Search Results (29)

Fire-resistant coatings have emerged as crucial materials for reducing fire hazards in various industries, including construction, textiles, electronics, and aerospace. This review provides a comprehensive account of recent advances in fire-resistant coatings, emphasizing environmentally friendly and high-performance systems. Beginning with a classification of traditional halogenated and non-halogenated flame retardants (FRs), this article progresses to cover nitrogen-, phosphorus-, and hybrid-based systems. The synthesis methods, structure–property relationships, and fire suppression mechanisms are critically discussed. A particular focus is placed on bio-based and waterborne formulations that align with green chemistry principles, such as tannic acid (TA), phytic acid (PA), lignin, and deep eutectic solvents (DESs). Furthermore, the integration of nanomaterials and smart functionalities into fire-resistant coatings has demonstrated promising improvements in thermal stability, char formation, and smoke suppression. Applications in real-world contexts, ranging from wood and textiles to electronics and automotive interiors, highlight the commercial relevance of these developments. This review also addresses current challenges such as long-term durability, environmental impacts, and the standardization of performance testing. Ultimately, this article offers a roadmap for developing safer, sustainable, and multifunctional fire-resistant coatings for future materials engineering. Full article

With the increasing urgency of petroleum resource scarcity and environmental challenges, the development of degradable bio-based flame retardants has become crucial for enhancing the fire safety of organic materials. In this work, a phosphorus-containing chitosan derivative (CS-PPOA) was synthesized via a one-step protonation reaction between chitosan (CS) and phenylphosphinic acid (PPOA) under mild conditions. The resulting multifunctional flame-retardant coating was applied to polyester (PET) fabrics. Comprehensive characterization using FT-IR, XPS, and NMR confirmed the successful protonation of chitosan amino groups through electrostatic interactions, forming a stable ionic complex. The CS-PPOA solution exhibited excellent rheological properties and film-forming ability, producing films with over 80% optical transmittance and flexibility. Thermogravimetric analysis (TGA) revealed that CS-PPOA achieved char residue yields of 76.8% and 40.2% under nitrogen and air atmospheres, respectively, significantly surpassing those of acetic acid-protonated chitosan (CS-HAc). The limiting oxygen index (LOI) of CS-PPOA increased to 48.3%, and vertical burning tests demonstrated rapid self-extinguishing behavior. When applied to PET fabrics at a 15% loading, the LOI value improved from 20.3% (untreated fabric) to 27.8%, forming a dense char layer during combustion while completely suppressing melt dripping. Additionally, the coated fabric exhibited broad-spectrum antibacterial activity, achieving a 99.99% inhibition rate against Escherichia coli and Staphylococcus aureus. This study provides a novel strategy for the green and efficient preparation of multifunctional bio-based flame-retardant coatings. Full article

A simple and innovative method was introduced for the production of green and recoverable flame-retardant cotton fabrics, where sulfonated cotton fabric (COT-SC) was synthesized by oxidizing cotton fabric with sodium periodate, followed by a sulfonation step with sodium bisulfite to provide active sites, which further chelated barium ions (Ba²⁺) to achieve flame retardancy. The morphological and structural characterizations of the fabricated cotton fabrics (COT-SC-Ba) demonstrated that the cleavage of C₂-C₃ free hydroxy groups within the cellulose macromolecule was chemically modified for grafting a considerable number of sulfonic acid groups, and Ba²⁺ ions were effectively immobilized on the macromolecule of the cotton fabric through a chelation effect. Results from cone calorimeter tests (CCTs) revealed that COT-SC-Ba became nonflammable, displayed a delayed ignition time, and decreased the values of the heat release rate (HRR), total smoke release (TSR), effective heat of combustion (EHC), and CO/CO₂ ratio. TG/DTG analysis demonstrated that COT-SC-Ba possessed greater thermal stability, fewer flammable volatiles, and more of a char layer during burning than that of the original cotton fabric. Its residual mass was increased from 0.02% to 26.9% in air and from 8.05% to 26.76% in N₂, respectively. The COT-SC-Ba not only possessed a limiting oxygen index (LOI) of up to 34.4% but could also undergo vertical burning tests evidenced by results such as the non-afterflame, non-afterglow, and a mere 75 mm char length. Those results demonstrated that the combination of SO₃⁻ and Ba²⁺ promoted the formation of a char layer. Moreover, cotton fabric regained its superior flame retardancy after being washed and re-chelated with Ba²⁺. Additional characteristics of the cotton fabric, such as the rupture strength, white degree, and hygroscopicity, were maintained at an acceptable level. In conclusion, this research can offer a fresh perspective on the design and development of straightforward, efficient, eco-friendly, and recoverable fire-retardant fabrics. Full article

