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Keywords = direct mass enforcement

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17 pages, 2978 KiB  
Article
Long-Term Assessment of the Properties of Load Sensors Applied in Weigh-in-Motion Systems
by Janusz Gajda, Ryszard Sroka, Piotr Burnos and Mateusz Daniol
Sensors 2025, 25(8), 2421; https://doi.org/10.3390/s25082421 - 11 Apr 2025
Viewed by 485
Abstract
The noticeable growth of road transport means that the protection of road infrastructure is becoming a critical issue. The main factor leading to the excessive degradation of roads are overloaded vehicles. The effective elimination of such vehicles from road traffic is possible through [...] Read more.
The noticeable growth of road transport means that the protection of road infrastructure is becoming a critical issue. The main factor leading to the excessive degradation of roads are overloaded vehicles. The effective elimination of such vehicles from road traffic is possible through widespread usage of Weigh-In-Motion (WIM) systems for direct mass enforcement, thus eliminating the need for “manual” vehicle checks which are currently carried out by the appropriate services. WIM mass enforcement systems require strict metrological control, meaning that an initial verification, conducted at the moment when the system is installed, and subsequent periodic verifications are required. These operations aim to ensure that vehicle weighing error is consistently maintained within a permissible range of values. Fulfilment of this condition allows for the minimisation of the probability that a vehicle loaded within normative limits will be classified as overloaded. The long-term study of two WIM systems located on provincial road 975 in Wielka Wies, in southern Poland, equipped with load sensors made using different technologies (strain gauge sensors and quartz sensors) and in different weather conditions, has allowed us to formulate recommendations regarding the frequency with which subsequent verifications should be performed in order to ensure the reliability of the weighing results. This paper presents the results of these studies and conclusions formulated based on them; in this case, they showed a verification of the system can be performed every 8 months. The conclusions and recommendations that we have presented concern primarily those WIM stations which were the object of our study and caution should be exercised when generalising these to other cases. Its novelty results from several premises. For the first time, long-term studies of two WIM systems equipped with load sensors made with different technologies were carried out. Both systems were installed on the same surface, in the immediate vicinity of each other. They were installed on a standard road and were subjected to the constant impact of road traffic with identical parameters. Tests of both WIM systems were performed periodically, using the pre-weighed vehicles method, in different seasons, for a period of 15 months. During the tests, the same test vehicles drove through both WIM systems at the same speed. All of this resulted in the obtainment of a unique set of measurement data, the analysis of which allowed for the assessment and comparison of the proprieties of the load sensors made with both technologies. Full article
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21 pages, 4695 KiB  
Article
Architecture and Genesis of Submarine Migrating Channel–Levee Systems in the Pearl River Mouth Basin, Northern South China Sea
by Zenggui Kuang, Zijian Zhang, Jinfeng Ren and Wei Deng
J. Mar. Sci. Eng. 2025, 13(3), 505; https://doi.org/10.3390/jmse13030505 - 5 Mar 2025
Viewed by 762
Abstract
Seismic data reveal that the shelf edge of the Pearl River Mouth Basin in the northern South China Sea is characterized by slope channels that have consistently migrated in a north-easterly direction over millions of years. Previous research suggests that the channel migration [...] Read more.
Seismic data reveal that the shelf edge of the Pearl River Mouth Basin in the northern South China Sea is characterized by slope channels that have consistently migrated in a north-easterly direction over millions of years. Previous research suggests that the channel migration is driven by the interplay between along-slope bottom currents and downslope turbidity currents. Here, we propose an alternative interpretation, suggesting the migrating channels are actually a series of channel–levee systems and the migration is driven by their own evolution of erosion–deposition under the influence of the Coriolis force. A detailed interpretation of high-resolution seismic data reveals seven types of architectural elements, characteristic of channel–levee systems, which are erosional bases, outer levees, inner levees, channel-axis fills, marginal slumps, drapes, and lobes. An analysis of the sequence stratigraphy and stacking pattern of channels suggests that channel migration from the middle Miocene to the present is discontinuous with at least three regional discontinuities within the channel migration sequence marked by regional drapes. Down-dipping reflections along the margin of channels, previously interpreted as bottom-currents deposits, are here reinterpreted as mass-transport processes along steep channel walls. The migration is most prominent in the middle reach, where erosion and deposition coexist and dominate alternately in two different phases. During the long-term canyon-filling turbidity currents prevailing phase, deposition dominates, leading to the development of a prominent asymmetric right-hand (west) inner levee due to the Coriolis force. In contrast, during the canyon-flushing turbidity currents prevailing phase, erosion dominates and the preferred right-hand (west) inner levee enforces the flow to erode eastward, then drives the channel migrating eastward. The alternating effects of erosion and deposition ultimately result in unidirectional channel migration. Full article
(This article belongs to the Section Coastal Engineering)
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18 pages, 1501 KiB  
Article
Minimum Space When Transporting Pigs: Where Is the “Good” Law?
