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Keywords = electrode cooling

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17 pages, 7068 KiB  
Article
Effect of Ni-Based Buttering on the Microstructure and Mechanical Properties of a Bimetallic API 5L X-52/AISI 316L-Si Welded Joint
by Luis Ángel Lázaro-Lobato, Gildardo Gutiérrez-Vargas, Francisco Fernando Curiel-López, Víctor Hugo López-Morelos, María del Carmen Ramírez-López, Julio Cesar Verduzco-Juárez and José Jaime Taha-Tijerina
Metals 2025, 15(8), 824; https://doi.org/10.3390/met15080824 - 23 Jul 2025
Viewed by 307
Abstract
The microstructure and mechanical properties of welded joints of API 5L X-52 steel plates cladded with AISI 316L-Si austenitic stainless steel were evaluated. The gas metal arc welding process with pulsed arc (GMAW-P) and controlled arc oscillation were used to join the bimetallic [...] Read more.
The microstructure and mechanical properties of welded joints of API 5L X-52 steel plates cladded with AISI 316L-Si austenitic stainless steel were evaluated. The gas metal arc welding process with pulsed arc (GMAW-P) and controlled arc oscillation were used to join the bimetallic plates. After the root welding pass, buttering with an ERNiCrMo-3 filler wire was performed and multi-pass welding followed using an ER70S-6 electrode. The results obtained by optical and scanning electron microscopy indicated that the shielding atmosphere, welding parameters, and electric arc oscillation enabled good arc stability and proper molten metal transfer from the filler wire to the sidewalls of the joint during welding. Vickers microhardness (HV) and tensile tests were performed for correlating microstructural and mechanical properties. The mixture of ERNiCrMo-3 and ER70S-6 filler materials presented fine interlocked grains with a honeycomb network shape of the Ni–Fe mixture with Ni-rich grain boundaries and a cellular-dendritic and equiaxed solidification. Variation of microhardness at the weld metal (WM) in the middle zone of the bimetallic welded joints (BWJ) is associated with the manipulation of the welding parameters, promoting precipitation of carbides in the austenitic matrix and formation of martensite during solidification of the weld pool and cooling of the WM. The BWJ exhibited a mechanical strength of 380 and 520 MPa for the yield stress and ultimate tensile strength, respectively. These values are close to those of the as-received API 5L X-52 steel. Full article
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20 pages, 4023 KiB  
Article
Numerical Study on the Thermal Behavior of Lithium-Ion Batteries Based on an Electrochemical–Thermal Coupling Model
by Xing Hu, Hu Xu, Chenglin Ding, Yupeng Tian and Kuo Yang
Batteries 2025, 11(7), 280; https://doi.org/10.3390/batteries11070280 - 21 Jul 2025
Viewed by 444
Abstract
The escalating demand for efficient thermal management in lithium-ion batteries necessitates precise characterization of their thermal behavior under diverse operating conditions. This study develops a three-dimensional (3D) electrochemical–thermal coupling model grounded in porous electrode theory and energy conservation principles. The model solves multi-physics [...] Read more.
The escalating demand for efficient thermal management in lithium-ion batteries necessitates precise characterization of their thermal behavior under diverse operating conditions. This study develops a three-dimensional (3D) electrochemical–thermal coupling model grounded in porous electrode theory and energy conservation principles. The model solves multi-physics equations such as Fick’s law, Ohm’s law, and the Butler–Volmer equation, to resolve coupled electrochemical and thermal dynamics, with temperature-dependent parameters calibrated via the Arrhenius equation. Simulations under varying discharge rates reveal that high-rate discharges exacerbate internal heat accumulation. Low ambient temperatures amplify polarization effects. Forced convection cooling reduces surface temperatures but exacerbates core-to-surface thermal gradients. Structural optimization strategies demonstrate that enhancing through-thickness thermal conductivity reduces temperature differences. These findings underscore the necessity of balancing energy density and thermal management in lithium-ion battery design, proposing actionable insights such as preheating protocols for low-temperature operation, optimized cooling systems for high-rate scenarios, and material-level enhancements for improved thermal uniformity. Full article
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21 pages, 5159 KiB  
Article
Energy-Efficient AC Electrothermal Microfluidic Pumping via Localized External Heating
by Diganta Dutta, Lanju Mei, Xavier Palmer and Matthew Ziemke
Appl. Sci. 2025, 15(13), 7369; https://doi.org/10.3390/app15137369 - 30 Jun 2025
Viewed by 247
Abstract
In this study, we present a comprehensive numerical investigation of alternating-current electrothermal (ACET) pumping strategies tailored for energy-efficient microfluidic applications. Using coupled electrokinetic and thermal multiphysics simulations in narrow microchannels, we systematically explore the effects of channel geometry, electrode asymmetry and external heating [...] Read more.
