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Keywords = fiber-reinforced elastomers

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19 pages, 6592 KiB  
Article
Tribological Performance of EPDM and TPV Elastomers Against Glass Fiber-Reinforced Polyamide 66 Composites
by Daniel Foltuț, Ion-Dragoș Uțu and Viorel-Aurel Șerban
Materials 2025, 18(11), 2515; https://doi.org/10.3390/ma18112515 - 27 May 2025
Viewed by 2376
Abstract
This study evaluates the tribological behavior of two elastomeric sealing materials—EPDM and TPV—sliding against 30 wt.% glass fiber-reinforced polyamide 66 (PA66GF30), a composite widely used in structural and guiding components. The application context is low-leakage valve systems in polymer electrolyte membrane fuel cells [...] Read more.
This study evaluates the tribological behavior of two elastomeric sealing materials—EPDM and TPV—sliding against 30 wt.% glass fiber-reinforced polyamide 66 (PA66GF30), a composite widely used in structural and guiding components. The application context is low-leakage valve systems in polymer electrolyte membrane fuel cells (PEMFCs), particularly on the cathodic (air) side, where dry contact and low-friction sealing are critical. Pin-on-disk tests were conducted under three normal loads (1, 3, and 6 N) and sliding speeds of approximately 0.05, 0.10, and 0.15 m/s (92, 183, and 286 RPM). The coefficient of friction (CoF), mass loss, and wear morphology were analyzed. TPV generally exhibited lower and more stable friction than EPDM, with CoF values exceeding 1.0 at 1 N but falling within 0.32–0.52 under typical operating conditions (≥3 N). EPDM reached a maximum mass loss of 0.060%, while TPV remained below 0.022%. Microscopy revealed more severe wear features in EPDM, including tearing and abrasive deformation, whereas TPV surfaces displayed smoother, more uniform wear consistent with its dual-phase morphology. These findings support the selection of TPV over EPDM in dry-contact sealing interfaces involving composite counterfaces in PEMFC systems. Full article
(This article belongs to the Special Issue Mechanical Behavior of Advanced Engineering Materials (2nd Edition))
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38 pages, 4607 KiB  
Review
Rubber-Based Sustainable Textiles and Potential Industrial Applications
by Bapan Adak, Upashana Chatterjee and Mangala Joshi
Textiles 2025, 5(2), 17; https://doi.org/10.3390/textiles5020017 - 8 May 2025
Viewed by 2200
Abstract
This review explores the evolving landscape of sustainable textile manufacturing, with a focus on rubber-based materials for various industrial applications. The textile and rubber industries are shifting towards eco-friendly practices, driven by environmental concerns and the need to reduce carbon footprints. The integration [...] Read more.
This review explores the evolving landscape of sustainable textile manufacturing, with a focus on rubber-based materials for various industrial applications. The textile and rubber industries are shifting towards eco-friendly practices, driven by environmental concerns and the need to reduce carbon footprints. The integration of sustainable textiles in rubber-based products, such as tires, conveyor belts, and defense products, is becoming increasingly prominent. This review discusses the adoption of natural fibers like flax, jute, and hemp, which offer biodegradability and improved mechanical properties. Additionally, it highlights sustainable elastomer sources, including natural rubber from Hevea brasiliensis and alternative plants like Guayule and Russian dandelion, as well as bio-based synthetic rubbers derived from terpenes and biomass. The review also covers sustainable additives, such as silica fillers, nanoclay, and bio-based plasticizers, which enhance performance while reducing environmental impact. Textile–rubber composites offer a cost-effective alternative to traditional fiber-reinforced polymers when high flexibility and impact resistance are needed. Rubber matrices enhance fatigue life under cyclic loading, and sustainable textiles like jute can reduce environmental impact. The manufacturing process involves rubber preparation, composite assembly, consolidation/curing, and post-processing, with precise control over temperature and pressure during curing being critical. These composites are versatile and robust, finding applications in tires, conveyor belts, insulation, and more. The review also highlights the advantages of textile–rubber composites, innovative recycling and upcycling initiatives, addressing current challenges and outlining future perspectives for achieving a circular economy in the textile and rubber sectors. Full article
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18 pages, 3525 KiB  
Article
The Development of a Non-Pneumatic Tire Concept Based on a Fiber-Reinforced Epoxy Composite
by Jonathan Andrä, Tales de Vargas Lisboa and Axel Spickenheuer
Polymers 2025, 17(4), 505; https://doi.org/10.3390/polym17040505 - 15 Feb 2025
Cited by 1 | Viewed by 857
Abstract
This paper investigates the use of glass and carbon fiber-reinforced polymer composites with epoxy matrices for non-pneumatic tires (NPTs), as an alternative to conventional elastomer-based designs. A novel NPT design approach was developed in three steps: (i) a finite element model with isotropic [...] Read more.