by Terry L. Whiting
Animals 2024, 14(18), 2732; https://doi.org/10.3390/ani14182732 - 21 Sep 2024
Viewed by 1864
Abstract
This paper focuses on the problem of numeracy when writing regulations, specifically how to describe a threshold for crowding of pigs during transport, considering transported pigs range in body mass from 5 to 500 kg. When scientific findings provide the basis for regulation [...] Read more.
This paper focuses on the problem of numeracy when writing regulations, specifically how to describe a threshold for crowding of pigs during transport, considering transported pigs range in body mass from 5 to 500 kg. When scientific findings provide the basis for regulation in the public interest, those findings must be communicated in a consistent way to regulators and policymaking bodies. Numeracy is the ability to understand, reason with, and apply appropriate numerical concepts to real-world questions. Scientific understanding is almost always based on rational understanding of numerical information, numeracy. The threshold of administrative offenses is often a numerical description. Commercial livestock transporters have an interest in loading livestock compartments to the maximum to achieve the largest payload allowed by axle weight laws, as is the case in all bulk commodity transport. Maximizing payload minimizes costs and environmental hazards of fuel exhaust and can benefit the public with lower pork prices, but has a serious animal welfare risk. Livestock production academics, veterinarians, and animal welfare activists have been working for decades to determine the level of livestock crowding in transport containers that would be appropriate for regulatory enforcement. The scientific discourse has been plagued by a lack of numerical standardization when describing results of trials and forming recommendations. Exceeding specific numerical thresholds is the core to implementing enforcement actions. This paper examines the communication and other barriers that have prevented emergence of a consensus on this question and provides a direction toward resolution. Further confirmation of effects of crowding livestock in transit is needed. This paper suggests that articulating an enforceable standard in pig transport is possible. In inspection for compliance, discovering the LP50 (lethal pressure—50) for slaughter-weight pigs is an initial global benchmark goal. The LP50 is the loading floor pressure in a commercial transport compartment, under field conditions, that would result in the death of at least one pig in the group 50% of the time. Full article
(This article belongs to the Special Issue Everlasting Battle against Animal Cruelty: Are We Making Progress?)
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25 pages, 9675 KiB  
Article
Strain Gauge Calibration for High Speed Weight-in-Motion Station
by Agnieszka Socha and Jacek Izydorczyk
Sensors 2024, 24(15), 4845; https://doi.org/10.3390/s24154845 - 25 Jul 2024
Cited by 4 | Viewed by 1630
Abstract
The development of systems for weighing vehicles in motion aims to introduce systems allowing automatic enforcement of regulations. HSWIM (high speed weight-in-motion) systems enable measurement of a mass of vehicles passing through a measurement station without disturbing the traffic flow. This article focuses [...] Read more.
