Search Results (1,744)

Thermochromic materials (TCMs) have attracted increasing attention as passive adaptive materials for solar regulation in buildings because they can reversibly change their optical properties in response to temperature without external energy input. Owing to this temperature-triggered optical modulation, they have been widely investigated for smart windows, temperature indicators, anti-counterfeiting labels, and flexible devices. In recent years, representative systems such as VO₂-based materials, polymers, hydrogels, and organic–inorganic hybrids have shown steady progress, especially in transition-temperature tuning, spectral selectivity, and cycling stability. This review summarizes the main classes of TCMs as well as their color-changing mechanisms, preparation methods, and performance-regulation strategies, with an emphasis on building energy efficiency and passive solar regulation. Typical applications and current bottlenecks are also discussed, including response speed, durability, environmental compatibility, and large-scale manufacturing. Finally, several practical directions for future work are highlighted, particularly low-cost synthesis, multifunctional integration, and application-oriented material design. Full article

Background/Objectives: The pre-diagnosis dietary intake in newly diagnosed multi-ethnic paediatric inflammatory bowel disease (PIBD) is not well understood. This study aimed to describe the pre-diagnosis diet and environmental factors in children with newly diagnosed PIBD attending a single Australian tertiary children’s hospital. Methods: A pilot cross-sectional study was conducted from February 2022 to February 2023 involving children with newly diagnosed PIBD. Results: Of 56 children confirmed with PIBD, 54% had Crohn’s disease (CD)—mean ± SD age, 11.55 years ± 2.84—and 46% had Ulcerative Colitis (UC)—11.50 years ± 2.94 (45%, non-Caucasian). More Caucasians had an IBD family history (48.3% vs. 20%; p = 0.02 *). Non-Caucasian children demonstrated significantly lower mean serum vitamin D levels than Caucasian children (42.5 vs. 69 nmol/L; p ≤ 0.001 ***). Most children across ethnicities for both IBD subtypes had ‘regular’ intakes of red meat, whereas more Caucasian children had ‘regular’ intakes of processed/deli meat (72% vs. 39%; p = 0.02 *). A total of 64% of non-Caucasian children with CD reported a usual pre-diagnosis diet that differed from the traditional diet, compared to 42% with UC (p = 0.29). When eating out, fast foods were chosen regularly by most children with PIBD. Pre-diagnosis dietary intake data indicated that most with PIBD ‘rarely/never’ had whole-food sources of plant protein and had ‘infrequent’ intake of rice. Plant food diversity was low (mean 11 types/week). Conclusions: The significantly lower likelihood of IBD family history, along with relatively lower vitamin D levels, and the predominance of a Western-style dietary pattern among non-Caucasian children are compatible with the hypothesis that non-genetic factors may be important in PIBD, warranting further investigation into diet and environmental factors in this group. Further investigation of the pre-disease modifiable non-genetic factors contributing to the development of PIBD in the migrant population group is recommended. The finding across ethnicities of low pre-diagnosis plant food diversity was novel; however, due to the lack of healthy controls and the use of a novel but non-validated exposome tool, causality associations should be interpreted cautiously. Full article

Due to the high level of innovation involved, and the requirements arising from a new environment, the use of a quasi-direct drive motor for space applications presents not only several challenges, but also great opportunities. Such a motor is particularly well-suited to dynamic applications like walking robots or robotic arms. To ensure that it can withstand the environmental challenges, the motor must undergo extensive testing. This paper briefly outlines the development of such a motor based on prior prototypes with different design concepts. It addresses the specific requirements of a space variant and describes the selected final design. Additionally, the development of corresponding motor electronics is described. Finally, the results of a test campaign are presented. The campaign included internal functional tests to characterize the motor and external environmental tests necessary for space qualification. These tests included vibration, thermal vacuum chamber (TVAC) and electromagnetic compatibility (EMC) tests. Together, they showcased a highly dynamic motor with an efficiency of up to 90% and moved it towards a technology readiness level (TRL) of 5. Full article

