Search Results (982)

According to the World Health Organization (WHO), substance dependence and mental health disorders, such as anxiety, depression, post-traumatic stress disorder (PTSD), insomnia, bipolar disorder, and schizophrenia, affect >360 million people worldwide. As a result the increasing use of psychoactive pharmaceuticals, including non-benzodiazepines (also referred to as Z-drugs), has been observed. The COVID-19 pandemic has also had an additional significant negative effect on people’s mental health. Among the aforementioned mental health disorders, chronic insomnia is reported to affect approximately 10% of the adult population. Z-drugs are frequently used in the treatment of insomnia due to their rapid onset of action. They are metabolized in the human organism, but noticeable amounts of the original compound are released to the environment via household wastewater. The extensive use of these pharmaceuticals has led to growing concern about the occurrence of their residues in the environment. Unfortunately, the information on the analytical methods for determining Z-drugs, their main metabolites and transformation products in the environment, efficiency of their removal in wastewater treatment plants, their fate, their presence in environmental matrices, and their ecotoxicological effects is limited. This review paper focuses on summarizing data on these topics. To the best of our knowledge, such a comprehensive review has not yet been published. Full article

Portable toilets (PTs) play a crucial role in addressing global sanitation needs at events, construction sites, disaster areas, and remote locations. However, conventional cleaning products for PTs often contain harmful chemicals, which pose environmental risks. These substances negatively impact wastewater treatment plant (WWTP) microorganisms and overload treatment systems. Worldwide regulatory changes are pushing for products that are safe for both end-users and the environment. This trend is driving the need for new formulations and technologies in PT products. While popular PT cleaning solutions effectively control odors and pathogens, they often cause ecotoxicity and regulatory issues. Consequently, there is a growing need to explore alternative solutions free from the drawbacks of harmful chemicals. This review examines available environmentally friendly solutions and critically evaluates their potential for use in cleaning portable toilets. Biopreparations containing microorganisms and/or enzymes show exceptional promise. These solutions accelerate organic breakdown, increase the biodegradability of PTs wastewater, suppress odors, and reduce sludge volume. Transitioning to sustainable, bio-based cleaners is essential for environmental protection and regulatory compliance. Therefore, despite some limitations of biopreparations, it is envisioned that the future portable toilets will move towards engineered biopreparation for sustainable, chemical-free sanitation solutions. Full article

This study assesses the environmental performance of three wastewater treatment setups through an attributional, gate-to-gate life cycle assessment (functional unit: 1 m³ of treated wastewater): (Sc1) a traditional municipal wastewater treatment plant, (Sc2) an aquaculture recirculation system using microalgae, and (Sc3) a domestic system combining UASB pretreatment with microalgae polishing. Inventory data were analyzed in SimaPro with ReCiPe 2016 Midpoint (Hierarchist) across seven effect categories. Robustness was tested through sensitivity analyses (±20%) of power consumption and influent characteristics, as well as an additional scenario exploring the offset of methane-recovery electricity. The global warming impact remained consistent across scenarios, ranging from 60.5 to 65.1 kg CO₂-eq·m⁻³, indicating no significant difference within the operational parameters. In most categories, power consumption and influent-related burdens were the main contributors, while the impacts from flocculants and microalgae inoculum were minimal. Sc3 showed a lower freshwater eutrophication potential compared to Sc1 and Sc2 (0.028 vs. approximately 0.049 kg P-eq·m⁻³). Normalization highlighted human carcinogenic toxicity and aquatic ecotoxicity as key impact categories. The methane-offset scenario caused only slight changes at low CH₄ outputs, suggesting that energy recovery depends on context. Full article

