Search Results (11)

Based on the medium-pressure natural gas ethane recovery and helium extraction process, this paper proposes three different refrigerant Schemes. Thermodynamic analysis and adaptability evaluation of the three Schemes were conducted using Aspen HYSYS V12 software. The ethylene–propane cascade refrigeration Scheme demonstrated superior energy efficiency in terms of comprehensive energy consumption, heat exchange performance in the cryogenic cold box, and exergy analysis. Adaptability analysis indicated that this Scheme exhibits strong tolerance to variations in feed gas temperature as well as N₂ and CO₂ content. The ethylene–propane cascade refrigeration process demonstrates significant energy-saving advantages and exhibits robust operational performance. Full article

Hydrate-based gas separation (HBGS) is a new method for extracting helium from helium-rich natural gas (HNG). The ethane in HNG affects the thermodynamic equilibrium hydrate formation pressure (Peq), and Peq is crucial to the application of HBGS for extracting helium. In this work, the Peq of the HNGs with different ethane contents (0.5 mol%, 1.0 mol%, and 10 mol%) and the solutions with different tetrahydrofuran (THF) contents (5 wt%, 10 wt%, and 19 mol%) at different temperatures were experimentally investigated through the isothermal pressure search method. Ethane and THF have a competitive effect on hydrate formation. A new thermodynamic model was proposed to predict the Peq of different HNG–THF solution systems. The effect of ethane on Peq can be quantitatively described, and the Peq of HNGs can be accurately predicted by the model in this work. The average relative deviation of the model for predicting Peq of HNGs in different THF aqueous solution systems is less than 3%. The results of this study can guide the operating conditions for the optimization of extracting helium from HNGs by the HBGS process. Full article

The investment estimation of the helium extraction project from natural gas is a crucial step in economically obtaining helium from both domestic and international projects. This article employs Aspen HYSYS to simulate the process and estimate the investment levels of Linde and Exxon Mobil integrated helium extraction processes. We investigate the influence of feed composition and processing capacity on investment costs and product returns. The results indicate that higher helium content of feed correlates with increased equipment investment costs and total capital cost (CAPEX), and that the Linde integrated process is significantly more sensitive to changes in helium content of feed than the Exxon Mobil integrated process. As the helium content of feed rises, the product returns of the two processes are evidently improved, leading to reduced investment payback periods. Both techniques exhibit favorable payback periods when the feed helium content exceeds 0.5 vol%. Nevertheless, elevated nitrogen content in the feed notably escalates the equipment investment costs and total capital costs. Furthermore, an increase in the processing capacity of feed gas leads to a nonlinear increase in total capital costs and annual operating costs. However, the cost per unit of helium extraction diminishes with increasing capacity. In general, the Linde integrated process requires higher separation energy consumption in comparison with the Exxon Mobil integrated process at similar processing capacities. Moreover, the sensitivity analysis shows that helium breakeven price is strongly affected by the price of both LNG and feed gas. Full article

Helium is an irreplaceable ore resource for many applications, such as nuclear magnetic resonance, aviation, semiconductors, and nuclear energy. Extracting helium in a free state from natural gas is currently the only economical approach at the industrial level. In this study, we compiled geochemical data of 719 natural gas samples from 36 oil and gas fields in the Tarim basin that include experimental results and previously reported data. Helium is of primarily crustal origin in the Tarim Basin according to helium isotope characteristics (not exceeding 0.1 Ra), except in the Ake gas field that has not more than 7% of mantle helium. Helium concentrations in diverse tectonic units vary considerably. Oil-type gas, on the whole, has a higher helium concentration relative to coal-type gas. Abundant helium flux, a favorable fault system between the source-reservoir system, no strong charging of gaseous hydrocarbons, and the good sealing capacity are important factors that control the formation of helium-rich gas fields. Considering both the helium concentration and natural gas reserves, helium-rich gas fields located in the Southwest Depression and Tabei Uplift can be regarded as the major favorable zones of further deployment for helium extraction. Full article

