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19 pages, 7223 KB  
Article
Analysis of Failure Cause in Steel Wire-Reinforced Thermoplastic Composite Pipes for Sour Gas Field Water Transportation
by Zhiming Yu, Shaomu Wen, Jie Wang, Jianwei Lin, Chuan Xie and Dezhi Zeng
Materials 2025, 18(21), 4865; https://doi.org/10.3390/ma18214865 - 24 Oct 2025
Abstract
Steel-reinforced thermoplastic pipe is widely used for water transportation in sour gas fields. However, under the combined effects of corrosive media, internal high pressure, and long-term environmental aging, premature failures such as leakage and bursting often occur. To clarify the failure causes and [...] Read more.
Steel-reinforced thermoplastic pipe is widely used for water transportation in sour gas fields. However, under the combined effects of corrosive media, internal high pressure, and long-term environmental aging, premature failures such as leakage and bursting often occur. To clarify the failure causes and primary contributing factors of the composite pipes, this study conducted a comprehensive analysis through microscopic morphology examination of different typical failure cases, differential scanning calorimetry, Fourier transform infrared spectroscopy, and mechanical property testing. The main failure mechanisms were investigated, and targeted protective measures are proposed. Key findings reveal that the typical failure modes are ductile cracking, aging-induced brittle cracking, and aging creep cracking. These failures follow a mechanism of degradation of the inner and outer polyethylene protective layers, penetration of the medium and corrosion of the steel wires, reduction in pressure-bearing capacity, and eventual structural damage or leakage propagation through the pipe wall. Notably, oxidation induction time values dropped as low as 1.4–17 min—far below the standard requirement of >20 min—indicating severe antioxidant depletion and material aging. The main controlling factors are poor material quality, external stress or mechanical damage, and long-term aging. The polyethylene used for the inner and outer protective layers is critical to the overall pipe performance; therefore, emphasis should be placed on evaluating its anti-aging properties and on protecting the pipe body during installation to ensure the long-term safety and stable operation of the pipeline system. Full article
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20 pages, 9486 KB  
Article
Softening Deformation Characteristics of Tuff Gully Tunnels Under Heavy Rainfall Infiltration and Their Influence on Stability
by Xuejun Liu, Shuo Wang, Wei Mao, Peng Shao, Ruheiyan Muhemaier, Yanjun Li and Liangfu Xie
Appl. Sci. 2025, 15(21), 11385; https://doi.org/10.3390/app152111385 - 24 Oct 2025
Abstract
Heavy rainfall infiltration is a key disaster-inducing factor that triggers the softening of surrounding rock and deformation of support structures in tuff gully tunnels. Based on the gully section of the left line of the Dabao Tunnel of the Leigongshan–Rongjiang Expressway in Guizhou [...] Read more.
Heavy rainfall infiltration is a key disaster-inducing factor that triggers the softening of surrounding rock and deformation of support structures in tuff gully tunnels. Based on the gully section of the left line of the Dabao Tunnel of the Leigongshan–Rongjiang Expressway in Guizhou Province, this study systematically reveals the synergistic disaster-inducing mechanism of “topography-seepage-softening” in tuff gully tunnels under heavy rainfall infiltration through laboratory tests and FLAC3D 3D numerical simulations. The main innovative conclusions are as follows: (1) The “phased” attenuation law of tuff mechanical parameters was quantified, and the critical water content for significant strength deterioration was determined to be 2.5%, with a saturated softening coefficient of 0.59. These results provide key data for early warning and evaluation of similar projects. (2) A “convergence-disorder” distribution pattern of pore water pressure controlled by gully topography was revealed. It was found that the rock mass directly below the aqueduct exhibits a disordered zone with downward-extending pore water pressure due to fluid convergence, with the maximum pore water pressure reaching 0.55 MPa. This clarifies the essence that tunnel stability is controlled by the coupling of topography and seepage field. (3) The key sensitive areas for tunnel stability—namely the gully bottom, arch haunches, and the area below the aqueduct—were accurately identified. The significant increase in displacement of these areas after rock stratum softening was quantified (e.g., the displacement at the crown of the secondary lining increased from 3 mm to 4 mm, and the influence range expanded to the arch haunches). This study clarifies the deformation characteristics and instability mechanism of tuff gully tunnels under heavy rainfall from two aspects: the “internal mechanism of rock mass softening” and the “external condition of topographic seepage control.” It can provide a theoretical basis and key technical pathway for disaster prevention and control as well as stability design of similar tunnels. Full article
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10 pages, 605 KB  
Case Report
Adaptation of Endoluminal Vacuum Therapy via Extra-Luminal Access in the Treatment of a High Pharyngeal Fistula: Technical Feasibility and Outcome
by Bogdan-Mihnea Ciuntu, Daniel Vasile Timofte, Andreea Ludușanu, Mihaela Corlade-Andrei, Roxana Elena Ciuntu, Irina Mihaela Abdulan, Alexandra-Simona Zamfir, Adelina Tanevski, Mădălina Maxim, Gheorghe Balan, Anca Bordianu and Bogdan Cobzeanu
Life 2025, 15(11), 1660; https://doi.org/10.3390/life15111660 - 23 Oct 2025
Abstract
Background: Perforation of the piriform sinus is a rare but severe clinical event that can lead to cervico-thoracic mediastinitis, a life-threatening condition requiring urgent multidisciplinary intervention. Among its etiologies, accidental ingestion of foreign bodies, including dental prostheses, is uncommon but poses significant [...] Read more.
