Search Results (1,338)

Wavefront sensing (WFS) is fundamental to adaptive optics, astronomical observation, biological microscopy, and free-space optical communications. However, conventional approaches—including Shack–Hartmann sensors, shearing interferometers, and transport of intensity equation-based methods—are inherently limited by trade-offs among spatial sampling density, angular dynamic range, and device compactness and have rarely been extended to the mid-infrared range. Here, we propose an on-chip mid-infrared wavefront sensing scheme operating based on vectorial photocurrent manipulation and analyze the properties of the proposed device through finite-element simulations. The proposed device comprises a hexagonal array of antenna-integrated graphene pixels, each equipped with three contacts and a microlens. Based on the antenna-induced vectorial photocurrent manipulation, angle-dependent absorption is translated into photocurrent signals, potentially enabling unambiguous recovery of both the elevation and azimuth angles of the incident light over an effective angular dynamic range of ±28°. The hexagonal layout provides a high spatial sampling density of 11,547 mm⁻². Southwell algorithm-based wavefront reconstruction and numerical simulations yield faithful recovery of parabolic, conical, and quadrangular pyramidal wavefronts. In addition, simulation results indicate that this approach can enable high-fidelity reconstruction of both the phase and intensity distributions of an object based on angular-spectrum diffraction theory. Overall, this work theoretically demonstrates a new route toward high-density wavefront measurement and complex light field imaging in the mid-infrared range without a conventional imaging lens. Full article

The present study investigated the effect of liquid smoke (LS) on the physicochemical, structural, barrier, and functional properties of okra mucilage–corn starch (OMCS) films. Formulations containing varying concentrations of LS (0–3%) were prepared using the casting method. The incorporation of LS modified the rheological behavior of the film-forming dispersions, as evidenced by increased apparent viscosity and consistency index. In the films, water solubility increased from 43.6 to 53.2%, contact angle increased from 31.9° to 55.6°, and opacity increased from 4.73 to 8.83, while water vapor permeability decreased from 1.05 to 0.88 g·mm·m⁻²·h⁻¹·kPa⁻¹, indicating modifications in matrix organization and surface hydrophobicity. Tensile strength increased from 26.3 to 40.5 MPa at 3% LS, accompanied by a slight reduction in elongation, suggesting enhanced structural rigidity. Structural analyses revealed interactions between the LS phenolic compounds and the polysaccharide hydroxyl groups, resulting in a more cohesive polymeric network. LS was the main contributor to the film’s antioxidant activity owing to its elevated phenolic content and free radical scavenging capacity. The films also showed substantial degradation under soil burial conditions, with mass loss ranging from 61% to 96%. Overall, LS proved to be an effective functional additive, improving the structural and antioxidant performance of OMCS films and expanding their potential for active food packaging applications. Full article

Regenerated cellulose is a promising tribopositive material for sustainable triboelectric nanogenerators (TENGs), although its electrical output remains sensitive to surface and interfacial properties. In this study, regenerated cellulose was modified using atomic layer deposition (ALD) of Al₂O₃, TiO₂, and ZnO to investigate how nanoscale oxide coatings influence triboelectric performance against a tribonegative PTFE counter layer. Two deposition regimes were examined: 7 ALD cycles, representing the early stage of ALD growth, and 200 cycles, representing a more developed coating regime. Triboelectric measurements, dielectric spectroscopy, structural characterization and contact angle analysis, were used to evaluate how ALD modification influences the electrical response of regenerated cellulose. All ALD-modified samples exhibited increased surface charge density and power output compared to unmodified cellulose, while also showing improved retention of triboelectric performance at elevated relative humidity. The 7-cycle samples consistently outperformed the corresponding 200-cycle coatings under low-humidity conditions, whereas the 200-cycle ZnO sample exhibited the highest humidity stability. No direct correlation between wettability and triboelectric output was observed. The results suggest that relatively small interfacial modifications introduced by ALD are sufficient to influence both the triboelectric response and humidity-dependent charge dissipation behavior of regenerated cellulose. Full article

