Search Results (91)

The description of the Earth’s gravitational field, governed by the fundamental potential equation (the Laplace equation), is conventionally expressed using spherical harmonics, yet the Cartesian formulation, using a Taylor series representation, offers significant algebraic advantages. This paper proposes a novel Direct Cartesian Method for generating spherical basis functions and coefficients directly within the Cartesian coordinate system, utilising the partial derivatives of the inverse distance ($1/R$) function. The present study investigates the structural correspondence between the Cartesian form of spherical basis functions and the high-order partial derivatives of $1/R$. The study reveals that spherical basis functions can be categorised into four distinct groups based on the parity of the degree n and order m. It is demonstrated that each spherical basis function is equivalent to a weighted summation of the partial derivatives of the inverse distance ($1/R$) with respect to Cartesian coordinates. Specifically, the basis functions are combined with those derivatives that share the same order of Z-differentiation and possess matching parities in their orders of differentiation with respect to X and Y. In order to facilitate the practical calculation of these high-degree derivatives, a recursive numerical algorithm has been developed. The method generates the polynomial coefficients for the numerator of the $1/R$ derivatives. A pivotal innovation is the implementation of a step-wise normalization scheme within the recursive relations. The integration of the recursive ratios of global normalization factors (including full Schmidt normalization) into each step of the algorithm effectively neutralises factorial growth, rendering the process immune to numerical overflow. The validity and numerical stability of the proposed method are demonstrated through a detailed step-by-step derivation of a sectorial basis function ($n=8,m=2$). Full article

The FY-4B satellite, launched in June 2021 as China’s new-generation geostationary meteorological satellite, carries three identical High-Energy Particle Detectors (HEPDs) that enable multi-directional, wide-spectral measurements of energetic electrons. The three units are mounted in the zenith (−Z), flight (+X with a +Y offset of 30°), and anti-flight (−X with a −Y offset of 30°) directions, allowing simultaneous observations from nine look directions over a field of view close to 180° in the 0.4–4 MeV energy range (eight energy channels). This paper systematically presents the design principles of the HEPD electron detector, the ground calibration scheme, and preliminary in-orbit validation results. The probe employs a multi-layer silicon semiconductor telescope technique to achieve high-precision measurements of electron energy spectra, fluxes, and directional anisotropy in the 0.4–4 MeV range. Ground synchrotron calibration shows that the energy resolution is better than 16% for energies above 1 MeV, and the angular resolution is about 20°, providing a solid basis for subsequent quantitative inversion. During in-orbit operation, HEPD remains stable under both quiet conditions and strong geomagnetic storms: the measured electron fluxes, differential energy spectra, and directional distributions show good agreement with GOES-16 observations in the same energy bands during quiet periods and for the first time provide from geostationary orbit pitch-angle-resolved images of the minute-scale evolution of electron enhancement events. These results demonstrate that HEPD is capable of long-term monitoring of the geostationary radiation environment and can supply high-quality, continuous, and reliable data to support studies of radiation-belt particle dynamics, data assimilation in space weather models, and radiation warnings for satellites in orbit. Full article