This paper investigates the use of glass and carbon fiber-reinforced polymer composites with epoxy matrices for non-pneumatic tires (NPTs), as an alternative to conventional elastomer-based designs. A novel NPT design approach was developed in three steps: (i) a finite element model with isotropic material properties was constructed to identify suitable spoke geometries; (ii) an anisotropic parametric study quantified key parameters influencing the load-bearing capability of two selected concepts from step (i); and (iii) a preferred version was chosen from step (ii) and evaluated under multiple load cases to ensure it met all requirements. The final tire design incorporates thick spiral spokes superimposed with a cosine-like function, showcasing the strengths and limitations of non-elastomeric reinforced polymers for NPT design. This study provides innovative insights into reducing the mass of NPTs and demonstrates the potential of fiber-reinforced polymer composites to achieve more lightweight, durable, and efficient NPT designs in comparison to pneumatic ones. Full article
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24 pages, 11348 KiB  
Article
Innovative and Eco-Friendly Natural Fiber Composites for Dental Impression Materials: A Study on Wheat Bran Reinforcement
by Mohamed A. Aboamer, Abdulmajeed Rasheed Almutairi, Ahmad Alassaf, Tarek M. Alqahtani, Turki F. Almutairi, Ghazwan Najdat Saijari and Nader A. Rahman Mohamed
Polymers 2025, 17(4), 476; https://doi.org/10.3390/polym17040476 - 11 Feb 2025
Viewed by 1316
Abstract
This study addresses the high cost of traditional dental impression materials by introducing a novel composite material reinforced with wheat bran powder, aiming to reduce expenses while maintaining suitable mechanical performance. Tensile and compression test specimens were prepared according to the ASTM D412 [...] Read more.
This study addresses the high cost of traditional dental impression materials by introducing a novel composite material reinforced with wheat bran powder, aiming to reduce expenses while maintaining suitable mechanical performance. Tensile and compression test specimens were prepared according to the ASTM D412 and ASTM D575 standards, respectively, to evaluate the mechanical properties of the pure elastomer and the wheat-bran-reinforced composite. Comparative t-tests were conducted to analyze the tensile and compression strengths of both materials, focusing on their cost-effectiveness and suitability for dental applications. The results demonstrate that the wheat-bran-reinforced composite exhibits compression strength (105 MPa) comparable to that of the pure elastomer while offering controlled deformation and enhanced stiffness under compression. Although the composite shows reduced tensile strength (7 MPa vs. 11 MPa), its performance remains adequate for applications requiring moderate tensile properties. Notably, the new material reduces costs by approximately 50%, making it an economical and sustainable alternative for dental impression materials. This innovation aligns with sustainable practices by incorporating natural fibers and offers dentists a cost-effective solution without compromising on performance. Full article
(This article belongs to the Special Issue Polymers for Medical and Dental Applications, 2nd Edition)
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17 pages, 6327 KiB  
Article
Enhanced Mechanical and Acoustic Properties of Basalt Fiber/Polyurethane Composites by Silane Coupling Agents
by Mengchen Ge, Xiaodong Li, Fei Han, Xing Su, Hao Jiang, Youhao Liu, Yangwei Wang and Meishuai Zou
Polymers 2025, 17(1), 61; https://doi.org/10.3390/polym17010061 - 29 Dec 2024
Cited by 7 | Viewed by 1565
Abstract
Modified basalt microfiber-reinforced polyurethane elastomer composites were prepared by a semi-prepolymer method with two different silane coupling agents (KH550 and KH560) in this study. Infrared spectroscopy was used to quantify the degree of microphase separation and analyze the formation of hydrogen bonding in [...] Read more.