Objective: To report a rare case of bilateral iris metastasis from small cell lung carcinoma (SCLC) and systematically review the literature on SCLC-associated iris metastases, with emphasis on clinical presentation, management, and outcomes. Materials and Methods: A systematic literature review was conducted in accordance with the Preferred Reporting Items for Systematic Reviews and Meta-Analyses (PRISMA) guidelines. PubMed, ScienceDirect, Scopus, and Web of Science were comprehensively searched on 10 July 2025. Eligible studies included English-language reports of iris metastasis originating from SCLC in human subjects. Case report: A 58-year-old woman with previously treated SCLC developed bilateral iris metastases one year after complete remission of the primary tumor. Ophthalmic examination revealed whitish-gray, vascularized iris masses with iridocorneal angle involvement, associated with secondary angle-closure glaucoma and markedly elevated intraocular pressure (48 mm Hg) in the left eye. Cyclocryotherapy, preceded by systemic and topical antiglaucoma therapy, resulted in pain relief and a reduction in intraocular pressure; the patient died four months later due to pneumonia. Results (Systematic Review): Seventeen studies comprising 17 patients were included; the median age was 60 years, and 64.7% were male. The median interval from SCLC diagnosis to ocular presentation was 4 months, although iris metastasis was occasionally the initial or concurrent manifestation of disease. The most common presenting features were visual impairment (58.8%), ocular pain (41.2%), and elevated intraocular pressure (41.2%), while iris neovascularization (35.3%) and synechiae (29.4%) were also frequent. Bilateral involvement was reported in only one previous case. Treatment approaches were heterogeneous and included antiglaucoma therapy, systemic chemotherapy, local radiotherapy, anti-VEGF therapy, and enucleation. Among patients with available follow-up (n = 12), 58.3% died within a median follow-up of 7.5 months. Conclusions: Bilateral iris metastasis from SCLC is rare and may occur as a manifestation of recurrent disease after remission. It is an aggressive condition characterized by nonspecific ocular symptoms, variable management, and poor survival, underscoring the importance of early recognition and the need for evidence-based diagnostic and therapeutic strategies. Full article

Accurate plant-level photovoltaic (PV) power estimation is important for performance monitoring, model benchmarking, and grid-integration studies. In bifacial horizontal single-axis tracking (HSAT) systems, this task is complicated by the coupled effects of front-side irradiance, rear-side irradiance, tracker position, and module temperature. This study proposes an algorithmic framework for same-time-step AC power estimation in a bifacial HSAT PV plant using field measurements of irradiance, tracker angle, module temperature, and inverter active power. The framework is not intended as an operational forecasting model because future irradiance and weather conditions are not predicted; instead, it evaluates how compact physics-based structure, interpretable nonlinear learning, and ensemble learning estimate measured AC power under nominal operating conditions. An empirical rear-to-front irradiance relationship was derived using solar-elevation bins and incorporated into a compact physics-based benchmark. This benchmark was compared with an additive Explainable Boosting Machine (EBM) and a Random Forest (RF) on a common test subset of 3916 observations. The physics-based model achieved an RMSE of 19.6 kW, an R² of 0.72, and an NRMSE of 0.38. The EBM improved these values to 17.09 kW, 0.786, and 0.334, respectively, while the RF achieved 15.96 kW, 0.814, and 0.312. Chronological validation showed weaker and more variable performance than randomized validation, indicating that temporal generalization remains challenging. Overall, the results support the use of interpretable PV-domain-guided learning as a transparent intermediate approach between compact physics-based modeling and more flexible ensemble regression. Full article