Integrated geo- and environmental monitoring in mining represents a high-dimensional challenge (location, altitude/depth, time and sensors). This is challenging for experts but poses great problems for a multitude of participants and stakeholders in building up a complete process understanding. The Epe research cooperation aims to elucidate the ground movement at the Epe cavern storage facility with a public participation process. The research cooperation was founded by the city of Gronau, the citizens’ initiative cavern field Epe, the company EFTAS, Münster, and the Research Center of Post-Mining at the Technische Hochschule Georg Agricola, Bochum. This research cooperation is the first in Germany to involve direct collaboration between science and the public. In the cavern field, which has been in operation since the 1970s, brine is extracted, and at the same time natural gas, crude oil and helium, as well as hydrogen in the future, are stored in the subsurface. The technical focus of this work was the development of a high-resolution spatiotemporal analysis of ground movements. The area is monitored annually by the mining company’s mine surveyor. The complexity of the monitoring issue lies in the fact that the western part is a bog area and a former bog area. Furthermore, the soils in the eastern part are very humus-rich and show strong fluctuations in the groundwater and therefore complex hydraulic conditions. At the same time, there are few fixed scatterers or prominent points in the area that allow high-resolution spatiotemporal monitoring using simple radar interferometry methods. Therefore, the SBAS method (Small Baseline Subset), which is based on an aerial method, was used to analyze the radar interferometric datasets. Using an SBAS analysis, it was possible to evaluate a time series of 760 scenes over the period from 2015 to 2023. The results were integrated with the mine survey maps on the ground movement and other open geodata on the surface, the soil layers and the overburden. The results show complex forms of ground movement. The main influence is that of mining. Nevertheless, the influence of organic soils with drying out due to drought years and uplift in wet years is great. Thus, in dry years, ground subsidence accelerates, and in wet years, ground subsidence not only slows down but in some cases also causes uplift. This complexity of ground movements and the necessary understanding of the processes involved has been communicated to the interested public at several public information events as part of the research cooperation. In this way, an understanding of the mining process was built up, and transparency was created in the subsurface use, also as a part of the energy transition. In technical terms, the research cooperation also provides a workflow for developing the annual mine survey maps into an integrated geo- and environmental monitoring system with the development of a transparent participatory geomonitoring process to provide resilience management to a mining location. Full article

The unconventional tight oil and gas resources in the Xinzhao East belt of the Hangjinqi Prospect area in the Ordos Basin of China are abundant. However, the reservoir’s internal storage space is complex, and the microscopic pore throat structural features are not well recognized, which has led to some trouble in the deployment of oil and gas exploration. To reveal the microscopic characteristics of the dense sandstone gas layer in the first member of the Lower Stone Box Formation of the D-well Zone in the Xinzhao East belt of the Hangjinqi Prospect area, a three-dimensional space digital core was built, and the stored set spatial data were extracted, based on rock sheet and coring data and X-CT scanning technology. Quartz grain size was segmented and analyzed based on an adaptive approach. The microscopic characteristics of the gas layer in the studied section and the factors influencing its development were studied, combining the use of a field emission scanning electron microscope, helium porosimeter, and gas permeability meter. We found that in the studied section, the porosity is relatively high, the pore throat size is large, and the pore permeability correlation is good. The reservoir space, which consists of intergranular pores, intragranular pores, and microcracks at the grain edges in the study area, is characterized by a complex distribution pattern. Within the gas layer, isolated pores are connected by microcracks to form a network of reservoir spaces, which increases the pore throat size, enhances the connectivity of the pore throat, and makes the microscopic characteristics of the reservoir space better. The first member of the Lower Stone Box Formation could be an advantageous reservoir. Hole–throat connectivity is poor because of the gas layer having underdeveloped primary pores, the blockage of pores by unstable minerals (kaolinite, etc.), and poorly connected pore throats based on insoluble mud cementation. The high content of quartz brittle minerals and the development of natural microcracks within the gas formation are favorable conditions for fracking development. The quartz grain size within the gas layer is positively correlated with the pore throat size, which suggests that the quartz grain size somewhat influences the microscopic characteristics of the reservoir space. This comprehensive study shows that the methodology of the study is more advantageous than traditional methods in the fine and three-dimensional spatial characterization of the microstructure of dense sandstone reservoirs. The research results of this paper have certain guiding significance for further reservoir evaluation and advantageous reservoir prediction in the Hangjinqi Prospect area in the Ordos Basin. We also provide the basis for the subsequent efficient development of the gas reservoir. Full article

In view of potential uses in short-term thermochemical heat storage by sorption of water vapor, the capacity to release a sufficient heat amount at the appropriate rate of a Prussian blue analogue (PBA) containing hexacyanocobaltate vacancies has been compared with those of 13X type zeolites possessing Na⁺, Ce³⁺, Ce⁴⁺, or Tb³⁺ extra-framework compensating cations. The extended structural and surface characterization demonstrated good reproducibility of the preparation procedures performed on a 10-g scale. The adsorbents were tested under dynamic conditions of gas flow with the aid of either a gas flow calorimeter (120 mL h⁻¹ helium flow) to measure the amount and rate of the integral heat release or a laboratory-scale test rig (15,000 to 22,800 mL h⁻¹ nitrogen flow) to monitor the outlet temperature of nitrogen heated by adsorption. For a regeneration temperature of 353 K and a partial H₂O pressure of 2.8 kPa in helium, the PBA sample yielded an integral heat ranging between 900 and 1020 kJ kg⁻¹ with a very slow heat release lasting for even 12–14 h. The zeolite-based materials generated between 350 and 950 kJ kg⁻¹ more rapidly (up to 6–7 h), depending on the nature and the content of compensating cations, as well as on the dehydration state achieved during regeneration. With the laboratory-scale test rig, the efficiency of heat extraction by convection was about 65% for Na-13X and only 38% for PBA, and it diminished with decreasing flow rate. Full article

