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15 pages, 3175 KiB  
Article
Creep Deformation Mechanisms of Gas-Bearing Coal in Deep Mining Environments: Experimental Characterization and Constitutive Modeling
by Xiaolei Sun, Xueqiu He, Liming Qiu, Qiang Liu, Limin Qie and Qian Sun
Processes 2025, 13(8), 2466; https://doi.org/10.3390/pr13082466 - 4 Aug 2025
Viewed by 143
Abstract
The impact mechanism of long-term creep in gas-containing coal on coal and gas outbursts has not been fully elucidated and remains insufficiently understood for the purpose of disaster engineering control. This investigation conducted triaxial creep experiments on raw coal specimens under controlled confining [...] Read more.
The impact mechanism of long-term creep in gas-containing coal on coal and gas outbursts has not been fully elucidated and remains insufficiently understood for the purpose of disaster engineering control. This investigation conducted triaxial creep experiments on raw coal specimens under controlled confining pressures, axial stresses, and gas pressures. Through systematic analysis of coal’s physical responses across different loading conditions, we developed and validated a novel creep damage constitutive model for gas-saturated coal through laboratory data calibration. The key findings reveal three characteristic creep regimes: (1) a decelerating phase dominates under low stress conditions, (2) progressive transitions to combined decelerating–steady-state creep with increasing stress, and (3) triphasic decelerating–steady–accelerating behavior at critical stress levels. Comparative analysis shows that gas-free specimens exhibit lower cumulative strain than the 0.5 MPa gas-saturated counterparts, with gas presence accelerating creep progression and reducing the time to failure. Measured creep rates demonstrate stress-dependent behavior: primary creep progresses at 0.002–0.011%/min, decaying exponentially to secondary creep rates below 0.001%/min. Steady-state creep rates follow a power law relationship when subject to deviatoric stress (R2 = 0.96). Through the integration of Burgers viscoelastic model with the effective stress principle for porous media, we propose an enhanced constitutive model, incorporating gas adsorption-induced dilatational stresses. This advancement provides a theoretical foundation for predicting time-dependent deformation in deep coal reservoirs and informs monitoring strategies concerning gas-bearing strata stability. This study contributes to the theoretical understanding and engineering monitoring of creep behavior in deep coal rocks. Full article
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19 pages, 6581 KiB  
Article
Simulation Study on Erosion of Gas–Solid Two-Phase Flow in the Wellbore near Downhole Chokes in Tight Gas Wells
by Cheng Du, Ruikang Ke, Xiangwei Bai, Rong Zheng, Yao Huang, Dan Ni, Guangliang Zhou and Dezhi Zeng
Processes 2025, 13(8), 2430; https://doi.org/10.3390/pr13082430 - 31 Jul 2025
Viewed by 219
Abstract
In order to study the problem of obvious wall thinning in the wellbore caused by proppant backflow and sand production under throttling conditions in tight gas wells. Based on the gas-phase control equation, particle motion equation, and erosion model, the wellbore erosion model [...] Read more.
In order to study the problem of obvious wall thinning in the wellbore caused by proppant backflow and sand production under throttling conditions in tight gas wells. Based on the gas-phase control equation, particle motion equation, and erosion model, the wellbore erosion model is established. The distribution law of pressure, temperature, and velocity trace fields under throttling conditions is analyzed, and the influences of different throttling pressures, particle diameters, and particle mass flows on wellbore erosion are analyzed. The flow field at the nozzle changes drastically, and there is an obvious pressure drop, temperature drop, and velocity rise. When the surrounding gas is completely mixed, the physical quantity gradually stabilizes. The erosion shape of the wellbore outlet wall has a point-like distribution. The closer to the throttle valve outlet, the more intense the erosion point distribution is. Increasing the inlet pressure and particle mass flow rate will increase the maximum erosion rate, and increasing the particle diameter will reduce the maximum erosion rate. The particle mass flow rate has the greatest impact on the maximum erosion rate, followed by the particle diameter. The erosion trend was predicted using multiple regression model fitting of the linear interaction term. The research results can provide a reference for the application of downhole throttling technology and wellbore integrity in tight gas exploitation. Full article
(This article belongs to the Section Process Control and Monitoring)
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17 pages, 3995 KiB  
Article
Nonlinear Vibration and Post-Buckling Behaviors of Metal and FGM Pipes Transporting Heavy Crude Oil
by Kamran Foroutan, Farshid Torabi and Arth Pradeep Patel
Appl. Sci. 2025, 15(15), 8515; https://doi.org/10.3390/app15158515 (registering DOI) - 31 Jul 2025
Viewed by 102
Abstract
Functionally graded materials (FGMs) have the potential to revolutionize the oil and gas transportation sector, due to their increased strengths and efficiencies as pipelines. Conventional pipelines frequently face serious problems such as extreme weather, pressure changes, corrosion, and stress-induced pipe bursts. By analyzing [...] Read more.