Background: Perforation of the piriform sinus is a rare but severe clinical event that can lead to cervico-thoracic mediastinitis, a life-threatening condition requiring urgent multidisciplinary intervention. Among its etiologies, accidental ingestion of foreign bodies, including dental prostheses, is uncommon but poses significant risks due to the anatomical vulnerability of the hypopharyngeal structures. Methods: We report a rare case of right piriform sinus perforation secondary to the ingestion of a dental prosthesis, complicated by cervico-mediastinitis, sepsis, tracheostomy, and sacral pressure ulcer. The clinical course required emergency surgical intervention and intensive supportive care. Results: A novel aspect of this case was the use of the Endoscopic Vacuum-Assisted Closure (EVAC) irrigation system as an adjunctive technique in the management of deep cervical drainage. Rather than approaching the fistula from within the lumen, the team created a controlled external drainage system, adaptation of the vacuum-assisted closure therapy directly over the fistulous tract. Conclusions: This case highlights the importance of early diagnosis, high clinical suspicion and coordinated management in the treatment of piriform sinus perforations. It also illustrates the potential applicability of modern technologies such as negative pressure irrigation in the complex management of deep neck infections and mediastinitis. Full article
(This article belongs to the Section Medical Research)
24 pages, 41034 KB  
Article
A Novel Design of a Sliding Mode Controller Based on Modified ERL for Enhanced Quadcopter Trajectory Tracking
by Ahmed Abduljabbar Mahmood, Fernando García and Abdulla Al-Kaff
Drones 2025, 9(11), 737; https://doi.org/10.3390/drones9110737 - 23 Oct 2025
Abstract
This paper introduces a new approach to obtain robust tracking performance, disturbance resistance, and input variation resistance, and eliminate chattering phenomena in the control signal and output responses of an unmanned aerial vehicle (UAV) quadcopter with parametric uncertainty. This method involves a modified [...] Read more.
This paper introduces a new approach to obtain robust tracking performance, disturbance resistance, and input variation resistance, and eliminate chattering phenomena in the control signal and output responses of an unmanned aerial vehicle (UAV) quadcopter with parametric uncertainty. This method involves a modified exponential reaching law (ERL) of the sliding mode control (SMC) based on a Gaussian kernel function with a continuous nonlinear Smoother Signum Function (SSF). The smooth continuous signum function is proposed as a substitute for the signum function to prevent the chattering effect caused by the switching sliding surface. The closed-loop system’s stability is ensured according to Lyapunov’s stability theory. Optimal trajectory tracking is attained based on particle swarm optimization (PSO) to select the controller parameters. A comparative analysis with a classical hierarchical SMC based on different ERLs (sign function, saturation function, and SSF) is presented to further substantiate the superior performance of the proposed controller. The outcomes of the simulation prove that the suggested controller has much better effectiveness, unknown disturbance resistance, input variation resistance, and parametric uncertainty than the other controllers, which produce chattering and make the control signal range fall within unrealistic values. Furthermore, the suggested controller outperforms the classical SMC by reducing the tracking integral mean squared errors by 96.154% for roll, 98.535% for pitch, 44.81% for yaw, and 22.8% for altitude under normal flight conditions. It also reduces the tracking mean squared errors by 99.05% for roll, 99.26% for pitch, 40.18% for yaw, and 99.998% for altitude under trajectory tracking flight conditions in the presence of external disturbances. Therefore, the proposed controller can efficiently follow paths in the presence of parameter uncertainties, input variation, and external disturbances. . Full article
(This article belongs to the Special Issue Path Planning, Trajectory Tracking and Guidance for UAVs: 3rd Edition)
12 pages, 1176 KB  
Article
Characterizing Surface Waviness of Aluminum Alloy: An Approach to Minimize Post-Processing in Wire Arc Additive Manufacturing (WAAM) Production
by Shammas Mahmood Shafi, Anis Fatima and Nicholas V. Hendrickson
J. Manuf. Mater. Process. 2025, 9(11), 347; https://doi.org/10.3390/jmmp9110347 - 23 Oct 2025
Abstract
Wire Arc Additive Manufacturing (WAAM) offers high deposition rates and cost-effective production of large metal components but suffers from poor surface quality, particularly surface waviness, which increases post-processing requirements and limits industrial adoption. Since waviness directly impacts structural integrity, resource efficiency, and industrial [...] Read more.