Stone heritage deteriorates through physical, chemical, and biological processes driven by water, climate, and microbial colonization. Multifunctional polymeric coatings combining hydrophobic and antimicrobial moieties have emerged as a promising conservation strategy, yet a substantial gap remains between laboratory innovation and real-world performance. This review critically examines advances from 2021 to 2026, covering wetting theory, antimicrobial mechanisms, and material architectures, including molecularly integrated systems, Sol–Gel hybrids, nanocomposites, and layered systems. Long-term studies on the Aurelian Walls in Rome and stone in Reims show that biocidal efficacy typically declines within one to two years despite the chemical persistence of the coatings. In parallel, hydrophobic performance often deteriorates over time due to UV exposure, particulate deposition, and surface chemical changes, leading to increased wettability and reduced protective efficiency. Substrate porosity governs durability and visual compatibility (ΔE* < 5 threshold), while treatments can reshape microbial communities, favoring stress-tolerant meristematic fungi. Regulatory pressure on fluorinated compounds drives the development of more sustainable alternatives. Emerging directions include stimuli-responsive systems, self-healing materials, slippery interfaces, and precision polymer architectures. However, future progress will depend on tailoring formulations to major lithotypes, improving compatibility with porous substrates, and validating performance through standardized accelerated aging and multi-year field trials. Bridging laboratory design with environmental exposure data and conservation practice will be essential for achieving durable and culturally acceptable protection strategies. Full article

Objective: Functional training exercises involve complex multi-joint movements that challenge traditional rule-based or data-driven recognition systems. This paper introduces a Movement Description Language (MDL) designed to formally represent, analyze, and evaluate such exercises using camera-based pose estimation and interpretable, composable structures. Methods: The proposed MDL models each exercise as a finite-state machine defined by pose-derived angle proxy transitions, allowing movements to be described in a modular and reusable way. Demonstrated with MediaPipe landmark extraction from monocular video, while the MDL remains compatible with any pose estimation algorithm, the framework focuses on exercise phase detection and repetition counting. Experimental validation was conducted on a dataset of 1513 videos of 12 functional exercises (squats, deadlifts, lunges, shoulder presses, planks, push-ups, pull-ups, bent-over rows, box jumps, thrusters, overhead squats, and burpees) obtained from public pose datasets, competition footage, and recordings of 9 participants in real-world environments. Results: Automated repetition counts were compared against manually annotated ground truth, showing an overall repetition-counting accuracy of 97.2%, with a mean per-exercise accuracy of 98.8% (range 95–100%). The MDL successfully handled both simple and compound exercises, maintaining reliable phase detection despite variations in execution speed, camera perspective, and environmental conditions. Conclusion: The system was implemented using real-time pose estimation to demonstrate the practical execution of the MDL framework. The proposed MDL provides a transparent, extensible, and computationally efficient framework for functional exercise analysis. By bridging human-readable movement semantics with executable motion logic, it enables interpretable automatic repetition counting and phase detection, offering an alternative to black-box recognition approaches. The results support its potential for scalable deployment in training, monitoring and movement analysis applications. The proposed system is not intended for biomechanical measurement or clinical-grade kinematic analysis, but rather for interpretable modeling of exercise structure and repetition detection using approximate pose-derived signals. Full article

This narrative review examines topical anti-inflammatory therapies in veterinary medicine through the lens of the One Health framework, integrating pharmacology, dermatology, ecotoxicology, food safety, and regulatory science. It discusses the interconnected roles of veterinarians, pharmacists, environmental scientists, public health authorities, and regulatory bodies in addressing antimicrobial resistance, environmental contamination, zoonotic transmission, and drug residues in food-producing animals. By emphasising cross-sector collaboration, the review highlights how coordinated strategies can enhance animal welfare, safeguard human health, and reduce ecological burden. The article analyses inflammatory conditions in companion and farm animals and compares systemic versus topical anti-inflammatory approaches. Particular attention is given to corticosteroids, NSAIDs, immunomodulators, pro-resolving lipid mediators, and plant-derived bioactives, alongside advances in vehicles such as lipid nanocarriers and biodegradable film-forming systems designed to minimise systemic absorption and environmental dispersion. Regulatory considerations, residue control, pharmacovigilance gaps, and sustainability-oriented formulation strategies are critically addressed. Topical anti-inflammatory therapies, when rationally designed and monitored under One Health principles, represent a strategic opportunity to improve therapeutic precision while limiting systemic toxicity and ecological impact. Future directions should prioritise translational research, eco-compatible formulation design, and harmonised regulatory frameworks. Full article

