Search Results (35)

Understanding mineral–fluid interactions in shale under supercritical CO₂ (scCO₂) conditions is relevant for assessing long-term geochemical containment. This study characterizes mineralogical transformations and elemental redistribution in five Caney Shale samples serving as proxies for reservoir (R1, R2, R3) and caprock (D1, D2) facies, subjected to 30-day static exposure to pure scCO₂ at 60 °C and 17.23 MPa (2500 psi), with no brine or impurities introduced. SEM-EDS analyses were conducted before and after exposure, with mineral phases classified into silicates, carbonates, sulfides, and organic matter. Initial compositions were dominated by quartz (38–47 wt.%), illite (16–23 wt.%), carbonates (12–18 wt.%), and organic matter (8–11 wt.%). Post-exposure, carbonate loss ranged from 15 to 40% in reservoir samples and up to 20% in caprock samples. Illite and K-feldspar showed depletion of Fe²⁺, Mg²⁺, and K⁺ at grain edges and cleavages, while pyrite underwent oxidation with Fe redistribution. Organic matter exhibited scCO₂-induced surface alteration and apparent sorption effects, most pronounced in R2 and R3. Elemental mapping revealed Ca²⁺, Mg²⁺, Fe²⁺, and Si⁴⁺ mobilization near reactive interfaces, though no secondary mineral precipitates formed. Reservoir samples developed localized porosity, whereas caprock samples retained more structural clay integrity. The results advance understanding of mineral reactivity and elemental fluxes in shale-based CO₂ sequestration. Full article

The mechanisms underlying formation energy depletion after initial fracturing and post-refracturing production decline in shale oil horizontal wells remain poorly understood. This study proposes a novel numerical simulation framework for refracturing processes based on a three-dimensional fully coupled hydromechanical model. By dynamically reconfiguring the in situ stress field through integration of production data from initial fracturing stages, our approach enables precise control over fracture propagation trajectories and intensities, thereby enhancing reservoir stimulation volume (RSV) and residual oil recovery. The implementation of fully coupled hydromechanical simulation reveals two critical findings: (1) the 70 m fracture half-length generated during initial fracturing fails to access residual oil-rich zones due to insufficient fracture network complexity; (2) a 3–5° stress reorientation combined with reservoir repressurization before refracturing significantly improves fracture network interconnectivity. Field validation demonstrates that refracturing extends fracture half-lengths to 97–154 m (38–120% increase) and amplifies RSV by 125% compared to initial operations. The developed seepage–stress coupling methodology establishes a theoretical foundation for optimizing repeated fracturing designs in unconventional reservoirs, providing critical insights into residual oil mobilization through engineered stress field manipulation. Full article

Efficient and accurate modeling of rock deformation and well production in weakly consolidated reservoirs requires reliable and accurate reservoir modeling techniques. During hydrocarbon production, the reservoir pressure is dropped, and rock compaction is induced. In such depletion-induced reservoir rock deformation, both elastic and plastic deformation can be generated. The numerical investigation of depletion-induced plasticity in shale oil reservoirs and its impact on coupled reservoir modeling helps provide insights into the optimization of horizontal well productivity. This study introduces a coupled flow and geomechanical model that considers porous media flow, elastoplastic deformation, horizontal well production, and the coupling between the flow and geomechanical processes. Simulation results are then provided along with numerical modeling parameters. Effects of relevant parameters, including depletion magnitude, rock mechanical properties, and hydraulic fracture parameters, jointly affect rock deformation, rock skeleton damage, and horizontal well productivity. Depletion-induced plasticity, stress, pressure, and subsidence are all characterized by the solution strategy. In addition, the implementation of direct and iterative solvers and the usage of full coupling and sequential coupling strategies are investigated, and the associated solver performance is quantified. It helps evaluate the numerical efficiency in the highly nonlinear numerical system. This study provides an efficient coupled flow and elastoplastic model for the simulation of depletion in weakly consolidated reservoirs. Full article

