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Keywords = fiberglass support

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25 pages, 3769 KiB  
Review
Finger Orthoses for Rehabilitation―Part I: Biomedical Insights and Additive Manufacturing Innovations
by Alireza Nouri, Lijing Wang, Hamed Bakhtiari, Yuncang Li and Cuie Wen
Prosthesis 2025, 7(3), 62; https://doi.org/10.3390/prosthesis7030062 - 3 Jun 2025
Cited by 1 | Viewed by 1441
Abstract
Background: Finger orthoses are essential for treating injuries, deformities, and disorders of the upper limbs by supporting, immobilizing, or correcting deformities. Recent advances in three-dimensional (3D) printing have significantly enhanced precision and customization compared to traditional fabrication methods such as thermoplastic molding, plaster [...] Read more.
Background: Finger orthoses are essential for treating injuries, deformities, and disorders of the upper limbs by supporting, immobilizing, or correcting deformities. Recent advances in three-dimensional (3D) printing have significantly enhanced precision and customization compared to traditional fabrication methods such as thermoplastic molding, plaster or fiberglass casting, and the use of prefabricated splints. Methods: The present review was conducted using PubMed, Scopus, and other databases with keywords such as “hand therapy”, “additive manufacturing”, “finger and thumb”, and “orthosis”. Only English-language publications were considered, with a primary focus on articles published between 2010 and 2025. Key themes were identified and categorized into conditions necessitating finger orthoses, types and classifications, ergonomic design considerations, and advancements in additive manufacturing. Results: Finger orthoses address musculoskeletal injuries, inflammatory diseases, and neuromuscular disorders. Three-dimensional printing provides enhanced customization, reduced material waste, rapid prototyping, and the ability to create complex geometries, improving patient comfort and functionality. Conclusions: Finger orthoses effectively treat various conditions by supporting and stabilizing fingers. A thorough understanding of anatomy, biomechanics, and fabrication methods is crucial for achieving functional and comfortable designs. Three-dimensional printing offers a transformative approach to producing lightweight, customizable, and cost-effective orthoses, enabling innovative and personalized solutions. By bridging clinical needs and design strategies, this review may guide future innovations in patient-specific orthotic development. Full article
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10 pages, 1124 KiB  
Article
Energetics of a Novel 3D-Printed Custom Ankle Foot Orthosis in a Population of Individuals with Foot Drop: A Pilot Study
by Paolo Caravaggi, Giulia Rogati, Massimiliano Baleani, Roberta Fognani, Luca Zamagni, Maurizio Ortolani, Alessandro Zomparelli, Franco Cevolini, Zimi Sawacha and Alberto Leardini
Appl. Sci. 2025, 15(11), 5885; https://doi.org/10.3390/app15115885 - 23 May 2025
Viewed by 634
Abstract
Passive Dynamic Ankle–Foot Orthoses (PD-AFOs) are medical devices prescribed to individuals with foot drop, a condition characterized by weakness of the ankle dorsiflexor muscles. PD-AFOs can store and release energy during the stance phase of the gait cycle, while supporting the foot in [...] Read more.
Passive Dynamic Ankle–Foot Orthoses (PD-AFOs) are medical devices prescribed to individuals with foot drop, a condition characterized by weakness of the ankle dorsiflexor muscles. PD-AFOs can store and release energy during the stance phase of the gait cycle, while supporting the foot in the swing phase. This study aimed at estimating the energetics of a novel fiberglass-reinforced polyamide custom PD-AFO in a population of mild foot drop patients. Eight PD-AFOs were designed and 3D-printed via selective laser sintering for eight participants with a unilateral foot drop condition. Lower limb kinematics and AFO flexion/extension were recorded during comfortable walking speed via skin marker-based stereophotogrammetry. The stiffness of each AFO was measured via an ad hoc experimental setup. The elastic work performed by the PD-AFO during gait was calculated as the dot product of the calf-shell resisting moment and the rotation angle. The average maximum energy stored by the calf-shell across all PD-AFOs was 0.013 ± 0.005 J/kg. According to this study, 3D-printed custom PD-AFOs made with fiberglass-reinforced polyamide can store some elastic energy, which is released to the ankle during push-off. Further studies should be conducted to assess the effect of this energy return mechanism in improving the gait of individuals with deficits of the ankle plantarflexor muscles. Full article
(This article belongs to the Special Issue 3D Printing Technologies in Biomedical Engineering)
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13 pages, 1955 KiB  
Article
Numerical Study on the Static Bending Response of Cracked Wind Turbine Blades Reinforced with Graphene Platelets
by Hyeong Jin Kim and Jin-Rae Cho
Nanomaterials 2024, 14(24), 2020; https://doi.org/10.3390/nano14242020 - 16 Dec 2024
Cited by 1 | Viewed by 1106
Abstract
With the growing demand for wind energy, the development of advanced materials for wind turbine support structures and blades has garnered significant attention in both industry and academia. In previous research, the authors investigated the incorporation of graphene platelets (GPLs) into wind turbine [...] Read more.
