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Keywords = diffractive-refractive hybrid optics

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18 pages, 5239 KB  
Article
Hybrid Reflection/Transmission Diffraction Grating Solar Sail
by Ryan M. Crum, Prateek R. Srivastava, Qing X. Wang, Tasso R. M. Sales and Grover A. Swartzlander
Photonics 2025, 12(10), 972; https://doi.org/10.3390/photonics12100972 - 30 Sep 2025
Cited by 3 | Viewed by 1183
Abstract
Diffractive sail components may be used in part or whole for in-space propulsion and attitude control. A sun-facing hybrid diffractive solar sail having reflective front facets and transmissive side facets is described. This hybrid design seeks to minimize the undesirable scattering from side [...] Read more.
Diffractive sail components may be used in part or whole for in-space propulsion and attitude control. A sun-facing hybrid diffractive solar sail having reflective front facets and transmissive side facets is described. This hybrid design seeks to minimize the undesirable scattering from side facets. Predictions of radiation pressure are compared for analytical geometrical optics and numerical finite difference time domain approaches. Our calculations across a spectral irradiance band from 0.5 to 3 μm suggest the transverse force in a sun facing configuration reaches 48% when the refractive index of the sail material is 1.5. Diffraction measurements at a representative optical wavelength of 633 nm support our predictions. Full article
(This article belongs to the Special Issue Diffractive Optics and Its Emerging Applications)
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9 pages, 1337 KB  
Communication
Photonic–Surface Plasmon Coupling Mode: Experimental Study with a Silver Thin-Film Coating on MPCC
by Pengfei Li, Zhanwu Xie, Haitao Yan and Shitong Zhong
Photonics 2025, 12(8), 811; https://doi.org/10.3390/photonics12080811 - 13 Aug 2025
Cited by 1 | Viewed by 1703
Abstract
In this paper, a silver thin film coating on a monolayer polystyrene colloidal crystal (MPCC) hybrid structure was fabricated, and a photonic–surface plasmon coupling mode was established and experimentally researched. The silver thin film was sputtered onto the MPCC to form Ag-MPCC. The [...] Read more.
In this paper, a silver thin film coating on a monolayer polystyrene colloidal crystal (MPCC) hybrid structure was fabricated, and a photonic–surface plasmon coupling mode was established and experimentally researched. The silver thin film was sputtered onto the MPCC to form Ag-MPCC. The silver film effectively excites surface plasmon polariton (SPP) modes upon the incidence of light, and the MPCC has an intrinsic mode. These two modes couple and result in the extraordinary optical transmission (EOT) phenomenon in the transmission spectrum. Reflection suppression arising from this photon coupling effect was discovered in the reflection spectrum. We etched the single-layer colloidal particles to change the period of the colloidal crystal, thereby forming the MPCC metal hybrid structure with different lattices. We discussed and analyzed the results through experiments. The EOT can be controlled by the incident angle, lattice periodicity, and refractive index distribution of the Ag-MPCC, and the diffraction behavior is determined using the lattice structure and refractive index of the MPCC. The coupling effect of the two models leads to wavelength shifts and intensity variations in the spectral eigenvalues. Reflection suppression is achieved when the reflectivity at a specific wavelength is close to 0.1. Full article
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35 pages, 3588 KB  
Article
Metasurface-Refractive Hybrid Lens Modeling with Vector Field Physical Optics
by Ko-Han Shih and C. Kyle Renshaw
Photonics 2025, 12(4), 401; https://doi.org/10.3390/photonics12040401 - 21 Apr 2025
Cited by 1 | Viewed by 3293
Abstract
Metasurfaces (MSs) have emerged as a promising technology for optical system design. When combined with traditional refractive optics, MS-refractive hybrid lenses can enhance imaging performance, reduce optical aberrations, and introduce new functionalities such as polarization control. However, modeling these hybrid lenses requires advanced [...] Read more.
