Search Results (12)

Nickel is used in aerospace, military, energy, and chemical sectors. Commercially pure (CP) Ni, and its alloys, including solid-solution strengthened (SSS), precipitation strengthened (PS), and specialty alloys (SA), are widely utilized, typically at elevated temperatures, in corrosive settings and in cryogenic milieu. Ni or Ni-based alloys frequently require welding realized, inter alia, via methods using electric arc and beam power. Tungsten inert gas (TIG) and Electron-beam welding (EBW) have been utilized most often. Friction stir welding (FSW) is the most promising solid-state welding technique for connecting Ni and its alloys. The primary weldability issues related to Ni and its alloys are porosity, as well as hot and warm cracking. CP Ni exhibits superior weldability. It is vulnerable to porosity and cracking during the solidification of the weld metal. Typically, SSS alloys demonstrate superior weldability when compared to PS Ni alloys; however, both types may experience weld metal solidification cracking, liquation cracking in the partially melted and heat-affected zones, as well as ductility-dip cracking (DDC). Furthermore, PS alloys are prone to strain-age cracking (SAC). The weldability of specialty Ni alloys is limited, and brazing might provide a solution. Employing appropriate filler metal, welding settings, and minimal restraint can reduce or avert cracking. Full article

Features of microstructure, mechanical properties, and cracking behaviour of the René 80-type superalloy manufactured by laser-based directed energy deposition (DED-LB) have been investigated. Different cracking behaviours were observed in two thin walls fabricated by DED-LB under different conditions. The defect-free thin wall was produced at low power and scanning speed, while increasing energy input during the process led to intensive cracking. Two types of cracks that developed in the René 80-type superalloy were identified: solidification hot cracking and ductility-dip cracking (DDC), caused by σ-phase particles. It was found that transition from an equiaxed structure to a columnar one increased the susceptibility to crack propagation. Full article

Ultrasonic frequency pulse assisted TIG welding (UFP-TIG) experiments were conducted to join Inconel 690 alloy (IN690) by adding Inconel 718 alloy (IN718) as the filler. The effect of the filler on the microstructure, mechanical properties, and ductility dip cracking (DDC) susceptibility of IN690 joints were investigated. The results show that a variety of precipitates, including MC-type carbide and Laves phases, are formed in the weld zone (WZ), which are uniformly dispersed in the interdendritic region and grain boundaries (GBs). The increase in the thickness of the IN718 filler facilitates the precipitation and growth of Laves phases and MC carbides. However, the formation of Laves phases in the WZ exhibits a lower bonding force with the matrix and deteriorates the tensile strength of IN690 joints. Due to the moderate content of Laves phases in the WZ, the IN690 joint with 1.0 mm filler reaches the maximum tensile strength (627 MPa), which is about 96.5% of that of the base metal (BM). The joint with 1.0 mm filler also achieves the highest elongation (35.4%). In addition, the strain-to-fracture tests indicate that the total length of cracks in the joint with the IN718 filler decreases by 66.49% under a 3.8% strain. As a result, the addition of the IN718 filler significantly improves the mechanical properties and DDC resistance of IN690 joints. Full article

Hot dip galvanizing is among the cheapest methods for protecting ferrous alloys against corrosion. The success is due to both the low cost of the process and the high degree of protection in many corrosive environments, where the coatings serve as sacrificial protection. The purpose of this analysis is to study the mechanical characteristics of steel plates, that have been hot dip coated with five different zinc alloy molten bath for different time periods. The mechanical tests performed is a non-standardized four-point bending test considering three distinct bending angles. Results are examined in terms of both mechanical behaviour and coating phase damage. The development of intermetallic phases and their damage are both influenced by the chemical compositions of the zinc bath, demonstrating that fractures arise mostly at the substrate-coating interface. All the coatings showed the arising of micro-cracks except for the Aluminium, which demonstrated its ductility. In addition, Zn-Ti coatings showed the arising of a new compact phase rich in iron, characterized by a great hardness. More research is needed to explore the aluminium impact on the zinc bath, the lack of tiny fractures in the phase, and the lesser thickness compared to the other coatings tested. Full article