Modified basalt microfiber-reinforced polyurethane elastomer composites were prepared by a semi-prepolymer method with two different silane coupling agents (KH550 and KH560) in this study. Infrared spectroscopy was used to quantify the degree of microphase separation and analyze the formation of hydrogen bonding in polyurethane. The interfacial surface and the morphology of fibers and composites from tensile fracture were examined by a scanning electron microscope. Further measurements were performed on an electronic universal testing machine for characterizing the mechanical properties of composites. Moreover, the loss factor and transmission loss of composite materials were obtained from dynamic thermomechanical analysis and acoustic impedance tube, respectively. The suitable concentrations in the modification of basalt fibers were established at 1% for KH550 and 1.5% for KH560. The best overall performance was obtained in KH550-BMF/PUE group, as the properties increased by 31% in tensile strength, 37% in elongation at break, and 21% in acoustic insulation. Full article
(This article belongs to the Special Issue Processing, Characterization and Modeling of Polymer Nanocomposites)
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15 pages, 3383 KiB  
Article
Improvement of Mechanical and Acoustic Characteristics of Halloysite Nanotube-Reinforced Polyurethane Elastomer Composites and Their Applications
by Mengchen Ge, Xiaodong Li, Xing Su, Hao Jiang, Yangwei Wang, Fei Han and Meishuai Zou
Polymers 2024, 16(21), 3025; https://doi.org/10.3390/polym16213025 - 28 Oct 2024
Cited by 3 | Viewed by 1475
Abstract
Polyurethane incorporated with nanofillers such as carbon nanotubes, basalt fibers, and clay nanoparticles has presented remarkable potential for improving the performance of the polymeric composites. In this study, the halloysite nanofiller-reinforced polyurethane elastomer composites were prepared via the semi-prepolymer method. The impact of [...] Read more.
Polyurethane incorporated with nanofillers such as carbon nanotubes, basalt fibers, and clay nanoparticles has presented remarkable potential for improving the performance of the polymeric composites. In this study, the halloysite nanofiller-reinforced polyurethane elastomer composites were prepared via the semi-prepolymer method. The impact of different halloysites (halloysite nanotubes and halloysite nanoplates) in polyurethane composites was investigated. Scanning electron microscopy, X-ray diffraction, infrared spectroscopy, electronic universal tensile testing, and acoustic impedance tube testing were employed to characterize the morphology, composition, phase separation, mechanical properties, and sound insulation of the samples. The composite fabricated with 0.5 wt% of halloysite nanotubes introduced during quasi-prepolymer preparation exhibited the highest tensile strength (22.92 ± 0.84 MPa) and elongation at break (576.67 ± 17.99%) among all the prepared samples. Also, the incorporation of 2 wt% halloysite nanotubes into the polyurethane matrix resulted in the most significant overall improvements, particularly in terms of tensile strength (~44%), elongation at break (~40%), and sound insulation (~25%) within the low-frequency range of 50 to 1600 Hz. The attainment of these impressive mechanical and acoustic characteristics could be attributed to the unique lumen structure of the halloysite nanotubes, good dispersion of the halloysites in the polyurethane, and the interfacial bonding between the matrix and halloysite fillers. Full article
(This article belongs to the Special Issue Processing, Characterization and Modeling of Polymer Nanocomposites)
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15 pages, 3035 KiB  
Article
Fiber-Reinforced Equibiaxial Dielectric Elastomer Actuator for Out-of-Plane Displacement
by Simon Holzer, Stefania Konstantinidi, Markus Koenigsdorff, Thomas Martinez, Yoan Civet, Gerald Gerlach and Yves Perriard
Materials 2024, 17(15), 3672; https://doi.org/10.3390/ma17153672 - 25 Jul 2024
Cited by 6 | Viewed by 1511
Abstract
Dielectric elastomer actuators (DEAs) have gained significant attention due to their potential in soft robotics and adaptive structures. However, their performance is often limited by their in-plane strain distribution and limited mechanical stability. We introduce a novel design utilizing fiber reinforcement to address [...] Read more.