Metasurfaces (MSs) have emerged as a promising technology for optical system design. When combined with traditional refractive optics, MS-refractive hybrid lenses can enhance imaging performance, reduce optical aberrations, and introduce new functionalities such as polarization control. However, modeling these hybrid lenses requires advanced simulation techniques that usually go beyond conventional raytracing tools. This work presents a physical optics framework for modeling MS-refractive hybrid lenses. We introduce a ray-wave hybrid method that integrates multiple propagation techniques to account for vector wave propagation through various optical elements. At the center of the proposed framework is the Gaussian decomposition method for modeling beam propagation through refractive optics. Ray-path diffraction is automatically considered in this method, and complex input wavefront can be modeled as well. Several techniques are integrated to ensure accuracy in decomposing an incoming vector wave into Gaussian beamlets, such as adaptive consideration of local wavefront principal curvatures and best-fit beam width estimation from the local covariance matrix. To demonstrate the effectiveness of our method, we apply it to several hybrid lens designs, including polarization-sensitive MSs and aberration-correcting MSs integrated into complex optical systems. Full article
(This article belongs to the Special Issue Advancements in Optical Metamaterials)
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24 pages, 2793 KB  
Article
Dispersive Sweatt Model for Broadband Lens Design with Metasurfaces
by Weiyu Chen, Ko-Han Shih and C. Kyle Renshaw
Photonics 2025, 12(1), 43; https://doi.org/10.3390/photonics12010043 - 6 Jan 2025
Cited by 2 | Viewed by 2466
Abstract
The Sweatt model has been extensively used to design optical systems containing diffractive optical elements (DOEs) because it captures the dispersive characteristics of DOEs. We introduce a new dispersive Sweatt model (DSM) that can describe meta-atom (MA) dispersion, which has material and geometric [...] Read more.
The Sweatt model has been extensively used to design optical systems containing diffractive optical elements (DOEs) because it captures the dispersive characteristics of DOEs. We introduce a new dispersive Sweatt model (DSM) that can describe meta-atom (MA) dispersion, which has material and geometric contributions in addition to diffraction. It uses a wavelength-dependent scalar coefficient to modify the diffractive dispersion and describe the dispersion of a given MA basis. This provides a robust framework to design systems containing metasurface (MS) elements while including their unique dispersive properties in the design optimization. Importantly, the DSM is based on ray optics and enables the design of MS-containing systems using conventional optical design software such as Zemax and Code V. We use the DSM to demonstrate the design of a hybrid refractive/MS achromatic doublet for the midwave infrared (MWIR) band. The design example includes multiple wavelengths and field angles during optimization and demonstrates excellent agreement between the DSM and real hybrid lens performance modeled using wave optics. We discuss the limits of the DSM and present a simple model to predict performance limits due to phase mismatch at Fresnel zone boundaries. Full article
(This article belongs to the Special Issue Advancements in Optical Metamaterials)
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12 pages, 4420 KB  
Article
Hybrid Space Calibrated 3D Network of Diffractive Hyperspectral Optical Imaging Sensor
by Hao Fan, Chenxi Li, Bo Gao, Huangrong Xu, Yuwei Chen, Xuming Zhang, Xu Li and Weixing Yu
Sensors 2024, 24(21), 6903; https://doi.org/10.3390/s24216903 - 28 Oct 2024
Cited by 2 | Viewed by 1614
Abstract
Diffractive multispectral optical imaging plays an essential role in optical sensing, which typically suffers from the image blurring problem caused by the spatially variant point spread function. Here, we propose a novel high-quality and efficient hybrid space calibrated 3D network “HSC3D” for spatially [...] Read more.
