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Search Results (3,069)

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Keywords = high frequency properties

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16 pages, 4733 KiB  
Article
Vibratory Pile Driving in High Viscous Soil Layers: Numerical Analysis of Penetration Resistance and Prebored Hole of CEL Method
by Caihui Li, Changkai Qiu, Xuejin Liu, Junhao Wang and Xiaofei Jing
Buildings 2025, 15(15), 2729; https://doi.org/10.3390/buildings15152729 (registering DOI) - 2 Aug 2025
Abstract
High-viscosity stratified strata, characterized by complex geotechnical properties such as strong cohesion, low permeability, and pronounced layered structures, exhibit significant lateral friction resistance and high-end resistance during steel sheet pile installation. These factors substantially increase construction difficulty and may even cause structural damage. [...] Read more.
High-viscosity stratified strata, characterized by complex geotechnical properties such as strong cohesion, low permeability, and pronounced layered structures, exhibit significant lateral friction resistance and high-end resistance during steel sheet pile installation. These factors substantially increase construction difficulty and may even cause structural damage. This study addresses two critical mechanical challenges during vibratory pile driving in Fujian Province’s hydraulic engineering project: prolonged high-frequency driving durations, and severe U-shaped steel sheet pile head damage in high-viscosity stratified soils. Employing the Coupled Eulerian–Lagrangian (CEL) numerical method, a systematic investigation was conducted into the penetration resistance, stress distribution, and damage patterns during vibratory pile driving under varying conditions of cohesive soil layer thickness, predrilled hole spacing, and aperture dimensions. The correlation between pile stress and penetration depth was established, with the influence mechanisms of key factors on driving-induced damage in high-viscosity stratified strata under multi-factor coupling effects elucidated. Finally, the feasibility of predrilling techniques for resistance reduction was explored. This study applies the damage prediction model based on the CEL method to U-shaped sheet piles in high-viscosity stratified formations, solving the problem of mesh distortion in traditional finite element methods. The findings provide scientific guidance for steel sheet pile construction in high-viscosity stratified formations, offering significant implications for enhancing construction efficiency, ensuring operational safety, and reducing costs in such challenging geological conditions. Full article
(This article belongs to the Section Building Structures)
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27 pages, 4070 KiB  
Article
Quantum Transport in GFETs Combining Landauer–Büttiker Formalism with Self-Consistent Schrödinger–Poisson Solutions
by Modesto Herrera-González, Jaime Martínez-Castillo, Pedro J. García-Ramírez, Enrique Delgado-Alvarado, Pedro Mabil-Espinosa, Jairo C. Nolasco-Montaño and Agustín L. Herrera-May
Technologies 2025, 13(8), 333; https://doi.org/10.3390/technologies13080333 (registering DOI) - 1 Aug 2025
Viewed by 46
Abstract
The unique properties of graphene have allowed for the development of graphene-based field-effect transistors (GFETs) for applications in biosensors and chemical devices. However, the modeling and optimization of GFET performance exhibit great challenges. Herein, we propose a quantum transport simulation model for graphene-based [...] Read more.
