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Search Results (375)

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Keywords = finite-difference time-domain method (FDTD)

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16 pages, 1413 KB  
Article
Electric Shock Simulation and Risk Assessment in Low-Voltage Distribution Networks Under Unknown Topology: A Two-Stage Approach Based on Smart Meter Data
by Zhe Li, Shoukang Luo, Xiaojia Sun, Yang Li, Yubo Zhang, Chakhung Yeung and Yuxuan Ding
Energies 2026, 19(11), 2723; https://doi.org/10.3390/en19112723 - 5 Jun 2026
Viewed by 193
Abstract
Low-voltage distribution networks are critical for supplying power to end-users, and electric shock safety is a key concern; however, the frequent incompleteness of topology information in practical operations makes it challenging to accurately assess electric shock risks. This paper proposes a two-stage approach [...] Read more.
Low-voltage distribution networks are critical for supplying power to end-users, and electric shock safety is a key concern; however, the frequent incompleteness of topology information in practical operations makes it challenging to accurately assess electric shock risks. This paper proposes a two-stage approach for electric shock simulation and risk assessment in low-voltage distribution networks with completely unknown topology and absent phase-angle measurements, addressing the critical challenge of unavailable, incomplete, or outdated topology information using only conventional smart meter data. It innovatively investigates shock risks under TT, TN-C, and TN-S grounding systems without prior topology knowledge or synchronized phasors. The proposed methodology combines a phase-angle-agnostic data-driven stage and a model-driven stage: the data-driven stage uses an iterative algorithm for topology label matrix estimation and weighted Laplacian matrix reconstruction with hierarchical clustering to identify network structure and line parameters, requiring only active power, reactive power, voltage magnitude, and current magnitude. The model-driven stage adopts modified nodal analysis with the finite-difference time-domain (MNA-FDTD) method to evaluate transient leakage voltage distribution under single-phase-to-ground faults, thereby assessing electric shock risks in line with international safety standards. Key contributions include a practical phase-free topology identification framework, comparative risk analysis of three grounding systems, and an integrated data-model approach for real-world low-observability networks. Simulation results show accurate topology/parameter identification with a relative Frobenius-norm error of only 1.8% even without phase data. TN-S provides the highest safety complying with IEC standards, followed by TN-C and TT under specific conditions, offering a practical solution for utilities lacking detailed topology records. Full article
(This article belongs to the Section A1: Smart Grids and Microgrids)
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32 pages, 3352 KB  
Article
Impact of Increasing Antenna Model Complexity on Microwave Tomography Using DBIM
by Thomas Vasileiou, Maria Koutsoupidou and Panagiotis Kosmas
Sensors 2026, 26(11), 3517; https://doi.org/10.3390/s26113517 - 2 Jun 2026
Viewed by 224
Abstract
In microwave tomography (MWT), reconstruction accuracy is challenged by modeling error, namely the mismatch between the numerical representation and the actual experiment. Accurate antenna modeling is perceived as an important step toward reducing this error, but the actual benefit of increasing antenna model [...] Read more.
In microwave tomography (MWT), reconstruction accuracy is challenged by modeling error, namely the mismatch between the numerical representation and the actual experiment. Accurate antenna modeling is perceived as an important step toward reducing this error, but the actual benefit of increasing antenna model complexity has not been analyzed in the literature. This work fills this gap by conducting a rigorous numerical analysis of the issue using two popular algorithms for its study: the finite-difference time-domain (FDTD) method for antenna and forward-problem modeling, and the distorted Born iterative method (DBIM) for implementing the iterative inversion algorithm. We consider various FDTD tools of increasing complexity to improve the agreement between the FDTD forward solver and an accurate numerical model implemented in commercial software. After validating these models for different antennas, we perform reconstructions for a stroke-detection scenario. Our results show that in a practical setting, sophisticated antenna modeling in the forward solver does not necessarily improve reconstruction accuracy for monopole-type antennas widely used in MWT. Our model-error analysis confirms that calibration is always necessary in practice and that its impact supersedes efforts to model the antenna more faithfully. Full article
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14 pages, 3637 KB  
Article
Luminescence Characteristics of Rare-Earth-Doped Microsphere Cavities
by Chaoqun Gong, Yao Zhou, Nannan Gong, Songzhu Lv, Rui Hong, Chonge Wang, Yue Zhang and Jianhong Zhou
Appl. Sci. 2026, 16(10), 5076; https://doi.org/10.3390/app16105076 - 19 May 2026
Viewed by 299
Abstract
Rare-earth-doped microsphere cavities have attracted significant interest for applications in miniaturized photonic devices due to their unique optical properties. In this work, Yb3+/Er3+ co-doped microsphere cavities were fabricated via a melting method, which enables uniform interior doping at high and [...] Read more.