Diffractive multispectral optical imaging plays an essential role in optical sensing, which typically suffers from the image blurring problem caused by the spatially variant point spread function. Here, we propose a novel high-quality and efficient hybrid space calibrated 3D network “HSC3D” for spatially variant diffractive multispectral imaging that utilizes the 3D U-Net structure combined with space calibration modules of magnification and rotation effects to achieve high-accuracy eight-channel multispectral restoration. The algorithm combines the advantages of the space calibrated module and U-Net architecture with 3D convolutional layers to improve the image quality of diffractive multispectral imaging without the requirements of complex equipment modifications and large amounts of data. A diffractive multispectral imaging system is established by designing and manufacturing one diffractive lens and four refractive lenses, whose monochromatic aberration is carefully corrected to improve imaging quality. The mean peak signal-to-noise ratio and mean structural similarity index of the reconstructed multispectral images are improved by 3.33 dB and 0.08, respectively, presenting obviously improved image quality compared with a typical Unrolled Network algorithm. The new algorithm with high space calibrated ability and imaging quality has great application potential in diffraction lens spectroscopy and paves a new method for complex practical diffractive multispectral image sensing. Full article
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10 pages, 3569 KB  
Communication
Hybrid Refractive and Diffractive Testing Method for Free-Form Convex Mirror in High-Resolution Remote-Sensing Cameras
by Nan Deng, Yanjie Li, He Ma and Feifei Zhang
Remote Sens. 2024, 16(20), 3865; https://doi.org/10.3390/rs16203865 - 17 Oct 2024
Cited by 1 | Viewed by 1915
Abstract
The development of high-resolution and large field of view remote-sensing cameras is inextricably linked to the application of free-form mirrors. The free-form mirror offers higher design of freedom and is more effective at correcting aberrations in optical systems. The surface shape error of [...] Read more.
The development of high-resolution and large field of view remote-sensing cameras is inextricably linked to the application of free-form mirrors. The free-form mirror offers higher design of freedom and is more effective at correcting aberrations in optical systems. The surface shape error of a free-form mirror directly affects the imaging quality of remote-sensing cameras. Consequently, a high-precision free-form mirror detection method is of paramount importance. For the convex free-form surface mirror with a large aperture, a hybrid refractive and diffractive testing method combining computer-generated holography (CGH) and spherical mirrors for high-precision null test is proposed in this paper. When comparing the effect of error and the detection sensitivity of different designs, the results showed that the influence of the system error is reduced by about 42% and the sensitivity is increased by more than 2.6 times. The proposed method can achieve higher testing accuracy and represents an effective and feasible approach for the surface shape detection method. Full article
(This article belongs to the Special Issue Optical Remote Sensing Payloads, from Design to Flight Test)
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11 pages, 1687 KB  
Article
Intra-Observer and Inter-Observer Variability of Intraocular Lens Measurements Using an Interferometry Metrology Device
by Benjamin Stern, Alain Saad, Roxane Flamant, Luc Joannes and Damien Gatinel
Diagnostics 2024, 14(2), 216; https://doi.org/10.3390/diagnostics14020216 - 19 Jan 2024
Cited by 3 | Viewed by 2700
Abstract
The NIMO TEMPO (Lambda-X, Nivelles, Belgium) is a novel, user-friendly and compact device designed for in vitro optical analysis of refractive and diffractive intraocular lenses (IOLs). This device analyzes the IOL wavefront and generates a synthetic eye model for numerical computation. The objective [...] Read more.