Functionally graded materials (FGMs) have the potential to revolutionize the oil and gas transportation sector, due to their increased strengths and efficiencies as pipelines. Conventional pipelines frequently face serious problems such as extreme weather, pressure changes, corrosion, and stress-induced pipe bursts. By analyzing the mechanical and thermal performance of FGM-based pipes under various operating conditions, this study investigates the possibility of using them as a more reliable substitute. In the current study, the post-buckling and nonlinear vibration behaviors of pipes composed of FGMs transporting heavy crude oil were examined using a Timoshenko beam framework. The material properties of the FGM pipe were observed to change gradually across the thickness, following a power-law distribution, and were influenced by temperature variations. In this regard, two types of FGM pipes are considered: one with a metal-rich inner surface and ceramic-rich outer surface, and the other with a reverse configuration featuring metal on the outside and ceramic on the inside. The nonlinear governing equations (NGEs) describing the system’s nonlinear dynamic response were formulated by considering nonlinear strain terms through the von Kármán assumptions and employing Hamilton’s principle. These equations were then discretized using Galerkin’s method to facilitate the analytical investigation. The Runge–Kutta method was employed to address the nonlinear vibration problem. It is concluded that, compared with pipelines made from conventional materials, those constructed with FGMs exhibit enhanced thermal resistance and improved mechanical strength. Full article
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17 pages, 2495 KiB  
Article
Production Capacity and Temperature–Pressure Variation Laws in Depressurization Exploitation of Unconsolidated Hydrate Reservoir in Shenhu Sea Area
by Yuanwei Sun, Yuanfang Cheng, Yanli Wang, Jian Zhao, Xian Shi, Xiaodong Dai and Fengxia Shi
Processes 2025, 13(8), 2418; https://doi.org/10.3390/pr13082418 - 30 Jul 2025
Viewed by 260
Abstract
The Shenhu sea area is rich in unconsolidated hydrate reserves, but the formation mineral particles are small, the rock cementation is weak, and the coupling mechanism of hydrate phase change, fluid seepage, and formation deformation is complex, resulting in unclear productivity change law [...] Read more.
The Shenhu sea area is rich in unconsolidated hydrate reserves, but the formation mineral particles are small, the rock cementation is weak, and the coupling mechanism of hydrate phase change, fluid seepage, and formation deformation is complex, resulting in unclear productivity change law under depressurization exploitation. Therefore, a thermal–fluid–solid–chemical coupling model for natural gas hydrate depressurization exploitation in the Shenhu sea area was constructed to analyze the variation law of reservoir parameters and productivity. The results show that within 0–30 days, rapid near-well pressure drop (13.83→9.8 MPa, 36.37%) drives peak gas production (25,000 m3/d) via hydrate dissociation, with porosity (0.41→0.52) and permeability (75→100 mD) increasing. Within 30–60 days, slower pressure decline (9.8→8.6 MPa, 12.24%) and fines migration cause permeability fluctuations (120→90 mD), reducing gas production to 20,000 m3/d. Within 60–120 days, pressure stabilizes (~7.6 MPa) with residual hydrate saturation < 0.1, leading to stable low permeability (60 mD) and gas production (15,000 m3/d), with cumulative production reaching 2.2 × 106 m3. This study clarifies that productivity is governed by coupled “pressure-driven dissociation–heat limitation–fines migration” mechanisms, providing key insights for optimizing depressurization strategies (e.g., timed heat supplementation, anti-clogging measures) to enhance commercial viability of unconsolidated hydrate reservoirs. Full article
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12 pages, 2015 KiB  
Article
Low-Order Modelling of Extinction of Hydrogen Non-Premixed Swirl Flames
by Hazem S. A. M. Awad, Savvas Gkantonas and Epaminondas Mastorakos
Aerospace 2025, 12(8), 676; https://doi.org/10.3390/aerospace12080676 - 29 Jul 2025
Viewed by 185
Abstract
Predicting the blow-off (BO) is critical for characterising the operability limits of gas turbine engines. In this study, the applicability of a low-order extinction prediction modelling, which is based on a stochastic variant of the Imperfectly Stirred Reactor (ISR) approach, to predict the [...] Read more.