Background/Objectives: The objective was to describe the one-year outcomes of salvage trabeculectomy (TLE) in eyes with persistent elevation of intraocular pressure (IOP) requiring early surgical intervention after failed minimally invasive glaucoma surgery (MIGS). Methods: This retrospective observational study included 38 eyes of 38 consecutive Japanese patients who underwent TLE within 100 days after Trabectome (TOM) or microhook ab interno trabeculotomy (μTLO) because of uncontrolled IOP despite maximally tolerated medical therapy. Surgical success was defined as (1) IOP reduction ≥30% from baseline, (2) 5 < IOP < 18 mmHg, (3) no additional glaucoma surgery, and (4) no loss of light perception. The Kaplan–Meier method was used to estimate the one-year success rate. Changes in IOP, medication use, best-corrected visual acuity (BCVA), and mean deviation (MD) were analyzed using the Wilcoxon matched-pairs signed-rank test and a linear mixed-effects model. Results: The median interval between MIGS and TLE was 41.5 days (interquartile range, 28–70 days). The one-year surgical success rate was 86.8% (Kaplan–Meier estimate). IOP and medication use were significantly reduced after TLE (p < 0.0001) and remained stable throughout the 12-month follow-up. BCVA did not differ significantly between baseline and 12 months after TLE, whereas a small but statistically significant difference in MD was observed. No serious vision-threatening complications were encountered. Conclusions: TLE performed shortly after failed MIGS achieved substantial IOP reduction with acceptable safety over a one-year follow-up period. TLE may be considered as one of the surgical options in cases where sufficient IOP reduction cannot be achieved after failed MIGS, and no effective alternative treatments are available. Full article

Water channel experiments were conducted to investigate the influence of aspect ratio (H/D = 0.9–1.9) on the flow-induced motion (FIM) and hydrokinetic energy conversion performance of an elastically mounted circular cylinder with T-shaped attachments (Cir-T-Att). The results indicate that the aspect ratio critically governs the vortex-induced vibration (VIV) to galloping transition by modulating the effective angle of attack. While larger H/D promotes galloping and higher amplitudes under low damping, this benefit is negated under elevated system damping, where amplitudes are uniformly suppressed. Consequently, the maximum power output exhibits a non-monotonic dependence with H/D. Within the investigated parametric range, peak performance occurs at H/D = 1.1, with a total damping ratio ζ_total = 0.122 and reduced velocity U_r = 11.25. For practical harvester design, the optimal H/D should be selected by aligning the intended oscillation regime with local flow characteristics. Full article

Reliable prediction of landslide run-out distance is of great importance for hazard zoning and risk mitigation. However, most previous studies evaluate model performance within a single landslide inventory, while the transferability of models across different triggering mechanisms remains insufficiently explored. To evaluate whether landslide run-out-prediction models and their uncertainty estimates remain reliable when transferred between rainfall-induced and earthquake-induced landslide inventories, this study investigates trigger-dependent run-out behavior and cross-trigger transferability using a harmonized inventory of 10,158 rainfall-induced and 681 earthquake-induced records. Common geometric descriptors, including run-out distance L, elevation difference H, source area A, source volume V, and mean slope angle $\theta$, were used for distributional comparison, scaling-law analysis, machine-learning prediction, tail-risk assessment, and uncertainty quantification. The results show that earthquake-induced landslides occupy a larger geometric domain, whereas rainfall-induced landslides exhibit greater elevation-normalized mobility. Cross-trigger prediction experiments reveal substantial and asymmetric transfer degradation, with systematic overprediction in R→E and underprediction in E→R. Prediction-interval reliability also deteriorates markedly under cross-trigger transfer, indicating that uncertainty estimates calibrated within one trigger type may not remain reliable when applied to another. These findings suggest that trigger-associated inventory differences should be explicitly considered in landslide run-out modeling. Direct application of models across rainfall- and earthquake-induced landslide inventories may lead to biased predictions and unreliable uncertainty estimates. Full article