Wire Arc Additive Manufacturing (WAAM) offers high deposition rates and cost-effective production of large metal components but suffers from poor surface quality, particularly surface waviness, which increases post-processing requirements and limits industrial adoption. Since waviness directly impacts structural integrity, resource efficiency, and industrial applicability, understanding how process parameters govern this feature is critical for reducing post-processing requirement. This study systematically investigated the influence of voltage, travel speed, and wire feed speed on surface waviness in aluminum alloy walls fabricated by WAAM. A two-level factorial design with 16 experiments was conducted, and surface waviness was quantified using height gauge measurements relative to the expected bead height. Statistical analyses, including ANOVA and multiple linear regression, were applied to evaluate parameter significance. The results revealed that wire feed speed was the most influential parameter, showing a strong positive correlation with waviness due to excess material deposition. Voltage exhibited a weaker, stabilizing effect, with higher values marginally reducing waviness through improved arc stability, while travel speed had negligible influence within the studied range. The regression model achieved an R2 0.389, with validation tests indicating reasonable predictive accuracy. These findings demonstrate that controlling wire feed speed is critical for minimizing waviness, while higher voltage may serve as a secondary stabilizing factor. The study was limited to surface waviness; however, future work should consider the role of thermal accumulation, inter-pass temperature, and external disturbances on surface stability. Such insights could enable adaptive parameter control strategies to further reduce post-processing needs and enhance the industrial viability of WAAM. Full article
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23 pages, 981 KB  
Article
Mediterranean and MIND Dietary Patterns and Cognitive Performance in Multiple Sclerosis: A Cross-Sectional Analysis of the UK Multiple Sclerosis Register
by Maggie Yu, Steve Simpson-Yap, Annalaura Lerede, Richard Nicholas, Shelly Coe, Thanasis G. Tektonidis, Eduard Martinez Solsona, Rod Middleton, Yasmine Probst, Adam Hampshire, Elasma Milanzi, Guangqin Cui, Rebekah Allison Davenport, Sandra Neate, Mia Pisano, Harry Kirkland and Jeanette Reece
Nutrients 2025, 17(21), 3326; https://doi.org/10.3390/nu17213326 - 22 Oct 2025
Abstract
Background: Multiple sclerosis (MS) is a chronic auto-immune neuroinflammatory disorder presenting as a range of systemic and neurological symptoms, including cognitive impairment. Emerging evidence suggests that diets targeting brain health—such as the Mediterranean (MED) and Mediterranean-DASH Intervention for Neurodegenerative Delay (MIND) diets—may improve [...] Read more.
