Search Results (2,615)

The evaporation dynamics of droplets on smooth and inclined micro-pillar surfaces were experimentally investigated. The surface temperature was increased from 50 °C to 120 °C, with the inclination angles being 0°, 30°, 45°, and 60° respectively. The dynamic parameters, including contact area, nucleation density, bubble stable diameter, and droplet asymmetry, were recorded using two high-speed video cameras, and the corresponding evaporation performance was analyzed. Experimental results showed that the inclination angle had a significant influence on the evaporation of micro-pillar surfaces than smooth surfaces as well as a positive correlation between the enhancement performance of the micro-pillars and increasing inclination angles. This angular dependence arises from surface inclination-induced tail elongation and the corresponding asymmetry of droplets. With definition of the one-dimensional asymmetry factor (ε) and volume asymmetry factor (γ), it was proven that although the asymmetric thickness of the droplets reduces the nucleation density and bubble stable diameter, the droplet asymmetry significantly increased the heat exchange area, resulting in a 37% improvement in the evaporation rate of micro-pillar surfaces and about a 15% increase in its enhancement performance to smooth surfaces when the inclination angle increased from 0°to 60°. These results indicate that asymmetry causes changes in heat transfer conditions, specifically, a significant increase in the wetted area and deformation of the liquid film, which are the direct enhancement mechanisms of inclined micro-pillar surfaces. Full article

This study investigates a novel heat pipe integrated cooling system designed for thermal management of Tesla’s 4680 cylindrical lithium–ion batteries in electric vehicles (EVs). Through a comprehensive approach combining experimental analysis, 1-D AMESim simulations, and 3-D Computational Fluid Dynamics (CFD) modeling, the thermal performance of various wick structures and working fluid filling ratios was evaluated. The experimental setup utilized a triangular prism chamber housing three surrogate heater blocks to replicate the heat generation of 4680 cells under 1C, 2C, and 3C discharge rates. Results demonstrated that a blended fabric wick with a crown-shaped design (Wick 5) at a 30–40% filling ratio achieved the lowest maximum temperature (T_max of 47.0°C), minimal surface temperature deviation (ΔT_surface of 2.8°C), and optimal thermal resistance (R_th of 0.27°C/W) under 85 W heat input. CFD simulations validated experimental findings, confirming stable evaporation–condensation circulation at a 40% filling ratio, while identifying thermal limits at high heat loads (155 W). The proposed hybrid battery thermal management system (BTMS) offers significant potential for enhancing the performance and safety of high-energy density EV batteries. This research provides a foundation for optimizing thermal management in next-generation electric vehicles. Full article

An advanced alkali-acid (NaOH-HCl) chemical method was used to deash aluminum-rich coals (ARCs) with a high ash content of 27.47 wt% to achieve a low ash content of 0.46 wt%. In the deashing process, aluminum in the coal ashes was dissolved in both alkali solutions and acid solutions. The deashing alkali solutions with dissolved coal ashes were regenerated by adding CaO, and the resulting precipitates were added with sodium bicarbonate for aluminum extraction. High temperatures increased aluminum extraction, and excessive sodium bicarbonate addition decreased aluminum extraction. The deashing acid solutions were concentrated by evaporation, and silica gels formed during the process. The obtained mixtures were calcinated at 350 °C for the decomposition of aluminum chlorides, and soaked with water at 60 °C to remove the soluble chlorides. For the insoluble oxides after soaking, diluted alkali solutions were used to extract the aluminum at 90 °C, and aluminum extraction failed due to the formation of albite in the presence of sodium, aluminum and silicon elements as proved by XRD and SEM/EDS. When silica gels were separated by pressure filtering, aluminum extraction greatly increased. Aluminum extractions were accordingly made in the form of sodium aluminate from the deashing solutions of coals, which could be advantageous for sandy alumina production. Full article