This study produced and analyzed composite membranes composed of polysulfone (PSf), polyvinylpyrrolidone (PVP) and Metal–Organic Framework (ZIF-8) for treating effluent generated by the Batik industry. The incorporation of ZIF-8 was performed to enhance membrane efficiency. The findings indicated that ZIF-8 markedly enhanced hydrophilicity and pure water flux of membranes. The M-0.5 membrane containing 0.5 g of ZIF-8 demonstrated superior performance, with a water contact angle of 49.4° and a porosity of 83.5%. In contrast, the ZIF-8-free membrane (M-0) displayed a water contact angle and porosity of 66.3° and 76.7%, respectively. These combined characteristics enabled the M-0.5 membrane to achieve the highest pure water flux of 197.1 L m⁻² h⁻¹ at 5 bar. All membranes attained complete total suspended solids (TSS) rejection at 100% efficiency. Turbidity rejection rates ranged from 75% to 92%, whilst color rejection rates ranged from 65.7% to 87.6%. The maximum chemical oxygen demand (COD) rejection observed was 57.9%, achieved by the M-0.25 membrane (0.25 g of ZIF-8) at an operational pressure of 4 bar. Meanwhile, for permeability and hydrophilicity, the ideal loading is 0.5 g of ZIF-8 (M-0.5). This concentration yielded the optimal equilibrium of porosity (83.5%), the minimal water contact angle (49.4°), and the maximal pure water flux (197.1 L m⁻² h⁻¹). Nonetheless, the TDS rejection rate was rather low at 8.0–21.1%. The membrane effectively preserved effluent pH stability between 7.9 and 8.3. The aggregation of ZIF-8 at elevated concentrations diminished mechanical strength and selectivity. Additional optimization is required to equilibrate these performance indicators. Full article

Air temperature measurements in atmospheric environmental monitoring are susceptible to radiation-induced bias under natural ventilation. This study develops a low-power naturally ventilated air temperature sensor and a correction method combining computational fluid dynamics (CFD) with machine learning. The sensor integrates a Pt100 thin-film platinum resistance probe (Heraeus Holding GmbH, Hanau, Germany), symmetric guide plates, and a dual aluminum-plate radiation shield to reduce radiative heating while improving airflow around the probe. A three-dimensional fluid–solid coupled heat-transfer model was established in ANSYS FLUENT 15.0 to optimize guide-plate spacing and inclination angle and quantify the effects of solar radiation, long-wave radiation, scattered radiation, air density, wind speed, solar elevation angle, and surface albedo on radiation error. CFD results identified a guide-plate spacing of 24 mm and an inclination angle of 45° as the preferred parameters. A multilayer perceptron (MLP) model trained with CFD-derived data was validated in field experiments using a Model 076B aspirated radiation shield (Met One Instruments, Inc., Grants Pass, OR, USA) as the reference. The model predicted radiation error with a root mean square error (RMSE) of 0.052 °C, a mean absolute error (MAE) of 0.042 °C, and a correlation coefficient of 0.92. The proposed sensor and correction method provide a low-power and easy-to-maintain approach for reducing radiation-induced bias in naturally ventilated air-temperature measurements, with potential applications in meteorological observation, air-quality monitoring, and agricultural microclimate assessment. Full article