Ketoprofen is a widely prescribed non-steroidal anti-inflammatory drug whose extensive global use, combined with limited biodegradability, has led to its increasing detection as a micropollutant in aquatic and terrestrial environments. Incomplete removal during wastewater treatment results in its continuous release into surface waters and soils, creating conditions for chronic, low-dose exposure of non-target organisms. This review synthesizes current knowledge on the physicochemical characteristics of ketoprofen, its mechanism of action, environmental occurrence, degradation pathways, and ecotoxicological effects. Particular emphasis is placed on biological and photochemical transformation processes that influence ketoprofen persistence and toxicity. While the acute toxicity of ketoprofen has been relatively well documented, data on chronic toxicity remain scarce, despite growing evidence that long-term exposure may pose significant ecological risks. Studies indicate that low environmental concentrations can induce hormetic responses in animals and plants, whereas higher levels may cause cellular damage associated with oxidative stress, affecting organisms ranging from microorganisms to vertebrates and vascular plants. By integrating available data on ketoprofen degradation and toxicity, this review highlights critical knowledge gaps regarding its chronic ecotoxicity and underscores the need for systematic environmental monitoring and the development of effective degradation strategies to mitigate risks to non-target organisms. Full article

Textile wastewater contains recalcitrant azo dyes and auxiliary chemicals that are resistant to conventional biological treatment, resulting in persistent organic pollution in aquatic ecosystems. While supercritical water oxidation (SCWO) achieves superior chromophore mineralization, its high energy requirements limit industrial scalability. Conversely, biomass-derived activated carbon (BAC) offers a low-cost adsorption solution, but it rapidly becomes saturated with toxic oxidation intermediates. Notably, the literature lacks systematic analyses of hybrid SCWO-BAC systems with integrated thermal energy, which represents a crucial gap in assessing their economic feasibility. This review employed a systematic methodology, selecting studies relevant to the topic from peer-reviewed publications and databases, including Scopus, SciELO, ScienceDirect, and Google Scholar, for critical synthesis. Using SCWO as a pretreatment (which significantly reduces COD load), followed by BAC polishing, results in superior detoxification compared to individual processes. However, three barriers hinder scale-up: (i) chloride ion corrosion in real effluents; (ii) irreversible collapse of BAC pores after multiple regeneration cycles; and (iii) absence of standardized ecotoxicity data for hybrid-treated streams. This work outlines a technological roadmap for integrated supercritical water oxidation and biological activated carbon (SCWO-BAC) systems, targeting economically viable operational parameters for industrial-scale implementation. Full article

Carbon dots (C-Dots) have attracted significant interest due to their strong photoluminescence, aqueous stability, and tunable surface chemistry; however, their environmental safety remains incompletely understood. In this work, C-Dots were synthesized via a rapid microwave-assisted method using two different carbon precursors, D-glucose and ascorbic acid, with ethylenediamine as a passivating agent. The resulting nanoparticles exhibited predominantly amorphous structures with sizes below 10 nm, characteristic absorption bands at ~280–330 nm, and blue photoluminescence centered at ~450 nm. Acute toxicity was evaluated using Brine shrimp at concentrations ranging from 10 to 2000 ppm after 24 and 48 h of exposure. C-Dots synthesized from ascorbic acid showed significant toxicity at 2000 ppm, inducing higher mortality rates after 24 h, whereas D-glucose-derived C-Dots exhibited minimal toxic effects under the same conditions. These findings demonstrate that carbon precursor selection plays a critical role in determining the environmental toxicity of C-Dots and highlight the importance of precursor-dependent design strategies to minimize potential ecological risks associated with carbon-based nanomaterials. Full article

With the rapid development of intensive animal husbandry, the widespread use of livestock and poultry manure as organic fertilizers has become a major anthropogenic source of antibiotic contamination in agricultural soils. Antibiotics, classified as “emerging contaminants” owing to their persistence, biological activity, and potential ecotoxicity, undergo environmental fate processes such as adsorption–desorption, migration, transformation, and degradation upon entering orchard soils, with their behaviors regulated by multiple factors, including soil physicochemical properties, microbial communities, and climatic conditions. Antibiotics not only alter the structure and diversity of soil microbial communities, inhibit soil enzyme activities, and interfere with the cycling of carbon, nitrogen, and phosphorus nutrients but also induce the generation and dissemination of antibiotic resistance genes (ARGs) and affect the growth and reproduction of soil animals, triggering cascading effects on ecological processes. Moreover, antibiotics can be absorbed by fruit tree roots and transported to aboveground organs via the xylem or phloem. By interfering with photosynthesis, disrupting antioxidant systems, and affecting hormone balance, they inhibit the growth and development of fruit trees, thereby altering the appearance, nutritional, and flavor qualities of fruits. Furthermore, antibiotic residues and ARGs in fruits pose potential risks to food safety. This paper thoroughly analyzes the pollution levels, environmental interactions, and disposition of antibiotics in orchard soils, focusing on the mechanisms that influence their impact on soil microecology and biochemical processes. It also explores the absorption, transport, and accumulation patterns of antibiotics in fruit trees, as well as their effects on tree physiology, growth, fruit quality, and safety. Finally, the current research gaps and prospects are identified, aiming to provide a theoretical basis for ecological risk assessment, scientific prevention and control of antibiotic contamination in orchard ecosystems, and safeguarding of agricultural product safety. Full article