Potassium bromide (KBr) thin films were deposited by resistive thermal evaporation at substrate temperatures ranging from 50 °C to 250 °C to systematically elucidate the temperature-dependent evolution of their physical properties. Structural, morphological, and optical characteristics were examined by X-ray diffraction (XRD), scanning electron microscopy (SEM), atomic force microscopy (AFM), and Fourier transform infrared spectroscopy (FTIR). The results reveal a complex, non-monotonic response to temperature rather than a simple linear trend. As the substrate temperature increases, growth evolves from a mixed polycrystalline texture to a pronounced (200) preferred orientation. Morphological analysis shows that the film surface is smoothest at 150 °C, while the microstructure becomes densest at 200 °C. These structural variations directly modulate the optical constants: the refractive index attains its highest values in the 150–200 °C window, approaching that of bulk KBr. Cryogenic temperature (6 K) FTIR measurements further demonstrate that suppression of multi-phonon absorption markedly enhances the infrared transmittance of the films. Taken together, the data indicate that 150–200 °C constitutes an optimal process window for fabricating KBr films that combine superior crystallinity, low defect density, and high packing density. This study elucidates the temperature-driven structure–property coupling and offers valuable guidance for optimizing high-performance infrared and cryogenic optical components. Full article

Traditional hydrogel preparation methods typically require multiple steps and certain external stimuli. In this study, rapid and stable gelation of polyvinyl alcohol (PVA)-tannic acid (TA)-based hydrogels was achieved through the regulation of hydrogen bonds. The cross-linking between PVA and TA is triggered by the evaporation of ethanol. Rheological testing and analysis of the liquid-solid transformation process of the hydrogel were performed. The gelation onset time (GOT) could be tuned from 10 s to over 100 s by adjusting the ethanol content and temperature. The addition of polyhydroxyl components (e.g., glycerol) significantly enhances the hydrogel’s water retention capacity (by 858%) and tensile strain rate (by 723%), while concurrently increasing the gelation time. Further studies have shown that the addition of alkaline substances (such as sodium hydroxide) promotes the entanglement of PVA molecular chains, increasing the tensile strength by 23% and the fracture strain by 41.8%. The experimental results indicate that the optimized PVA-TA hydrogels exhibit a high tensile strength (>2 MPa) and excellent tensile properties (~600%). Moreover, the addition of an excess of weakly alkaline substances (such as sodium acetate) reduces the degree of hydrolysis of PVA, enabling the system to form a hydrogel with extrudable characteristics before the ethanol has completely evaporated. This property allows for patterned printing and thus demonstrates the potential of the hydrogel in 3D printing. Overall, this study provides new insights for the application of PVA-TA based hydrogels in the fields of rapid prototyping and strength optimization. Full article

Ultrahigh-temperature ceramic composites based on hafnium diboride have a wide range of applications, including as components for high-speed aircraft and energy generation and storage devices. Consequently, developing methodologies for their fabrication and studying their properties are of paramount importance, in particular in using them as an electrode material for energy storage devices with increased oxidation resistance. This study investigates the behavior of ceramic composites based on the HfB₂-HfO₂-SiC system, obtained using 15 vol% Ti₂AlC MAX-phase as a sintering component, under the influence of subsonic flow of dissociated air. It was determined that incorporating the modifying component (Ti₂AlC) altered the composition of the silicate melt formed on the surface during ceramic oxidation. This modification led to the observation of a protective antioxidant function. Consequently, liquation was observed in the silicate melt layer, resulting in the formation of spherical phase inhomogeneities in its volume with increased content of titanium, aluminum, and hafnium. It is hypothesized that the increase in the high-temperature viscosity of this melt prevents it from being carried away in the form of drops, even at a surface temperature of ~1900–2000 °C. Despite the established temperature, there is no sharp increase in its values above 2400–2500 °C. This is due to the evaporation of silicate melt from the surface. In addition, the electrochemical behavior of the obtained material in a liquid electrolyte medium (KOH, 3 mol/L) was examined, and it was shown that according to the value of electrical conductivity and specific capacitance, it is a promising electrode material for supercapacitors. Full article