Mine fires have always been one of the disasters that restrict coal mining in China and endanger the life safety of underground workers. The research and development of new fire prevention materials are undoubtedly important to ensure the safe and efficient production of modern mines. At present, the main inhibiting materials used are grout material, inert gas, retarding agent, foam, gel, and so on. In order to explore the current situation of coal spontaneous combustion (CSC) fire prevention, the existing fire prevention materials were reviewed and prospected from three aspects: physical, chemical, and physicochemical inhibition. The results show that, at present, most of the methods of physicochemical inhibition are used to inhibit CSC. Antioxidants have become popular chemical inhibitors in recent years. In terms of physical inhibition, emerging biomass-based green materials, including foams, gels, and gel foams, are used to inhibit CSC. In addition, CSC fire-fighting materials also have shortcomings, including incomplete research on the mechanism of material action, poor stability of inhibitory properties, low efficiency, and economic and environmental protection to be improved. The future research direction of fire-fighting materials will be based on theoretical experiments and numerical simulation to study the mechanism and characteristics of CSC and develop new directional suppression materials with physicochemical synergies. These findings have extremely important implications for improving materials designed to prevent CSC. Full article

This article investigates the effects of combining a novel protic ionic liquid-based fire retardant (FR) with alkalized hemp fiber. A pivotal importance of this study refers to the hydrophilic properties and limits regarding poor thermal resistance of green composites where standard guidelines for fire risks are crucial. Although it is well-studied that alkalization is essential for green composite’s moisture and mechanical durability, research on the flammability of such a combined treatment for natural fiber-reinforced biopolymer composites is lacking. The alkaline treatment used in the current study follows a process already studied as optimal, particularly for the selected hemp fiber. The fire performance was examined using a bench scale approach based on self and piloted ignition from cone calorimeter tests. The result from the Fourier-transform infrared analysis of the hemp fiber confirms phosphorylation following the fire-retardant treatment, which was visible from the morphological examination with scanning electron microscope. The presence of FR in the composites led to impactful moisture sorption. However, the FR composites demonstrated an enhanced response to fire, indicating potential use as a Class B standard for building construction, and hazard level 3 (HL3) classification as an interior material in vehicles, provided the problem of high emission of smoke is mitigated. Full article

As a way to accommodate the rising demand for “green” wood-based products, agricultural waste from Areca (Areca catechu) nut farms, which is generally burned on-site, can be used to raise the value of alternative lignocellulosic raw materials. This research aimed to investigate and evaluate the effect of technical lignin (kraft lignin or lignosulfonate) addition on particleboard properties from areca bonded with ultra-low-emitting urea formaldehyde (UF) resin. The physical properties, mechanical properties, and fire resistance of the laboratory-made particleboards were tested and evaluated in accordance with the applicable Japanese industrial standards (JIS). The highest density of 0.84 g/cm³ was determined for the laboratory boards, bonded with an adhesive mixture of UF resin and kraft lignin with three washing treatments. The lowest moisture content of 9.06%, thickness swelling of 71.16%, and water absorption of 129.17% were determined for the boards bonded with lignosulfonate with three washing treatments, with commercial lignin, and with lignosulfonate with five washing treatments, respectively. The highest MOR and MOE values, i.e., 113.49 kg/cm² and 10,663 kg/cm², respectively, were obtained for the particleboards bonded with lignosulfonate with five washing treatments. Interestingly, all laboratory boards exhibited good fire resistance following the UL-94 standard. Based on the gas torch test, the lowest weight loss of 16.7% was determined in the boards fabricated with lignosulfonate with five washing treatments. This study demonstrated that adding lignin-based fire retardants represents a viable approach to producing lignocellulosic composites with enhanced fire resistance and a lower carbon footprint. Full article

Fire is a typical disaster in the processing industry. Ionic liquids, as a type of green flame retardant, play an important role in process safety. In order to grasp the current research status, hotspots, and frontiers in the field of ionic liquids in flame retardancy, the bibliometric mapping method is applied to study the relevant literature in Web of Science datasets from 2000–2022 in this paper. The results show that the research on ionic liquids in flame retardancy is multidisciplinary and involves some disciplines such as energy science, material science, and environmental protection. Journal of Power Sources, Polymer Degradation and Stability, ACS Applied Materials and Interfaces, and Chemical Engineering Journal are the core journals in the field. The results of keyword co-occurrence indicate that the hotspots of research can be divided into five components: the improvement and application of pure ionic liquids electrolytes, the research of gel polymer electrolytes, applying ionic liquids to enhance the polymer materials’ flame retardancy properties, utilizing ionic liquids and inorganic materials to synergize flame retardant polymers, and using ionic liquids flame retardant to improve material’s multiple properties. The burst terms and time zone diagram’s results point out the combination of computational quantum chemistry to study the flame retardancy mechanism of ionic liquids, the study of fluorinated electrolytes, ionic liquids for smoke suppression, phosphorus-containing ionic liquids for flame retardant, and machine learning-assisted design of ILs flame retardants are the research frontiers and future research trends. Full article