With the growing demand for wind energy, the development of advanced materials for wind turbine support structures and blades has garnered significant attention in both industry and academia. In previous research, the authors investigated the incorporation of graphene platelets (GPLs) into wind turbine blades, focusing on the structural performance and cost-effectiveness relative to conventional fiberglass composites. These studies successfully demonstrated the potential advantages of GPL reinforcement in improving blade performance and reducing the blade’s weight and costs. Building upon prior work, the present study conducts a detailed investigation into the static bending behavior of GPL-reinforced wind turbine blades, specifically examining the impact of crack location and length. A finite element model of the SNL 61.5 m wind turbine blade was rigorously developed and validated through comparison with the existing literature to ensure its accuracy. Comprehensive parametric analyses were performed to assess deflection under various crack lengths and positions, considering both flapwise and edgewise bending deformations. The findings indicate that GPL-reinforced blades exhibit reduced sensitivity to crack propagation compared to traditional fiberglass blades. Furthermore, the paper presents a thorough parametric analysis of the effects of crack location and length on blade performance. Full article
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22 pages, 11955 KiB  
Article
Optimization of Advanced Support Parameters of Surrounding Rock in Tunnels Constructed by ADECO-RS
by Xin Huang, Huaxu Zhang, Jiaqi Guo, Zonglei Zhang and Xiaohui Chao
Buildings 2024, 14(10), 3297; https://doi.org/10.3390/buildings14103297 - 18 Oct 2024
Viewed by 947
Abstract
So as to efficiently address the distortion of surrounding rock in tunnels constructed utilizing ADECO-RS, it is crucial to define suitable parameters for advanced support systems. This study took the 8 # tunnel in the F3 portion of the E60 Expressway in Georgia [...] Read more.
So as to efficiently address the distortion of surrounding rock in tunnels constructed utilizing ADECO-RS, it is crucial to define suitable parameters for advanced support systems. This study took the 8 # tunnel in the F3 portion of the E60 Expressway in Georgia as an engineering case. Initially, the original support scheme underwent systematic monitoring and analysis in the field. Subsequently, the FLAC3D 6.0 software was employed to examine the influence of the advanced pipe roof and tunnel face fiberglass bolts on the steady state of the surrounding rock. Optimization of the support parameters was also proposed. Further, the sensitivity of different parameters to the distortion of the rock surrounding the tunnel was analyzed and ranked via an orthogonal experiment. Ultimately, the effectiveness of the optimization scheme was evaluated by numerical methods and field observations. The findings of the research indicate the following: (1) The monitoring results of the original support parameters show that the irrational design of the support parameters can bring about deformation non-convergence in the tunnel’s surrounding rock. Support parameters must be optimized. (2) The spacing of the pipe roof is positively correlated with the distortion of the surrounding rock. In contrast, the length and the grouting strength are negatively correlated with the distortion of the surrounding rock. The reinforcement density, length, and lap length of glass fiber bolts exhibit an inverse relationship with the distortion of the surrounding rock. (3) The efficacy of pipe shed grouting in mitigating subsidence and deformation of the vault is superior, followed by the spacing of the supports. In contrast, the length