The rapidly growing concern over the hazardous impact of phthalates on the environment and public health has led to a critical need for alternative and environmentally friendly plastics. Plasticizers developed from natural materials represent one possible solution. This paper explores four types of renewable feedstocks (sorbitol/polyols, glycerin, cardanol from cashew nutshell liquid, and limonene from citrus peels) as sources for developing alternative plasticizer systems. Key areas explored include the type of feedstock utilized, the methods used for extracting or processing the feedstocks, the nature of the chemical modification processes (e.g., esterification, epoxidation, etherification, or reactive grafting) applied to generate the respective plasticizers, and the resultant physical and mechanical properties. The performance of each plasticizer system in polymers such as PVC, PLA, and polysaccharide-based bioplastics is evaluated, alongside the compatibility with biological tissues, toxicological properties, biodegradability, and chemical migration into food simulants. The feasibility of each family of plasticizers is also assessed from an economic perspective, including availability of the feedstocks, economies of scale associated with large-volume production, and competitive pricing relative to established petroleum-derived plasticizers. Overall, sorbitol/polyol and glycerin derivative families have reached a level of maturity that provides a good balance of processability, food-contact safety, and biodegradability. Cardanol-based systems provide an attractive option where aromatic functional groups and combined plasticization–stabilization effects are needed. Limonene-derived plasticizer systems appear promising for use in PLA, but their broader utility may be limited by volatility, strong odors, and susceptibility to oxidation. Common issues identified across all four families include chemical migration into food products, regulatory approval, and the need for detailed life-cycle assessments. Full article

Arsenic contamination in groundwater is a severe and widespread environmental and public health challenge. Recent years have witnessed rapid advances in catalytic remediation technologies, particularly those integrating advanced oxidation processes (AOPs), bifunctional materials, and field-scale applications. This comprehensive review synthesizes recent developments, emphasizing the synergy between catalytic oxidation and adsorption, the design of innovative and recyclable materials, and the practical translation of laboratory findings to real-world remediation scenarios. Key breakthroughs include dual-function catalysts for combined contaminant removal, scalable systems compatible with renewable energy, and hybrid strategies integrating conventional and catalytic routes. Case studies from arsenic hotspots worldwide demonstrate not only technological feasibility but also highlight knowledge gaps and sustainability challenges. By evaluating catalytic mechanisms, operational performance, and environmental impact, this review identifies promising directions for the next generation of arsenic remediation and offers a critical roadmap to guide future research and practice. Full article

Two-dimensional (2D) magnetic materials have emerged as a promising platform for next-generation sensing technologies due to their atomic thickness, tunable magnetic properties, and compatibility with van der Waals heterostructures. Rapid progress in material discovery, synthesis, and device integration has expanded opportunities for compact, low-power, and highly sensitive sensor platforms. This review examines selected sensing mechanisms enabled by 2D magnetic materials, highlighting recent experimental advances and emerging device concepts. Current limitations and challenges such as environmental stability, scalability, and room-temperature operation are considered in the context of ongoing research efforts. By examining these approaches, this review aims to provide insight into the current development and potential of 2D magnetic materials for sensing technologies. This review is organized to first introduce the fundamental properties and challenges of 2D magnetic materials, followed by a survey of key sensing mechanisms and representative device implementations, and concludes with an outlook on future research directions. Full article