The development of different efficient flame retardants (FRs) to improve the fire safety of polymers has been a hot research topic. As the concept of green sustainability has gradually been raised to the attention of the whole world, it has even dominated the research direction of all walks of life. Therefore, there is an urgent calling to explore the green and simple preparation methods of FRs. The development of supramolecular chemistry in the field of flame retardancy is expanding gradually. It is worth noting that the synthesis of supramolecular flame retardants (SFRs) based on non-covalent bonds is in line with the current concepts of environmental protection and multi-functionality. This paper introduces the types of SFRs with different dimensions. SFRs were applied to typical polymers to improve their flame retardancy. The influence on mechanical properties and other material properties under the premise of flame retardancy was also summarized. Full article

With the aggravation of fire and smoke pollution, it is urgent to develop green, lower-cost and high-performance Foamed Wood–Plastic Composite (FWPC) to meet the standards of antistatic and flame retardant in practical application. Therefore, the flame retardant and antistatic FWPCs were prepared by compression molding in this study. High-density polyethylene (PE-HD) and Salix wood flour were used as main raw materials, and azodicarbonamide (AC) was used as foaming agent; Nano-carbon black (Nano-CB) was used as antistatic filler, and ammonium polyphosphate (APP) and zinc borate (ZB) were used as flame retardants. The static bending strength and elastic modulus of FWPC-20 were up to 30.01 MPa and 2636 MPa, respectively, which can meet the commercial application of wood–plastic decorative board. The logarithm of surface resistivity and volume resistivity of FWPC-20 was kept at eight, indicating that it has antistatic effect. The residual carbon rate of FWPC-20 increased to 38.58% at 800 °C, indicating that FWPC had high thermal stability. The minimum heat release rate of FWPC-20 was 226.75 kw/m², and the average heat release rate was 110.53 kw/m². The total heat release was 66.96 MJ/m², and the Limit Oxygen Index was 27.3%, which indicated that FWPC-20 had flame retardant and smoke suppression effects. This study provides a low-cost and simple method for the design of flame retardant, antistatic and high-performance FWPC, and has broad application prospects in the fields of packaging and construction. Full article

Because of incomplete recycling resource management and technology development, inorganic sludge and slag has been misused in Taiwan. The recycling of inorganic sludge and slag is a pressing crisis. Resource materials with a sustainable use value are misplaced and have a significant impact on society and the environment, which greatly reduces industrial competitiveness. To solve the dilemma of EAF oxidizing slag recycled from the steel-making process, it is important to find solutions to improve the stability of EAF oxidizing slags based on the innovative thinking of the circular economy. We can improve the value of recycling resources and solve the contradiction between economic development and environmental impact. The project team intends to investigate the development and application of reclaiming EAF oxidizing slags blended with fire-retardant materials, which will integrate R&D work from four different aspects. First, a verification mechanism is carried out to establish stainless steel furnace materials. Suppliers must be assisted in conducting quality management for EAF oxidizing slags to ensure the quality of the materials provided. Next, high-value building materials must be developed using slag stabilization technology, and fire-retardant tests must be conducted on the recycled building materials. A comprehensive evaluation and verification of the recycled building materials must be undertaken, and high-value green building materials must be produced with fire-retardant and sound-proofing characteristics. Integration with national standards and regulations can drive the market integration of high-value building materials and the industrial chain. On the other hand, the applicability of existing regulations to facilitate the legal use of EAF oxidizing slags will be explored. Full article

To meet modern society’s requirements for sustainability and environmental protection, innovative and smart surface coatings are continually being developed to improve or impart surface functional qualities and protective features. These needs regard numerous different sectors, such as cultural heritage, building, naval, automotive, environmental remediation and textiles. In this regard, researchers and nanotechnology are therefore mostly devoted to the development of new and smart nanostructured finishings and coatings featuring different implemented properties, such as anti-vegetative or antibacterial, hydrophobic, anti-stain, fire retardant, controlled release of drugs, detection of molecules and mechanical resistance. A variety of chemical synthesis techniques are usually employed to obtain novel nanostructured materials based on the use of an appropriate polymeric matrix in combination with either functional doping molecules or blended polymers, as well as multicomponent functional precursors and nanofillers. Further efforts are being made, as described in this review, to carry out green and eco-friendly synthetic protocols, such as sol–gel synthesis, starting from bio-based, natural or waste substances, in order to produce more sustainable (multi)functional hybrid or nanocomposite coatings, with a focus on their life cycle in accordance with the circular economy principles. Full article

