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16 pages, 1466 KiB  
Article
A Discrete Element Model for Characterizing Soil-Cotton Seeding Equipment Interactions Using the JKR and Bonding Contact Models
by Xuyang Ran, Long Wang, Jianfei Xing, Lu Shi, Dewei Wang, Wensong Guo and Xufeng Wang
Agriculture 2025, 15(15), 1693; https://doi.org/10.3390/agriculture15151693 - 5 Aug 2025
Abstract
Due to the increasing demand for agricultural water, the water availability for winter and spring irrigation of cotton fields has decreased. Consequently, dry seeding followed by irrigation (DSSI) has become a widespread cotton cultivation technique in Xinjiang. This study focused on the interaction [...] Read more.
Due to the increasing demand for agricultural water, the water availability for winter and spring irrigation of cotton fields has decreased. Consequently, dry seeding followed by irrigation (DSSI) has become a widespread cotton cultivation technique in Xinjiang. This study focused on the interaction between soil particles and cotton seeding equipment under DSSI in Xinjiang. The discrete element method (DEM) simulation framework was employed to compare the performance of the Johnson-Kendall-Roberts (JKR) model and Bonding model in simulating contact between soil particles. The models’ ability to simulate the angle of repose was investigated, and shear tests were conducted. The simulation results showed that both models had comparable repose angles, with relative errors of 0.59% for the JKR model and 0.36% for the contact model. However, the contact model demonstrated superior predictive accuracy in simulating direct shear test results, predicting an internal friction angle of 35.8°, with a relative error of 5.8% compared to experimental measurements. In contrast, the JKR model exhibited a larger error. The Bonding model provides a more accurate description of soil particle contact. Subsoiler penetration tests showed that the maximum penetration force was 467.2 N, closely matching the simulation result of 485.3 N, which validates the reliability of the model parameters. The proposed soil simulation framework and calibrated parameters accurately represented soil mechanical properties, providing a robust basis for discrete element modeling and structural optimization of soil-tool interactions in cotton field tillage machinery. Full article
(This article belongs to the Section Agricultural Technology)
20 pages, 10605 KiB  
Article
Network Analysis of Outcome-Based Education Curriculum System: A Case Study of Environmental Design Programs in Medium-Sized Cities
by Yang Wang, Zixiao Zhan and Honglin Wang
Sustainability 2025, 17(15), 7091; https://doi.org/10.3390/su17157091 - 5 Aug 2025
Abstract
With deepening global higher education reforms, outcome-based education has emerged as the core paradigm for teaching model innovation. This study investigates the structural dependencies and teaching effectiveness of the Environmental Design curriculum at Hubei Engineering University in medium-sized cities, China, addressing challenges of [...] Read more.
With deepening global higher education reforms, outcome-based education has emerged as the core paradigm for teaching model innovation. This study investigates the structural dependencies and teaching effectiveness of the Environmental Design curriculum at Hubei Engineering University in medium-sized cities, China, addressing challenges of enrollment decline and market contraction critical for urban sustainability. Using network analysis, we construct curriculum support and contribution networks and course temporal networks to assess structural dependencies and teaching effectiveness, revealing structural patterns and optimizing the OBE-based Environmental Design curriculum to enhance educational quality and student competencies. Analysis reveals computer basic courses as knowledge transmission hubs, creating a course network with a distinct core–periphery structure. Technical course reforms significantly outperform theoretical course reforms in improving student performance metrics, such as higher average scores, better grade distributions, and reduced performance gaps, while innovative practice courses show peripheral isolation patterns, indicating limited connectivity with core curriculum modules, which reduces their educational impact. These findings provide empirical insights for curriculum optimization, supporting urban sustainable development through enhanced professional talent cultivation equipped to address environmental challenges like sustainable design practices and resource-efficient urban planning. Network analysis applications introduce innovative frameworks for curriculum reform strategies. Future research expansion through larger sample validation will support urban sustainable development goals and enhance professional talent cultivation outcomes. Full article
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19 pages, 3220 KiB  
Review
Integrated Technology of CO2 Adsorption and Catalysis
by Mengzhao Li and Rui Wang
Catalysts 2025, 15(8), 745; https://doi.org/10.3390/catal15080745 - 5 Aug 2025
Abstract
This paper discusses the integrated technology of CO2 adsorption and catalysis, which combines adsorption and catalytic conversion, simplifies the traditional process, reduces energy consumption, and improves efficiency. The traditional carbon capture technology has the problems of high energy consumption, equipment corrosion, and [...] Read more.