Background: Multiple sclerosis (MS) is a chronic auto-immune neuroinflammatory disorder presenting as a range of systemic and neurological symptoms, including cognitive impairment. Emerging evidence suggests that diets targeting brain health—such as the Mediterranean (MED) and Mediterranean-DASH Intervention for Neurodegenerative Delay (MIND) diets—may improve cognitive function; however, studies examining their role in people living with MS are limited. Methods: We examined cross-sectional associations between diet and cognition data from 967 participants in the United Kingdom Multiple Sclerosis Register (UKMSR). Dietary pattern scores (alternate Mediterranean; aMED, and MIND) were derived from the 130-item EPIC-Norfolk food frequency questionnaire. Cognition was assessed using the MS-specific Cognitron-MS (C-MS) battery (13 tasks) and summarised as overall cognition (global G factor) and four domains (object memory, problem solving, information processing speed [IPS], and words memory). Cognitive outcomes were expressed as Deviation-from-Expected (DfE) scores standardised to demographic and device characteristics using external regression-based norms. Linear models were adjusted for total energy intake, MS phenotype, disease duration since diagnosis, and current disease-modifying therapy (DMT) use. Interactions tested moderation by MS phenotype (relapsing vs. progressive MS) and current DMT use (yes vs. no). Sensitivity analyses included within-domain multiple-comparison control, rank-based inverse-normal transformation, and winsorisation. Results: Greater alignment with aMED and MIND dietary patterns were associated with higher scores in specific cognitive domains but not in overall cognition. Higher aMED scores were associated most consistently with better IPS, while higher MIND scores were additionally associated with better words memory. In categorical models, participants with the middle or highest tertiles of aMED or MIND scores performed up to ~0.4 SD better on tasks of Verbal Analogies, Word Definitions, Simple Reaction Time, Words Memory Immediate, or Words Memory Delays compared with those in the lowest tertile. These findings were robust across sensitivity analyses. Stratified analyses showed differential cognitive performance and diet-cognition associations by MS phenotype and DMT use. Conclusions: Mediterranean and MIND dietary patterns showed modest cross-sectional associations with specific cognition domains, with differential cognitive performance in different subgroups according to MS phenotype and DMT use. Although causal inference is not possible, our findings indicate future MS-related dietary studies (longitudinal and/or randomised controlled trials) examining cognitive function domains across different MS subgroups are warranted. Full article
(This article belongs to the Special Issue Dietary Factors and Interventions for Cognitive Neuroscience)
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18 pages, 1328 KB  
Article
Effect of Ultrasonic Condensation Time on Void Formation and Microhardness of Well-RootTM PT Apical Plugs in 3D-Printed Immature Teeth
by Krasimir Hristov and Ralitsa Bogovska-Gigova
Materials 2025, 18(21), 4835; https://doi.org/10.3390/ma18214835 - 22 Oct 2025
Abstract
Background: This study aimed to evaluate the impact of varying durations of ultrasonic condensation on the formation of internal and external voids and the microhardness of apical plugs created with premixed bioceramic putty Well-RootTM PT in standardized 3D-printed immature permanent teeth using [...] Read more.
Background: This study aimed to evaluate the impact of varying durations of ultrasonic condensation on the formation of internal and external voids and the microhardness of apical plugs created with premixed bioceramic putty Well-RootTM PT in standardized 3D-printed immature permanent teeth using micro-CT imaging and Vickers microhardness testing. Methods: Forty-eight 3D-printed upper incisors with simulated open apices (2 mm canal diameter) were divided into four groups (n = 12 each) based on apical plug condensation technique as follows: Group 1 (control, manual condensation), Group 2 (3-s Ultrasonic at 25 kHz), Group 3 (9-s Ultrasonic at 25 kHz), and Group 4 (15-s Ultrasonic at 25 kHz). Well-RootTM PT was used to form 5 mm apical plugs under a microscope. Samples were stored at 37 °C and 100% humidity for one week. Micro-CT imaging was used to quantify internal, external, and total void volumes (% of total material volume), while microhardness was measured using a Vickers tester (1 kgf load, 10 s) on polished apical plug sections. Statistical analysis was performed using ANOVA and Tukey post hoc tests. Results: Group 4 (15-s Ultrasonic) exhibited significantly higher external and total void volumes compared to Groups 1–3 (p < 0.001), with no significant differences in internal voids across groups (p > 0.05). Microhardness was highest in Group 1 (mean VHN: 76.95 ± 3.73), followed by Group 2 (73.11 ± 4.82), Group 3 (55.11 ± 5.28), and Group 4 (51.25 ± 7.73) (p < 0.05). Shorter ultrasonic durations (3-s Ultrasonic) resulted in fewer voids and higher microhardness compared to longer durations (15-s Ultrasonic). There was no statistically significant difference in void size among the groups compared (p > 0.05). Fractal dimension analysis showed that prolonged ultrasonic condensation results in less complex voids compared to shorter activation. Conclusion: Manual condensation of premixed bioceramic putty, by promoting denser particle packing without ultrasonic-induced disruptions, leads to higher microhardness. Brief ultrasonic activation (3-s Ultrasonic) optimizes the quality of Well-RootTM PT apical plugs by minimizing voids and maintaining higher microhardness, thus enhancing the apical seal. Prolonged ultrasonic activation (15-s Ultrasonic) increases void formation and reduces microhardness, potentially compromising the long-term integrity of the apical barrier. Full article
(This article belongs to the Special Issue Mechanical Properties of Dental Materials)
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24 pages, 303 KB  
Article
Flexibility by Design: A Methodological Approach to Assessing Electrical Asset Potential Inspired by Smart Readiness Concepts
by Luis Carlos Parada, Gregorio Fernández, Rafael Camarero Rodríguez, Blanca Martínez, Nikolas Spiliopoulos and Paula Hernamperez
Appl. Sci. 2025, 15(21), 11334; https://doi.org/10.3390/app152111334 - 22 Oct 2025
Abstract
The growing integration of distributed energy resources and electrification of end users is driving the need for greater system flexibility in modern power grids. Various electrical assets can contribute to this flexibility, either inherently or through external control mechanisms, although their suitability varies [...] Read more.