Climate change is increasing forest vulnerability, and extreme disturbances such as windstorms can cause major economic and social losses. Forest recovery after such events often relies on salvage logging and extensive planting of seedlings produced in nurseries to rapidly restore forest cover. While effective, these interventions, particularly when applied over large areas, may also produce environmental impacts that are largely absent under spontaneous regeneration. Following the Vaia windstorm in northern Italy in 2018, several reforestation interventions were implemented to restore forest cover. We focused on one intervention and conducted a life cycle assessment to quantify its environmental impacts, using the planting of 800 four-year-old Norway spruce (Picea abies (L.) H. Karst) seedlings as the functional unit, combined with chipping on the site of forest biomass residues. The largest contributions were to global warming potential (443.91 kg CO₂ eq), human toxicity (167.72 kg 1,4-DCB eq), and freshwater ecotoxicity (142.43 kg 1,4-DCB eq). Seedling production and field establishment dominated these impact categories. Among field operations, manufacturing and transporting plastic shelters for seedling protection accounted for the highest share of global warming potential. Full article

Background: Traditional methods exhibit an extremely low removal efficiency for antibiotics in water, making an efficient and energy-saving approach urgently needed. Methods and Results: In this study, a novel catalytic approach based on the in situ generation of high-valent iron (Fe(IV)/Fe(V)) has been developed by adding biochar instead of modifying the electrode materials (in previous studies) for the efficient removal of sulfamethoxazole (SMX) from water. Fe(IV)/Fe(V) was produced by the anodic oxidation of low concentrations of Fe(III) and subsequently activated by nitrogen-doped corn stalk biochar (NBC). The results showed that the degradation efficiency increased from 50.83% to 90.67% within 60 min after the addition of nitrogen-modified biochar. The abundant defect structures, graphitic N and oxygen-containing functional groups in NBC endowed the catalyst with excellent activation capability. Quenching experiments and methyl phenyl sulfoxide (PMSO) probe experiments revealed that singlet oxygen (¹O₂) and Fe(IV)/Fe(V) were the main contributors to SMX degradation. Degradation pathways were inferred based on transformation products (TPs) and density functional theory (DFT) calculations. Ecotoxicity prediction using the ECOSAR program indicated that the TPs formed in the E/Fe(III)/NBC system exhibited markedly lower toxicity to aquatic organisms than the parent SMX. Furthermore, the E/Fe(III)/NBC system maintained a high degradation efficiency for SMX in real aquatic environments. Additionally, the E/Fe(III)/NBC system showed high removal rates for other sulfonamides such as sulfadiazine (SDZ), sulfamethoxypyridazine (SMP), sulfathiazole (STZ) and sulfadoxine (SDX). Conclusions: Overall, the E/Fe(III)/NBC system was demonstrated to be a highly efficient and sustainable technology for removing various antibiotics from water. Full article