In this study, we present a comprehensive numerical investigation of alternating-current electrothermal (ACET) pumping strategies tailored for energy-efficient microfluidic applications. Using coupled electrokinetic and thermal multiphysics simulations in narrow microchannels, we systematically explore the effects of channel geometry, electrode asymmetry and external heating on flow performance and thermal management. A rigorous mesh convergence study confirms velocity deviations below ±0.006 µm/s across the entire operating envelope, ensuring reliable prediction of ACET-driven flows. We demonstrate that increasing channel height from 100 µm to 500 µm reduces peak temperatures by up to 79 K at a constant 2 W heat input, highlighting the critical role of channel dimensions in convective heat dissipation. Introducing a localized external heat source beneath asymmetric electrode pairs enhances convective circulations, while doubling the fluid’s electrical conductivity yields a ~29% increase in net flow rate. From these results, we derive practical design guidelines—combining asymmetric electrode layouts, tailored channel heights, and external heat bias—to realize self-regulating, low-power microfluidic pumps. Such devices hold significant promises for on-chip semiconductor cooling, lab-on-a-chip assays and real-time thermal control in high-performance microelectronic and analytical systems. Full article
(This article belongs to the Section Applied Thermal Engineering)
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27 pages, 26121 KiB  
Article
Spark Plasma Sintering and Electrospark Deposition of High Entropy Alloys with Elemental Variation
by Ciprian Alexandru Manea, Laura Elena Geambazu, Ileana Mariana Mateș, Delia Pătroi, Gabriela Beatrice Sbârcea, Dorinel Tălpeanu, Jan Přikryl, Gifty B. Oppong and Augustin Semenescu
Materials 2025, 18(12), 2799; https://doi.org/10.3390/ma18122799 - 13 Jun 2025
Viewed by 430
Abstract
A novel processing route of producing CrFeNiMo, Co0.5CrFeNiMo, and Al0.5CrFeNiMo high-entropy alloy coatings was proposed in this work. Pre-alloyed HEAs were consolidated by spark plasma sintering (SPS) in order to fabricate electrodes for electrospark deposition (ESD) coatings on carbon [...] Read more.
A novel processing route of producing CrFeNiMo, Co0.5CrFeNiMo, and Al0.5CrFeNiMo high-entropy alloy coatings was proposed in this work. Pre-alloyed HEAs were consolidated by spark plasma sintering (SPS) in order to fabricate electrodes for electrospark deposition (ESD) coatings on carbon steel substrates. Investigations were performed to observe aspects such as phase composition and stability, contamination level, homogeneity, elemental distribution, and microstructural integrity. The results indicated phase stability and lower porosity when increasing the SPS temperature by 50 °C for all cases, with tetragonal distortion related to the HEAs’ severe lattice distortion core effect. The coating surface analysis indicated that a continuous and compact coating was obtained, correlated with the ESD layering count, but microfissures were present after 6 layers were applied due to the reduced ductility combined with rapid cooling under Ar atmosphere. The chemical integrity of both the sintered samples and the coatings was preserved during the processing, revealing a uniform elemental distribution with no contaminations or impurities present. The results indicated successful HEA sintering and deposition, highlighting the potential of the combined SPS-ESD process for high-performance material fabrication with possible applications in aggressive environments. Full article
(This article belongs to the Section Metals and Alloys)
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26 pages, 85427 KiB  
Article
Analysis of the Effects of Tandem Welding (Fronius TPS/i - TWIN) of S1100QL and S1300QL Steels
by Mateusz Karczewski, Krzysztof Mroczka, Sławomir Parzych, Piotr Bała, Grzegorz Cios, Janusz Mikuła and Grzegorz Jeż
Materials 2025, 18(11), 2577; https://doi.org/10.3390/ma18112577 - 31 May 2025
Viewed by 551
Abstract
S1100QL and S1300QL steels are classified as fine-grained steels with a low-carbon martensitic structure. Tandem welding is a method of creating a joint by melting two electrode wires in a one-behind-the-other configuration. This article presents the effects of creating dissimilar joints, elements of [...] Read more.
