Search Results (23)

Flexible polymer-based piezoelectric nanogenerators (PENGs) have gained significant interest due to their ability to deliver clean and sustainable energy for self-powered electronics and wearable devices. Recently, the incorporation of fillers into the ferroelectric polymer matrix has been used to improve the relatively low piezoelectric properties of polymer-based PENGs. In this study, we investigated the effect of various nanofillers such as titania (TiO₂), zinc oxide (ZnO), reduced graphene oxide (rGO), and lead zirconate titanate (PZT) on the PENG performance of the nanocomposite thin films containing the nanofillers in poly(vinylidene fluoride-co-trifluoro ethylene) (P(VDF-TrFE)) matrix. The nanocomposite films were prepared by depositing molecularly thin films of P(VDF-TrFE) and nanofiller nanoparticles (NPs) spread at the air/water interface onto the indium tin oxide-coated polyethylene terephthalate (ITO-PET) substrate, and they were characterized by measuring their microstructures, crystallinity, β-phase contents, and piezoelectric coefficients (d₃₃) using SEM, FT-IR, XRD, and quasi-static meter, respectively. Multiple PENGs incorporating various nanofillers within the polymer matrix were developed by assembling thin film-coated substrates into a sandwich-like structure. Their piezoelectric properties, such as open-circuit output voltage (V_OC) and short-circuit current (I_SC), were analyzed. As a result, the PENG containing 4 wt% PZT, which was named P-PZT-4, showed the best performance of V_OC of 68.5 V with the d₃₃ value of 78.2 pC/N and β-phase content of 97%. The order of the maximum V_OC values for the PENGs of nanocomposite thin films containing various nanofillers was PZT (68.5 V) > rGO (64.0 V) > ZnO (50.9 V) > TiO₂ (48.1 V). When the best optimum PENG was integrated into a simple circuit comprising rectifiers and a capacitor, it demonstrated an excellent two-dimensional power density of 20.6 μW/cm² and an energy storage capacity of 531.4 μJ within 3 min. This piezoelectric performance of PENG with the optimized nanofiller type and content was found to be superior when it was compared with those in the literature. This PENG comprising nanocomposite thin film with optimized nanofiller type and content shows a potential application for a power source for low-powered electronics such as wearable devices. Full article

The hygrothermal deformation of nanocomposite piezoelectric plates containing internal pores lying on elastic foundations is illustrated in this paper by utilizing a novel quasi-3D plate theory (Q3DT). This nanocomposite plate has been strengthened by functionally graded graphene platelets (FG GPLs). For the purpose of identifying the FG porous materials, four alternative patterns of porosity distribution are employed, with the first pattern having a uniform distribution and the others having an uneven one. The material properties of the reinforced plate are estimated based on the Halpin–Tsai model. From the proposed theory and the virtual work principle, the basic differential equations are derived. The Levy method is used to convert the deduced partial differential equations to ordinary ones. The differential quadrature method (DQM) as a fast-converging method is utilized to solve these equations for various boundary conditions. The minimal number of grid points needed to obtain the converging solution is found by introducing a convergence study. After validating the obtained results with the studies of other researchers, this study’s findings are provided tabularly and graphically with numerous comprehensive discussions to examine the impact of the various factors of the proposed responding system. Full article