Dielectric elastomer actuators (DEAs) have gained significant attention due to their potential in soft robotics and adaptive structures. However, their performance is often limited by their in-plane strain distribution and limited mechanical stability. We introduce a novel design utilizing fiber reinforcement to address these challenges. The fiber reinforcement provides enhanced mechanical integrity and improved strain distribution, enabling efficient energy conversion and out-of-plane displacement. We discuss an analytical model and the fabrication process, including material selection, to realize fiber-reinforced DEAs. Numerical simulations and experimental results demonstrate the performance of the fiber-reinforced equibiaxial DEAs and characterize their displacement and force capabilities. Actuators with four and eight fibers are fabricated with 100 μm and 200 μm dielectric thicknesses. A maximal out-of-plane displacement of 500 μm is reached, with a force of 0.18 N, showing promise for the development of haptic devices. Full article
(This article belongs to the Special Issue Interactive Fiber Rubber Composites—Volume II)
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21 pages, 3432 KiB  
Article
The Effect of Thermoplastic Elastomer and Fly Ash on the Properties of Polypropylene Composites with Long Glass Fibers
by George Mihail Teodorescu, Zina Vuluga, Rodica Mariana Ion, Toma Fistoș, Andreea Ioniță, Sofia Slămnoiu-Teodorescu, Jenica Paceagiu, Cristian Andi Nicolae, Augusta Raluca Gabor and Marius Ghiurea
Polymers 2024, 16(9), 1238; https://doi.org/10.3390/polym16091238 - 29 Apr 2024
Cited by 7 | Viewed by 2213
Abstract
A cost-effective solution to the problems that the automotive industry is facing nowadays regarding regulations on emissions and fuel efficiency is to achieve weight reduction of automobile parts. Glass fiber-reinforced polymers are regularly used to manufacture various components, and some parts may also [...] Read more.
A cost-effective solution to the problems that the automotive industry is facing nowadays regarding regulations on emissions and fuel efficiency is to achieve weight reduction of automobile parts. Glass fiber-reinforced polymers are regularly used to manufacture various components, and some parts may also contain thermoplastic elastomers for toughness improvement. This work aimed to investigate the effect of styrene-(ethylene-co-butylene)-styrene triblock copolymer (E) and treated fly ash (C) on the morphological, thermal, and mechanical properties of long glass fiber (G)-reinforced polypropylene (PP). Results showed that the composites obtained through melt processing methods presented similar thermal stability and improved (nano)mechanical properties compared to 25–30 wt.% G-reinforced PP composites (PP-25G/PP-30G). Specifically, the impact strength and surface hardness were greatly improved. The addition of 20 wt.% E led to a 25–39% increase in impact strength and surface elasticity, while the addition of 6.5 wt.% C led to a 16% increase in surface hardness. The composite based on 25 wt.% G, 6.5 wt.% C, and 20 wt.% E presented the best-balanced properties (8–17% increase in impact strength, 38–41% increase in axial strain, and 35% increase in surface hardness) compared with PP-30G/PP-25G. Structural and morphological analysis confirmed the presence of a strong interaction between the components that make the composites. Based on these results, the PP–G–E–C composites could be presented as a viable material for automotive applications. Full article
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24 pages, 10893 KiB  
Article
Experimental Investigation of a Device to Restrain the Horizontal Sliding of U-FREIs
by Paolo Angeli, Giada Frappa and Margherita Pauletta
Appl. Sci. 2024, 14(8), 3380; https://doi.org/10.3390/app14083380 - 17 Apr 2024
Cited by 1 | Viewed by 981
Abstract
Fiber-reinforced elastomeric isolators (FREIs) are composite devices consisting of an alternation of elastomer layers and fiber reinforcement layers. They have mechanical properties comparable to those of conventional Steel-Reinforced Elastomeric Isolators (SREIs). The mechanical and construction characteristics of FREIs, together with their lower cost, [...] Read more.