Predicting the blow-off (BO) is critical for characterising the operability limits of gas turbine engines. In this study, the applicability of a low-order extinction prediction modelling, which is based on a stochastic variant of the Imperfectly Stirred Reactor (ISR) approach, to predict the lean blow-off (LBO) curve and the extinction conditions in a hydrogen Rich-Quench-Lean (RQL)-like swirl combustor is investigated. The model predicts the blow-off scalar dissipation rate (SDR), which is then extrapolated using Reynolds-Averaged Navier–Stokes (RANS) cold-flow simulations and simple scaling laws, to determine the critical blow-off conditions. It has been found that the sISR modelling framework can predict the BO flow split ratio at different global equivalence ratios, showing a reasonable agreement with the experimental data. This further validates sISR as an efficient low-order modelling flame extinction tool, which can significantly contribute to the development of robust hydrogen RQL combustors by enabling the rapid exploration of combustor operability during the preliminary design phases. Full article
(This article belongs to the Special Issue Scientific and Technological Advances in Hydrogen Combustion Aircraft)
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19 pages, 8002 KiB  
Article
3D Forward Simulation of Borehole-Surface Transient Electromagnetic Based on Unstructured Finite Element Method
by Jiayi Liu, Tianjun Cheng, Lei Zhou, Xinyu Wang and Xingbing Xie
Minerals 2025, 15(8), 785; https://doi.org/10.3390/min15080785 - 26 Jul 2025
Viewed by 157
Abstract
The time-domain electromagnetic method has been widely applied in mineral exploration, oil, and gas fields in recent years. However, its response characteristics remain unclear, and there is an urgent need to study the response characteristics of the borehole-surface transient electromagnetic(BSTEM) field. This study [...] Read more.
The time-domain electromagnetic method has been widely applied in mineral exploration, oil, and gas fields in recent years. However, its response characteristics remain unclear, and there is an urgent need to study the response characteristics of the borehole-surface transient electromagnetic(BSTEM) field. This study starts from the time-domain electric field diffusion equation and discretizes the calculation area in space using tetrahedral meshes. The Galerkin method is used to derive the finite element equation of the electric field, and the vector interpolation basis function is used to approximate the electric field in any arbitrary tetrahedral mesh in the free space, thus achieving the three-dimensional forward simulation of the BSTEM field based on the finite element method. Following validation of the numerical simulation method, we further analyze the electromagnetic field response excited by vertical line sources.. Through comparison, it is concluded that measuring the radial electric field is the most intuitive and effective layout method for BSTEM, with a focus on the propagation characteristics of the electromagnetic field in both low-resistance and high-resistance anomalies at different positions. Numerical simulations reveal that BSTEM demonstrates superior resolution capability for low-resistivity anomalies, while showing limited detectability for high-resistivity anomalies Numerical simulation results of BSTEM with realistic orebody models, the correctness of this rule is further verified. This has important implications for our understanding of the propagation laws of BSTEM as well as for subsequent data processing and interpretation. Full article
(This article belongs to the Special Issue Geoelectricity and Electrical Methods in Mineral Exploration)
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19 pages, 15236 KiB  
Article
Sedimentary Characteristics and Model of Estuary Dam-Type Shallow-Water Delta Front: A Case Study of the Qing 1 Member in the Daqingzijing Area, Songliao Basin, China
by Huijian Wen, Weidong Xie, Chao Wang, Shengjuan Qian and Cheng Yuan
Appl. Sci. 2025, 15(15), 8327; https://doi.org/10.3390/app15158327 - 26 Jul 2025
Viewed by 255
Abstract
The sedimentary characteristics and model of the shallow-water delta front are of great significance for the development of oil and gas reservoirs. At present, there are great differences in the understanding of the distribution patterns of estuary dams in the shallow-water delta front. [...] Read more.