Deep shale formations pose significant challenges in forming high-conductivity fractures, leading to low ultimate recoverable reserves (EUR) per well under conventional fracturing techniques. Dense-cutting fracturing is a commonly employed method to enhance the EUR of individual wells; however, the critical process parameters influencing EUR remain unclear. This study develops a novel EUR calculation model tailored for deep shale gas dense-cutting, integrating the Warren-Root model with the constant-volume gas reservoir material balance equation. The model comprehensively incorporates Knudsen diffusion and adsorption-desorption phenomena in deep shale gas, corrects apparent permeability, and employs the finite element method to simulate dynamic pressure depletion during production. The study examines the impact of fracture half-lengths, cluster spacing, fracture conductivity and horizontal section lengths on EUR under tight-cutting fracturing. Orthogonal experiments combined with multiple linear regression analysis reveal the hierarchy of influence among the four factors on EUR: horizontal section length > fracture half-length > cluster spacing > fracture conductivity. The study derives EUR correlation expressions that incorporate the effects of crack half-length, cluster spacing, fracture conductivity, and horizontal segment length. The orthogonal experimental results indicate that EUR exhibits positive correlations with crack half-length, fracture conductivity, and horizontal segment length, while showing a negative correlation with cluster spacing. The multiple regression equation achieves a coefficient of determination (R²) of 0.962 and an average relative error of 3.79%, outperforming traditional prediction methods in both accuracy and computational simplicity. The findings are of substantial significance for the rapid estimation of EUR in individual wells following deep shale gas fracturing and offer valuable theoretical insights for practical engineering applications. Full article

Multi-layer horizontal well development and hydraulic fracturing are key techniques for enhancing production from shale oil reservoirs. During well development, the fracturing performance and well-pad production are affected by depletion-induced stress changes. Previous studies generally focused on the stress and fracturing interference within the horizontal layers, and the infilled multi-layer development was not thoroughly investigated. This study introduces a modeling workflow based on finite element and displacement discontinuity methods that accounts for dynamic porous media flow, geomechanics, and hydraulic fracturing modeling. It quantitatively characterizes the in situ stress alteration in various layers caused by the historical production of parent wells and quantifies the hydraulic fracturing interference in infill wells. In situ stress changes and reorientation and the non-planar propagation of hydraulic fractures were simulated. Thus, the workflow characterizes infill-well fracturing interferences in shale oil reservoirs developed by multi-layer horizontal wells. Non-planar fracturing in infill wells is affected by the parent-well history production, infilling layers, and cluster number. They also affect principal stress reorientations and reversal of the fracturing paths. Interwell interference can be decreased by optimizing the infilling layer, infill-well fracturing timing, and cluster numbers. This study extends the numerical investigation of interwell fracturing interference to multi-layer development. Full article

Refracturing is an important technology for tapping remaining oil and gas areas and enhancing recovery in old oilfields. However, a complete and detailed refracturing timing optimization scheme has not yet been proposed. In this paper, based on the finite volume method and the embedded discrete fracture model, a new coupled fluid flow/geomechanics pore-elastic-fractured reservoir model is developed. The COMSOL 3.5 commercial software was used to verify the accuracy of our model, and by studying the influence of matrix permeability, initial stress difference, cluster spacing, and fracture half-length on the orientation of maximum horizontal stress, a timing optimization method for refracturing is proposed. The results of this paper show that the principle of optimizing the refracturing timing is to avoid the time window where the percentage of Type I (Type I indicates that stress inversion has occurred, $0^{\circ }\le \alpha \le {20}^{\circ }$; Type II indicates that the turning degree is strong, ${20}^{\circ }<\alpha \le {70}^{\circ }$; and Type III indicates less stress reorientation, ${70}^{\circ }<\alpha \le {90}^{\circ }$) stress reorientation area is relatively large, so that the fractures can extend perpendicular to the horizontal wellbore. At the same time, the simulation results show that with the increase in production time, the percentage of Type I and Type II increases first and then decreases, while the percentage of Type III decreases first and then increases. When the reservoir permeability, stress difference, and cluster spacing are larger, the two types of refracturing measures can be implemented earlier. But, with the increase in fracture half-length, the timing of refracturing Method I is earlier, and the timing of refracturing Method II is later. The research results of this paper are of great significance to the perfection of the refracturing theory and the optimization of refracturing design. Full article