The unique properties of graphene have allowed for the development of graphene-based field-effect transistors (GFETs) for applications in biosensors and chemical devices. However, the modeling and optimization of GFET performance exhibit great challenges. Herein, we propose a quantum transport simulation model for graphene-based field-effect transistors (GFETs) implemented in the open-source Octave programming language. The proposed simulation model (named SimQ) combines the Landauer–Büttiker formalism with self-consistent Schrödinger–Poisson solutions, enabling reliable simulations of transport phenomena. Our approach agrees well with established models, achieving Landauer–Büttiker transmission and tunneling transmission of 0.28 and 0.92, respectively, which are validated against experimental data. The model can predict key GFET characteristics, including carrier mobilities (500–4000 cm2/V·s), quantum capacitance effects, and high-frequency operation (80–100 GHz). SimQ offers detailed insights into charge distribution and wave function evolution, achieving an enhanced computational efficiency through optimized algorithms. Our work contributes to the modeling of graphene-based field-effect transistors, providing a flexible and accessible simulation platform for designing and optimizing GFETs with potential applications in the next generation of electronic devices. Full article
(This article belongs to the Special Issue Technological Advances in Science, Medicine, and Engineering 2024)
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31 pages, 5480 KiB  
Review
Solid Core Magnetic Gear Systems: A Comprehensive Review of Topologies, Core Materials, and Emerging Applications
by Serkan Sezen, Kadir Yilmaz, Serkan Aktas, Murat Ayaz and Taner Dindar
Appl. Sci. 2025, 15(15), 8560; https://doi.org/10.3390/app15158560 (registering DOI) - 1 Aug 2025
Viewed by 175
Abstract
Magnetic gears (MGs) are attracting increasing attention in power transmission systems due to their contactless operation principles, low frictional losses, and high efficiency. However, the broad application potential of these technologies requires a comprehensive evaluation of engineering parameters, such as material selection, energy [...] Read more.
Magnetic gears (MGs) are attracting increasing attention in power transmission systems due to their contactless operation principles, low frictional losses, and high efficiency. However, the broad application potential of these technologies requires a comprehensive evaluation of engineering parameters, such as material selection, energy efficiency, and structural design. This review focuses solely on solid-core magnetic gear systems designed using laminated electrical steels, soft magnetic composites (SMCs), and high-saturation alloys. This review systematically examines the topological diversity, torque transmission principles, and the impact of various core materials, such as electrical steels, soft magnetic composites (SMCs), and cobalt-based alloys, on the performance of magnetic gear systems. Literature-based comparative analyses are structured around topological classifications, evaluation of material properties, and performance analyses based on losses. Additionally, the study highlights that aligning material properties with appropriate manufacturing methods, such as powder metallurgy, wire electrical discharge machining (EDM), and precision casting, is essential for the practical scalability of magnetic gear systems. The findings reveal that coaxial magnetic gears (CMGs) offer a favorable balance between high torque density and compactness, while soft magnetic composites provide significant advantages in loss reduction, particularly at high frequencies. Additionally, application trends in fields such as renewable energy, electric vehicles (EVs), aerospace, and robotics are highlighted. Full article
(This article belongs to the Section Electrical, Electronics and Communications Engineering)
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21 pages, 1569 KiB  
Article
A Multibody-Based Benchmarking Framework for the Control of the Furuta Pendulum
by Gerardo Peláez, Pablo Izquierdo, Gustavo Peláez and Higinio Rubio
Actuators 2025, 14(8), 377; https://doi.org/10.3390/act14080377 (registering DOI) - 31 Jul 2025
Viewed by 119
Abstract
The Furuta pendulum is a well-known benchmark in the field of underactuated mechanical systems due to its reduced number of control inputs compared to its degrees of freedom, and richly nonlinear behavior. This work addresses the challenge of accurately modeling and controlling such [...] Read more.