A novel Z-scheme Dy₂TmSbO₇/BiHoO₃ heterostructure photocatalyst was synthesized with the ultrasound-assisted solvothermal method. The Dy₂TmSbO₇/BiHoO₃ heterojunction photocatalyst (DBHP) reflected wonderful separation efficiency of photogenerated electrons and photogenerated holes owing to the efficient direct Z-scheme heterojunction structure characteristic. The lattice parameter and the bandgap energy of the Dy₂TmSbO₇ were 10.52419 Å and 2.58 eV, simultaneously, the lattice parameter and the bandgap energy of the BiHoO₃ were 5.42365 Å and 2.25 eV, additionally, the bandgap energy of the DBHP was 2.32 eV. Above results indicated that DBHP, Dy₂TmSbO₇ or BiHoO₃ possessed an excellent ability for absorbing visible light energy, therefore, DBHP, Dy₂TmSbO₇ or BiHoO₃ owned superior photocatalytic activity for degrading the sulphamethoxypyridazine (SMP) under visible light irradiation. The removal rate of the SMP after visible light irradiation of 135 min with the DBHP was 99.47% for degrading the SMP during the photocatalytic degradation (PADA) process, correspondingly, the removal rate of the total organic carbon (TOC) concentration after visible light irradiation of 135 min with the DBHP was 98.02% for degrading the SMP during the PADA process. The removal rate of the SMP after visible light irradiation of 135 min with the DBHP was 1.15 times, 1.29 times or 2.60 times that with Dy₂TmSbO₇, BiHoO₃ or nitrogen-doped TiO₂ (N-T). Therefore, the DBHP displayed higher photocatalytic activity for degrading the SMP under visible light irradiation compared with Dy₂TmSbO₇, BiHoO₃ or N-T. Specifically, the mineralization rate for removing the TOC concentration during the PADA process of the SMP with the DBHP was 1.18 times, 1.32 times or 2.79 times that with Dy₂TmSbO₇, BiHoO₃ or N-T. In addition, the stability and reusability of the DBHP were systematically evaluated, confirming that the DBHP owned potential applicability for degrading the antibiotic pollutant, which derived from the practical industrial wastewater. Trapping radicals experiments and the electron paramagnetic resonance measurement experiments were conducted for identifying the reactive radicals, such as the hydroxyl radicals (•OH), the superoxide anions (•O₂⁻) and the photogenerated holes (h⁺), which were generated with the DBHP for degrading the SMP during the PADA process under visible light irradiation, as a result, the •O₂⁻ possessed the maximal oxidative capability compared with the •OH or the h⁺. Above results indicated the degradation mechanism and the degradation pathways which were related to the SMP. In conclusion, this study makes a significant contribution for the development of the efficient Z-scheme heterostructure photocatalysts and provides a key opinion to the development of the sustainable remediation method with the view of mitigating the antibiotic pollution. Full article

Photocatalytic technology offers significant potential for pollutant remediation through efficient, cost-effective mineralization but faces inherent limitations, including catalyst agglomeration and rapid charge recombination. To address these challenges, we developed activated carbon-modified porous graphitic carbon nitride (APCN) synthesized through the co-polycondensation of dicyandiamide with NH₄Cl and fir-wood-derived activated carbon (AC). The incorporated AC effectively prevented the agglomeration of carbon nitride frameworks, thereby enhancing the specific surface area (S_BET) of APCN. This matrix was subsequently composited with hydrothermally prepared (1T/2H) mixed-phase MoS₂ through ultrasonication, forming a MoS₂/APCN heterostructure. Characterizations including Scanning electron microscopy (SEM), Transmission electron microscopy (TEM), and N₂ adsorption–desorption isotherms (BET) confirmed that MoS₂ was successfully loaded onto APCN via an ultrasonic synthesis method. The composite exhibited outstanding photocatalytic activity, degrading 95.5% RhB in 40 min (pH = 7) and 97.4% in 25 min (pH = 3.5), with 87.3% efficiency retention after four cycles (pH = 7). Crucially, AC enhanced visible-light absorption and functioned as an electron-mediating component. Photoelectrochemical analyses and radical-trapping experiments confirmed a direct Z-scheme charge transfer mechanism, wherein conductive AC accelerates electron transport and suppresses carrier recombination. This study establishes both an efficient RhB degradation photocatalyst and a sustainable strategy for valorizing agricultural waste in advanced material design. Full article

Seismic response analysis of underground structures at coral sand sites is a critical component in ensuring the structural safety of island reef engineering. Current experimental studies in this field have primarily focused on unidirectional seismic excitation. To investigate the seismic response differences under multidirectional seismic loading, this study designed a series of shaking table tests under unidirectional, bidirectional, and triaxial loading schemes. The seismic responses of underground structures and coral sand foundations were compared under different loading conditions, including boundary effects, ground and structural accelerations, Fourier spectra, and structural strains. The results indicate that the soil–structure system exhibits responses in the non-excitation directions during the shaking table tests. Compared to the excitation direction, boundary effects are more pronounced in the non-excitation directions, with vibrations in these directions primarily concentrated in the high-frequency range (16–20 Hz). The ground acceleration amplification factors in the X-, Y-, and Z-directions in different loading directions are 0.9–1.3, 1.4–2, and 3.4–3.7, respectively, showing significant differences. Under triaxial loading, the peak strain in the underground structure is significantly higher than that under unidirectional loading. Full article