Fiber-reinforced elastomeric isolators (FREIs) are composite devices consisting of an alternation of elastomer layers and fiber reinforcement layers. They have mechanical properties comparable to those of conventional Steel-Reinforced Elastomeric Isolators (SREIs). The mechanical and construction characteristics of FREIs, together with their lower cost, make them potentially usable on a large scale. However, for their actual use, it is necessary to take into account the current regulations regarding seismic isolation. The application of FREIs provides the absence of anchoring to the structure, but the European Technical Standard UNI EN 15129 requires that the isolators are attached to the structure by mechanical fastening only. In this research work, a constraint device that fulfills this requirement but, at the same time, does not significantly alter the mechanical behavior of FREIs is investigated. The properties of the selected device and its installation method are presented. The results of both a simple compression test and a combined compression and shear test performed on two isolators reinforced by quadri-directional carbon fiber fabrics and two isolators reinforced by bi-directional fabrics are presented. The tests were performed in the absence and presence of the constraint device in order to investigate the modifications produced by the device. Full article
(This article belongs to the Special Issue Advances in Building Materials and Concrete, 2nd Edition)
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18 pages, 10999 KiB  
Article
Investigation of Additive-Manufactured Carbon Fiber-Reinforced Polyethylene Terephthalate Honeycomb for Application as Non-Pneumatic Tire Support Structure
by Siwen Wang, Pan He, Quanqiang Geng, Hui Huang, Lin Sang and Zaiqi Yao
Polymers 2024, 16(8), 1091; https://doi.org/10.3390/polym16081091 - 13 Apr 2024
Cited by 5 | Viewed by 2104
Abstract
A non-pneumatic tire (NPT) overcomes the shortcomings of a traditional pneumatic tire such as wear, punctures and blowouts. In this respect, it shows great potential in improving driving safety, and has received great attention in recent years. In this paper, a carbon fiber-reinforced [...] Read more.
A non-pneumatic tire (NPT) overcomes the shortcomings of a traditional pneumatic tire such as wear, punctures and blowouts. In this respect, it shows great potential in improving driving safety, and has received great attention in recent years. In this paper, a carbon fiber-reinforced polyethylene terephthalate (PET/CF) honeycomb is proposed as a support structure for NPTs, which can be easily prepared using 3D printing technology. The experimental results showed that the PET/CF has high strength and modulus and provides excellent mechanical properties. Then, a finite element (FE) model was established to predict the compression performance of auxetic honeycombs. Good agreement was achieved between the experimental data and FE analysis. The influence of the cell parameters on the compressive performance of the support structure were further analyzed. Both the wall thickness and the vertically inclined angle could modulate the mechanical performance of the NPT. Finally, the application of vertical force is used to analyze the static load of the structure. The PET/CF honeycomb as the support structure of the NPT showed outstanding bearing capacity and stiffness in contrast with elastomer counterparts. Consequently, this study broadens the material selection for NPTs and proposes a strategy for manufacturing a prototype, which provides a reference for the design and development of non-pneumatic tires. Full article
(This article belongs to the Special Issue Advanced Additive Processes and 3D Printing for Polymer Composites)
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16 pages, 4003 KiB  
Article
Carbon Fiber Reinforced Recycled Polypropylene/Polyolefin Elastomer Composites with High Mechanical Properties
by Jin Wei, Abdukeyum Abdurexit, Ruxangul Jamal, Tursun Abdiryim, Jiangan You, Zhiwei Li, Jin Shang and Qian Cheng
Polymers 2024, 16(7), 972; https://doi.org/10.3390/polym16070972 - 3 Apr 2024
Cited by 2 | Viewed by 2924
Abstract
The treatment of waste plastics has gradually become a hot topic in the current scientific community. In response to the needs for high-impact performance R-PP-based composites, carbon fiber (CF)-reinforced polyolefin elastomer (POE)/recycled polypropylene (R-PP) composite (CF/POE/R-PP) was prepared by the mechanical blending method, [...] Read more.