of the supports demonstrates comparatively lesser effectiveness. Under optimal parameters, the vault subsidence was reduced by 23.2%, 10.2%, and 2.0%, respectively. The most significant factor controlling the extrusion deformation of the tunnel face is bolt lap length, followed by reinforcement density and then reinforcement length. Extrusion displacement was reduced by 52.5%, 40.3%, and 9.3%, respectively, under the optimal parameters. (4) In comparison to the primordial support system, the optimized support scheme reduces the subsidence of the vault by about one time and the convergence deformation around the cave by about two times. The research findings offer guidance for analogous engineering support design and parameter optimization. Full article
(This article belongs to the Section Building Structures)
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22 pages, 1464 KiB  
Article
Supervised Machine Learning Models for Mechanical Properties Prediction in Additively Manufactured Composites
by Dario Prada Parra, Guilherme Rezende Bessa Ferreira, Jorge G. Díaz, Mateus Gheorghe de Castro Ribeiro and Arthur Martins Barbosa Braga
Appl. Sci. 2024, 14(16), 7009; https://doi.org/10.3390/app14167009 - 9 Aug 2024
Cited by 8 | Viewed by 2841
Abstract
This paper analyses mechanical property prediction through Machine Learning for continuous fiber-reinforced polymer matrix composites printed using the novel Material Extrusion Additive Manufacturing technique. The composite is formed by a nylon-based matrix and continuous fiber (carbon, Kevlar, or fiberglass). From the literature, the [...] Read more.
This paper analyses mechanical property prediction through Machine Learning for continuous fiber-reinforced polymer matrix composites printed using the novel Material Extrusion Additive Manufacturing technique. The composite is formed by a nylon-based matrix and continuous fiber (carbon, Kevlar, or fiberglass). From the literature, the elastic modulus and tensile strength were taken along with printing parameters like fiber content, fiber fill type, matrix lattice, matrix fill density, matrix deposition angle, and fiber deposition angle. Such data were fed to several supervised learning algorithms: Ridge Regression, Bayesian Ridge Regression, Lasso Regression, K-Nearest Neighbor Regression, CatBoost Regression, Decision Tree Regression, Random Forest Regression, and Support Vector Regression. The Machine Learning analysis confirmed that fiber content is the most influential parameter in elasticity (E) and strength (σ). The results show that the K-Nearest Neighbors and CatBoost provided the closest predictions for E and σ compared to the other models, and the tree-based model presented the narrowest error distribution. The computational metrics point to a size versus prediction time tradeoff between these two best predictors, and adopting the prediction time as the most relevant criterion leads to the conclusion that the CatBoost model can be considered, when compared to the others tested, the most appropriate solution to work as a predictor in the task at hand. Full article
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18 pages, 6108 KiB  
Article
In-Depth Study on the Application of a Graphene Platelet-reinforced Composite to Wind Turbine Blades
by Hyeong Jin Kim and Jin-Rae Cho
Materials 2024, 17(16), 3907; https://doi.org/10.3390/ma17163907 - 7 Aug 2024
Cited by 2 | Viewed by 1276
Abstract
Graphene platelets (GPLs) are gaining popularity across various sectors for enhancing the strength and reducing the weight of structures, thanks to their outstanding mechanical characteristics and low manufacturing cost. Among many engineering structures, wind turbine blades are a prime candidate for the integration [...] Read more.