Securing mine sites is a challenging task due to the complexity of the infrastructure, the variety of physical and digital components, the distribution of assets and machineries, and the large number of stakeholders involved. Given the risks that are present in Tailings Storage Facilities (TSFs), mine operators are seeking technologies to accurately monitor the state of their dams. The latest developments implement evolutive monitoring and responsive risk management systems by adapting accurate Internet of Things technologies, automated mathematical model calculation to continually monitor the structural/geotechnical aspects of TSF, and a portfolio of innovative applications to support decision-making. Within this study, a comprehensive methodology is developed for assessing the environmental sustainability of a smart monitoring solution combining the life cycle assessment (LCA) method with the environmental risk assessment, which quantifies risk reduction potential. The use case scenario is identified based on real industrial data, also aligned with the common characteristics of tailing dams in Europe. Environmental sustainability of the smart monitoring solution is assessed through a cradle-to-grave LCA based on the ReCiPe 2016 (v1.1 Midpoint (H)) method. Monitoring impact alone is reduced primarily by the 40% reduction in monitoring visits, while the results show the environmental improvement of the TSF life cycle by 24% for CO₂-eq., as a step in-line with the EU’s long-term strategy for total decarbonisation in 2050, and Sustainable Development Goal 9 for Industry by the United Nations. Additionally, the 27% freshwater ecotoxicity reduction, 20% human toxicity (cancer) decrease, and the rest of the studied categories indicate an overall footprint improvement for the monitoring solution application on TSFs. The findings demonstrate clearly theoretical, practical and policy implications, not only for the benefit of such solutions for environmental protection, but also for the necessity of integrating risk in sustainability analysis approaches. Full article

In this study, menus created by considering different food categories by the Mediterranean diet (MD) and Western diet (WD) were evaluated in terms of healthy nutrition, and their environmental footprints were comprehensively compared with life cycle analysis (LCA). The analysis was modeled using SimaPro 9.6, and the EcoInvent 3.10 and Agri-footprint 6.3 databases were used as secondary data sources. In 12 of the 15 environmental impact categories examined, MD had lower environmental impacts than WD. The climate change impact was estimated as 2.19 kg CO₂-eq for MD, while it was 3.53 kg CO₂-eq for WD. Similarly, freshwater ecotoxicity was 103 CTUe for MD and 418 CTUe for WD. However, MD showed 72% higher human toxicity (cancer) (ΔHTC), 32.5% higher water use (ΔWU), and 12.7% higher mineral-metal resource use (ΔRUM). The findings suggest that MD supports environmental sustainability because of its plant-based structure, whereas WD creates a greater environmental burden due to its high animal-derived content. Full article

The potential withdrawal of glyphosate necessitates a comprehensive evaluation of alternative weed control strategies that balances human health safety with environmental concerns. This study applied a decision-support grid to compare the impacts of glyphosate-based reference strategies against chemical and non-chemical alternatives across four Belgian case studies: pome fruit orchards, grassland renewal, arable weed patches, and railways. The assessment integrated twelve risk indicators including human, environmental and biodiversity risk, and life cycle assessment for global warming potential (GWP) into a Final Scenario Score (FSS). The results indicated that only one alternative strategy, the chemical alternative in local weed patch control, achieved the FSS threshold (<0.75) required to justify substitution (FSS = 0.70). Chemical alternatives in other case studies frequently shifted burdens; for instance, bio-herbicides in railways increased risks to residents and aquatic organisms compared to the reference. Conversely, mechanical and thermal alternatives eliminated chemical toxicity but resulted in GWP increases up to 32 times higher than glyphosate-based practices. These findings demonstrate that chemical substitutes often maintain toxicity risks while non-chemical strategies trade them for increased climate impacts. Consequently, a ban on glyphosate is currently unsupported by the environmental performance of available alternatives in these temperate high-intensity systems. Sustainable progress requires a transition period where optimized conventional strategies remain available within integrated weed management, while innovations in electrification and precision technology are accelerated to resolve current trade-offs. Full article

