Search Results (225)

A novel type of multifunctional hybrid membranes combining modified chitosan, functionalized multi-walled carbon nanotubes (MWCNTs), and rare earth element ion-imprinted polymers (REEIIPs) were designed and characterized. The synthesized materials were characterized by thermogravimetric analysis (TGA), scanning electron microscopy (SEM), vibrating sample magnetometry (VSM), X-ray diffraction (XRD), X-ray micro-tomography, and Fourier transform infrared spectroscopy (FTIR). The hybrid membranes were also studied in terms of their mechanical and rheological properties. The key element of the proper preparation of hybrid membranes using the casting method in an external magnetic field was to synthesize membrane components with appropriate magnetic properties. It was found that they showed tunable weak ferromagnetic properties, and the increase in modified nanotube addition caused the rise in the membrane’s saturation magnetization, which for Nd-selective hybrid membranes reached 0.44 emu/g. Also, the increase in thermooxidative stability was noted after introducing functionalized nanotubes into polymer matrices, which, in the case of Gd-selective membranes, were stable even up to 730 °C. The rise in the modified MWCNT addition and selection of appropriate REE ion-imprinted polymers improved mechanical (Rm and E values increase even twice) and rheological parameters (almost double growth of E′ and E″ values) of the tested membranes. Synthesized hybrid membranes showed a high rejection of matrix components and an increase in retention ratio with rising MWCNT-REEIIP addition, ultimately reaching 94.35%, 92.12%, and 90.11% for Nd, Pr, and Gd, respectively. The performed analysis confirmed homogeneous dispersion, phase compatibility, network integration, formation of a complex 3D microstructure, and improved operational stability of created hybrid membranes, which is significant for their future applications in Nd, Pr, and Gd recovery from coal fly ash extracts. Full article

An altermagnet, characterized by its distinctive magnetic properties, may hold potential applications in diverse fields such as magnetic materials, spintronics, data storage, and quantum computing. As a prototypical altermagnet, RuO₂ exhibits spin polarization and demonstrates the advantageous characteristics of high electrical conductivity and low thermal conductivity. These exceptional properties endow it with considerable promise in the emerging field of thermal spintronics. We studied the electronic structure and thermoelectric properties of RuO₂; the constructed RuO₂/TiO₂/RuO₂ all-antiferromagnetic tunnel junction (AFMTJ) exhibited thermally induced magnetoresistance (TIMR), reaching a maximum TIMR of 1756% at a temperature gradient of 5 K. Compared with prior studies on RuO₂-based antiferromagnetic tunnel junctions, the novelty of this work lies in the thermally induced magnetoresistance based on its superior thermoelectric properties. In parallel structures, the spin-down current dominates the transmission spectrum, whereas in antiparallel structures, the spin-up current governs the transmission spectrum, underscoring the spin-polarized thermal transport. In addition, thermoelectric efficiency emphasizes the potential of RuO₂ to link antiferromagnetic robustness with ferromagnetic spin functionality. These findings promote the development of efficient spintronic devices and spin-based storage technology for waste heat recovery and emphasize the role of spin splitting in zero-magnetization systems. Full article

This paper investigates the dependencies between the design parameters of the armature (stator) winding of a high-speed PMSM machine and the electrical losses in its windings resulting from eddy currents. In addition, the factors accounting for the occurrence of parasitic circulating currents, whose presence in the phase windings is associated with the design specificity, are analyzed. Quantitative analysis is carried out by the application of a newly developed mathematical model for the calculation of fundamental and additional losses in a multi-turn coil enclosed in the slots of a ferromagnetic core. The analysis takes into account the actual design of the slot and the conductor, the variable arrangement of individual conductors in the slot, the core saturation and the presence of the excitation field—to represent the main factors that affect the process of additional losses in the slot of the electric machine. The verification of the mathematical model developed in this study was carried out by comparing the distribution of power losses in the slot section of the coil, consisting of several elementary conductors connected in parallel and located in a rectangular open slot, with an identical distribution derived on the basis of an analytical method from the classical circuit theory. For the purpose of confirming the results and conclusions derived from simulation studies, a number of physical experiments were carried out, consisting in determining the power losses in multi-turn coils of different designs. Recommendations have been developed to minimize additional losses by optimizing the arrangement of conductors within the slot, selecting the appropriate cross-sectional size of a single conductor and the saturation level of the tooth zone. Full article