Addressing global energy and environmental issues calls for the development of effective photocatalysts capable of enabling solar-driven water splitting, a key route toward sustainable hydrogen generation. In this work, we conducted a detailed density functional theory (DFT) study on three bilayer van der Waals (vdW) heterojunctions, Ga₂SSe/GaP, Ga₂SSe/PtSSe, and Ga₂SSe/SnSSe, each explored in four distinct stacking configurations, with Ga₂SSe serving as the base monolayer. We assessed their structural stability, electronic properties, and optical responses to determine their suitability for photocatalytic water splitting. The analysis showed that Ga₂SSe/GaP and Ga₂SSe/SnSSe exhibit type-II band alignment, while Ga₂SSe/PtSSe displays a type-I alignment. Electrostatic potential profiles and Bader charge calculations identified SeGa₂S/SSnSe and SeGa₂S/SeSnS as direct Z-scheme systems, offering efficient charge carrier separation and robust redox potential. For effective water splitting, the band edges must straddle the water redox potentials. Our results indicate that configurations A and B in Ga₂SSe/GaP, along with C and D in Ga₂SSe/SnSSe, fulfill this requirement. These four configurations also exhibit strong absorption in both the visible and ultraviolet spectral ranges. Notably, configurations C and D of Ga₂SSe/SnSSe achieve high solar-to-hydrogen (STH) efficiencies, reaching 38.44% and 21.75%, respectively. Overall, our findings suggest that these direct Z-scheme heterostructures are promising candidates for water splitting photocatalysis. Full article

Titanium alloys (Ti-6Al-4V) are widely used in the aerospace field. However, as a typical difficult-to-machine material, titanium alloys have a low thermal conductivity, a high chemical activity, and a significant adiabatic shear effect. In conventional milling (CM), the temperature in the cutting zone rises sharply, leading to tool adhesion, rapid wear, and damage to the workpiece surface. This article systematically investigated the influence of process parameters on the surface roughness, cutting force, and cutting temperature in the ultrasonic-vibration-assisted milling (UAM) process of titanium alloys, based on which multi-objective optimization process of the milling process parameters was conducted, by utilizing the grey relational analysis method. An orthogonal experiment with four factors and four levels was conducted. The effects of various process parameters on the surface roughness, cutting force, and cutting temperature were systematically analyzed for both UAM and CM. The grey relational analysis method was employed to transform the optimization problem of multiple process target parameters into a single-objective grey relational degree optimization problem. The optimized parameter combination was as follows: an ultrasonic amplitude of 6 μm, a spindle speed of 6000 rpm, a cutting depth of 0.20 mm, and a feed rate of 200 mm/min. The experimental results indicated that the surface roughness Sa was 0.268 μm, the cutting temperature was 255.39 °C, the cutting force in the X direction (FX) was 5.2 N, the cutting force in the Y direction (FY) was 7.9 N, and the cutting force in the Z direction (FZ) was 6.4 N. The optimization scheme significantly improved the machining quality and reduced both the cutting forces and the cutting temperature. Full article