Graphene platelets (GPLs) are gaining popularity across various sectors for enhancing the strength and reducing the weight of structures, thanks to their outstanding mechanical characteristics and low manufacturing cost. Among many engineering structures, wind turbine blades are a prime candidate for the integration of such advanced nanofillers, offering potential improvements in the efficiency of energy generation and reductions in the construction costs of support structures. This study aims to explore the potential of GPLs for use in wind turbine blades by evaluating their impact on material costs as well as mechanical performance. A series of finite element analyses (FEAs) were conducted to examine the variations of mechanical performances—specifically, free vibration, bending, torsional deformation, and weight reductions relative to conventional fiberglass-based blades. Details of computational modeling techniques are presented in this paper. Based on the outcomes of these analyses, the mechanical performances of GPL-reinforced wind turbine blades are reviewed along with a cost–benefit analysis, exemplified through a 5MW-class wind turbine blade. The findings affirm the practicality and benefits of employing GPLs in the design and fabrication of wind turbine blades. Full article
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12 pages, 2845 KiB  
Article
Evaporation-Driven Energy Generation Using an Electrospun Polyacrylonitrile Nanofiber Mat with Different Support Substrates
by Yongbum Kwon, Dai Bui-Vinh, Seung-Hwan Lee, So Hyun Baek, Songhui Lee, Jeungjai Yun, Minwoo Baek, Hyun-Woo Lee, Jaebeom Park, Miri Kim, Minsang Yoo, Bum Sung Kim, Yoseb Song, Handol Lee, Do-Hyun Lee and Da-Woon Jeong
Polymers 2024, 16(9), 1180; https://doi.org/10.3390/polym16091180 - 23 Apr 2024
Cited by 4 | Viewed by 2864
Abstract
Water evaporation-driven energy harvesting is an emerging mechanism for contributing to green energy production with low cost. Herein, we developed polyacrylonitrile (PAN) nanofiber-based evaporation-driven electricity generators (PEEGs) to confirm the feasibility of utilizing electrospun PAN nanofiber mats in an evaporation-driven energy harvesting system. [...] Read more.
Water evaporation-driven energy harvesting is an emerging mechanism for contributing to green energy production with low cost. Herein, we developed polyacrylonitrile (PAN) nanofiber-based evaporation-driven electricity generators (PEEGs) to confirm the feasibility of utilizing electrospun PAN nanofiber mats in an evaporation-driven energy harvesting system. However, PAN nanofiber mats require a support substrate to enhance its durability and stability when it is applied to an evaporation-driven energy generator, which could have additional effects on generation performance. Accordingly, various support substrates, including fiberglass, copper, stainless mesh, and fabric screen, were applied to PEEGs and examined to understand their potential impacts on electrical generation outputs. As a result, the PAN nanofiber mats were successfully converted to a hydrophilic material for an evaporation-driven generator by dip-coating them in nanocarbon black (NCB) solution. Furthermore, specific electrokinetic performance trends were investigated and the peak electricity outputs of Voc were recorded to be 150.8, 6.5, 2.4, and 215.9 mV, and Isc outputs were recorded to be 143.8, 60.5, 103.8, and 121.4 μA, from PEEGs with fiberglass, copper, stainless mesh, and fabric screen substrates, respectively. Therefore, the implications of this study would provide further perspectives on the developing evaporation-induced electricity devices based on nanofiber materials. Full article
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20 pages, 5661 KiB  
Article
A Sustainable Solution with Improved Chemical Resilience Using Repurposed Glass Fibers for Sewage Rehabilitation Pipes
by Devanand Chelot, Shivnarain Ravichandran and Priyank Upadhyaya
Recycling 2024, 9(2), 28; https://doi.org/10.3390/recycling9020028 - 31 Mar 2024
Viewed by 2328
Abstract
This paper introduces a sustainable sewage rehabilitation solution, utilizing repurposed glass fibers for enhanced chemical resilience and environmental conservation. The approach involves dividing a unitary pipe into segments, assembled during commissioning, aiming to reduce installation and transportation costs, particularly in less accessible areas. [...] Read more.
