Search Results (2,968)

To address the integrated demands of structural reinforcement and energy-efficient retrofitting for existing buildings, a cementitious material modified with vitrified microspheres and SiO₂ aerogel was developed to realize the synergistic enhancement of thermal insulation and mechanical strength. By substituting fine sand with equal mass fractions of SiO₂ aerogel and vitrified microspheres in the cement matrix, this study systematically investigated the synergistic regulatory effects of this binary modification on two core performance metrics—thermal conductivity and compressive strength. All performance tests were conducted in triplicate, and the results are presented as the mean values. The results indicated that the thermal conductivity of the composite exhibited a trend of decreasing first and then increasing with the rise in aerogel content. At an aerogel dosage of 6%, the thermal conductivity dropped to 0.2237 W/(m·K), achieving optimal thermal insulation performance while retaining a compressive strength of 17.96 MPa. The subsequent incorporation of 15% vitrified microspheres further reduced the thermal conductivity to 0.1642 W/(m·K) while maintaining a compressive strength of 15.34 MPa, thereby achieving an optimal balance between thermal insulation and mechanical performance. Microstructural characterization revealed that the incorporation of aerogel significantly increased the internal porosity of the composite, effectively reducing thermal conductivity by obstructing heat transfer pathways. Vitrified microspheres enhance thermal resistance via their closed-cell structure and promote the formation and densification of C-S-H gel. Synergistically with SiO₂ aerogel, they construct a multi-scale porous composite system. By optimizing the interfacial bonding state and pore structure, this system achieves the synergistic optimization of mechanical strength and thermal insulation of cement-based composites, providing new materials and a theoretical basis for the functional integrated retrofitting of existing building structures. Full article

Carbon fiber-reinforced resin matrix composites (CFRC) are extensively used in aerospace, automotive manufacturing, and sports equipment. However, the brittle nature of the resin matrix causes CFRC to exhibit severe vibrations and noise under dry friction conditions. Enhancing the intrinsic damping properties of the resin matrix serves as a fundamental and effective strategy to mitigate vibration and noise radiation in composite components. This study systematically investigates high-temperature co-curing damping composites using co-curing technology, aiming to improve the mechanical performance and damping characteristics of traditional fiber-reinforced epoxy resin composites. A novel carbon fiber-reinforced terminal carboxyl nitrile epoxy pre-polymer composite material demonstrates both stable chemical properties and excellent high-temperature resistance. Through formulation adjustments, the curing temperature and time of epoxy resin are matched with those of the terminal carboxyl nitrile epoxy pre-polymer. The performance of epoxy carbon fiber composites was evaluated through tensile tests, flexural tests, impact tests, infrared spectroscopy, thermogravimetric analysis, dynamic mechanical analysis, scanning electron microscopy, and X-ray diffraction. Results show that blending epoxy resin with terminal carboxyl nitrile liquid rubber enhances energy dissipation by increasing intermolecular friction and hydrogen bonding interactions. The damping ratio of epoxy resin-based carbon fiber composites reaches as high as 1.67%. Tensile strength, flexural strength, and impact strength reach 1968 MPa, 1343 MPa, and 127 kJ/m², respectively. The addition of terminal carboxylated nitrile liquid rubber facilitates the formation of continuous friction membranes, enhancing friction stability. Tensile tests demonstrate that carbon fiber composites containing 25% terminal carboxylated nitrile liquid rubber outperforms other formulations. As evidenced by impact tests, the performance of the prepared composites is superior to that of other configurations. Dynamic mechanical analysis indicates that the 25% rubber-containing composites exhibit enhanced damping characteristics and higher loss modulus. Experimental results confirm that this study advances the development of functional composites for vibration reduction and noise control applications. Full article