The growing integration of distributed energy resources and electrification of end users is driving the need for greater system flexibility in modern power grids. Various electrical assets can contribute to this flexibility, either inherently or through external control mechanisms, although their suitability varies even within the same category of assets. This paper presents a novel methodological approach to assess the flexibility potential of electrical assets based on their inherent technical characteristics and their intended installation context. Inspired by the principles of the Smart Readiness Indicator (SRI) for buildings, the proposed method employs a scoring system to evaluate a set of key functionalities that determine an asset’s readiness to contribute to system flexibility, then through a weighted sum a final index is obtained. These scores are combined through a weighted aggregation to produce a single, easy-to-interpret index that synthesizes multiple characteristics, enabling comparisons across different technologies. Unlike the SRI, this approach is not focused on certification but rather on providing a decision-support tool for end-users. The applicability of the method is demonstrated through a case study evaluating a photovoltaic inverter, followed by a sensitivity analysis to assess the robustness of the weighting scheme. Results indicate that the proposed index provides a transparent and replicable means of quantifying flexibility potential, supporting more informed planning and investment decisions. Full article
25 pages, 4789 KB  
Article
A New Hybrid Rigid–Flexible Coupling Modeling for Efficient Vibration Analysis of the Cooling System of New Energy Vehicles
by Ning Zhang, Yuankai Ren, Zihong Li and Hangyu Lu
Actuators 2025, 14(11), 512; https://doi.org/10.3390/act14110512 - 22 Oct 2025
Abstract
The cooling system is a core component for a vehicle’s powertrains to operate smoothly and maintain a satisfying noise, vibration, and harshness (NVH) performance. However, advances in new energy vehicles bring with them complex requirements for the cooling fan design due to new [...] Read more.
The cooling system is a core component for a vehicle’s powertrains to operate smoothly and maintain a satisfying noise, vibration, and harshness (NVH) performance. However, advances in new energy vehicles bring with them complex requirements for the cooling fan design due to new issues such as increased heat load, dynamic variations, and high-speed vibrations, which demand the optimization of fan dynamics over a wide range of parameters. In this paper, by thoroughly checking the effect of rigid–flexible coupling and the geometrically complex elastic frame of the fan, we propose a combined modeling approach to reduce the computational time of broad-range parameter variation analysis and examine the vibration problem in the cooling fans under various external excitations. First, the complicated frame of the fan is simplified through virtual prototyping based on an experiment. Then, modal transition is applied, reducing the complex kinetic expression, and a time-invariant system model is derived with multi-blade coordinate transformation. Stability and bifurcation analysis are performed regarding different excitation couplings from the rotor, powertrain, and road. The results of the simulation and experiment illustrate that the proposed methodology achieves a substantial reduction in computational time, and all degrees of freedom (DOFs) are divided into two groups including symmetrical and asymmetrical types. The results also imply the great potential for the optimization and control of the high-speed fan’s vibration for new energy cars. Full article
(This article belongs to the Section Actuators for Surface Vehicles)
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43 pages, 8058 KB  
Article
Biomechanical Design and Adaptive Sliding Mode Control of a Human Lower Extremity Exoskeleton for Rehabilitation Applications
by Sk K. Hasan and Nafizul Alam
Robotics 2025, 14(10), 146; https://doi.org/10.3390/robotics14100146 - 21 Oct 2025
Viewed by 227
Abstract
The human lower extremity plays a vital role in locomotion, posture, and weight-bearing through coordinated motion at the hip, knee, and ankle joints. These joints facilitate essential functions including flexion, extension, and internal and external rotation. To address mobility impairments through personalized therapy, [...] Read more.