Accumulation of ferrous sulfate residue (FSR) not only occupies land but also results in environmental pollution and waste of iron resource; thus, recycling of iron from FSR has attracted widespread concern. To this end, this article shows fabrication and system analysis of hematite (HM) nanoparticles from FSR via microwave-assisted reduction technology. Physicochemical properties of HM nanoparticles were investigated by multiple analytical techniques including X-ray diffraction (XRD), Fourier transform infrared spectrum (FTIR), Raman spectroscopy, scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), ultraviolet visible (UV-Vis) spectrum, vibrating sample magnetometer (VSM), and the Brunauer–Emmett–Teller (BET) method. Analytic results indicated that the special surface area, pore volume, and pore size of HM nanoparticles with the average particle size of 45 nm were evaluated to be ca. 20.999 m²/g, 0.111 cm³/g, and 0.892 nm, respectively. Magnetization curve indicated that saturation magnetization Ms for as-synthesized HM nanoparticles was calculated to be approximately 1.71 emu/g and revealed weakly ferromagnetic features at room temperature. In addition, HM nanoparticles exhibited noticeable light absorption performance for potential applications in many fields such as electronics, optics, and catalysis. Hence, synthesis of HM nanoparticles via microwave-assisted reduction technology provides an effective way for utilizing FSR and easing environmental burden. Full article

The eddy current testing (ECT) technique enables efficient and non-destructive conductivity measurement. However, conventional ECT is significantly influenced by the thickness of the material, often resulting in the arbitrary selection of excitation frequency. In addition, complex inverse calculations in the eddy current analytical model pose challenges for practical application. This paper proposes a method for measuring the conductivity of non-ferromagnetic materials based on a simplified analytical model. Firstly, the classical Dodd–Deeds analytical model is simplified based on the electromagnetic properties of materials under high-frequency conditions, resulting in a simplified model that directly relates the coil impedance phase to the material’s conductivity. Furthermore, in combination with a finite element method (FEM) analysis, a frequency selection criterion is proposed, and a corresponding measurement method is developed. This method enables direct conductivity calculation by substituting the measured coil impedance phase into the simplified model. Finally, experiments were conducted to verify the effectiveness of the proposed method. The results demonstrate that the proposed method accurately measures the conductivity of non-ferromagnetic materials over a range of 0.5–58.5 MS/m, achieving absolute and relative errors less than 1.05 MS/m and 1.83%, respectively, without requiring complex inversion calculations or multiple calibrations. This advancement in measurement principles provides a new theoretical foundation and technical pathway for developing online inspection systems and portable instrumentation. Full article

Novel diluted magnetic semiconductors derived from BaZn₂As₂ are of considerable importance owing to their elevated Curie temperature of 260 K, the diversity of magnetic states they exhibit, and their prospective applications in multilayer heterojunctions. However, the transition from the intrinsic semiconductor BaZn₂As₂ (BZA) to its doped compounds has not been extensively explored, especially in relation to the significant intermediate compound Ba(Zn,Mn)₂As₂ (BZMA). This study aims to address this gap by performing susceptibility and magnetization measurements, in addition to electronic transport analyses, on these compounds in their single crystal form. Key findings include the following: (1) carriers can significantly modulate the magnetism, transitioning from a non-magnetic BZA to a weak magnetic BZMA, and subsequently to a hard ferromagnet (Ba,K)(Zn,Mn)₂As₂ with potassium (K) doping to BZMA; (2) two distinct sets of metal-insulator transitions were identified, which can be elucidated by the involvement of carriers and the emergence of various magnetic states, respectively; and (3) BZMA exhibits colossal negative magnetoresistance, and by lanthanum (La) doping, a potential n-type (Ba,La)(Zn,Mn)₂As₂ single crystal was synthesized, demonstrating promising prospects for p-n junction applications. This study enhances our understanding of the magnetic interactions and evolutions among these compounds, particularly in the low-doping regime, thereby providing a comprehensive physical framework that complements previous findings related to the high-doping region. Full article