The treatment of waste plastics has gradually become a hot topic in the current scientific community. In response to the needs for high-impact performance R-PP-based composites, carbon fiber (CF)-reinforced polyolefin elastomer (POE)/recycled polypropylene (R-PP) composite (CF/POE/R-PP) was prepared by the mechanical blending method, and its mechanical and thermal properties were systematically studied. It was found that the CF could effectively improve the bending and notch impact strength as well as enhance the thermal stability of POE/R-PP. Furthermore, a stable and dispersed composite interface formed by the combination of maleic anhydride-grafted polypropylene (PP-g-MAH) with the surface of CF and the fusion alkyl chains in R-PP and POE further enhanced the CF’s reinforcing effect. As a result, the addition of 9 wt.% CF successfully improved the heat resistance of the composite material, and the residual carbon content increased by 97.84% after sintering. The composite toughening of POE and CF effectively improved the impact strength of the composite material, with a maximum increase of over 1000%. This study ultimately resulted in a high-impact-resistant composite material. Full article
(This article belongs to the Section Polymer Composites and Nanocomposites)
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16 pages, 4126 KiB  
Article
Low-Density and High-Performance Fiber-Reinforced PP/POE Composite Foam via Irradiation Crosslinking
by Hongfu Li, Tianyu Wang, Changwei Cui, Yuxi Mu and Kangmin Niu
Polymers 2024, 16(6), 745; https://doi.org/10.3390/polym16060745 - 8 Mar 2024
Cited by 2 | Viewed by 2081
Abstract
This study addresses the challenge of achieving foam with a high expansion ratio and poor mechanical properties, caused by the low melt viscosity of semi-crystalline polypropylene (PP). We systematically employ a modification approach involving blending PP with polyolefin elastomers (POE), irradiation crosslinking, and [...] Read more.
This study addresses the challenge of achieving foam with a high expansion ratio and poor mechanical properties, caused by the low melt viscosity of semi-crystalline polypropylene (PP). We systematically employ a modification approach involving blending PP with polyolefin elastomers (POE), irradiation crosslinking, and fiber reinforcement to prepare fiber-reinforced crosslinked PP/POE composite foam. Through optimization and characterization of material composition and processing conditions, the obtained fiber-reinforced crosslinked PP/POE composite foam exhibits both low density and high performance. Specifically, at a crosslinking degree of 12%, the expansion ratio reaches 16 times its original value, and a foam density of 0.057 g/cm3 is reduced by 36% compared to the non-crosslinked PP/POE system with a density of 0.089 g/cm3. The density of the short-carbon-fiber-reinforced crosslinked sCF/PP/POE composite foam is comparable to that of the crosslinked PP/POE system, but the tensile strength reaches 0.69 MPa, representing a 200% increase over the crosslinked PP/POE system and a 41% increase over the non-crosslinked PP/POE system. Simultaneously, it exhibits excellent impact strength, tear resistance, and low heat shrinkage. Irradiation crosslinking is beneficial for enhancing the melt strength and resistance to high temperature thermal shrinkage of PP/POE foam, while fiber reinforcement contributes significantly to improving mechanical properties. These achieve a good complementary effect in low-density and high-performance PP foam modification. Full article
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15 pages, 5362 KiB  
Article
Understanding the Impact of Active-to-Passive Area Ratio on Deformation in One-Dimensional Dielectric Elastomer Actuators with Uniaxial Strain State
by Hans Liebscher, Markus Koenigsdorff, Anett Endesfelder, Johannes Mersch, Martina Zimmermann and Gerald Gerlach
Materials 2023, 16(21), 6897; https://doi.org/10.3390/ma16216897 - 27 Oct 2023
Cited by 5 | Viewed by 1648
Abstract
There is increasing interest in the use of novel elastomers with inherent or modified advanced dielectric and mechanical properties, as components of dielectric elastomer actuators (DEA). This requires corresponding techniques to assess their electro-mechanical performance. A common way to test dielectric materials is [...] Read more.