The demand for self-powered, flexible, and wearable electronic devices has been increasing in recent years for physiological and biomedical applications in real-time detection due to their higher flexibility and stretchability. This work fabricated a highly sensitive, self-powered wearable microdevice with Poly-Vinylidene Fluoride-Tetra Fluoroethylene (PVDF-TrFE) nano-fibers using an electrospinning technique. The dielectric response of the polymer was improved by incorporating the reduced-graphene-oxide (rGO) multi-walled carbon nano-tubes (MWCNTs) through doping. The dielectric behavior and piezoelectric effect were improved through the stretching and orientation of polymeric chains. The outermost layer was attained by chemical vapor deposition (CVD) of conductive polymer poly (3,4-ethylenedioxythiophene) to enhance the electrical conductivity and sensitivity. The hetero-structured nano-composite comprises PVDF-TrFE doped with rGO-MWCNTs over poly (3,4-ethylenedioxythiophene) (PEDOT), forming continuous self-assembly. The piezoelectric pressure sensor is capable of detecting human physiological vital signs. The pressure sensor exhibits a high-pressure sensitivity of 19.09 kPa⁻¹, over a sensing range of 1.0 Pa to 25 kPa, and excellent cycling stability of 10,000 cycles. The study reveals that the piezoelectric pressure sensor has superior sensing performance and is capable of monitoring human vital signs, including heartbeat and wrist pulse, masticatory movement, voice recognition, and eye blinking signals. The research work demonstrates that the device could potentially eliminate metallic sensors and be used for early disease diagnosis in biomedical and personal healthcare applications. Full article

The implementation of a machine learning approach to predict vibration suppression, as derived from nanocomposite laminates with piezoelectric shunted systems, is studied in this article. Datasets providing the vibration response and vibration attenuation are developed using parametric finite element simulations. A graphene/fibre-reinforced laminate cantilever beam is used in those simulations. Parameters, including the graphene and fibre reinforcements content, as well as the fibre angles, are among the inputs. Output is the vibration suppression achieved by the piezoelectric shunted system. Artificial Neural Networks are trained and tested using the derived datasets. The proposed methodology can be used for a fast and accurate prediction of the vibration response of nanocomposite laminates. Full article

Civil engineering structures need to be protected from earthquakes, representing a new area of research that is growing continuously and very rapidly. Design engineers are always searching for lightweight, stronger, and stiffer materials to be applied as vibration-damping materials. Stability in dynamics necessitates an active, robust, and convenient mechanism that can absorb the kinetic energy of vibration to prevent the structural system from resonance. Recently, many researchers have successfully used nanomaterials to develop energy-absorbing materials that are lightweight and cost-effective. Traditional damping treatments are based on combinations of viscoelastic, elastomeric, magnetic, and piezoelectric materials. In this paper, a review of various damping techniques for composites made of cement modified by various nanomaterials like Nano Al2O₃ (Aluminum Dioxide), Nano SiO₂ (Silicon Dioxide), Nano TiO₂ (Titanium Dioxide), Graphene, and CNTs (Carbon Nanotubes) is presented. The designs of various nano-composite dampers are presented to strengthen the information progress in this field. The current study’s goal is to discover how nanoparticles impact the cement-based material’s damping properties. The study examined several nanomaterials in cement composites at differing concentrations. With the help of the Dynamic Mechanical Analysis (DMA) method and the Logarithmic Decrement approach, the damping properties of these composites were examined. Scanning Electron Microscopy (SEM) was used to examine the effects of nanomaterials on the microstructure and pore size distribution of the composite. Increasing the quantity of nanoparticles in cement paste may improve its capacity to lessen vibration. The experiments also showed that certain nanomaterials may improve load transmission inside the cement matrix and connect neighboring hydration products, helping to reduce energy loss during the loading process. These nanoparticles will eventually replace the large machinery employed to dampen vibrations in buildings due to their small weight, increased mechanical strength, and effective damping properties. Full article

