Search Results (176)

Concrete production contributes approximately 4–8% of global cardon dioxide emissions, largely due to Portland cement. Incorporating municipal solid waste (MSW) into concrete offers a pathway to reduce cement demand while supporting circular economy objectives. This study evaluates the mechanical performance, environmental impacts, and optimization potential of concrete incorporating three MSW-derived materials: cardboard kraft fibers (KFs), recycled high-density polyethylene (HDPE), and textile fibers. A maximum 10% cement replacement strategy was adopted. Compressive strength was assessed at 7, 14, and 28 days, and a cradle-to-gate life cycle assessment (LCA) was conducted using OpenLCA to quantify global warming potential (GWP100) and other midpoint impacts. A surrogate-based optimization implemented using Non-dominated Sorting Genetic Algorithm II (NSGA-II) was applied to minimize cost and GWP while enforcing compressive strength as a feasibility constraint. The results show that fiber-based wastes significantly reduce embodied carbon, with KF achieving the largest GWP reduction (19%) and textile waste achieving moderate reductions (10%) relative to the control. HDPE-modified concrete exhibited near-control mechanical performance but increased GWP and fossil depletion due to polymer processing burdens. The optimization results revealed well-defined Pareto trade-offs for KF and textile concretes, identifying clear compromise solutions between cost and emissions, while HDPE was consistently dominated. Overall, textile waste emerged as the most balanced option, offering favorable environmental gains with minimal cost and acceptable mechanical performance. The integrated LCA optimization framework demonstrates a robust approach for evaluating MSW-derived concrete and supports evidence-based decision-making toward low-carbon, circular construction materials. Full article

Spunbonding drafters play a decisive role in determining fiber attenuation, morphology, and final nonwoven quality; however, their internal airflow behavior remains poorly characterized due to limited physical accessibility and historically empirical design practices. This work employs high-fidelity computational fluid dynamics (CFD) to systematically resolve the airflow field inside a laboratory-scale drafter and to quantify the impact of geometry on fiber drawing conditions. The simulations reveal a previously unreported “braking effect,” where adverse flow structures reduce effective shear drag, limit drawability, and increase the likelihood of fiber breakage. Parametric virtual experimentation across seven geometric variables demonstrates that the drafter configuration strongly governs shear distribution, flow uniformity, and energy consumption. Using a performance-oriented optimization framework, three key processing objectives were targeted: (i) maximizing shear drag to promote stable fiber attenuation, (ii) improving axial drawing uniformity, and (iii) minimizing pressurized-air demand. CFD-guided design modifications—including controlled widening, tailored wall divergence and convergence, and an extensible lower section—were implemented and subsequently validated using a newly constructed prototype. Experimental measurements on polypropylene (PP) and high-density polyethylene (HDPE) fibers confirm substantial reductions in fiber breakage and improvements in drawing stability, thereby demonstrating the effectiveness of simulation-driven process optimization in spunbonding equipment design. Full article

This study investigates the ballistic performance and energy-absorption behavior of advanced multilayer ceramic composite armor systems composed of silicon carbide (SiC) ceramics, composite metal foam (CMF), rolled homogeneous armor (RHA), ultra-high-molecular-weight polyethylene (UHMWPE), aluminum, and rubber interlayers. The objective is to enhance impact resistance and optimize energy dissipation efficiency against armor-piercing (AP) projectiles. Ballistic tests were performed following the NIJ Standard 0101.06 Level IV specifications using .30” caliber AP M2 rounds with an impact velocity of 784–844 m/s. Experimental results revealed that the SiC front layer effectively fragmented the projectile and dispersed its kinetic energy, while the CMF and UHMWPE layers were the primary energy absorbers, dissipating approximately 70% of the total impact energy (≈3660 J). The aluminum and RHA layers provided additional reinforcement, and the rubber interlayer significantly reduced stress-wave propagation and suppressed crack growth in the ceramic. The most efficient configuration 0.5 mm RHA + 7 mm SiC + 7 mm EPDM + 7 mm CMF + 5 mm UHMWPE achieved an areal density absorption of 77.2 J·m²/kg and a unit thickness absorption of 190.6 J/mm. These findings establish a quantitative layer-wise energy dissipation framework, highlighting the synergistic interaction between brittle, porous, and ductile layers. This work provides practical design principles for developing lightweight, high-efficiency composite armor systems applicable to defense, aerospace, and personal protection fields. Moreover, this study not only validates the NIJ Standard 0101.06 ballistic performance experimentally but also establishes a reproducible methodology for quantitative, layer-wise energy analysis of hybrid ceramic-CMF-fiber armor systems, offering a scientific framework for future model calibration and optimization. Full article