Dental implant papilla (DIP) is susceptible to bacterial adhesion and biofilm formation, and oral pathogenic biofilms can cause persistent oral infections. Enrichment of bacterial biofilms on implants can lead to soft tissue irritation and adjacent bone resorption, severely compromising dental health and potentially leading to periodontitis, implant loss and costly follow-up care. Nanozymes (NZs) are recently used in biofilm removal as they can induce the production of reactive oxygen species (ROS), which can kill bacteria. However, the short lifespan of ROS limits their diffusion distance, and affects their therapeutic efficacy. In this study, we prepared Fe₃O₄ nanoparticles (NZs) with different morphologies: flower-like (F-Fe₃O₄), hollow spherical (M-Fe₃O₄), octahedral (O-Fe₃O₄), and conventional nanoparticles (N-Fe₃O₄). The ferromagnetic properties of Fe₃O₄ NZs allow them to move and penetrate the biofilm under the action of a magnetic field. The saturation magnetic intensities of the four samples were as follows: F-Fe₃O₄ (23.1 emu g⁻¹), M-Fe₃O₄ (73.34 emu g⁻¹), O-Fe₃O₄ (96.06 emu g⁻¹), and N-Fe₃O₄ (52.15 emu g⁻¹). The synergistic combination of photothermal action and catalytic sterilization can effectively remove the biofilm. In addition, the prepared Fe₃O₄ nanozymes were able to maintain high biological activity on the implant surface with some osteogenic effect. Full article

Stem-cell-based therapies rely on the transplantation of stem cells or stem-cell-derived organotypic cells into injured tissues in order to improve or restore tissue function that has been impaired by various diseases. The potential of induced pluripotent stem cells has created many applications in the field of cell therapy, for example. Some applications, for example, those in cardiac cell therapy, suffer from low or very low efficiencies of cell engraftment. Therefore, magnetic cell targeting can be discussed as a method for capturing superparamagnetic nanoparticle-labelled cells in the tissue. Here, we employ superparamagnetic iron oxide nanoparticles (SPIONs) for the intracellular magnetic loading of mesenchymal stem cells (MSCs). In addition, we test a novel strategy of labelling MSCs with ferromagnetic particles. The adhesion assays demonstrate a faster adhesion kinetic of SPIONs-loaded MSC spheroids when a magnetic field was applied, resulting in >50% spheroid adhesion after 30 min. Clustering of cells inside the magnetic field is a second potential mechanism of magnetic cell retention and >80% of cells were found to be aggregated in clusters when placed in a magnetic field for 10 min. SPIONs-loaded and ferromagnetic-particle-loaded cells performed equally in the cell clustering assay. In conclusion, the clustering of SPION-labelled cells explains the observation that magnetic targeting reaches maximal efficiency in vivo after only 10 min of magnetic field application. This has significant implications for magnetic-targeting-assisted stem cell and cell replacement therapies. Full article

The spin wave renormalization processes in two-dimensional van der Waals ferromagnetic monolayers are investigated using an established non-bosonic diagram technique based on the drone-fermion perturbation method. The aim is to evaluate the damping of the long-wavelength spin wave modes at temperatures below the Curie temperature. In addition to the multi-magnon scattering processes, which typically dominate at low temperatures, an additional mechanism is found here that becomes important at elevated temperatures. This spin disorder damping mechanism, which was mainly studied previously in bulk magnetic materials and thicker films, features a spin wave or magnon being scattered by the magnetic disorder that is present when a longitudinal spin component undergoes large thermal fluctuations. The magnetic ordering in the monolayers is stabilized by an out-of-plane single-ion or Ising-type anisotropy, which influences the damping properties. Numerical results are derived for monolayer films of the van der Waals ferromagnet Cr₂Ge₂Te₆. Full article