This paper introduces a sustainable sewage rehabilitation solution, utilizing repurposed glass fibers for enhanced chemical resilience and environmental conservation. The approach involves dividing a unitary pipe into segments, assembled during commissioning, aiming to reduce installation and transportation costs, particularly in less accessible areas. Each pipe segment comprises a multi-layered glass fiber composite sandwich, joined by an adhesive reinforced with recycled glass fibers. The glass fiber-reinforced plastic (GFRP) pipe features a core of blended sand impregnated with resin, an outer layer for impact resistance, and an inner layer to prevent corrosion. Chemical resilience is assessed through a 10,000 h strain corrosion study exposing both unitary and two-piece circular GFRP pipes to sulfuric acid in a deflected condition. An apparent hoop tensile test evaluates mechanical integrity before and after exposure. The experimental results reveal that the two-piece pipe with a tongue and groove joint (TGJ) with recycled glass fiber adhesive exhibits superior long-term bending stress and failure strain % compared to unitary pipes. This enhancement is attributed to the TGJ’s improved load-bearing capability and chemical resistance. The failure strain % of the two-piece pipe (1.697%) is higher compared to the unitary pipe (1.2613%). The long-term bending stress of the two-piece pipe obtained is 119.94 MPa whereas the unitary pipe reaches 93.48 MPa at the 50-year mark. The cost analysis supports the adoption of the two-piece pipe over unitary pipes due to a 40% reduction in carbon emissions and transportation cost. The novelty lies in the utilization of multi-piece pipes with enhanced chemical resilience, achieved through the incorporation of milled fiberglass reinforcements in the TGJ. Strain corrosion tests take a long time to perform; hence, an accelerated test is needed to improve the current recommended testing standard. Full article
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15 pages, 3147 KiB  
Article
Numerical Investigation of the Effect of Longitudinal Fiberglass Dowels on Tunnel Face Support in Layered Soils
by Morteza Esmaeili, Jafar Hosseini Manoujan, Jafar Chalabii, Farshad Astaraki and Majid Movahedi Rad
Infrastructures 2023, 8(10), 138; https://doi.org/10.3390/infrastructures8100138 - 24 Sep 2023
Cited by 2 | Viewed by 2354
Abstract
Tunnel face extrusion rigidity is an important factor for solving stress–strain problems in loose ground conditions. In previous studies, the effect of horizontal and vertical soil layering on tunnel excavation face stability in the presence of longitudinal fiberglass dowels has not been studied. [...] Read more.
Tunnel face extrusion rigidity is an important factor for solving stress–strain problems in loose ground conditions. In previous studies, the effect of horizontal and vertical soil layering on tunnel excavation face stability in the presence of longitudinal fiberglass dowels has not been studied. Therefore, in this study, the effect of fiberglass dowels on the stability of the tunnel face in layered soil has been investigated. In this matter, the best dowel arrangement for minimizing the excavation face extrusion in the case of two-layer soil (horizontal or vertical) has been focused on. For this purpose, firstly, a 3D numerical model was validated based on field data provided previously, and then a 3D numerical tunnel was developed in FLAC3D, adopting the Mohr–Coulomb failure criterion. In continuation, the effect of tunnel diameter, initial pressure ranging from 0.5 to 1.5 MPa, and different placement angles of fiberglass dowels ranging from 0 to 9 degrees, with respect to the tunnel longitudinal axes on the tunnel face extrusion, have been investigated. In the case of horizontal layering, the results showed that the maximum extrusion rate is significantly increased where the elasticity modulus of the soil is reduced. In addition, comparing the maximum extrusion in vertical and horizontal layering, it was found that its value in the horizontal mode is much higher than in the vertical. Additionally, the extrusion of the tunnel face has changed significantly due to an alteration in the initial stress. Finally, it was discovered that tunnel face extrusion is not significantly affected by altering the angle of the fiberglass dowels. Full article
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12 pages, 4291 KiB  
Article
Post Placement and Restoration of Endodontically Treated Canines: A Finite Element Analysis Study
by Alexandru Dan Popescu, Dragoș Laurențiu Popa, Andreea Gabriela Nicola, Ionela Teodora Dascălu, Cristian Petcu, Tiberiu Tircă, Mihaela Jana Tuculina, Horia Mocanu, Adela Nicoleta Staicu and Lelia Mihaela Gheorghiță
Int. J. Environ. Res. Public Health 2022, 19(15), 8928; https://doi.org/10.3390/ijerph19158928 - 22 Jul 2022
Cited by 6 | Viewed by 2529
Abstract
The purpose of this study was to show the improved outcomes of restoring endodontically treated teeth with fiberglass posts compared to restorations using metal posts. In our study, we used the Finite Element Method (FEM), which is based on the principle that a [...] Read more.