The sedimentary characteristics and model of the shallow-water delta front are of great significance for the development of oil and gas reservoirs. At present, there are great differences in the understanding of the distribution patterns of estuary dams in the shallow-water delta front. Therefore, this paper reveals the distribution characteristics of estuary dams through the detailed dissection of the Qing 1 Member in the Daqingzijing area and establishes a completely new distribution pattern of estuary dams. By using geological data such as logging and core measurements, sedimentary microfacies at the shallow-water delta front are classified and logging facies identification charts for each sedimentary microfacies are developed. Based on the analysis of single-well and profile facies, the sedimentary evolution laws of the Qing 1 Member reservoirs are analyzed. On this basis, the sedimentary characteristics and model of the lacustrine shallow-water delta front are established. The results indicate that the Qing 1 Member in the Daqingzijing area exhibits a transitional sequence from a delta front to pro-delta facies and finally to deep lacustrine facies, with sediments continuously retrograding upward. Subaqueous distributary channels and estuary dams constitute the skeletal sand bodies of the retrogradational shallow-water delta. The estuary dam sand bodies are distributed on both sides of the subaqueous distributary channels, with sand body development gradually decreasing in scale from bottom to top. These bodies are intermittently distributed, overlapping, and laterally connected in plan view, challenging the conventional understanding that estuary dams only occur at the bifurcation points of underwater distributary channels. Establishing the sedimentary characteristics and model of the shallow-water delta front is of great significance for the exploration and development of reservoirs with similar sedimentary settings. Full article
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18 pages, 2813 KiB  
Article
Spatiotemporal Differentiation and Driving Factors Analysis of the EU Natural Gas Market Based on Geodetector
by Xin Ren, Qishen Chen, Kun Wang, Yanfei Zhang, Guodong Zheng, Chenghong Shang and Dan Song
Sustainability 2025, 17(15), 6742; https://doi.org/10.3390/su17156742 - 24 Jul 2025
Viewed by 302
Abstract
In 2022, the Russia–Ukraine conflict has severely impacted the EU’s energy supply chain, and the EU’s natural gas import pattern has begun to reconstruct, and exploring the spatiotemporal differentiation of EU natural gas trade and its driving factors is the basis for improving [...] Read more.