This paper discusses the integrated technology of CO2 adsorption and catalysis, which combines adsorption and catalytic conversion, simplifies the traditional process, reduces energy consumption, and improves efficiency. The traditional carbon capture technology has the problems of high energy consumption, equipment corrosion, and absorbent loss, while the integrated technology realizes the adsorption, conversion, and catalyst regeneration of CO2 in a single reaction system, avoiding complex desorption steps. Through micropore confinement and surface electron transfer mechanism, the technology improves the reactant concentration and mass transfer efficiency, reduces the activation energy, and realizes the low-temperature and high-efficiency conversion of CO2. In terms of materials, MOF-based composites, alkali metal modified oxides, and carbon-based hybrid materials show excellent performance, helping to efficiently adsorb and transform CO2. However, the design and engineering of reactors still face challenges, such as the development of new moving bed reactors. This technology provides a new idea for CO2 capture and resource utilization and has important environmental significance and broad application prospects. Full article
(This article belongs to the Special Issue Catalysis Accelerating Energy and Environmental Sustainability)
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14 pages, 1058 KiB  
Article
Sex- and Age-Specific Utilization Patterns of Nuclear Medicine Procedures at a Public Tertiary Hospital in Jamaica
by Tracia-Gay Kennedy-Dixon, Mellanie Didier, Fedrica Paul, Andre Gordon, Marvin Reid and Maxine Gossell-Williams
Hospitals 2025, 2(3), 21; https://doi.org/10.3390/hospitals2030021 - 5 Aug 2025
Abstract
Understanding the utilization patterns of nuclear medicine (NM) services is essential for optimizing resource allocation and service provision. This study aimed to address the regional evidence gap by reporting the demand for NM services by sex and age at a public hospital in [...] Read more.
Understanding the utilization patterns of nuclear medicine (NM) services is essential for optimizing resource allocation and service provision. This study aimed to address the regional evidence gap by reporting the demand for NM services by sex and age at a public hospital in Jamaica. This was a non-experimental, retrospective study of NM scans that were completed at the University Hospital of the West Indies from 1 June 2022 to 31 May 2024. While all scans were reported in the descriptive totals, for patients with multiple scans during the study period, only the data from the first visit was used in the inferential statistical analysis. This was performed with the IBM SPSS (version 29.0) software and involved the use of chi-square goodness of fit and multinomial logistic regression. A total of 1135 NM scans for 1098 patients were completed (37 patients had more than one scan); 596 (54.3%) were female and 502 (45.7%) were male, with the ages ranging from 3 days to 94 years old. Among the female patients, there was a greater demand in the ≥60 years age group for cardiac amyloid scans (χ2 = 6.40, p < 0.05), while females 18–59 years had a greater demand for thyroid scans (χ2 = 7.714, p < 0.05) and bone scans (χ2 = 3.904, p < 0.05). On the other hand, significantly more males in the ≥60 age group presented for cardiac amyloid (χ2 = 4.167; p < 0.05) and bone scans (χ2 = 145.79, p < 0.01). Males were significantly less likely to undergo a thyroid scan than females (p < 0.01, OR = 0.072, 95% CI: 0.021, 0.243) while individuals aged 18–59 years were more likely to undergo this scan than patients aged 60 or older (p = 0.02, OR = 3.565, 95% CI: 1.258, 10.104). Males were more likely to do a cardiac amyloid scan (p < 0.05, OR = 2.237, 95% CI: 1.023, 4.891) but less likely to undergo a cardiac rest/stress test than females (p = 0.02, OR = 0.307, 95% CI: 0.114, 0.828). Prolonged life expectancy and an aging population have the potential to impact NM utilization, thus requiring planning for infrastructure, equipment, work force, and supplies. Cancer-related and cardiovascular indications are a top priority at this facility; hence, age- and sex-specific analysis are useful in establishing models for policy makers with regard to the allocation of economic and human resources for the sustainability of this specialized service. Full article
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22 pages, 6187 KiB  
Article
Device Modeling Method for the Entire Process of Energy-Saving Retrofit of a Refrigeration Plant
by Xuanru Xu, Lun Zhang, Jun Chen, Qingbin Lin and Junjie Chen
Energies 2025, 18(15), 4147; https://doi.org/10.3390/en18154147 - 5 Aug 2025
Abstract
With the increasing awareness of energy consumption issues, there has been a growing emphasis on energy-saving retrofits for central air-conditioning systems that constitute a significant proportion of energy consumption in buildings. Efficient energy utilization can be achieved by optimizing the modeling of the [...] Read more.