The Furuta pendulum is a well-known benchmark in the field of underactuated mechanical systems due to its reduced number of control inputs compared to its degrees of freedom, and richly nonlinear behavior. This work addresses the challenge of accurately modeling and controlling such a system without relying on traditional linearization techniques. In contrast to the common approach based on Lagrangian analytical modeling and state–space linearization, we propose a methodology that integrates a high-fidelity multibody model developed in Simscape Multibody (MATLAB), capturing the complete nonlinear dynamics of the system. The multibody model includes all geometric, inertial, and joint parameters of the physical hardware and interfaces directly with Simulink, enabling realistic simulation and control integration. To validate the physical fidelity of the multibody model, we perform a frequency-domain analysis of the pendulum’s natural free response. The dominant vibration frequency extracted from the simulation is compared with the theoretical prediction, demonstrating accurate capture of the system’s inertial and dynamic properties. This validation strategy strengthens the reliability of the model as a digital twin. The classical analytical formulation is provided to validate the simulation model and serve as a comparative framework. This dual modeling strategy allows for benchmarking control strategies against a trustworthy nonlinear digital twin of the Furuta pendulum. Preliminary experimental results using a physical prototype validate the feasibility of the proposed approach and set the foundation for future work in advanced nonlinear control design using the multibody representation as a digital validation tool. Full article
(This article belongs to the Special Issue Dynamics and Control of Underactuated Systems)
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18 pages, 2263 KiB  
Article
Predicting Antimicrobial Peptide Activity: A Machine Learning-Based Quantitative Structure–Activity Relationship Approach
by Eliezer I. Bonifacio-Velez de Villa, María E. Montoya-Alfaro, Luisa P. Negrón-Ballarte and Christian Solis-Calero
Pharmaceutics 2025, 17(8), 993; https://doi.org/10.3390/pharmaceutics17080993 (registering DOI) - 31 Jul 2025
Viewed by 240
Abstract
Background: Peptides are a class of molecules that can be presented as good antimicrobials and with mechanisms that avoid resistance, and the design of peptides with good activity can be complex and laborious. The study of their quantitative structure–activity relationships through machine [...] Read more.
Background: Peptides are a class of molecules that can be presented as good antimicrobials and with mechanisms that avoid resistance, and the design of peptides with good activity can be complex and laborious. The study of their quantitative structure–activity relationships through machine learning algorithms can shed light on a rational and effective design. Methods: Information on the antimicrobial activity of peptides was collected, and their structures were characterized by molecular descriptors generation to design regression and classification models based on machine learning algorithms. The contribution of each descriptor in the generated models was evaluated by determining its relative importance and, finally, the antimicrobial activity of new peptides was estimated. Results: A structured database of antimicrobial peptides and their descriptors was obtained, with which 56 machine learning models were generated. Random Forest-based models showed better performance, and of these, regression models showed variable performance (R2 = 0.339–0.574), while classification models showed good performance (MCC = 0.662–0.755 and ACC = 0.831–0.877). Those models based on bacterial groups showed better performance than those based on the entire dataset. The properties of the new peptides generated are related to important descriptors that encode physicochemical properties such as lower molecular weight, higher charge, propensity to form alpha-helical structures, lower hydrophobicity, and higher frequency of amino acids such as lysine and serine. Conclusions: Machine learning models allowed to establish the structure–activity relationships of antimicrobial peptides. Classification models performed better than regression models. These models allowed us to make predictions and new peptides with high antimicrobial potential were proposed. Full article
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22 pages, 6682 KiB  
Article
An FR4-Based Oscillator Loading an Additional High-Q Cavity for Phase Noise Reduction Using SISL Technology
by Jingwen Han, Ningning Yan and Kaixue Ma
Electronics 2025, 14(15), 3041; https://doi.org/10.3390/electronics14153041 - 30 Jul 2025
Viewed by 140
Abstract
An FR4-based X-band low phase noise oscillator loading an additional high-Q cavity resonator was designed in this study using substrate-integrated suspended line (SISL) technology. The additional resonator was coupled to an oscillator by the transmission line (coupling TL). The impact of the [...] Read more.
