Search Results (17)

Complex geological, gas geochemical and hydro meteorological studies were conducted to investigate the methane fields present in the bottom sediments and seawater of the Red River and Phu Khanh sedimentary basins. We demonstrate that the system of tectonic faults that formed the sedimentary basins of the Red River and the Phu Khanh (the eastern shelf and slope of Vietnam) created the necessary conditions for the generation and migration of endogenous methane into the bottom sediments and seawater. It is shown that dissolved methane in seawater can be transported by marine currents, which in turn can be influenced by seasonal and irregular synoptic processes. The research shows that part of the dissolved methane contained in the waters above the Ken Bau gas field can be transported to the south by the coastal Vietnamese current, which adapts to the conditions of the winter northeast monsoon. It is concluded that there could be at least two deep sources of hydrocarbon gas emissions in the Phu Khanh basin. The impact of Typhoon Nakri on the transport of dissolved methane in the water column of the Phu Khanh sedimentary basin has been investigated. The typhoon could create favorable hydrodynamic conditions for the movement of dissolved gases from oil and gas deposits near the coasts of the islands of Kalimantan and Palawan to the Phu Khanh basin. A possible route for this transfer has been identified. Full article

The bioconversion of agricultural and industrial wastes is considered a green and sustainable alternative method for producing high-value biochemicals. As a major catalytic product of greenhouse gases and a by-product in the fermentation and lignocellulose processing industries, acetate is a promising bioconversion raw material. In this work, endogenous and heterologous enzymes were manipulated in Yarrowia lipolytica to achieve the conversion of acetate to high-value citric acid and itaconic acid, respectively. After the combinational expression of the key enzymes in the acetate metabolic pathway, the citric acid synthesis pathway, and the mitochondrial transport system, acetate could be efficiently converted to citric acid. Coupled with the down-regulation of fatty acid synthase expression in the competitive pathway, more acetyl-CoA flowed into the synthesis of citric acid, and the titer reached 15.11 g/L with a productivity of 0.51 g/g acetate by the engineered Y. lipolytica, which is comparable to the results using glucose as the substrate. On this basis, the heterologous cis-aconitate decarboxylase from Aspergillus terreus was introduced into the engineered Y. lipolytica to achieve the catalytic synthesis of itaconic acid from acetate. Combined with investigating the effects of multiple enzymes in the synthesis pathway, the titer of itaconic acid reached 1.87 g/L with a yield of 0.43 g/g DCW by the final engineered strain, which is the highest reported titer of itaconic acid derived from acetate by engineered microbes in shake flasks. It is demonstrated that acetate has the potential to replace traditional starch-based raw materials for the synthesis of high-value organic acids and our work lays a foundation for the rational utilization of industrial wastes and the catalytic products of greenhouse gases. Full article

Atmospheric stressors include a variety of pollutant gases such as CO₂, nitrous oxide (NOx), and sulfurous compounds which could have a natural origin or be generated by uncontrolled human activity. Nevertheless, other atmospheric elements including high and low temperatures, ozone (O₃), UV-B radiation, or acid rain among others can affect, at different levels, a large number of plant species, particularly those of agronomic interest. Paradoxically, both nitric oxide (NO) and hydrogen sulfide (H₂S), until recently were considered toxic since they are part of the polluting gases; however, at present, these molecules are part of the mechanism of response to multiple stresses since they exert signaling functions which usually have an associated stimulation of the enzymatic and non-enzymatic antioxidant systems. At present, these gasotransmitters are considered essential components of the defense against a wide range of environmental stresses including atmospheric ones. This review aims to provide an updated vision of the endogenous metabolism of NO and H₂S in plant cells and to deepen how the exogenous application of these compounds can contribute to crop resilience, particularly, against atmospheric stressors stimulating antioxidant systems. Full article

The color changes brought on by the enzymatic interactions of phenolic compounds with released endogenous polyphenol oxidase and the penetration of oxygen into the tissue has a significant impact on the commercialization of fresh-cut fruit, such as apples. This process causes a loss of quality in fresh-cut apples, resulting in browning of the fruit surface. By acting as a semipermeable barrier to gases and water vapor and thus lowering respiration, enzymatic browning, and water loss, edible coatings can provide a chance to increase the shelf life of fresh-cut produce. In this study, the effect of edible coatings composed of carboxymethylcellulose (CMC, 1%), sodium alginate (SA, 1%), citric acid (CA, 1%), and oxalic acid (OA, 0.5%) on fresh-cut ‘Annurca Rossa del Sud’ apple was studied. Four formulations of edible coatings, A. SA+CMC, B. SA+CMC+CA, C. SA+CMC+OA, and D. SA+CMC+CA+OA, were tested. Fresh-cut apples were dipped into different solutions and then stored at 4 °C, and physicochemical and biochemical analyses were performed at 0, 4, 8, and 12 days of storage. Results demonstrated that all four combinations improved the shelf-life of fresh-cut apple by slowing down the qualitative postharvest decay, total soluble solid, and titratable acidity. The browning index was highest in the control samples (82%), followed by CMC+SA (53%), CMC+SA+CA (32%), CMC+SA+OA (22%), and finally CMC+SA+CA+OA (7%) after 12 days of cold storage. Furthermore, coating application increased the bioactive compound content and antioxidant enzyme activities. Furthermore, the synergistic activity of SA+CMC+CA+OA reduces enzymatic browning, prolonging the postharvest life of minimally processed ‘Annurca Rossa del Sud’ apples. Full article

