of a ready-to-press WC-25Co powder as a reliable feedstock for L-DED process. This powder required pre-heat treatment studies to prevent fragmentation during powder feeding, due to the absence of metallurgical bonding between WC and Co particles. In the current study, the Taguchi methodology was used, varying laser power, powder feed rate, and scanning speed to reach an optimised deposition window. The best bead morphology resulted from 2400 W laser power, 11 mm/s scanning speed, and 9 g/min feed rate. Moreover, defects such as porosity and cracking were mitigated by applying a remelting strategy of 2400 W and 9 mm/s. Therefore, a perfect deposition is obtained using the optimised processing parameters. Microstructural analysis of the optimised deposited line revealed a fine structure, comprising columnar and equiaxed dendrites of complex carbides. The average hardness of the deposited WC-25Co powder on a AISI 1045 steel was 854 ± 37 HV0.2. These results demonstrate the potential of L-DED for processing high-performance cemented carbide coatings. Full article
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15 pages, 12102 KiB  
Article
Multi-Model Collaborative Optimization of Inconel 690 Deposited Geometry in Laser-Directed Energy Deposition: Machine Learning Prediction and NSGA-II Decision Framework
by Chen Liu, Junxiao Liu, Xiuyuan Yin, Xiaoyu Zhang, Shuo Shang and Changsheng Liu
Metals 2025, 15(8), 905; https://doi.org/10.3390/met15080905 - 14 Aug 2025
Viewed by 68
Abstract
The critical challenge of achieving precise geometric control in laser directed energy deposition (L-DED) of Inconel 690 for nuclear applications is addressed by this study. We established a data-driven optimization framework that reduces time-consuming trial-and-error experiments. A comprehensive process-geometry dataset was generated through [...] Read more.
The critical challenge of achieving precise geometric control in laser directed energy deposition (L-DED) of Inconel 690 for nuclear applications is addressed by this study. We established a data-driven optimization framework that reduces time-consuming trial-and-error experiments. A comprehensive process-geometry dataset was generated through full-factor experiments. Pearson correlation analysis revealed significant correlations: strong positive correlations between laser power and bead width (r = 0.82) and depth (r = 0.85), and between powder feed rate and height (r = 0.70). A hybrid machine learning model was subsequently developed. It used a Backpropagation Neural Network (BPNN) to achieve excellent prediction of width, height, and depth (R2 ≤ 0.962). It also generated 100 uniformly distributed Pareto optimal process parameter sets via the Non-dominated Sorting Genetic Algorithm II (NSGA-II). Experimental validation confirmed the model’s high predictive accuracy—relative error ≤ 5% for width/depth, and a maximum relative error of 5.34% for height. This demonstrates the framework’s effectiveness for reliable multi-objective process optimization in high-precision deposition tasks. It also highlights its potential for use in nuclear component repair and other material systems. Full article
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11 pages, 1072 KiB  
Article
Design and Characteristic Simulation of Polarization-Maintaining Anti-Resonant Hollow-Core Fiber for 2.79 μm Er, Cr: YSGG Laser Transmission
by Lei Huang and Yinze Wang
Optics 2025, 6(3), 37; https://doi.org/10.3390/opt6030037 - 14 Aug 2025
Viewed by 64
Abstract
Anti-resonant hollow-core fibers have exhibited excellent performance in applications such as high-power pulse transmission, network communication, space exploration, and precise sensing. Employing anti-resonant hollow-core fibers instead of light guiding arms for transmitting laser energy at the 2.79 μm band can significantly enhance the [...] Read more.