In this study, a Z-scheme Ho₂InSbO₇/Ag₃PO₄ (HAO) heterojunction photocatalyst was successfully fabricated for the first time by ultrasound-assisted solvothermal method. The structural features, compositional components and morphological characteristics of the synthesized materials were thoroughly characterized by a series of techniques, including X-ray diffraction, Fourier transform infrared spectroscopy, Raman spectrum, X-ray photoelectron spectroscopy, transmission electron microscopy, scanning electron microscopy and energy-dispersive X-ray spectroscopy. A comprehensive array of analytical techniques, including ultraviolet-visible diffuse reflectance absorption spectra, photoluminescence spectroscopy, time-resolved photoluminescence spectroscopy, photocurrent testing, electrochemical impedance spectroscopy, electron paramagnetic resonance, and ultraviolet photoelectron spectroscopy, was employed to systematically investigate the optical, chemical, and photoelectronic properties of the materials. Using oxytetracycline (OTC), a representative tetracycline antibiotic, as the target substrate, the photocatalytic activity of the HAO composite was assessed under visible light irradiation. Comparative analyses demonstrated that the photocatalytic degradation capability of the HAO composite surpassed those of its individual components. Notably, during the degradation process, the application of the HAO composite resulted in an impressive removal efficiency of 99.89% for OTC within a span of 95 min, along with a total organic carbon mineralization rate of 98.35%. This outstanding photocatalytic performance could be ascribed to the efficient Z-scheme electron-hole separation system occurring between Ho₂InSbO₇ and Ag₃PO₄. Moreover, the adaptability and stability of the HAO heterojunction were thoroughly validated. Through experiments involving the capture of reactive species and electron paramagnetic resonance analysis, the active species generated by HAO were identified as hydroxyl radicals (•OH), superoxide anions (•O₂⁻), and holes (h⁺). This identification provides valuable insights into the mechanisms and pathways associated with the photodegradation of OTC. In conclusion, this research not only elucidates the potential of HAO as an efficient Z-scheme heterojunction photocatalyst but also marks a significant contribution to the advancement of sustainable remediation strategies for OTC contamination. Full article

The photocatalytic performance of heterojunctions is often restricted by inferior contact interface and low charge transfer efficiency. In this work, Ti₃C₂O MXene was crafted with AgI/MoS₂ to produce a Z-scheme heterojunction (AgI/MoS₂/Ti₃C₂O). Interfacial electric fields and chemical bonds were proven to exist in the heterojunction. The interfacial electric fields supplied a powerful driving force, and the interfacial Ti-O-Mo bonds served as an atomic-level channel for synergistically expediting the vectorial transfer of photogenerated carriers. As a result, AgI/MoS₂/Ti₃C₂O exhibited significantly improved photocatalytic activity, demonstrating a high H₂O₂ production rate of 700 μmol·g⁻¹·h⁻¹ and a rapid degradation of organic pollutants. Full article

The combination of additive manufacturing technology and biomimetic structures plays an increasingly important role in the lightweight design of automotive parts. This work provides a lightweight design and manufacturing method for the spider web biomimetic structure of car roof handrails. Firstly, in order to obtain a more reasonable combination of spider web structure and roof handrail, three new schemes are designed, namely spider web biomimetic roof handrail distributed along the x, y and z axes. Further simulation and comparison of the three new solutions with traditional handrails are performed to determine the final solution. The simulation results show that under the influence of different loads, the design along the z-axis direction is superior to the design in other directions, and it reduces weight by 32.03% compared to the traditional handrail theoretically while meeting the mechanical performance requirements, demonstrating a good lightweight effect. In addition, multiple material comparative tests are conducted by conducting tensile tests on car roof handrails made of different materials. The results indicate that the handrail made of PA6-CF has excellent overall performance, meeting safety standards and allowing for significant elastic deformation, optimizing the user experience. Full article

This study introduces a Self-Attention (SA) Generative Adversarial Network (GAN) framework that applies artificial intelligence techniques to microwave sensing for electromagnetic imaging. The approach involves illuminating anisotropic objects using Transverse Magnetic (TM) and Transverse Electric (TE) electromagnetic waves, while sensing antennas collecting the scattered field data. To simplify the training process, a Back Propagation Scheme (BPS) is employed initially to calculate the preliminary permittivity distribution, which is then fed into the GAN with SA for image reconstruction. The proposed GAN with SA offers superior performance and higher resolution compared with GAN, along with enhanced generalization capability. The methodology consists of two main steps. First, TM waves are used to estimate the initial permittivity distribution along the z-direction using BPS. Second, TE waves estimate the x- and y-direction permittivity distribution. The estimated permittivity values are used as inputs to train the GAN with SA. In our study, we add 5% and 20% noise to compare the performance of the GAN with and without SA. Numerical results indicate that the GAN with SA demonstrates higher efficiency and resolution, as well as better generalization capability. Our innovation lies in the successful reconstruction of various uniaxial objects using a generator integrated with a self-attention mechanism, achieving reduced computational time and real-time imaging. Full article