With the increasing awareness of energy consumption issues, there has been a growing emphasis on energy-saving retrofits for central air-conditioning systems that constitute a significant proportion of energy consumption in buildings. Efficient energy utilization can be achieved by optimizing the modeling of the equipment within the chiller plants of central air-conditioning systems. Traditional modeling approaches have been static and have focused on modeling within narrow time frames when a certain amount of equipment operating data has accumulated, thus prioritizing the precision of the model itself while overlooking the fact that energy-saving retrofits are a long-term process. This study proposes a modeling scheme for the equipment within chiller plants throughout the energy-saving retrofit process. Based on the differences in the amount of available operating data for the equipment and the progress of retrofit implementation, the retrofit process was divided into three stages, each employing different modeling techniques and ensuring smooth transitions between the stages. The equipment within the chiller plants is categorized into two types based on the clarity of their operating characteristics, and two modeling schemes are proposed accordingly. Based on the proposed modeling scheme, chillers and chilled-water pumps were selected to represent the two types of equipment. Real operating data from actual retrofit projects was used to model the equipment and evaluate the accuracy of the model predictions. The results indicate that the models established by the proposed modeling scheme exhibit good accuracy at each stage of the retrofit, with the coefficients of variation (CV) remaining below 6.88%. Furthermore, the prediction accuracy improved as the retrofitting process progressed. The modeling scheme performs better on equipment with simpler and clearer operating characteristics, with a CV as low as 0.67% during normal operation stages. This underscores the potential application of the proposed modeling scheme throughout the energy-saving retrofit process and provides a model foundation for the subsequent optimization of the refrigeration system. Full article
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19 pages, 3110 KiB  
Article
Integrated Environmental–Economic Assessment of Small-Scale Natural Gas Sweetening Processes
by Qing Wen, Xin Chen, Xingrui Peng, Yanhua Qiu, Kunyi Wu, Yu Lin, Ping Liang and Di Xu
Processes 2025, 13(8), 2473; https://doi.org/10.3390/pr13082473 - 5 Aug 2025
Abstract
Effective in situ H2S removal is essential for the utilization of small, remote natural gas wells, where centralized treatment is often unfeasible. This study presents an integrated environmental–economic assessment of two such processes, LO-CAT® and triazine-based absorption, using a scenario-based [...] Read more.
Effective in situ H2S removal is essential for the utilization of small, remote natural gas wells, where centralized treatment is often unfeasible. This study presents an integrated environmental–economic assessment of two such processes, LO-CAT® and triazine-based absorption, using a scenario-based framework. Environmental impacts were assessed via the Waste Reduction Algorithm (WAR), considering both Potential Environmental Impact (PEI) generation and output across eight categories, while economic performance was analyzed based on equipment, chemical, energy, environmental treatment, and labor costs. Results show that the triazine-based process offers superior environmental performance due to lower toxic emissions, whereas LO-CAT® demonstrates better economic viability at higher gas flow rates and H2S concentrations. An integrated assessment combining monetized environmental impacts with economic costs reveals that the triazine-based process becomes competitive only if environmental impacts are priced above specific thresholds. This study contributes a practical evaluation framework and scenario-based dataset that support sustainable process selection for decentralized sour gas treatment applications. Full article
(This article belongs to the Section Chemical Processes and Systems)
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21 pages, 3283 KiB  
Article
Atypical Pressure Dependent Structural Phonon and Thermodynamic Characteristics of Zinc Blende BeO
by Devki N. Talwar and Piotr Becla
Materials 2025, 18(15), 3671; https://doi.org/10.3390/ma18153671 - 5 Aug 2025
Abstract
Under normal conditions, the novel zinc blende beryllium oxide (zb BeO) exhibits in a metastable crystalline phase, which is less stable than its wurtzite counterpart. Ultrathin zb BeO epifilms have recently gained significant interest to create a wide range of advanced high-resolution, high-frequency, [...] Read more.