In 2022, the Russia–Ukraine conflict has severely impacted the EU’s energy supply chain, and the EU’s natural gas import pattern has begun to reconstruct, and exploring the spatiotemporal differentiation of EU natural gas trade and its driving factors is the basis for improving the resilience of its supply chain and ensuring the stable supply of energy resources. This paper summarizes the law of the change of its import volume by using the complex network method, constructs a multi-dimensional index system such as demand, economy, and security, and uses the geographic detector model to mine the driving factors affecting the spatiotemporal evolution of natural gas imports in EU countries and propose different sustainable development paths. The results show that from 2000 to 2023, Europe’s natural gas imports generally show an upward trend, and the import structure has undergone great changes, from pipeline gas dominance to LNG diversification. After the conflict between Russia and Ukraine, the number of import source countries has increased, the market network has become looser, France has become the core hub of the EU natural gas market, the importance of Russia has declined rapidly, and the status of countries in the United States, North Africa, and the Middle East has increased rapidly; natural gas consumption is the leading factor in the spatiotemporal differentiation of EU natural gas imports, and the influence of import distance and geopolitical risk is gradually expanding, and the proportion of energy consumption is significantly higher than that of other factors in the interaction with other factors. Combined with the driving factors, three different evolutionary directions of natural gas imports in EU countries are identified, and energy security paths such as improving supply chain control capabilities, ensuring export stability, and using location advantages to become hub nodes are proposed for different development trends. Full article
(This article belongs to the Topic Energy Economics and Sustainable Development)
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27 pages, 3280 KiB  
Article
Design and Implementation of a Robust Hierarchical Control for Sustainable Operation of Hybrid Shipboard Microgrid
by Arsalan Rehmat, Farooq Alam, Mohammad Taufiqul Arif and Syed Sajjad Haider Zaidi
Sustainability 2025, 17(15), 6724; https://doi.org/10.3390/su17156724 - 24 Jul 2025
Viewed by 424
Abstract
The growing demand for low-emission maritime transport and efficient onboard energy management has intensified research into advanced control strategies for hybrid shipboard microgrids. These systems integrate both AC and DC power domains, incorporating renewable energy sources and battery storage to enhance fuel efficiency, [...] Read more.
The growing demand for low-emission maritime transport and efficient onboard energy management has intensified research into advanced control strategies for hybrid shipboard microgrids. These systems integrate both AC and DC power domains, incorporating renewable energy sources and battery storage to enhance fuel efficiency, reduce greenhouse gas emissions, and support operational flexibility. However, integrating renewable energy into shipboard microgrids introduces challenges, such as power fluctuations, varying line impedances, and disturbances caused by AC/DC load transitions, harmonics, and mismatches in demand and supply. These issues impact system stability and the seamless coordination of multiple distributed generators. To address these challenges, we proposed a hierarchical control strategy that supports sustainable operation by improving the voltage and frequency regulation under dynamic conditions, as demonstrated through both MATLAB/Simulink simulations and real-time hardware validation. Simulation results show that the proposed controller reduces the frequency deviation by up to 25.5% and power variation improved by 20.1% compared with conventional PI-based secondary control during load transition scenarios. Hardware implementation on the NVIDIA Jetson Nano confirms real-time feasibility, maintaining power and frequency tracking errors below 5% under dynamic loading. A comparative analysis of the classical PI and sliding mode control-based designs is conducted under various grid conditions, such as cold ironing mode of the shipboard microgrid, and load variations, considering both the AC and DC loads. The system stability and control law formulation are verified through simulations in MATLAB/SIMULINK and practical implementation. The experimental results demonstrate that the proposed secondary control architecture enhances the system robustness and ensures sustainable operation, making it a viable solution for modern shipboard microgrids transitioning towards green energy. Full article
(This article belongs to the Special Issue Smart Grid Technologies and Energy Sustainability)
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15 pages, 2521 KiB  
Article
Interface-Driven Electrothermal Degradation in GaN-on-Diamond High Electron Mobility Transistors
by Huanran Wang, Yifan Liu, Xiangming Dong, Abid Ullah, Jisheng Sun, Chuang Zhang, Yucheng Xiong, Peng Gu, Ge Chen and Xiangjun Liu
Nanomaterials 2025, 15(14), 1114; https://doi.org/10.3390/nano15141114 - 18 Jul 2025
Viewed by 321
Abstract
Diamond is an attractive substrate candidate for GaN high-electron-mobility transistors (HEMT) to enhance heat dissipation due to its exceptional thermal conductivity. However, the thermal boundary resistance (TBR) at the GaN–diamond interface poses a significant bottleneck to heat transport, exacerbating self-heating and limiting device [...] Read more.