This work reports the investigations of the electric potential impacts on the mechanical buckling of the piezoelectric nanocomposite doubly curved shallow shells reinforced by functionally gradient graphene platelets (FGGPLs). A four-variable shear deformation shell theory is utilized to describe the components of displacement. The present nanocomposite shells are presumed to be rested on an elastic foundation and subject to electric potential and in-plane compressive loads. These shells are composed of several bonded layers. Each layer is composed of piezoelectric materials strengthened by uniformly distributed GPLs. The Halpin–Tsai model is employed to calculate the Young’s modulus of each layer, whereas Poisson’s ratio, mass density, and piezoelectric coefficients are evaluated based on the mixture rule. The graphene components are graded from one layer to another according to four different piecewise laws. The stability differential equations are deduced based on the principle of virtual work. To test the validity of this work, the current mechanical buckling load is analogized with that available in the literature. Several parametric investigations have been performed to demonstrate the effects of the shell geometry elastic foundation stiffness, GPL volume fraction, and external electric voltage on the mechanical buckling load of the GPLs/piezoelectric nanocomposite doubly curved shallow shells. It is found that the buckling load of GPLs/piezoelectric nanocomposite doubly curved shallow shells without elastic foundations is reduced by increasing the external electric voltage. Moreover, by increasing the elastic foundation stiffness, the shell strength is enhanced, leading to an increase in the critical buckling load. Full article

In this study, a polyvinylidene fluoride (PVDF)/graphene nanoplatelet (GNP) micro-nanocomposite membrane was fabricated through electrospinning technology and was employed in the fabrication of a fiber-reinforced polymer composite laminate. Some glass fibers were replaced with carbon fibers to serve as electrodes in the sensing layer, and the PVDF/GNP micro-nanocomposite membrane was embedded in the laminate to confer multifunctional piezoelectric self-sensing ability. The self-sensing composite laminate has both favorable mechanical properties and sensing ability. The effects of different concentrations of modified multiwalled carbon nanotubes (CNTs) and GNPs on the morphology of PVDF fibers and the β-phase content of the membrane were investigated. PVDF fibers containing 0.05% GNPs were the most stable and had the highest relative β-phase content; these fibers were embedded in glass fiber fabric to prepare the piezoelectric self-sensing composite laminate. To test the laminate’s practical application, four-point bending and low-velocity impact tests were performed. The results revealed that when damage occurred during bending, the piezoelectric response changed, confirming that the piezoelectric self-sensing composite laminate has preliminary sensing performance. The low-velocity impact experiment revealed the effect of impact energy on sensing performance. Full article

Natural polymers such as cellulose have interesting tribo- and piezoelectric properties for paper-based energy harvesters, but their low performance in providing sufficient output power is still an impediment to a wider deployment for IoT and other low-power applications. In this study, different types of celluloses were combined with nanosized carbon fillers to investigate their effect on the enhancement of the electrical properties in the final nanogenerator devices. Cellulose pulp (CP), microcrystalline cellulose (MCC) and cellulose nanofibers (CNFs) were blended with carbon black (CB), carbon nanotubes (CNTs) and graphene nanoplatelets (GNPs). The microstructure of the nanocomposite films was characterized by scanning electron and probe microscopies, and the electrical properties were measured macroscopically and at the local scale by piezoresponse force microscopy. The highest generated output voltage in triboelectric mode was obtained from MCC films with CNTs and CB, while the highest piezoelectric voltage was produced in CNF-CNT films. The obtained electrical responses were discussed in relation to the material properties. Analysis of the microscopic response shows that pulp has a higher local piezoelectric d₃₃ coefficient (145 pC/N) than CNF (14 pC/N), while the macroscopic response is greatly influenced by the excitation mode and the effective orientation of the crystals relative to the mechanical stress. The increased electricity produced from cellulose nanocomposites may lead to more efficient and biodegradable nanogenerators. Full article

In this study we fabricated a piezoelectric nanogenerator (PENG) of nanocomposite thin film comprising a conductive nanofiller of reduced graphene oxide (rGO) dispersed in a poly(vinylidene fluoride-co-trifluoroethylene) (P(VDF-TrFE)) matrix that was anticipated to show enhanced energy harvest performance. For the film preparation we employed the Langmuir-Schaefer (LS) technique to provide direct nucleation of the polar β-phase without any traditional polling or annealing process. We prepared five PENGs consisting of the nanocomposite LS films with different rGO contents in the P(VDF-TrFE) matrix and optimized their energy harvest performance. We found that the rGO-0.002 wt% film yielded the highest peak-peak open-circuit voltage (V_OC) of 88 V upon bending and releasing at 2.5 Hz frequency, which was more than two times higher than the pristine P(VDF-TrFE) film. This optimized performance was explained by increased β-phase content, crystallinity, and piezoelectric modulus, and improved dielectric properties, based on scanning electron microscopy (SEM), Fourier transform infrared (FT-IR), x-ray diffraction (XRD), piezoelectric modulus, and dielectric property measurement results. This PENG with enhanced energy harvest performance has great potential in practical applications for low energy power supply in microelectronics such as wearable devices. Full article