Rare-earth-doped microsphere cavities have attracted significant interest for applications in miniaturized photonic devices due to their unique optical properties. In this work, Yb3+/Er3+ co-doped microsphere cavities were fabricated via a melting method, which enables uniform interior doping at high and tunable rare-earth concentrations through a simpler and more cost-effective process compared with existing coating and fiber-etching approaches. Whispering gallery modes (WGMs) enhanced upconversion luminescence, which was observed using tapered fiber coupling, producing a vivid green fluorescence ring near the equatorial region of the microsphere. The luminescence characteristics of the microsphere cavity were investigated by measuring the fluorescence spectra under varying excitation powers. The results indicated that the fluorescence emission follows a two-photon absorption process, consistent with the upconversion emission mechanism of Er3+. A finite difference time domain (FDTD) model was employed to simulate the optical field distribution within the microsphere cavity. At a microsphere diameter of 90 μm and a coupling gap of 0 μm, both the 980 nm pump light and the emitted light were effectively confined near the equatorial region of the microsphere, forming WGM confinement patterns. These findings are expected to advance the application of rare-earth-doped microsphere cavities in fields such as biosensing, bioimaging, optical communications, and upconversion microlasers. Full article
(This article belongs to the Section Optics and Lasers)
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17 pages, 2213 KB  
Article
Reconstruction of Ionospheric Electron Density Using Lightning-Generated Whistlers Based on Simulation and Observations
by Tian Xiang, Chen Zhou and Moran Liu
Remote Sens. 2026, 18(8), 1244; https://doi.org/10.3390/rs18081244 - 20 Apr 2026
Viewed by 442
Abstract
Electron density is a fundamental parameter characterizing the ionosphere. Multiple ground-based and space-based detection technologies are applied to detect ionospheric electron density using artificial electromagnetic waves, based on the ionospheric effects of reflection, refraction, incoherent scattering, and doppler shift on radio waves. Lightning-generated [...] Read more.
Electron density is a fundamental parameter characterizing the ionosphere. Multiple ground-based and space-based detection technologies are applied to detect ionospheric electron density using artificial electromagnetic waves, based on the ionospheric effects of reflection, refraction, incoherent scattering, and doppler shift on radio waves. Lightning-generated whistlers (LGWs) constitute a natural signal with a wide spatiotemporal distribution that can substitute for these artificial transmissions, achieving global ionospheric detection. This paper proposes a method for reconstructing ionospheric electron density profiles by comparing simulated and observed dispersion of LGWs. We develop an LGW propagation model based on the finite-difference time-domain (FDTD) algorithm, where the background electron density is derived from the International Reference Ionosphere (IRI) model. The dispersion of simulated whistlers is compared with satellite observations, and a modification factor is introduced to modify the background electron density based on the relationship between dispersion and electron density. The approach is applied to two events, and the electron density modification effect is assessed with independent data sources. The results show that the errors between the modified electron density and the true value in two events are reduced by 62.81% and 69.29%, respectively, confirming the efficacy of the proposed method. Full article
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11 pages, 817 KB  
Article
Retrieval of Sunrise C-Region Electron Density Using Mid-Range VLF Amplitude and FDTD-Based Optimization
by Taira Shirasaki, Yuki Itabashi and Yoshiaki Ando
Atmosphere 2026, 17(4), 350; https://doi.org/10.3390/atmos17040350 - 31 Mar 2026
Cited by 1 | Viewed by 427
Abstract
This study presents a method to retrieve the electron density structure of the transient C-region using very-low-frequency (VLF) Earth–ionosphere waveguide propagation. Here, we demonstrate the identification of the C-region from amplitude variations of a mid-range VLF propagation path that is nearly perpendicular to [...] Read more.