Human−exhaled breath mainly contains water, oxygen, carbon dioxide, and endogenous gases closely related to human metabolism. The linear relationship between breath acetone and blood glucose concentration has been revealed when monitoring diabetes patients. Considerable attention has been directed toward developing a highly sensitive volatile organic compounds (VOCs) sensing material that can detect breath acetone. In this study, we propose a tungsten oxide/tin oxide/silver/poly (methyl methacrylate) (WO₃/SnO₂/Ag/PMMA) sensing material fabricated using the electrospinning technique. By monitoring the evolution of sensing materials’ extinction spectra, low concentrations of acetone vapor can be detected. Moreover, the interfaces between SnO₂ and WO₃ nanocrystals construct n−n junctions, which generate more electron–hole pairs than those without such structure when the light strikes. This helps to improve the sensitivity of sensing materials when they are subjected to acetone surroundings. The established sensing materials (WO₃/SnO₂/Ag/PMMA) exhibit a sensing limit of 20 ppm for acetone vapor and show specificity for acetone even in ambient humidity. Full article

This paper aims to present the real improvement opportunities of a simple organic Rankine cycle (ORC) as waste heat recovery system (WHRS) from the exhaust gases of a natural gas engine using toluene as the working fluid, based on the exergy and environmental point of view. From the energy and exergy balances, the advanced exergetic analysis was developed to determine the irreversibilities and opportunities for improvement. Since the traditional exergo-environmental analysis, it was found that the component with the greatest potential environmental impact associated with exergy (bF = 0.067 mPts/MJ) and per unit of exergy (ḂD = 8.729 mPts/h) was the condenser, while the exergy-environmental fraction was presented in the turbine (52.51%) and pump-2 (21.12%). The advanced exergo-environmental analysis showed that the environmental impact is more associated with the operational behavior of the components, with 75.33% of the environmental impacts being of endogenous nature, showing that the environmental impacts are generated to a reduced magnitude through the interactions between components. However, it was identified that much of the environmental impacts in ITC 1 could be reduced, with 81.3% of these impacts being avoidable. Finally, the sensitivity analysis results revealed that steel is the material of the components with the least environmental impact. Full article

Hydrogen sulfide (H₂S) and nitric oxide (NO) are especially known as toxic and polluting gases, yet they are also endogenously produced and play key roles in numerous biological processes. These two opposing aspects of the gases highlight the need for new types of materials to be developed in addition to the most common materials such as activated carbons and zeolites. Herein, a new imine-linked polymer organic framework was obtained using the inexpensive and easy-to-access reagents isophthalaldehyde and 2,4,6-triaminopyrimidine in good yield (64%) through the simple and catalyst-free Schiff-base reaction. The polymeric material has microporosity, an A_BET surface area of 51 m²/g, and temperature stability up to 300 °C. The obtained 2,4,6-triaminopyrimidine imine-linked polymer organic material has a higher capacity to adsorb NO (1.6 mmol/g) than H₂S (0.97 mmol/g). Release studies in aqueous solution showed that H₂S has a faster release (3 h) from the material than NO, for which a steady release was observed for at least 5 h. This result is the first evaluation of the possibility of an imine-linked polymer organic framework being used in the therapeutic release of NO or H₂S. Full article

Endogenous gases have attracted much attention due to their potent applications in disease therapies. The combined therapy, including gaseous molecules and other medicines that can create synergistic effects, is a new way for future treatment. However, due to the gaseous state, gas utilization in medical service is still limited. To pave the way for future usage, in this work, an amphiphilic block copolymer containing nitrobenzyl ether, 3-hydroxyflavone (3-HF) derivatives and ether linker was constructed. The nitrobenzyl ether group endows the polymer with a photo-responsive character. Upon light illumination, 3-HF derivatives can be triggered for carbon monoxide (CO) release. The ether linker can also be released emitting formaldehyde (FA). The self-assembly induced micelle can encompass medicine, e.g., doxorubicin (DOX), into it and a controlled release of DOX can be realized upon light illumination. As far as we know, there is no report on the combination donor of CO and DOX and this is the first attempt on the co-release of CO, FA and DOX. Full article