S1100QL and S1300QL steels are classified as fine-grained steels with a low-carbon martensitic structure. Tandem welding is a method of creating a joint by melting two electrode wires in a one-behind-the-other configuration. This article presents the effects of creating dissimilar joints, elements of varying thicknesses made from S1100QL and S1300QL steels. The analysis focused on temperature changes in the heat-affected zone (HAZ) during welding, as well as the macro and microstructure, and the properties of the joints created at welding speeds of 80, 90, and 100 cm/min. The shortest cooling time (t8/5) in the HAZ for S1300QL steel was 9.4 s, while the longest was 12.4 s. Thermal cycle simulations were performed for the analyzed materials, with a cooling time of 5 s. The test results demonstrated that TWIN welding was stable, and an optimum welding speed is 80 cm/min. The HAZ microstructure for the highest cooling speed (t8/5 = 5 s) of S1100QL steel contains, in addition to martensite, lower bainite, while S1300QL steel consists of martensite. Tempered martensite was also detected at slower cooling rates. For all speed variants, the impact energy is above 27 J at a test temperature of −40 °C. In turn, hardness tests showed that the base material for both steels has the highest hardness. However, the lowest hardness was found for the weld. Full article
(This article belongs to the Section Manufacturing Processes and Systems)
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17 pages, 14716 KiB  
Article
Research on Electromagnetic Control Technology for the Roll Profile of Wide-Width Electrode Roll Press Rolls
by Chaojian Guo, Hao Chen, Jingna Sun, Huagui Huang, Xuening Fu and Zhijie Yang
Processes 2025, 13(5), 1448; https://doi.org/10.3390/pr13051448 - 9 May 2025
Viewed by 482
Abstract
To address the challenge of transverse thickness consistency in wide-width electrode calendering, this study developed a flexible roll profile regulation technology based on electromagnetic induction heating. An axisymmetric electromagnetic–thermal–structural coupling finite element model is established and validated on a self-built experimental platform. Systematic [...] Read more.
To address the challenge of transverse thickness consistency in wide-width electrode calendering, this study developed a flexible roll profile regulation technology based on electromagnetic induction heating. An axisymmetric electromagnetic–thermal–structural coupling finite element model is established and validated on a self-built experimental platform. Systematic simulations were conducted to investigate the influence of equivalent current density Js, current frequency f, and coil turn n on the roll temperature and roll profile. The maximum temperature of the roll’s inner bore and the roll crown exhibit a positive correlation with Js, f, and n. A cyclic heating strategy was developed to control and stabilize the roll profile. The stable crown CW shows linear correlation with heating durations t1 and a nonlinear trend with Js. Under fixed Js and t1, further optimization of duty cycle and cooling conditions enables long-term stabilization of the roll profile. Full article
(This article belongs to the Section Energy Systems)
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41 pages, 10418 KiB  
Review
Advancements in Vibration Testing: Effects on Thermal Performance and Degradation of Modern Batteries
by Khursheed Sabeel, Maher Al-Greer and Imran Bashir
Batteries 2025, 11(2), 82; https://doi.org/10.3390/batteries11020082 - 19 Feb 2025
Cited by 1 | Viewed by 3934
Abstract
Lithium-ion cells are increasingly being used as central power storage systems for modern applications, i.e., e-bikes, electric vehicles (EVs), satellites, and spacecraft, and they face significant and constant vibrations. This review examines how these vibrations affect the batteries’ mechanical, thermal, and electrical properties. [...] Read more.