The development of systems for weighing vehicles in motion aims to introduce systems allowing automatic enforcement of regulations. HSWIM (high speed weight-in-motion) systems enable measurement of a mass of vehicles passing through a measurement station without disturbing the traffic flow. This article focuses on the calibration of a weighing station for moving vehicles, where strain gauge sensors are used to measure pressures. A solution was proposed to replace the calibration coefficients with calibration functions. The analysis was performed for two methods of determining wheel loads: based on the maximum of the signal from strain gauge sensors and on a method using the field under the signal and the vehicle’s speed. Calibration functions were determined jointly for all test vehicles and separately for each of them. The use of a calibration function for a specific vehicle type made it possible to determine wheel pressure and gross weight with a level of accuracy that allowed the weigh-in-motion station to be classified as a direct enforcement system. The achieved improvement in the accuracy of weighing in motion did not require any interference with the measurement station. The proposed change in the method of calibration and, ultimately, determination of wheel loads required only a change in the algorithm for determining wheel loads. Full article
(This article belongs to the Special Issue Vehicle Sensing and Dynamic Control)
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11 pages, 4902 KiB  
Article
Rapid Separation and Detection of Drugs in Complex Biological Matrix Using TD-CDI Mass Spectrometer
by Wenyan Shi, Zi Ye, Qin Yang, Jianhua Zhou, Jiasi Wang and Xinming Huo
Biosensors 2024, 14(6), 271; https://doi.org/10.3390/bios14060271 - 25 May 2024
Cited by 2 | Viewed by 1736
Abstract
The drug detection technology plays a pivotal role in the domains of pharmaceutical regulation and law enforcement. In this study, we introduce a method that combines thermal desorption corona discharge ionization (TD-CDI) with mass spectrometry for efficient drug detection. The TD-CDI module, characterized [...] Read more.
The drug detection technology plays a pivotal role in the domains of pharmaceutical regulation and law enforcement. In this study, we introduce a method that combines thermal desorption corona discharge ionization (TD-CDI) with mass spectrometry for efficient drug detection. The TD-CDI module, characterized by its compact and simple design, enables the separation of analytes within seconds and real-time presentation of one or two analyte peaks on the mass spectrum most of the time, which reduces matrix interference and improves detection performance. Through experimental investigation, we studied the characteristics of TD-CDI for analyte separation and detection, even with the same mass number, and optimized the TD-CDI approach. TD-CDI-MS was employed for the rapid detection of drugs in various traditional medicine, food products, and human samples. Additionally, by utilizing TD-CDI for segmented hair direct analysis, it becomes possible to trace the drug usage cycle of individuals. This underscores the feasibility of the proposed analytical method within the realm of drug detection. Full article
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21 pages, 6499 KiB  
Article
Weigh-in-Motion Site for Type Approval of Vehicle Mass Enforcement Systems in Poland
by Janusz Gajda, Ryszard Sroka, Piotr Burnos and Mateusz Daniol
Sensors 2023, 23(22), 9290; https://doi.org/10.3390/s23229290 - 20 Nov 2023
Cited by 6 | Viewed by 2065
Abstract
The need to protect road infrastructure makes it necessary to direct the mass enforcement control of motor vehicles. Such control, in order to fulfil its role, must be continuous and universal. The only tool currently known to achieve these goals are weigh-in-motion (WIM) [...] Read more.
The need to protect road infrastructure makes it necessary to direct the mass enforcement control of motor vehicles. Such control, in order to fulfil its role, must be continuous and universal. The only tool currently known to achieve these goals are weigh-in-motion (WIM) systems. The implementation of mass enforcement WIM systems is possible only if the requirements for their metrological properties are formulated, followed by the implementation of administrative procedures for the type approval of WIM systems, rules for their metrological examination, and administrative regulations for their practical use. The AGH University of Krakow, in cooperation with the Central Office of Measures (Polish National Metrological Institute), has been conducting research in this direction for many years, and, now, as part of a research project financed by the Ministry of Education and Science. In this paper, we describe a unique WIM system located in the south of Poland and the results of over two years of our research. These studies are intended to lead to the formulation of requirements for metrological legalisation procedures for this type of system. Our efforts are focused on implementing WIM systems in Poland for direct mass enforcement. The tests carried out confirmed that the constructed system is fully functional. Its equipment with quartz and bending plate load sensors allows for the comparison of both technologies and the measurement of many parameters of the weighed vehicle and environmental parameters affecting weighing accuracy. The tests confirmed the stability of its metrological parameters. The GVW maximal measurement error does not exceed 5%, and the single axle load maximal measurement error does not exceed 12%. The sensors of the environmental parameters allow for the search for correlations between weighing accuracy and the intensity of these parameters. Full article
(This article belongs to the Section Electronic Sensors)
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16 pages, 2878 KiB  
Article
Optimal Transport and Seismic Rays
by Fabrizio Magrini and Malcolm Sambridge
Mathematics 2023, 11(22), 4686; https://doi.org/10.3390/math11224686 - 17 Nov 2023
Viewed by 1832
Abstract
We present a theoretical framework that links Fermat’s principle of least time to optimal transport theory via a cost function that enforces local transport. The proposed cost function captures the physical constraints inherent in wave propagation; when paired with specific mass distributions, it [...] Read more.