Diamond is an attractive substrate candidate for GaN high-electron-mobility transistors (HEMT) to enhance heat dissipation due to its exceptional thermal conductivity. However, the thermal boundary resistance (TBR) at the GaN–diamond interface poses a significant bottleneck to heat transport, exacerbating self-heating and limiting device performance. In this work, TCAD simulations were employed to systematically investigate the effects of thermal boundary layer (TBL) thickness (dTBL) and thermal conductivity (κTBL) on the electrothermal behavior of GaN-on-diamond HEMTs. Results show that increasing the TBL thickness (5–20 nm) or decreasing its thermal conductivity (0.1–1.0 W/(m·K)) leads to elevated hotspot temperatures and degraded electron mobility, resulting in a notable deterioration of IV characteristics. The nonlinear dependence of device performance on κTBL is attributed to Fourier’s law, where heat flux is inversely proportional to thermal resistance. Furthermore, the co-analysis of substrate thermal conductivity and interfacial quality reveals that interface TBR has a more dominant impact on device behavior than substrate conductivity. Remarkably, devices with low thermal conductivity substrates and optimized interfaces can outperform those with high-conductivity substrates but poor interfacial conditions. These findings underscore the critical importance of interface engineering in thermal management of GaN–diamond HEMTs and provide a theoretical foundation for future work on phonon transport and defect-controlled thermal interfaces. Full article
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22 pages, 3439 KiB  
Article
Metabolomics Analysis Reveals the Influence Mechanism of Different Growth Years on the Growth, Metabolism and Accumulation of Medicinal Components of Bupleurum scorzonerifolium Willd. (Apiaceae)
by Jialin Sun, Jianhao Wu, Weinan Li, Xiubo Liu and Wei Ma
Biology 2025, 14(7), 864; https://doi.org/10.3390/biology14070864 - 16 Jul 2025
Viewed by 230
Abstract
Bupleurum scorzonerifolium Willd. is a perennial herbaceous plant of the genus Bupleurum in the Apiaceae family. Also known as red Bupleurum, it is mainly distributed in Northeast China, North China and other regions and is a commonly used medicinal plant. It is [...] Read more.
Bupleurum scorzonerifolium Willd. is a perennial herbaceous plant of the genus Bupleurum in the Apiaceae family. Also known as red Bupleurum, it is mainly distributed in Northeast China, North China and other regions and is a commonly used medicinal plant. It is difficult for the wild plant resources of Bupleurum scorzonerifolium Willd. to meet the market demand. In artificial cultivation, there are problems such as a low yield per plant, low quality, weakened stress resistance and variety degradation. The contents of bioactive components and metabolites in traditional Chinese medicinal materials vary significantly across different growth years. The growth duration directly impacts their quality and clinical efficacy. Therefore, determining the optimal growth period is one of the crucial factors in ensuring the quality of traditional Chinese medicinal materials. In this study, Gas Chromatography–Mass Spectrometry (GC-MS) and High-performance liquid chromatography (HPLC) were comprehensively applied to analyze the metabolically differential substances in different parts of Bupleurum scorzonerifolium Willd. By comparing the compositions and content differences of chemical components in different growth years and different parts, the chemical components with significant differences were accurately screened out. In order to further explore the dynamic change characteristics and internal laws of metabolites, a metabolic network was constructed for a visual analysis and, finally, to see the optimal growth years of Bupleurum scorzonerifolium Willd. This result showed that with the accumulation of the growth cycle, the height, root width, fresh mass and saikosaponins content of Bupleurum scorzonerifolium Willd. increased year by year. Except for sodium and calcium elements in the main shoot, the other elements were significantly reduced. In addition, 59 primary metabolites were identified by GC-MS, with the accumulation of the growth cycle, the contents of organic acids, sugars, alcohols and amino acids gradually decreased, while the contents of alkyl, glycosides and other substances gradually increased. There were 53 positive correlations and 18 negative correlations in the triennial Bupleurum scorzonerifolium Willd. grid, all of which were positively correlated with saikosaponins. Therefore, the triennial Bupleurum scorzonerifolium Willd. was considered to be the suitable growth year. It not only provided a new idea and method for the quality evaluation of Bupleurum scorzonerifolium Willd., but also provided a scientific basis for the quality control of Chinese herbs. Full article
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17 pages, 228 KiB  
Article
Why Are Cultural Rights over Sea Country Less Recognised than Terrestrial Ones?
by Rhetti Hoskins, Gareth Ogilvie, Matthew Storey and Alexandra Hill
Heritage 2025, 8(7), 283; https://doi.org/10.3390/heritage8070283 - 16 Jul 2025
Viewed by 458
Abstract
This article identifies the nature of Traditional Owners’ interests in Sea Country and addresses issues associated with all offshore energy projects—gas and wind. Exploring the impacts of offshore development on First Nations’ cultural heritage, the article proposes integration of free, prior and informed [...] Read more.