The purpose of this study was to show the improved outcomes of restoring endodontically treated teeth with fiberglass posts compared to restorations using metal posts. In our study, we used the Finite Element Method (FEM), which is based on the principle that a physical model that supports a given load distributes the stress throughout its volume. We sought to assess what stress results in a tooth when it is restored using a fiberglass post compared to restoration using a metal post. The finite element analysis showed that a system consisting of a tooth with a fiberglass post is more stable in terms of the maximum stress than a system consisting of a tooth with a metal post. The maximum displacements and deformations were obtained in the case of a canine restored with a fiberglass post, which showed that this system had a high elasticity, therefore, higher strength than a canine restored with a metal post, which had high rigidity. Full article
(This article belongs to the Special Issue Oral Health and Dental Caries)
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10 pages, 3029 KiB  
Article
Development of a Novel Passive-Dynamic Custom AFO for Drop-Foot Patients: Design Principles, Manufacturing Technique, Mechanical Properties Characterization and Functional Evaluation
by Paolo Caravaggi, Alessandro Zomparelli, Giulia Rogati, Massimiliano Baleani, Roberta Fognani, Franco Cevolini, Cristina Fanciullo, Arianna Cinquepalmi, Giada Lullini, Lisa Berti and Alberto Leardini
Appl. Sci. 2022, 12(9), 4721; https://doi.org/10.3390/app12094721 - 7 May 2022
Cited by 10 | Viewed by 3838
Abstract
Ankle foot orthoses (AFOs) are medical devices prescribed to support the foot and ankle of drop-foot patients. Passive-dynamic AFOs (PD-AFOs) are an effective solution for less severe cases. While off-the-shelf PD-AFOs are rather inexpensive, they provide poor anatomical fit and do not account [...] Read more.
Ankle foot orthoses (AFOs) are medical devices prescribed to support the foot and ankle of drop-foot patients. Passive-dynamic AFOs (PD-AFOs) are an effective solution for less severe cases. While off-the-shelf PD-AFOs are rather inexpensive, they provide poor anatomical fit and do not account for the required patient-specific biomechanical support. Three-dimensional (3D) scanning and manufacturing technologies allow manufacturing PD-AFOs customized for the patient’s anatomy and functional needs. This paper aimed to report the overall procedure for designing and manufacturing a novel, fiberglass-reinforced polyamide, custom PD-AFO. The feasibility of the proposed procedure was tested in a case study. The methodology can be divided into the following steps: (i) foot and leg scanning, (ii) 3D design, and (iii) additive manufacturing via selective laser sintering. A custom PD-AFO was designed and manufactured for a 67-year-old male drop-foot patient following paraparesis in severe discarthrosis after spine stabilization surgery. AFO mechanical properties were measured via an ad hoc setup based on a servohydraulic testing machine. The functional outcome was assessed via gait analysis in three conditions: shod (no AFO), wearing an off-the-shelf PD-AFO, and wearing the patient-specific PD-AFO. As expected, wearing the PD-AFO resulted in increased ankle dorsiflexion in the swing phase with respect to the shod condition. Sagittal rotations of the hip, knee, and ankle joints were similar across PD-AFO conditions, but the custom PD-AFO resulted in faster walking speed with respect to the off-the-shelf (walking speed: 0.91 m/s versus 0.85 m/s). Additionally, the patient scored the custom PD-AFO as more comfortable (VAS score: 9.7 vs. 7.3). While the present analysis should be extended to a larger cohort of drop-foot patients, the novel PD-AFO seems to offer a valid, custom solution for drop-foot patients not satisfied with standard orthotics. Full article
(This article belongs to the Special Issue Composite and Biomaterials in Biomedical Applications)
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15 pages, 2821 KiB  
Article
Sorption Potential of Different Forms of TiO2 for the Removal of Two Anticancer Drugs from Water
by Kristina Tolić Čop, Dragana Mutavdžić Pavlović, Katarina Duić, Minea Pranjić, Iva Fereža, Igor Jajčinović, Ivan Brnardić and Vedrana Špada
Appl. Sci. 2022, 12(9), 4113; https://doi.org/10.3390/app12094113 - 19 Apr 2022
Cited by 5 | Viewed by 2358
Abstract
Anticancer drugs pose a potential risk to the environment due to their significant consumption and biological effect even at low concentrations. They can leach into soils and sediments, wastewater, and eventually into drinking water supplies. Many conventional technologies with more effective advanced oxidation [...] Read more.