We present a theoretical framework that links Fermat’s principle of least time to optimal transport theory via a cost function that enforces local transport. The proposed cost function captures the physical constraints inherent in wave propagation; when paired with specific mass distributions, it yields shortest paths in the considered media through the optimal transport plans. In the discrete setting, our formulation results in physically significant optimal couplings, whose off-diagonal entries identify shortest paths in both directed and undirected graphs. For undirected graphs with positive edge weights, commonly used to parameterize seismic media, our method provides solutions to the Eikonal equation consistent with those from the Dijkstra algorithm. For directed negative-weight graphs, corresponding to transportation cost matrices with negative entries, our approach aligns with the Bellman–Ford algorithm but offers considerable computational advantages. We also highlight potential research directions. These include the use of sparse cost matrices to reduce the number of unknowns and constraints in the considered transportation problem, and solving specific classes of optimal transport problems through the Dijkstra algorithm to enhance computational efficiency. Full article
(This article belongs to the Special Issue Mathematical Modeling in Geophysics: Concepts and Practices)
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17 pages, 954 KiB  
Article
Estimating Travel Choice Probability of Link-Based Congestion Charging Scheme for Car Commuter Trips in Jakarta
by Masrono Yugihartiman, B. Budiono, Maman Setiawan and Achmad Kemal Hidayat
Sustainability 2023, 15(10), 8104; https://doi.org/10.3390/su15108104 - 16 May 2023
Cited by 4 | Viewed by 2110
Abstract
The likely effects on car commuters of enforcing congestion charging using the link-based corridor method include that they may shift to public transport, divert their route of travel, or decide not to travel to the related area. However, most recent research has focused [...] Read more.
The likely effects on car commuters of enforcing congestion charging using the link-based corridor method include that they may shift to public transport, divert their route of travel, or decide not to travel to the related area. However, most recent research has focused mainly on the choice of modes. This paper examined the travel choices of private car commuters resulting from the congestion charging scheme set to be implemented in Jakarta, Indonesia. The scheme is intended to replace the current odd-even strategy. It is imperative to study all possible mutually exclusive alternatives faced by car commuters. A web-based e-survey was used for data collection, employing the stated preference method. The discrete choice multinomial logit model was chosen to analyze the data. A total of 401 of the 2125 respondents to the e-survey questionnaire link, evenly distributed to all areas of Greater Jakarta, were sampled in this study. The sample respondents who traveled by car, passing through the eight designated corridors, were analyzed. NLOGIT6 software was used to analyze the parameter of attributes, the probability of alternatives chosen, and the marginal effects of congestion charging on such corridors, employing the multinomial logit model (MNLM). One surprising finding was that the load factor and taxi fares were not significant, indicating that the level of in-vehicle overcrowding is not a concern of respondents, and taxi services are not a substitute for car travel. Another surprising finding was that income variables and job type do not significantly influence travel behavior. In terms of the probability of commuters to continue to travel by car when link-based congestion charging is imposed, only around half of the car travelers were willing to pay the congestion levy and pass through congestion charging corridors. The probability of car travelers diverting onto alternative roads is high, i.e., around 16.82% to 22.88%, while the probability of car travelers shifting to mass transportation is 17.69%. When interpreting direct marginal effects, there is a change in the probability of all travelers choosing to use private cars through the congestion charging corridor of −0.0338, or a decrease of −3.38% for every IDR 1000 increase in the congestion charging levy rate, ceteris paribus. Full article
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19 pages, 1412 KiB  
Article
Optimal Circle-to-Ellipse Orbit Transfer for Sun-Facing E-Sail
by Alessandro A. Quarta, Giovanni Mengali, Marco Bassetto and Lorenzo Niccolai
Aerospace 2022, 9(11), 671; https://doi.org/10.3390/aerospace9110671 - 29 Oct 2022
Cited by 8 | Viewed by 2587
Abstract
The transfer between two coplanar Keplerian orbits of a spacecraft with a continuous-thrust propulsion system is a classical problem of astrodynamics, in which a numerical procedure is usually employed to find the transfer trajectory that optimizes (i.e., maximizes or minimizes) a given performance [...] Read more.