The NIMO TEMPO (Lambda-X, Nivelles, Belgium) is a novel, user-friendly and compact device designed for in vitro optical analysis of refractive and diffractive intraocular lenses (IOLs). This device analyzes the IOL wavefront and generates a synthetic eye model for numerical computation. The objective of this study was to evaluate the precision of this innovative device. Intra- and inter-observer variability were calculated using a two-way analysis of variance (ANOVA) after conducting ten measurements of eight different IOL models, with each measurement being repeated by three distinct operators (resulting in a total of 30 measurements for each IOL). The device demonstrated satisfactory intra- and inter-observer variability in evaluating IOL power and modulation transfer function (MTF) profiles, with values of 0.066 and 0.078 diopters for IOL power and 0.018 and 0.019 for MTF measurements, respectively. Furthermore, this hybrid optical and numerical in vitro IOL wavefront analyzer appears to have several advantages over conventional optical bench devices. It reduces the need for operator manipulation, and allows for numerical modeling of various optical environments, including cornea models and apertures. In conclusion, this novel metrology device designed for refractive and diffractive IOLs appears to provide a satisfactory precision, making it a promising tool in the field of IOL metrology. Full article
(This article belongs to the Section Biomedical Optics)
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14 pages, 3836 KB  
Article
Injection Molding of Encapsulated Diffractive Optical Elements
by Stefan Wagner, Kevin Treptow, Sascha Weser, Marc Drexler, Serhat Sahakalkan, Wolfgang Eberhardt, Thomas Guenther, Christof Pruss, Alois Herkommer and André Zimmermann
Micromachines 2023, 14(6), 1223; https://doi.org/10.3390/mi14061223 - 9 Jun 2023
Cited by 8 | Viewed by 3383
Abstract
Microstructuring techniques, such as laser direct writing, enable the integration of microstructures into conventional polymer lens systems and may be used to generate advanced functionality. Hybrid polymer lenses combining multiple functions such as diffraction and refraction in a single component become possible. In [...] Read more.
Microstructuring techniques, such as laser direct writing, enable the integration of microstructures into conventional polymer lens systems and may be used to generate advanced functionality. Hybrid polymer lenses combining multiple functions such as diffraction and refraction in a single component become possible. In this paper, a process chain to enable encapsulated and aligned optical systems with advanced functionality in a cost-efficient way is presented. Within a surface diameter of 30 mm, diffractive optical microstructures are integrated in an optical system based on two conventional polymer lenses. To ensure precise alignment between the lens surfaces and the microstructure, resist-coated ultra-precision-turned brass substrates are structured via laser direct writing, and the resulting master structures with a height of less than 0.002 mm are replicated into metallic nickel plates via electroforming. The functionality of the lens system is demonstrated through the production of a zero refractive element. This approach provides a cost-efficient and highly accurate method for producing complicated optical systems with integrated alignment and advanced functionality. Full article
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20 pages, 2046 KB  
Article
Extreme Refractive-, Diffractive- and Hybrid-Hyperchromats: Minimizing the Equivalent Abbe Number of a Two-Lens System
by Lukas Werner, Erik Förster, Matthias Kraus, Hartmut Hillmer and Robert Brunner
Photonics 2023, 10(5), 556; https://doi.org/10.3390/photonics10050556 - 10 May 2023
Cited by 7 | Viewed by 3520
Abstract
This work provides a comprehensive analysis of the maximum chromatic axial split of two-element hyperchromats, with the distance between the two lenses being a key variable. Purely refractive and diffractive systems are considered, as well as hybrid layouts combining refractive and diffractive elements. [...] Read more.
This work provides a comprehensive analysis of the maximum chromatic axial split of two-element hyperchromats, with the distance between the two lenses being a key variable. Purely refractive and diffractive systems are considered, as well as hybrid layouts combining refractive and diffractive elements. In order to achieve extreme chromatic axial splitting and accordingly a minimum equivalent Abbe number for lens combinations, a three-step procedure was used. In the first paraxial step, purely optical quantities such as focal lengths of the lenses, inter-lens distances and dispersion properties of the lenses were investigated. In the second step, which also takes place in the paraxial domain, additional geometric boundary conditions such as the radii, diameters and thicknesses of the lenses are taken into account. The results of this step serve as an input for the final optimization using optical design software, which derives practical solutions for minimum equivalent Abbe numbers with diffraction-limited image quality. As a significant result, the comparison with directly cemented lens doublets shows that the introduction of a distance between the elements allows for a much stronger chromatic decomposition for refractive, diffractive and also hybrid combinations. Quantitatively, the minimum equivalent Abbe number for refractive systems is reduced from 2.5 (without spacing) to 1.79 (with spacing). For hybrid combinations, a corresponding reduction from 0.4 to 0.29 is achieved. Full article
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13 pages, 2883 KB  
Article
New Hybrid PVC/PVP Polymer Blend Modified with Er2O3 Nanoparticles for Optoelectronic Applications
by Alhulw H. Alshammari, Majed Alshammari, Mohammed Ibrahim, Khulaif Alshammari and Taha Abdel Mohaymen Taha
Polymers 2023, 15(3), 684; https://doi.org/10.3390/polym15030684 - 29 Jan 2023
Cited by 43 | Viewed by 4372
Abstract
Polymer blend hybrid nanocomposites are of great importance for future optoelectronic applications. This paper presents the preparation of new polymer blend hybrid nanocomposites based on PVC/PVP modified with Er2O3 nanoparticles. A low-cost solution casting method has been used to prepare [...] Read more.