This study presents a method to retrieve the electron density structure of the transient C-region using very-low-frequency (VLF) Earth–ionosphere waveguide propagation. Here, we demonstrate the identification of the C-region from amplitude variations of a mid-range VLF propagation path that is nearly perpendicular to the solar terminator. Previous investigations have primarily relied on phase measurements along long-distance paths with small terminator angles, whereas the present approach utilizes amplitude information under conditions where modal interference is significant. The Faraday International Reference Ionosphere (FIRI-2018) provides an effective semi-empirical model of the lower-ionospheric electron density; however, discrepancies between simulations and observations are often observed at sunrise. To resolve this issue, we introduce Gaussian perturbations to the electron density profile output by FIRI-2018 and optimize their parameters so that finite-difference time-domain (FDTD) simulations reproduce the observed VLF amplitude. The analysis is performed for the 22.2 kHz JJI transmitter signal received in Chofu, Japan over a mid-range propagation path, ∼900 km. The optimized electron density profile successfully reproduces the characteristic features of the C-region, including a temporary enhancement near 65 km altitude during sunrise. These results demonstrate that mid-range VLF amplitude analysis provides a quantitative tool for identifying transient lower- ionospheric structures. Full article
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15 pages, 1663 KB  
Communication
A Simulation-Based Computational Study on the Dielectric Response of Human Hand Tissues to Radiofrequency Radiation from Mobile Devices
by Agaku Raymond Msughter, Jonathan Terseer Ikyumbur, Matthew Inalegwu Amanyi, Eghwubare Akpoguma, Ember Favour Waghbo and Patience Uneojo Amaje
NDT 2026, 4(1), 11; https://doi.org/10.3390/ndt4010011 - 13 Mar 2026
Viewed by 664
Abstract
This study presents a computational, simulation-based investigation of the dielectric response of human hand tissues, skin, fat, muscle, and bone to radiofrequency (RF) electromagnetic fields emitted by mobile devices. The widespread adoption of handheld devices and the deployment of fifth-generation (5G) networks, including [...] Read more.
This study presents a computational, simulation-based investigation of the dielectric response of human hand tissues, skin, fat, muscle, and bone to radiofrequency (RF) electromagnetic fields emitted by mobile devices. The widespread adoption of handheld devices and the deployment of fifth-generation (5G) networks, including millimetre-wave (mmWave) bands, have intensified concerns regarding localized human exposure to RF radiation, particularly in the hand, which serves as the primary interface during device operation. Using validated dielectric property datasets, numerical simulations were performed across the frequency range of 0.5–40 GHz, employing the Finite-Difference Time-Domain (FDTD) method to solve Maxwell’s equations, with analytical evaluations conducted in Maple-18. A heterogeneous multilayer hand phantom was developed, and simulations were conducted under controlled exposure conditions, including a transmitted power of 1 W, antenna gain of 2 dBi, and incident power density of 5 W/m2, consistent with ICNIRP and NCC safety guidelines. Tissue responses were assessed over a temperature range of 10–40 °C to account for thermal variability. The results demonstrate strong frequency- and temperature-dependent behaviour of dielectric properties, intrinsic impedance, reflection coefficient, attenuation, and specific absorption rate (SAR). At lower frequencies (<1 GHz), RF energy penetrated more deeply with distributed absorption and relatively low SAR values, whereas higher frequencies (3–40 GHz) produced highly localized absorption in superficial tissues, particularly skin and muscle. Increasing temperature led to significant increases in permittivity, conductivity, and SAR, with up to a twofold enhancement observed between 10 °C and 40 °C. These findings confirm that 5G and mmWave exposures result in predominantly surface-confined energy deposition in hand tissues. The study provides a robust computational framework for evaluating hand device electromagnetic interactions and offers quantitative insights relevant to antenna design, exposure compliance assessment, and the development of evidence-based safety guidelines. Full article
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13 pages, 2388 KB  
Article
Bandgap Simulations in Randomized 3D Photonic Crystal Supercells
by Marcus Hall and Chris E. Finlayson
Photonics 2026, 13(3), 251; https://doi.org/10.3390/photonics13030251 - 4 Mar 2026
Viewed by 805
Abstract
Periodic supercell lattice structures with elements of random polydispersity disorder were created to simulate the effect of randomization on photonic crystals using finite-difference time domain (FDTD) methods. As a key exemplar system, a three-dimensional “inverse opal” structure of a face-centered cubic lattice with [...] Read more.