Typhoon Yagi (2024) was a rapidly moving storm that lasted for eight days and made landfall in three locations, producing heavy rainfall over Hainan and Vietnam. This study aims to investigate the dynamical processes contributing to the heavy rainfall, concentrating on enthalpy flux (EF) and moisture flux (MF). The results indicate that both EF and MF increased significantly during the typhoon’s intensification stage and were high at the time of landfall. Before landfalling at Hainan, latent heat flux (LHF) reached 600 W/m², while sensible heat flux (SHF) was recorded as 80 W/m². Landfall at Hainan resulted in a decrease in LHF and SHF. LHF and SHF subsequently increased to 700 W/m² and 100 W/m², respectively, as noted prior to the landfall in Vietnam. The increased LHF led to higher evaporation, which subsequently elevated moisture flux (MF) following the landfall in Vietnam, while the region’s topography further intensified the rainfall. The mean daily rainfall observed over Philippines is 75 mm on 2 September (landfall and passing through), 100 mm over Hainan (landfall and passing through) on 6 September, and 95 mm at over Vietnam on 7 September (landfall and after), respectively. Heavy rainfall was observed over the land while the typhoon was passing and during the landfall. This research reveals that Typhoon Yagi’s intensity was maintained by a well-organized and extensive circulation system, supported by favorable weather conditions, including high sea surface temperatures (SST) exceeding 30.5 °C, substantial low-level moisture convergence, and elevated EF during the landfall in Vietnam. Full article

This study focuses on developing a climate-flood model to investigate and interpret the relationship and impact of climate on runoff/flooding at a sub-regional scale using multiple linear regression (MLR) with 30 years of hydro-climatic data for the Cross River Basin, Nigeria. Data were obtained from Nigerian Meteorological Agency (NIMET) for the following climatic parameters: annual average rainfall, maximum and minimum temperatures, humidity, duration of sunlight (sunshine hours), evaporation, wind speed, soil temperature, cloud cover, solar radiation, and atmospheric pressure. These hydro-meteorological data were analysed and used as parameters input to the climate-flood model. Results from multiple regression analyses were used to develop climate-flood models for all the gauge stations in the basin. The findings suggest that at 95% confidence, the climate-flood model was effective in forecasting the annual runoff at all the stations. The findings also identified the climatic parameters that were responsible for 100% of the runoff variability in Calabar (R² = 1.000), 100% the runoff in Uyo (R² = 1.000), 98.8% of the runoff in Ogoja (R² = 0.988), and 99.9% of the runoff in Eket (R² = 0.999). Based on the model, rainfall depth is the only climate parameter that significantly predicts runoff at 95% confidence intervals in Calabar, while in Ogoja, rainfall depth, temperature, and evaporation significantly predict runoff. In Eket, rainfall depth, relative humidity, solar radiation, and soil temperatures are significant predictors of runoff. The model also reveals that rainfall depth and evaporation are significant predictors of runoff in Uyo. The outcome of the study suggests that climate change has impacted runoff and flooding within the Cross River Basin. Full article

Combining Organic Rankine Cycles (ORC) with cooling cycles offers a promising approach to achieving greater outputs within a single system. In this study, a novel directly combined ORC-VCC system has been designed to not only meet the cooling demand using a geothermal heat source but also generate power. The proposed novel ORC-VCC system has been analyzed for its energetic performance using four selected fluids: R290, R600a, R601, and R1234ze(E). Parametric analysis has been conducted to investigate the effects of parameters of heat source temperature, heat source mass flow rate, cooling capacities, condenser temperature, ORC evaporator temperature, pinch point temperature difference and isentropic efficiencies on net power production. Among the working fluids, R290 has provided the highest net power production under all conditions in which it was available to operate. Additionally, the results have been analyzed concerning a reference cycle for comparative evaluation. The proposed novel cycle has outperformed the reference cycle in all investigated cases in terms of net power production such as demonstrating an improvement of approximately from 8.7% to 57.8% in geothermal heat source temperature investigations. Similar improvements have been observed over the reference cycle at lower heat source mass flow rates, where net power increases by up to 50.8%. Full article