The human lower extremity plays a vital role in locomotion, posture, and weight-bearing through coordinated motion at the hip, knee, and ankle joints. These joints facilitate essential functions including flexion, extension, and internal and external rotation. To address mobility impairments through personalized therapy, this study presents the design, dynamic modeling, and control of a four-degree-of-freedom (4-DOF) lower limb exoskeleton robot. The system actuates hip flexion–extension and internal–external rotation, knee flexion–extension, and ankle dorsiflexion–plantarflexion. Anatomically aligned joint axes were incorporated to enhance biomechanical compatibility and reduce user discomfort. A detailed CAD model ensures ergonomic fit, modular adjustability, and the integration of actuators and sensors. The exoskeleton robot dynamic model, derived using Lagrangian mechanics, incorporates subject-specific anthropometric parameters to accurately reflect human biomechanics. A conventional sliding mode controller (SMC) was implemented to ensure robust trajectory tracking under model uncertainties. To overcome limitations of conventional SMC, an adaptive sliding mode controller with boundary layer-based chattering suppression was developed. Simulations in MATLAB/Simulink 2025 R2025a demonstrate that the adaptive controller achieves smoother torque profiles, minimizes high-frequency oscillations, and improves tracking accuracy. This work establishes a comprehensive framework for anatomically congruent exoskeleton design and robust control, supporting the future integration of physiological intent detection and clinical validation for neurorehabilitation applications. Full article
(This article belongs to the Section Neurorobotics)
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16 pages, 2711 KB  
Article
Study on the Passivation of Defect States in Wide-Bandgap Perovskite Solar Cells by the Dual Addition of KSCN and KCl
by Min Li, Zhaodong Peng, Xin Yao, Jie Huang and Dawei Zhang
Nanomaterials 2025, 15(20), 1602; https://doi.org/10.3390/nano15201602 - 21 Oct 2025
Viewed by 116
Abstract
Wide-bandgap (WBG) perovskite solar cells (PSCs) are critical for high-efficiency tandem photovoltaic devices, but their practical application is severely limited by phase separation and poor film quality. To address these challenges, this study proposes a dual-additive passivation strategy using potassium thiocyanate (KSCN) and [...] Read more.
Wide-bandgap (WBG) perovskite solar cells (PSCs) are critical for high-efficiency tandem photovoltaic devices, but their practical application is severely limited by phase separation and poor film quality. To address these challenges, this study proposes a dual-additive passivation strategy using potassium thiocyanate (KSCN) and potassium chloride (KCl) to synergistically optimize the crystallinity and defect state of WBG perovskite films. The selection of KSCN/KCl is based on their complementary functionalities: K+ ions occupy lattice vacancies to suppress ion migration, Cl ions promote oriented crystal growth, and SCN ions passivate surface defects via Lewis acid-base interactions. A series of KSCN/KCl concentrations (relative to Pb) were tested, and the effects of dual additives on film properties and device performance were systematically characterized using scanning electron microscopy (SEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), photoluminescence (PL), space-charge-limited current (SCLC), current-voltage (J-V), and external quantum efficiency (EQE) measurements. Results show that the dual additives significantly enhance film crystallinity (average grain size increased by 27.0% vs. control), reduce surface roughness (from 86.50 nm to 24.06 nm), and passivate defects-suppressing non-radiative recombination and increasing electrical conductivity. For WBG PSCs, the champion device with KSCN (0.5 mol%) + KCl (1 mol%) exhibits a power conversion efficiency (PCE) of 16.85%, representing a 19.4% improvement over the control (14.11%), along with enhanced open-circuit voltage (Voc: +2.8%), short-circuit current density (Jsc: +6.7%), and fill factor (FF: +8.9%). Maximum power point (MPP) tracking confirms superior operational stability under illumination. This dual-inorganic-additive strategy provides a generalizable approach for the rational design of stable, high-efficiency WBG perovskite films. Full article
(This article belongs to the Section Solar Energy and Solar Cells)
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17 pages, 4603 KB  
Article
Development of Optical and Electrical Sensors for Non-Invasive Monitoring of Plant Water Status
by Nasreddine Makni, Riccardo Collu and Massimo Barbaro
J. Sens. Actuator Netw. 2025, 14(5), 103; https://doi.org/10.3390/jsan14050103 - 21 Oct 2025
Viewed by 133
Abstract
Monitoring plant water status is vital for optimizing irrigation in precision agriculture. This study explores the use of two simple, affordable, and non-invasive sensor systems, electrical impedance spectroscopy (EIS) and infrared (IR) spectroscopy, to assess plant water status directly from leaf tissues. This [...] Read more.