Biodegradable active packaging that incorporates food-grade additives offers a promising solution for extending shelf life and minimizing food waste. This study investigates the development of functional packaging films for cheese applications by blending thermoplastic starch (TPS) and poly (butylene adipate-co-terephthalate) (PBAT) in a 60/40 (w/w) ratio with various concentrations of sodium lactate (SL; 1–7% w/w) using blown-film extrusion. Spectroscopic analyses, including ¹H NMR and FTIR, confirmed the presence of hydrogen-bonding and ionic interactions between the hydroxyl (–OH) groups of thermoplastic starch (TPS) and the carboxylate (–COO⁻) groups of sodium lactate, which enhanced interfacial compatibility and produced smoother, more compact film morphologies. SL acted as a multifunctional plasticizer and compatibilizer, improving film flexibility while slightly reducing tensile strength. Notably, SL incorporation increased water vapor permeability and surface wettability but significantly decreased oxygen permeability to below 1 cc·mm/m²·day·atm. At moderate concentrations (≥ 3% w/w), SL also exhibited antimicrobial activity against Staphylococcus aureus. When applied to cheese packaging, SL-modified films effectively maintained color stability for up to 9 days under refrigerated storage. Notably, cheeses packaged with films containing 3–7% (w/w) SL exhibited significantly lower hardness values than the control on day 3, indicating improved moisture retention and texture preservation, although these differences were no longer significant by day 9. These findings demonstrate that sodium lactate can simultaneously enhance interfacial miscibility, oxygen barrier performance, and antimicrobial functionality in sustainable, biodegradable active packaging systems. Full article

In this study, we develop bio-epoxy composites incorporating bio-oils obtained from the pyrolysis of almond and walnut shells at 400 °C and 600 °C, with the aim of evaluating their potential as renewable precursors for epoxy resin modification. The influence of pyrolysis temperature on bio-oil yield and chemical composition is examined to identify phenolic-rich fractions relevant to epoxy curing. Bio-oil production increased with temperature, reaching 40.46% for walnut shells and 36.84% for almond shells at 600 °C. Chemical analysis revealed that aromatic compounds, particularly phenolics, were the major constituents associated with epoxy curing reactivity. For walnut hulls, the total aromatic fraction increased from 30.4% at 400 °C to 35.2% at 600 °C, while almond hulls showed an increase from 23.8% to 26.1% over the same temperature range. Incorporation of bio-oil into the epoxy matrix promoted three-dimensional network formation through reactions between epoxy groups and the functional moieties present in the bio-oil, resulting in a higher cross-linking degree, Young’s modulus, and tensile strength. However, compared to neat epoxy, the bio-oil-modified systems exhibited reduced storage modulus (E′) and glass transition temperature (Tg), attributed to the plasticizing effect of lighter oxygenated species. Overall, although bio-oil incorporation decreases Tg and cross-linking degree, it still provides a viable pathway toward partially bio-based epoxy resins with enhanced stiffness and competitive mechanical performance. Full article

The increasing demand for sustainable agriculture necessitates the development of eco-friendly alternatives to chemical pesticides. This study reports the design and characterization of biodegradable fibrous mats for the delivery of Bacillus subtilis, a plant-beneficial biocontrol agent, using cellulose acetate (CA) scaffolds functionalized with chitooligosaccharides (COS). Electrospun CA fibers were coated by electrospraying with COS or COS/B. subtilis suspensions in a single-step process to produce open, porous biohybrid scaffolds. Scanning electron microscopy confirmed uniform fiber formation and successful deposition of COS and bacterial layers, while ATR-FTIR spectroscopy verified the chemical composition of the fibrous mats. Water contact angle measurements indicated a shift from hydrophobic to highly hydrophilic surfaces, enhancing microbial adhesion and moisture-mediated activation. Mechanical testing demonstrated that thin COS coatings slightly improved tensile strength without compromising flexibility. Viability assays confirmed that encapsulated B. subtilis remained viable and capable of sporulation, and dual-culture assays demonstrated effective inhibition of Alternaria solani, Fusarium avenaceum, and Rhizoctonia solani. These results indicate that the electrospun/electrosprayed CA/COS platform provides a protective, sustainable, and effective delivery system for biocontrol agents. This approach offers a promising strategy for reducing reliance on synthetic pesticides while maintaining crop protection efficacy. Full article

