Search Results (26)

In this work, we present the fabrication of low-cost, stable nanocellulose colloidal suspensions with an average particle size of approximately 160 nm, produced via a straightforward, solvent-free ultrasonication process that eliminates the need for corrosive chemicals or energy-intensive mechanical treatments. The resulting nanocellulose suspensions were utilized as reinforcing additives in urea-formaldehyde (UF) resins, which were subsequently applied in the production of particle boards. This approach addresses the increasing EU regulatory constraints regarding low formaldehyde-to-urea (F/U) molar ratios and the broader need for biobased, eco-friendly alternatives in the wood adhesive industry. Mechanical testing of the nanocellulose reinforced boards revealed notable improvements in the internal bond strength and modulus of rupture, along with a significant decrease in formaldehyde release compared to boards produced with conventional UF resins. These findings highlight the potential of ultrasonication-derived nanocellulose as an environmentally friendly, cost-effective additive to enhance the mechanical performance and reduce the environmental impact of UF-based wood composites. Full article

Limited cadaver availability and health risks from formaldehyde-treated cadavers have increased the need for alternative learning materials in veterinary anatomy education. Two studies were conducted to investigate whether low-fidelity 3D-printed models provide comparable learning outcomes to real specimens. In study 1, veterinary students were assigned to two groups to study the equine distal limb on a real specimen (n = 67) or a 3D model (n = 68). In study 2, students were divided into four groups to study the canine forelimb on a real specimen (n = 44), a 3D model (n = 45), a 3D model followed by a real specimen (n = 47), or the reverse combination (n = 47). Learning outcomes were measured through a knowledge assessment. Afterwards, learning materials were evaluated by students. Both studies showed significantly higher learning outcomes in the groups learning with real specimens compared to other test groups. While students preferred to start learning with 3D models before switching to real specimens, this method had the lowest learning outcomes. However, students emphasized the value of 3D models for independent learning outside the dissection hall and desired further 3D models of other anatomical specimens. Findings indicated that low-fidelity 3D-printed models cannot replace real specimens but are a useful complementary tool in veterinary anatomy education. Full article

To address the problem of environmental pollution caused by the extensive use of low-density polyethylene (LDPE) mulch film, this study developed a novel sprayable mulch using natural fibers and biodegradable polymers. Urea–formaldehyde resin (UF), strengthened with polyvinyl alcohol (PVA), was used as a modifier to induce beneficial physicochemical structural changes in PVA-modified urea–formaldehyde (PUF) resins. Characterization of these resins was conducted using Fourier transformation infrared spectroscopy (FT-IR), thermogravimetric analysis (TGA), and scanning electron microscopy (SEM). Preparation of the biodegradable mulch was conducted using Xuan paper waste residue (XP) as an enhancer, with PUF as the auxiliary agent. The resulting film (PUF-XP) was examined for differences in thickness, morphological characterization, and rate of weight loss, and the effects of different covering films on cucumber growth, root development, soil temperature, and weed control were evaluated. Characterization reveals that when the PVA content was 4% (W4UF), the film had the lowest free formaldehyde content (0.26%) and highest elongation at break (5.70%). In addition, W4UF could easily undergo thermal degradation at 278.4 °C and possessed a close-knit, three-dimensional structural network. W4UF was then mixed with paper powder and water in various proportions to produce three mulch films (BioT1, BioT2, and BioT3) that demonstrated excellent water retention and heat preservation and inhibited weed growth by 68.8–96.8%. Compared to no mulching (NM), BioT1 increased both the specific root length and root density, as well as improved the plant height, stem diameter, and total biomass of the cucumbers by 43.5%, 34.1%, and 33.9%, respectively. Therefore, a mass ratio of paper powder, water, and W4UF of 1:30:2 produced a biodegradable mulch film that could be used as an alternative to LDPE, mitigating the environmental pollution rendered by synthetic plastic mulch films and offering the potential for a sustainable agricultural application. Full article

Simple urea-based chemicals have been used in the textile industry for “ironing-free clothes” for decades. One of the most used chemicals is 1,3-dimethylol-4,5-dihydroxyethyleneurea (DMDHEU), which consists of urea, glyoxal and formaldehyde. DMDHEU and related chemicals are considered safe and environmentally benign. We have therefore synthesized these compounds and studied their properties as H₂S scavengers as alternatives to the “triazine” compounds used in the offshore industry today. Several derivatives are easily available, and we have evaluated their scavenging properties using Raman spectroscopy. This study reveals that this class of compounds scavenges H₂S under conditions similar to the triazine-based scavengers and gives insight into the structural requirements needed. Full article