The transfer between two coplanar Keplerian orbits of a spacecraft with a continuous-thrust propulsion system is a classical problem of astrodynamics, in which a numerical procedure is usually employed to find the transfer trajectory that optimizes (i.e., maximizes or minimizes) a given performance index such as, for example, the delivered payload mass, the propellant mass, the total flight time, or a suitable combination of them. In the last decade, this class of problem has been thoroughly analyzed in the context of heliocentric mission scenarios of a spacecraft equipped with an Electric Solar Wind Sail as primary propulsion system. The aim of this paper is to further extend the existing related literature by analyzing the optimal transfer of an Electric Solar Wind Sail-based spacecraft with a Sun-facing attitude, a particular configuration in which the sail nominal plane is perpendicular to the Sun-spacecraft (i.e., radial) direction, so that the propulsion system is able to produce its maximum propulsive acceleration magnitude. The problem consists in transferring the spacecraft, which initially traces a heliocentric circular orbit, into an elliptic coplanar orbit of given eccentricity with a minimum-time trajectory. Using a classical indirect approach for trajectory optimization, the paper shows that a simplified version of the optimal control problem can be obtained by enforcing the typical transfer constraints. The numerical simulations show that the proposed approach is able to quantify the transfer performance in a parametric and general form, with a simple and efficient algorithm. Full article
(This article belongs to the Special Issue Advances in CubeSat Sails and Tethers)
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10 pages, 2910 KiB  
Article
Measuring Odor Transport of Narcotic Substances Using DART-MS
by Torki A. Zughaibi, Kenneth G. Furton, Howard K. Holness and Michelle R. Peace
Forensic Sci. 2022, 2(1), 262-271; https://doi.org/10.3390/forensicsci2010020 - 13 Mar 2022
Viewed by 3426
Abstract
The employment of canines in matters of law enforcement is due to their heightened olfactory senses, which helps in evaluating the presence of illicit substances. However, there have been instances where canines are signaling the presence of narcotics when they are not there. [...] Read more.
The employment of canines in matters of law enforcement is due to their heightened olfactory senses, which helps in evaluating the presence of illicit substances. However, there have been instances where canines are signaling the presence of narcotics when they are not there. This study aimed to analyze how active odorants transport from one area to another. Direct Analysis in Real-Time coupled to a high-resolution mass spectrometer (DART-MS) was used to analyze, in real-time, the volatile organic compounds (VOCs) of two narcotic substances: cocaine and methamphetamine. This study found that the transfer of VOCs from these narcotics does occur. Methyl benzoate was detected at 39.3 ± 3.2 s after exposure from 3 meters away, whereas benzaldehyde was detected at 43.3 ± 0.6 s from the same distance. The guidelines used for canine certification should be revisited to account for these results to lower or eliminate unconfirmed alerts by canines. Full article
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12 pages, 3346 KiB  
Article
Optimised Autocalibration Algorithm of Weigh-In-Motion Systems for Direct Mass Enforcement
by Piotr Burnos and Janusz Gajda
Sensors 2020, 20(11), 3049; https://doi.org/10.3390/s20113049 - 27 May 2020
Cited by 20 | Viewed by 2903
Abstract
Dynamic vehicle weighing systems, also known as Weigh-In-Motion (WIM), are sensitive to factors which interfere with the measurement, including weather and climate conditions. This is a result of the sensitivity of the axle load sensors used in the systems. As a result, a [...] Read more.