Water pipe surface deterioration is the result of continuous electrochemical reactions attacking the surface due to the interaction of the pipe surface with environments through the time function. The study presents corrosion characterization at the surface and sub-surface of damaged ductile iron pipe (DIP) and galvanized steel (GS) pipes which served for more than 40 and 20 years, respectively. The samples were obtained from Addis Ababa city water distribution system for the analysis of corrosion morphology patterns at different surface layers. Mountains 8.2 surface analysis software was utilized based on the ISO 25178-2 watershed segmentation method to investigate corrosion features of damaged pipe surface and to evaluate maximum pit depth, area, and volume in-situ condition. Based on the analysis maximum values of pit depth, area and volume were 380 $\mathsf{\mu }$ m, 4000 $\mathsf{\mu }$m², and 200,000 $\mathsf{\mu }$m³, respectively, after 25% loss of the original 8 mm thickness of DIP. Similarly, the pit depth of the GS pipe was 390 $\mathsf{\mu }\mathrm{m}$ whereas the maximum pit area and volume are 4000 $\mathsf{\mu }$m² and 16,000 $\mathsf{\mu }$m³, respectively. In addition, characterizations of new pipes were evaluated to study microstructures by using an optical microscope (OM), and a scanning electron microscope (SEM) was used to analyze corrosion morphologies. Based on the SEM analysis, cracks were observed at the sub-surface layer of the pipes. The results show that uniform corrosion attacked the external pipe surface whereas pitting corrosion damaged the subsurface of pipes. The output of this study will be utilized by water suppliers and industries to investigate corrosion phenomena at any damage stage. Full article

During the welding of 690 nickel-based alloy, solidification cracking (SFC) and ductility-dip cracking (DDC) easily forms, which has a negative effect on the quality of welded joints and service life. The present study examined the effects of welding heat input and cladding layers on the SFC and DDC, as well as their formation mechanism. The microstructure observation, elemental distribution, and Varestraint test were carried out. The results show that SFC and DDC were formed for the Inconel filler metal 52M, and SFC is more prone to form than DDC. The alloy elements such as Fe, Si, C, and P from base metal can expand the solidification temperature range, such that the SFC sensitivity increases. With the increase of welding heat input, the grain size of cladding metal is increased with a great SFC sensitivity. The increasing welding heat input also makes DDC possible due to the formation of a large angle grain boundary. Full article

This paper reviews state of the art laser powder bed fusion (L-PBF) manufacturing of γ′ nickel-based superalloys. L-PBF resembles welding; therefore, weld-cracking mechanisms, such as solidification, liquation, strain age, and ductility-dip cracking, may occur during L-PBF manufacturing. Spherical pores and lack-of-fusion voids are other defects that may occur in γ′-strengthened nickel-based superalloys manufactured with L-PBF. There is a correlation between defect formation and the process parameters used in the L-PBF process. Prerequisites for solidification cracking include nonequilibrium solidification due to segregating elements, the presence of liquid film between cells, a wide critical temperature range, and the presence of thermal or residual stress. These prerequisites are present in L-PBF processes. The phases found in L-PBF-manufactured γ′-strengthened superalloys closely resemble those of the equivalent cast materials, where γ, γ′, and γ/γ′ eutectic and carbides are typically present in the microstructure. Additionally, the sizes of the γ′ particles are small in as-built L-PBF materials because of the high cooling rate. Furthermore, the creep performance of L-PBF-manufactured materials is inferior to that of cast material because of the presence of defects and the small grain size in the L-PBF materials; however, some vertically built L-PBF materials have demonstrated creep properties that are close to those of cast materials. Full article

The role of impurity sulphur in the ductility trough of iron–nickel (Fe–Ni) alloys is investigated using hot tensile tests. A strong detrimental effect of some ppm levels of sulphur is demonstrated. In addition, it is shown that, in the ductility trough, material failure occurs through subcritical grain boundary crack propagation, involving dynamic embrittlement at the crack tip, due to the sulphur. Very high intergranular crack growth rates are observed. This is possible because plastic deformation accelerates the transport of sulphur to the crack tip, by several orders of magnitude, compared to normal bulk diffusion. The ductility is recovered at high strain rates, which correlates with a decrease in the sulphur concentration measured on the fracture surface. It is suggested that the main mechanism of sulphur transport is dragging by moving dislocations. Full article