Lithium-ion cells are increasingly being used as central power storage systems for modern applications, i.e., e-bikes, electric vehicles (EVs), satellites, and spacecraft, and they face significant and constant vibrations. This review examines how these vibrations affect the batteries’ mechanical, thermal, and electrical properties. Vibrations can cause structural issues, such as the separation of electrodes and the deformation of separators. These problems raise internal resistance and lead to localized heat generation. As a result, thermal management becomes more complicated, battery aging accelerates, and safety risks arise, including short circuits and thermal runaways. To tackle these challenges, we need more realistic testing protocols that consider the combined effects of vibrations, temperature, and mechanical stress. Improving thermal management systems (TMSs) using advanced cooling techniques and materials, e.g., phase change solutions, can help to alleviate these problems. It is also essential to design batteries with vibration-resistant materials and enhanced structural integrity to boost their durability. Moreover, vibrations play a significant role in various degradation mechanisms, including dendrite formation, self-discharge, and lithium plating, all of which can reduce battery capacity and lifespan. Our current research builds on these insights using a multiscale physics-based modeling approach to investigate how vibrations interact with thermal behavior and contribute to battery degradation. By combining computational models with experimental data, we aim to develop strategies and tools to enhance lithium-ion batteries’ safety, reliability, and longevity in challenging environments. Full article
(This article belongs to the Special Issue Advances in Lithium-Ion Battery Safety and Fire)
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14 pages, 2751 KiB  
Article
Synthesis of Y2O3 Oxide Dispersion-Strengthened Ti-6Al-2Sn-4Zr-2Mo Alloy Powder by In Situ Gas Atomization Method
by Hyeon-Tae Im, Ryun-Ho Kwak, Sung-Min Park, Chang-Soo Park and Hyung-Ki Park
Materials 2025, 18(3), 521; https://doi.org/10.3390/ma18030521 - 23 Jan 2025
Cited by 1 | Viewed by 1011
Abstract
Oxide dispersion-strengthened (ODS) alloys demonstrate enhanced mechanical properties at elevated temperatures and show potential as next-generation powder materials for additive manufacturing. These alloys can mitigate defects such as micropores and cracks by regulating solidification and grain growth behaviors during the additive manufacturing process. [...] Read more.
Oxide dispersion-strengthened (ODS) alloys demonstrate enhanced mechanical properties at elevated temperatures and show potential as next-generation powder materials for additive manufacturing. These alloys can mitigate defects such as micropores and cracks by regulating solidification and grain growth behaviors during the additive manufacturing process. This study investigates the fabrication technology for ODS Ti-6Al-2Sn-4Zr-2Mo (Ti6242) alloy powder to achieve uniform oxide distribution within the alloy powders. Thermodynamic calculations were employed to determine the optimal Ti6242–Y2O3 composition for in situ gas atomization, ensuring complete dissolution of the oxide in the Ti6242 molten metal and subsequent reprecipitation upon cooling. A rod-shaped ingot was produced via vacuum arc melting, resulting in coarse Y2O3 precipitating along the grain boundaries. The powder was fabricated through an electrode induction gas atomization method, and the ODS Ti6242 powder exhibited a spherical shape and a smooth surface. Cross-sectional analysis revealed the uniform distribution of Y2O3 oxide particles, measuring several tens of nanometers in size, within the alloy powder. This research demonstrates the successful synthesis of oxide-integrated ODS Ti6242 alloy powder through the in situ gas atomization method, potentially advancing the field of additive manufacturing for high-temperature applications. Full article
(This article belongs to the Special Issue Advanced Materials for Multifunctional Applications, 2nd Edition)
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36 pages, 7199 KiB  
Review
Electric Vehicle Battery Technologies: Chemistry, Architectures, Safety, and Management Systems
by Dmitrii K. Grebtsov, Mikhail K. Kubasov, Egor R. Bernatskii, Pavel A. Beliauski, Andrey A. Kokorenko, Shakhboz Sh. Isokjanov, Sergey P. Kazikov, Alexey M. Kashin, Daniil M. Itkis and Sofia M. Morozova
World Electr. Veh. J. 2024, 15(12), 568; https://doi.org/10.3390/wevj15120568 - 10 Dec 2024
Cited by 3 | Viewed by 7994
Abstract
Electric and hybrid vehicles have become widespread in large cities due to the desire for environmentally friendly technologies, reduction of greenhouse gas emissions and fuel, and economic advantages over gasoline and diesel vehicles. In electric vehicles, overheating, vibration, or mechanical damage due to [...] Read more.