Under normal conditions, the novel zinc blende beryllium oxide (zb BeO) exhibits in a metastable crystalline phase, which is less stable than its wurtzite counterpart. Ultrathin zb BeO epifilms have recently gained significant interest to create a wide range of advanced high-resolution, high-frequency, flexible, transparent, nano-electronic and nanophotonic modules. BeO-based ultraviolet photodetectors and biosensors are playing important roles in providing safety and efficiency to nuclear reactors for their optimum operations. In thermal management, BeO epifilms have also been used for many high-tech devices including medical equipment. Phonon characteristics of zb BeO at ambient and high-pressure P ≠ 0 GPa are required in the development of electronics that demand enhanced heat dissipation for improving heat sink performance to lower the operating temperature. Here, we have reported methodical simulations to comprehend P-dependent structural, phonon and thermodynamical properties by using a realistic rigid-ion model (RIM). Unlike zb ZnO, the study of the Grüneisen parameter γ(T) and thermal expansion coefficient α(T) in zb BeO has revealed atypical behavior. Possible reasons for such peculiar trends are attributed to the combined effect of the short bond length and strong localization of electron charge close to the small core size Be atom in BeO. Results of RIM calculations are compared/contrasted against the limited experimental and first-principle data. Full article
(This article belongs to the Special Issue The Heat Equation: The Theoretical Basis for Materials Processing)
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23 pages, 3087 KiB  
Article
MCMBAN: A Masked and Cascaded Multi-Branch Attention Network for Bearing Fault Diagnosis
by Peng Chen, Haopeng Liang and Alaeldden Abduelhadi
Machines 2025, 13(8), 685; https://doi.org/10.3390/machines13080685 - 4 Aug 2025
Abstract
In recent years, deep learning methods have made breakthroughs in the field of rotating equipment fault diagnosis, thanks to their powerful data analysis capabilities. However, the vibration signals usually incorporate fault features and background noise, and these features may be scattered over multiple [...] Read more.
In recent years, deep learning methods have made breakthroughs in the field of rotating equipment fault diagnosis, thanks to their powerful data analysis capabilities. However, the vibration signals usually incorporate fault features and background noise, and these features may be scattered over multiple frequency levels, which increases the complexity of extracting important information from them. To address this problem, this paper proposes a Masked and Cascaded Multi-Branch Attention Network (MCMBAN), which combines the Noise Mask Filter Block (NMFB) with the Multi-Branch Cascade Attention Block (MBCAB), and significantly improves the noise immunity of the fault diagnostic model and the efficiency of fault feature extraction. NMFB novelly combines a wide convolutional layer and a top k neighbor self-attention masking mechanism, so as to efficiently filter unnecessary high-frequency noise in the vibration signal. On the other hand, MBCAB strengthens the interaction between different layers by cascading the convolutional layers of different scales, thus improving the recognition of periodic fault signals and greatly enhancing the diagnosis accuracy of the model when processing complex signals. Finally, the time–frequency analysis technique is employed to explore the internal mechanisms of the model in depth, aiming to validate the effectiveness of NMFB and MBCAB in fault feature recognition and to improve the feature interpretability of the proposed modes in fault diagnosis applications. We validate the superior performance of the network model in dealing with high-noise backgrounds by testing it on a standard bearing dataset from Case Western Reserve University and a self-constructed composite bearing fault dataset, and the experimental results show that its performance exceeded six of the top current fault diagnosis techniques. Full article
(This article belongs to the Special Issue Fault Diagnosis and Fault Tolerant Control in Mechanical System)
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1 pages, 155 KiB  
Correction
Correction: Santos et al. Performance Assessment of Object Detection Models Trained with Synthetic Data: A Case Study on Electrical Equipment Detection. Sensors 2024, 24, 4219
by David O. Santos, Jugurta Montalvão, Charles A. C. Araujo, Ulisses D. E. S. Lebre, Tarso V. Ferreira and Eduardo O. Freire
Sensors 2025, 25(15), 4801; https://doi.org/10.3390/s25154801 - 4 Aug 2025
Abstract
The changes are described below [...] Full article
(This article belongs to the Topic Applications in Image Analysis and Pattern Recognition)
28 pages, 2340 KiB  
Article
Determining the Operating Performance of an Isolated, High-Power, Photovoltaic Pumping System Through Sensor Measurements
by Florin Dragan, Dorin Bordeasu and Ioan Filip
Appl. Sci. 2025, 15(15), 8639; https://doi.org/10.3390/app15158639 (registering DOI) - 4 Aug 2025
Abstract
Modernizing irrigation systems (ISs) from traditional gravity methods to sprinkler and drip technologies has significantly improved water use efficiency. However, it has simultaneously increased electricity demand and operational costs. Integrating photovoltaic generators into ISs represents a promising solution, as solar energy availability typically [...] Read more.