A two-phase closed thermosyphon (TPCT), a gravity-assisted heat pipe, is a highly efficient heat transmitter involving liquid–vapor phase change. It is used in many applications, including heat spreading, thermal management and control, and energy saving. The main objective of this study is to investigate the effects of the operating conditions for a thermosyphon used in solar water heaters. The study particularly focuses on the influence of the inclination angle. Thus, a comprehensive simulation model is developed using the volume of fluid (VOF) approach. Complex and related phenomena, including two-phase flow, phase change, and heat exchange, are taken into account. To implement the model, an open-source CFD toolbox based on finite volume formulation, OpenFOAM, is used. The model is then validated by comparing numerical results to the experimental data from the literature. The obtained results show that the simulation model is reliable for investigating the effects of various operating conditions on the transient and steady-state behavior of the thermosyphon. In fact, bubble creation, growth, and advection can be tracked correctly in the liquid pool at the evaporator. The effects of the designed operating conditions on the heat transfer parameters are also discussed. In particular, the optimal tilt angle is shown to be 60° for the intermediate saturation temperature (<50 °C) and 90° for the larger saturation temperature (>60 °C). Full article

Massachusetts Bay in the northeastern United States is highly vulnerable to ocean acidification (OA) due to reduced buffering capacity from significant freshwater inputs. We hypothesize that acidification varies across temporal and spatial scales, with short-term variability driven by seasonal biological respiration, precipitation–evaporation balance, and river discharge, and long-term changes linked to global warming and river flux shifts. These patterns arise from complex nonlinear interactions between physical and biogeochemical processes. To investigate OA variability, we applied the Northeast Biogeochemistry and Ecosystem Model (NeBEM), a fully coupled three-dimensional physical–biogeochemical system, to Massachusetts Bay and Boston Harbor. Numerical simulation was performed for 2016. Assimilating satellite-derived sea surface temperature and sea surface height improved NeBEM’s ability to reproduce observed seasonal and spatial variability in stratification, mixing, and circulation. The model accurately simulated seasonal changes in nutrients, chlorophyll-a, dissolved oxygen, and pH. The model results suggest that nearshore areas were consistently more susceptible to OA, especially during winter and spring. Mechanistic analysis revealed contrasting processes between shallow inner and deeper outer bay waters. In the inner bay, partial pressure of pCO₂ (pCO₂) and aragonite saturation (Ω_a) were influenced by sea temperature, dissolved inorganic carbon (DIC), and total alkalinity (TA). TA variability was driven by nitrification and denitrification, while DIC was shaped by advection and net community production (NCP). In the outer bay, pCO₂ was controlled by temperature and DIC, and Ω_a was primarily determined by DIC variability. TA changes were linked to NCP and nitrification–denitrification, with DIC also influenced by air–sea gas exchange. Full article

The feasibility of utilizing biochar as a static floating material for agricultural applications was researched to prevent evaporation from open water static storage systems or as a floating barrier in slurry pits, for instance. Five types of biochar were created from chips, bark, and pellets of pine and residues from two acacia species using a pyrolysis time between 60 and 120 min and mean temperatures between 380 and 690 °C in a simple double-chamber reactor. Biomass and biochar were characterized for their main properties: bulk density, moisture content, volatile matter, ash content, fixed carbon, and pH. Biochar was also evaluated through a basic floatability test over 27 days (648 h) in distilled water. The highest fixed carbon content was observed in pine bark biochar (69.5%), followed by the pine pellets (67.4%) and pine chips (63.4%). Despite their high carbon content, the pellets exhibited a low floatability level, whereas pine bark biochar showed superior static floatage times, together with chip and ground chip biochar. These results suggest that biochar produced from bark and wood chips may be suitable for application as floatability material in water or slurry management systems. These results warrant further research into the static floating of biochar. Full article

Maintaining the required relative humidity values in the vehicle cabin is an important HVAC task, along with considerations related to the temperature, velocity, air pressure and noise. Deviation from the optimal values worsens the psycho-physiological state of the driver and affects the energy efficiency of the train. In this study, a model of liquid film formation on and removal from various cabin surfaces was constructed using the fundamental Navier–Stokes hydrodynamic equations. A special transport model based on the liquid vapor diffusion equation was used to simulate the air environment inside the cabin. The evaporation and condensation of surface films were simulated using the Euler film model, which directly considers liquid–gas and gas–liquid transitions. Numerical results were obtained using the RANS equations and a turbulence model by means of the finite volume method in Ansys CFD. Conjugate fields of temperature, velocity and moisture concentration were constructed for various time intervals, and the dependence values for the film thicknesses on various surfaces relative to time were determined. The verification was conducted in comparison with the experimental data, based on the protocol for measuring the microclimate indicators in workplaces, as applied to the train cabin: the average ranges encompassed temperature changes from 11% to 18%, and relative humidity ranges from 16% to 26%. Comparison with the results of other studies, without considering the phase transition and condensation, shows that, for the warm mode, the average air temperature in the cabin with condensation is 12.5% lower than without condensation, which is related to the process of liquid evaporation from the heated walls. The difference in temperature values for the model with and without condensation ranged from −12.5% to +4.9%. We demonstrate that, with an effective mode of removing condensate film from the window surface, including recirculation modes, the energy consumption of the climate control system improves significantly, but this requires a more accurate consideration of thermodynamic parameters and relative humidity. Thus, considering the moisture condensation model reveals that this variable can significantly affect other parameters of the microclimate in cabins: in particular, the temperature. This means that it should be considered in the numerical modeling, along with the basic heat transfer equations. Full article