In the flame retardancy of the biopolymer matrix and natural fibre reinforcement containing green composites, researchers face multiple challenges, such as low thermal stability, the candlewick effect of fibres and compatibility issues. Cellulosic fibres have been shown to have char-promoting properties and to advantageously interact with intumescent systems. In this work, melamine-polyphosphate was combined with neat or flame-retardant-treated cellulosic fibres differing in fibre length to obtain intumescent flame retarded poly(lactic acid) composites. The effect of the cellulose fibre length was evaluated in both forms. The structure-property relationships were evaluated by thermal and flammability test methods. It was found that the formation and the structure of the fire-protecting char are influenced by the length of the cellulose fibres, and thus it noticeably affects the effectiveness of the flame-retardant system. Cellulose fibres with an average length of 30–60 µm were found to contribute the best to the formation of an integrated fibrous-intumescent char structure with enhanced barrier characteristics. Full article

Wood-based materials are multifunctional green and environmentally friendly natural construction materials, and are widely used in decorative building materials. For this reason, a lot of research has been carried out to develop new and innovative wood surface improvements and make wood more appealing through features such as fire-retardancy, hydrophobicity, and antibacterial properties. To improve the performance of wood, more and more attention is being paid to the functioning of the surface. Understanding and mastering technology to improve the surface functionality of wood opens up new possibilities for developing multifunctional and high-performance materials. Examples of these techniques are ion crosslinking modification and coating modification. Researchers have been trying to make wooden surfaces more practical for the past century. This study has gradually gained popularity in the field of wood material science over the last 10 years. This paper provides an experimental reference for research on wood surface functionalization and summarizes the most current advancements in hydrophobic, antibacterial, and flame-retardant research on wood surfaces. Full article

Wood is widely used as a construction material due to its many advantages, such as good mechanical properties, low production costs, and renewability. However, its flammability limits its use in construction. To solve the problem of wood flammability, the most common method to improve the fire safety of wood is to modify the wood by deep impregnation or surface coating with flame retardants. Therefore, many researchers have found that environmentally friendly and low-cost biomass materials can be used as a source of green flame retardants. Two aspects of biomass-based intumescent flame retardants are summarized in this paper. On the one hand, biomass is used as one of the three sources or as a flame-retardant synergist in combination with other flame retardants, which are called composite biomass intumescent flame retardants. On the other hand, biomass is used alone as a feedstock to produce all-biomass intumescent flame retardants. In addition, the potential of biomass-based materials as an environmentally friendly and low-cost FR source to produce high-performance biomass-based flame retardants with improved technology was also discussed in detail. The development of biomass-based intumescent flame retardants represents a viable and promising approach for the efficient and environmentally friendly production of biomass-based flame retardants. Full article

Currently, polyurethane (PU) manufacturers seek green alternatives for sustainable production. In this work, sunflower oil is studied as a replacement and converted to a reactive form through epoxidation and oxirane opening to produce rigid PU foams. Confirmatory tests such as Fourier-transform infrared spectroscopy (FT-IR), gel permeation chromatography (GPC), and hydroxyl value among others were performed to characterize the synthesized polyol. Despite the versatility of rigid PU foams, they are highly flammable, which makes eco-friendly flame retardants (FRs) desired. Herein, expandable graphite (EG) and dimethyl methyl phosphonate (DMMP), both non-halogenated FR, were incorporated under different concentrations to prepare rigid PU foams. Their effects on the physio-mechanical and fire-quenching properties of the sunflower oil-based PU foams were elucidated. Thermogravimetric and compression analysis showed that these foams presented appreciable compressive strength along with good thermal stability. The closed-cell contents (CCC) were around 90% for the EG-containing foams and suffered a decrease at higher concentrations of DMMP to 72%. The burning test showed a decrease in the foam’s flammability as the neat foam had a burning time of 80 s whereas after the addition of 13.6 wt.% of EG and DMMP, separately, there was a decrease to 6 and 2 s, respectively. Hence, our research suggested that EG and DMMP could be a more viable alternative to halogen-based FR for PU foams. Additionally, the adoption of sunflower polyol yielded foams with results comparable to commercial ones. Full article