An FR4-based X-band low phase noise oscillator loading an additional high-Q cavity resonator was designed in this study using substrate-integrated suspended line (SISL) technology. The additional resonator was coupled to an oscillator by the transmission line (coupling TL). The impact of the additional resonator on startup conditions, Q factor enhancement, and phase noise reduction was thoroughly investigated. Three oscillators loading an additional high-Q cavity resonator, loading an additional high-Q cavity resonator and performing partial dielectric extraction, and loading an original parallel feedback oscillator for comparison were presented. The experimental results showed that the proposed oscillator had a low phase noise of −131.79 dBc/Hz at 1 MHz offset from the carrier frequency of 10.088 GHz, and the FOM was −197.79 dBc/Hz. The phase noise was reduced by 1.66 dB through loading the additional resonator and further reduced by 1.87 dB through partially excising the substrate. To the best of our knowledge, the proposed oscillator showed the lowest phase noise and FOM compared with other all-FR4-based oscillators. The cost of fabrication was markedly reduced. The proposed oscillator also has the advantages of compact size and self-packaging properties. Full article
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21 pages, 6310 KiB  
Article
Geological Evaluation of In-Situ Pyrolysis Development of Oil-Rich Coal in Tiaohu Mining Area, Santanghu Basin, Xinjiang, China
by Guangxiu Jing, Xiangquan Gao, Shuo Feng, Xin Li, Wenfeng Wang, Tianyin Zhang and Chenchen Li
Energies 2025, 18(15), 4034; https://doi.org/10.3390/en18154034 - 29 Jul 2025
Viewed by 160
Abstract
The applicability of the in-situ pyrolysis of oil-rich coal is highly dependent on regional geological conditions. In this study, six major geological factors and 19 key parameters influencing the in-situ pyrolysis of oil-rich coal were systematically identified. An analytic hierarchy process incorporating index [...] Read more.
The applicability of the in-situ pyrolysis of oil-rich coal is highly dependent on regional geological conditions. In this study, six major geological factors and 19 key parameters influencing the in-situ pyrolysis of oil-rich coal were systematically identified. An analytic hierarchy process incorporating index classification and quantification was employed in combination with the geological features of the Tiaohu mining area to establish a feasibility evaluation index system suitable for in-situ development in the study region. Among these factors, coal quality parameters (e.g., coal type, moisture content, volatile matter, ash yield), coal seam occurrence characteristics (e.g., seam thickness, burial depth, interburden frequency), and hydrogeological conditions (e.g., relative water inflow) primarily govern pyrolysis process stability. Surrounding rock properties (e.g., roof/floor lithology) and structural features (e.g., fault proximity) directly impact pyrolysis furnace sealing integrity, while environmental geological factors (e.g., hazardous element content in coal) determine environmental risk control effectiveness. Based on actual geological data from the Tiaohu mining area, the comprehensive weight of each index was determined. After calculation, the southwestern, central, and southeastern subregions of the mining area were identified as favorable zones for pyrolysis development. A constraint condition analysis was then conducted, accompanied by a one-vote veto index system, in which the thresholds were defined for coal seam thickness (≥1.5 m), burial depth (≥500 m), thickness variation coefficient (≤15%), fault proximity (≥200 m), tar yield (≥7%), high-pressure permeability (≥10 mD), and high-pressure porosity (≥15%). Following the exclusion of unqualified boreholes, three target zones for pyrolysis furnace deployment were ultimately selected. Full article
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13 pages, 2826 KiB  
Article
Design and Application of p-AlGaN Short Period Superlattice
by Yang Liu, Changhao Chen, Xiaowei Zhou, Peixian Li, Bo Yang, Yongfeng Zhang and Junchun Bai
Micromachines 2025, 16(8), 877; https://doi.org/10.3390/mi16080877 - 29 Jul 2025
Viewed by 206
Abstract
AlGaN-based high-electron-mobility transistors are critical for next-generation power electronics and radio-frequency applications, yet achieving stable enhancement-mode operation with a high threshold voltage remains a key challenge. In this work, we designed p-AlGaN superlattices with different structures and performed energy band structure simulations using [...] Read more.