The viscoelastic behavior of shale reservoirs indeed impacts permeability evolution and further gas flow characteristics, which have been experimentally and numerically investigated. However, its impact on the gas depletion profile at the field scale has seldom been addressed. To compensate for this deficiency, we propose a multiscaled viscoelasticity constitutive model, and furthermore, a full reservoir deformation–fluid flow coupled model is formed under the frame of the classical triple-porosity approach. In the proposed approach, a novel friction-based creep model comprising two distinct series of parameters is developed to generate the strain–time profiles for hydraulic fracture and natural fracture systems. Specifically, an equation considering the long-term deformation of hydraulic fracture, represented by the softness of Young’s modulus, is proposed to describe the conductivity evolution of hydraulic fractures. In addition, an effective strain permeability model is employed to replicate the permeability evolution of a natural fracture system considering viscoelasticity. The coupled model was implemented and solved within the framework of COMSOL Multiphysics (Version 5.4). The proposed model was first verified using a series of gas production data collected from the Barnett shale, resulting in good fitting results. Subsequently, a numerical analysis was conducted to investigate the impacts of the newly proposed parameters on the production process. The transient creep stage significantly affects the initial permeability, and its contribution to the permeability evolution remains invariable. Conversely, the second stage controls the long-term permeability evolution, with its dominant role increasing over time. Creep deformation lowers the gas flow rate, and hydraulic fracturing plays a predominant role in the early term, as the viscoelastic behavior of the natural fracture system substantially impacts the long-term gas flow rate. A higher in situ stress and greater formation depth result in significant creep deformation and, therefore, a lower gas flow rate. This work provides a new tool for estimating long-term gas flow rates at the field scale. Full article

With the increasing demand for energy and the depletion of traditional resources, the development of alternative energy sources has become a critical issue. Shale gas, as an abundant and widely distributed resource, has great potential as a substitute for conventional natural gas. However, due to the low permeability of shale-gas reservoirs, efficient extraction poses significant challenges. The application of hydraulic fracturing technology has been proven to effectively enhance rock permeability, but the influence of environmental factors on its efficiency remains unclear. In this study, we investigate the impact of gas fracturing on shale-gas extraction efficiency under varying environmental conditions using numerical simulations. Our simulations provide a comprehensive analysis of the physical changes that occur during the fracturing process, allowing us to evaluate the effects of gas fracturing on rock mechanics and permeability. We find that gas fracturing can effectively induce internal fractures within the rock, and the magnitude of tensile stress decreases gradually during the process. The boundary pressure of the rock mass is an important factor affecting the effectiveness of gas fracturing, as it exhibits an inverse relationship with the gas content present within the rock specimen. Furthermore, the VL constant demonstrates a direct correlation with gas content, while the permeability and PL constant exhibit an inverse relationship with it. Our simulation results provide insights into the optimization of gas fracturing technology under different geological parameter conditions, offering significant guidance for its practical applications. Full article

The extraction of shale gas from onshore and offshore shale gas reservoirs will play an important role in meeting China’s future energy needs, which will not only help alleviate the energy crisis but also contribute to climate change mitigation. As for the target shale formation enriched by thin sandstone layers in typical basins, an analytical calculation method is proposed to perform pressure analysis for multi-layer shale gas reservoirs considering the adsorption–desorption characteristics of shale layer and the interlayer cross-flow. Firstly, the changes in storage capacity and flow resistance are obtained by using the distance of investigation equation. According to the electrical analogy, the equivalent total storage capacity and flow resistance can be calculated considering the sandstone-shale crossflow. Because production from one time step to the other causes depletion of the storage capacity, the reservoir pressure in different time steps can be calculated based on the material balance equation. Numerical models have been constructed based on three typical reservoir lithology combinations (sandstone-shale, shale-sandstone-shale and sandstone-shale-sandstone) to validate the accuracy of the proposed analytical calculation method. Furthermore, three important factors (porosity, the ratio of horizontal/vertical permeability (k_h/k_v) and the layer thickness) have been selected for the sensitivity analysis to verify the stability. The comparative results indicate that the proposed analytical calculation method is suitable for pressure analysis in shale gas reservoirs containing thin sandstone layers. It will provide theoretical support for the further enhancement of the production of this type of gas reservoirs. Full article

Molecular and stable carbon isotopic compositions of 32 crude oils from the Kekeya area of the Southwest Depression, Tarim Basin, were analyzed comprehensively to clarify oil groups and trace oil sources. The results indicate that lacustrine shale sequences within the Upper-Middle Permian Pusige Formation (P_3–2p) are the major effective oil sources; the thermal maturation effects exert the crucial impact on geochemical compositions of crude oils. In the Kekeya structural belt, crude oils produced from the Lower-Neogene, Middle-Paleogene and Middle-Cretaceous sandstone reservoirs were generated mainly from deeply buried P_3–2p at the late-to-high maturity stage. These condensates are depleted in terpanes, steranes and triaromatic steranes and enriched in adamantanes and diamantanes. The evaluated thermal maturity levels of crude oils by terpanoids and steranes are generally lower than that of diamondoids, implying at least two phases of oil charging. In the Fusha structural belt, oils produced from the Lower-Jurassic reservoirs (J₁s) of Well FS8 were generated from the local P_3–2p at the middle to late mature stage. On the contrary, these oils are relatively rich in molecular biomarkers such as terpanes and steranes and depleted in diamondoids with only adamantanes detectable. The P_3–2p-associated oils can migrate laterally from the Kekeya to Fusha structural belt, but not to the location of Well FS8. The Middle-Lower Jurassic (J_1–2) lacustrine shales as the major oil sources are limited to the area around Well KS101 in the Kekeya structural belt. Crude oils originated from J_1–2 and P_3–2p can mix together within the Cretaceous reservoirs of Well KS101 by presenting the concurrence of high concentrations of terpane and sterane biomarkers and diamondoids as well as 2–4% ¹³C-enriched n-alkanes than those of P_3–2p derived oils. This study provides a better understanding of hydrocarbon sources and accumulation mechanisms and hence petroleum exploration in this region. Full article