Periodic supercell lattice structures with elements of random polydispersity disorder were created to simulate the effect of randomization on photonic crystals using finite-difference time domain (FDTD) methods. As a key exemplar system, a three-dimensional “inverse opal” structure of a face-centered cubic lattice with air spheres in a silicon dielectric was simulated, with sphere radii within supercells following a randomized Gaussian distribution, with characteristic standard deviation and mean. A corresponding ordered lattice with a bandgap with magnitude 3.5% of the normalized frequency range was used as a direct control, with sphere radius 0.34 times the lattice constant a. For a range of standard deviations, up to 5.9% of the 0.34a mean, a Monte Carlo-style approach was adopted, with photonic band properties analyzed over a large number of repeat simulations to ensure statistical significance. The corresponding Gaussian distribution in the resultant photonic bandgap magnitudes is broadened with increasing polydispersity such that an evolving fraction of simulations no longer exhibits a non-zero bandgap. A characteristic pseudo-transition occurs at a standard deviation of approximately 4.1% of the 0.34a mean, above where the frequency of simulations still returning a finite bandgap rapidly diminishes. Some isolated configurations, with a high degree of uniqueness, can exhibit enhanced bandgap properties (greater than the 3.5% benchmark) despite considerable polydisperse disordering; we envisage that these findings point towards the use of engineered randomness in supercell systems to create desired photonic crystal properties and functionality, such as localization and photonic bandgaps. Full article
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25 pages, 12794 KB  
Article
Numerical Simulation Analysis of Ground-Penetrating-Radar-Based Advanced Detection Ahead of the Perfect and Irregular Tunnel Face
by Hao Li, Yanqing Wu and Liang Du
Geosciences 2026, 16(3), 99; https://doi.org/10.3390/geosciences16030099 - 27 Feb 2026
Viewed by 625
Abstract
When examining ground-penetrating radar (GPR)-based advanced detection ahead of the tunnel face for tunnel constructions, existing numerical forward simulations have not effectively accounted for the actual orientation of the strata and the conditions, limiting their theoretical guidance. In this study, we classify tunnel [...] Read more.
When examining ground-penetrating radar (GPR)-based advanced detection ahead of the tunnel face for tunnel constructions, existing numerical forward simulations have not effectively accounted for the actual orientation of the strata and the conditions, limiting their theoretical guidance. In this study, we classify tunnel boring through strata attitudes into horizontal, vertical, positively inclined, reverse inclined, and other anomalous structures. We also consider tunnel faces with different planarity (perfectly smooth or irregular). Using the finite-difference time-domain method with a generalized perfectly matched layer, we simulated 21 forward models for GPR-based advanced detection ahead of the tunnel face. The comparative simulation results indicate that the superposition of reflections from different directions at irregular tunnel faces, lithological interfaces, complicated numerical forward models of typical target geological bodies, making it difficult to distinguish the reflection signals of target geological bodies, and the signal strength in numerical forward modeling profiles with antenna touch with tunnel face is significantly stronger than those without such touch. The flatness of the tunnel face and the close proximity between the antenna and tunnel face are the keys to obtain high-quality original data. These research findings will contribute to improving instruments, data processing, and geologic interpretation in future. Full article
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15 pages, 1756 KB  
Article
Dynamical Correlations and Chimera-like States of Nanoemitters Coupled to Plasmon Polaritons in a Lattice of Conducting Nanorings
by Boris A. Malomed, Gennadiy Burlak, Gustavo Medina-Ángel and Yuri Karlovich
Physics 2026, 8(1), 21; https://doi.org/10.3390/physics8010021 - 16 Feb 2026
Viewed by 567
Abstract
We systematically investigate semiclassical dynamics of the optical field produced by quantum nanoemitters (NEs) embedded in a periodic lattice of conducting nanorings (NRs), in which plasmon polaritons (PPs) are excited. The coupling between PPs and NEs through the radiated optical field leads to [...] Read more.