Hydrogen sulfide (H₂S) is an endogenous biologically active gas produced in mammalian tissues. It plays a very critical role in many pathophysiological processes in the body. It can be endogenously produced through many enzymes analogous to the cysteine family, while the exogenous source may involve inorganic sulfide salts. H₂S has recently been well investigated with regard to the onset of various carcinogenic diseases such as lung, breast, ovaries, colon cancer, and neurodegenerative disorders. H₂S is considered an oncogenic gas, and a potential therapeutic target for treating and diagnosing cancers, due to its role in mediating the development of tumorigenesis. Here in this review, an in-detail up-to-date explanation of the potential role of H₂S in different malignancies has been reported. The study summarizes the synthesis of H₂S, its roles, signaling routes, expressions, and H₂S release in various malignancies. Considering the critical importance of this active biological molecule, we believe this review in this esteemed journal will highlight the oncogenic role of H₂S in the scientific community. Full article

Sepsis, a potentially lethal condition resulting from failure to control the initial infection, is associated with a dysregulated host defense response to pathogens and their toxins. Sepsis remains a leading cause of morbidity, mortality and disability worldwide. The pathophysiology of sepsis is very complicated and is not yet fully understood. Worse still, the development of effective therapeutic agents is still an unmet need and a great challenge. Gases, including nitric oxide (NO), carbon monoxide (CO) and hydrogen sulfide (H₂S), are small-molecule biological mediators that are endogenously produced, mainly by enzyme-catalyzed reactions. Accumulating evidence suggests that these gaseous mediators are widely involved in the pathophysiology of sepsis. Many sepsis-associated alterations, such as the elimination of invasive pathogens, the resolution of disorganized inflammation and the preservation of the function of multiple organs and systems, are shaped by them. Increasing attention has been paid to developing therapeutic approaches targeting these molecules for sepsis/septic shock, taking advantage of the multiple actions played by NO, CO and H₂S. Several preliminary studies have identified promising therapeutic strategies for gaseous-mediator-based treatments for sepsis. In this review article, we summarize the state-of-the-art knowledge on the pathophysiology of sepsis; the metabolism and physiological function of NO, CO and H₂S; the crosstalk among these gaseous mediators; and their crucial effects on the development and progression of sepsis. In addition, we also briefly discuss the prospect of developing therapeutic interventions targeting these gaseous mediators for sepsis. Full article

One of the major natural hazards occurring during the process of mining exploitation are endogenous fires. They cause very large material losses and constitute a threat to the health and life of the workers. Such fires usually start and develop in the goafs. The remaining coal and the oxygen-containing air flowing at a certain rate may lead to endogenous fires. The basic element of the assessment of the occurrence of an endogenous fire and the degree of its development is the chemical composition of the air flowing out of the longwall and the goafs. The monitoring of this composition also makes it possible to assess the severity of such a fire. The damage that can be caused by the endogenous fire requires scientific and experimental research being carried out on a wide scale in order to limit its occurrence and development. All papers and research mentioned in the paper aim to find a tool that will help to control the fires. The paper discusses the development of a new and original method of combating the threat of endogenous fires. It is based on the installation designed to feed an ash and water mixture or an ash and water mixture with carbon dioxide to goafs. The foundation of the paper is a method based on a vast depth of expertise and knowledge gained by the authors in the field of combating endogenous fires. The developed installation prepares and transports ash and water mixtures together with carbon dioxide to the zones with high probability of endogenous fires. The mixture is a preparation of the surface of a mine, and later, it is transported underground by pipelines to the goafs where a high level of the fire hazard was identified. The construction of the system and the composition of the mixture used are both original solutions; their practical application limited the process of spontaneous heating of coal. Monitoring the chemical composition of gases in the air of the goafs made it possible to control the effects of applied measures; it proved that carbon dioxide used as an inert gas disturbs the process of carbon oxidation, and the water and ash mixture limits the inflow of the air with oxygen. The advantage of the method is particularly evident in the case of the exploitation of deposits where coal has a short incubation time. This original approach allows for a better and more effective response to endogenous fires. Full article