This study presents a comparative Life Cycle Assessment (LCA) of packaging for 1000 kg of fresh-cut salad using conventional polypropylene (PP) and bio-based INZEA^® FH05 bags. Using the Product Environmental Footprint (PEF) methodology, the analysis revealed weighted scores of 152 ± 14 mPt for PP and 158 ± 14 mPt for the bioplastic. To distinguish between statistical significance and practical relevance, a Monte Carlo Analysis (MCA) was performed. Statistical significance was defined by the probability P(PP ≥ INZEA^®), representing the frequency of iterations where the PP impact was greater than or equal to the bioplastic, while practical relevance was assessed by the percentage difference (Δ) between mean values. The MCA demonstrates that the PP system is the environmentally preferable option in 91.5% of the simulated iterations; correspondingly, there is only an 8.5% probability (P) that PP results in a higher impact than the bioplastic. Despite this high frequency of preference, the overall tangible benefit remains modest, with a 4.1% reduction (Δ) in the total PEF score for PP. At the characterization level, bioplastic films showed a robust advantage in fossil resource depletion (P = 96.2%; Δ = +4.7% for PP); however, this was offset by significantly higher impacts in categories such as Acidification (P = 0%; Δ = −11.0%) and Freshwater Ecotoxicity (P = 0%; Δ = −29.7%). Conversely, the Climate Change category showed environmental parity with no tangible benefit (Δ = −0.5%) and a lack of statistical significance (P = 43%). These findings indicate that the theoretical benefits of compostability are currently hindered by industrial infrastructural deficiencies. Under current scenarios, PP maintains a competitive environmental profile, highlighting that a successful transition to bioplastics requires both material innovation and systemic improvements in waste management infrastructure. Full article

Organic dye pollution in industrial wastewater poses a serious environmental challenge, with methylene blue (MB) serving as a typical persistent pollutant due to its stable chemical structure, recalcitrance to degradation, and eco-toxicity. Conventional physical, chemical, and biological treatment methods suffer from limitations such as insufficient efficiency, high cost, or the tendency to generate secondary pollution. Based on green and sustainable photocatalysis technology, this study designed and prepared a NiO/SrTiO₃ p-n heterojunction photocatalysts, aiming to broaden the light-response range and enhance charge-carrier separation efficiency. The optimal sample (NiO (10%)/SrTiO₃) achieved complete photocatalytic degradation of MB within 9 min, with an apparent rate constant 34.6 times that of pure SrTiO₃. It also showed good cyclic stability. Trapping experiments confirmed that •OH and •O₂⁻ were the key active species in the degradation process. Combined with band structure and PL analyses, an S-scheme charge-transfer mechanism was proposed, clarifying the critical role of the built-in electric field at the heterojunction interface in promoting carrier separation while maintaining high redox capability. This work not only provides a new pathway for developing efficient and stable SrTiO₃-based photocatalysts but also offers theoretical and experimental support for the practical application of p-n heterojunction photocatalysts in environmental pollution control. Full article

Artificial water bodies in post-mining landscapes often remain chemically altered and ecologically degraded, yet their ecological risk is frequently underestimated by conventional water quality assessments. Persistent toxicity in mining-impacted waters is a global challenge, as acidity alone often fails to explain the adverse biological effects observed. This study assessed the ecological condition of three artificial ponds in a former gold–antimony mining area (Midões, northern Portugal), using an integrated framework that combined physicochemical and biological (phytoplankton and macroinvertebrates) elements with ecotoxicological assays. Ecotoxicity was evaluated using Lemna minor (growth inhibition) and Daphnia magna (acute toxicity, survival, and feeding rate) under untreated water and pH-adjusted conditions to disentangle acidity-driven effects from other chemical stressors. According to Water Framework Directive metrics, all ponds were classified as having moderate ecological potential, driven by persistent acidic conditions and elevated heavy metal concentrations (e.g., zinc and cadmium). Biological communities showed marked temporal/spatial variability, reflecting physicochemical differences among ponds. Phytoplankton showed summer blooms of cyanobacteria, while macroinvertebrates were generally dominated by tolerant taxa (exhibiting low taxonomic richness/diversity). Ecotoxicological assays showed consistent toxicity across all sampling periods, with high mortality and reduced feeding rates in D. magna and growth inhibition in L. minor. Notably, toxicity often persisted even after pH adjustment, indicating that the observed biological effects were not driven by acidity but were largely attributable to residual metal contamination. These findings highlight the ecological vulnerability of mining-impacted water bodies and underscore the need for management and remediation strategies that address metal removal in addition to pH correction. Full article