Anti-resonant hollow-core fibers have exhibited excellent performance in applications such as high-power pulse transmission, network communication, space exploration, and precise sensing. Employing anti-resonant hollow-core fibers instead of light guiding arms for transmitting laser energy at the 2.79 μm band can significantly enhance the flexibility of medical laser handles, reduce system complexity, and increase laser transmission efficiency. Nevertheless, common anti-resonant hollow-core fibers do not have the ability to maintain the polarization state of light during laser transmission, which greatly affects their practical applications. In this paper, we propose a polarization-maintaining anti-resonant hollow-core fiber applicable for transmission at the mid-infrared 2.79 μm band. This fiber features a symmetrical geometric structure and an asymmetric refractive index cladding composed of quartz and a type of mid-infrared glass with a higher refractive index. Through optimizing the fiber structure at the wavelength scale, single-polarization transmission can be achieved at the 2.79 μm wavelength, with a polarization extinction ratio exceeding 1.01 × 105, indicating its stable polarization-maintaining performance. Simultaneously, it possesses low-loss transmission characteristics, with the loss in the x-polarized fundamental mode being less than 9.8 × 10−3 dB/m at the 2.79 µm wavelength. This polarization-maintaining anti-resonant hollow-core fiber provides a more reliable option for the light guiding system of the 2.79 μm Er; Cr: YSGG laser therapy device. Full article
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17 pages, 3151 KiB  
Article
Research on the Application of Laser Ablation in the Rapid Detection of Ablation Resistance on the Surface of AgNi Contact Materials
by Yun Wang, Lintao Liu, Wenhua Li, Mingyu Lu, Bokai Jin, Yuxuan Ji, Rui Ma, Shuhua Miao, Xuanwei Zhang and Tianai Luo
Appl. Sci. 2025, 15(16), 8961; https://doi.org/10.3390/app15168961 - 14 Aug 2025
Viewed by 89
Abstract
The ablation resistance of electrical contact materials is a key factor in ensuring the long-term stable operation of electrical equipment. However, conventional electrical contact tests often suffer from long testing cycles, high resource consumption, and poor repeatability, which severely limits the efficient screening [...] Read more.
The ablation resistance of electrical contact materials is a key factor in ensuring the long-term stable operation of electrical equipment. However, conventional electrical contact tests often suffer from long testing cycles, high resource consumption, and poor repeatability, which severely limits the efficient screening and engineering application of new materials. In this study, the thermal erosion behavior of AgNi-series silver-based contact materials under various laser energy inputs was systematically investigated using laser ablation technology. An integrated laser testing platform was employed to extract multiple parameters, including longitudinal ablation depth, linear ablation rate, depth-to-diameter ratio, and ablation area growth rate, enabling quantitative analysis of thermal response characteristics and performance comparison among materials. Furthermore, fractal dimension analysis was introduced to characterize the evolution of surface morphological complexity after ablation, and Pearson correlation analysis was performed to compare the results with those from conventional electrical contact tests. The results showed high consistency in ablation resistance ranking and surface response trends between the two methods, with correlation coefficients for all three materials exceeding 0.78, and AgNi10 exhibiting the best ablation resistance. This study demonstrates that laser ablation technology can significantly shorten testing cycles and improve repeatability while ensuring result reliability, providing an efficient and feasible approach for high-throughput screening and industrial application of electrical contact materials. Full article
(This article belongs to the Section Electrical, Electronics and Communications Engineering)
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10 pages, 2113 KiB  
Article
Generation of 27 nm Spectral Bandwidth, Two-Port Output Pulses Directly from a Yb-Doped Fiber Laser
by Junyu Chen, Mengyun Hu, Jianing Chen, Chixuan Zou, Zichen Zhao, Gantong Zhong and Shuai Yuan
Photonics 2025, 12(8), 812; https://doi.org/10.3390/photonics12080812 - 14 Aug 2025
Viewed by 166
Abstract
We reported on a generation of 27 nm spectral bandwidth, two-port output ultrashort pulses directly from an all-normal-dispersion passively mode-locked Yb-fiber laser. Based on the nonlinear polarization rotation (NPR) mode-locking technique, high pump power and optical devices with high damage thresholds were introduced [...] Read more.
We reported on a generation of 27 nm spectral bandwidth, two-port output ultrashort pulses directly from an all-normal-dispersion passively mode-locked Yb-fiber laser. Based on the nonlinear polarization rotation (NPR) mode-locking technique, high pump power and optical devices with high damage thresholds were introduced to achieve broad spectral bandwidth and strong output power. The dual wavelengths were emitted from the clockwise and counterclockwise ports, respectively, and self-started mode-locking was achieved. The bidirectional output laser generates stable pulses with up to 223.5 mW average power at a 46.04 MHz repetition rate, corresponding to a pulse energy of 5 nJ. The bidirectional ultrashort outputs of the laser provide potential applications in supercontinuum generation and medical and biological applications. Full article
(This article belongs to the Special Issue Advances in Ultrafast Laser Science and Applications)
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14 pages, 3262 KiB  
Article
Integrated LCOS-SLM-Based Laser Slicing System for Aberration Correction in Silicon Carbide Substrate Manufacturing
by Heng Wang, Qiang Cao, Yuting Hou, Lulu Yu, Tianhao Wu, Zhenzhong Wang and Du Wang
Micromachines 2025, 16(8), 930; https://doi.org/10.3390/mi16080930 - 13 Aug 2025
Viewed by 192
Abstract
Silicon carbide (SiC), a wide-bandgap semiconductor, is renowned for its exceptional performance in power electronics and extreme-temperature environments. However, precision low-loss laser slicing of SiC is impeded by energy divergence and crack delamination induced by refractive-index-mismatch interfacial aberrations. This study presents an integrated [...] Read more.