Anticancer drugs pose a potential risk to the environment due to their significant consumption and biological effect even at low concentrations. They can leach into soils and sediments, wastewater, and eventually into drinking water supplies. Many conventional technologies with more effective advanced oxidation processes such as photocatalysis are being extensively studied to find an economical and environmentally friendly solution for the removal of impurities from wastewater as the main source of these pharmaceuticals. Since it is impossible to treat water by photocatalysis if there is no sorption of a contaminant on the photocatalyst, this work investigated the amount of imatinib and crizotinib sorbed from an aqueous medium to different forms of photocatalyst. In addition, based on the sorption affinity studied, the applicability of sorption as a simpler and less costly process was tested in general as a potential route to remove imatinib and crizotinib from water. Their sorption possibility was investigated determining the maximum of sorption, influence of pH, ionic strength, temperature, and sorbent dosage in form of the suspension and immobilized on the fiberglass mesh with only TiO2 and in combination with TiO2/carbon nanotubes. The sorption isotherm data fitted well the linear, Freundlich, and Langmuir model for both pharmaceuticals. An increasing trend of sorption coefficients Kd was observed in the pH range of 5–9 with CRZ, showing higher sorption affinity to all TiO2 forms, which was supported by KF values higher than 116 (μg/g)(mL/μg)1/n. The results also show a positive correlation between Kd and temperature as well as sorbent dosage for both pharmaceuticals, while CRZ sorbed less at higher salt concentration. The kinetic data were best described with a pseudo-second-order model (R2 > 0.995). Full article
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10 pages, 1543 KiB  
Communication
Interfacial Deposition of Titanium Dioxide at the Polarized Liquid–Liquid Interface
by Karolina Kowalewska, Karolina Sipa, Barbara Burnat, Sławomira Skrzypek and Lukasz Poltorak
Materials 2022, 15(6), 2196; https://doi.org/10.3390/ma15062196 - 16 Mar 2022
Cited by 2 | Viewed by 2103
Abstract
The interfacial polycondensation of titanium dioxide was studied at the bare and fiberglass membrane supported polarized liquid–liquid interface (LLI). Titanium dioxide synthesis was derived from the titanium (IV) tetrabutoxide (initially dissolved in the 1,2-dichloroethane) interfacial hydrolysis followed by its condensation. Experimental parameters, such [...] Read more.
The interfacial polycondensation of titanium dioxide was studied at the bare and fiberglass membrane supported polarized liquid–liquid interface (LLI). Titanium dioxide synthesis was derived from the titanium (IV) tetrabutoxide (initially dissolved in the 1,2-dichloroethane) interfacial hydrolysis followed by its condensation. Experimental parameters, such as the pH of the aqueous phase and the influence of titanium alkoxide concentration in the organic phase on the electrochemical signal and material morphology, were investigated. The latter was achieved with fiberglass membranes used as the LLI support during TiO2 interfacial deposition. Cyclic voltammetry was used for the in situ studies, whereas scanning electron microscopy, energy-dispersive X-ray spectroscopy, and infrared spectroscopy were used during ex situ examination. The interfacial polycondensation reaction could be studied using electrified LLI and resulted in the material being a TiO2 film alone or film decorated with particles. Full article
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10 pages, 4537 KiB  
Article
A New Approach for a Safe and Reproducible Seeds Positioning for Diffusing Alpha-Emitters Radiation Therapy of Squamous Cell Skin Cancer: A Feasibility Study
by Giacomo Feliciani, Salvatore Roberto Bellia, Massimo Del Duca, Giorgio Mazzotti, Manuela Monti, Ignazio Stanganelli, Yona Keisari, Itzhak Kelson, Aron Popovtzer, Antonino Romeo and Anna Sarnelli
Cancers 2022, 14(1), 240; https://doi.org/10.3390/cancers14010240 - 4 Jan 2022
Cited by 6 | Viewed by 3145
Abstract
The purpose of this study is to discuss how to use an external radio-opaque template in the Diffusing Alpha-emitters Radiation Therapy (DaRT) technique’s pre-planning and treatment stages. This device would help to determine the proper number of sources for tumour coverage, accounting for [...] Read more.