High-resolution Köppen–Geiger projections indicate that several cold desert (BWk) regions are likely to transition toward hot desert (BWh) regimes during the twenty-first century, challenging the environmental logic of vernacular architecture. Despite extensive simulation-based research on passive cooling in established BWh contexts, limited attention has been given to climate-type transition zones and to the morphological continuity of traditional housing systems. This study investigates the adaptive capacity of Bukhara’s courtyard houses under projected BWk–BWh reclassification. Employing an analytical generalization approach, the research integrates systematic literature mapping, typological morphological analysis, and a threshold-based compatibility matrix. Findings reveal that climate transition produces a form of morphological discontinuity by weakening diurnal discharge assumptions embedded in high thermal mass systems. However, courtyard typologies retain a resilient passive core when recalibrated through microclimatic amplification strategies. The proposed staged adaptation framework contributes a heritage-sensitive decision model that reconciles climatic performance with spatial integrity, offering transferable guidance for cli-mate-intensifying desert regions. Full article

The growing need for lightweight, multifunctional, and high-performance structures in the automotive, aerospace, electronics, and medical industries has driven the development of advanced joining technologies for polymers and metal-polymer combinations. Among these, ultrasonic welding (USW) and friction stir spot welding (FSSW) have emerged as promising solid-state techniques capable of producing reliable joints with minimal thermal degradation and enhanced interfacial bonding. This review focuses on recent developments in USW and FSSW of thermoplastics, fiber-reinforced composites, and hybrid metal–polymer systems, with a particular emphasis on process mechanics, microstructural evolution, and joint performance. The mechanisms of heat generation, material flow behavior, and consolidation are discussed in relation to key process parameters, including applied pressure, rotational speed, vibration amplitude, plunge depth, and dwell time. Microstructural transformations such as polymer chain orientation, recrystallization, interfacial diffusion, and defect formation are analyzed to establish process–structure–property relationships. Mechanical performance metrics, including lap shear strength, fatigue resistance, impact behavior, and environmental durability, are critically compared across different materials and welding methods. Furthermore, recent advances in numerical and thermo-mechanical modeling, in situ process monitoring, and data-driven optimization are discussed to highlight pathways toward predictive and scalable manufacturing. Current industrial applications and existing limitations such as challenges in automation, thickness constraints, and hybrid material compatibility are also evaluated. Finally, key research gaps and future directions are identified to improve joint reliability, sustainability, and broader industrial adoption of advanced solid-state welding technologies. Full article

Polyphenols are structurally diverse plant secondary metabolites with broad biological activities and growing applications across the food, health, and materials sectors. Conventional extraction based on organic solvents (e.g., methanol, ethanol) is often energy-intensive, inefficient, and environmentally burdensome. Ionic liquids (ILs) and deep eutectic solvents (DESs) have therefore emerged as greener alternatives for polyphenol extraction. This review evaluates recent advances in solvent design, extraction performance, and process sustainability. Imidazolium-based ILs frequently achieve high yields and selectivity, particularly when coupled with ultrasound or microwave-assisted extraction, but high cost, synthetic complexity, viscosity-related constraints, and potential toxicity hinder scaleup. By contrast, DESs—especially those derived from choline chloride or lactic acid—are easier to prepare, less costly, and more compatible with industrial implementation, with efficiency enhanced by tailoring hydrogen bond networks, water content, and process intensification. Critical downstream challenges persist for both solvent classes, notably in extract purification and solvent recovery due to low volatility; approaches such as resin adsorption, antisolvent precipitation, and direct formulation have been explored. Overall, ILs and DESs represent compelling alternatives to conventional solvents, and future progress will depend on integrated extraction–recovery strategies, systematic solvent selection, and validation under scalable, sustainable processing conditions. Full article