Monitoring plant water status is vital for optimizing irrigation in precision agriculture. This study explores the use of two simple, affordable, and non-invasive sensor systems, electrical impedance spectroscopy (EIS) and infrared (IR) spectroscopy, to assess plant water status directly from leaf tissues. This approach is well-suited for the realization of large networks of distributed sensors wirelessly connected to a central hub. An outdoor experiment was conducted over two phases of 20 day-experiment involving six Hydrangea macrophylla plants subjected to two irrigation treatments: a control group (well-irrigated) and a test group (poorly irrigated) designed to induce water stress. The standard relative water content (RWC) method validated the treatment effects on the plants, and both EIS and IR sensors effectively distinguished between the two groups. Impedance-derived parameters, particularly the normalized intracellular resistance (R0) and the cell membrane capacitance (C0), exhibited statistically significant differences between the treatments. In addition, the IR measurements showed moderate correlations with RWC, with determination coefficients of R2 = 0.56 and R2 = 0.51 for first and second phases of the experiment, respectively. Despite some limitations concerning the electrode–leaf conformity and external sunlight interference, the results point to the advantages of these methods for real-time plant monitoring and decision-making in smart irrigation systems. Full article
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22 pages, 1585 KB  
Article
Sustainable Control of Large-Scale Industrial Systems via Approximate Optimal Switching with Standard Regulators
by Alexander Chupin, Zhanna Chupina, Oksana Ovchinnikova, Marina Bolsunovskaya, Alexander Leksashov and Svetlana Shirokova
Sustainability 2025, 17(20), 9337; https://doi.org/10.3390/su17209337 - 21 Oct 2025
Viewed by 105
Abstract
Large-scale production systems (LSPS) operate under growing complexity driven by digital transformation, tighter environmental regulations, and the demand for resilient and resource-efficient operation. Conventional control strategies, particularly PID and isodromic regulators, remain dominant in industrial automation due to their simplicity and robustness; however, [...] Read more.
Large-scale production systems (LSPS) operate under growing complexity driven by digital transformation, tighter environmental regulations, and the demand for resilient and resource-efficient operation. Conventional control strategies, particularly PID and isodromic regulators, remain dominant in industrial automation due to their simplicity and robustness; however, their capability to achieve near-optimal performance is limited under constraints on control amplitude, rate, and energy consumption. This study develops an analytical–computational approach for the approximate realization of optimal nonlinear control using standard regulator architectures. The method determines switching moments analytically and incorporates practical feasibility conditions that account for nonlinearities, measurement noise, and actuator limitations. A comprehensive robustness analysis and simulation-based validation were conducted across four representative industrial scenarios—energy, chemical, logistics, and metallurgy. The results show that the proposed control strategy reduces transient duration by up to 20%, decreases overshoot by a factor of three, and lowers transient energy losses by 5–8% compared with baseline configurations, while maintaining bounded-input–bounded-output (BIBO) stability under parameter uncertainty and external disturbances. The framework provides a clear implementation pathway combining analytical tuning with observer-based derivative estimation, ensuring applicability in real industrial environments without requiring complex computational infrastructure. From a broader sustainability perspective, the proposed method contributes to the reliability, energy efficiency, and longevity of industrial systems. By reducing transient energy demand and mechanical wear, it supports sustainable production practices consistent with the following United Nations Sustainable Development Goals—SDG 7 (Affordable and Clean Energy), SDG 9 (Industry, Innovation and Infrastructure), and SDG 12 (Responsible Consumption and Production). The presented results confirm both the theoretical soundness and practical feasibility of the approach, while experimental validation on physical setups is identified as a promising direction for future research. Full article
(This article belongs to the Special Issue Large-Scale Production Systems: Sustainable Manufacturing and Service)
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17 pages, 452 KB  
Article
Owning Workplace Safety: Investigating Safety Locus of Control Among Nurses
by Archana Manapragada Tedone, Jessica Mesmer-Magnus, Julie J. Lanz and Chockalingam Viswesvaran
Eur. J. Investig. Health Psychol. Educ. 2025, 15(10), 216; https://doi.org/10.3390/ejihpe15100216 - 21 Oct 2025
Viewed by 111
Abstract
Workplace accidents and injuries continue to be a challenge in high-risk industries such as healthcare, where safety is a daily critical concern. Although organizational factors such as safety climate have been well-established as predictors of safety-related outcomes, less is known about the role [...] Read more.