Traditional research on apparent permeability in shale reservoirs has mainly focussed on effects such as poromechanics and porosity-assisted adsorption layers. However, for a more realistic representation of field conditions, a comprehensive multi-scale and multi-flowing mechanism model, considering the fracturing process, has not been thoroughly explored. To address this research gap, this study introduces an innovative workflow for dynamic permeability assessment. Initially, an accurate description of the pore size distribution (PSD) within three major mineral types in shale is developed using focussed ion beam-scanning electron microscopy (FIB-SEM) and nuclear magnetic resonance (NMR) data. Subsequently, an apparent permeability model is established by combining the PSD data, leading to the derivation of dynamic permeability. Finally, the PSD-related dynamic permeability model is refined by incorporating the effects of imbibition resulting from the fracturing process preceding shale gas production. The developed dynamic permeability model varies with pore and fracture pressures in the shale reservoir. The fracturing process induces water blockage, water-film formation, and water-bridging phenomena in shale, requiring additional pressure inputs to counteract capillary effects in hydrophilic minerals in shale, But also increases the overall permeability from increasing permeability at larger scale pores. Unlike traditional reservoirs, the production process commences when the fracture is depleted to 1–2 MPa exceeds the pore pressure, facilitated by the high concentration of hydrophobic organic matter pores in shale, this phenomenon explains the gas production at the intial production stage. The reduction in adsorption-layer thickness resulting from fracturing impacts permeability on a nano-scale by diminishing surface diffusion and the corresponding slip flow of gas. this phenomenon increases viscous-flow permeability from enlarged flow spacing, but the increased viscous flow does not fully offset the reduction caused by adsorbed-gas diffusion and slip flow. In addition to the phenomena arising from various field conditions, PSD in shale emerges as a crucial factor in determining dynamic permeability. Furthermore, considering the same PSD in shale, under identical pore spacing, the shape factor of slit-like clay minerals significantly influences overall permeability characteristics, much more slit-shaped pores(higher shape factor) reduce the overall permeability. The dynamic permeability-assisted embedded discrete fracture model (EDFM) showed higher accuracy in predicting shale gas production compared to the original model. Full article

The current oil recovery of the Lucaogou shale oil reservoir is predicted to be about 7.2%. It is crucial to explore improved oil recovery (IOR) technologies, and further experimental and field research needs to be conducted to study the complex mechanism. In this study, laboratory experiments were carried out to investigate the performance of one-step and multi-step depletion, CO₂ huff-n-puff, and surfactant imbibition based on nuclear magnetic resonance (NMR). The sweep efficiencies were assessed via NMR imaging. In addition, hybrid methods of combining surfactant with CO₂ huff-n-puff and the performance of injection sequence on oil recovery were investigated. The experimental results indicate that oil recoveries of depletion development at different initial pressures range from 4% to 11%. CO₂ huff-n-puff has the highest oil recovery (30.45% and 40.70%), followed by surfactant imbibition (24.24% and 20.89%). Pore size distribution is an important factor. After three more cycles of surfactant imbibition and CO₂ huff-n-puff, the oil recovery can be increased by 11.27% and 26.27%, respectively. Surfactant imbibition after CO₂ huff-n-puff shows a viable method. Our study can provide guidance and theoretical support for shale oil development in the Lucaogou shale oil reservoir. Full article