Silicon carbide (SiC), a wide-bandgap semiconductor, is renowned for its exceptional performance in power electronics and extreme-temperature environments. However, precision low-loss laser slicing of SiC is impeded by energy divergence and crack delamination induced by refractive-index-mismatch interfacial aberrations. This study presents an integrated laser slicing system based on a liquid crystal on silicon spatial light modulator (LCOS-SLM) to address aberration-induced focal elongation and energy inhomogeneity. Through dynamic modulation of the laser wavefront via an inverse ray-tracing algorithm, the system corrects spherical aberrations from refractive index mismatch, thus achieving precise energy concentration at wanted depths. A laser power attenuation model based on interface reflection and the Lambert–Beer law is established to calculate the required laser power at varying processing depths. Experimental results demonstrate that aberration correction reduces focal depth to approximately one-third (from 45 μm to 15 μm) and enhances energy concentration, eliminating multi-layer damage and increasing crack propagation length. Post-correction critical power measurements across depths are consistent with model predictions, with maximum error decreasing from >50% to 8.4%. Verification on a 6-inch N-type SiC ingot shows 90 μm damage thickness, confirming system feasibility for SiC laser slicing. The integrated aberration-correction approach provides a novel solution for high-precision SiC substrate processing. Full article
(This article belongs to the Section D:Materials and Processing)
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23 pages, 9592 KiB  
Article
Study on Laser Drilling of Micro-Holes Using a Breakthrough Detection Method
by Liang Wang, Yefei Rong, Long Xu, Changjian Wu and Kaibo Xia
Materials 2025, 18(16), 3764; https://doi.org/10.3390/ma18163764 - 11 Aug 2025
Viewed by 262
Abstract
Achieving high efficiency and quality in millisecond pulsed laser drilling of metallic through-holes is contingent on precise process control. This study introduces a penetration detection-based method to determine the pulse count threshold, effectively overcoming the limitations of conventional approaches. We systematically investigated the [...] Read more.
Achieving high efficiency and quality in millisecond pulsed laser drilling of metallic through-holes is contingent on precise process control. This study introduces a penetration detection-based method to determine the pulse count threshold, effectively overcoming the limitations of conventional approaches. We systematically investigated the effects of pulse energy, defocus, and beam expansion ratio on the drilling of 3 mm thick 304 stainless steel and TC4 titanium alloy. The experiments revealed that for stainless steel 304, the minimum taper angle was achieved at a pulse energy of 2.2 J, a defocus amount of −0.5 mm, and a beam expansion ratio of 2.5. Additionally, relatively high drilling efficiency was observed when the pulse energy ranged from 2.6 to 2.8 J, the defocus amount was −1 to 0 mm, and the beam expansion ratio was 3 to 4. For titanium alloy TC4, the minimum taper angle was achieved at a pulse energy of 2.6 J, a defocus amount of −0.5 mm, and a beam expansion ratio of 3.5. High drilling efficiency was recorded when the pulse energy was 2.8 J, the defocus amount was −0.5 mm, and the beam expansion ratio ranged from 2.5 to 3. When stainless steel 304 and titanium alloy TC4 were processed using the same laser parameters, the drilling efficiency of stainless steel 304 was higher than that of titanium alloy TC4 under the same conditions. This work provides a practical process control strategy and a valuable parameter database for high-quality, efficient laser drilling of these industrially important metals. Full article
(This article belongs to the Special Issue Development and Applications of Laser-Based Additive Manufacturing)
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16 pages, 9287 KiB  
Article
Nanosecond Laser Cutting of Double-Coated Lithium Metal Anodes: Toward Scalable Electrode Manufacturing
by Masoud M. Pour, Lars O. Schmidt, Blair E. Carlson, Hakon Gruhn, Günter Ambrosy, Oliver Bocksrocker, Vinayakraj Salvarrajan and Maja W. Kandula
J. Manuf. Mater. Process. 2025, 9(8), 275; https://doi.org/10.3390/jmmp9080275 - 11 Aug 2025
Viewed by 180
Abstract
The transition to high-energy-density lithium metal batteries (LMBs) is essential for advancing electric vehicle (EV) technologies beyond the limitations of conventional lithium-ion batteries. A key challenge in scaling LMB production is the precise, contamination-free separation of lithium metal (LiM) anodes, hindered by lithium’s [...] Read more.