Workplace accidents and injuries continue to be a challenge in high-risk industries such as healthcare, where safety is a daily critical concern. Although organizational factors such as safety climate have been well-established as predictors of safety-related outcomes, less is known about the role of individual differences in workplace safety. This research investigates safety locus of control, which captures an employee’s tendency to believe that their safety-oriented behaviors actually play a role in preventing safety incidents. Individuals with a highly internal safety locus of control tend to recognize the importance of their own and others’ safety actions for promoting workplace safety and preventing safety-related incidents from occurring in their workplace, whereas employees with low internal safety locus of control tend to believe that adverse safety outcomes have less to do with employee behavior and are more the result of luck or chance (i.e., have a more external orientation). Across three studies (with a total of 792 participants), we developed a measure for assessing safety locus of control (Study 1), evaluated its construct validity (Study 2), and measured its incremental validity on workplace safety beyond other important constructs like safety climate (Study 3). Results suggest that safety locus of control helps to explain critical workplace safety outcomes (such as safety performance) beyond environmental factors such as safety climate alone and plays an influential role on well-established safety processes within the workplace. This research highlights the importance of considering individual differences alongside environmental factors in workplace safety models. Full article
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19 pages, 3339 KB  
Article
Sensorless Control of Permanent Magnet Synchronous Motor in Low-Speed Range Based on Improved ESO Phase-Locked Loop
by Minghao Lv, Bo Wang, Xia Zhang and Pengwei Li
Processes 2025, 13(10), 3366; https://doi.org/10.3390/pr13103366 - 21 Oct 2025
Viewed by 208
Abstract
Aiming at the speed chattering problem caused by high-frequency square wave injection in permanent magnet synchronous motors (PMSMs) during low-speed operation (200–500 r/min), this study intends to improve the rotor position estimation accuracy of sensorless control systems as well as the system’s ability [...] Read more.
Aiming at the speed chattering problem caused by high-frequency square wave injection in permanent magnet synchronous motors (PMSMs) during low-speed operation (200–500 r/min), this study intends to improve the rotor position estimation accuracy of sensorless control systems as well as the system’s ability to resist harmonic interference and sudden load changes. The goal is to enhance the control performance of traditional control schemes in this scenario and meet the requirement of stable low-speed operation of the motor. First, the study analyzes the harmonic error propagation mechanism of high-frequency square wave injection and finds that the traditional PI phase-locked loop (PI-PLL) is susceptible to high-order harmonic interference during demodulation, which in turn leads to position estimation errors and periodic speed fluctuations. Therefore, the extended state observer phase-locked loop (ESO-PLL) is adopted to replace the traditional PI-PLL. A third-order extended state observer (ESO) is used to uniformly regard the system’s unmodeled dynamics, external load disturbances, and harmonic interference as “total disturbances”, realizing real-time estimation and compensation of disturbances, and quickly suppressing the impacts of harmonic errors and sudden load changes. Meanwhile, a dynamic pole placement strategy for the speed loop is designed to adaptively adjust the controller’s damping ratio and bandwidth parameters according to the motor’s operating states (loaded/unloaded, steady-state/transient): large poles are used in the start-up phase to accelerate response, small poles are switched in the steady-state phase to reduce errors, and a smooth attenuation function is used in the transition phase to achieve stable parameter transition, balancing the system’s dynamic response and steady-state accuracy. In addition, high-frequency square wave voltage signals are injected into the dq axes of the rotating coordinate system, and effective rotor position information is extracted by combining signal demodulation with ESO-PLL to realize decoupling of high-frequency response currents. Verification through MATLAB/Simulink simulation experiments shows that the improved strategy exhibits significant advantages in the low-speed range of 200–300 r/min: in the scenario where the speed transitions from 200 r/min to 300 r/min with sudden load changes, the position estimation curve of ESO-PLL basically overlaps with the actual curve, while the PI-PLL shows obvious deviations; in the start-up and speed switching phases, dynamic pole placement enables the motor to respond quickly without overshoot and no obvious speed fluctuations, whereas the traditional fixed-pole PI control has problems of response lag or overshoot. In conclusion, the “ESO-PLL + dynamic pole placement” cooperative control strategy proposed in this study effectively solves the problems of harmonic interference and load disturbance caused by high-frequency square wave injection in the low-speed range and significantly improves the accuracy and robustness of PMSM sensorless control. This strategy requires no additional hardware cost and achieves performance improvement only through algorithm optimization. It can be directly applied to PMSM control systems that require stable low-speed operation, providing a reliable solution for the promotion of sensorless control technology in low-speed precision fields. Full article
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