Calcium carbide slag and silica fume was used as a cement replacement material, combined with excavated soil and EPS (expanded polystyrene) particles, to develop a new green and low-carbon lightweight fluid solidified soil (LFSS). Focusing on the performance regulation of LFSS, this study adopted the paste volume ratio (PV, defined as the volume ratio of paste to total mixture) and the water–binder ratio (w/b) to systematically construct a mix ratio design system and proposed EPS particle interface modification and shell formation technology to improve the weak interface bonding between EPS and the matrix. Firstly, based on the paste volume method, the effects of PV and w/b on the flowability and strength of LFSS were analyzed, and a linear correlation model between the water–solid volume ratio and flowability, as well as a quadratic function prediction model for 28-day strength, was established. Secondly, the “core–shell structure” of EPS particles was constructed by combining EVA (ethylene-vinyl acetate) modification with the coating of calcium carbide slag–silica fume paste. Considering the influence of the coating method, w/b, and material mass ratio on interface bonding comprehensively, the optimal process parameters were determined to achieve the interface reinforcement of EPS particle. The results showed that the water–solid volume ratio was significantly linearly correlated with the flowability of LFSS. PV and w/b respectively controlled the framework formation and pore structure evolution of LFSS, with optimal overall performance at PV = 0.55 and w/b = 2.5. The modification shell formation significantly reduced the shell loss rate of EPS particles and increased the 28-day compressive strength of LFSS by 21.7%. SEM (scanning electron microscope) and EDS (energy-dispersive spectroscopy) analysis further revealed that the shell-formation technique promoted the densification of the interface transition zone, enhanced the deposition of hydration products, and strengthened the synergistic effect of Na and Ca elements, thereby significantly improving interface bonding and overall structural stability. This study established a “mix ratio optimization-modification and shell formation” dual-regulation mechanism, providing an effective technical approach and theoretical basis for the engineering application of calcium carbide slag–silica fume-based LFSS. Full article

The demand for sustainable food packaging is increasing. This study developed a novel ternary composite film based on gellan gum (GG), chitosan (CS), and melatonin (MT) for preserving fresh blueberries. For the first time, MT was incorporated as a functional agent into a GG/CS matrix. Films with varying compositions were prepared and characterized. The GG-dominant film with the highest MT content (G2C-M50, 2:1:0.5 w/w) exhibited optimal properties, including high tensile strength, enhanced flexibility, and a superior moisture barrier. In a 7-day storage trial, this film dramatically extended blueberry shelf-life, reducing the spoilage rate to 2.2% while maintaining 80.5% of the initial anthocyanin content. This success is attributed to the synergy between the robust GG/CS physical network and the multifunctional (antioxidant, antimicrobial) activities of MT. This work presents a highly effective strategy for active food packaging. Full article

Obesity has become so prevalent in many developed countries that it is increasingly perceived as a new norm, despite decades of interventions and drug development. Although research continues to explore novel strategies, no single approach to date has demonstrated sustained success in reducing its population-level dominance. This underscores the need to better evaluate and integrate the growing body of knowledge surrounding obesity’s multifaceted nature. Stamped under one ‘fat’ name, adipose tissue varies by color, location, morphology, composition, and function. This variability suggests a level of complexity that demands deeper investigation. Although the relevance and roles of different adipose types have been extensively discussed throughout the literature, their interdependence, synergy, and collective impact on the body remain to be fully expounded. This review aims to further consolidate and elucidate the available information on the different adipose tissue types and their association with obesity and metabolic health. We also discuss existing and emerging therapeutic strategies, highlighting their respective strengths and limitations. Full article

Background: Cancer-related health outcomes are shaped by the interplay of aging, complex treatment exposures, and individual psychological characteristics. Mitochondrial dysfunction has been implicated as an underlying biological process affecting cancer-related outcomes. This secondary, exploratory pilot analysis aimed to examine age- and treatment-related differences in fatigue, coping self-efficacy, resilience, and skeletal muscle mitochondrial oxidative capacity, measured via phosphorus-31 magnetic resonance spectroscopy (³¹P-MRS). Methods: Eleven cancer survivors (mean age 53.3 ± 12.7 years) were recruited from a larger symptom management trial. Participants underwent ³¹P-MRS to assess mitochondrial function via phosphocreatine recovery time constant (τPCr). Patient-reported outcome measures and physical function assessments were collected. Group comparisons and correlation analyses were conducted to evaluate differences and associations based on age (<65 vs. ≥65 years) and treatment. Because treatment categories were not mutually exclusive and the time since last treatment was not collected, treatment-related comparisons are descriptive only. Given the small available sample size, we conducted this study as exploratory and hypothesis-generating. Results: Older survivors (≥65) had longer τPCr (59.5 vs. 50.1 s), weaker grip strength, higher fatigue, and lower physical performance compared to younger participants, although differences were not statistically significant. Treatment-related patterns were descriptive; participants receiving multiple treatments had shorter τPCr but lower muscular strength, while immunotherapy recipients reported higher fatigue and lower physical activity. Among younger participants, a negative correlation was observed between τPCr and fatigue (ρ = −0.71), and positive correlations were observed with resilience (ρ = 0.61) and coping self-efficacy (ρ = 0.74), reflecting a pattern that warrants cautious interpretation in this small sample. Conclusions: These preliminary results suggest age- and treatment-related differences in fatigue, physical performance, psychological factors, and skeletal muscle mitochondrial bioenergetics. These signals warrant further testing in larger, adequately powered cohorts to clarify mechanisms and inform the development of personalized survivorship care strategies. Full article