Thermoset composites provide excellent strength but pose major recycling challenges due to their crosslinked structure. In this study, epoxy–polyurethane–glass fiber (EPG) wastes were mechanically recycled into low-density polyethylene (LDPE), high-density polyethylene (HDPE), and polyamide-6 (PA6) matrices to produce second-generation thermoplastic composites (STCs). Fillers at 10–50 wt% were processed by single-screw extrusion and compression molding, and the resulting composites were comprehensively characterized. For LDPE, the tensile modulus increased by ~286–589% and tensile strength increased by 40–47% at 20–30 wt% loading, though ductility decreased at higher levels. HDPE composites showed a ~347% rise in modulus and ~24% increase in strength, but performance declined with more than 40 wt% filler. PA6 offered the most balanced outcome, retaining ~70% of its neat tensile strength while achieving an ~300% modulus improvement at 40 wt% loading. Thermal stability was strongly enhanced, with char residue at 700 °C rising from 0.4% to 38.7% in PA6 and from ~2.5% to 33–46% in polyolefins. In contrast, crystallinity decreased (e.g., LDPE 62.2% → 23.7%), and impact strength dropped at a loading above 30 wt%. Overall, the results demonstrate that EPG wastes can be reprocessed into functional composites without compatibilizers, with PA6 providing the most robust property retention at high filler contents. Full article

Advancements in bioinks and three-dimensional (3D) printing and bioprinting have significantly advanced cardiovascular tissue engineering by enabling the fabrication of biomimetic cardiac and vascular constructs. Traditional 3D printing has contributed to the development of acellular scaffolds, vascular grafts, and patient-specific cardiovascular models that support surgical planning and biomedical applications. In contrast, 3D bioprinting has emerged as a transformative biofabrication technology that allows for the spatially controlled deposition of living cells and biomaterials to construct functional tissues in vitro. Bioinks—derived from natural biomaterials such as collagen and decellularized matrix, synthetic polymers such as polyethylene glycol (PEG) and polycaprolactone (PCL), or hybrid combinations—have been engineered to replicate extracellular environments while offering tunable mechanical properties. These formulations ensure biocompatibility, appropriate mechanical strength, and high printing fidelity, thereby maintaining cell viability, structural integrity, and precise architectural resolution in the printed constructs. Advanced bioprinting modalities, including extrusion-based bioprinting (such as the FRESH technique), droplet/inkjet bioprinting, digital light processing (DLP), two-photon polymerization (TPP), and melt electrowriting (MEW), enable the fabrication of complex cardiovascular structures such as vascular patches, ventricle-like heart pumps, and perfusable vascular networks, demonstrating the feasibility of constructing functional cardiac tissues in vitro. This review highlights the respective strengths of these technologies—for example, extrusion’s ability to print high-cell-density bioinks and MEW’s ultrafine fiber resolution—as well as their limitations, including shear-induced cell stress in extrusion and limited throughput in TPP. The integration of optimized bioink formulations with appropriate printing and bioprinting platforms has significantly enhanced the replication of native cardiac and vascular architectures, thereby advancing the functional maturation of engineered cardiovascular constructs. Full article

High-density polyethylene (HDPE) is widely used for different applications, but its low resistance to ultraviolet radiation, plastic deformation, chemical stability, and wear re-sistance limits its use in high-demand work environments. Modifying of the surface characteristics could improve the work efficiency of the parts exposed to an aggressive environment. Plasma treatments change the surface characteristics with deposition of a coating or by modifying the surface’s energy, varying the surface properties. This study presents the mechanical and tribological properties of a titanium (Ti) layer with fiber-like morphology produced on HDPE surfaces by plasma treatment involving plasma etching and the deposition of Ti atoms, through DC magnetron sputtering. On the HDPE substrates grew up Ti layer with fibers-like morphology with a diameter of 1.6 ± 0.44 μm. These fibers were elemental composed by 91.5 ± 0.9% Ti and 8.5 ± 0.6% O with α-Ti phase combined with HDPE crystalline structure. The Ti coating increased the hardness of the substrate and showed a good adhesion to HDPE surface. During the sliding test, the Ti layer with fiber-like morphology exhibited plastic deformation and debris accumulation, leading to the formation of a tribolayer without layer detachment. Notably, no detachment of the layer was observed, effectively protected the polymer surface, and enhanced its performance for tribological applications. Full article