The newly discovered 2D spin-gapless magnetic materials, which provide new opportunities for combining spin polarization and the quantum anomalous Hall effect, provide a new method for the design and application of memory and nanoscale devices. However, a low Curie temperature (T_C) is a common limitation in most 2D ferromagnetic materials, and research on the topological properties of nontrivial 2D spin-gapless materials is still limited. We predict a novel spin-gapless semiconductor of monolayer h-VN, which has a high Curie temperature (~543 K), 100% spin polarization, and nontrivial topological properties. A nontrivial band gap is opened in the spin-gapless state when considering the spin–orbit coupling (SOC); it can increase with the intensity of spin–orbit coupling and the band gap increases linearly with SOC. By calculating the Chern number and edge states, we find that when the SOC strength is less than 250%, the monolayer h-VN is a quantum anomalous Hall insulator with a Chern number C = 1. In addition, the monolayer h-VN still belongs to the quantum anomalous Hall insulators with its tensile strain. Interestingly, the quantum anomalous Hall effect with a non-zero Chern number can be maintained when using h-BN as the substrate, making the designed structure more suitable for experimental implementation. Our results provide an ideal candidate material for achieving the QAHE at a high Curie temperature. Full article

We study the topological defects and spin structures of rotating SU(3) spin–orbit-coupled spin F$=1$ Bose–Einstein condensates (BECs) in an in-plane quadrupole field with ferromagnetic spin interaction, and the BECs is confined by a harmonic trap. Without rotation, as the quadrupole field strength is increased, the spin F$=1$ BECs with SU(3) spin–orbit coupling (SOC) evolves from the initial Thomas–Fermi phase into the stripe phase; then, it enters a vortex–antivortex cluster state and eventually a polar-core vortex state. In the absence of rotation with the given quadrupole field, the enhancing SU(3) SOC strength can cause a phase transition from a central Mermin–Ho vortex to a vortex–antivortex cluster, subsequently converting to a bending vortex–antivortex chain. In addition, when considering rotation, it is found that this system generates the following five typical quantum phases: a three-vortex-chain cluster structure with mutual angles of approximately ${\displaystyle \frac{2\pi }{3}}$, a tree-fork-like vortex chain cluster, a rotationally symmetric vortex necklace, a diagonal vortex chain cluster, and a density hole vortex cluster. Particularly, the system exhibits unusual topological structures and spin textures, such as a bending half-skyrmion–half-antiskyrmion (meron–antimeron) chain, three half-skyrmion (meron) chains with mutual angles of an approximately ${\displaystyle \frac{2\pi }{3}}$, slightly curved diagonal half-skyrmion (meron) cluster lattice, a skyrmion–half-skyrmion (skyrmion-meron) necklace, and a tree-fork-like half-skyrmion (meron) chain cluster lattice. Full article

In recent years, the discovery of the two-dimensional (2D) intrinsically ferromagnetic monolayer CrI₃ has opened up promising avenues for the advancement of spintronic devices. Nevertheless, the relatively low Curie temperature poses a significant challenge for practical applications. Herein, we determine changes in the superexchange interaction of ferromagnetic coupling caused under pressure by using first-principles calculations and Monte Carlo simulations. Based on the superexchange interaction of ferromagnetic coupling, the effect of applying high pressure on the Curie temperature of monolayer CrI₃ is investigated. With a pressure coefficient of 2.0%, the Curie temperature is enhanced to 97.3 K, which is nearly double that of the monolayer CrI₃ without pressure. In addition, the direction of the easy magnetization axis changes from the out-of-plane to the in-plane one when the pressure coefficient is 1.2%. Meanwhile, the band gap of monolayer CrI₃ can be transformed from indirect to direct by applying high pressure. Our work enriches the process of modulating the magnetic and electronic properties of 2D monolayer materials. Full article