Polymer additive manufacturing (AM) has grown rapidly in the past decade, with material extrusion, vat photopolymerization, powder bed fusion and jetting now widely used for functional polymer parts. The mechanical performance of these parts depends strongly on process parameters such as layer height, build orientation, energy input and post-processing conditions, which motivate the development of predictive models for process–property relationships. Classical approaches based on Taguchi designs, ANOVA and response surface methodology have provided valuable insight, but the potential of modern machine learning (ML) techniques is not yet fully exploited. This review surveys recent work on ML-based prediction of mechanical properties of polymer AM parts using process parameters as inputs. Across the literature, well-tuned artificial neural networks, tree-based ensembles and support vector regression typically achieve prediction errors below about 5–10% for strength and modulus, showing that data-driven surrogates can substantially reduce experimental trial-and-error in process optimization. Ongoing challenges include small datasets, missing standardized error metrics, and limited coverage of non-quasi-static phenomena like fatigue, impact, and environmental degradation. Full article

The incorporation of carbon nanotubes (CNT) into cementitious composites has shown strong potential for enhancing mechanical performance. However, conventional dispersion methods, such as ultrasonication and chemical functionalization, are costly, complex, and difficult to scale for construction applications. This study introduces an alternative approach based on the in situ synthesis of CNT on active silica grains, which enables their direct incorporation into mortar formulations. The material was produced via chemical vapor deposition and characterized by scanning electron microscopy, thermogravimetric analysis, energy-dispersive spectroscopy, and Fourier-transform infrared spectroscopy. The resulting nanostructured active silica (NAS) exhibited high carbon content (80.7%) and a 1350% yield, confirming efficient nanotubular deposition. Residual oxygen (9.12%), Mg (0.75%), and Al (0.17%) indicated partial retention of catalytic species, while Fe–Co promoters with Mg–Al modifiers enabled a catalytically active surface favorable to CNT growth. Mortars incorporating NAS restored the flexural strength losses associated with cement replacement by silica, achieving values comparable to the reference mixture and outperforming the silica-only sample; compressive strength increased by ~16.5%. These results demonstrate that NAS promotes effective CNT dispersion at the composite scale without additional dispersion techniques, reduces process complexity, and adds value to commercial silica, providing a scalable route for developing nanostructured cementitious composites for construction applications. Full article

This study developed biodegradable carboxymethyl cellulose (CMC) films crosslinked with citric acid (CA) and X-ray irradiation as sustainable packaging alternatives to reduce plastic use. CMC/CA films were subjected to three doses of X-ray irradiation at two energy levels. CMC/CA films exposed to 10 kGy at 350 kV exhibited a significant three-fold reduction in water solubility compared to non-irradiated films, while also lowering water vapor and oxygen permeability without affecting mechanical strength (p ≤ 0.05). FTIR analysis confirmed the esterification between CMC and CA, which reduced the film hydrophilicity. Onion peel extract (OPE) was added as a bioactive compound to provide antifungal properties. Release studies showed reduced OPE diffusion in irradiated films, with lower release rate constant (k_kp) values. The in situ test on cheese inoculated with Penicillium commune showed that the irradiated bioactive films prolonged shelf life, reducing fungal counts to log 2.3 CFU/g after 18 days compared to log 5.7 CFU/g in control samples. Cheese wrapped with irradiated bioactive films had weight loss from 1.05 to 9.37%, whereas uncovered samples exhibited the highest weight loss (2.07 to 15.07%). Overall, irradiation-assisted crosslinking and OPE incorporation improved film functionality, offering a sustainable and effective packaging solution for cheese preservation within a circular economy framework. Full article