AlGaN-based high-electron-mobility transistors are critical for next-generation power electronics and radio-frequency applications, yet achieving stable enhancement-mode operation with a high threshold voltage remains a key challenge. In this work, we designed p-AlGaN superlattices with different structures and performed energy band structure simulations using the device simulation software Silvaco. The results demonstrate that thin barrier structures lead to reduced acceptor incorporation, thereby decreasing the number of ionized acceptors, while facilitating vertical hole transport. Superlattice samples with varying periodic thicknesses were grown via metal-organic chemical vapor deposition, and their crystalline quality and electrical properties were characterized. The findings reveal that although gradient-thickness barriers contribute to enhancing hole concentration, the presence of thick barrier layers restricts hole tunneling and induces stronger scattering, ultimately increasing resistivity. In addition, we simulated the structure of the enhancement-mode HEMT with p-AlGaN as the under-gate material. Analysis of its energy band structure and channel carrier concentration indicates that adopting p-AlGaN superlattices as the under-gate material facilitates achieving a higher threshold voltage in enhancement-mode HEMT devices, which is crucial for improving device reliability and reducing power loss in practical applications such as electric vehicles. Full article
(This article belongs to the Special Issue III–V Compound Semiconductors and Devices, 2nd Edition)
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13 pages, 4956 KiB  
Article
The Influence of Crystal Anisotropy in Femtosecond Laser Processing of Single-Crystal Diamond
by Guolong Wang, Ji Wang, Kaijie Cheng, Kun Yang, Bojie Xu, Wenbo Wang and Wenwu Zhang
Nanomaterials 2025, 15(15), 1160; https://doi.org/10.3390/nano15151160 - 28 Jul 2025
Viewed by 283
Abstract
The single-crystal diamond (SCD), owing to its extreme physical and chemical properties, serves as an ideal substrate for quantum sensing and high-frequency devices. However, crystal anisotropy imposes significant challenges on fabricating high-quality micro-nano structures, directly impacting device performance. This work investigates the effects [...] Read more.
The single-crystal diamond (SCD), owing to its extreme physical and chemical properties, serves as an ideal substrate for quantum sensing and high-frequency devices. However, crystal anisotropy imposes significant challenges on fabricating high-quality micro-nano structures, directly impacting device performance. This work investigates the effects of femtosecond laser processing on the SCD under two distinct crystallographic orientations via single-pulse ablation. The results reveal that ablation craters along the <100> orientation exhibit an elliptical shape with the major axis parallel to the laser polarization, whereas those along the <110> orientation form near-circular craters with the major axis at a 45° angle to the polarization. The single-pulse ablation threshold of the SCD along <110> is 9.56 J/cm2, representing a 7.8% decrease compared to 10.32 J/cm2 for <100>. The graphitization threshold shows a more pronounced reduction, dropping from 4.79 J/cm2 to 3.31 J/cm2 (31% decrease), accompanied by enhanced sp2 carbon order evidenced by the significantly intensified G-band in the Raman spectra. In addition, a phase transition layer of amorphous carbon at the nanoscale in the surface layer (thickness of ~40 nm) and a narrow lattice spacing of 0.36 nm are observed under TEM, corresponding to the interlayer (002) plane of graphite. These observations are attributed to the orientation-dependent energy deposition efficiency. Based on these findings, an optimized crystallographic orientation selection strategy for femtosecond laser processing is proposed to improve the quality of functional micro-nano structures in the SCD. Full article
(This article belongs to the Special Issue Trends and Prospects in Laser Nanofabrication)
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17 pages, 2625 KiB  
Article
Monitoring and Diagnostics of Non-Thermal Plasmas in the Food Sector Using Optical Emission Spectroscopy
by Sanda Pleslić and Franko Katalenić
Appl. Sci. 2025, 15(15), 8325; https://doi.org/10.3390/app15158325 - 26 Jul 2025
Viewed by 108
Abstract
Non-thermal plasma technology is used in the food sector due to its many advantages such as low operating costs, fast and efficient processing at low temperatures, minimal environmental impact, and preservation of sensory and nutritional properties. In this article, the plasma was generated [...] Read more.