The thermal, thermomechanical, and viscoelastic properties of continuous unidirectional (UD) glass fiber/high-density polyethylene (GF/HDPE) and ultra-high-molecular-weight polyethylene/high-density polyethylene (UHMWPE/HDPE) tapes are characterized in this paper in order to support their use in extreme environments. Unlike prior studies that focus on short-fiber composites or limited thermal conditions, this work examines continuous fiber architectures under five operational environments derived from Army Regulation 70-38, reflecting realistic defense-relevant extremes. Differential scanning calorimetry (DSC) was used to identify melting transitions for GF/HDPE and UHMWPE/HDPE, which guided the selection of test conditions for thermomechanical analysis (TMA) and dynamic mechanical analysis (DMA). TMA revealed anisotropic thermal expansion consistent with fiber orientation, while DMA, via strain sweep, temperature ramp, frequency sweep, and stress relaxation, quantified their temperature- and time-dependent viscoelastic behavior. The frequency-dependent storage modulus highlighted multiple resonant modes, and stress relaxation data were fitted with high accuracy (R² > 0.99) to viscoelastic models, yielding model parameters that can be used for predictive simulations of time-dependent material behavior. A comparative analysis between the two material systems showed that UHMWPE/HDPE offers enhanced unidirectional stiffness and better low-temperature performance. At the same time, GF/HDPE exhibits lower thermal expansion, better transverse stiffness, and greater stability at elevated temperatures. These differences highlight the impact of fiber type on thermal and mechanical responses, informing material selection for applications that require directional load-bearing or dimensional control under thermal cycling. By integrating thermal and viscoelastic characterization across realistic operational profiles, this study provides a foundational dataset for the application of continuous fiber thermoplastic tapes in structural components exposed to harsh thermal and mechanical conditions. Full article

To improve the reliability of glass-fiber/epoxy-reinforced polymer (GFRP) composites, four laminates were manufactured by vacuum bagging: (i) a virgin baseline, (ii) an epoxy system modified with 15 wt% high-density polyethylene (PE) powder, (iii) a laminate interleaved with electrospun polyacrylonitrile (PAN)-based nanofiber mats, and (iv) a hybrid combining both modifiers. The specimens were subjected to low-velocity impacts; half were then heated at 150 °C for 30 min and re-impacted. PE caused peak-load loss up to 30% compared to virgin specimens but recovered 25% after heating by filling cracks. PAN interleaves limited the loss to 5%, and the hybrid laminate merged the benefits: it showed the highest first-impact load, retained 96% on re-impact, and gained a further 10% after heating while keeping the smallest permanent indentation. SEM confirmed molten PE migrating along the nanofiber mat to repair delamination fronts, explaining the laminate’s bell-shaped, oscillation-free force response and demonstrating a practical, synergistic self-healing mechanism. Collectively, the results demonstrate a clear structure–property connection: PAN nanofibers capture crack growth, while PE provides temperature-triggered self-healing, and their synergy offers a practical pathway to lightweight GFRP structures with enhanced impact resilience and restoration of mechanical integrity. Full article

Alkali-activated building materials have attracted the interest of many researchers due to their low cost and eco-efficiency. Different binders with different chemical compositions can be used for their production, so the reaction mechanism can become complex and the results of studies can vary widely. In this work, several alkali-activated mortars based on marginal by-products as binders, such as high calcium fly ash and ladle furnace slag, are investigated. Their mechanical (flexural and compressive strength, ultrasonic pulse velocity, and modulus of elasticity) and physical (porosity, absorption, specific gravity, and pH) properties were determined. After evaluating the mechanical performance of the mortars, the optimum mixture containing fly ash, which reached 15 MPa under compression at 90 days, was selected for the production of precast compressed slabs. Steel or glass fibers were also incorporated to improve their ductility. To reduce the density of the slabs, 60% of the siliceous sand aggregate was also replaced with recycled polyethylene terephthalate (PET) plastic aggregate. The homogeneity, density, porosity, and capillary absorption of the slabs were measured, as well as their flexural strength and fracture energy. The results showed that alkali activation can be used to improve the mechanical properties of weak secondary binders such as ladle furnace slag and hydrated fly ash. The incorporation of recycled PET aggregates produced slabs that could be classified as lightweight, with similar porosity and capillary absorption values, and over 65% achieved strength compared to the normal weight slabs. Full article