The purpose of this study is to discuss how to use an external radio-opaque template in the Diffusing Alpha-emitters Radiation Therapy (DaRT) technique’s pre-planning and treatment stages. This device would help to determine the proper number of sources for tumour coverage, accounting for subcutaneous invasion and augmenting DaRT safety. The procedure will be carried out in a first phase on a phantom and then applied to a clinical case. A typical DaRT procedure workflow comprises steps like tumour measurements and delineation, source number assessment, and therapy administration. As a first step, an adhesive fiberglass mesh (spaced by 2 mm) tape was applied on the skin of the patient and employed as frame of reference. A physician contoured the lesion and marked the entrance points for the needles with a radio opaque ink marker. According to the radio opaque marks and metabolic uptake the clinical target volume was defined, and with a commercial brachytherapy treatment planning system (TPS) it was possible to simulate and adjust the spatial seeds distribution. After the implant procedure a CT was again performed to check the agreement between simulations and seeds positions. With the procedure described above it was possible to simulate a DaRT procedure on a phantom in order to train physicians and subsequently apply the novel approach on patients, outlining the major issues involved in the technique. The present work innovates and supports DaRT technique for the treatment of cutaneous cancers, improving its efficacy and safety. Full article
(This article belongs to the Collection Advances in Diagnostic and Interventional Radiology in Oncology)
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15 pages, 6966 KiB  
Article
Evaluation of the Bonding Strength between Various Dental Zirconia Models and Human Teeth for Dental Posts through In Vitro Aging Tests
by Shih-Chieh Lin, Wei-Chun Lin, Tai-Chia Hu, Min Yan and Cheng-Ming Tang
Coatings 2021, 11(9), 1017; https://doi.org/10.3390/coatings11091017 - 25 Aug 2021
Cited by 6 | Viewed by 3854
Abstract
In dentistry, root canal treatment reduces support of the tooth, making it necessary to insert a cylindrical body into the treated tooth to strengthen the crown. In the past, metal or fiberglass was often used. However, metal is too different in color from [...] Read more.
In dentistry, root canal treatment reduces support of the tooth, making it necessary to insert a cylindrical body into the treated tooth to strengthen the crown. In the past, metal or fiberglass was often used. However, metal is too different in color from teeth, so the esthetics are poor, and fiberglass is not as strong as metal. Therefore, an alternative is zirconia, which has the characteristics of high light transmittance, esthetics, good biocompatibility, and high breaking strength. The surface morphology and composition of zirconia ceramics are the key to their bond strength with teeth. Therefore, in this study, the surface characteristics of different brands of zirconia commonly used in clinical practice were evaluated in terms of their surface morphology and surface elements. The surface was modified by sandblasting, and its effect on the bonding strength was discussed. Finally, the stability of the material was evaluated through artificial aging. The results showed that the surface roughness of the zirconia specimens increased after sandblasting, whereas the surface microhardness decreased. The shear test results showed that the 3D shape of the zirconia surface could help improve the bonding strength. The bonding strength of DeguDent increased the most after sandblasting. After 20,000 cycles of aging treatment, the shear strength of each specimen decreased. Field emission scanning electron microscopy results showed that the adhesive remained intact on the surface of zirconia, indicating that adhesion failure occurred between the adhesive and the teeth. This confirms that sandblasting can improve the bonding strength of zirconia. Based on the results obtained, it was concluded that the surface roughness of zirconia is the main factor affecting the bond strength. Full article
(This article belongs to the Special Issue Dentistry and Dental Biomaterials)
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