Gas reservoirs have significant engineering characteristics of injection and extraction. The reservoir cap rock is subjected to cyclic alternating loading and has the potential risk of seal failure. Therefore, it is necessary to study the stress−percolation−damage mechanism of the reservoir cap rock in depleted gas reservoirs. The rock Mechanics Test System (MTS) was used to study the permeability characteristics of a typical mud shale cap layer under different loading and unloading rates, analyze the deformation characteristics and permeability performance evolution law of the rock under the confining pressure alternation, and study the effects of loading and unloading rate, confining pressure and number of cycles on the permeability of the cap rock. The test results show that with the increase in the number of cycles, the hysteresis loop moves in the direction of axial strain increase offset. The overall morphology is presented as an elongated type, and the damage of the specimen is small in the cyclic confining pressure; At the beginning of the cycling period, the permeability decreases with the increase in the confining pressure in the form of a negative exponential. At the later stage of the cycling period, the permeability basically stays unchanged, and is maintained at a low level; At low confining pressure, permeability also decreases in a negative exponential form with the increase in the number of confining pressure cycles; The greater the loading and unloading rate at the beginning of the cycle, the more the permeability decreases; There is a tendency of sealing improvement under cyclic loading in the gas storage of depleted reservoirs with mud shale as the cap layer. The results of the study can provide technical parameters for the evaluation of the cap sealing of gas storage of depleted reservoirs. Full article

The Chang 7 shale oil reservoir has low natural energy and is both tight and highly heterogeneous, resulting in significant remaining oil after depletion development. CO₂ huff and puff (huff-n-puff) is an effective way to take over from depletion development. Numerous scholars have studied and analyzed the CO₂ huff-n-puff mechanism and parameters based on laboratory core sample huff-n-puff experiments. However, experimental procedures are not comprehensive, leading to more general studies of some mechanisms, and existing CO₂ huff-n-puff experiments struggle to reflect the effect of actual reservoir heterogeneity due to the limited length of the experimental core samples. In this paper, CO₂ huff-n-puff laboratory experiments were performed on short (about 5 cm) and long (about 100 cm) core samples from the Chang 7 shale oil reservoir, and the microscopic pore fluid utilization in the short samples was investigated using a nuclear magnetic resonance (NMR) technique. We then analyzed and discussed the seven controlling factors of CO₂ huff-n-puff and their recovery-enhancing mechanisms. The experimental results show that the cumulative recovery increased with the number of huff-n-puff cycles, but the degree of cycle recovery decreased due to the limitation of the differential pressure of the production. The significant increase in recovery after the CO₂ mixed-phase drive was achieved by increasing the minimum depletion pressure as well as the gas injection amount. The soaking time was adjusted appropriately to ensure that the injected energy was thoroughly utilized; too short or too long a soaking time was detrimental. The pressure depletion rate was the main factor in the CO₂ huff-n-puff effect in shale. If the pressure depletion rate was very high, the effective permeability loss was larger. In the CO₂ huff-n-puff process of the Chang 7 shale oil reservoir, the improvement in oil recovery was mainly contributed to by mesopores and small pores. The huff-n-puff experiments using long cores could better characterize the effect of heterogeneity on the huff-n-puff effect than short cores. Full article

The development of shale gas reservoirs often involves the utilization of horizontal well segmental multi-stage fracturing techniques. However, these reservoirs face challenges, such as rapid initial wellhead pressure and production decline, leading to extended periods of low-pressure production. To address these issues and enhance the production during the low-pressure stage, pressurized mining is considered as an effective measure. Determining the appropriate pressurization target and method for the shale gas wells is of great practical significance for ensuring stable production in shale gas fields. This study takes into account the current development status of shale gas fields and proposes a three-stage pressurization process. The process involves primary supercharging at the center station of the block, secondary supercharging at the gas collecting station, and the introduction of a small booster device located behind the platform separator and in front of the outbound valve group. By incorporating a compressor, the wellhead pressure can be reduced to 0.4 MPa, resulting in a daily output of 12,000 to 14,000 cubic meters from the platform. Using a critical liquid-carrying model for shale gas horizontal wells, this study demonstrates that reducing the wellhead pressure decreases the critical flow of liquid, thereby facilitating the discharge of the accumulated fluid from the gas well. Additionally, the formation pressure of shale gas wells is estimated using the mass balance method. This study calculates the cumulative production of different IPR curves based on the formation pressure. It develops a dynamic production decline model for gas outlet wells and establishes a relationship between the pressure depletion of gas reservoirs and the cumulative gas production before and after pressurization of H10 −2 and H10 −3 wells. The final estimated ultimate recovery of two wells is calculated. In conclusion, the implementation of multi-stage pressurization, as proposed in this study, effectively enhances the production of, and holds practical significance for, stable development of shale gas fields. Full article