Although intensive outpatient programmes (IOPs) are becoming more prevalent, the evidence base, particularly within the UK, remains limited. Given clinicians’ central role in developing, delivering, and adapting these emerging models of care, their perspectives are essential to understanding how IOPs function in practice. This study therefore aims to address a significant gap in the literature by exploring clinicians’ experiences of working with an IOP and the strengths and opportunities arising from this. Fifteen experienced clinicians participated in individual semi-structured interviews after working with the IOP. Open-ended questions guided the discussions, which were recorded and transcribed verbatim. Data were analysed using the six stages of reflexive thematic analysis. The analysis generated three key themes: (1) Tri-directional Collaboration, (2) Creating Space for Change, and (3) Transitions as Turning Points. Clinicians felt that the IOP provided a structure that strengthened and reinforced the therapeutic alliance between parents and clinicians, helped arrest rapid deterioration, and created space for thoughtful planning. Embedding IOPs within stepped-care frameworks may offer an effective and scalable means of expanding system capacity while delivering enhanced, flexible support during periods of heightened risk. However, longitudinal, mixed-methods evaluations are needed to clarify the sustainability of progress post-IOP and to identify predictors of positive transitions. Full article

In response to the problems of loose soil structure and insufficient water and nutrient retention capacity of sandy bank slopes in arid regions, which constrain vegetation establishment and long-term slope stability, this study focuses on typical sandy soils in arid northwestern China. The desert plant Alhagi sparsifolia, characterized by clonal root sucker reproduction, was selected as the study species to construct and optimize a composite-amended sandy substrate suitable for ecological restoration of bank slopes. Based on an orthogonal experimental design, carboxymethyl cellulose sodium (CMC), straw fibers (SF), and fly ash (FA) were combined at different proportions to assess (i) the vertical distribution of soil water and nutrients in the A. sparsifolia growth habitat, (ii) aggregate structure, (iii) plant trait responses to environmental regulation, and (iv) the shear strength of root–soil composites. The results indicate that when the contents of CMC, SF, and FA were 0.5%, 1.0%, and 5.0%, respectively, the substrate environment promoted a vertically oriented root system with pronounced lateral root development in A. sparsifolia, and the plants adopted an adaptive strategy that balances resource acquisition efficiency and environmental constraints by regulating aboveground growth allocation. This growth pattern reduced the risk of disturbances to slope stability caused by excessive aboveground biomass while maintaining the sand-fixing function of root morphological traits. This study provides a plant functional trait-based regulation strategy for ecological restoration of typical sandy slopes in arid regions, and the proposed composite substrate optimization scheme offers a feasible reference for improving vegetation establishment and substrate performance in sandy habitats. Full article

This study investigates the combined effect of waste-based metakaolin, cellulose fibres and functional waterproofing additive on the physical, mechanical, and durability-related properties of sustainable concrete. A total of 12 concrete mixtures were produced, varying in cellulose fibre content (0–2%), metakaolin waste replacement levels (up to 10% of binder), and functional waterproofing additive content (1%). The experimental program assessed workability, density, compressive and flexural strength, ultrasonic pulse velocity (UPV) and alkali–silica reaction (ASR) resistance. The presence of metakaolin due to high pozzolanic activity (1451 mg/g) and fine particle size enhance the formation of additional C–S–H phases. The incorporation of cellulose fibres (1–2 mm in length) improved crack-bridging ability and structural integrity, while functional waterproofing additive enhanced water tightness. Results demonstrated that the synergistic use of these materials led to improved mechanical performance (flexural strength varies from 4.87 MPa to 6.81 MPa; compressive strength varies from 24.01 MPa to 32.97 MPa) and enhanced notable ASR resistance (decrease in expansion varies from 0.209% to 0.029%). The findings highlight the potential of combining waste-derived pozzolanic and fibrous materials with functional admixtures to develop environmentally friendly and performance-optimized concrete composites. Full article