Modernizing irrigation systems (ISs) from traditional gravity methods to sprinkler and drip technologies has significantly improved water use efficiency. However, it has simultaneously increased electricity demand and operational costs. Integrating photovoltaic generators into ISs represents a promising solution, as solar energy availability typically aligns with peak irrigation periods. Despite this potential, photovoltaic pumping systems (PVPSs) often face reliability issues due to fluctuations in solar irradiance, resulting in frequent start/stop cycles and premature equipment wear. The IEC 62253 standard establishes procedures for evaluating PVPS performance but primarily addresses steady-state conditions, neglecting transient regimes. As the main contribution, the current paper proposes a non-intrusive, high-resolution monitoring system and a methodology to assess the performance of an isolated, high-power PVPS, considering also transient regimes. The system records critical electrical, hydraulic and environmental parameters every second, enabling in-depth analysis under various weather conditions. Two performance indicators, pumped volume efficiency and equivalent operating time, were used to evaluate the system’s performance. The results indicate that near-optimal performance is only achievable under clear sky conditions. Under the appearance of clouds, control strategies designed to protect the system reduce overall efficiency. The proposed methodology enables detailed performance diagnostics and supports the development of more robust PVPSs. Full article
(This article belongs to the Special Issue New Trends in Renewable Energy and Power Systems)
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20 pages, 3145 KiB  
Article
Determination of Dynamic Elastic Properties of 3D-Printed Nylon 12CF Using Impulse Excitation of Vibration
by Pedro F. Garcia, Armando Ramalho, Joel C. Vasco, Rui B. Ruben and Carlos Capela
Polymers 2025, 17(15), 2135; https://doi.org/10.3390/polym17152135 - 4 Aug 2025
Abstract
Material Extrusion (MEX) process is increasingly used to fabricate components for structural applications, driven by the availability of advanced materials and greater industrial adoption. In these contexts, understanding the mechanical performance of printed parts is crucial. However, conventional methods for assessing anisotropic elastic [...] Read more.
Material Extrusion (MEX) process is increasingly used to fabricate components for structural applications, driven by the availability of advanced materials and greater industrial adoption. In these contexts, understanding the mechanical performance of printed parts is crucial. However, conventional methods for assessing anisotropic elastic behavior often rely on expensive equipment and time-consuming procedures. The aim of this study is to evaluate the applicability of the impulse excitation of vibration (IEV) in characterizing the dynamic mechanical properties of a 3D-printed composite material. Tensile tests were also performed to compare quasi-static properties with the dynamic ones obtained through IEV. The tested material, Nylon 12CF, contains 35% short carbon fibers by weight and is commercially available from Stratasys. It is used in the fused deposition modeling (FDM) process, a Material Extrusion technology, and exhibits anisotropic mechanical properties. This is further reinforced by the filament deposition process, which affects the mechanical response of printed parts. Young’s modulus obtained in the direction perpendicular to the deposition plane (E33), obtained via IEV, was 14.77% higher than the value in the technical datasheet. Comparing methods, the Young’s modulus obtained in the deposition plane, in an inclined direction of 45 degrees in relation to the deposition direction (E45), showed a 22.95% difference between IEV and tensile tests, while Poisson’s ratio in the deposition plane (v12) differed by 6.78%. This data is critical for designing parts subject to demanding service conditions, and the results obtained (orthotropic elastic properties) can be used in finite element simulation software. Ultimately, this work reinforces the potential of the IEV method as an accessible and consistent alternative for characterizing the anisotropic properties of components produced through additive manufacturing (AM). Full article
(This article belongs to the Special Issue Mechanical Characterization of Polymer Composites)
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16 pages, 3373 KiB  
Article
Knowledge-Augmented Zero-Shot Method for Power Equipment Defect Grading with Chain-of-Thought LLMs
by Jianguang Du, Bo Li, Zhenyu Chen, Lian Shen, Pufan Liu and Zhongyang Ran
Electronics 2025, 14(15), 3101; https://doi.org/10.3390/electronics14153101 - 4 Aug 2025
Abstract
As large language models (LLMs) increasingly enter specialized domains, inference without external resources often leads to knowledge gaps, opaque reasoning, and hallucinations. To address these challenges in power equipment defect grading, we propose a zero-shot question-answering framework that requires no task-specific examples. Our [...] Read more.