Non-thermal plasma technology is used in the food sector due to its many advantages such as low operating costs, fast and efficient processing at low temperatures, minimal environmental impact, and preservation of sensory and nutritional properties. In this article, the plasma was generated using a high-voltage electrical discharge (HVED) with argon at a voltage of 35 kV and a frequency of 60 Hz. Plasma monitoring and diagnostics were performed using optical emission spectroscopy (OES) to optimise the process parameters and for quality control. OES was used as a non-invasive sensor to collect useful information about the properties of the plasma and to identify excited species. The values obtained for electron temperature and electron density (up to 2.3 eV and up to 1023 m3) confirmed that the generated plasma is a non-thermal plasma. Therefore, the use of OES is recommended in the daily control of food processing, as this is necessary to confirm that the processes are non-thermal and suitable for the food sector. Full article
(This article belongs to the Special Issue Innovative Technology in Food Analysis and Processing)
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26 pages, 10667 KiB  
Article
Influence of Nitrogen and Hydrogen Addition on Composition, Morphology, Adhesion, and Wear Resistance of Amorphous Carbon Coatings Produced by RFCVD Method on Surface-Hardened Ultra-Fine Grained Bainitic 30HGSNA Steel
by Karol Wunsch, Tomasz Borowski, Emilia Skołek, Agata Roguska, Rafał Chodun, Michał Urbańczyk, Krzysztof Kulikowski, Maciej Spychalski, Andrzej Wieczorek and Jerzy Robert Sobiecki
Coatings 2025, 15(8), 877; https://doi.org/10.3390/coatings15080877 - 26 Jul 2025
Viewed by 303
Abstract
Ultra-fine-grained bainitic (UFGB) steels offer excellent mechanical properties, which can be further improved by applying diamond-like carbon (DLC) coatings. However, poor adhesion between the coating and substrate remains a key limitation. Since the steel’s microstructure degrades at high temperatures, enhancing adhesion without heating [...] Read more.
Ultra-fine-grained bainitic (UFGB) steels offer excellent mechanical properties, which can be further improved by applying diamond-like carbon (DLC) coatings. However, poor adhesion between the coating and substrate remains a key limitation. Since the steel’s microstructure degrades at high temperatures, enhancing adhesion without heating the substrate is essential. This study investigates surface hardening combined with simultaneous nitrogen and hydrogen doping during the Radio Frequency Chemical Vapor Deposition (RFCVD) process to improve coating performance. Varying gas compositions were tested to assess their effects on coating properties. Nitrogen incorporation decreased hardness from 12 GPa to 9 GPa but improved adhesion, while hydrogen limited damage after coating failure. Optimizing the gas mixture led to enhanced adhesion and wear resistance. Raman and X-ray photoelectron spectroscopy (XPS) analyses confirmed that the optimized coatings had the highest sp3 bond content and elevated nitrogen levels. While both hardness and adhesion contributed to wear resistance, no direct link to coating thickness was found. Overall, co-doping with nitrogen and hydrogen is an effective approach to improve adhesion and wear resistance without requiring high processing temperatures or complex equipment. Full article
(This article belongs to the Special Issue Recent Advances in Surface Functionalisation, 2nd Edition)
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24 pages, 4281 KiB  
Article
Free Vibration Characteristics of FG-CNTRC Conical–Cylindrical Combined Shells Resting on Elastic Foundations Using the Haar Wavelet Discretization Method
by Jianyu Fan, Haoran Zhang, Yongqiang Tu, Shaohui Yang, Yan Huang, Zhichang Du and Hakim Boudaoud
Polymers 2025, 17(15), 2035; https://doi.org/10.3390/polym17152035 - 25 Jul 2025
Viewed by 203
Abstract
Functionally graded carbon nanotube reinforced composites (FG-CNTRCs) are a novel breed of polymer nanocomposite, in which the nonuniform distribution of the carbon nanotube (CNT) reinforcement is adopted to maximize the macro-mechanical performance of the polymer with a lower content of CNTs. Composite conical–cylindrical [...] Read more.