Two-dimensional direct Z-scheme photocatalysts have emerged as highly promising photocatalysts for solar-driven water splitting owing to their effective separation of photogenerated carriers and strong redox abilities. This study focuses on the theoretical prediction of promising Z-scheme photocatalysts for solar-driven water splitting based on M₂X/BiOY (M = Ag, Au; X = S, Se; Y = Cl, Br, I) heterojunctions using first-principles calculations. All M₂X/BiOY heterojunctions possess staggered band alignments, Z-scheme carrier migration, and suitable band edges for overall water splitting. Optical absorption spectra indicate that these heterojunctions exhibit significantly extended solar absorption in the visible and near-infrared regions. Moreover, the interfacial built-in electric fields of (0.46–0.72 V/Å) point from M₂X to BiOY, promote photogenerated carrier separation, and enhance redox overpotentials, thereby improving photocatalytic performance. These results suggest that M₂X/BiOY heterojunctions are promising Z-scheme photocatalysts for solar-driven water splitting and are expected to be experimentally prepared and realized in the near future. Full article

Food spoilage caused by microbial contamination remains a global challenge, driving demand for sustainable antibacterial packaging. Conventional photocatalytic materials suffer from limited spectral response, rapid charge recombination, and insufficient reactive oxygen species (ROS) generation under visible light. Here, a Z-scheme heterojunction was constructed by coupling zeolitic imidazolate framework-8 (ZIF-8) with Ag₃PO₄, achieving dual-spectral absorption and spatial charge separation. The directional electron transfer from Ag₃PO₄’s conduction band to ZIF-8 effectively suppresses electron-hole recombination, prolonging carrier lifetimes and amplifying ROS production (·O₂⁻/·OH). Synergy with Ag⁺ release further enhances bactericidal efficacy. Incorporated into a cellulose acetate matrix (CAM), the ZIF-8/Ag₃PO₄/CAM film demonstrates 99.06% antibacterial efficiency against meat surface microbiota under simulated sunlight, alongside high transparency. This study proposes a Z-scheme heterojunction strategy to maximize ROS generation efficiency and demonstrates a scalable fabrication approach for active food packaging materials, effectively targeting microbial contamination control and shelf-life prolongation. Full article

The energy consumption of rotary-wing unmanned aerial vehicles has become an important factor restricting their long-term application. This article focuses on decoupling the motion channel and reducing control energy consumption, and proposes a decoupling controller based on dynamic inversion for the complete dynamics of quadcopter unmanned aerial vehicles. Firstly, we design a direct closed-loop feedback controller for the z-channel to exhibit second-order linear dynamic characteristics with adjustable parameters. Then, the specific functions of pitch angle and yaw angle are combined as virtual control variables for the comprehensive decoupling design of the x-direction and y-direction, so that the x-channel and y-channel also exhibit independent parameter-adjustable second-order linear dynamic characteristics. Next, by solving the actual control variables, a fast convergence system is dynamically formed by the deviation between the virtual control variables and their actual values, ensuring that the specific function combination of pitch angle and yaw angle quickly converges to the expected value. Finally, the effectiveness and low energy consumption control characteristics of the decoupling control scheme were demonstrated through simulation comparison with other control methods (such as classical PID) in terms of energy consumption. Full article

Direct Z-scheme heterojunctions are known for their unique carrier mobility mechanism, which significantly improves photocatalytic water splitting efficiency. In this study, we use first-principles simulations to determine the stability, electrical, and photocatalytic properties of a SnC/SnS₂ heterojunction. Analyses of the projected energy band and state density demonstrate that the SnC/SnS₂ heterojunction exhibits an indirect band gap of 0.80 eV and a type-II band alignment. Analysis of its work function shows that the SnC/SnS₂ heterojunction has a built-in electric field pointing from the SnC monolayer to the SnS₂ monolayer. The band edge position and the differential charge density indicate that the SnC/SnS₂ heterostructure exhibits a Z-scheme photocatalytic mechanism. Furthermore, the SnC/SnS₂ heterojunction exhibits excellent visible-light absorption and high solar-to-hydrogen efficiency of 32.8%. It is found that the band gap and light absorption of the heterojunction can be effectively tuned by biaxial strain. These results demonstrate that the fabricated SnC/SnS₂ heterojunction has significant photocatalysis potential. Full article