Electric and hybrid vehicles have become widespread in large cities due to the desire for environmentally friendly technologies, reduction of greenhouse gas emissions and fuel, and economic advantages over gasoline and diesel vehicles. In electric vehicles, overheating, vibration, or mechanical damage due to collision with an object or another vehicle can lead to the failure of lithium-ion batteries up to thermal runaway and fire. Therefore, the development of battery safety control systems is one of the most important factors contributing to the large-scale electrification of public and private transport. This review examines the design features of the location and management of the battery pack to achieve maximum safety and operational efficiency when using an electric vehicle. The power characteristics and life-cycles of various types of lithium-ion batteries depending on the chemical nature of their electrodes are considered, using the example of commercial vehicles’—Tesla, Nissan Leaf, Porsche Taycan, Zeekr, and Chevrolet Volt—strategic technologies for the placement and packaging of batteries, and battery cooling and monitoring systems (State of Health and State of Charge) are also discussed. In conclusion, the current challenges in the field are summarized and promising research directions are proposed. Full article
(This article belongs to the Special Issue Intelligent Electric Vehicle Control, Testing and Evaluation)
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15 pages, 4303 KiB  
Article
Energy Efficiency in Measurement and Image Reconstruction Processes in Electrical Impedance Tomography
by Barbara Stefaniak, Tomasz Rymarczyk, Dariusz Wójcik, Marta Cholewa-Wiktor, Tomasz Cieplak, Zbigniew Orzeł, Janusz Gudowski, Ewa Golec, Michał Oleszek and Marcin Kowalski
Energies 2024, 17(23), 5828; https://doi.org/10.3390/en17235828 - 21 Nov 2024
Viewed by 781
Abstract
This paper presents an energy optimization approach to applying electrical impedance tomography (EIT) for medical diagnostics, particularly in detecting lung diseases. The designed Lung Electrical Tomography System (LETS) incorporates 102 electrodes and advanced image reconstruction algorithms. Energy efficiency is achieved through the use [...] Read more.
This paper presents an energy optimization approach to applying electrical impedance tomography (EIT) for medical diagnostics, particularly in detecting lung diseases. The designed Lung Electrical Tomography System (LETS) incorporates 102 electrodes and advanced image reconstruction algorithms. Energy efficiency is achieved through the use of modern electronic components and high-efficiency DC/DC converters that reduce the size and weight of the device without the need for additional cooling. Special attention is given to minimizing energy consumption during electromagnetic measurements and data processing, significantly improving the system’s overall performance. Research studies confirm the device’s high energy efficiency while maintaining the accuracy of the classification of lung disease using the LightGBM algorithm. This solution enables long-term patient monitoring and precise diagnosis with reduced energy consumption, marking a key step towards sustainable medical diagnostics based on EIT technology. Full article
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16 pages, 1791 KiB  
Article
Exploring the Impact of State of Charge and Aging on the Entropy Coefficient of Silicon–Carbon Anodes
by Kevin Böhm, Simon Zintel, Philipp Ganninger, Jonas Jäger, Torsten Markus and David Henriques
Energies 2024, 17(22), 5790; https://doi.org/10.3390/en17225790 - 20 Nov 2024
Cited by 1 | Viewed by 1094
Abstract
Due to its improved capacity compared to graphite, silicon is a promising candidate to handle the demands of high-energy batteries. With the introduction of new materials, further aspects of the battery system must be reconsidered. One of those aspects is the heat generation [...] Read more.