MXene materials have the metallic conductivity of transition metal carbides. Among them, Ti₃C₂T_X with an accordion structure has great application prospects in the field of wearable devices. However, flexible wearable electronic devices face the problem of single function in practical application. Therefore, it is particularly important to study a flexible sensor with multiple functions for electronic skin. In this work, the near-field electrohydrodynamic printing (NFEP) method was proposed to prepare the composite thin film with a micro/nanofiber structure on the flexible substrate using a solution of poly(vinylidene fluoride)/MXene nanosheet/reduced graphene oxide (PMR) nanocomposites as the printing solution. A dual-mode flexible sensor for electronic skin based on the PMR nanocomposite thin film was fabricated. The flexible sensor had the detection capability of the piezoresistive mode and the piezoelectric mode. In the piezoresistive mode, the sensitivity was 29.27 kPa⁻¹ and the response/recovery time was 36/55 ms. In the piezoelectric mode, the sensitivity was 8.84 kPa⁻¹ and the response time was 18.2 ms. Under the synergy of the dual modes, functions that cannot be achieved by a single mode sensor can be accomplished. In the process of detecting the pressure or deformation of the object, more information is obtained, which broadens the application range of the flexible sensor. The experimental results show that the dual-mode flexible sensor has great potential in human motion monitoring and wearable electronic device applications. Full article

This research is devoted to investigating the thermo-piezoelectric bending of functionally graded (FG) porous piezoelectric plates reinforced with graphene platelets (GPLs). A refined four-variable shear deformation plate theory is utilized considering the transverse shear strain to describe the displacement components. The porous nanocomposite plate is composed of polymer piezoelectric material containing internal pores and reinforced with FG GPLs. In accordance with modified distribution laws, the porosity and GPLs volume fraction are presumed to vary continuously through the plate thickness. Four GPLs and porosity distribution types are presented. By applying the Halpin–Tsai model, the elastic properties of the nanocomposite plate are calculated. The governing equations are derived based on the present theory and the principle of virtual work. The deduced partial differential equations are converted to ordinary equations by employing Levy-type solution. These equations are numerically solved based on the differential quadrature method (DQM). In order to determine the minimum grid points sufficient to gain a converging solution, a convergence study is introduced. Moreover, the accuracy of the present formulations are examined by comparing the obtained results with those published in the literature. Additional parametric analyses are introduced to investigate the influences of the GPLs weight fraction, distribution types, side-to-thickness ratio, external electric voltage and temperature on the thermal bending of FG GPLs porous nanocomposite piezoelectric plates. Full article

This paper studies wave propagation in a new structure composed of three layers. The upper and lower layers are made of a piezoelectromagnetic material reinforced with graphene platelets (GPLs) that may be uniformly disseminated or continuously varied throughout the thickness of the layers. To produce a lighter plate, the core layer is assumed to comprise honeycomb structures. The smart nanocomposite plate is exposed to external electric and magnetic potentials. The effective elastic modulus of the face layers of the sandwich plate is evaluated based on Halpin-Tsai model. Whereas, the mixture rule is utilized to calculate mass density, Poisson’s ratio and electric and magnetic properties of both upper and lower layers of the sandwich plate. The governing motion equations of the lightweight sandwich plate are obtained by refined higher-order shear deformation plate theory and Hamilton’s principle. These equations are solved analytically to obtain wave dispersion relations. Impacts of the geometry of plates, GPLs weight fraction, GPLs distribution patterns, piezoelectric properties, external electric voltage and external magnetic potential on the wave frequency and phase velocity of the GPLs lightweight plates are discussed in detail. Full article