Growing interest in environmentally compatible stored-product pest control has highlighted diatomaceous earth (DE) and 1,8-cineole as promising agents, both alone and in combination. Their different modes of action, together with the limitations associated with higher-dose single applications, support evaluating their combined use at lower doses. This study was conducted to compare the effects of DE and 1,8-cineole, applied alone and in combination, on the larval, pupal, and adult stages of Tenebrio molitor. Five different concentrations were tested for each substance (DE at 25, 50, 100, 250, and 500 ppm, and 1,8-cineole at 2.5, 5, 10, 15, and 20 ppm), and four DE + 1,8-cineole combinations were evaluated within the same experimental system. Mortality was monitored over time, LC₅₀ values were calculated by probit analysis, and larval output observed after adult treatments was also evaluated. The findings indicated that the biological response was associated with developmental stage. The lowest LC₅₀ for DE was recorded in larvae at 86.11 ppm on day 3, whereas for 1,8-cineole the lowest LC₅₀ was recorded in adults at 94.83 ppm on day 3. Combined treatments generally tended to produce faster and stronger mortality; in particular, the DE250 + CIN20 treatment reached 100% mortality in larvae and adults and 93.33% mortality in pupae by day 7. In addition, larval output decreased in the single-treatment groups, the proportion of dead larvae among the observed larvae increased to 96–100%, and no larval output was detected in the combination groups. Combinations of DE and 1,8-cineole tended to produce more pronounced mortality responses than the single treatments, particularly in the larval and adult stages. The present findings indicate that combining DE with 1,8-cineole may provide a promising stage-specific strategy for improving the control of T. molitor under laboratory conditions. Full article

Marine biofouling remains a major challenge for maritime industries, affecting submerged structures and vessels worldwide. The long-standing reliance on biocidal coatings, together with their documented environmental impacts, has led to increasingly restrictive regulations and an urgent demand for environmentally compatible antifouling (AF) solutions. This study evaluates the AF potential and toxicological profile of two nucleoside analogues, hypoxanthine arabinoside (1′) and 2′-deoxyinosine (2′), selected based on the previously reported non-lethal AF activity of the naturally occurring nucleosides adenosine and 2′-deoxyadenosine from cyanobacteria. Both analogues inhibited the growth of Navicula sp. by approximately 60% without inducing mortality and significantly reduced settlement of Mytilus galloprovincialis plantigrades, with EC₅₀ values of 5.50 µM (1′) and 8.54 µM (2′), and no lethality detected (LC₅₀ > 200 µM). At near-EC₅₀ concentrations, both compounds increased acetylcholinesterase and tyrosinase activities, supported by molecular docking results, suggesting involvement of neurotransmission- and byssal formation-related pathways. Proteomic analysis revealed compound-specific molecular responses. No lethal effects were observed in non-target organisms (LC₅₀ > 32 µM for A. amphitrite and LC₅₀ > 50 µM for A. salina), and environmental fate modelling predicted low bioaccumulation and rapid degradation. Overall, substitution of the amino group by a carbonyl group preserved AF efficacy without increasing toxicity, highlighting nucleosides as promising low-toxicity AF agents. Full article

For the complex problems of multi-aircraft cooperative game guidance with No-Fly Zone (NFZ) avoidance and cross-task constraint propagation, a deep deterministic policy gradient algorithm with temporal awareness and priority cooperative optimization (TP-MADDPG) is proposed. Based on the three-body cooperative guidance, a new coupled guidance task is formed by adding the NFZ avoidance constraint. At the same time, considering the constraint compatibility problem in dynamic task switching, the cooperative aircraft are modeled as independent agents with differentiated policy networks. First, a nonlinear kinematic model of the three-body game constructed by Evader–Pursuer–Defender is established. And four complex constraint conditions, namely homing guidance, NFZ avoidance, collision avoidance, and cooperative guidance, are modeled separately. Secondly, the Long Short-Term Memory-based (LSTM) Actor–Critic framework is proposed to dynamically capture the evolution patterns of adversarial scenarios by mining hidden correlations in historical state-action sequences. This enables smooth policy transitions between the cooperative guidance phase and subsequent homing guidance phase, effectively addressing the challenges of environmental non-stationarity and temporal task dependencies. Then, a priority-driven adaptive sampling mechanism is proposed along with a heterogeneous roles cooperative reward function to specifically address credit assignment imbalance and sparse reward problems, respectively. The sampling mechanism capitalizes on the efficient retrieval properties of SumTree data structures while integrating bias correction techniques to expedite policy gradient convergence. The reward function utilizes the reward shaping method to formulate cooperative reward components that explicitly capture behavioral correlations among agents. Finally, simulations show that the proposed method significantly outperforms multi-agent reinforcement learning baselines, effectively improving the performance of cooperative game guidance under complex constraints. Full article