Helium is the second most abundant element in the Universe after hydrogen. Considerable resources of helium-3 isotope (He3) are located mostly outside the Earth. He3 is very important for science and industry, especially for airport neutron detectors, lung tomography and helium dilution refrigerators. Besides, global warming is forcing the industry and governments to search for alternative energy sources, and He3 has the potential to be used as fuel in future nuclear fusion power plants. Unfortunately, the price of gaseous He3 has recently increased from $200 per liter to over $2750. The expected further increase in price and demands led us to present an analysis of the economic profitability for He3 separation process, which utilizes the properties of superfluid helium. This paper shows the arguments supporting the idea that extraction from natural sources is the only economically viable way of obtaining He3 isotope nowadays. The method could be relatively easily implemented into the production cycles of the low temperature natural gas purification plant. Full article

The occurrence of hydrocarbon gases (HCG) in unusually high concentrations for magmatic complexes, in the Lovozero and some other alkaline massifs, is of both geochemical and practical interest. The nature of these gases, despite the long history of research, remains the subject of debate. As an approach to solving this problem, we studied the coupled distribution of occluded HCG and the recognized tracers of various geological processes, such as helium and argon isotopes. The extraction of the gas components trapped in fluid micro-inclusions was carried out by the mechanical crushing of rock and mineral samples. A positive correlation was found between the ³He/⁴He and CH₄/C₂H₆ ratios, whereas a negative correlation of the latter was found with the ³⁶Ar concentration, which in turn was directly related, in varying degrees, to the content of HCG and most strongly with pentanes. Conjugacy of the processes of the heavier gaseous hydrocarbons, a loss of the deep component of the fluid phase and dilution of it with the atmogenic component was established. In the absence of a correlation between CH₄ and ³He, the value of the CH₄/³He ratio in the Lovozero gas substantially exceeded the estimates of it in gases of a mantle origin, and mainly corresponded to the crustal values. However, in some samples, a small fraction of mantle methane was allowed. The peculiarities of the relationships between hydrocarbon gases and the isotopes of noble gases indicate a sequential process of abiogenic generation and transformation of HCG at the magmatic and post-magmatic stages during the formation of the Lovozero massif. The obtained results confirm the usefulness of this approach in solving the origin of reduced gases in alkaline igneous systems. Full article

The aim of the study was to evaluate the chemical composition of crushed, extracted human teeth and the quantity of biomaterial that can be obtained from this process. A total of 100 human teeth, extracted due to trauma, decay, or periodontal disease, were analyzed. After extraction, all the teeth were classified, measured, and weighed on a microscale. The human teeth were crushed immediately using the Smart Dentin Grinder machine (KometaBio Inc., Cresskill, NJ, USA), a device specially designed for this procedure. The human tooth particles obtained were of 300–1200 microns, obtained by sieving through a special sorting filter, which divided the material into two compartments. The crushed teeth were weighed on a microscale, and scanning electron microscopy (SEM) evaluation was performed. After processing, 0.25 gr of human teeth produced 1.0 cc of biomaterial. Significant differences in tooth weight were found between the first and second upper molars compared with the lower molars. The chemical composition of the particulate was clearly similar to natural bone. Scanning electron microscopy–energy dispersive X-ray (SEM–EDX) analysis of the tooth particles obtained mean results of Ca% 23.42 ± 0.34 and P% 9.51 ± 0.11. Pore size distribution curves expressed the interparticle pore range as one small peak at 0.0053 µm. This result is in accordance with helium gas pycnometer findings; the augmented porosity corresponded to interparticle spaces and only 2.533% corresponded to intraparticle porosity. Autogenous tooth particulate biomaterial made from human extracted teeth may be considered a potential material for bone regeneration due to its chemical composition and the quantity obtained. After grinding the teeth, the resulting material increases in quantity by up to three times its original volume, such that two extracted mandibular lateral incisors teeth will provide a sufficient amount of material to fill four empty mandibular alveoli. The tooth particles present intra and extra pores up to 44.48% after pycnometer evaluation in order to increase the blood supply and support slow resorption of the grafted material, which supports healing and replacement resorption to achieve lamellar bone. After SEM–EDX evaluation, it appears that calcium and phosphates are still present within the collagen components even after the particle cleaning procedures that are conducted before use. Full article

Membrane separation for helium extraction from natural gas gained increased interest recently. Several vendors offer membrane elements for helium extraction, although data on their performance and operating experience are unpublished. The aim of this work was to obtain and study the separation performance of asymmetric hollow-fiber membrane element from commercial polyamide-imide Torlon^®, in conditions close to the industrial process of helium extraction from natural gas. A membrane element with an active area of 0.177 m², a helium permeance of 100 l(STP)/(m²·h·bar), and a selectivity α(He/CH₄) = 340 was produced. This corresponds to a selective layer thickness of 82.3 nm, which was confirmed by SEM and resistance model calculations. The obtained membrane element was employed to decrease the concentration of helium in its binary mixture with methane from 0.4% to 0.05%. A relationship of separation characteristics from transmembrane pressure is also presented. At 70 bar and a stage cut of 2.7%, the feed flow rate was 0.16 m³(STP)/h, which yielded a helium permeate concentration of 14.7%. At 80 bar, a decrease in permeance to 60 l(STP)/(m²·h·bar) and in selectivity to 240 was observed. It was shown that the main reason for aging was the increased support resistance, due to a partial compaction of pores with a radius of less than 15 nm. Full article