There is increasing interest in the use of novel elastomers with inherent or modified advanced dielectric and mechanical properties, as components of dielectric elastomer actuators (DEA). This requires corresponding techniques to assess their electro-mechanical performance. A common way to test dielectric materials is the fabrication of actuators with pre-stretch fixed by a stiff frame. This results in the problem that the electrode size has an influence on the achievable actuator displacement and strain, which is detrimental to the comparability of experiments. This paper presents an in-depth study of the active-to-passive ratio with the aim of investigating the influence of the coverage ratio on uniaxial actuator displacement and strain. To model the effect, a simple lumped-parameter model is proposed. The model shows that the coverage ratio for maximal displacement is 50%. To validate the model results, experiments are carried out. For this, a rectangular, fiber-reinforced DEA is used to assess the relation of the coverage ratio and deformation. Due to the stiffness of the fibers, highly anisotropic mechanical properties are achieved, leading to the uniaxial strain behavior of the actuator, which allows the validation of the one-dimensional model. To consider the influence of the simplifications in the lumped-parameter model, the results are compared to a hyperelastic model. In summary, it is shown that the ratio of the active-to-passive area has a significant influence on the actuator deformation. Both the model and experiments confirm that an active-to-passive ratio of 50% is particularly advantageous in most cases. Full article
(This article belongs to the Special Issue Interactive Fiber Rubber Composites—Volume II)
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14 pages, 3752 KiB  
Article
Mechanical and Dynamic Mechanical Behavior of the Lignocellulosic Pine Needle Fiber-Reinforced SEBS Composites
by Dinesh, Bijender Kumar and Jaehwan Kim
Polymers 2023, 15(5), 1225; https://doi.org/10.3390/polym15051225 - 28 Feb 2023
Cited by 14 | Viewed by 3157
Abstract
Aiming to generate wealth from waste and due to their significant fire threats to forests and their rich cellulose content, lignocellulosic pine needle fibers (PNFs) are utilized in this study as a reinforcement of the thermoplastic elastomer styrene ethylene butylene styrene (SEBS) matrix [...] Read more.
Aiming to generate wealth from waste and due to their significant fire threats to forests and their rich cellulose content, lignocellulosic pine needle fibers (PNFs) are utilized in this study as a reinforcement of the thermoplastic elastomer styrene ethylene butylene styrene (SEBS) matrix to create environmentally friendly and economical PNF/SEBS composites using a maleic anhydride-grafted SEBS compatibilizer. The chemical interaction in the composites studied by FTIR shows that strong ester bonds are formed between reinforcing PNF, the compatibilizer, and the SEBS polymer, leading to strong interfacial adhesion between the PNF and SEBS in the composites. This strong adhesion in the composite exhibits higher mechanical properties than the matrix polymer indicating a 1150 % higher modulus and a 50 % higher strength relative to the matrix. Further, the SEM pictures of the tensile-fractured samples of the composites validate this strong interface. Finally, the prepared composites show better dynamic mechanical behavior indicating higher storage and loss moduli and Tg than the matrix polymer suggesting their potential for engineering applications. Full article
(This article belongs to the Section Polymer Composites and Nanocomposites)
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14 pages, 4952 KiB  
Article
Research on Properties of Dopamine and Silicon Carbon Black Modified Basalt Fiber Reinforced Magnetorheological Elastomer
by Shaoqiang Wang, Tianbao Liu, Yi Li and Ce Liang
Polymers 2022, 14(19), 3949; https://doi.org/10.3390/polym14193949 - 21 Sep 2022
Cited by 4 | Viewed by 1990
Abstract
The basalt fibers (BF) and the basalt fibers etched by H2SO4 (BFH) were modified by polydopamine (PDA) or synergistically modified by PDA and silicon carbon black (SiCB). The effects of modified BF, BFH and SiCB on the basic [...] Read more.
The basalt fibers (BF) and the basalt fibers etched by H2SO4 (BFH) were modified by polydopamine (PDA) or synergistically modified by PDA and silicon carbon black (SiCB). The effects of modified BF, BFH and SiCB on the basic mechanical properties and magnetorheological (MR) effects of natural rubber/butadiene rubber-based magnetorheological elastomer precursors (MREs) were investigated. The results show that the tensile strength, tear strength and stress at 300% strain of MREs/PDA-BFH-SiCB prepared with BFH synergistically modified by PDA and SiCB reach the maximum values, which are 9.58 MPa, 24.07 kN/m and 4.13 MPa, respectively. Additionally, its MR effect is more than three times higher than that of MREs before composite modification. Full article
(This article belongs to the Section Polymer Fibers)
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