Polymer blend hybrid nanocomposites are of great importance for future optoelectronic applications. This paper presents the preparation of new polymer blend hybrid nanocomposites based on PVC/PVP modified with Er2O3 nanoparticles. A low-cost solution casting method has been used to prepare the polymer nanocomposites at 0.0, 0.1, 0.3 and 0.6 wt% of Er2O3. X-ray diffraction (XRD), Fourier transform infrared (FTIR), Raman spectroscopy, and environmental scanning electron microscopy (ESEM) measurements have all been used to examine the impact of a varying wt% of Er2O3 on the structural and optical characteristics of PVP/PVC polymer blends. The PVC/PVP polymer blend and Er2O3 nanoparticles showed a strong interaction, which was validated by XRD, FTIR, and Raman spectrum investigations. The SEM micrographs showed a remarkable complexation among the components of the polymer nanocomposites. The activation energies for thermal decomposition of PVC/PVP doped with different Er2O3 concentrations were less than that of the pure polymer film. The linear and nonlinear refractive indexes, dispersion energy, optical susceptibility and the energy gap values were found to be Er2O3 concentration-dependent. With an increase in Er2O3 concentration to 0.1 and 0.3 wt%, the dispersion energy and nonlinear refractive index improved, and thereafter decreased when the concentration was further increased to 0.6For the film doped with 0.1 wt% Er2O3, the optical band gap (Eopt) of the composite film enhanced by about 13%. The optical absorption measurements revealed clear improvements with the addition of erbium oxide. Higher refractive index values of PVC/PVP/Er2O3 films qualify the polymer blend as a cladding for electro-optic modulators. Our results indicated that the PVC/PVP/Er2O3 polymer films could be suitable for optoelectronic space applications. Full article
(This article belongs to the Special Issue Optical Polymer Materials and Devices for Space Based Applications)
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20 pages, 6177 KB  
Article
Hybrid Refractive-Diffractive Lens with Reduced Chromatic and Geometric Aberrations and Learned Image Reconstruction
by Viktoria V. Evdokimova, Vladimir V. Podlipnov, Nikolay A. Ivliev, Maxim V. Petrov, Sofia V. Ganchevskaya, Vladimir A. Fursov, Yuriy Yuzifovich, Sergey O. Stepanenko, Nikolay L. Kazanskiy, Artem V. Nikonorov and Roman V. Skidanov
Sensors 2023, 23(1), 415; https://doi.org/10.3390/s23010415 - 30 Dec 2022
Cited by 22 | Viewed by 6088
Abstract
In this paper, we present a hybrid refractive-diffractive lens that, when paired with a deep neural network-based image reconstruction, produces high-quality, real-world images with minimal artifacts, reaching a PSNR of 28 dB on the test set. Our diffractive element compensates for the off-axis [...] Read more.