Functionally graded carbon nanotube reinforced composites (FG-CNTRCs) are a novel breed of polymer nanocomposite, in which the nonuniform distribution of the carbon nanotube (CNT) reinforcement is adopted to maximize the macro-mechanical performance of the polymer with a lower content of CNTs. Composite conical–cylindrical combined shells (CCCSs) are widely utilized as loading-bearing components in various engineering applications, and a comprehensive understanding of the vibration characteristics of these shells under different external excitations and boundary conditions is crucial for engineering applications. In this study, the free vibration behaviors of FG-CNTRC CCCSs supported by an elastic foundation are examined using the Haar wavelet discretization method (HWDM). First, by means of the HWDM, the equations of motion of each shell segment, the continuity and boundary conditions are converted into a system of algebraic equations. Subsequently, the natural frequencies and modes of the CCCSs are achieved by calculating the resultant algebraic equations. The convergence and accuracy are evaluated, and the results demonstrate that the proposed method has stable convergence, high efficiency, and excellent accuracy. Furthermore, an exhaustive parametric investigation is conducted to reveal the effects of foundation stiffnesses, boundary conditions, material mechanical properties, and geometric parameters on the vibration characteristics of the FG-CNTRC CCCS. Full article
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19 pages, 1307 KiB  
Article
Three-Dimensional Non-Stationary MIMO Channel Modeling for UAV-Based Terahertz Wireless Communication Systems
by Kai Zhang, Yongjun Li, Xiang Wang, Zhaohui Yang, Fenglei Zhang, Ke Wang, Zhe Zhao and Yun Wang
Entropy 2025, 27(8), 788; https://doi.org/10.3390/e27080788 - 25 Jul 2025
Viewed by 174
Abstract
Terahertz (THz) wireless communications can support ultra-high data rates and secure wireless links with miniaturized devices for unmanned aerial vehicle (UAV) communications. In this paper, a three-dimensional (3D) non-stationary geometry-based stochastic channel model (GSCM) is proposed for multiple-input multiple-output (MIMO) communication links between [...] Read more.
Terahertz (THz) wireless communications can support ultra-high data rates and secure wireless links with miniaturized devices for unmanned aerial vehicle (UAV) communications. In this paper, a three-dimensional (3D) non-stationary geometry-based stochastic channel model (GSCM) is proposed for multiple-input multiple-output (MIMO) communication links between the UAVs in the THz band. The proposed channel model considers not only the 3D scattering and reflection scenarios (i.e., reflection and scattering fading) but also the atmospheric molecule absorption attenuation, arbitrary 3D trajectory, and antenna arrays of both terminals. In addition, the statistical properties of the proposed GSCM (i.e., the time auto-correlation function (T-ACF), space cross-correlation function (S-CCF), and Doppler power spectrum density (DPSD)) are derived and analyzed under several important UAV-related parameters and different carrier frequencies, including millimeter wave (mmWave) and THz bands. Finally, the good agreement between the simulated results and corresponding theoretical ones demonstrates the correctness of the proposed GSCM, and some useful observations are provided for the system design and performance evaluation of UAV-based air-to-air (A2A) THz-MIMO wireless communications. Full article
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17 pages, 1441 KiB  
Article
The Relaxation Behavior of Water Confined in AOT-Based Reverse Micelles Under Temperature-Induced Clustering
by Ivan V. Lunev, Alexander N. Turanov, Mariya A. Klimovitskaya, Artur A. Galiullin, Olga S. Zueva and Yuriy F. Zuev
Int. J. Mol. Sci. 2025, 26(15), 7152; https://doi.org/10.3390/ijms26157152 - 24 Jul 2025
Viewed by 245
Abstract
Relaxation behavior of water confined in reverse micelles under temperature-induced micelle clustering is undertaken using broadband dielectric spectroscopy in frequency range 1 Hz–20 GHz. All microemulsion systems with sufficiently noticeable micelle water pool (water/surfactant molar ratio W > 10) depict three relaxation processes, [...] Read more.