Dynamic vehicle weighing systems, also known as Weigh-In-Motion (WIM), are sensitive to factors which interfere with the measurement, including weather and climate conditions. This is a result of the sensitivity of the axle load sensors used in the systems. As a result, a significant change in the precision of weighing can be observed over short periods of time (even less than 1 h). This fact is a deterrent to the use of such systems for direct mass enforcement. In this article, we present a solution for this problem using an optimised autocalibration algorithm. We show the results of simulation studies which we conducted on the proposed algorithm. These were then verified experimentally at an in-road site. We demonstrated that autocalibration of the WIM system allows for effective limitation of the sensitivity of weighing results to interfering factors. This is, however, conditioned on a sufficiently high frequency of reference vehicles crossing the WIM site. The required frequency depends on the speed of change in the concentration of influencing factors. Full article
(This article belongs to the Section Electronic Sensors)
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13 pages, 1894 KiB  
Article
Chemical Fingerprinting of Wood Sampled along a Pith-to-Bark Gradient for Individual Comparison and Provenance Identification
by Victor Deklerck, Cady A. Lancaster, Joris Van Acker, Edgard O. Espinoza, Jan Van den Bulcke and Hans Beeckman
Forests 2020, 11(1), 107; https://doi.org/10.3390/f11010107 - 15 Jan 2020
Cited by 22 | Viewed by 4658
Abstract
Background and Objectives: The origin of traded timber is one of the main questions in the enforcement of regulations to combat the illegal timber trade. Substantial efforts are still needed to develop techniques that can determine the exact geographical provenance of timber and [...] Read more.
Background and Objectives: The origin of traded timber is one of the main questions in the enforcement of regulations to combat the illegal timber trade. Substantial efforts are still needed to develop techniques that can determine the exact geographical provenance of timber and this is vital to counteract the destructive effects of illegal logging, ranging from economical loss to habitat destruction. The potential of chemical fingerprints from pith-to-bark growth rings for individual comparison and geographical provenance determination is explored. Materials and Methods: A wood sliver was sampled per growth ring from four stem disks from four individuals of Pericopsis elata (Democratic Republic of the Congo) and from 14 stem disks from 14 individuals of Terminalia superba (Côte d’Ivoire and Democratic Republic of the Congo). Chemical fingerprints were obtained by analyzing these wood slivers with Direct Analysis in Real Time Time-Of-Flight Mass Spectrometry (DART TOFMS). Results: Individual distinction for both species was achieved but the accuracy was dependent on the dataset size and number of individuals included. As this is still experimental, we can only speak of individual comparison and not individual distinction at this point. The prediction accuracy for the country of origin increases with increasing sample number and a random sample can be placed in the correct country. When a complete disk is removed from the training dataset, its rings (samples) are correctly attributed to the country with an accuracy ranging from 43% to 100%. Relative abundances of ions appear to contribute more to differentiation compared to frequency differences. Conclusions: DART TOFMS shows potential for geographical provenancing but is still experimental for individual distinction; more research is needed to make this an established method. Sampling campaigns should focus on sampling tree cores from pith-to-bark, paving the way towards a chemical fingerprint database for species provenance. Full article
(This article belongs to the Special Issue Wood Science and Tropical Forest Ecology)
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13 pages, 4713 KiB  
Article
P2O5-Free Cerium Containing Glasses: Bioactivity and Cytocompatibility Evaluation
by Gigliola Lusvardi, Francesca Sgarbi Stabellini and Roberta Salvatori
Materials 2019, 12(19), 3267; https://doi.org/10.3390/ma12193267 - 8 Oct 2019
Cited by 14 | Viewed by 3560
Abstract
(1) Background: valuation of the bioactivity and cytocompatibility of P2O5-free and CeO2 doped glasses. (2) Methods: all glasses are based on the Kokubo (K) composition and prepared by a melting method. Doped glassed, K1.2, K3.6 and K5.3 contain [...] Read more.