We systematically investigate semiclassical dynamics of the optical field produced by quantum nanoemitters (NEs) embedded in a periodic lattice of conducting nanorings (NRs), in which plasmon polaritons (PPs) are excited. The coupling between PPs and NEs through the radiated optical field leads to establishment of a significant cross-correlation between NEs, so that their internal dynamics (photocurrent affected by the laser irradiation) depends on the NR’s plasma frequency ωp. The transition to this regime, combined with the nonlinearity of the system, leads to a quite increase in the photocurrent in the NEs, as well as to non-smooth (chimera-like or chaotic) behavior in the critical (transition) region, where considerably small variations in ωp lead to significant changes in the level of the NE pairwise cross-correlations. The chimera-like state is realized as coexistence of locally synchronized and desynchronized NE dynamical states. A fit of the dependence of the critical current on ωp is found, being in agreement with results of numerical simulations. The critical effect may help to design new optical devices, using dispersive nanolattices which are made available by modern nanoelectronics. Full article
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23 pages, 2820 KB  
Article
Empirical Modeling of Current Drawn by High-Speed Circuits for Power Integrity Simulations
by Raul Fizesan
Electronics 2026, 15(3), 713; https://doi.org/10.3390/electronics15030713 - 6 Feb 2026
Viewed by 689
Abstract
Firm requirements on electromagnetic compatibility (EMC) of electronic devices demand low electromagnetic emissions (EMI) of high-speed circuits, especially in the automotive industry. To be able to apply cost-effective anti-perturbative measures that reduce noise emission, critical signal integrity and power integrity (SI/PI) tools are [...] Read more.
Firm requirements on electromagnetic compatibility (EMC) of electronic devices demand low electromagnetic emissions (EMI) of high-speed circuits, especially in the automotive industry. To be able to apply cost-effective anti-perturbative measures that reduce noise emission, critical signal integrity and power integrity (SI/PI) tools are needed for developing high-speed printed circuit board (PCB) designs. This paper presents an efficient method for modeling and analyzing the current drawn by digital ICs based on SPICE modeling data. The profile of the current drawn by the ICs from the power supply is composed of the static supply current and the dynamic supply current. This method enables power integrity engineers, in particular, PhD students and researchers who aim to develop an intuitive understanding of PI phenomena during the pre-layout phase, to see the hidden impact of the supply current on the power rail noise through time domain simulations, using a complex simulation model that integrates the Finite-Difference Time-Domain (FDTD) method of modeling the power and ground plane, with Voltage Regulator Modules (VRMs) and decoupling capacitors. A comparison of simulation results between the proposed models and SPICE IC models is also included to validate the proposed model. Full article
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16 pages, 3301 KB  
Article
Ultra-Wideband Solar Energy Absorption Device Based on Metal–Dielectric Symmetrical Gap Separation
by Jie Luo, Jiangtao Guo, Guangxu Zhao, Yan Shao, Pinghui Wu, Peng Chen and Zao Yi
Coatings 2026, 16(2), 211; https://doi.org/10.3390/coatings16020211 - 6 Feb 2026
Cited by 51 | Viewed by 1386
Abstract
Solar energy stands as one of the most promising green energy sources today. This paper proposes a symmetrical gap-type separated solar absorber and radiator (SETR) featuring a dielectric layer of Al2O3 and metal W as separation columns. Its unique structure [...] Read more.
Solar energy stands as one of the most promising green energy sources today. This paper proposes a symmetrical gap-type separated solar absorber and radiator (SETR) featuring a dielectric layer of Al2O3 and metal W as separation columns. Its unique structure enhances absorption within the effective solar energy spectrum, thereby alleviating solar energy absorption challenges. The finite difference time domain method (FDTD) results show that the SETR achieves an absorption rate of more than 90% in the 280–2096 nm band, which perfectly covers the visible light band range. The weighted average absorption in the 280–2500 nm band is 95.22% under AM1.5 conditions. The thermal emission efficiency at 1500 K is 95.13%, and the thermal radiation loss is less than 5%. Beyond analyzing the results, we also investigated the overall band absorption efficiency of the SETR under varying conditions by adjusting its structural parameters and physical parameters such as materials. This approach enables effective control over the absorption spectrum. Additionally, the proposed SETR is independent of polarization conditions. Both the TM and TE modes are insensitive to large incident angles. In the future, broadband SETRs can be applied to solar energy harvesting, thermoelectric conversion, and imaging fields, as it holds broad application prospects. Full article
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15 pages, 1004 KB  
Article
Approximating Incoherent Monochromatic Light Sources in FDTD Simulations
by Dominik Metzner, Jens Potthoff, Thomas Zentgraf and Jens Förstner
Photonics 2026, 13(2), 128; https://doi.org/10.3390/photonics13020128 - 29 Jan 2026
Viewed by 859
Abstract
Light-emitting diodes (LEDs) are becoming increasingly important across various sectors of the lighting industry and are being used more frequently. In the field of symbolic projection, research is increasingly focusing on implementing light modulation using energy-efficient, incoherent LEDs rather than lasers. Since light [...] Read more.