The waste heat recovery system (WHRS) is a good alternative to provide a solution to the waste energy emanated in the exhaust gases of the internal combustion engine (ICE). Therefore, it is useful to carry out research to improve the thermal efficiency of the ICE through a WHRS based on the organic Rankine cycle (ORC), since this type of system takes advantage of the heat of the exhaust gases to generate electrical energy. The organic working fluid selection was developed according to environmental criteria, operational parameters, thermodynamic conditions of the gas engine, and investment costs. An economic analysis is presented for the systems operating with three selected working fluids: toluene, acetone, and heptane, considering the main costs involved in the design and operation of the thermal system. Furthermore, an exergo-advanced study is presented on the WHRS based on ORC integrated to the ICE, which is a Jenbacher JMS 612 GS-N of 2 MW power fueled with natural gas. This advanced exergetic analysis allowed us to know the opportunities for improvement of the equipment and the increase in the thermodynamic performance of the ICE. The results show that when using acetone as the organic working fluid, there is a greater tendency of improvement of endogenous character in Pump 2 of around 80%. When using heptane it was manifested that for the turbine there are near to 77% opportunities for improvement, and the use of toluene in the turbine gave a rate of improvement of 70%. Finally, some case studies are presented to study the effect of condensation temperature, the pinch point temperature in the evaporator, and the pressure ratio on the direct, indirect, and fixed investment costs, where the higher investment costs were presented with the acetone, and lower costs when using the toluene as working fluid. Full article

In the Czech part of the Upper Silesian Coal Basin (Moravian-Silesian region, Czech Republic), there are many deposits of endogenous combustion (e.g., localized burning soil bodies, landfills containing industrial waste, or slag rocks caused by mining processes). The Hedwig mining dump represents such an example of these sites where, besides the temperature and the concentrations of toxic gases, electric and non-electric quantities are also monitored within the frame of experimentally proposed and patented technology for heat collection (the so-called “Pershing” system). Based on these quantities, this paper deals with the determination and evaluation of negative heat sources and the optimization of the positive heat source dependent on measured temperatures within evaluation points or on a thermal profile. The optimization problem is defined based on a balance of the heat sources in the steady state while searching for a local minimum of the objective function for the heat source. From an implementation point of view, it is the interconnection of the numerical model of the heat collector in COMSOL with a user optimization algorithm in MATLAB using the LiveLink for MATLAB. The results are elaborated in five case studies based on the susceptibility testing of the numerical model by input data from the evaluation points. The tests were focused on the model behavior in terms of preprocessing for measurement data from each chamber of the heat collector and for the estimated value of temperature differences at 90% and 110% of the nominal value. It turned out that the numerical model is more sensitive to the estimates in comparison with the measured data of the chambers, and this finding does not depend on the type optimization algorithm. The validation of the model by the use of the mean-square error led to the finding of optimal value, also valid with respect to the other evaluation. Full article

The most commonly used practice to assess fire hazard development in underground coal mines is based on the measurement of the concentration of selected gases in the mine’s air. The main goal of this study was present a strategy to monitor the gaseous atmosphere in the mine in order to identify the onset of an endogenous fire in the coal seam. For that purpose, the principal component analysis (PCA) and the hierarchical clustering analysis (HCA) were applied. The monitoring covers the measurements of concentration of CO, CO₂, H₂, O₂, N₂, and selected hydrocarbons, respectively throughout the whole of one year. The chemometric methods applied allow for effective exploration of the similarities between the studied samples collected both under fire hazard conditions and under safe conditions. Based on the constructed models, the groups of objects characterized with the highest content of ethylene, acetylene, propylene, and carbon monoxide were identified. These samples indicate the endogenic fire in coal mine. Full article

Taiwan suffers from energy insecurity and the threat of potential damage from global climate changes. Finding ways to alleviate these forces is the key to Taiwan’s future social and economic development. This study examines the economic and environmental impacts when ethanol, conventional electricity and pyrolysis-based electricity are available alternatives. Biochar, as one of the most important by-product from pyrolysis, has the potential to provide significant environmental benefits. Therefore, alternative uses of biochar are also examined in this study. In addition, because planting energy crops would change the current land use pattern, resulting in significant land greenhouse gases (GHG) emissions, this important factor is also incorporated. Results show that bioenergy production can satisfy part of Taiwan’s energy demand, but net GHG emissions offset declines if ethanol is chosen. Moreover, at high GHG price conventional electricity and ethanol will be driven out and pyrolysis will be a dominant technology. Fast pyrolysis dominates when ethanol and GHG prices are low, but slow pyrolysis is dominant at high GHG price, especially when land GHG emissions are endogenously incorporated. The results indicate that when land GHG emission is incorporated, up to 3.8 billion kWh electricity can be produced from fast pyrolysis, while up to 2.2 million tons of CO₂ equivalent can be offset if slow pyrolysis is applied. Full article