The transition to high-energy-density lithium metal batteries (LMBs) is essential for advancing electric vehicle (EV) technologies beyond the limitations of conventional lithium-ion batteries. A key challenge in scaling LMB production is the precise, contamination-free separation of lithium metal (LiM) anodes, hindered by lithium’s strong adhesion to mechanical cutting tools. This study investigates high-speed, contactless laser cutting as a scalable alternative for shaping double-coated LiM anodes. The effects of pulse duration, pulse energy, repetition frequency, and scanning speed were systematically evaluated using a nanosecond pulsed laser system on 30 µm LiM foils laminated on both sides of an 8 µm copper current collector. A maximum single-pass cutting speed of 3.0 m/s was achieved at a line energy of 0.06667 J/mm, with successful kerf formation requiring both a minimum pulse energy (>0.4 mJ) and peak power (>2.4 kW). Cut edge analysis showed that shorter pulse durations (72 ns) significantly reduced kerf width, the heat-affected zone (HAZ), and bulge height, indicating a shift to vapor-dominated ablation, though with increased spatter due to recoil pressure. Optimal edge quality was achieved with moderate pulse durations (261–508 ns), balancing energy delivery and thermal control. These findings define critical laser parameter thresholds and process windows for the high-speed, high-fidelity cutting of double-coated LiM battery anodes, supporting the industrial adoption of nanosecond laser systems in scalable LMB electrode manufacturing. Full article
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30 pages, 20069 KiB  
Article
Evaluation of CoFe2O4-L-Au (L: Citrate, Glycine) as Superparamagnetic–Plasmonic Nanocomposites for Enhanced Cytotoxic Activity Towards Oncogenic (A549) Cells
by Alberto Lozano-López, Mario E. Cano-González, J. Ventura-Juárez, Martín H. Muñoz-Ortega, Israel Betancourt, Juan Antonio Zapien and Iliana E. Medina-Ramirez
Int. J. Mol. Sci. 2025, 26(16), 7732; https://doi.org/10.3390/ijms26167732 - 10 Aug 2025
Viewed by 221
Abstract
We investigated the influence of gold deposition on the magnetic behavior, biocompatibility, and bioactivity of CoFe2O4 (MCF) nanomaterials (NMs) functionalized with sodium citrate (Cit) or glycine (Gly). The resulting multifunctional plasmonic nanostructured materials (MCF-Au-L, where L is Cit, Gly) exhibit [...] Read more.
We investigated the influence of gold deposition on the magnetic behavior, biocompatibility, and bioactivity of CoFe2O4 (MCF) nanomaterials (NMs) functionalized with sodium citrate (Cit) or glycine (Gly). The resulting multifunctional plasmonic nanostructured materials (MCF-Au-L, where L is Cit, Gly) exhibit superparamagnetic behavior with magnetic saturation of 59 emu/g, 55 emu/g, and 60 emu/g, and blocking temperatures of 259 K, 311 K, and 322 K for pristine MCF, MCF-Au-Gly, and MCF-Au-Cit, respectively. The MCF NMs exhibit a small uniform size (with a mean size of 7.1 nm) and an atomic ratio of Fe:Co (2:1). The gold nanoparticles (AuNPs) show high heterogeneity as determined by high-resolution transmission electron microscopy (HR-TEM) and energy-dispersive X-ray spectroscopy (EDX). The UV-Vis spectroscopy of the composites reveals two localized surface plasmons (LSPs) at 530 nm and 705 nm, while Fourier Transformed-Infrared spectroscopy (FTIR) and thermogravimetric analysis (TGA) confirm the presence of Cit and Gly on their surface. Subsequent biocompatibility tests confirm that MCF-Au-L NMs do not exert hemolytic activity (hemolysis < 5%). In addition, the CCK-8 viability assay tests indicate the higher sensitivity of cancerous cells (A549) to the photoactivity of MCF-Au compared to healthy Detroit 548 (D548) cell lines. We use advanced microscopy techniques, namely atomic force, fluorescence, and holotomography microscopies (AFM, FM, and HTM, respectively) to provide further insights into the nature of the observed photoactivity of MCF-Au-L NMs. In addition, in situ radiation, using a modified HTM microscope with an IR laser accessory, demonstrates the photoactivity of the MCF-Au NMs and their suitability for destroying cancerous cells through photodynamic therapy. The combined imaging capabilities demonstrate clear morphological changes, NMs internalization, and oxidative damage. Our results confirm that the fabricated multifunctional NMs exhibit high stability in aqueous solution, chemical solidity, superparamagnetic behavior, and effective IR responses, making them promising precursors for hybrid cancer therapy. Full article
(This article belongs to the Special Issue Toxicity of Nanoparticles: Second Edition)
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17 pages, 17722 KiB  
Article
Direct Glass-to-Metal Welding by Femtosecond Laser Pulse Bursts: II, Enhancing the Weld Between Glass and Polished Metal Surfaces
by Qingfeng Li, Fei Luo, Gabor Matthäus, David Sohr and Stefan Nolte
Nanomaterials 2025, 15(16), 1215; https://doi.org/10.3390/nano15161215 - 8 Aug 2025
Viewed by 274
Abstract
We present a comprehensive study on the femtosecond laser direct welding of glass and metal, focusing on optimizing processing parameters and understanding the influence of material properties and beam shaping on welding quality. Using microscopy, we identified optimal pulse energy, focal position, and [...] Read more.