This article identifies the nature of Traditional Owners’ interests in Sea Country and addresses issues associated with all offshore energy projects—gas and wind. Exploring the impacts of offshore development on First Nations’ cultural heritage, the article proposes integration of free, prior and informed consent (FPIC) and the United Nations Declaration on the Rights of Indigenous Peoples (UNDRIP), into the regulatory and legislative offshore environment. In the Australian context, this particularly regards administrative and regulatory reforms to overcome uncertainty arising from recent decisions in the Federal Court. The international focus on new energy has fast-tracked many processes that sideline First Nations’ rights, hitherto understood within the onshore minerals extraction regimes. The reforms proposed in this article recognise an international commitment to enact the principles contained in the UNDRIP and other relevant international law. Full article
21 pages, 4101 KiB  
Article
A Physics-Informed Neural Network Solution for Rheological Modeling of Cement Slurries
by Huaixiao Yan, Jiannan Ding and Chengcheng Tao
Fluids 2025, 10(7), 184; https://doi.org/10.3390/fluids10070184 - 13 Jul 2025
Viewed by 368
Abstract
Understanding the rheological properties of fresh cement slurries is essential to maintain optimal pumpability, achieve dependable zonal isolation, and preserve long-term well integrity in oil and gas cementing operations and the 3D printing cement and concrete industry. However, accurately and efficiently modeling the [...] Read more.
Understanding the rheological properties of fresh cement slurries is essential to maintain optimal pumpability, achieve dependable zonal isolation, and preserve long-term well integrity in oil and gas cementing operations and the 3D printing cement and concrete industry. However, accurately and efficiently modeling the rheological behavior of cement slurries remains challenging due to the complex fluid properties of fresh cement slurries, which exhibit non-Newtonian and thixotropic behavior. Traditional numerical solvers typically require mesh generation and intensive computation, making them less practical for data-scarce, high-dimensional problems. In this study, a physics-informed neural network (PINN)-based framework is developed to solve the governing equations of steady-state cement slurry flow in a tilted channel. The slurry is modeled as a non-Newtonian fluid with viscosity dependent on both the shear rate and particle volume fraction. The PINN-based approach incorporates physical laws into the loss function, offering mesh-free solutions with strong generalization ability. The results show that PINNs accurately capture the trend of velocity and volume fraction profiles under varying material and flow parameters. Compared to conventional solvers, the PINN solution offers a more efficient and flexible alternative for modeling complex rheological behavior in data-limited scenarios. These findings demonstrate the potential of PINNs as a robust tool for cement slurry rheological modeling, particularly in scenarios where traditional solvers are impractical. Future work will focus on enhancing model precision through hybrid learning strategies that incorporate labeled data, potentially enabling real-time predictive modeling for field applications. Full article
(This article belongs to the Special Issue Advances in Computational Mechanics of Non-Newtonian Fluids)
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21 pages, 3369 KiB  
Article
Thermal Runaway Critical Threshold and Gas Release Safety Boundary of 18,650 Lithium-Ion Battery in State of Charge
by Jingyu Zhao, Kexin Xing, Xinrong Jiang, Chi-Min Shu and Xiangrong Sun
Processes 2025, 13(7), 2175; https://doi.org/10.3390/pr13072175 - 8 Jul 2025
Viewed by 725
Abstract
In this study, we systematically investigated the characteristic parameter evolution laws of thermal runaway with respect to 18,650 lithium-ion batteries (LIBs) under thermal abuse conditions at five state-of-charge (SOC) levels: 0%, 25%, 50%, 75%, and 100%. In our experiments, we combined infrared thermography, [...] Read more.