Relaxation behavior of water confined in reverse micelles under temperature-induced micelle clustering is undertaken using broadband dielectric spectroscopy in frequency range 1 Hz–20 GHz. All microemulsion systems with sufficiently noticeable micelle water pool (water/surfactant molar ratio W > 10) depict three relaxation processes, in low, high and microwave frequencies, anchoring with relaxation of shell (bound) water, orientation of surfactant anions at water-surfactant interface and relaxation of bulk water confined in reverse micelles. The analysis of dielectric relaxation processes in AOT-based w/o microemulsions under temperature induced clustering of reverse micelles were made according to structural information obtained in NMR and conductometry experiments. The “wait and switch” relaxation mechanism was applied for the explanation of results for water in the bound and bulk states under spatial limitation in reverse micelles. It was shown that surfactant layer predominantly influences the bound water. The properties of water close to AOT interface are determined by strong interactions between water and ionic AOT molecules, which perturb water H-bonding network. The decrease in micelle size causes a weakening of hydrogen bonds, deformation of its steric network and reduction in co-operative relaxation effects. Full article
(This article belongs to the Section Molecular Informatics)
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32 pages, 4464 KiB  
Review
Multifunctional Polyimide for Packaging and Thermal Management of Electronics: Design, Synthesis, Molecular Structure, and Composite Engineering
by Xi Chen, Xin Fu, Zhansheng Chen, Zaiteng Zhai, Hongkang Miu and Peng Tao
Nanomaterials 2025, 15(15), 1148; https://doi.org/10.3390/nano15151148 - 24 Jul 2025
Viewed by 442
Abstract
Polyimide, a class of high-performance polymers, is renowned for its exceptional thermal stability, mechanical strength, and chemical resistance. However, in the context of high-integration and high-frequency electronic packaging, polyimides face critical challenges including relatively high dielectric constants, inadequate thermal conductivity, and mechanical brittleness. [...] Read more.
Polyimide, a class of high-performance polymers, is renowned for its exceptional thermal stability, mechanical strength, and chemical resistance. However, in the context of high-integration and high-frequency electronic packaging, polyimides face critical challenges including relatively high dielectric constants, inadequate thermal conductivity, and mechanical brittleness. Recent advances have focused on molecular design and composite engineering strategies to address these limitations. This review first summarizes the intrinsic properties of polyimides, followed by a systematic discussion of chemical synthesis, surface modification approaches, molecular design principles, and composite fabrication methods. We comprehensively examine both conventional polymerization synthetic routes and emerging techniques such as microwave-assisted thermal imidization and chemical vapor deposition. Special emphasis is placed on porous structure engineering via solid-template and liquid-template methods. Three key modification strategies are highlighted: (1) surface modifications for enhanced hydrophobicity, chemical stability, and tribological properties; (2) molecular design for optimized dielectric performance and thermal stability; and (3) composite engineering for developing high-thermal-conductivity materials with improved mechanical strength and electromagnetic interference (EMI) shielding capabilities. The dielectric constant of polyimide is reduced while chemical stability and wear resistance can be enhanced through the introduction of fluorine groups. Ultra-low dielectric constant and high-temperature resistance can be achieved by employing rigid monomers and porous structures. Furthermore, the incorporation of fillers such as graphene and boron nitride can endow the composite materials with high thermal conductivity, excellent EMI shielding efficiency, and improved mechanical properties. Finally, we discuss representative applications of polyimide and composites in electronic device packaging, EMI shielding, and thermal management systems, providing insights into future development directions. Full article
(This article belongs to the Special Issue Functional and Structural Properties of Polymeric Nanocomposites)
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