The present study investigates the effect of whey powder incorporation on the nutritional composition, structural characteristics, and functional properties of rice flour-based gluten-free systems. Composite flours and biscuits were formulated by substituting rice flour with 5%, 10%, and 15% whey powder. Proximate composition, mineral profile, and structural modifications were evaluated using standard analytical methods, complemented by Fourier Transform Infrared Spectroscopy (FTIR) and Small-Angle X-ray Scattering (SAXS). The results showed that whey addition significantly improved the protein content of both flours and biscuits, increasing from 8.45% in the control to 15.06% at the highest enrichment level. Whey powder showed elevated phosphorus (912 mg/kg), sodium (434.65 mg/kg), and calcium (526.49 mg/kg) contents compared to rice flour. Consequently, mineral levels increased progressively in the composite flours, with phosphorus rising from 528 mg/kg to 647 mg/kg, sodium from 105.66 mg/kg to 132.81 mg/kg, and calcium from 102.15 mg/kg to 137.33 mg/kg as the whey incorporation level increased. Iron content showed minor variations among the gluten-free biscuit formulations (76.01–95.16 mg/kg). Whey incorporation led to a progressive increase in copper content, from 8.91 mg/kg in the control biscuits to 15.50 mg/kg, while zinc levels decreased from 27.47 mg/kg to 18.47 mg/kg with increasing whey addition. FTIR analysis revealed clear structural changes associated with whey addition, including the progressive intensification of amide I and II bands and a reduction in starch-specific signals, confirming the incorporation of whey proteins into the starch matrix and the formation of protein–starch interactions. These findings were supported by SAXS analysis, which indicated modifications in the internal structural organization of the systems. Sensory evaluation indicated good overall acceptability of the fortified biscuits at moderate whey incorporation levels, while higher whey addition slightly reduced taste scores due to the characteristic salty flavor associated with acid whey. Overall, the study demonstrates that whey powder is an effective functional ingredient for enhancing the nutritional and structural properties of gluten-free products. However, achieving an optimal balance between improved nutritional quality, technological performance, and mineral composition remains essential for the development of high-quality gluten-free formulations. Full article

The nanoindentation analysis of zirconium carbide (ZrC) has been studied through molecular dynamics simulations, focusing on various factors such as temperature, stoichiometric ratio, and crystal orientation. The findings show that as temperature increases, both the critical pop-in load and the maximum load decrease, while atomic strain, von Mises stress, and residual indentation depth increase. High temperatures facilitate the nucleation and propagation of 1/2<110> dislocations, which enhance the material’s ability to undergo plastic deformation. Both indentation hardness and Young’s modulus decrease linearly as temperature rises or the concentration of C vacancy increases. For stoichiometric ZrC, as the temperature rises from 10 K to 2100 K, the hardness decreases from 45.04 GPa to 20.36 GPa, and Young’s modulus drops from 396.28 GPa to 254.45 GPa. At 10 K, when the C/Zr ratio is reduced to 0.5, the hardness and Young modulus decrease to 25.32 GPa and 192.09 GPa, respectively. This reduction is attributed to the weakening of Zr-C bonds, which also reduces stress concentration. At elevated temperatures, the impact of C vacancies on the nanoindentation process diminishes due to the thermal softening of the substrate, which lessens the effects of vacancy-induced softening. Regarding anisotropy, Young’s modulus at room temperature decreases from 383.39 GPa on the (001) plane to 335.93 GPa on the $(1\stackrel{\mathrm{-}}{1}0)$ plane, and it reduces further to 303.31 GPa on the $(1\stackrel{\mathrm{-}}{1}1)$ plane; hardness shows a similar decreasing trend. This trend is primarily due to differences in slip systems, surface energies, and the angles between the plane normal and the Zr-C bond axis located directly beneath the surface atoms. Overall, these results may provide theoretical support for the processing and application of ZrC. Full article

Wood’s inherent flammability, arising from its cellular organic composition, demands effective protective strategies. This study aimed to develop a multifunctional bio-based wood coating simultaneously integrating flame retardancy, optical transparency, moisture-triggered self-healing, and surface hydrophobicity within a single formulation. An intumescent flame retardant (PAGHR) was synthesized via ionic assembly of a phytic acid–phosphorylated polyethylene glycol conjugate (PgP) with a piperazine–etidronic acid salt (HEPHR), subsequently blended with gelatin (G) and surface-finished with fluorosilane. The optimized coating (G/PAGHR-4) achieved a limiting oxygen index (LOI) of 37.2% and passed the UL-94 V-0 rating. Cone calorimetry demonstrated reductions of 75.1% in peak heat release rate (pHRR) and 50.0% in total heat release (THR) relative to the neat gelatin control. Char yield at 700 °C increased substantially from 17.8 wt% to 41.0 wt%, confirming effective condensed-phase char promotion. Beyond fire performance, the coating maintained high visible-light transmittance, preserved natural wood aesthetics, and achieved macroscopic scratch healing within 40 min upon ambient water contact. Fluorosilane finishing elevated the water contact angle to 122°. These results establish a scalable, environmentally friendly strategy for multifunctional bio-based protective coatings applicable to wood, textiles, and polymer substrates. Full article