This paper aims to study the hygrothermal buckling of smart graphene/piezoelectric circular nanoplates lying on an elastic medium and subjected to an external electric field. The circular nanoplates are made of piezoelectric polymer reinforced with graphene platelets that are uniformly distributed through the thickness of the nanoplate. The material properties of the nanocomposite plate are determined based on the modified Halpin-Tsai model. To capture the nanoscale effects, the nonlocal strain gradient theory is applied. Moreover, the principle of virtual work is employed to establish the nonlinear stability equations in the framework of classical theory. The differential quadrature method is utilized to solve the governing equations. Among the important aims of the paper is to study the influences of various parameters such as graphene weight fraction, elastic foundation parameters, external applied electric field, humid conditions, and boundary conditions on the thermal buckling of the smart nanocomposite circular nanoplates. It is found that the increase in graphene components and elastic foundation stiffness enhances the strength of the plates; therefore, the buckling temperature will increase. Full article

Pristine and doped polyvinylidene fluoride (PVDF) are actively investigated for a broad range of applications in pressure sensing, energy harvesting, transducers, porous membranes, etc. There have been numerous reports on the improved piezoelectric and electric performance of PVDF-doped reduced graphene oxide (rGO) structures. However, the common in situ doping methods have proven to be expensive and less desirable. Furthermore, there is a lack of explicit extraction of the compression mode piezoelectric coefficient ($d_{33}$) in ex situ rGO doped PVDF composite films prepared using low-cost, solution-cast processes. In this work, we describe an optimal procedure for preparing high-quality pristine and nano-composite PVDF films using solution-casting and thermal poling. We then verify their electromechanical properties by rigorously characterizing $\beta$-phase concentration, crystallinity, piezoelectric coefficient, dielectric permittivity, and loss tangent. We also demonstrate a novel stationary atomic force microscope (AFM) technique designed to reduce non-piezoelectric influences on the extraction of $d_{33}$ in PVDF films. We then discuss the benefits of our $d_{33}$ measurements technique over commercially sourced piezometers and conventional piezoforce microscopy (PFM). Characterization outcomes from our in-house synthesized films demonstrate that the introduction of 0.3%w.t. rGO nanoparticles in a solution-cast only marginally changes the $\beta$-phase concentration from 83.7% to 81.7% and decreases the crystallinity from 42.4% to 37.3%, whereas doping increases the piezoelectric coefficient by 28% from $d_{33}$ = 45 pm/V to $d_{33}$ = 58 pm/V, while also improving the dielectric by 28%. The piezoelectric coefficients of our films were generally higher but comparable to other in situ prepared PVDF/rGO composite films, while the dielectric permittivity and $\beta$-phase concentrations were found to be lower. Full article

The incorporation of ceramic nanoinclusions in carbon nanocomposites can induce additional functionality in the field of magnetic properties, piezoelectricity, etc. In this study, series of nanocomposites, consisting of different carbon nanoinclusions (carbon black, MWCNTs, graphene nanoplatelets, nanodiamonds) and magnetite nanoparticles incorporated into a commercially available epoxy resin were developed varying the filler type and concentration. Experimental data from the static tensile tests and dynamic mechanical analysis (DMA) demonstrated that the elastic tensile modulus and storage modulus of hybrid nanocomposites increase with an increase in filler content up to almost 100% due to the inherent filler properties and the strong interactions at the interface between the epoxy matrix and the nanoinclusions. Strong interactions are implied by the increasing values of the glass transition temperature recorded by differential scanning calorimetry (DSC). On the contrary, tensile strength and fracture strain of the nanocomposites were found to decrease with filler content. The results highlight the potentials and capabilities of developing hybrid multifunctional nanocomposites with enriched properties while holding their structural integrity. Full article