As large language models (LLMs) increasingly enter specialized domains, inference without external resources often leads to knowledge gaps, opaque reasoning, and hallucinations. To address these challenges in power equipment defect grading, we propose a zero-shot question-answering framework that requires no task-specific examples. Our system performs two-stage retrieval—first using a Sentence-BERT model fine-tuned on power equipment maintenance texts for coarse filtering, then combining TF-IDF and semantic re-ranking for fine-grained selection of the most relevant knowledge snippets. We embed both the user query and the retrieved evidence into a Chain-of-Thought (CoT) prompt, guiding the pre-trained LLM through multi-step reasoning with self-validation and without any model fine-tuning. Experimental results show that on a held-out test set of 218 inspection records, our method achieves a grading accuracy of 54.2%, which is 6.0 percentage points higher than the fine-tuned BERT baseline at 48.2%; an Explanation Coherence Score (ECS) of 4.2 compared to 3.1 for the baseline; a mean retrieval latency of 28.3 ms; and an average LLM inference time of 5.46 s. Ablation and sensitivity analyses demonstrate that a fine-stage retrieval pool size of k = 30 offers the optimal trade-off between accuracy and latency; human expert evaluation by six senior engineers yields average Usefulness and Trustworthiness scores of 4.1 and 4.3, respectively. Case studies across representative defect scenarios further highlight the system’s robust zero-shot performance. Full article
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21 pages, 1682 KiB  
Article
Profiling External Load in U14 Basketball: Cluster Analysis of Competition Performance Using Inertial Devices
by João Rocha, João Serrano, Pablo López-Sierra and Sergio J. Ibáñez
Appl. Sci. 2025, 15(15), 8616; https://doi.org/10.3390/app15158616 (registering DOI) - 4 Aug 2025
Abstract
Physical performance data is essential for planning youth training effectively; however, there is a lack of scientific information regarding performance in youth competitions. To address this gap, an innovative study was conducted with Portuguese U14 regional selections. Each player was equipped with a [...] Read more.
Physical performance data is essential for planning youth training effectively; however, there is a lack of scientific information regarding performance in youth competitions. To address this gap, an innovative study was conducted with Portuguese U14 regional selections. Each player was equipped with a WimuPro™ inertial device. Six variables were considered: accelerations, decelerations, speed, player load, impacts, and high impacts. The objective of this study, based on data from official competitions, was to statistically analyze the distribution and intensity thresholds of six physical performance variables across five defined zones. A cluster k-means analysis was performed for a significance value of p < 0.05. Five zones were identified for all variables: acceleration [<0.37; 0.37 to 0.81; 0.81 to 1.54; 1.54 to 3.49; >3.49 m/s2], deceleration [<−0.26; −0.27 to −0.63; −0.63 to −1.22; −1.22 to −2.545; >−2.54 m/s2], speed [<5.42; 5.42 to 10.19; 10.20 to 14.63; 14.64 to 18.59; >18.59 km/h2], player load [<1.07; 1.07 to 1.36; 1.37 to 1.63; 1.64 to 1.95; >1.95 u.a./min], impacts [<133.45; 133.45 to 158.75; 158.76 to 181.45; 181.46 to 206.59; >206.59 cont/min], and high impacts [<1.13; 1.14 to 2.11; 2.12 to 3.13; 3.14 to 4.42; >4.42 cont/min]. These intensity zones should be taken into account to optimize training and enhance the understanding of competition in U14 basketball. Full article
(This article belongs to the Special Issue Science and Basketball: Recent Advances and Practical Applications)
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24 pages, 1517 KiB  
Article
Physics-Informed Neural Network Enhanced CFD Simulation of Two-Dimensional Green Ammonia Synthesis Reactor
by Ran Xu, Shibin Zhang, Fengwei Rong, Wei Fan, Xiaomeng Zhang, Yunlong Wang, Liang Zan, Xu Ji and Ge He
Processes 2025, 13(8), 2457; https://doi.org/10.3390/pr13082457 - 3 Aug 2025
Viewed by 54
Abstract
The synthesis of “green ammonia” from “green hydrogen” represents a critical pathway for renewable energy integration and industrial decarbonization. This study investigates the green ammonia synthesis process using an axial–radial fixed-bed reactor equipped with three catalyst layers. A simplified two-dimensional physical model was [...] Read more.