In this study, we systematically investigated the characteristic parameter evolution laws of thermal runaway with respect to 18,650 lithium-ion batteries (LIBs) under thermal abuse conditions at five state-of-charge (SOC) levels: 0%, 25%, 50%, 75%, and 100%. In our experiments, we combined infrared thermography, mass loss analysis, temperature monitoring, and gas composition detection to reveal the mechanisms by which SOC affects the trigger time, critical temperature, maximum temperature, mass loss, and gas release characteristics of thermal runaway. The results showed that as the SOC increases, the critical and maximum temperatures of thermal runaway increase notably. At a 100% SOC, the highest temperature on the positive electrode side reached 1082.1 °C, and the mass loss increased from 6.90 g at 0% SOC to 25.75 g at 100% SOC, demonstrating a salient positive correlation. Gas analysis indicated that under high-SOC conditions (75% and 100%), the proportion of flammable gases such as CO and CH4 produced during thermal runaway significantly increases, with the CO/CO2 ratio exceeding 1, indicating intensified incomplete combustion and a significant increase in fire risk. In addition, flammability limit analysis revealed that the lower explosive limit for gases is lower (17–21%) at a low SOC (0%) and a high SOC (100%), indicating greater explosion risks. We also found that the composition of gases released during thermal runaway varies substantially at different SOC levels, with CO, CO2, and CH4 accounting for over 90% of the total gas volume, while toxic gases, such as HF, although present in smaller proportions, pose noteworthy hazards. Unlike prior studies that relied on post hoc analysis, this work integrates real-time multi-parameter monitoring (temperature, gas composition, and mass loss) and quantitative explosion risk modeling (flammability limits via the L-C formula). This approach reveals the unique dynamic SOC-dependent mechanisms of thermal runaway initiation and gas hazards. This study provides theoretical support for the source tracing of thermal runaway fires and the development of preventive LIB safety technology and emphasizes the critical influence of the charge state on the thermal safety of batteries. Full article
(This article belongs to the Special Issue Machine Learning Optimization of Chemical Processes)
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20 pages, 3465 KiB  
Article
Phase-Controlled Closing Strategy for UHV Circuit Breakers with Arc-Chamber Insulation Deterioration Consideration
by Hao Li, Qi Long, Xu Yang, Xiang Ju, Haitao Li, Zhongming Liu, Dehua Xiong, Xiongying Duan and Minfu Liao
Energies 2025, 18(13), 3558; https://doi.org/10.3390/en18133558 - 5 Jul 2025
Viewed by 424
Abstract
To address the impact of insulation medium degradation in the arc quenching chambers of ultra-high-voltage SF6 circuit breakers on phase-controlled switching accuracy caused by multiple operations throughout the service life, this paper proposes an adaptive switching algorithm. First, a modified formula for [...] Read more.
To address the impact of insulation medium degradation in the arc quenching chambers of ultra-high-voltage SF6 circuit breakers on phase-controlled switching accuracy caused by multiple operations throughout the service life, this paper proposes an adaptive switching algorithm. First, a modified formula for the breakdown voltage of mixed gases is derived based on the synergistic effect. Considering the influence of contact gap on electric field distortion, an adaptive switching strategy is designed to quantify the dynamic relationship among operation times, insulation strength degradation, and electric field distortion. Then, multi-round switching-on and switching-off tests are carried out under the condition of fixed single-arc ablation amount, and the laws of voltage–current, gas decomposition products, and pre-breakdown time are obtained. The test data are processed by the least squares method, adaptive switching algorithm, and machine learning method. The results show that the coincidence degree of the pre-breakdown time obtained by the adaptive switching algorithm and the test value reaches 90%. Compared with the least squares fitting, this algorithm achieves a reasonable balance between goodness of fit and complexity, with prediction deviations tending to be randomly distributed, no obvious systematic offset, and low dispersion degree. It can also explain the physical mechanism of the decay of insulation degradation rate with the number of operations. Compared with the machine learning method, this algorithm has stronger generalization ability, effectively overcoming the defects of difficult interpretation of physical causes and the poor engineering adaptability of the black box model. Full article
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