Optimizing the structural stability of foundations is challenging in modern geotechnical engineering. This study investigated the mechanism of geocell-reinforced foundations through discrete element modeling based on transparent soil model tests. A three-dimensional particle flow code (PFC^3D) model was developed to investigate the micromechanical soil–geocell interactions in both unreinforced and geocell-reinforced foundations under strip loading. Particle displacement, contact force distribution, and structural deformation within the foundation system were analyzed to quantify the performance of geocell reinforcement. The results show that geocell inclusion enhances structural performance by 2.1 times compared to an unreinforced foundation, increasing the bearing capacity from 60.6 to 126.8 kPa at a defined bearing capacity criterion. The geocell walls act as rigid physical boundaries that microscopically intercept the lateral migration and horizontal extrusion of soil particles. The kinematic trajectories of soil particles beneath the loading plate are forced into a downward realignment, decreasing the displacement vector rotation angle from 42° in the unreinforced soil to 27° in the reinforced soil and effectively mitigating the heave of adjacent surfaces. Furthermore, the quasi-rigid three-dimensional network completely interrupts the continuous steep contact force chains inherent in unreinforced foundations. Concentrated vertical stresses are converted into horizontal components through interfacial friction and mechanical interlocking, resulting in the lateral redistribution of the applied load by a distance of approximately 0.06 m. The geocell–soil composite considered as a flexible raft foundation extends load dispersion and reduces average subsoil pressure. A coupled tension and compression stress state in the horizontal plane is developed within the geocell structure. Forces are channeled along rigid paths by elevated bending moments and stress concentrations at the cell junctions. These findings provide micromechanical insights into the performance of geocell-reinforced-foundation systems. Full article

Reliable spatial georeferencing of mobile mapping platforms is a fundamental prerequisite for high-fidelity urban remote sensing products such as 3D point clouds and digital twins. However, in deep urban canyons, severe signal occlusion and multipath effects reduce visible GNSS satellites, causing ambiguity resolution (AR) failure and degraded observation geometry for UGV-borne systems. Conventional Vehicle-to-Vehicle (V2V) cooperation offers limited improvement due to symmetric ground-level occlusion. To overcome this, we propose an asymmetric GNSS/UWB fusion method that introduces Unmanned Aerial Vehicles (UAVs) as high-altitude dynamic spatial anchors to reconstruct the 3D observation geometry. Two contributions are presented: (i) an asymmetric heterogeneous stochastic model coupling carrier-to-noise ratio (C/N0) and elevation angle to handle the quality disparity between air and ground sensor links, preventing multipath contamination of high-fidelity UAV observations; and (ii) a dynamic baseline constrained least-squares algorithm integrating Ultra-Wideband (UWB) ranging to stabilize GNSS positioning under high-dynamic relative motion. Validated through high-fidelity simulations and field experiments, the method achieves a 98.2% AR success rate and sub-decimeter 3D accuracy under extreme occlusion (≤3 visible satellites), while urban-canyon tests demonstrate 100% positioning availability across all evaluated epochs and reduce the 95th-percentile 3D error from 7.25 m to 0.19 m under the tested single-UAV/single-UGV configuration. The framework supports smart city modeling, 3D reconstruction, and infrastructure monitoring. Full article