We present a comprehensive study on the femtosecond laser direct welding of glass and metal, focusing on optimizing processing parameters and understanding the influence of material properties and beam shaping on welding quality. Using microscopy, we identified optimal pulse energy, focal position, and line-spacing for achieving high-quality welds. We further investigated the effects of laser beam shaping and material property differences in various glass-to-metal pairs, including borosilicate, fused silica, and Zerodur glasses welded with mirror-polished metals such as Cu, Mo, Al, Ti, and AISI316 steel. Our results show that Ti and AISI316 steel exhibit the lowest adhesion to borosilicate and fused silica glasses, while Zerodur glass achieves good adhesion with all tested metals. To understand the weldability differences among material pairs, we employed a time-dependent finite-element method to analyze the laser heating-induced thermal stress. Our findings indicate that the welding quality is significantly influenced by the choice of materials and beam shaping, with the vortex beam showing potential for improved welding outcomes. This study provides valuable insights for optimizing glass-to-metal welding processes for various industrial applications. Full article
(This article belongs to the Special Issue Ultrafast Laser Micro-Nano Welding: From Principles to Applications)
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13 pages, 3998 KiB  
Article
Promoting Surface Energy and Osteoblast Viability on Zirconia Implant Abutments Through Glass–Ceramic Spray Deposition Technology
by Wen-Chieh Hsu, Tao-Yu Cha, Yu-Chin Yao, Chien-Ming Kang, Sheng-Han Wu, Yuichi Mine, Chien-Fu Tseng, I-Ta Lee, Dan-Jae Lin and Tzu-Yu Peng
J. Funct. Biomater. 2025, 16(8), 288; https://doi.org/10.3390/jfb16080288 - 7 Aug 2025
Viewed by 525
Abstract
Zirconia is used widely for high-precision custom abutments; however, stress concentration can compromise osseointegration. Although glass–ceramic spray deposition (GCSD) can enhance the surface properties of zirconia, its biological effects remain unclear. In this study, the biological responses of human osteoblast-like (MG-63) cells to [...] Read more.
Zirconia is used widely for high-precision custom abutments; however, stress concentration can compromise osseointegration. Although glass–ceramic spray deposition (GCSD) can enhance the surface properties of zirconia, its biological effects remain unclear. In this study, the biological responses of human osteoblast-like (MG-63) cells to GCSD-modified zirconia surfaces were evaluated to assess the potential application in zirconia abutments. Disk-shaped zirconia and titanium alloy samples were prepared; titanium served as the control (Ti). Zirconia was subjected to polishing (NT), airborne-particle abrasion (AB), or GCSD with (GE) or without (GC) hydrofluoric acid (HF) etching. Surface characteristics, including wettability, surface energy (SE), and surface potential (SP), were analyzed. Cytotoxicity and MG-63 cell adhesion were assessed using the PrestoBlue assay, scanning electron microscopy (SEM), viability staining, and confocal laser scanning microscopy (CLSM). Statistical analysis was performed with a significance level of 0.05. GCSD produced a dense glass–ceramic coating on the zirconia surface, which significantly enhanced hydrophilicity as indicated by reduced water contact angles and increased SE in the GC and GE groups (p < 0.05). HF etching increased SP (p < 0.05). No cytotoxicity was observed in any group. SEM, viability staining, and CLSM revealed enhanced MG-63 cell attachment on Ti and GE surfaces and the highest viability ratio in the GE group. The NT group exhibited the lowest cell attachment and viability at all time points. GCSD effectively improved zirconia abutment surface properties by enhancing hydrophilicity and promoting MG-63 cell adhesion, with biocompatibility comparable to or better than that of titanium. Full article
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