Considerable efforts have been made to replace formaldehyde-containing adhesives in the manufacturing of wood products, particularly particleboard, with natural alternatives. One promising solution is the liquefaction of lignocellulosic materials such as wood using glycerol (C₃H₈O₃) under sulfuric acid catalysis (H₂SO₄). The aim of this study was to investigate the chemical composition and properties of spruce and oak biomass after liquefaction and to evaluate its potential as a formaldehyde-free adhesive substitute. All samples were liquefied at 150 °C for 120 min in five different wood–glycerol ratios (1:1 to 1:5). The liquefaction percentage, the insoluble residue, the dry matter and the hydroxyl (OH) number were determined as characteristic values for the polymer properties of the liquefied samples. The results showed the liquefaction percentage was up to 90% for spruce and oak. The insoluble residue ranged from 10 to 29% for spruce and from 10 to 22% for oak, the dry matter ranged from 54 to 70% for spruce and from 51 to 62% for oak, while the highest xydroxyl number was 570 mg KOH/g for spruce and 839 mg KOH/g for oak. Based on these results, liquefied wood was shown to be an effective natural alternative to synthetic resins in particleboard adhesives and a way to reduce formaldehyde emissions. This research not only supports environmentally sustainable practices but also paves the way for various bioproducts derived from liquefied biomass and points to future avenues for innovation and development in this area. Full article

This paper describes studies on the preparation of an o–cresol–furfural–formaldehyde resin in the presence of an alkaline catalyst and its modification with n-butanol or 2-ethylhexanol. The novelty of this research is to obtain a furfural-based resin of the resole type and its etherification. Such resins are not described in the literature and also are not available on the market. The obtained resin based on furfural, which can be obtained from agricultural waste, had a low minimum content of free o–cresol < 1 wt.%, furfural < 0.1 wt.%, and formaldehyde < 0.1 wt.%. The resin structure was characterized by mass spectrometry (ESI-MS), FT-IR, and NMR spectroscopy, which showed the presence of hydroxymethylene groups in the resin before modification and alkyl groups derived from n-butanol and 2-ethylhexanol after modification. The etherified resins had a lower viscosity and were more flexible (DSC) than the resin before modification and they can be used as an environmentally friendly, safe, and sustainable alternative to traditional phenol–formaldehyde resins in the paint industry. They demonstrate the ability to create a protective coating with good adherence to metal substrates and an excellent balance of flexibility and hardness. Full article

The inefficient reuse and recycling of plastics—and the current surge of medical and take-out food packaging use during the pandemic—have exacerbated the environmental burden. This impels the development of alternative recycling/upcycling methods to pivot toward circularity. We report the use of the Mannich three-component coupling reaction for the modification of polystyrene (PS) recovered with a 99.1% yield from waste food containers to form functionalized nitrogen and oxygen-rich PS derivatives. A series of functionalized PS with increasing moles of formaldehyde (F) and morpholine (M) (0.5 × 10⁻², 1.0 × 10⁻², and 2.0 × 10⁻² mol) was achieved using a sol–gel-derived Fe-TiO₂ catalyst in a solvent-free, microwave-assisted synthesis. Modified polymers were characterized with viscometry, ¹H NMR, ¹³CNMR (DEPT) FTIR, XPS, UV, and TGA. Functionalization scaled with an increasing ratio, validating the 3CR approach. Further functionalization was constrained by a competing oxidative degradation; however, the varying hydrogen bond density due to nitrogen and oxygen-rich species at higher ratios was shown to compensate for molecular weight loss. The integration of the N-cyclic quaternary ammonium cations exhibited the potential of functionalized polymers for ion-exchange membrane applications. Full article

Soy protein isolate (SPI) is an attractive natural material for preparing wood adhesives that has found broad application. However, poor mechanical properties and unfavorable water resistance of wood composites with SPI adhesive bonds limit its more extensive utilization. The combination of lysine (Lys) with a small molecular structure as a curing agent for modified soy-based wood adhesive allows Lys to penetrate wood pores easily and can result in better mechanical strength of soy protein-based composites, leading to the formation of strong chemical bonds between the amino acid and wood interface. Scanning electron microscopy (SEM) results showed that the degree of penetration of the S/G/L-9% adhesive into the wood was significantly increased, the voids, such as ducts of wood at the bonding interface, were filled, and the interfacial bonding ability of the plywood was enhanced. Compared with the pure SPI adhesive, the corresponding wood breakage rate was boosted to 84%. The wet shear strength of the modified SPI adhesive was 0.64 MPa. When Lys and glycerol epoxy resin (GER) were added, the wet shear strength of plywood prepared by the S/G/L-9% adhesive reached 1.22 MPa, which increased by 29.8% compared with only GER (0.94 MPa). Furthermore, the resultant SPI adhesive displayed excellent thermostability. Water resistance of S/G/L-9% adhesive was further enhanced with respect to pure SPI and S/GER adhesives through curing with 9% Lys. In addition, this work provides a new and feasible strategy for the development and application of manufacturing low-cost, and renewable biobased adhesives with excellent mechanical properties, a promising alternative to traditional formaldehyde-free adhesives in the wood industry. Full article