In this paper, the impact of annealing at different temperatures (973 K, 1073 K, and 1123 K for 1 h) on the magnetic and microstructural properties of MnFePSi-based glass-coated microwires is studied. Annealing significantly influences the magnetic and microstructural properties of Mn–Fe–P–Si glass-coated microwires. XRD analysis reveals that increasing the annealing temperature leads to a notable increase in the Fe₂P phase content, reaching a maximum at 1123 K, while simultaneously reducing the presence of secondary phases observed in the as-prepared sample. The reduction in secondary phases in Mn–Fe–P–Si-based microwires, grain size, and internal stress relaxation have a profound impact on their magnetic behavior. High coercivity values are observed in both the as-prepared and annealed samples. However, annealing at higher temperatures (1073 K and 1123 K) results in a significant reduction in coercivity, decreasing from 1200 Oe for the sample annealed at 973 K to 300 Oe and 150 Oe, respectively. In addition, the sample annealed at 1123 K for 1 h shows a notable paramagnetic behavior for loops measured from 200 K to 300 K. Meanwhile, the other samples show ferromagnetic behavior for all measured temperatures from 5 to 300 K. This study highlights the significant potential for tailoring and modifying various magnetic properties of Mn–Fe–P–Si glass-coated microwires, including metamagnetic phase transitions, magnetic behavior, and the control of magnetic response (hardness/softness). Such tailored properties make Mn–Fe–P–Si glass-coated microwires promising candidates for a wide range of applications. Full article

Here, we report the hydrothermal synthesis of BFO (bismuth ferrite) and Bi_1−xAg_xFeO₃ (x = 0.01, 0.02) ultrafine nanopowders. The diffraction patterns show that all obtained particles belong to the R3c space group. On top of that, crystal structure prediction has been accomplished using bond valence calculations (BVCs). Several promising perovskite structures have been proposed together with experimentally observed modifications of BFO as a function of silver doping. Magnetization measurements were performed on BFO, both pure and substituted with 1% and 2% of Ag. The addition of Ag in BFO did not affect the Neel temperature, T_N = 630 K for all samples; instead, the influence of Ag was observed in the increase in the value and irreversibility of magnetization, which are usual characteristics of weak ferromagnetism. Our calculations based on density functional theory (DFT) are in agreement with the experimental finding of enhanced magnetization upon Ag doping of antiferromagnetic BFO, which is assigned to the perturbation of magnetic-type interactions between Fe atoms by Ag substitutional doping. Additionally, electronic and magnetic properties were studied for all phases predicted by the BVCs study. DFT predicted half-metallicity in the γ phase of BFO, which may be of great interest for further study and potential applications. Full article

The printing of composite magnetic filaments using additive manufacturing techniques has emerged as a promising approach for biomedical applications, particularly in bone tissue engineering and magnetic hyperthermia treatments. This study focuses on the synthesis of nanocomposite ferromagnetic filaments and the fabrication of bone tissue scaffolds with time-dependent properties. Three classes of polylactic acid-based biocompatible polymers—EasyFil, Tough and Premium—were combined with magnetite nanoparticles (Fe₃O₄) at concentrations of 10 wt% and 20 wt%. Extruded filaments were evaluated for microstructural integrity, printed dog-bone-shaped specimens were tested for elongation and mechanical properties, and cylindrical scaffolds were analyzed for magnetic hyperthermia performance. The tensile strength of EasyFil polylactic acid decreased from 1834 MPa (0 wt% Fe₃O₄) to 1130 MPa (−38%) at 20 wt% Fe₃O₄, while Premium polylactic acid showed a more moderate reduction from 1800 MPa to 1567 MPa (−13%). The elongation at break was reduced across all samples, with the highest decrease observed in EasyFil polylactic acid (from 42% to 26%, −38%). Magnetic hyperthermia performance, measured by the specific absorption rate, demonstrated that the 20 wt% Fe₃O₄ scaffolds achieved specific absorption rate values of 2–7.5 W/g, depending on polymer type. Our results show that by carefully selecting the right thermoplastic material, we can balance both mechanical integrity and thermal efficiency. Among the tested materials, Tough polylactic acid composites demonstrated the most promising potential for magnetic hyperthermia applications, providing optimal heating performance without significantly compromising scaffold strength. These findings offer critical insights into designing magnetic scaffolds optimized for tissue regeneration and hyperthermia-based therapies. Full article