In this paper, we present a hybrid refractive-diffractive lens that, when paired with a deep neural network-based image reconstruction, produces high-quality, real-world images with minimal artifacts, reaching a PSNR of 28 dB on the test set. Our diffractive element compensates for the off-axis aberrations of a single refractive element and has reduced chromatic aberrations across the visible light spectrum. We also describe our training set augmentation and novel quality criteria called “false edge level” (FEL), which validates that the neural network produces visually appealing images without artifacts under a wide range of ISO and exposure settings. Our quality criteria (FEL) enabled us to include real scene images without a corresponding ground truth in the training process. Full article
(This article belongs to the Special Issue State-of-the-Art Optical Sensors Technology in Russia 2021-2022)
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10 pages, 5189 KB  
Communication
Design of a Hybrid Refractive/Diffractive Lens System for Broadband UV
by Yuan Hu, Jiaqi Huo and Binpeng Cheng
Sensors 2023, 23(1), 143; https://doi.org/10.3390/s23010143 - 23 Dec 2022
Cited by 7 | Viewed by 3537
Abstract
Traditional broadband UV optical designs often have complex structural problems and cannot meet the current requirements of light and miniaturization. In this study, we first design the substrate material of double-layer diffractive optical elements (DOEs) in the 0.23–0.8 μm band, optimize the diffraction [...] Read more.
Traditional broadband UV optical designs often have complex structural problems and cannot meet the current requirements of light and miniaturization. In this study, we first design the substrate material of double-layer diffractive optical elements (DOEs) in the 0.23–0.8 μm band, optimize the diffraction efficiency and analyze the effect of the angle of incidence on the diffraction efficiency of double-layer DOEs. Second, we design a refractive lens system and a refractive/diffractive hybrid lens system with double-layer DOEs designed for a wide UV wavelength range of 0.23–0.8 μm, a half field of view of 15 mm, an objective aperture of 0.1 and a magnification of 1. The refractive/diffractive hybrid lens system designed with seven lenses produces a higher image quality than the refractive lens system. The novel design is an effective solution to the problem of the low transmission rate of traditional UV refractive lens systems. Full article
(This article belongs to the Section Sensing and Imaging)
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11 pages, 4077 KB  
Article
Computational Imaging in Dual-Band Infrared Hybrid Optical System with Wide Temperature Range
by Shan Mao, Huaile Nie, Tao Lai and Na Xie
Sensors 2022, 22(14), 5291; https://doi.org/10.3390/s22145291 - 15 Jul 2022
Cited by 8 | Viewed by 2583
Abstract
The special dispersion and temperature characteristics of diffractive optical element (DOE) make them widely used in optical systems that require both athermalization and achromatic aberrations designs. The multi-layer DOE (MLDOE) can improve the diffraction efficiency of the overall broad waveband, but its diffraction [...] Read more.
The special dispersion and temperature characteristics of diffractive optical element (DOE) make them widely used in optical systems that require both athermalization and achromatic aberrations designs. The multi-layer DOE (MLDOE) can improve the diffraction efficiency of the overall broad waveband, but its diffraction efficiency decreases with changes in ambient temperature. When the ambient temperature changes, the micro-structure heights of MLDOE and the refractive index of the substrate materials change, ultimately affecting its diffraction efficiency, and, further, the optical transform function (OTF). In this paper, the influence of ambient temperature on the diffraction efficiency of MLDOE in a dual-infrared waveband is proposed and discussed, the diffraction efficiency of MLDOE caused by ambient temperature is derived, and a computational imaging method that combines optical design and image restoration is proposed. Finally, a dual-infrared waveband infrared optical system with athermalization and achromatic aberrations corrected based on computational imaging method is designed. Results show that this method can effectively reduce the diffraction efficiency of MLDOE by ambient temperature and improve the imaging quality of hybrid optical systems. Full article
(This article belongs to the Section Sensor Networks)
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14 pages, 2889 KB  
Article
Characterisation of Holographic Recording in Environmentally Stable Photopolymerisable Glass
by Tatsiana Mikulchyk, Pamela Stoeva, Alicja Kaworek, Mohamed Oubaha, Brian Rogers, Suzanne Martin, Dervil Cody and Izabela Naydenova
Appl. Sci. 2022, 12(12), 5969; https://doi.org/10.3390/app12125969 - 11 Jun 2022
Cited by 11 | Viewed by 3520
Abstract
Photopolymerisable glasses are holographic recording materials which provide good recording capability, improved dimensional stability, and negligible shrinkage. Recently, a novel photopolymerisable hybrid sol-gel (PHSG) for holographic recording of volume gratings has been reported. The PHSG has significantly improved gelation time and high water [...] Read more.