(1) Background: valuation of the bioactivity and cytocompatibility of P2O5-free and CeO2 doped glasses. (2) Methods: all glasses are based on the Kokubo (K) composition and prepared by a melting method. Doped glassed, K1.2, K3.6 and K5.3 contain 1.2, 3.6, and 5.3 mol% of CeO2. Bioactivity and cytotoxicity tests were carried out in simulated body fluid (SBF) solution and murine osteocyte (MLO-Y4) cell lines, respectively. Leaching of ions concentration in SBF was determined by inductively coupled plasma mass spectrometry (ICP-MS) and optical emission spectrometry (ICP-OES). The surface of the glasses were characterized by scanning electron microscopy (SEM) and X-ray diffraction (XRD) techniques. (3) Results: P2O5-free cerium doped glasses are proactive according to European directives. Cerium increases durability and retards, but does not inhibit, (Ca10(PO4)6(OH)2, HA) formation at higher cerium amounts (K3.6 and K5.3); however, cell proliferation increases with the amount of cerium especially evident for K5.3. (4) Conclusions: These results enforce the use of P2O5-free cerium doped bioactive glasses as a new class of biomaterials. Full article
(This article belongs to the Special Issue Bioactive Glasses 2019)
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16 pages, 1762 KiB  
Article
Passive Sampling and Analysis of Naphthalene in Internal Combustion Engine Exhaust with Retracted SPME Device and GC-MS
by Nassiba Baimatova, Jacek A. Koziel and Bulat Kenessov
Atmosphere 2017, 8(7), 130; https://doi.org/10.3390/atmos8070130 - 22 Jul 2017
Cited by 10 | Viewed by 6033
Abstract
Exhaust gases from internal combustion engines are the main source of urban air pollution. Quantification of Polycyclic aromatic hydrocarbons (PAHs) in the exhaust gases is needed for emissions monitoring, enforcement, development, and testing of control technologies. The objective was to develop quantification of [...] Read more.
Exhaust gases from internal combustion engines are the main source of urban air pollution. Quantification of Polycyclic aromatic hydrocarbons (PAHs) in the exhaust gases is needed for emissions monitoring, enforcement, development, and testing of control technologies. The objective was to develop quantification of gaseous naphthalene in diesel engine exhaust based on diffusion-controlled extraction onto a retracted solid-phase microextraction (SPME) fiber coating and analysis on gas chromatography-mass spectrometry (GC-MS). Extraction of naphthalene with retracted fibers followed Fick’s law of diffusion. Extracted mass of naphthalene was proportional to Cg, t, Dg, T and inversely proportional to Z. Method detection limit (p = 0.95) was 11.5 ppb (0.06 mg·m−3) at t = 9 h, Z = 10 mm and T = 40 °C, respectively. It was found that the % mass extracted of naphthalene by SPME needle assembly depended on the type of fiber. Storage time at different temperatures did not affect analyte losses extracted by polydimethylsiloxane (PDMS) 100 µm fiber. The developed method was tested on exhaust gases from idling pickup truck and tractor, and compared side-by-side with a direct injection of sampled exhaust gas method. Time-weighted average (TWA) concentrations of naphthalene in exhaust gases from idling pickup truck and a tractor ranged from 0.08 to 0.3 mg·m−3 (15.3–53.7 ppb). Full article
(This article belongs to the Section Air Quality)
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26 pages, 13203 KiB  
Article
The Influence of Natura 2000 Sites on Land-Taking Processes at the Regional Level: An Empirical Analysis Concerning Sardinia (Italy)
by Sabrina Lai and Corrado Zoppi
Sustainability 2017, 9(2), 259; https://doi.org/10.3390/su9020259 - 13 Feb 2017
Cited by 15 | Viewed by 6162
Abstract
This article focuses on the role that the provisions of the Natura 2000 Network play in affecting land-taking processes by looking at the Italian region of Sardinia, where strict rules on land development have been enforced since 1993 through regional landscape plans and [...] Read more.
This article focuses on the role that the provisions of the Natura 2000 Network play in affecting land-taking processes by looking at the Italian region of Sardinia, where strict rules on land development have been enforced since 1993 through regional landscape plans and where an extensive Natura 2000 Network, covering nearly 19% of the regional land mass, was established in compliance with Directive 92/43/EEC on the conservation of natural habitats and of wild fauna and flora and Directive 2009/147/EC on the conservation of wild birds. The results and inferences of our study could be easily generalized to other European Union regions, provided that similar geographic datasets are available. By shedding some light on the relation between land take on the one hand, and nature conservation and landscape protection on the other, it is possible to enhance regional planning policies to prevent or hinder land-taking processes, and, by doing so, to help implementing the European Commission recommendation on no net land take by 2050 into the EU regional policies. Full article
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