Due to its improved capacity compared to graphite, silicon is a promising candidate to handle the demands of high-energy batteries. With the introduction of new materials, further aspects of the battery system must be reconsidered. One of those aspects is the heat generation during the charging and discharging of a cell, which delivers important information for the development of cooling systems, the battery management system and the overall performance of the cell. Since the reversible heat presents an important contribution to the overall heat generation during cycling, the entropy coefficient is the main value that needs to be determined. This study evaluates the entropy coefficient of custom-produced 2032 coin half-cells with lithium counter electrodes, containing 45 wt% nanosilicon and 45 wt% carbon black. The potentiometric method, utilizing VR and self-discharge curves, produced reliable results, yielding entropy coefficient values between 95% SoC and 10% SoC during delithiation. These values of the entropy coefficient are consistently negative. Furthermore, ICA measurements identified two phase transitions during delithiation, with these transitions shifting to lower SoC as SoH decreases, impacting the slope of the entropy coefficient. Full article
(This article belongs to the Section D2: Electrochem: Batteries, Fuel Cells, Capacitors)
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17 pages, 3162 KiB  
Article
Enhancing the Reliability of NO2 Monitoring Using Low-Cost Sensors by Compensating for Temperature and Humidity Effects
by Daniellys Alejo Sánchez, Olivier Schalm, Arianna Álvarez Cruz, Erik Hernández Rodríguez, Alain Martínez Laguardia, David Kairuz Cabrera and Mayra C. Morales Pérez
Atmosphere 2024, 15(11), 1365; https://doi.org/10.3390/atmos15111365 - 13 Nov 2024
Cited by 1 | Viewed by 1168
Abstract
The study investigates methods to enhance the reliability of NO2 monitoring using low-cost electrochemical sensors to measure gaseous pollutants in air by addressing the impacts of temperature and relative humidity. The temperature within a plastic container was controlled using an internal mica [...] Read more.
The study investigates methods to enhance the reliability of NO2 monitoring using low-cost electrochemical sensors to measure gaseous pollutants in air by addressing the impacts of temperature and relative humidity. The temperature within a plastic container was controlled using an internal mica heater, an external hot air blower, or cooling packs, while relative humidity was adjusted using glycerine solutions. Findings indicated that the auxiliary electrode signal is susceptible to temperature and moderately affected by relative humidity. In contrast, the working electrode signal is less affected by temperature and relative humidity; however, adjustments are still required to determine gas concentrations accurately. Tests involving on/off cycles showed that the auxiliary electrode signal experiences exponential decay before stabilizing, requiring the exclusion of initial readings during monitoring activities. Additionally, calibration experiments in zero air allowed the determination of the compensation factor nT across different temperatures and humidity levels. These results highlight the importance of compensating for temperature and humidity effects to improve the accuracy and reliability of NO2 measurements using low-cost electrochemical sensors. This refinement makes the calibration applicable across a broader range of environmental conditions. However, the experiments also show a lack of repeatability in the zero air calibration. Full article
(This article belongs to the Section Air Quality)
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14 pages, 6148 KiB  
Article
Pt3(CoNi) Ternary Intermetallic Nanoparticles Immobilized on N-Doped Carbon Derived from Zeolitic Imidazolate Frameworks for Oxygen Reduction
by Shiqi Song, Junhua Hu, Chupeng Wang, Mingsheng Luo, Xiaoxia Wang, Fengxia Zhai and Jianyong Zheng
Materials 2024, 17(19), 4775; https://doi.org/10.3390/ma17194775 - 28 Sep 2024
Viewed by 1112
Abstract
Pt-based intermetallic compound (IMC) nanoparticles have been considered the most promising catalysts for oxygen reduction reaction (ORR) in proton exchange membrane fuel cells (PEMFC). Herein, we propose a strategy for producing ordered Pt3(CoNi) ternary IMC nanoparticles supported on N-doped carbon materials. [...] Read more.