The study evaluates the performance of laboratory, single-layered particleboards made out of fructose-hydroxymethylfurfural-bishexamethylenetriamine (SusB) adhesive as a sustainable alternative. Several production parameters such as mat moisture content (MMC), adhesive amount and press time were varied and their effect on the bonding efficiency investigated. The internal bond strength (IB) and thickness swelling after 24 h of water immersion (TS) were taken as evaluation criteria for the bonding efficiency. pMDI-bonded particleboards were produced as fossil-based, formaldehyde-free reference. Particleboard testing was complemented by tensile shear strength measurements and thermal analysis. It was found that the MMC has the highest impact on the internal bond strength of SusB-bonded particleboards. In the presence of water, the reaction enthalpy of the main curing reaction (occurring at 117.7 °C) drops from 371.9 J/mol to 270.5 J/mol, leading to side reactions. By reducing the MMC from 8.7%, the IB increases to 0.61 N/mm², thus surpassing P2 requirements of the European standard EN312. At a press factor of 10 s/mm, SusB-bonded particleboards have a similar IB strength as pMDI-bonded ones, with 0.59 ± 0.12 N/mm² compared to 0.59 ± 0.09 N/mm². Further research on the improvement of the dimensional stabilization of SusB-bonded PBs is needed, as the TS ranges from 30–40%. Full article

The objective of this study was to develop a novel melamine-based resin suitable for producing formaldehyde-free leather with improved retanning properties. The resin was prepared by optimized condensation of melamine, glyoxal and metanilic acid. The novel resin was compared with a commercial resin against different parameters. Functional group analysis of the polymer structure and the route of synthesis was verified with the help of FT-IR spectroscopy. A Leica metallurgical microscope coupled with a CCD camera was used for SEM analysis. The results revealed that the mechanical and organoleptic properties of the novel resin were better than those of the commercial melamine resin. Tensile strength, tear strength and percentage elongation of leather were increased by 17.43%, 10.41% and 8.62%, respectively, in the direction parallel to the backbone, while the increases in these parameters were 15.17%, 9.79% and 6.0%, respectively, in the direction perpendicular to the backbone at the same dose. We observed a 100% reduction in free formaldehyde content in retanned leather as well as in effluent produced by the novel melamine resin. Pollution load study of effluent showed reductions in chemical oxygen demand, total suspended solids and total dissolved solids by 9.21%, 5.60% and 6.97%, respectively, for the novel melamine resin, reflecting its improved exhaustion. The fiber structure of the leather produced by the novel melamine resin was more orderly arranged, showing its improved retanning. These results prove that the novel melamine resin is an effective retanning agent suitable for producing formaldehyde-free leather with a reduction in effluent pollution load. This work introduces an alternative to formaldehyde for amino resins to address its carcinogenic effects. Full article

Due to its carcinogenic properties, the presence of formaldehyde in resins and other industrial products has been a subject of great concern in recent years. The presented review focuses on modern alternatives for the production of wood-based panels; i.e., substitutes for formaldehyde in the production of amino and phenolic resins, as well as novel hardeners for formaldehyde-free wood adhesives. Solutions in which formaldehyde in completely replaced are presented in this review. Recent advances indicate that it is possible to develop new formaldehyde-free systems of resins with compatible hardeners. The formaldehyde substitutes that have primarily been tested are glyoxal, glutaraldehyde, furfural, 5-hydroxymethylfurfural, and dimethoxyethanal. The use of such substitutes eliminates the problem of free formaldehyde emission originating from the resin used in the production of wood-based panels. However, these alternatives are mostly characterized by worse reactivity, and, as a result, the use of formaldehyde-free resins may affect the mechanical and strength properties of wood-based panels. Nonetheless, there are still many substantial challenges for the complete replacement of formaldehyde and further research is needed, especially in the field of transferring the technology to industrial practice. Full article