Ni₅₈Cr₃₂Fe₁₀-based alloys, such as Alloy 690 and filler metal 52 (FM-52), suffer from ductility dip cracking (DDC). It is reported that decreasing the stacking fault energy (SFE) of these materials could improve the DDC resistance of Alloy 690. In this work, the effects of alloying elements on the stacking fault energies (SFEs) of Ni₅₈Cr₃₂Fe₁₀ alloys were studied using first-principle calculations. In our simulations, 2 at.% of Ni is replaced by alloy element X (X=Al, Co, Cu, Hf, Mn, Nb, Ta, Ti, V, and W). At a finite temperature, the SFEs were divided into the magnetic entropy (SFE^mag) and 0 K (SFE⁰) contributions. Potentially, the calculated results could be used in the design of high-performance Ni₅₈Cr₃₂Fe₁₀-based alloys or filler materials. Full article

In order to investigate the fatigue cracking resistance of engineered cementitious composites (ECC) used in in total life pavement, the semi-circular bending (SCB) test and improved three-point bending fatigue test (ITBF) were utilized in this study. The digital image correlation (DIC) method was also utilized to track the surface strain fields of specimens during the SCB test. X-ray computed tomography (CT) and digital image processing (DIP) technologies were applied to measure the internal-crack distribution of the ITBF specimen. The results of the SCB test showed that the fatigue cracking damage process of ECC can be divided into three stages and that the cracking stable propagating stages occupied the main part, which indicates that ECC has excellent ductility and toughness and could work very well with existing cracks. The ITBF results showed that the fatigue cracking resistance of ECC was better than epoxy asphalt concrete (EAC). In addition, the internal-crack distribution along the depth direction of the ITBF specimen could be presented well by the image pixel statistical (IPS) method based on CT scanning of image slices. It could be found that multiple cracks propagate simultaneously in ECC, instead of a single crack, under the OSBD pavement working condition. Full article

Overlay-welding of IN52M and IN52MSS onto CF8A stainless steel (SS) was conducted by a gas tungsten arc welding process in multiple passes. An electron probe micro-analyzer (EPMA) was applied to determine the distributions and chemical compositions of the grain boundary microconstituents, and the structures were identified by electron backscatter diffraction (EBSD). The hot cracking of the overlay welds was related to the microconstituents at the interdendritic boundaries. The formation of γ-intermetallic (Ni₃(Nb,Mo)) eutectics was responsible predominantly for the hot cracking of the 52M and 52MSS overlays. The greater Nb and Mo contents in the 52MSS overlay enhanced the formation of coarser microconstituents in greater amounts at the interdendritic boundaries. Thus, the hot cracking sensitivity of the 52MSS overlay was higher than that of the 52M overlay. Moreover, migrated grain boundaries were observed in the 52M and 52MSS overlays but did not induce ductility dip cracking (DDC) in this study. Full article

The K417G Ni-based superalloy is widely used in aeroengine turbine blades for its excellent properties. However, the turbine blade root with fir tree geometry experiences early failure frequently, because of the wear problems occurring in the working process. Laser forming repairing (LFR) is a promising technique to repair these damaged blades. Unfortunately, the laser formed Ni-based superalloys with high content of (Al + Ti) have a high cracking sensitivity. In this paper, the crack characterization of the laser forming repaired (LFRed) K417G—the microstructure, microhardness, and tribological properties of the coating before and after laser remelting—is presented. The results show that the microstructure of as-deposited K417G consists of γ phase, γ′ precipitated phase, γ + γ′ eutectic, and carbide. Cracking mechanisms including solidification cracking, liquation cracking, and ductility dip cracking are proposed based on the composition of K417G and processing characteristics to explain the cracking behavior of the K417G superalloy during LFR. After laser remelting, the microstructure of the coating was refined, and the microhardness and tribological properties was improved. Laser remelting can decrease the size of the cracks in the LFRed K417G, but not the number of cracks. Therefore, laser remelting can be applied as an effective method for strengthening coatings and as an auxiliary method for controlling cracking. Full article