Pt-based intermetallic compound (IMC) nanoparticles have been considered the most promising catalysts for oxygen reduction reaction (ORR) in proton exchange membrane fuel cells (PEMFC). Herein, we propose a strategy for producing ordered Pt3(CoNi) ternary IMC nanoparticles supported on N-doped carbon materials. Particularly, the Co and Ni are originally embedded into ZIF-derived carbon, which diffuse into Pt nanocrystals to form Pt3(CoNi) nanoparticles. Moreover, a thin layer of carbon develops outside of Pt3(CoNi) nanoparticles during the cooling process, which contributes to stabilizing the Pt3(CoNi) on carbon supports. The optimal Pt3(CoNi) nanoparticle catalyst has achieved significantly enhanced activity and stability, exhibiting a half-wave potential of 0.885 V vs reversible hydrogen electrode (RHE) and losing only 16 mV after 10,000 potential cycles between 0.6 and 1.0 V. Unlike the direct-use commercial carbon (VXC-72) for depositing Pt, we utilized ZIF-derived carbon containing dispersed Co and Ni nanocluster or nanoparticles to prepare ordered Pt3(CoNi) intermetallic catalysts. Full article
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18 pages, 6032 KiB  
Article
Evaluating a Fe-Based Metallic Glass Powder as a Novel Negative Electrode Material for Applications in Ni-MH Batteries
by Oscar Sotelo, John Henao, Carlos Poblano, Bernardo Campillo, Erick Castañeda, Néstor Flores, Arturo Molina and Horacio Martínez
Batteries 2024, 10(9), 312; https://doi.org/10.3390/batteries10090312 - 1 Sep 2024
Viewed by 1643
Abstract
Metallic glasses (MGs) are a type of multicomponent non-crystalline metallic alloys obtained by rapid cooling, which possess several physical, mechanical, and chemical advantages against their crystalline counterparts. In this work, an Fe-based MG is explored as a hydrogen storage material, especially, due to [...] Read more.
Metallic glasses (MGs) are a type of multicomponent non-crystalline metallic alloys obtained by rapid cooling, which possess several physical, mechanical, and chemical advantages against their crystalline counterparts. In this work, an Fe-based MG is explored as a hydrogen storage material, especially, due to the evidence in previous studies about the capability of some amorphous metals to store hydrogen. The evaluation of an Fe-based MG as a novel negative electrode material for nickel/metal hydride (Ni-MH) batteries was carried out through cyclic voltammetry and galvanostatic charge–discharge tests. A conventional LaNi5 electrode was also evaluated for comparative purposes. The electrochemical results obtained by cyclic voltammetry showed the formation of three peaks, which are associated with the formation of Fe oxides/oxyhydroxides and hydroxides. Cycling charge/discharge tests revealed activation of the MG electrode. The highest discharge capacity value was 173.88 mAh/g, but a decay in its capacity was observed after 25 cycles, contrary to the LaNi5, which presents an increment of the discharge capacity for all the current density values evaluated, reached its value maximum at 183 mAh/g. Characterization analyses performed by X-ray diffraction, Scanning Electron Microscopy and Raman Spectroscopy revealed the presence of corrosion products and porosity on the surface of the Fe-based MG electrodes. Overall, the Fe-based MG composition is potentially able to work as a negative electrode material, but degradation and little information about storage mechanisms means that it requires further investigation. Full article
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22 pages, 12319 KiB  
Article
Electric-Thermal Analysis of Power Supply Module in Graphitization Furnace
by Xiangbin Xia, Shijun Li, Derong Luo, Sen Chen, Jing Liu, Jiacheng Yao, Liren Wu and Ximing Zhang
Energies 2024, 17(17), 4251; https://doi.org/10.3390/en17174251 - 26 Aug 2024
Cited by 1 | Viewed by 4090
Abstract
Graphite, a key anode material in lithium-ion batteries, primarily relies on the Acheson graphitization furnace (AGF) for production. This research focuses on the power supply module of the AGF, particularly the electrodes and their power transmission clamps. A three-dimensional transient electric-thermal-fluid coupling model [...] Read more.
Graphite, a key anode material in lithium-ion batteries, primarily relies on the Acheson graphitization furnace (AGF) for production. This research focuses on the power supply module of the AGF, particularly the electrodes and their power transmission clamps. A three-dimensional transient electric-thermal-fluid coupling model was developed to numerically analyze the temperature and electric field distributions during operation. The study revealed that heat conduction through furnace electrodes dominates temperature rise. Notably, clamping plates within transmission clamps exhibit high temperatures and gradients, posing a thermal failure risk. Efficient cooling plate design with liquid-cooled channels is crucial for temperature control. Additionally, maintaining high electrode temperatures reduces resistivity, lowering power consumption in the power supply module. This study provides insights into optimizing AGF power supply module design, emphasizing the importance of effective cooling strategies for clamping plates and the benefits of maintaining elevated electrode temperatures for energy efficiency. Full article
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