The results of experimental data on the heat transfer coefficient during the boiling of pro-ecological refrigerants in a compact tube-shell heat exchanger are presented. The boiling process occurred in the micro-space of the exchanger shell on the surface of horizontal tubes, which were heated from the inside with warm water. The flow of the refrigerant was gravity-based. The heat exchanger was practically flooded with liquid refrigerant at a saturation temperature (ts), which flowed out after evaporation in a gaseous form. The tests were conducted for four refrigerants: R1234ze, R1234yf, R134a (a high-pressure refrigerant), and HFE7100 (a low-pressure refrigerant). Thermal characteristics describing the heat transfer process throughout the entire compact heat exchanger, specifically for the boiling process itself, were developed. It was found that in the case of micro-space boiling, there is an exponential dependence of the heat transfer coefficient on the heat flux density on the heated surface. Experimental data were compared to experimental and empirical data presented in other studies. Our own empirical models were proposed to determine the heat transfer coefficient for boiling in a mini-space for individual refrigerants. The proposed calculation models were also generalized for various refrigerants by introducing the value of reduced pressure into the calculation relationship. The developed relationship enables the determination of heat transfer coefficient values during boiling in a micro-space on the surface of horizontal tubes for various refrigerants with an accuracy of ±25%. Full article

Stable oxygen isotopes in tree rings (δ¹⁸O) serve as important proxies for climate change and offer unique advantages for climate reconstruction in arid and semi-arid regions. We established an annual δ¹⁸O chronology spanning 1964–2023 using Juniperus excelsa tree-ring samples collected from the Alborz Mountains in Iran. We analyzed relationships between δ¹⁸O and key climate variables: precipitation, temperature, Palmer Drought Severity Index (PDSI), vapor pressure (VP), and potential evapotranspiration (PET). Correlation analysis reveals that tree-ring δ¹⁸O is highly sensitive to hydroclimatic variations. Tree-ring cellulose δ¹⁸O shows significant negative correlations with annual total precipitation and spring PDSI, and significant positive correlations with spring temperature (particularly maximum temperature), April VP, and spring PET. The strongest correlation occurs with spring PET. These results indicate that δ¹⁸O responds strongly to the balance between springtime moisture supply (precipitation and soil moisture) and atmospheric evaporative demand (temperature, VP, and PET), reflecting an integrated signal of both regional moisture availability and energy input. The pronounced response of δ¹⁸O to spring evaporative conditions highlights its potential for capturing high-resolution changes in spring climatic conditions. Our δ¹⁸O series remained stable from the 1960s to the 1990s, but showed greater interannual variability after 2000, likely linked to regional warming and climate instability. A comparison with the δ¹⁸O variations from the eastern Alborz Mountains indicates that, despite some differences in magnitude, δ¹⁸O records from the western and eastern Alborz Mountains show broadly similar variability patterns. On a larger climatic scale, δ¹⁸O correlates significantly and positively with the Niño 3.4 index but shows no significant correlation with the Arctic Oscillation (AO) or the North Atlantic Oscillation (NAO). This suggests that ENSO-driven interannual variability in the tropical Pacific plays a key role in regulating regional hydroclimatic processes. This study confirms the strong potential of tree-ring oxygen isotopes from the Alborz Mountains for reconstructing hydroclimatic conditions and high-frequency climate variability. Full article