In this study, the optimal design of the central pipe in a middle-deep geothermal heat pump (MD-GHP) system is studied using the response surface method to improve the system’s coefficient of performance (COP) and operational reliability. Firstly, a model describing the energy transfer and conversion mechanisms of the MD-GHP system, incorporating unsteady heat transfer in the central pipe, is established and validated using field test data. Secondly, taking the inner diameter, wall thickness, and effective thermal conductivity of the central pipe as design variables, the effects of these parameters on the COP of a 2700 m deep MD-GHP system are analyzed and optimized via the response surface method. The resulting optimal parameters are as follows: an inner diameter of 88 mm, a wall thickness of 14 mm, and an effective thermal conductivity of 0.2 W/(m·K). Based on these results, a composite central pipe composed of high-density polyethylene (HDPE), silica aerogels, and glass fiber tape is designed and fabricated. The developed pipe achieves an effective thermal conductivity of 0.13 W/(m·K) and an axial tensile force of 29,000 N at 105 °C. Compared with conventional PE and vacuum-insulated pipes, the composite central pipe improves the COP by 11% and 7%, respectively. This study proposes an optimization-based design approach for central pipe configuration in MD-GHP systems and presents a new composite pipe with enhanced thermal insulation and mechanical performance. Full article

Composite pressure vessels offer significant advantages over traditional metal-lined designs due to their high strength-to-weight ratio, corrosion resistance, and design flexibility. This study investigates the structural design, winding process, finite element analysis, and experimental validation of a glass fiber-reinforced composite low-pressure vessel. A high-density polyethylene (HDPE) liner was designed with a nominal thickness of 1.5 mm and manufactured via blow molding. The optimal blow-up ratio was determined as 2:1, yielding a wall thickness distribution between 1.39 mm and 2.00 mm under a forming pressure of 6 bar. The filament winding process was simulated using CADWIND software (version 10.2), resulting in a three-layer winding scheme consisting of two helical layers (19.38° winding angle) and one hoop layer (89.14°). The calculated thickness of the composite winding layer was 0.375 mm, and the coverage rate reached 107%. Finite element analysis, conducted using Abaqus, revealed that stress concentrations occurred at the knuckle region connecting the dome and the cylindrical body. The vessel was predicted to fail at an internal pressure of 5.00 MPa, primarily due to fiber breakage initiated at the polar transition. Experimental hydrostatic burst tests validated the simulation, with the vessel exhibiting failure at an average pressure of 5.06 MPa, resulting in an error margin of only 1.2%. Comparative tests on vessels without adhesive sealing at the head showed early failure at 2.46 MPa, highlighting the importance of head sealing on vessel integrity. Scanning electron microscopy (SEM) analysis confirmed strong fiber–matrix adhesion and ductile fracture characteristics. The close agreement between the simulation and experimental results demonstrates the reliability of the proposed design methodology and validates the use of CADWIND and FEA in predicting the structural performance of composite pressure vessels. Full article

Polyethylene films prepared from orientation-dependent methods are strong and resilient, have reduced permeability, and possess higher tensile strength. A molecular dynamics investigation is performed to reveal the emergence of chain folding and lamellar crystal axis alignment along the stretching axis (tilt angle) in the stretch-induced crystallization (SIC) of high-density polyethylene (HDPE), which mimics the internal structure of the fiber. The morphology in phase transition is assessed by the total density (ρ), degree of crystallinity (%${\chi }_c$), average number of entanglements per chain (<Z>), elastic modulus of the mechanical property, and lamellar chain tilt angle (θ) from the stretch-axis. The simulation emphasizes crystal formation by changing the total ρ from 0.85 g·cm⁻³ to 0.90 g·cm⁻³ and by tracking the gradual increase in %${\chi }_c$ during stretching (~40%) and relaxation processes (~50%). Moreover, the primitive path analysis-based <Z> decreased during stretching and further in the subsequent relaxation process, supporting the alignment and thickening of the lamellar chain structure and chain folding from the random coil structure. The elastic modulus of ~350–400 MPa evidences the high alignment of the lamellar chains along the stretching axis. Consistent with the chain tilt angle of the HDPE in SAXS/WAXS experiments, the model estimated the lamellar chain title angle (θ) relative to the stretching axis to be ~20–35°. In conclusion, SIC is a convenient approach for simulating high stiffness, tensile strength, reduced permeability, and chain alignment in fiber film models, which can help design new fiber morphology-based polymers or composites. Full article