Traditional low-density polyethylene (LDPE) film causes environmental pollution; there is a pressing need to make new bio-based polymers for alternative products, to meet agricultural production needs and for sustainable ecological development. In this study, urea-formaldehyde resin (UF) was modified with polyvinyl alcohol (PVA) and 1–2.5% bio-based sulfonate (BBS). The influence of BBS inducing on the functional groups, microstructure, and thermal behavior was evaluated by Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), differential scanning calorimetry (DSC), and thermogravimetric analysis (TGA). A biodegradable film was prepared with modified UF resin as adhesive and pulp lignocellulose as raw material. The biodegradable mulch film samples were tested for biodegradability, water retention, and cooling soil temperature characters using LDPE and no mulching (NM) as a control. The results showed that with the increase of BBS content, the viscosity and reactivity of modified PUF resin increased, and the free formaldehyde content decreased. A 2%BBS modified PUF resin (2.0BBS/PUF) accelerated the curing process of the PUF resin, formed a flexible macromolecular network structure, and enhanced the toughness of the resin. The biodegradable mulch prepared with PUF, BBS, and 2.0BBS/PUF as adhesives had good water retention. BBS modification increased the degradation rate of mulch by 17.53% compared to the PUF. Three biodegradable films compared with LDPE and NM significantly reduced the soil temperature under summer cucumber cultivation, and the 2.0BBS/PUF coating had the lowest diurnal temperature difference, which provided a suitable soil environment for crop growth. Full article

Formaldehyde-derived wood adhesives have dominated in woody composites production up to now, while facing a significant challenge in non-renewable raw materials and the formaldehyde emission. To solve these problems, an eco-friendly soybean protein-based wood adhesive was explored via the addition of renewable cardanol based epoxy (CBE) as cross-linking agent. The curing mechanism and viscosity of the adhesives were investigated and the bonding performance was evaluated with three-ply plywood. Fourier transformed infrared spectroscopy (FTIR) analysis confirmed the formation of new ether linkages and the consumption of epoxy groups in the cured adhesives, thereby improving the thermal stabilities and cohesion. Plywood bonded with the CBE-modified soybean protein-based adhesive reached the maximum wet shear strength of 1.11 MPa (4 wt.% CBE addition), a 48% increase compared to the control, whereas the viscosity of adhesive decreased by 68.2%. The wet shear strength of the plywood met the requirements of the Chinese National Standard GB/T 9846-2015 for interior plywood application. The formaldehyde-free adhesive with excellent water resistance adhesiveness performance shows great potential in woody composites as an alternative to formaldehyde derived wood adhesives. Full article

Recently, MnO₂-coated polymeric filters have shown promising performance in room-temperature formaldehyde abatement. However, a commonly known concern of MnO₂/polymer composites is either MnO₂ crystal encapsulation or weak adhesion. This work reports a low-cost high-throughput and green strategy to produce binder-free MnO₂-nonwoven composite air filters. The production approach is energy saving and environmentally friendly, which combines MnO₂ crystal coating on bicomponent polyolefin spunbond nonwovens and subsequent heat immobilizing of crystals, followed by the removal of weakly bonded MnO₂. The binder-free MnO₂-nonwoven composites show firm catalyst-fiber adhesion, a gradient porous structure, and excellent formaldehyde removal capability (94.5% ± 0.4%) at room temperature, and the reaction rate constant is 0.040 min⁻¹. In contrast to the MnO₂-nonwoven composites containing organic binders, the HCHO removal of binder-free filters increased by over 4%. This study proposes an alternative solution in producing catalyst/fabric composite filters for formaldehyde removal. Full article

Resole resins have many applications, especially for foam production. However, the use of phenol, a key ingredient in resoles, has serious environmental and economic disadvantages. In this work, lignin extracted from pine wood using a “green” solvent, levulinic acid, was used to partially replace the non-sustainable phenol. The physicochemical properties of this novel resin were compared with resins composed of different types of commercial lignins. All resins were optimized to keep their free formaldehyde content below 1 wt%, by carefully adjusting the pH of the mixture. Substitution of phenol with lignin generally increases the viscosity of the resins, which is further increased with the lignin mass fraction. The addition of lignin decreases the kinetics of gelification of the resin. The type and amount of lignin also affect the thermal stability of the resins. It was possible to obtain resins with higher thermal stability than the standard phenol-formaldehyde resins without lignin. This work provides new insights regarding the development of lignin-based resoles as a very promising sustainable alternative to petrol-based resins. Full article