Light-emitting diodes (LEDs) are becoming increasingly important across various sectors of the lighting industry and are being used more frequently. In the field of symbolic projection, research is increasingly focusing on implementing light modulation using energy-efficient, incoherent LEDs rather than lasers. Since light modulation in micro- and nano-optics is typically achieved through phase modulation, Finite-Difference Time-Domain (FDTD) simulations are employed for analysis. The objective of this article is to investigate different approaches for approximating incoherent monochromatic light sources within FDTD simulations. To this end, two approaches based on dipole sources are considered, as well as a method involving plane waves with modulated wavefronts based on Cosine–Fourier functions and a method based on the superposition of Gaussian beams. These methods are evaluated in terms of their accuracy using a two-dimensional double-slit configuration and are compared against a fully incoherent analytical reference. Full article
(This article belongs to the Special Issue Diffractive Optics and Its Emerging Applications)
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23 pages, 10136 KB  
Article
Three-Dimensional Finite-Difference Time-Domain (3D-FDTD) Simulation of Radio Wave Propagation in Coal Seams
by Kairui Yang, Yanqing Wu, Wanbo Zheng, Jinxiao Dong, Xu Li, Yueming Kang, Zhenghao Jin and Zhixiang Bi
Appl. Sci. 2026, 16(2), 1049; https://doi.org/10.3390/app16021049 - 20 Jan 2026
Viewed by 455
Abstract
During coal mining, detecting subsurface structures (such as faults, voids, collapse columns, etc.) using radio waves in existing mines is hindered by the absence of effective three-dimensional coal seam medium models and simulation methods, adversely affecting the forward modeling of data analysis. This [...] Read more.
During coal mining, detecting subsurface structures (such as faults, voids, collapse columns, etc.) using radio waves in existing mines is hindered by the absence of effective three-dimensional coal seam medium models and simulation methods, adversely affecting the forward modeling of data analysis. This study establishes a Three-Dimensional Finite-Difference Time-Domain (3D-FDTD) radio wave penetration medium model based on coal seam tunnel penetration working conditions to simulate the electric field intensity characteristics of longitudinal and transverse waves in various coal rock mediums. Firstly, a higher-order finite difference method based on Maxwell’s equations is employed to analyze the electric field characteristics of gas-enriched areas under various geological conditions, enabling the exploration of the relationship between the position and size of the electromagnetic wave field strength in different areas. The electromagnetic wave field strength response data are then analyzed during the actual detection process to determine the specific location, shape, and size of the abnormal area. Finally, by comparing the simulation results with an actual engineering project, electromagnetic wave field strength attenuation data were collected from 158 measuring points at a working face of a coal mine in Anhui. The detection results clearly illustrate the changes in electric field intensity (with attenuation coefficients ranging from 0.41 to 0.77 dB/m) in anomalous areas, enabling the forward simulation to accurately determine the position and size of faults. The novelty of this study lies in the establishment of a conductivity-weighted 3D-FDTD model specifically calibrated for complex coal seam environments, which significantly improves the accuracy of fault boundary detection compared to traditional linear inversion methods. Full article
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13 pages, 2867 KB  
Article
Facile Fabrication of Moderate Sensitivity SERS Substrate Using Cu-Plasma Polymer Fluorocarbon Nanocomposite Thin Film
by Sejin Cho, Sung Hyun Kim, Joowon Lee and Sang-Jin Lee
Coatings 2026, 16(1), 108; https://doi.org/10.3390/coatings16010108 - 13 Jan 2026
Viewed by 815
Abstract
Herein, we propose a simple and cost-effective method for fabricating moderate-sensitivity surface-enhanced Raman scattering (SERS) substrates using Cu-plasma polymer fluorocarbon (Cu-PPFC) nanocomposite films fabricated through RF sputtering. The use of a composite target composed of carbon nanotube (CNT), Cu, and polytetrafluoroethylene (PTFE) powders [...] Read more.