This study explores the lamination performance of wood-plastic composite boards designed for indoor decoration, aiming to enhance adhesion between a wood fiber/high-density polyethylene (HDPE) composite board and poplar wood veneer by incorporating fabrics (canvas or polyester fibers) as an intermediate layer. Traditional adhesives, such as polyvinyl acetate (PVAc) and isocyanate, were utilized to create decorative panels with a multi-interface sandwich structure. The impacts of factors such as the hot-pressing temperature, wood fiber content in the substrate, and fabric type on the performance of the panels were systematically investigated. The results indicated that the hot-pressing temperature of the substrate had minimal effect on the lamination performance. Panels that used canvas fabric as the intermediate layer and bonded with a mixed adhesive of PVAc and isocyanate exhibited superior surface bonding strength (2.76 MPa), bending properties (strength = 49.21 MPa; modulus = 3.92 MPa), and tensile properties (strength = 31.62 MPa; modulus = 1.51 GPa). The enhanced performance was attributed to the covalent bonding formed by isocyanate with canvas fabric, polyester fibers, and wood veneer, whereas PVAc primarily established physical bonds through penetration. Full article

The accumulation of polyolefin waste, particularly high-density polyethylene (HDPE), presents a growing environmental challenge due to limited recycling options and poor end-of-life recovery. This study explores a strategy to convert HDPE into mesophase pitch (MP), a valuable carbon precursor, by integrating polyolefin recycling with the mild solvolysis liquefaction (MSL) of low-rank coals. HDPE was first hydrogenolyzed into a hydrogen-rich aromatic liquid (HDPE-liquid), which was then used as the liquefaction solvent. Under identical conditions (400 °C, 60 min), Utah Sufco coal co-liquefied with HDPE-liquid produced tar that formed mesophase pitch with a higher mesophase content (84.5% vs. 78.6%) and a lower softening point (~302 °C vs. >350 °C) compared to pitch from conventional tetralin (THN). The approach was extended to Illinois #6 and Powder River Basin coals, increasing the mesophase content from 12.4% to 32.6% and 17.8% to 62.1%, respectively. These improvements are attributed to differences in tar composition: HDPE-derived tars had lower terminal methyl (Hγ) contents, reducing cross-linking during thermal upgrading. This work demonstrates that HDPE-derived liquids can act as functional solvents for coal liquefaction, enabling an effective route to recycle polyolefin waste into durable carbon products, while also reducing reliance on fossil-based solvents for mesophase pitch production. Full article

Maintaining the consistency of linear density in ultra-high-molecular-weight polyethylene (UHMWPE) fiber has been a critical challenge in the production of UHMWPE fibers. However, there has been limited research focusing on the impact of UHMWPE resin parameters on the consistency in fiber linear density. In this study, a series of UHMWPE fibers were produced through wet spinning using UHMWPE resins with varying parameters. The effects of molecular weight, molecular weight distribution, particle size, and particle size distribution of UHMWPE resins on the consistency of linear density and the mechanical properties of UHMWPE fibers were systematically investigated. The experimental findings revealed that narrowing the molecular weight distribution and particle size distribution of ultra-high molecular weight polyethylene (UHMWPE) resin precursors significantly enhanced the consistency of resultant UHMWPE fibers, concurrently improving their tensile strength and elastic modulus. Notably, while the absolute molecular weight of the resin demonstrated no statistically significant correlation with fiber consistency, an optimal molecular weight range was identified to maximize the mechanical performance of UHMWPE fibers. Specifically, fibers synthesized from resin precursors within this molecular weight window exhibited peak values in both strength and modulus, suggesting a critical balance between molecular chain entanglement and processability. Full article