Photopolymerisable glasses are holographic recording materials which provide good recording capability, improved dimensional stability, and negligible shrinkage. Recently, a novel photopolymerisable hybrid sol-gel (PHSG) for holographic recording of volume gratings has been reported. The PHSG has significantly improved gelation time and high water resistance, both of which make it an attractive material for mass production of holographic optical elements (HOEs) with no sensitivity to ambient humidity. In order to achieve full control over the performance of the material and further improve its properties, a study of grating formation under holographic patterning is essential. This paper reports characterisation of the grating recording in PHSG. The approach is based on the analysis of grating parameters during exposure and post-recording dark processes. The obtained results suggest that photopolymerisation of the methacrylate groups is the main contributor to the creation of refractive index modulation during exposure. During the dark process, the enhancement of the refractive index modulation is observed, probably due to further polycondensation. The observations made facilitate controlled and predictable diffraction efficiency of gratings recorded on the PHSG, thereby furthering the prospect of the development of HOEs with customisable specification. Full article
(This article belongs to the Special Issue Photosensitive Materials and Their Applications)
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20 pages, 6215 KB  
Article
Microstructure Study and Linear/Nonlinear Optical Performance of Bi-Embedded PVP/PVA Films for Optoelectronic and Optical Cut-Off Applications
by H. Elhosiny Ali, Mohammad Abdel-Aziz, Ashraf Mahmoud Ibrahiem, Mahmoud A. Sayed, Hisham S. M. Abd-Rabboh, Nasser S. Awwad, Hamed Algarni, Mohd. Shkir and M. Yasmin Khairy
Polymers 2022, 14(9), 1741; https://doi.org/10.3390/polym14091741 - 25 Apr 2022
Cited by 59 | Viewed by 4101
Abstract
Hybrid polymer films of polyvinyl pyrrolidone (PVP)/polyvinyl alcohol (PVA) embedded with gradient levels of Bi-powder were prepared using a conventional solution casting process. XRD, FTIR, and SEM techniques have been used to examine the micro/molecular structure and morphology of the synthesized flexible films. [...] Read more.
Hybrid polymer films of polyvinyl pyrrolidone (PVP)/polyvinyl alcohol (PVA) embedded with gradient levels of Bi-powder were prepared using a conventional solution casting process. XRD, FTIR, and SEM techniques have been used to examine the micro/molecular structure and morphology of the synthesized flexible films. The intensities of the diffraction peaks and transmission spectrum of the PVP/PVA gradually declined with the introduction of Bi-metal. In addition, filler changes the microstructure surface of the pure film. The modification in the microstructure leads to an enhancement in the optical absorption characteristic of the blend films. The indirect allowed transition energy was calculated via Tauc’s and ASF (Absorption Spectra Fitting) models. The decrease in the hybrid film’s bandgap returns to the localized states in the forbidden region, which led the present films to be suitable for photo-electric, solar cell, etc., applications. The relation between the transition energy and the refractive index was studied. The enhancement in the refractive index with Bi-metal concentrations led to use the as-prepared films in optical sensors. The rise of Bi-metal concentrations leads also to the improvement of the nonlinear susceptibility and refractive parameters. The optical limiting characteristics revealed that the higher concentration dopant films reduce the light transmission intensity which is appropriate for laser attenuation and optical limiting in photonic devices. The results suggest that hybrid films are promising materials in a wide range of opto-electronic applications. Full article
(This article belongs to the Section Polymer Composites and Nanocomposites)
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