Herein, we propose a simple and cost-effective method for fabricating moderate-sensitivity surface-enhanced Raman scattering (SERS) substrates using Cu-plasma polymer fluorocarbon (Cu-PPFC) nanocomposite films fabricated through RF sputtering. The use of a composite target composed of carbon nanotube (CNT), Cu, and polytetrafluoroethylene (PTFE) powders (5:60–80:35–15 wt%) offers the advantage of the simple fabrication of moderate-sensitivity SERS substrates with a single cathode compared to co-sputtering. X-ray photoelectron spectroscopy (XPS) revealed that the film surface was partially composed of metallic Cu with Cu-F bonds and Cu–O bonds, confirming the coexistence of the conducting and plasmon-active domains. UV-VIS spectroscopy revealed a distinct absorption peak at approximately 680 nm, indicating the excitation of localized surface plasmon resonances in the Cu nanoclusters embedded in the plasma polymer fluorocarbon (PPFC) matrix. Atomic force microscopy and grazing incidence small-angle X-ray scattering analyses confirmed that the Cu nanoparticles were uniformly distributed with interparticle distances of 20–35 nm. The Cu-PPFC nanocomposite film with the highest Cu content (80 wt%) exhibited a Raman enhancement factor of 2.18 × 104 for rhodamine 6G, demonstrating its potential as a moderate-sensitivity SERS substrate. Finite-difference time-domain (FDTD) simulations confirmed the strong electromagnetic field localization at the Cu-Cu nanogaps separated by the PPFC matrix, corroborating the experimentally observed SERS enhancement. These results suggest that a Cu-PPFC nanocomposite film, easily fabricated using a composite target, provides an efficient and scalable route for fabricating reproducible, inexpensive, and moderate-sensitivity SERS substrates suitable for practical sensing applications. Full article
(This article belongs to the Special Issue Advanced Optical Film Coating)
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14 pages, 7536 KB  
Article
The Modulated Hot Spot Formation of Void Defects During Laser Initiation in RDX Energetic Crystals
by Zhonghua Yan, Jiaojun Yang, Shuhuai Zhang, Jiangen Zheng, Weiping Li, Nana Pan, Xiang Chen, Xia Xiang, Xiaotao Zu, Bisheng Tan, Xiaodong Yuan and Ranran Fang
Crystals 2026, 16(1), 27; https://doi.org/10.3390/cryst16010027 - 30 Dec 2025
Viewed by 836
Abstract
The interaction between laser irradiation and energetic materials is critically influenced by microstructural void defects that determine local energy deposition and initiation sensitivity. In this work, a three-dimensional finite-difference time-domain (3D-FDTD) method was employed to investigate the modulation effects of void defects on [...] Read more.
The interaction between laser irradiation and energetic materials is critically influenced by microstructural void defects that determine local energy deposition and initiation sensitivity. In this work, a three-dimensional finite-difference time-domain (3D-FDTD) method was employed to investigate the modulation effects of void defects on optical field distributions and hot spot formation in RDX energetic crystals. The influences of void geometry, spatial position, and void number on the modulation of the incident laser beam were systematically analyzed. It reveals that void defects exhibit strong focusing and scattering behavior, leading to localized high-intensity regions both inside RDX bulk crystals and in void defects. For a single void defect, increasing either the width or depth can significantly enhance the peak electric field and thus the laser sensitivity of RDX crystals. When two voids are present, the number of high-intensity spots first increases and then decreases with increasing separation distance, and the strongest modulation effects are obtained at separations of 0.75λ–3λ. Furthermore, as the number of void defects increases, the modulation effect intensifies, promoting the formation of more hot spots. These findings provide quantitative insight into how void structures govern laser–matter interactions in energetic crystals, offering guidance for understanding and controlling laser initiation behavior. Full article
(This article belongs to the Section Inorganic Crystalline Materials)
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