The synthesis of “green ammonia” from “green hydrogen” represents a critical pathway for renewable energy integration and industrial decarbonization. This study investigates the green ammonia synthesis process using an axial–radial fixed-bed reactor equipped with three catalyst layers. A simplified two-dimensional physical model was developed, and a multiscale simulation approach combining computational fluid dynamics (CFD) with physics-informed neural networks (PINNs) employed. The simulation results demonstrate that the majority of fluid flows axially through the catalyst beds, leading to significantly higher temperatures in the upper bed regions. The reactor exhibits excellent heat exchange performance, ensuring effective preheating of the feed gas. High-pressure zones are concentrated near the top and bottom gas outlets, while the ammonia mole fraction approaches 100% near the bottom outlet, confirming superior conversion efficiency. By integrating PINNs, the prediction accuracy was substantially improved, with flow field errors in the catalyst beds below 4.5% and ammonia concentration prediction accuracy above 97.2%. Key reaction kinetic parameters (pre-exponential factor k0 and activation energy Ea) were successfully inverted with errors within 7%, while computational efficiency increased by 200 times compared to traditional CFD. The proposed CFD–PINN integrated framework provides a high-fidelity and computationally efficient simulation tool for green ammonia reactor design, particularly suitable for scenarios with fluctuating hydrogen supply. The reactor design reduces energy per unit ammonia and improves conversion efficiency. Its radial flow configuration enhances operational stability by damping feed fluctuations, thereby accelerating green hydrogen adoption. By reducing fossil fuel dependence, it promotes industrial decarbonization. Full article
(This article belongs to the Section AI-Enabled Process Engineering)
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20 pages, 4961 KiB  
Article
Optimization of Thermal Conductivity of Bismaleimide/h-BN Composite Materials Based on Molecular Structure Design
by Weizhuo Li, Run Gu, Xuan Wang, Chenglong Wang, Mingzhe Qu, Xiaoming Wang and Jiahao Shi
Polymers 2025, 17(15), 2133; https://doi.org/10.3390/polym17152133 - 3 Aug 2025
Viewed by 65
Abstract
With the rapid development of information technology and semiconductor technology, the iteration speed of electronic devices has accelerated in an unprecedented manner, and the market demand for miniaturized, highly integrated, and highly intelligent devices continues to rise. But when these electronic devices operate [...] Read more.
With the rapid development of information technology and semiconductor technology, the iteration speed of electronic devices has accelerated in an unprecedented manner, and the market demand for miniaturized, highly integrated, and highly intelligent devices continues to rise. But when these electronic devices operate at high power, the electronic components generate a large amount of integrated heat. Due to the limitations of existing heat dissipation channels, the current heat dissipation performance of electronic packaging materials is struggling to meet practical needs, resulting in heat accumulation and high temperatures inside the equipment, seriously affecting operational stability. For electronic devices that require high energy density and fast signal transmission, improving the heat dissipation capability of electronic packaging materials can significantly enhance their application prospects. In order to improve the thermal conductivity of composite materials, hexagonal boron nitride (h-BN) was selected as the thermal filling material in this paper. The BMI resin was structurally modified through molecular structure design. The results showed that the micro-branched structure and h-BN synergistically improved the thermal conductivity and insulation performance of the composite material, with a thermal conductivity coefficient of 1.51 W/(m·K) and a significant improvement in insulation performance. The core mechanism is the optimization of the dispersion state of h-BN filler in the matrix resin through the free volume in the micro-branched structure, which improves the thermal conductivity of the composite material while maintaining high insulation. Full article
(This article belongs to the Special Issue Electrical Properties of Polymer Composites)
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